Knowledge

Heat of combustion

Source πŸ“

823:. The combustion of a stoichiometric mixture of fuel and oxidizer (e.g. two moles of hydrogen and one mole of oxygen) in a steel container at 25 Β°C (77 Β°F) is initiated by an ignition device and the reactions allowed to complete. When hydrogen and oxygen react during combustion, water vapor is produced. The vessel and its contents are then cooled to the original 25 Β°C and the higher heating value is determined as the heat released between identical initial and final temperatures. 675:) indicates the upper limit of the available thermal energy produced by a complete combustion of fuel. It is measured as a unit of energy per unit mass or volume of substance. The HHV is determined by bringing all the products of combustion back to the original pre-combustion temperature, including condensing any vapor produced. Such measurements often use a standard temperature of 25 Β°C (77 Β°F; 298 K). This is the same as the thermodynamic heat of combustion since the 3379: 3393: 721:) is another measure of available thermal energy produced by a combustion of fuel, measured as a unit of energy per unit mass or volume of substance. In contrast to the HHV, the LHV considers energy losses such as the energy used to vaporize water - although its exact definition is not uniformly agreed upon. One definition is simply to subtract the 862:). For hydrogen, the difference is much more significant as it includes the sensible heat of water vapor between 150 Β°C and 100 Β°C, the latent heat of condensation at 100 Β°C, and the sensible heat of the condensed water between 100 Β°C and 25 Β°C. In all, the higher heating value of hydrogen is 18.2% above its lower heating value (142 1085:
Engine manufacturers typically rate their engines fuel consumption by the lower heating values since the exhaust is never condensed in the engine, and doing this allows them to publish more attractive numbers than are used in conventional power plant terms. The conventional power industry had used
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The difference between HHV and LHV definitions causes endless confusion when quoters do not bother to state the convention being used. since there is typically a 10% difference between the two methods for a power plant burning natural gas. For simply benchmarking part of a reaction the LHV may be
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By convention, the (higher) heat of combustion is defined to be the heat released for the complete combustion of a compound in its standard state to form stable products in their standard states: hydrogen is converted to water (in its liquid state), carbon is converted to carbon dioxide gas, and
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The difference between the two heating values depends on the chemical composition of the fuel. In the case of pure carbon or carbon monoxide, the two heating values are almost identical, the difference being the sensible heat content of carbon dioxide between 150 Β°C and 25 Β°C
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HHV (high heat value) exclusively for decades, even though virtually all of these plants did not condense exhaust either. American consumers should be aware that the corresponding fuel-consumption figure based on the higher heating value will be somewhat higher.
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used for space heat). In other words, HHV assumes all the water component is in liquid state at the end of combustion (in product of combustion) and that heat delivered at temperatures below 150 Β°C (302 Β°F) can be put to use.
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The definition in which the combustion products are all returned to the reference temperature is more easily calculated from the higher heating value than when using other definitions and will in fact give a slightly different answer.
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change for the reaction assumes a common temperature of the compounds before and after combustion, in which case the water produced by combustion is condensed to a liquid. The higher heating value takes into account the
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and other reaction products is not recovered. It is useful in comparing fuels where condensation of the combustion products is impractical, or heat at a temperature below 150 Β°C (302 Β°F) cannot be put to use.
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Both HHV and LHV can be expressed in terms of AR (all moisture counted), MF and MAF (only water from combustion of hydrogen). AR, MF, and MAF are commonly used for indicating the heating values of coal:
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It gives 545 kJ/mole, whereas the value calculated from heats of formation is around 1561 kJ/mole. For glycerine trinitrate (nitroglycerine) it gives 0, though nitroglycerine does not actually combust.
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Most applications that burn fuel produce water vapor, which is unused and thus wastes its heat content. In such applications, the lower heating value must be used to give a 'benchmark' for the process.
3713:"The difference between LCV and HCV (or Lower and Higher Heating Value, or Net and Gross) is clearly understood by all energy engineers. There is no 'right' or 'wrong' definition. - Claverton Group" 3165:
There is no difference between the lower and higher heating values for the combustion of carbon, carbon monoxide and sulfur since no water is formed during the combustion of those substances.
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accounts for water in the exhaust leaving as vapor, as does LHV, but gross heating value also includes liquid water in the fuel prior to combustion. This value is important for fuels like
837:
Note: Higher heating value (HHV) is calculated with the product of water being in liquid form while lower heating value (LHV) is calculated with the product of water being in vapor form.
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of all combustion products minus the enthalpy of the fuel at the reference temperature (API research project 44 used 25 Β°C. GPSA currently uses 60 Β°F), minus the enthalpy of the
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Hosokai, Sou; Matsuoka, Koichi; Kuramoto, Koji; Suzuki, Yoshizo (1 November 2016). "Modification of Dulong's formula to estimate heating value of gas, liquid and solid fuels".
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There are two kinds of enthalpy of combustion, called high(er) and low(er) heat(ing) value, depending on how much the products are allowed to cool and whether compounds like
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Another definition of the LHV is the amount of heat released when the products are cooled to 150 Β°C (302 Β°F). This means that the latent heat of vaporization of
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of the products and reactants (though this approach is somewhat artificial since most heats of formation are typically calculated from measured heats of combustion)..
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Zwolinski and Wilhoit defined, in 1972, "gross" and "net" values for heats of combustion. In the gross definition the products are the most stable compounds, e.g.
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Dlugogorski, B. Z.; Mawhinney, J. R.; Duc, V. H. (1994). "The Measurement of Heat Release Rates by Oxygen Consumption Calorimetry in Fires Under Suppression".
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indicates that the fuel heating value has been measured after the fuel has been dried of all inherent moisture but still retaining its ash-forming minerals.
