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Plasticizer

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alkyl alcohols meet these specifications and are common plasticizers. Ortho-phthalate esters have traditionally been the most dominant plasticizers, but regulatory concerns have led to the move away from classified substances to non-classified which includes high molecular weight ortho-phthalates and other plasticisers, especially in Europe.
840:, energy yield per gram of propellant, or similar indices) of the propellant. An energetic plasticizer improves the physical properties of an energetic material while also increasing its specific energy yield. Energetic plasticizers are usually preferred to non-energetic plasticizers, especially for solid 844:. Energetic plasticizers reduce the required mass of propellant, enabling a rocket vehicle to carry more payload or reach higher velocities than would otherwise be the case. However, safety or cost considerations may demand that non-energetic plasticizers be used, even in rocket propellants. The solid 214:
is dependent on both temperature and plasticizer concentration. Below a certain concentration, referred to as the crossover concentration, a plasticizer can decrease the modulus of a material. The material's glass transition temperature will decrease, however, at all concentrations. In addition to a
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Plasticizers for polymers are either liquids with low volatility or solids. According to 2017 data, the total global market for plasticizers was 7.5 million metric tonnes. In North America the 2017 volume was ~1.01 million metric tonnes and in Europe the figure was 1.35 million metric tonnes, split
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of polycarboxylic acids with linear or branched aliphatic alcohols of moderate chain length. These compounds are selected on the basis of many critieria including low toxicity, compatibility with the host material, nonvolatility, and expense. Phthalate esters of straight-chain and branched-chain
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on to the gypsum particles, giving them a negative charge, which leads to repulsion between particles. Lignin and naphthalene sulfonate plasticizers are organic polymers. The long molecules wrap themselves around the gypsum particles, giving them a highly negative charge so that they repel each
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and strength. The strength of concrete is inversely proportional to the amount of water added, i.e., the water-cement (w/c) ratio. In order to produce stronger concrete, less water is added (without "starving" the mix), which makes the concrete mixture less workable and difficult to mix,
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mixtures to improve workability. In order to reduce the energy consumed drying wallboard, less water is added, which makes the gypsum mixture very unworkable and difficult to mix, necessitating the use of plasticizers, water reducers, or dispersants. Some studies also show that too much
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lignosulfonate dispersant could result in a set-retarding effect. Data showed that amorphous crystal formations occurred that detracted from the mechanical needle-like crystal interaction in the core, preventing a stronger core. The sugars, chelating agents in lignosulfonates such as
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The molecules of plasticizer take control over mobility of the chain - a polymer chain does not show an increase of the free volume around polymer ends. If plasticizer/water creates hydrogen bonds with hydrophilic parts of the polymer, the associated free volume can be decreased.
734:, although newer products based on polycarboxylic ethers are now available. Traditional lignosulfonate-based plasticisers, naphthalene and melamine sulfonate-based superplasticisers disperse the flocculated cement particles through a mechanism of electrostatic repulsion (see 238:
plasticizers are selected based upon cost-performance evaluation. The rubber compounder must evaluate ester plasticizers for compatibility, processibility, permanence and other performance properties. The wide variety of ester chemistries that are in production include
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temperature for the plastic and making it softer. It was later shown that the free volume explanation could not account for all of the effects of plasticization. The mobility of a polymer chain is more complex in the presence of plasticizer than what the
582:- based plasticizers provide excellent compatibility with a range of plastic materials and synthetic rubbers (specifically nitrile rubber and neoprene), superior properties at low temperatures, and good oil resistivity. Some examples are: 759:(PC), work differently from sulfonate-based superplasticizers, giving cement dispersion by steric stabilisation. This form of dispersion is more powerful in its effect and gives improved workability retention to the cementitious mix. 349:" is often attributed to plasticizers or their degradation products, however, multiple studies on the makeup of the smell do not find phthalates in appreciable amounts, likely due to their extremely low volatility and vapor pressure. 148:
between various end-use applications with a chemical type trend moving to higher molecular weight (HMW) orthophthalates and alternative types following regulatory issues concerning lower molecular weight (LMW) orthophthalates.
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Geiss, O.; Tirendi, S.; Barrero-Moreno, J.; Kotzias, D., "Investigation of volatile organic compounds and phthalates present in the cabin air of used private cars", Environment International 2009, 35, 1188-1195.
746:, naphthalene, and melamine sulfonate superplasticisers are organic polymers. The long molecules wrap themselves around the cement particles, giving them a highly negative charge so that they repel each other. 231:
Over the last 60 years more than 30,000 different substances have been evaluated for their suitability as polymer plasticizers. Of these, only a small number – approximately 50 – are today in commercial use.
446:. DEHP was the most common plasticizer for decades and still holds that title globally even as it has largely been replaced now with higher molecular weight phthalates and alternatives in the US and Europe 835:
for guns, often employ plasticizers to improve physical properties of the propellant binder or of the overall propellant, to provide a secondary fuel, and ideally, to improve specific energy yield (e.g.
