278:
169:
33:
42:
568:
563:
629:
24:
782:
634:
1404:
has been investigated for use as a high resolution photoresist material since the early 1970s, using aqueous etchants. Although these aqueous etchants allowed for low-aspect ratio 2-D structures to be fabricated, they do not allow for the etching of high aspect ratio structures with 3-D periodicity.
632:
1629:
Regulation (EC) No 1272/2008 of the
European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC)
2029:
Wong, Sean H.; Thiel, Michael; Brodersen, Peter; Fenske, Dieter; Ozin, Geoffrey A.; Wegener, Martin; von
Freymann, Georg (2007). "Highly Selective Wet Etch for High-Resolution Three-Dimensional Nanostructures in Arsenic Sulfide All-Inorganic Photoresist".
1457:. It is transparent for light between wavelengths of 620 nm and 11 μm. The arsenic trisulfide glass is more resistant to oxidation than crystalline arsenic trisulfide, which minimizes toxicity concerns. It can be also used as an
870:
As(III) centres linked by sulfide centres. The sulfide centres are two-fold coordinated to two arsenic atoms. In the crystalline form, the compound adopts a ruffled sheet structure. The bonding between the sheets consists of
576:
2126:
Linping Kuai, Arjun A. Nair, and Martin F. Polz "Rapid and Simple Method for the Most-Probable-Number
Estimation of Arsenic-Reducing Bacteria" Appl Environ Microbiol. 2001, vol. 67, 3168–3173.
543:
1107:. When a film of this material is exposed to an external energy source such as thermal energy (via thermal annealing ), electromagnetic radiation (i.e. UV lamps, lasers, electron beams)), As
633:
2232:
953:
is obtained via the fusion of the elements at 390 °C. Rapid cooling of the reaction melt gives a glass. The reaction can be represented with the chemical equation:
2161:, IARC Monographs on the Evaluation of Carcinogenic Risks to Humans Supplement 7, Lyon, France: International Agency for Research on Cancer, 1987, pp. 100–6,
635:
3722:
1847:
Zoubir, Arnaud; Richardson, Martin; Rivero, Clara; Schulte, Alfons; Lopez, Cedric; et al. (2004-04-01). "Direct femtosecond laser writing of waveguides in As
3706:
3358:
2963:
3802:
3738:
3354:
2952:
2111:
3798:
3786:
3321:
1614:
669:
1405:
Certain organic reagents, used in organic solvents, permit the high-etch selectivity required to produce high-aspect ratio structures with 3-D periodicity.
3782:
2956:
2183:, IARC Monographs on the Evaluation of Carcinogenic Risks to Humans 84, Lyon, France: International Agency for Research on Cancer, 2004, pp. 39–267,
1525:
is so insoluble that its toxicity is low. Aged samples can contain substantial amounts of arsenic oxides, which are soluble and therefore highly toxic.
840:(Latin: auripigmentum), which has been used as a pigment called King's yellow. It is produced in the analysis of arsenic compounds. It is a group V/VI,
795:
1906:
Nordman, Olli; Nordman, Nina; Peyghambarian, Nasser (1998). "Electron beam induced changes in the refractive index and film thickness of amorphous As
1387:
with a full-photonic band-gap. Advances in laser patterning techniques such as three-dimensional direct laser writing (3-D DLW) and chemical wet-
657:
32:
327:
2277:
1657:, U.S. Department of Health and Human Services (NIOSH) Publication No. 2005-149, Washington, DC: Government Printing Office, 2005,
2229:
2218:
126:
1501:
Precipitation of arsenic trisulfide is used as an analytical test for presence of dissimilatory arsenic-reducing bacteria (DARB).
1313:
in air gives volatile, toxic derivatives, this conversion being one of the hazards associated with the refining of heavy metal
790:
2065:
Stoycheva, Rumiana; Simidchieva, Penka; Buroff, Atanas (1987). "Temperature dependence of the photodissociation of a-As2S3".
23:
1646:
2099:
Zenkin, S. A.; Mamedov, S. B.; Mikhailov, M. D.; Turkina, E. Yu.; Yusupov, I. Yu. Glass Phys. Chem. 1997, 5, pp 393-399.
1804:; Connell, G. A. N. (1978-12-15). "Thermally induced effects in evaporated chalcogenide films. II. Optical absorption".
1537:. It is sometimes found in low-temperature hydrothermal veins, together with some other sulfide and sulfosalt minerals.
2696:
1976:"Direct Laser Writing of Three- Dimensional Photonic Crystals with a Complete Photonic Bandgap in Chalcogenide Glasses"
1628:
2188:
2166:
1961:
1682:
1662:
292:
2108:
643:
802:
3919:
2270:
567:
2250:
976:
2203:(PDF), U.S. Department of Health and Human Services, Public Health Service, National Toxicology Program, 2005.