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The heating value of a fuel can be calculated with the results of ultimate analysis of fuel. From analysis, percentages of the combustibles in the fuel (
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Another definition, used by Gas Processors Suppliers Association (GPSA) and originally used by API (data collected for API research project 44), is the
1130:(dry and ash-free) indicates that the fuel heating value has been measured in the absence of inherent moisture- and ash-forming minerals. 3846: 732:
LHV calculations assume that the water component of a combustion process is in vapor state at the end of combustion, as opposed to the
1010:{\displaystyle \mathrm {HHV} =\mathrm {LHV} +H_{\mathrm {v} }\left({\frac {n_{\mathrm {H_{2}O,out} }}{n_{\mathrm {fuel,in} }}}\right)} 1060:
However, for true energy calculations in some specific cases, the higher heating value is correct. This is particularly relevant for
830:(LHV) is determined, cooling is stopped at 150 Β°C and the reaction heat is only partially recovered. The limit of 150 Β°C is based on 3348:
The lower heating value of natural gas is normally about 90% of its higher heating value. This table is in Standard cubic metres (1
603:) are known. Since the heat of combustion of these elements is known, the heating value can be calculated using Dulong's Formula: 3824: 3646: 878:
the higher heating value exceeds the lower heating value by about 10% and 7%, respectively, and for natural gas about 11%.
121:. Low heat values are calculated from high heat value test data. They may also be calculated as the difference between the 1110:(as received) indicates that the fuel heating value has been measured with all moisture- and ash-forming minerals present. 3870: 644:
are the contents of carbon, hydrogen, oxygen, nitrogen, and sulfur on any (wet, dry or ash free) basis, respectively.
3885: 71: 492:(l). In the net definition the products are the gases produced when the compound is burned in an open flame, e.g. 393:
Chlorine and sulfur are not quite standardized; they are usually assumed to convert to hydrogen chloride gas and
3652: 788:) at the reference temperature, minus the heat of vaporization of the vapor content of the combustion products. 744:) which assumes that all of the water in a combustion process is in a liquid state after a combustion process. 122: 3791: 729:
O formed as a vapor that is released as a waste. The energy required to vaporize the water is therefore lost.
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calculations if only to avoid confusion, and in any case, the value or convention should be clearly stated.
3427: 756: 421:, respectively, when the combustion is conducted in a bomb calorimeter containing some quantity of water. 3407: 3178: 1091: 180:
usually to a good approximation (Β±3%), though it gives poor results for some compounds such as (gaseous)
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that condense the water vapor produced by combustion, recovering heat which would otherwise be wasted.
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Air Quality Engineering, CE 218A, W. Nazaroff and R. Harley, University of California Berkeley, 2007
3617:"Theoretical Analysis of Waste Heat Recovery from an Internal Combustion Engine in a Hybrid Vehicle" 3895: 3890: 722: 681: 3503: 2627: 2050: 3773: 3472: 3417: 1073: 3530: 3437: 820: 870:
MJ/kg). For hydrocarbons, the difference depends on the hydrogen content of the fuel. For
8: 3875: 3442: 2031: 3534: 688:
in the combustion products, and is useful in calculating heating values for fuels where
3477: 2093: 2012: 859: 32: 3820: 3642: 3181:
reports the following typical higher heating values per Standard cubic metre of gas:
2131: 1065: 3738: 3737:. NIST Standard Reference Database Number 69. NIST Office of Data and Informatics. 3685: 3596: 3538: 3384: 855: 118: 3689: 3462: 3447: 3096: 2996: 2853: 2646: 2442: 1993: 185: 117:
are allowed to condense. The high heat values are conventionally measured with a
3543: 3518: 3880: 3504:"Effect of structural conduction and heat loss on combustion in micro-channels" 3432: 3316: 2915: 2877: 2234: 79: 3519:"Why Combustions Are Always Exothermic, Yielding About 418 kJ per Mole of O 2" 3172: 3864: 3398: 3326: 3015: 2337: 1400: 1069: 847: 781: 418: 3306: 3296: 2977: 2958: 2934: 2896: 2809: 2608: 2399: 2380: 2212: 2074: 1334: 1298: 689: 181: 225:
nitrogen is converted to nitrogen gas. That is, the heat of combustion, Ξ”
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BTU/lb values are calculated from MJ/kg (1 MJ/kg = 430 BTU/lb).
2749: 2112: 1710: 1522: 1352: 1174: 1061: 875: 851: 91: 75: 44: 3616: 1064:, whose high hydrogen content produces much water, when it is burned in 3336: 3196: 2831: 2790: 2730: 1974: 1561: 1374: 63: 3840: 3467: 3226: 2768: 2480: 2423: 2275: 2256: 2174: 1955: 1691: 1685: 1625: 1577: 1518: 1506: 1440: 1170: 1158: 3742: 811:, which will usually contain some amount of water prior to burning. 3266: 3077: 3058: 2692: 2586: 2564: 2542: 2461: 2356: 2313: 2193: 2155: 1931: 1912: 1641: 1529: 1316: 1184: 871: 831: 777: 676: 596: 3392: 3186: 3115: 3034: 2711: 2523: 2504: 1836: 1798: 1760: 1722: 1609: 1593: 1545: 1396: 1279: 1241: 1203: 3847:"Lower and Higher Heating Values of Gas, Liquid and Solid Fuels" 16:
Amount of heat released by combustion of a quantity of substance
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of the water from the higher heating value. This treats any H
685: 541:(g). In both definitions the products for C, F, Cl and N are 83: 692:
of the reaction products is practical (e.g., in a gas-fired
51:
released during the combustion of a specified amount of it.