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Migration of plasticizers out of their host plastics leads to loss of flexibility, embrittlement, and cracking. This decades-old plastic lamp cord crumbles when flexed, due to loss of the plasticizers.
935: 2232: 483:(DTDP) is the highest molecular weight phthalate plasticizer, providing greater performance at high temperature. It is the preferred plasticizer for automotive cable and wire application. 68:, either to facilitate the handling of the raw material during fabrication, or to meet the demands of the end product's application. Plasticizers are especially key to the usability of 341:
Substantial concerns have been expressed over the safety of some polymer plasticizers, especially because some low molecular weight ortho-phthalates have been classified as potential
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are isomeric with ortho phthalates but have proven to have cleaner toxicological results due to their inability to form stable monoesters during hydrolysis and metabolic breakdown.
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with some developmental toxicity reported. Plasticizers can escape plastics due to migration and abrasion of the plastic since they are not bound to the polymer matrix. The "
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condensate, although polycarboxylic ethers represent more modern alternatives. Both of these high range water reducers are used at 1/2 to 1/3 of the lignosulfonate types.
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is added to concrete to improve strength. This method of mix proportioning is especially popular when producing high-strength concrete and fiber-reinforced concrete.
1413: 474: 872: 749: 1417: 480: 1149: 434:(DEHP) also commonly known as (dioctyl phthalate, DOP or diethylhexyl phthalate), historically used in flooring materials, medical devices, myriad consumer 72:(PVC), the third most widely used plastic. In the absence of plasticizers, PVC is hard and brittle; with plasticizers, it is suitable for products such as 946:
groups, NG and BTTN have relatively low thermal stability. TMETN, DEGDN, BDNPF, and BDNPA have relatively low energies. NG and DEGDN have relatively high
1956: 477:(DIUP), used for insulation of wires and cables, car undercoating, shoes, carpets, pool liners. Good high temperature and outdoor weathering performance 632: 984: 302:, and chemical structure. Compatibility and performance attributes are key factors in developing a rubber formulation for a particular application. 99:
formulations to make them more workable and fluid for pouring, thus allowing the water contents to be reduced. Similarly, they are often added to
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and extractive compounds are mainly responsible for set retardation. These low range water reducing dispersants are commonly manufactured from
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are used in automobile interiors and other applications where resistance to high temperature is required. They have extremely low volatility.
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Adding 1-2% plasticizer per unit weight of cement is usually sufficient. Adding an excessive amount of plasticizer will result in excessive
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crossover concentration, a crossover temperature exists. Below the crossover temperature the plasticizer will also increase the modulus.
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David F. Cadogan and Christopher J. Howick "Plasticizers" in Ullmann's Encyclopedia of Industrial Chemistry 2000, Wiley-VCH, Weinheim.
366:-based plasticizers are used in situations where good resistance to water and oils is required. Some common phthalate plasticizers are: 1405: 264: 271:
applications such as tubing and hose products, flooring, wall-coverings, seals and gaskets, belts, wire and cable, and print rolls.
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are also called high range water reducers. When added to concrete mixtures, they confer a number of properties including improved
162:, giving this material improved flexibility and durability. Other polymers which can contain high loadings of plasticizers include 322:
that have effect opposite to those of plasticizers. They increase the modulus while decreasing the glass transition temperature.
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Kirby, Glen H.; Jennifer A. Lewis (2002). "Rheological property evolution in concentrated cement-polyelectrolyte suspensions".
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and is not advisable. Depending on the particular chemical used, use of too much plasticizer may result in a retarding effect.
504:(DEHT; Dioctyl terephthalate, DOTP) (Eastman Chemical Company Trademark: Eastman 168™), used as a replacement for DEHP and DINP 1832: 2291: 2242: 2211: 1296: 804:
sulfonate-based plasticisers disperse the flocculated gypsum particles through a mechanism of electrostatic repulsion (see
1942: 1449: 1001: 1050:(1) Casalini, R.; Ngai, K. L.; Robertson, C. G.; Roland, C. M. J. Polym. Sci. Part B Polym. Phys. 2000, 38, 1841–1847. 267:, and other specialty blends. This broad product line provides an array of performance benefits required for the many 856: 510:
Dibutyl terephthalate (DBT)(Eastman Chemical Trademark: Eastman Effusion™), used as a replacement for DBP and DiBP
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Diisopentyl terephthalate (DiPT)(Evonik Industries Trademark: ELATUR® DPT), used as a replacement for DBP and DiBP
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on to the cement particles, giving them a negative charge, which leads to repulsion between particles.
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necessitating the use of plasticizers, water reducers, superplasticizers, fluidizer or dispersants.