1482:
The ancient
Egyptians reportedly used orpiment, natural or synthetic, as a pigment in artistry and cosmetics.
2221:
1974:
Wong, S.; Deubel, M.; Pérez-Willard, F.; John, S.; Ozin, G. A.; Wegener, M.; von
Freymann, G. (2006-02-03).
1498:
for the production of pencil blue, which allowed dark blue hues to be added to fabric via pencil or brush.
867:
235:
164:
1464:
Arsenic trisulfide was used for the distinctive eight-sided conical nose over the infra-red seeker of the
256:
3934:
3929:
2263:
1388:
693:
680:
866:
occurs both in crystalline and amorphous forms. Both forms feature polymeric structures consisting of
41:
3642:
1000:
761:
176:
273:
3638:
3924:
3754:
3674:
3218:
3112:
2199:
1465:
841:
449:
2149:
1757:
molecule as a structural model for amorphous arsenic sulfide from mass spectrometric analysis".
3818:
3750:
3718:
3670:
3658:
3610:
2689:
1533:
Orpiment is found in volcanic environments, often together with other arsenic sulfides, mainly
2175:
890:, there is no medium or long-range order, but the first co-ordination sphere is well defined.
146:
3835:
3814:
3690:
3654:
3606:
3305:
3247:
3209:
3201:
3089:
3085:
2991:
2979:
2933:
2910:
2787:
2632:
2624:
2582:
2493:
2410:
2374:
2364:
2240:
1555:
1245:
dissolves to give a variety of species containing both S–S and As–S bonds. One derivative is
746:
590:
555:
527:
2245:
2213:
3770:
3702:
3686:
3454:
3435:
3408:
3378:
3235:
3194:
3073:
3007:
2975:
2922:
2906:
2655:
2402:
2393:
1987:
1864:
1813:
1766:
1715:
1578:
741:
562:
244:
54:
1694:
102:
8:
3858:
3847:
3766:
3734:
3626:
3420:
3393:
3294:
3178:
3069:
2995:
2944:
2833:
2554:
2501:
2485:
2439:
2342:
1391:, has allowed this material to be used as a photoresist to fabricate 3-D nanostructures.
1365:
1026:
872:
751:
736:
92:
1991:
1868:
1817:
1770:
1719:
1582:
277:
168:
3622:
3458:
3386:
3128:
3059:
2926:
2849:
2477:
2415:
2387:
2382:
2303:
2011:
1447:
818:
756:
2078:
1975:
999:. Arsenic was in the past analyzed and assayed by this reaction, which results in the
836:. It is a dark yellow solid that is insoluble in water. It also occurs as the mineral
3862:
3474:
3446:
3401:
3370:
3186:
3159:
3051:
2890:
2837:
2821:
2816:
2751:
2682:
2641:
2600:
2517:
2434:
2420:
2224:
2184:
2162:
2082:
2047:
2003:
1957:
1939:
1888:
1880:
1829:
1782:
1778:
1731:
1727:
1678:
1658:
1491:
467:
2131:
2015:
208:
3524:
3504:
3500:
3491:
3148:
3003:
2782:
2775:
2722:
2526:
2447:
2369:
2354:
2348:
2332:
2319:
2313:
2127:
2074:
2039:
1995:
1956:
Holleman, A. F.; Wiberg, E. "Inorganic
Chemistry" Academic Press: San Diego, 2001.
1931:
1872:
1821:
1774:
1723:
1586:
1510:
1384:
1361:
731:
499:
424:
350:
3512:
3486:
3466:
3282:
3278:
3261:
3166:
3123:
2899:
2742:
2425:
2359:
2337:
2115:
1801:
1590:
1272:
1165:
902:
886:
does not possess a layered structure but is more highly cross-linked. Like other
3346:
3337:
3316:
3266:
3252:
3035:
3019:
2807:
2767:
2308:
773:
1652:
1610:
1160:
characteristically dissolves upon treatment with aqueous solutions containing
3913:
3135:
3096:
2864:
2756:
2453:
2086:
2051:
2007:
1943:
1884:
1833:
1825:
1786:
1735:
1677:
Wells, A.F. (1984). Structural
Inorganic Chemistry, Oxford: Clarendon Press.
1458:
1434:
have been investigated as treatments for acute promyelocytic leukemia (APL).