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Higher heating values of natural gases from various sources
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at constant temperature. Examples: heat of vaporization or
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The higher heating value is experimentally determined in a
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and release heat. It may be expressed with the quantities:
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gas, respectively, or to dilute aqueous hydrochloric and
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or other organic molecule reacting with oxygen to form
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One definition of lower heating value, adopted by the
233:, is the heat of reaction of the following process: 890: 62:
released as heat when a substance undergoes complete
3757:"CDP Technical Note: Conversion of fuel data to MWh" 3374: 3359:Β°C), to convert to values per Normal cubic metre (1 759:(API), uses a reference temperature of 60 Β°F ( 1009: 840: 3819:. Publication de l'Institut FranΓ§ais du PΓ©trole. 3637:. In Dwight E., Gray; Billings, Bruce H. (eds.). 3862: 3630:Zwolinski, Bruno J; Wilhoit, Randolf C. (1972). 3629: 1090:appropriate, but HHV should be used for overall 1675:Lower heating value for some organic compounds 850:exchange causes a change of temperature, while 3551: 3510: 1046:is the number of moles of water vaporized and 3632:"Heats of formation and Heats of Combustion" 3516: 1422: 1140:Higher (HHV) and lower (LHV) heating values 1134: 881:A common method of relating HHV to LHV is: 814: 3585:"Heats of combustion of organic compounds" 1097: 1053:is the number of moles of fuel combusted. 3600: 3542: 733: 3732: 3582: 827: 424: 3728: 3726: 3589:Bureau of Standards Journal of Research 3517:Schmidt-Rohr, Klaus (8 December 2015). 647: 74:. The chemical reaction is typically a 3863: 3814: 3639:American Institute of Physics Handbook 1027:is the heat of vaporization of water, 795: 700: 3367:Β°C), multiply above table by 1.0549. 164:, the (higher) heat of combustion is 3792:"Key World Energy Statistics (2016)" 3784: 3723: 202:, such as for glycerine dinitrate, 13: 3856:. U.S. Department of Energy. 2011. 3808: 995: 992: 986: 983: 980: 977: 965: 962: 959: 953: 944: 925: 912: 909: 906: 898: 895: 892: 188:, and can be significantly off if 14: 3907: 3834: 3641:. McGraw-Hill. pp. 316–342. 1080: 3583:Kharasch, M.S. (February 1929). 3391: 3377: 429: 3766: 3749: 3705: 841:Relation between heating values 652:The higher heating value (HHV; 3696: 3669: 3623: 3609: 3576: 3567: 3506:. Taylor & Francis Online. 3496: 1142:of some common fuels at 25 Β°C 705:The lower heating value (LHV; 1: 3523:Journal of Chemical Education 3490: 3413:Cost of electricity by source 1673: 1494: 1138: 3690:10.1016/j.fuproc.2016.06.040 3428:Energy conversion efficiency 1126:(moisture- and ash-free) or 757:American Petroleum Institute 7: 3544:10.1021/acs.jchemed.5b00333 3408:Adiabatic flame temperature 3370: 3179:International Energy Agency 854:is added or subtracted for 682:latent heat of vaporization 140:For a fuel of composition C 10: 3912: 3871:Engineering thermodynamics 3678:Fuel Processing Technology 1656: 1640: 1624: 1608: 1592: 1576: 1560: 1544: 1528: 1498:of some less common fuels 1475: 1457: 1439: 1417: 1391: 1369: 1351: 1333: 1315: 1297: 1278: 1259: 1240: 1221: 1202: 1183: 3052: 2952: 2871: 2686: 2498: 2417: 2374: 2331: 2149: 2068: 1949: 1716: 1149: 1146: 1135:Heat of combustion tables 100:energy/volume of the fuel 3886:Thermodynamic properties 3854:Biomass Energy Data Book 3733:Linstrom, Peter (2021). 3717:www.claverton-energy.com 815:Measuring heating values 1098:Accounting for moisture 3841:NIST Chemistry WebBook 3815:Guibet, J.-C. (1997). 3735:NIST Chemistry WebBook 3423:Energy content of fuel 2953:Aldehydes and ketones 2628:1,2,4-Trimethylbenzene 2051:2,2,4-Trimethylpentane 1011: 669:higher calorific value 3817:Carburants et moteurs 3473:Mechanical efficiency 3418:Electrical efficiency 1496:Higher heating value 1074:flue-gas condensation 1012: 738:gross calorific value 715:lower calorific value 662:gross calorific value 425:Ways of determination 3602:10.6028/jres.002.007 3438:Energy value of coal 888: 734:higher heating value 723:heat of vaporization 648:Higher heating value 47:), is the amount of 3559:Fire Safety Science 3535:2015JChEd..92.2094S 3443:Exothermic reaction 2032:2,3-Dimethylpentane 1678: 1499: 1143: 1116:(moisture-free) or 828:lower heating value 801:Gross heating value 796:Gross heating value 707:net calorific value 701:Lower heating value 658:upper heating value 581:(g), respectively. 