295: 2118: 2108: 1970: 1657: 1604: 1494: 571: 287: 561: 244: 41:) is a substance that is added to a material to make it softer and more flexible, to increase its 1708: 1599: 1584: 1564: 824: 706: 2123: 2001: 1756: 1484: 1442: 893: 657: 417: 200: 471:(DIDP), used for insulation of wires and cables, car undercoating, shoes, carpets, pool liners 459:(DINP), used in flooring materials, found in garden hoses, shoes, toys, and building materials 2333: 2303: 2007: 1652: 1183: 1166: 1121: 653: 190:
It was commonly thought that plasticizers work by embedding themselves between the chains of
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Capponi, S.; Alvarez, F.; Racko, D. (2020), "Free Volume in a PVME Polymer–Water Solution",
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2,2,2-trinitroethyl 2-nitroxyethyl ether and a method of preparation - US Patent 4745208
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Low to high polarity esters provide utility in a wide range of elastomers including
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Triethylene glycol di-2ethylhexanoate (Eastman Chemical Trademark: Eastman TEG-EH)
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High range superplasticizers (dispersants) have generally been manufactured from
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Alkyl sulphonic acid phenyl ester (ASE). (Lanxess Chemical Trademark: Mesamoll)
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PVC, used extensively in sewage pipes, is only useful because of plasticizers.
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Bis(2-ethylhexyl) cyclohexane-1,4-dicarboxylate (Hanwha Trademark: Eco-DEHCH)
495: 421: 346: 325: 248: 420:(benzyl butyl phthalate, BBzP) is found in vinyl tiles, traffic cones, food 1889: 1879: 1741: 1688: 1589: 1534: 1509: 1192: 776: 731: 522: 108: 73: 2135: 1624: 21: 2072: 2044: 1899: 1579: 1574: 801: 794: 724: 691: 665: 565: 396: 85: 1090: 294:. Plasticizer-elastomer interaction is governed by many factors such as 2148: 1776: 1766: 809: 739: 660:
is used broadly as a secondary plasticizer in many vinyl applications.
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Substance added to a material to make it softer and more flexible
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Plasticizers used in PVC and other plastics are often based on
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C&EN: Coverstory - Synthetic Chemistry Moves Into Concrete
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Allsopp, M. W.; Vianello, G. (2012). "Poly(Vinyl Chloride)".
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Bio-based plasticizers have been investigated, such as
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http://pubs.acs.org/cen/whatstuff/stuff/8020stuff.html
808:). In normal plasticisers, the active substances are 738:). In normal plasticisers, the active substances are 1114:"Chemical Economics Handbook Report on Plasticizers" 1059: 465:(DPHP), used in cables, wires and roofing materials 1111: 633:1,2-Cyclohexane dicarboxylic acid diisononyl ester 151:Almost 90% of polymer plasticizers, most commonly 1222:Chemical and Engineering News, 2002, 80(20), 45; 531:(TEHTM) (TOTM, Trioctyl Trimellitate plasticizer) 2325: 127:Europe's and Global Plasticiser Use by type 2017 981: 960:Conservation and restoration of plastic objects 1264:Ullmann's Encyclopedia of Industrial Chemistry 1262:Cadogan DF, Howick CJ (2000). "Plasticizers". 985:Ullmann's Encyclopedia of Industrial Chemistry 352: 1950: 1443: 1261: 977: 975: 712:Plasticizers are commonly manufactured from 555: 1957: 1943: 1450: 1436: 672: 1182: 1089: 972: 656:. They are used in niche applications. 