97:energy/mass of fuel 72:standard conditions 3478:Thermal efficiency 2295:2-Methyl-1-pentene 2094:Methylcyclopentane 2013:2,3-Dimethylbutane 1674: 1495: 1139: 1066:condensing boilers 1007: 3826:978-2-7108-0704-9 3648:978-0-07-001485-5 3529:(12): 2094–2099. 3157: 3156: 3140: 3059:Carbon (graphite) 2132:Methylcyclohexane 1677:(at 25 Β°C ) 1672: 1671: 1493: 1492: 1092:energy efficiency 1001: 856:phase transitions 123:heat of formation 3903: 3857: 3851: 3830: 3803: 3802: 3796: 3788: 3782: 3781: 3778:webbook.nist.gov 3770: 3764: 3763: 3761: 3753: 3747: 3746: 3730: 3721: 3720: 3709: 3703: 3700: 3694: 3693: 3673: 3667: 3666: 3664: 3663: 3657: 3651:. 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3695: 3668: 3647: 3622: 3608: 3575: 3566: 3550: 3509: 3494: 3492: 3489: 3487: 3486: 3485:: heat density 3480: 3475: 3470: 3465: 3460: 3455: 3450: 3445: 3440: 3435: 3433:Energy density 3430: 3425: 3420: 3415: 3410: 3404: 3403: 3402: 3388: 3372: 3369: 3345: 3344: 3334: 3324: 3317:United Kingdom 3314: 3304: 3294: 3284: 3274: 3264: 3254: 3244: 3234: 3224: 3214: 3204: 3194: 3183: 3174: 3171: 3170: 3169: 3166: 3162: 3161: 3155: 3154: 3151: 3148: 3145: 3142: 3131: 3130: 3127: 3124: 3121: 3118: 3112: 3111: 3108: 3105: 3102: 3099: 3093: 3092: 3089: 3086: 3083: 3080: 3074: 3073: 3070: 3067: 3064: 3061: 3055: 3054: 3053:Other species 3050: 3049: 3046: 3043: 3040: 3037: 3031: 3030: 3027: 3024: 3021: 3018: 3012: 3011: 3008: 3005: 3002: 2999: 2993: 2992: 2989: 2986: 2983: 2980: 2974: 2973: 2970: 2967: 2964: 2961: 2955: 2954: 2950: 2949: 2946: 2943: 2940: 2937: 2931: 2930: 2927: 2924: 2921: 2918: 2916:Propoxypropane 2912: 2911: 2908: 2905: 2902: 2899: 2893: 2892: 2889: 2886: 2883: 2880: 2878:Methoxymethane 2874: 2873: 2869: 2868: 2865: 2862: 2859: 2856: 2850: 2849: 2846: 2843: 2840: 2837: 2828: 2827: 2824: 2821: 2818: 2815: 2806: 2805: 2802: 2799: 2796: 2793: 2787: 2786: 2783: 2780: 2777: 2774: 2765: 2764: 2761: 2758: 2755: 2752: 2746: 2745: 2742: 2739: 2736: 2733: 2727: 2726: 2723: 2720: 2717: 2714: 2708: 2707: 2704: 2701: 2698: 2695: 2689: 2688: 2684: 2683: 2680: 2677: 2674: 2671: 2665: 2664: 2661: 2658: 2655: 2652: 2650:-Propylbenzene 2643: 2642: 2639: 2636: 2633: 2630: 2624: 2623: 2620: 2617: 2614: 2611: 2605: 2604: 2601: 2598: 2595: 2592: 2583: 2582: 2579: 2576: 2573: 2570: 2561: 2560: 2557: 2554: 2551: 2548: 2539: 2538: 2535: 2532: 2529: 2526: 2520: 2519: 2516: 2513: 2510: 2507: 2501: 2500: 2496: 2495: 2492: 2489: 2486: 2483: 2477: 2476: 2473: 2470: 2467: 2464: 2458: 2457: 2454: 2451: 2448: 2445: 2439: 2438: 2435: 2432: 2429: 2426: 2420: 2419: 2415: 2414: 2411: 2408: 2405: 2402: 2396: 2395: 2392: 2389: 2386: 2383: 2377: 2376: 2372: 2371: 2368: 2365: 2362: 2359: 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1829: 1826: 1823: 1820: 1814: 1813: 1810: 1807: 1804: 1801: 1795: 1794: 1791: 1788: 1785: 1782: 1776: 1775: 1772: 1769: 1766: 1763: 1757: 1756: 1753: 1750: 1747: 1744: 1738: 1737: 1734: 1731: 1728: 1725: 1719: 1718: 1714: 1713: 1704: 1698: 1689: 1683: 1670: 1669: 1666: 1663: 1660: 1654: 1653: 1650: 1647: 1644: 1638: 1637: 1634: 1631: 1628: 1622: 1621: 1618: 1615: 1612: 1606: 1605: 1602: 1599: 1596: 1590: 1589: 1586: 1583: 1580: 1574: 1573: 1570: 1567: 1564: 1558: 1557: 1554: 1551: 1548: 1542: 1541: 1538: 1535: 1532: 1526: 1525: 1516: 1510: 1504: 1491: 1490: 1488: 1486: 1483: 1480: 1473: 1472: 1470: 1468: 1465: 1462: 1455: 1454: 1451: 1449: 1446: 1443: 1437: 1436: 1434: 1432: 1429: 1426: 1415: 1414: 1412: 1410: 1407: 1404: 1389: 1388: 1386: 1384: 1381: 1378: 1367: 1366: 1363: 1361: 1358: 1355: 1349: 1348: 1345: 1343: 1340: 1337: 1331: 1330: 1327: 1325: 1322: 1319: 1313: 1312: 1309: 1307: 1304: 1301: 1295: 1294: 1291: 1288: 1285: 1282: 1276: 1275: 1272: 1269: 1266: 1263: 1257: 1256: 1253: 1250: 1247: 1244: 1238: 1237: 1234: 1231: 1228: 1225: 1219: 1218: 1215: 1212: 1209: 1206: 1200: 1199: 1196: 1193: 1190: 1187: 1181: 1180: 1177: 1168: 1162: 1155: 1154: 1151: 1148: 1136: 1133: 1132: 1131: 1121: 1111: 1099: 1096: 1082: 1081:Usage of terms 1079: 1078: 1077: 1058: 1050: 1037: 1031: 1024: 1018: 1017: 1005: 997: 994: 991: 988: 985: 982: 979: 974: 967: 964: 961: 958: 955: 950: 946: 940: 934: 927: 922: 918: 914: 911: 908: 904: 900: 897: 894: 860:heat of fusion 842: 839: 816: 813: 797: 794: 785: 782:stoichiometric 736:(HHV) (a.k.a. 726: 702: 699: 649: 646: 641: 637: 633: 629: 625: 619: 615: 611: 607: 585: 575: 563: 547: 535: 523: 511: 498: 486: 477: 465: 453: 440: 431: 428: 426: 423: 419:sulfuric acids 411: 399: 391: 390: 383: 355: 332: 317: 275: 264: 253: 242: 230: 217: 213: 209: 205: 166:419 kJ/mol Γ— ( 159: 153: 147: 141: 132: 110: 102: 101: 98: 95: 80:carbon dioxide 15: 9: 6: 4: 3: 2: 3908: 3897: 3894: 3892: 3889: 3887: 3884: 3882: 3879: 3877: 3874: 3872: 3869: 3868: 3866: 3855: 3848: 3844: 3842: 3839: 3838: 3828: 3822: 3818: 3813: 3812: 3800: 3793: 3787: 3779: 3775: 3769: 3758: 3752: 3744: 3740: 3736: 3729: 3727: 3718: 3714: 3708: 3699: 3691: 3687: 3683: 3679: 3672: 3658:on 2021-08-06 3654: 3650: 3644: 3640: 3633: 3626: 3618: 3612: 3603: 3598: 3594: 3590: 3586: 3579: 3570: 3563: 3560: 3554: 3545: 3540: 3536: 3532: 3528: 3524: 3520: 3513: 3505: 3499: 3495: 3484: 3481: 3479: 3476: 3474: 3471: 3469: 3466: 3464: 3461: 3459: 3456: 3454: 3451: 3449: 3446: 3444: 3441: 3439: 3436: 3434: 3431: 3429: 3426: 3424: 3421: 3419: 3416: 3414: 3411: 3409: 3406: 3405: 3400: 3399:Energy portal 3394: 3389: 3386: 3375: 3368: 3354: 3338: 3335: 3328: 3327:United States 3325: 3318: 3315: 3308: 3305: 3298: 3295: 3288: 3285: 3278: 3275: 3268: 3265: 3258: 3255: 3248: 3245: 3238: 3235: 3228: 3225: 3218: 3215: 3208: 3205: 3198: 3195: 3188: 3185: 3184: 3182: 3180: 3167: 3164: 3163: 3159: 3158: 3152: 3149: 3146: 3143: 3136: 3133: 3132: 3128: 3125: 3122: 3119: 3117: 3114: 3113: 3109: 3106: 3103: 3100: 3098: 3095: 3094: 3090: 3087: 3084: 3081: 3079: 3076: 3075: 3071: 3068: 3065: 3062: 3060: 3057: 3056: 3051: 3047: 3044: 3041: 3038: 3036: 3033: 3032: 3028: 3025: 3022: 3019: 3017: 3016:Butyraldehyde 3014: 3013: 3009: 3006: 3003: 3000: 2998: 2995: 2994: 2990: 2987: 2984: 2981: 2979: 2976: 2975: 2971: 2968: 2965: 2962: 2960: 2957: 2956: 2951: 2947: 2944: 2941: 2938: 2936: 2933: 2932: 2928: 2925: 2922: 2919: 2917: 2914: 2913: 2909: 2906: 2903: 2900: 2898: 2895: 2894: 2890: 2887: 2884: 2881: 2879: 2876: 2875: 2870: 2866: 2863: 2860: 2857: 2855: 2852: 2851: 2847: 2844: 2841: 2838: 2836: 2834: 2830: 2829: 2825: 2822: 2819: 2816: 2814: 2812: 2808: 2807: 2803: 2800: 2797: 2794: 2792: 2789: 2788: 2784: 2781: 2778: 2775: 2773: 2771: 2767: 2766: 2762: 2759: 2756: 2753: 2751: 2748: 2747: 2743: 2740: 2737: 2734: 2732: 2729: 2728: 2724: 2721: 2718: 2715: 2713: 2710: 2709: 2705: 2702: 2699: 2696: 2694: 2691: 2690: 2685: 2681: 2678: 2675: 2672: 2670: 2667: 2666: 2662: 2659: 2656: 2653: 2651: 2649: 2645: 2644: 2640: 2637: 2634: 2631: 2629: 2626: 2625: 2621: 2618: 2615: 2612: 2610: 2607: 2606: 2602: 2599: 2596: 2593: 2591: 2589: 2585: 2584: 2580: 2577: 2574: 2571: 2569: 2567: 2563: 2562: 2558: 2555: 2552: 2549: 2547: 2545: 2541: 2540: 2536: 2533: 2530: 2527: 2525: 2522: 2521: 2517: 2514: 2511: 2508: 2506: 2503: 2502: 2497: 2493: 2490: 2487: 2484: 2482: 2479: 2478: 2474: 2471: 2468: 2465: 2463: 2460: 2459: 2455: 2452: 2449: 2446: 2444: 2441: 2440: 2436: 2433: 2430: 2427: 2425: 2422: 2421: 2416: 2412: 2409: 2406: 2403: 2401: 2398: 2397: 2393: 2390: 2387: 2384: 2382: 2379: 2378: 2373: 2369: 2366: 2363: 2360: 2358: 2355: 2354: 2350: 2347: 2344: 2341: 2339: 2338:1,3-Butadiene 2336: 2335: 2330: 2326: 2323: 2320: 2317: 2315: 2312: 2311: 2307: 2304: 2301: 2298: 2296: 2293: 2292: 2288: 2285: 2282: 2279: 2277: 2274: 2273: 2269: 2266: 2263: 2260: 2258: 2255: 2254: 2250: 2247: 2244: 2241: 2239: 2237: 2233: 2232: 2228: 2225: 2222: 2219: 2217: 2215: 2211: 2210: 2206: 2203: 2200: 2197: 2195: 2192: 2191: 2187: 2184: 2181: 2178: 2176: 2173: 2172: 2168: 2165: 2162: 2159: 2157: 2154: 2153: 2148: 2144: 2141: 2138: 2135: 2133: 2130: 2129: 2125: 2122: 2119: 2116: 2114: 2111: 2110: 2106: 2103: 2100: 2097: 2095: 2092: 2091: 2087: 2084: 2081: 2078: 2076: 2073: 2072: 2067: 2063: 2060: 2057: 2054: 