1184:10.1146/annurev.publhealth.012809.103714 936:2,2,2-Trinitroethyl 2-nitroxyethyl ether 594:, Di-octyl Sebacate (or DOS plasticizer) 324: 217: 138: 130: 122: 92:, and electric wire insulation/coating. 20: 1352:Journal of the American Ceramic Society 1299:. www.admixtures.org.uk. Archived from 143:Europe's Plasticiser Market Trends 2017 2326: 1540:Polyethylene terephthalate (PET, PETE) 1164: 890:(NG, aka "nitro", glyceryl trinitrate) 816: 698:Plasticizers are also often used when 452:High Molecular Weight Ortho Phthalates 336: 185: 1938: 1480:Cross-linked polyethylene (PEX, XLPE) 1475:Acrylonitrile butadiene styrene (ABS) 1431: 908:(TMETN, aka Metriol trinitrate, METN) 863:, as a non-energetic secondary fuel. 370:Low Molecular Weight Ortho Phthalates 203:predicts for a simple polymer chain. 95:Plasticizers are also often added to 2292:List of environmental health hazards 2212:List of environmental health hazards 867:Plasticizers for energetic materials 53:during its handling in manufacture. 600: 574:(DEHA, dioctyl adipate plasticizer) 357: 313: 56:Plasticizers are commonly added to 13: 2097:Miscellaneous additives incl. PHCs 1364:10.1111/j.1151-2916.2002.tb00568.x 1105: 14: 2360: 1420:, Risk Assessment Reports by the 1385: 489: 1629: 1623: 1515:Polybutylene terephthalate (PBT) 1490:Poly(methyl methacrylate) (PMMA) 1112:Malveda, Michael P (July 2015). 635:(BASF Trademark: Hexamoll DINCH) 516: 1495:Poly(ethyl methacrylate) (PEMA) 1392:Plasticisers Information Centre 1370: 1343: 1326: 1315: 1288: 1255: 1246: 1237: 1228: 1216: 1199: 800:Traditional lignosulfonate and 619:2-Ethylhexyl diphenyl phosphate 502:Bis(2-ethylhexyl) terephthalate 118: 1858:Category:Plastics applications 1605:Styrene maleic anhydride (SMA) 1600:Polyvinylidene chloride (PVDC) 1585:Polytetrafluoroethylene (PTFE) 1295:Cement Admixture Association. 1171:Annual Review of Public Health 1158: 1141: 1053: 1044: 1035: 1026: 1010: 210:The effect of plasticizers on 1: 1565:Poly(p-phenylene oxide) (PPO) 965: 767:Plasticizers can be added to 686:technology, plasticizers and 529:Tri(2-ethylhexyl)trimellitate 463:Bis(2-propylheptyl) phthalate 135:Europe's Plasticiser Use 2017 2282:Persistent organic pollutant 2243:Toxic Substances Control Act 2202:Persistent organic pollutant 1485:Ethylene vinyl acetate (EVA) 1457: 1212:10.1016/j.envint.2009.07.016 1082:10.1021/acs.macromol.0c00472 930:Bis(2,2-dinitropropyl)acetal 924:Bis(2,2-dinitropropyl)formal 918:Triethylene glycol dinitrate 906:Trimethylolethane trinitrate 547:Tri(isotridecyl)trimellitate 226: 7: 2275:Great Pacific garbage patch 2197:Great Pacific garbage patch 1610:Styrene-acrylonitrile (SAN) 1525:Polyetheretherketone (PEEK) 1167:"Plastics and Health Risks" 953: 920:(TEGDN, less commonly TEGN) 914:(DEGDN, less commonly DEGN) 912:Diethylene glycol dinitrate 677: 432:Bis(2-ethylhexyl) phthalate 353:Common polymer plasticizers 330:Bis(2-ethylhexyl) phthalate 10: 2365: 2238:Japan Toxic Substances Law 2033:Miscellaneous plasticizers 180:cellulose acetate butyrate 2312: 2257: 2233:European REACH regulation 2228:California Proposition 65 2220: 2177: 2134: 2096: 2063: 2032: 1978: 1971:polyhalogenated compounds 1927: 1872: 1848:High-performance plastics 1817: 1810: 1722: 1681: 1673:High-performance plastics 1638: 1621: 1465: 1422:European Chemicals Bureau 762: 727:condensate or sulfonated 541:Tri(isodecyl)trimellitate 535:Tri(isononyl)trimellitate 1658:Fibre-reinforced plastic 1595:Polyvinyl chloride (PVC) 1272:10.1002/14356007.a20_439 1165:Halden, Rolf U. (2010). 1022:10.1002/14356007.a20_439 994:10.1002/14356007.a21_717 825:pyrotechnic compositions 783:, a by-product from the 716:, a by-product from the 626: 592:Di(2-ethylhexyl)sebacate 572:Bis(2-ethylhexyl)adipate 556:Adipates & Sebacates 332:is a common plasticizer. 288:chlorinated polyethylene 170:-type plastics, such as 1709:Biodegradable additives 1152:March 27, 2009, at the 988:. Weinheim: Wiley-VCH. 707:segregation of concrete 673:For inorganic materials 609:include the following: 2124:Perfluorooctanoic acid 1560:Polyphenyl ether (PPE) 1555:Polyoxymethylene (POM) 1500:Polyacrylic acid (PAA) 1337:July 24, 2011, at the 1129:Cite journal requires 894:Butanetriol trinitrate 873:energetic plasticizers 658:Epoxidized soybean oil 568:light. An example is: 475:Diisoundecyl phthalate 418:Butyl benzyl phthalate 333: 223: 144: 136: 128: 26: 2304:Biodegradable plastic 1653:Thermosetting polymer 1550:Polylactic acid (PLA) 750:Polycarboxylate ether 654:acetyltributylcitrate 328: 318:Antiplasticizers are 221: 142: 134: 126: 49:, and/or to decrease 24: 2315:Identification codes 1915:Foam food containers 1838:Engineering plastics 853:solid rocket booster 481:Ditridecyl phthalate 469:Diisodecyl phthalate 457:Diisononyl phthalate 393:Di-n-butyl phthalate 387:Diisobutyl phthalate 343:endocrine disruptors 296:solubility parameter 2349:Concrete admixtures 2154:Endocrine disruptor 1752:Compression molding 1704:Polymer stabilizers 1243:TOTM as plasticizer 1074:2020MaMol..53.4770C 827:, especially solid 817:Energetic materials 650:glycerol triacetate 613:Tricresyl phosphate 428:, and plastic foams 337:Safety and toxicity 186:Mechanism of action 2169:Polymer fume fever 1828:Commodity plastics 1802:Rotational molding 1772:Fiberglass molding 1732:Injection moulding 1714:Filler (materials) 1663:Corrugated plastic 1615:Tritan copolyester 1570:Polypropylene (PP) 1520:Polycarbonate (PC) 1252:DEHS (plasticizer) 1234:DEHP (plasticizer) 877:rocket propellants 842:rocket propellants 829:rocket propellants 822:Energetic material 426:artificial leather 375:Dimethyl phthalate 334: 224: 201:Flory–Fox equation 145: 137: 129: 70:polyvinyl chloride 45:, to decrease its 27: 2321: 2320: 2299:Plastic recycling 2265:Plastic pollution 2251: 2250: 2185:Plastic pollution 1965:Health issues of 1923: 1922: 1819:Plastics industry 1737:Plastic extrusion 1590:Polyurethane (PU) 1580:Polysulfone (PES) 1535:Polyethylene (PE) 1510:Polybutylene (PB) 1358:(12): 2989–2994. 1303:on March 16, 2008 944:secondary alcohol 881:smokeless powders 848:used to fuel the 846:rocket propellant 833:smokeless powders 688:superplasticizers 413:insect repellents 381:Diethyl phthalate 320:polymer additives 172:cellulose acetate 109:solid rocket fuel 2356: 2190:Rubber pollution 2040:Organophosphates 1959: 1952: 1945: 1936: 1935: 1815: 1814: 1787:Filament winding 1762:Transfer molding 1689:Polymer additive 1633: 1627: 1575:Polystyrene (PS) 1452: 1445: 1438: 1429: 1428: 1397:Glass transition 1379: 1374: 1368: 1367: 1347: 1341: 1330: 1324: 1319: 1313: 1312: 1310: 1308: 1292: 1286: 1285: 1259: 1253: 1250: 1244: 1241: 1235: 1232: 1226: 1220: 1214: 1203: 1197: 1196: 1186: 1162: 1156: 1145: 1139: 1138: 1132: 1127: 1125: 1117: 1109: 1103: 1102: 1093: 1068:(XXX): XXX–XXX, 1057: 1051: 1048: 1042: 1039: 1033: 1030: 1024: 1014: 1008: 1007: 979: 861:synthetic rubber 838:specific impulse 753:superplasticizer 652:(Triacetin) and 607:Organophosphates 601:Organophosphates 586:Dibutyl sebacate 358:Ortho phthalates 314:Antiplasticizers 300:molecular weight 196:glass transition 2364: 2363: 2359: 2358: 2357: 2355: 2354: 2353: 2324: 2323: 2322: 2317: 2308: 2253: 2252: 