2052: 2049: 2048: 2044: 2041: 2038: 2035: 2033: 2030: 2029: 2025: 2022: 2019: 2016: 2014: 2011: 2010: 2006: 2003: 2000: 1997: 1995: 1992: 1991: 1987: 1984: 1981: 1978: 1976: 1973: 1972: 1968: 1965: 1962: 1959: 1957: 1954: 1953: 1950:Isoparaffins 1948: 1944: 1941: 1938: 1935: 1933: 1930: 1929: 1925: 1922: 1919: 1916: 1914: 1911: 1910: 1906: 1903: 1900: 1897: 1895: 1892: 1891: 1887: 1884: 1881: 1878: 1876: 1873: 1872: 1868: 1865: 1862: 1859: 1857: 1854: 1853: 1849: 1846: 1843: 1840: 1838: 1835: 1834: 1830: 1827: 1824: 1821: 1819: 1816: 1815: 1811: 1808: 1805: 1802: 1800: 1797: 1796: 1792: 1789: 1786: 1783: 1781: 1778: 1777: 1773: 1770: 1767: 1764: 1762: 1759: 1758: 1754: 1751: 1748: 1745: 1743: 1740: 1739: 1735: 1732: 1729: 1726: 1724: 1721: 1720: 1715: 1712: 1708: 1705: 1702: 1699: 1697: 1693: 1690: 1687: 1684: 1681: 1680: 1667: 1664: 1661: 1659: 1655: 1651: 1648: 1645: 1643: 1639: 1635: 1632: 1629: 1627: 1623: 1619: 1616: 1613: 1611: 1607: 1603: 1600: 1597: 1595: 1591: 1587: 1584: 1581: 1579: 1575: 1571: 1568: 1565: 1563: 1559: 1555: 1552: 1549: 1547: 1543: 1539: 1536: 1533: 1531: 1527: 1524: 1520: 1517: 1514: 1511: 1508: 1505: 1502: 1501: 1489: 1487: 1484: 1481: 1478: 1474: 1471: 1469: 1466: 1463: 1460: 1456: 1452: 1450: 1447: 1444: 1442: 1438: 1435: 1433: 1430: 1427: 1424: 1420: 1416: 1413: 1411: 1408: 1405: 1402: 1398: 1394: 1390: 1387: 1385: 1382: 1379: 1376: 1372: 1368: 1364: 1362: 1359: 1356: 1354: 1350: 1346: 1344: 1341: 1338: 1336: 1332: 1328: 1326: 1323: 1320: 1318: 1314: 1310: 1308: 1305: 1302: 1300: 1296: 1292: 1289: 1286: 1283: 1281: 1277: 1273: 1270: 1267: 1264: 1262: 1258: 1254: 1251: 1248: 1245: 1243: 1239: 1235: 1232: 1229: 1226: 1224: 1220: 1216: 1213: 1210: 1207: 1205: 1201: 1197: 1194: 1191: 1188: 1186: 1182: 1178: 1176: 1172: 1169: 1166: 1163: 1160: 1157: 1156: 1152: 1145: 1129: 1125: 1122: 1119: 1115: 1112: 1109: 1106: 1105: 1104: 1095: 1093: 1087: 1075: 1071: 1067: 1063: 1059: 1056: 1055: 1054: 1049: 1030: 1023: 1003: 989: 972: 956: 948: 938: 932: 920: 916: 902: 884: 883: 882: 879: 877: 873: 866:MJ/kg vs. 120 861: 857: 853: 849: 848:sensible heat 838: 835: 833: 829: 824: 822: 812: 810: 806: 802: 793: 789: 783: 779: 774: 758: 753: 750: 745: 743: 739: 735: 730: 724: 720: 716: 712: 708: 698: 695: 691: 687: 683: 678: 674: 670: 666: 663: 659: 655: 645: 622: 604: 602: 598: 594: 589: 588: 582: 430:Gross and net 422: 420: 371: 365: 343: 326: 304: 292: 286: 278: 267: 256: 245: 236: 235: 234: 228: 222: 200: 196: 192: 187: 183: 177: 173: 169: 162: 156: 150: 144: 138: 128: 124: 120: 99: 96: 93: 89: 88: 87: 85: 81: 77: 73: 69: 65: 61: 58:is the total 57: 52: 50: 46: 42: 38: 34: 30: 26: 22: 21:heating value 3853: 3816: 3798: 3786: 3777: 3768: 3751: 3734: 3716: 3707: 3698: 3681: 3677: 3671: 3660:. Retrieved 3653:the original 3638: 3625: 3611: 3592: 3588: 3578: 3569: 3561: 3558: 3553: 3526: 3522: 3512: 3498: 3347: 3307:Turkmenistan 3297:Saudi Arabia 3176: 2978:Acetaldehyde 2959:Formaldehyde 2935:Butoxybutane 2897:Ethoxyethane 2832: 2810: 2769: 2647: 2609:Ethylbenzene 2587: 2565: 2543: 2400:Nitropropane 2381:Nitromethane 2235: 2213: 2150:Monoolefins 2075:Cyclopentane 1335:Jet kerosene 1299:Paraffin wax 1127: 1123: 1117: 1113: 1107: 1101: 1088: 1084: 1070:power plants 1047: 1028: 1021: 1019: 880: 844: 836: 825: 818: 800: 799: 790: 775: 754: 746: 741: 737: 731: 718: 714: 710: 706: 704: 690:condensation 672: 668: 664: 661: 657: 654:gross energy 653: 651: 623: 606:HHV = 33.87m 605: 590: 584: 583: 433: 392: 369: 363: 341: 324: 302: 290: 284: 276: 265: 254: 243: 226: 223: 198: 194: 190: 182:formaldehyde 175: 171: 167: 160: 154: 148: 142: 139: 126: 103: 55: 53: 35:, usually a 28: 25:energy value 24: 20: 18: 3684:: 399–405. 3483:Wobbe index 3458:Food energy 3247:Netherlands 2750:Isopropanol 2418:Acetylenes 2113:Cyclohexane 2069:Naphthenes 1062:natural gas 852:latent heat 834:dew-point. 773: Β°C). 618:Γ· 8) + 9.4m 76:hydrocarbon 45:food energy 3876:Combustion 3865:Categories 3774:"Methanal" 3662:2021-08-06 3595:(2): 359. 3491:References 3337:Uzbekistan 3197:Bangladesh 2791:Isobutanol 2731:1-Propanol 2499:Aromatics 2332:Diolefins 1975:Isopentane 1562:1-Propanol 1375:anthracite 283:(std.) + ( 64:combustion 3468:ISO 15971 3227:Indonesia 2867:2,769.3? 