2247: 2216: 2173: 2130: 2092: 2059: 2028: 1974: 1963: 1929: 1919: 1868: 1806: 1792:Solvent bonding 1782:Plastic welding 1724: 1718: 1677: 1640: 1634: 1628: 1619: 1530:Polyester (PEs) 1467: 1461: 1456: 1388: 1383: 1382: 1375: 1371: 1348: 1344: 1339:Wayback Machine 1331: 1327: 1320: 1316: 1306: 1304: 1293: 1289: 1282: 1260: 1256: 1251: 1247: 1242: 1238: 1233: 1229: 1221: 1217: 1204: 1200: 1163: 1159: 1154:Wayback Machine 1146: 1142: 1130: 1128: 1119: 1118: 1110: 1106: 1058: 1054: 1049: 1045: 1040: 1036: 1031: 1027: 1015: 1011: 1004: 980: 973: 968: 956: 869: 819: 781:lignosulfonates 765: 757:polycarboxylate 714:lignosulfonates 680: 675: 629: 603: 558: 519: 492: 360: 355: 339: 316: 292:epichlorohydrin 280:polychloroprene 229: 212:elastic modulus 188: 121: 17: 12: 11: 5: 2362: 2352: 2351: 2346: 2341: 2336: 2319: 2318: 2313: 2310: 2309: 2307: 2306: 2301: 2296: 2295: 2294: 2289: 2284: 2279: 2278: 2277: 2261: 2259: 2255: 2254: 2249: 2248: 2246: 2245: 2240: 2235: 2230: 2224: 2222: 2218: 2217: 2215: 2214: 2209: 2204: 2199: 2194: 2193: 2192: 2181: 2179: 2175: 2174: 2172: 2171: 2166: 2161: 2156: 2151: 2146: 2140: 2138: 2132: 2131: 2129: 2128: 2127: 2126: 2116: 2111: 2106: 2100: 2098: 2094: 2093: 2091: 2090: 2083:Vinyl chloride 2080: 2077:Polycarbonates 2069: 2067: 2061: 2060: 2058: 2057: 2051: 2042: 2036: 2034: 2030: 2029: 2027: 2026: 2021: 2016: 2010: 2005: 1999: 1994: 1988: 1986: 1976: 1975: 1962: 1961: 1954: 1947: 1939: 1933: 1931: 1925: 1924: 1921: 1920: 1918: 1917: 1912: 1907: 1902: 1897: 1892: 1890:Packaging film 1887: 1882: 1876: 1874: 1873:Specific goods 1870: 1869: 1867: 1866: 1860: 1855: 1850: 1845: 1840: 1835: 1830: 1824: 1822: 1812: 1808: 1807: 1805: 1804: 1799: 1797:Vacuum forming 1794: 1789: 1784: 1779: 1774: 1769: 1764: 1759: 1754: 1749: 1744: 1739: 1734: 1728: 1726: 1720: 1719: 1717: 1716: 1711: 1706: 1701: 1696: 1691: 1685: 1683: 1679: 1678: 1676: 1675: 1670: 1668:Polymeric foam 1665: 1660: 1655: 1650: 1644: 1642: 1636: 1635: 1622: 1620: 1618: 1617: 1612: 1607: 1602: 1597: 1592: 1587: 1582: 1577: 1572: 1567: 1562: 1557: 1552: 1547: 1545:Polyimide (PI) 1542: 1537: 1532: 1527: 1522: 1517: 1512: 1507: 1505:Polyamide (PA) 1502: 1497: 1492: 1487: 1482: 1477: 1471: 1469: 1463: 1462: 1455: 1454: 1447: 1440: 1432: 1426: 1425: 1399: 1394: 1387: 1386:External links 1384: 1381: 1380: 1369: 1342: 1325: 1314: 1287: 1280: 1254: 1245: 1236: 1227: 1215: 1198: 1157: 1140: 1131:|journal= 1104: 1062:Macromolecules 1052: 1043: 1034: 1025: 1009: 1003:978-3527306732 1002: 970: 969: 967: 964: 963: 962: 955: 952: 948:vapor pressure 940: 939: 933: 927: 921: 915: 909: 903: 900:Dinitrotoluene 897: 891: 888:Nitroglycerine 871:Here are some 868: 865: 818: 815: 785:paper industry 764: 761: 755:(PCE) or just 718:paper industry 700:pozzolanic ash 679: 676: 674: 671: 670: 669: 646: 645: 642: 639: 636: 628: 625: 624: 623: 622: 621: 616: 602: 599: 598: 597: 596: 595: 589: 577: 576: 575: 557: 554: 553: 552: 551: 550: 544: 538: 532: 518: 515: 514: 513: 512: 511: 508: 505: 496:Terephthalates 491: 490:Terephthalates 488: 487: 486: 485: 484: 478: 472: 466: 460: 449: 448: 447: 429: 422:conveyor belts 415: 390: 384: 378: 367: 359: 356: 354: 351: 338: 335: 315: 312: 249:terephthalates 228: 225: 187: 184: 176:nitrocellulose 158:, are used in 120: 117: 82:vinyl flooring 15: 9: 6: 4: 3: 2: 2361: 2350: 2347: 2345: 2342: 2340: 2337: 2335: 2332: 2331: 2329: 2316: 2311: 2305: 2302: 2300: 2297: 2293: 2290: 2288: 2285: 2283: 2280: 2276: 2273: 2272: 2271: 2270:Garbage patch 2268: 2267: 2266: 2263: 2262: 2260: 2256: 2244: 2241: 2239: 2236: 2234: 2231: 2229: 2226: 2225: 2223: 2219: 2213: 2210: 2208: 2205: 2203: 2200: 2198: 2195: 2191: 2188: 2187: 2186: 2183: 2182: 2180: 2176: 2170: 2167: 2165: 2162: 2160: 2157: 2155: 2152: 2150: 2147: 2145: 2142: 2141: 2139: 2137: 2136:Health issues 2133: 2125: 2122: 2121: 2120: 2117: 2115: 2112: 2110: 2107: 2105: 2102: 2101: 2099: 2095: 2088: 2084: 2081: 2078: 2074: 2071: 2070: 2068: 2066: 2062: 2055: 2052: 2050: 2046: 2043: 2041: 2038: 2037: 2035: 2031: 2025: 2022: 2020: 2017: 2014: 2011: 2009: 2006: 2003: 2000: 1998: 1995: 1993: 1990: 1989: 1987: 1985: 1981: 1977: 1972: 1968: 1960: 1955: 1953: 1948: 1946: 1941: 1940: 1937: 1932: 1926: 1916: 1913: 1911: 1910:Shopping bags 1908: 1906: 1903: 1901: 1898: 1896: 1893: 1891: 1888: 1886: 1883: 1881: 1878: 1877: 1875: 1871: 1865:(Agriculture) 1864: 1863:Plasticulture 1861: 1859: 1856: 1854: 1851: 1849: 1846: 1844: 1843:Geosynthetics 1841: 1839: 1836: 1834: 1831: 1829: 1826: 1825: 1823: 1820: 1816: 1813: 1809: 1803: 1800: 1798: 1795: 1793: 1790: 1788: 1785: 1783: 1780: 1778: 1775: 1773: 1770: 1768: 1765: 1763: 1760: 1758: 1755: 1753: 1750: 1748: 1747:Thermoforming 1745: 1743: 1740: 1738: 1735: 1733: 1730: 1729: 1727: 1721: 1715: 1712: 1710: 1707: 1705: 1702: 1700: 1697: 1695: 1692: 1690: 1687: 1686: 1684: 1680: 1674: 1671: 1669: 1666: 1664: 1661: 1659: 1656: 1654: 1651: 1649: 1648:Thermoplastic 1646: 1645: 1643: 1637: 1632: 1626: 1616: 1613: 1611: 1608: 1606: 1603: 1601: 1598: 1596: 1593: 1591: 1588: 1586: 1583: 1581: 1578: 1576: 1573: 1571: 1568: 1566: 1563: 1561: 1558: 1556: 1553: 1551: 1548: 1546: 1543: 1541: 1538: 1536: 1533: 1531: 1528: 1526: 1523: 1521: 1518: 1516: 1513: 1511: 1508: 1506: 1503: 1501: 1498: 1496: 1493: 1491: 1488: 1486: 1483: 1481: 1478: 1476: 1473: 1472: 1470: 1464: 1460: 1453: 1448: 1446: 1441: 1439: 1434: 1433: 1430: 1423: 1419: 1415: 1411: 1407: 1403: 1400: 1398: 1395: 1393: 1390: 1389: 1378: 1373: 1365: 1361: 1357: 1353: 1346: 1340: 1336: 1333: 1329: 1323: 1318: 1302: 1298: 1291: 1283: 1277: 1273: 1269: 1265: 1258: 1249: 1240: 1231: 1225: 1219: 1213: 1209: 1202: 1194: 1190: 1185: 1180: 1176: 1172: 1168: 1161: 1155: 1151: 1148: 1144: 1136: 1123: 1115: 1108: 1101: 1097: 1092: 1087: 1083: 1079: 1075: 1071: 1067: 1063: 1056: 1047: 1038: 1029: 1023: 1019: 1013: 1005: 999: 995: 991: 987: 986: 978: 976: 971: 961: 958: 957: 951: 949: 945: 937: 934: 931: 928: 925: 922: 919: 916: 913: 910: 907: 904: 901: 898: 895: 892: 889: 886: 885: 884: 882: 878: 874: 864: 862: 858: 854: 851: 850:Space Shuttle 847: 843: 839: 834: 830: 826: 823: 814: 811: 807: 803: 798: 796: 793: 788: 786: 782: 778: 777:aldonic acids 773: 770: 760: 758: 754: 751: 747: 745: 741: 737: 733: 730: 726: 723: 719: 715: 710: 708: 703: 701: 696: 693: 689: 685: 667: 663: 662: 661: 659: 655: 651: 643: 640: 637: 634: 631: 630: 620: 617: 614: 611: 610: 608: 605: 604: 593: 590: 587: 584: 583: 581: 578: 573: 570: 569: 567: 563: 560: 559: 548: 545: 542: 539: 536: 533: 530: 527: 526: 524: 523:Trimellitates 521: 520: 517:Trimellitates 509: 506: 503: 500: 499: 497: 494: 493: 482: 479: 476: 473: 470: 467: 464: 461: 458: 455: 454: 453: 450: 445: 441: 437: 433: 430: 427: 423: 419: 416: 414: 410: 406: 402: 398: 397:nail polishes 394: 391: 388: 385: 382: 379: 376: 373: 372: 371: 368: 365: 362: 361: 350: 348: 347:new car smell 344: 331: 327: 323: 321: 311: 308: 303: 301: 297: 293: 289: 285: 281: 277: 272: 270: 266: 262: 258: 254: 250: 246: 242: 237: 233: 220: 216: 213: 208: 204: 202: 197: 193: 183: 181: 177: 173: 169: 165: 161: 157: 154: 149: 141: 133: 125: 116: 114: 110: 106: 102: 98: 93: 91: 87: 83: 79: 75: 71: 67: 63: 59: 54: 52: 48: 44: 40: 36: 32: 23: 19: 2334:Plasticizers 1980:Plasticizers 1979: 1928:Environment 