2835:-Pentanol 2687:Alcohols 2481:1-Pentyne 2424:Acetylene 2276:1-Pentene 2257:Isobutene 2238:-2-Butene 2216:-2-Butene 2175:Propylene 2107:3,756.6? 1956:Isobutane 1626:Hydrazine 1578:Acetylene 1441:Wood fuel 826:When the 784:oxygen (O 610:+ 122.3(m 33:substance 3619:. Jstor. 3371:See also 3267:Pakistan 3082:120.971 3078:Hydrogen 2972:570.78 2948:4,922.4 2929:3,568.0 2910:2,510.2 2891:1,322.3 2864:13,509? 2858:31.416? 2848:3,061.2 2826:2,415.3 2813:-Butanol 2804:2,442.9 2785:2,501.6 2772:-Butanol 2763:1,829.9 2744:1,843.9 2725:1,230.1 2693:Methanol 2462:1-Butyne 2357:Isoprene 2314:1-Hexene 2194:1-Butene 2156:Ethylene 2145:4,259.5 2126:3,656.8 2104:19,193? 2098:44.636? 2088:3,129.0 2064:5,061.5 2045:4,458.5 2026:3,848.7 2007:3,850.7 1988:3,264.1 1969:2,651.0 1945:7,519.6 1932:Dodecane 1926:6,908.0 1913:Undecane 1907:6,294.5 1888:5,683.3 1869:5,074.9 1850:4,465.8 1831:3,856.7 1812:3,272.6 1793:2,659.3 1774:2,044.2 1755:1,437.2 1717:Alkanes 1652:4,200.0 1642:Hexamine 1530:Methanol 1317:Kerosene 1185:Hydrogen 872:gasoline 832:acid gas 778:enthalpy 742:gross CV 677:enthalpy 597:hydrogen 569:(g) and 529:(g) and 471:(s) and 3799:iea.org 3531:Bibcode 3339:: 37.89 3329:: 38.42 3319:: 39.71 3309:: 37.89 3299:: 38.00 3289:: 38.23 3279:: 41.40 3269:: 34.90 3259:: 39.24 3249:: 33.32 3239:: 39.36 3229:: 40.60 3219:: 38.93 3209:: 39.00 3199:: 36.00 3189:: 39.57 3187:Algeria 3153:293.82 3129:317.56 3120:18.646 3116:Ammonia 3110:283.24 3101:10.112 3088:52,017 3063:32.808 3039:28.548 3035:Acetone 3020:31.610 3001:28.889 2982:24.156 2963:17.259 2945:16,253 2939:37.798 2926:15,633 2920:36.355 2907:14,563 2901:33.867 2888:12,342 2882:28.703 2872:Ethers 2861:35.64? 2845:14,933 2839:34.727 2823:14,012 2817:32.587 2801:14,172 2795:32.959 2782:14,222 2776:33.075 2760:13,092 2754:30.447 2741:13,192 2735:30.680 2722:12,412 2712:Ethanol 2697:19.930 2673:41.217 2654:41.193 2632:40.984 2613:40.938 2594:40.798 2590:-Xylene 2572:40.961 2568:-Xylene 2550:40.961 2546:-Xylene 2528:40.589 2524:Toluene 2509:40.170 2505:Benzene 2485:45.217 2466:45.590 2447:46.194 2428:48.241 2404:20.693 2385:10.513 2361:44.078 2342:44.613 2318:44.426 2299:44.799 2280:45.031 2261:45.055 2242:45.124 2220:45.194 2198:45.334 2179:45.799 2160:47.195 2142:18,653 2136:43.380 2123:18,684 2117:43.450 2101:33.43? 2085:19,193 2079:44.636 2061:19,053 2055:44.310 2042:19,133 2036:44.496 2023:19,203 2017:44.659 2004:19,213 1998:44.682 1985:19,454 1979:45.241 1966:19,614 1960:45.613 1942:18,983 1936:44.147 1923:19,003 1917:44.194 1904:19,023 1898:44.240 1885:19,054 1879:44.311 1866:19,104 1860:44.427 1847:19,163 1841:44.566 1837:Heptane 1828:19,504 1822:44.752 1809:21,706 1803:45.357 1799:Pentane 1790:19,673 1784:45.752 1771:19,934 1765:46.357 1761:Propane 1752:20,551 1746:47.794 1736:802.34 1733:21,504 1727:50.009 1723:Methane 1610:Ammonia 1594:Benzene 1546:Ethanol 1397:lignite 1280:Pentane 1242:Propane 1204:Methane 1198:119.96 1051:fuel,in 768:⁄ 640:, and m 624:where m 373:⁄ 345:⁄ 306:⁄ 294:⁄ 94:of fuel 90:energy/ 31:) of a 3823:  3645:  3564:: 877. 3365:  3363:atm, 0 3361:  3357:  3350:  3341:  3331:  3321:  3311:  3301:  3291:  3287:Russia 3281:  3271:  3261:  3257:Norway 3251:  3241:  3231:  3221:  3211:  3207:Canada 3201:  3191:  3150:3,940 3144:9.163 3135:Sulfur 3126:8,018 3107:4,348 3042:22.62 2942:28.88 2923:26.76 2904:24.16 2842:28.28 2820:25.45 2798:26.43 2779:26.79 2757:23.93 2738:24.65 2719:22.77 2716:26.70 2706:638.6 2703:8,570 2700:15.78 2669:Cumene 2139:33.40 2120:33.85 2082:33.52 2058:30.49 2039:30.92 2020:29.56 2001:29.18 1982:27.87 1939:33.11 1920:32.70 1901:33.29 1894:Decane 1882:31.82 1875:Nonane 1856:Octane 1844:30.48 1825:29.30 1818:Hexane 1806:28.39 1780:Butane 1742:Ethane 1668:393.5 1665:14,100 1658:Carbon 1649:12,900 1636:622.0 1620:382.6 1604:3,268 1601:18,000 1588:1,300 1585:21,500 1572:2,020 1569:14,500 1556:1,367 1553:12,800 1479:(damp) 1383:14,000 1360:19,300 1353:Diesel 1329:43.00 1324:19,862 1311:41.50 1306:19,900 1293:45.35 1287:21,876 1274:45.75 1268:20,900 1261:Butane 1255:46.35 1249:21,700 1236:47.62 1230:22,400 1223:Ethane 1217:50.00 1211:23,900 1192:61,000 1189:141.80 1179:MJ/kg 1020:where 876:diesel 868:  864:  694:boiler 601:sulfur 593:carbon 338:(g) + 323:(g) β†’ 174:βˆ’ 0.5 170:+ 0.3 70:under 68:oxygen 60:energy 3881:Fuels 