1880:Blister pack 1833:Construction 1742:Blow molding 1698: 1372: 1355: 1351: 1345: 1328: 1317: 1305:. Retrieved 1301:the original 1290: 1263: 1257: 1248: 1239: 1230: 1218: 1201: 1174: 1170: 1160: 1143: 1122:cite journal 1107: 1091:10261/218380 1065: 1061: 1055: 1046: 1037: 1028: 1012: 983: 941: 870: 820: 799: 789: 766: 756: 748: 732:formaldehyde 711: 704: 697: 681: 647: 451: 369: 340: 317: 304: 273: 234: 230: 209: 205: 189: 150: 146: 119:For polymers 94: 86:rain gutters 74:vinyl siding 55: 38: 30: 28: 18: 2221:Regulations 2073:Bisphenol A 1757:Calendering 1699:Plasticizer 1639:Mechanical 1177:: 179–194. 942:Due to the 802:naphthalene 795:naphthalene 725:naphthalene 692:workability 666:Bisphenol A 566:ultraviolet 438:, and high 253:dibenzoates 113:dispersants 39:plasticiser 31:plasticizer 2328:Categories 2149:Carcinogen 2114:Organotins 1984:Phthalates 1930:and health 1777:Pultrusion 1767:Laminating 1725:processing 1281:3527306730 966:References 792:sulfonated 722:sulfonated 442:, such as 440:explosives 409:emollients 405:sunscreens 261:phthalates 257:glutarates 43:plasticity 2178:Pollution 2144:Teratogen 2075:(BPA, in 1723:Plastics 1694:Colorants 1682:Additives 1466:Chemical 1100:219911779 769:wallboard 364:Phthalate 269:elastomer 241:sebacates 227:Selection 168:cellulose 164:acrylates 153:phthalate 47:viscosity 2344:Concrete 2159:Diabetes 2065:Monomers 2045:Adipates 1967:plastics 1821:segments 1811:Products 1459:Plastics 1335:Archived 1307:April 2, 1193:20070188 1150:Archived 954:See also 875:used in 855:employs 810:adsorbed 740:adsorbed 729:melamine 684:concrete 678:Concrete 580:Sebacate 549:(TITDTM) 436:products 401:shampoos 265:azelates 245:adipates 192:polymers 97:concrete 90:plumbing 64:such as 62:plastics 58:polymers 51:friction 2287:Dioxins 2207:Dioxins 2164:Obesity 1905:Cutlery 1895:Bottles 1070:Bibcode 932:(BDNPA) 926:(BDNPF) 813:other. 806:Colloid 736:colloid 682:In the 562:Adipate 543:(TIDTM) 537:(TINTM) 407:, skin 276:nitrile 78:roofing 2339:Cement 2004:(BBzP) 1973:(PHCs) 1885:Chairs 1853:Nurdle 1424:(ECB). 1278:  1191:  1098:  1000:  938:(TNEN) 896:(BTTN) 772:stucco 763:Stucco 744:Lignin 664:Note: 444:Semtex 411:, and 389:(DIBP) 307:esters 290:, and 156:esters 105:stucco 2258:Waste 2104:PBDEs 2015:(DOP) 1641:types 1468:types 1297:"CAA" 1096:S2CID 902:(DNT) 627:Other 615:(TCP) 588:(DBS) 236:Ester 101:clays 2119:PFCs 2109:PCBs 2085:(in 2049:DEHA 2024:DINP 2019:DIDP 2013:DEHP 2008:DIHP 1992:DIBP 1969:and 1900:Bags 1418:DEHP 1406:DINP 1402:DIDP 1309:2008 1276:ISBN 1189:PMID 1135:help 998:ISBN 879:and 859:, a 857:HTPB 831:and 284:EPDM 178:and 166:and 60:and 2087:PVC 2054:DOA 2002:BBP 1997:DBP 1416:, * 1414:BBP 1410:DBP 1404:, * 1360:doi 1268:doi 1208:doi 1179:doi 1086:hdl 1078:doi 1066:XXX 1018:doi 990:doi 160:PVC 66:PVC 2330:: 1982:: 1412:, 1408:, 1356:85 1354:. 1274:. 1266:. 1187:. 1175:31 1173:. 1169:. 1126:: 1124:}} 1120:{{ 1094:, 1084:, 1076:, 1064:, 996:. 974:^ 950:. 883:: 787:. 424:, 403:, 298:, 286:, 282:, 278:, 263:, 259:, 255:, 251:, 247:, 243:, 182:. 174:, 115:. 107:, 103:, 88:, 84:, 80:, 76:, 37:: 35:UK 29:A 2089:) 2079:) 2056:) 2047:( 1958:e 1951:t 1944:v 1451:e 1444:t 1437:v 1366:. 1362:: 1311:. 1284:. 1270:: 1210:: 1195:. 1181:: 1137:) 1133:( 1116:. 1088:: 1080:: 1072:: 1020:: 1006:. 992:: 33:(

Index


UK
plasticity
viscosity
friction
polymers
plastics
PVC
polyvinyl chloride
vinyl siding
roofing
vinyl flooring
rain gutters
plumbing
concrete
clays
stucco
solid rocket fuel
dispersants



phthalate
esters
PVC
acrylates
cellulose
cellulose acetate
nitrocellulose
cellulose acetate butyrate

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