3850:(PDF) 3795:(PDF) 3760:(PDF) 3656:(PDF) 3635:(PDF) 3343:MJ/Sm 3333:MJ/Sm 3323:MJ/Sm 3313:MJ/Sm 3303:MJ/Sm 3293:MJ/Sm 3283:MJ/Sm 3277:Qatar 3273:MJ/Sm 3263:MJ/Sm 3253:MJ/Sm 3243:MJ/Sm 3233:MJ/Sm 3223:MJ/Sm 3217:China 3213:MJ/Sm 3203:MJ/Sm 3193:MJ/Sm 3139:solid 2236:trans 1768:25.3 1682:Fuel 1633:8,370 1617:9,690 1537:9,800 1485:2,500 1467:6,500 1464:15.00 1461:(dry) 1453:17.0 1448:6,400 1431:8,700 1428:21.70 1409:6,500 1406:15.00 1380:32.50 1365:43.4 1357:44.80 1347:44.1 1339:46.42 1321:46.20 1303:46.00 1290:3,509 1284:48.60 1271:2,877 1265:49.50 1252:2,220 1246:50.35 1233:1,560 1227:51.90 1208:55.50 1147:Fuel 1072:with 749:water 713:, or 686:water 667:, or 557:(g), 553:(g), 517:(g), 505:(g), 459:(l), 447:(l), 197:> 84:water 66:with 43:(see 3821:ISBN 3643:ISBN 3562:1007 3453:Fire 3355:, 15 3237:Iran 3177:The 3160:Note 3091:244 3085:1.8 2811:tert 1730:6.9 1703:/lb 1688:/kg 1662:32.8 1646:30.0 1630:19.4 1614:22.5 1598:41.8 1582:49.9 1566:33.6 1550:29.7 1540:726 1534:22.7 1503:Fuel 1482:6.00 1477:Peat 1459:Peat 1445:16.0 1419:Wood 1393:Coal 1371:Coal 1167:/lb 1161:/kg 1153:LHV 1150:HHV 1068:and 1044:,out 874:and 809:coal 805:wood 366:) + 231:comb 184:and 92:mole 82:and 54:The 49:heat 41:food 37:fuel 23:(or 19:The 3739:doi 3686:doi 3682:152 3597:doi 3539:doi 3353:atm 2214:cis 1711:mol 1701:BTU 1523:mol 1515:/lb 1513:BTU 1509:/kg 1423:MAF 1401:USA 1214:890 1195:286 1175:mol 1165:BTU 1128:DAF 1124:MAF 1118:dry 807:or 740:or 719:LCV 711:NCV 684:of 673:HCV 665:GCV 636:, m 632:, m 628:, m 614:- m 405:or 389:(g) 39:or 27:or 3867:: 3852:. 3797:. 3776:. 3725:^ 3715:. 3680:. 3591:. 3587:. 3537:. 3527:92 3525:. 3521:. 3147:β€” 3141:) 3123:β€” 3104:β€” 3072:β€” 3069:β€” 3066:β€” 3048:β€” 3045:β€” 3029:β€” 3026:β€” 3023:β€” 3010:β€” 3007:β€” 3004:β€” 2991:β€” 2988:β€” 2985:β€” 2969:β€” 2966:β€” 2885:β€” 2682:β€” 2679:β€” 2676:β€” 2663:β€” 2660:β€” 2657:β€” 2641:β€” 2638:β€” 2635:β€” 2622:β€” 2619:β€” 2616:β€” 2603:β€” 2600:β€” 2597:β€” 2581:β€” 2578:β€” 2575:β€” 2559:β€” 2556:β€” 2553:β€” 2537:β€” 2534:β€” 2531:β€” 2518:β€” 2515:β€” 2512:β€” 2494:β€” 2491:β€” 2488:β€” 2475:β€” 2472:β€” 2469:β€” 2456:β€” 2453:β€” 2450:β€” 2437:β€” 2434:β€” 2431:β€” 2413:β€” 2410:β€” 2407:β€” 2394:β€” 2391:β€” 2388:β€” 2370:β€” 2367:β€” 2364:- 2351:β€” 2348:β€” 2345:β€” 2327:β€” 2324:β€” 2321:β€” 2308:β€” 2305:β€” 2302:β€” 2289:β€” 2286:β€” 2283:β€” 2270:β€” 2267:β€” 2264:β€” 2251:β€” 2248:β€” 2245:β€” 2229:β€” 2226:β€” 2223:β€” 2207:β€” 2204:β€” 2201:β€” 2188:β€” 2185:β€” 2182:β€” 2169:β€” 2166:β€” 2163:β€” 1963:β€” 1863:β€” 1787:β€” 1749:β€” 1707:kJ 1692:MJ 1686:MJ 1519:kJ 1507:MJ 1399:- 1171:kJ 1159:MJ 1114:MF 1108:AR 761:15 717:; 709:; 671:; 660:, 656:, 599:, 595:, 559:Cl 555:HF 543:CO 531:SO 507:Br 482:SO 449:Br 407:SO 395:SO 328:CO 311:) 299:- 287:+ 221:. 193:+ 3829:. 3801:. 3780:. 3762:. 3745:. 3741:: 3719:. 3692:. 3688:: 3665:. 3605:. 3599:: 3593:2 3547:. 3541:: 3533:: 3137:( 2833:n 2770:n 2648:n 2588:p 2566:m 2544:o 1709:/ 1696:L 1694:/ 1521:/ 1425:) 1421:( 1403:) 1395:( 1377:) 1373:( 1342:- 1173:/ 1048:n 1042:O 1038:2 1033:H 1029:n 1025:v 1022:H 1004:) 996:n 993:i 990:, 987:l 984:e 981:u 978:f 973:n 966:t 963:u 960:o 957:, 954:O 949:2 945:H 939:n 933:( 926:v 921:H 917:+ 913:V 910:H 907:L 903:= 899:V 896:H 893:H 846:( 786:2 770:9 766:5 763:+ 727:2 642:S 638:N 634:O 630:H 626:C 620:S 616:O 612:H 608:C 576:2 571:N 564:2 548:2 536:2 524:2 519:I 512:2 503:O 499:2 494:H 487:4 478:2 473:H 466:2 461:I 454:2 445:O 441:2 436:H 412:3 400:2 384:2 379:N 375:2 370:n 364:l 362:( 360:O 356:2 351:H 347:2 342:h 333:2 325:c 318:2 313:O 308:2 303:o 296:4 291:h 285:c 277:o 271:O 266:n 260:N 255:h 249:H 244:c 238:C 229:Β° 227:H 218:2 216:N 214:7 212:O 210:6 208:H 206:3 204:C 199:c 195:n 191:o 178:) 176:o 172:h 168:c 161:n 158:N 155:o 152:O 149:h 146:H 143:c 133:f 127:H 125:Ξ” 115:O 111:2 106:H

Index

substance
fuel
food
food energy
heat
energy
combustion
oxygen
standard conditions
hydrocarbon
carbon dioxide
water
mole
bomb calorimeter
heat of formation
formaldehyde
carbon monoxide
sulfuric acids
carbon
hydrogen
sulfur
enthalpy
latent heat of vaporization
water
condensation
boiler
heat of vaporization
higher heating value
water
American Petroleum Institute

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