918:
906:
845:
608:
413:
403:
157:
3289:
3064:
2844:
1999:
1892:
656:
1876:
1369:
1231:
875:. The crystalline form is usually found in geological samples. Amorphous
479:
2235:
642:
2869:
1495:
1253:, an eight-membered ring that contains 7 S atoms and 1 As atom, and an
1082:
649:
435:
372:
177:
137:
2043:
1556:"Refinement of the crystal structures of realgar, AsS and orpiment, As
2177:
Some
Drinking-water Disinfectants and Contaminants, including Arsenic
1935:
1443:
1254:
1059:"cracks" to give a mixture of molecular species, including molecular
2255:
772:
Except where otherwise noted, data are given for materials in their
2295:
1477:
1451:
1286:
1271:
also dissolves in strongly alkaline solutions to give a mixture of
926:
922:
837:
615:
1627:
Index no. 033-002-00-5 of Annex VI, Part 3, to
1608:
125:
2705:
2674:
2568:
2286:
1534:
1257:
1161:
991:
forms when aqueous solutions containing As(III) are treated with
823:
650:
441:
393:
195:
2509:
1454:
829:
1846:
1168:
887:
520:α = 90°, β = 90.68(8)°, γ = 90°
219:
115:
261:
1973:
1905:
1223:
is the anhydride of the hypothetical trithioarsenous acid,
706:
2064:
1314:
2028:
604:
2151:
1799:
1615:
National
Institute for Occupational Safety and Health
1164:
ions. The dissolved arsenic species is the pyramidal
925:
of 2.7 eV. The wide band gap makes it transparent to
1649:, 58 FR 35310, June 30, 1993, as amended.
848:
and exhibits photo-induced phase-change properties.
1749:
Hammam, M.; Santiago, J.J. (1986). "Evidence for As
1636:
L353, 31.12.2008, pp 1–1355 at p 427.
2038:(17). American Chemical Society (ACS): 4213–4221.
1812:(12). American Physical Society (APS): 6915–6919.
1706:Martin, T.P. (1983). "Arsenic sulfide clusters".
3911:
905:and exhibits a wide glass-forming region in its
596:
207:
631:
101:
1748:
1437:
1355:
600:
2690:
2271:
1553:
1383:has been investigated for the fabrication of
1471:
2697:
2683:
2278:
2264:
929:light between 620 nm and 11 μm.
301:InChI=1S/As4S6/c5-1-6-3-8-2(5)9-4(7-1)10-3
276:
167:
145:
311:InChI=1/As4S6/c5-1-6-3-8-2(5)9-4(7-1)10-3
243:
1651:"Arsenic (inorganic compounds, as As)",
1645:"Arsenic, inorganic compounds (as As)",
1609:NIOSH Pocket Guide to Chemical Hazards.
970:
418:707 °C (1,305 °F; 980 K)
2200:Report on Carcinogens, Eleventh Edition
1408:
272:
3912:
2732:
1705:
1604:
1602:
1600:
1040:is so insoluble that it is not toxic.
408:310 °C (590 °F; 583 K)
158:
3595:
2678:
2285:
2259:
1554:Mullen, D. J. E.; Nowacki, W (1972),
1547:
1528:
1490:Arsenic trisulfide is also used as a
1442:Arsenic trisulfide manufactured into
304:Key: OUFDYFBZNDIAPD-UHFFFAOYSA-N
1350:
1048:Upon heating in a vacuum, polymeric
937:
1597:
314:Key: OUFDYFBZNDIAPD-UHFFFAOYAM
198:
13:
2704:
2141:
1863:(7). The Optical Society: 748–50.
1639:
1621:
627:
14:
3946:
2207:
2148:"Arsenic and arsenic compounds",
2067:Journal of Non-Crystalline Solids
1930:(11). AIP Publishing: 6055–6058.
1494:agent. It was formerly used with
1085:geometry, like that observed for
2197:"Arsenic Compounds, Inorganic",
1654:Pocket Guide to Chemical Hazards
1485:
1260:center attached to the As atom.
780:
566:
561:
40:
31:
22:
2132:10.1128/AEM.67.7.3168-3173.2001
2120:
2102:
2093:
2058:
2022:
1967:
1950:
1899:
1840:
1647:29 C.F.R. § 1910.1018
776:(at 25 °C , 100 kPa).
356:
2214:UK Poison Information Document
1793:
1742:
1699:
1688:
1671:
1025:can even be precipitated in 6
977:Qualitative inorganic analysis
362:
1:
2233:Poisons Information Monograph
2222:Environmental Health Criteria
2174:"Arsenic in Drinking Water",
2079:10.1016/s0022-3093(87)80482-9
2073:(1–3). Elsevier BV: 541–544.
1540:
912:
674:(US health exposure limits):
2241:WHO Food Additives Series 24
1779:10.1016/0038-1098(86)90705-2
1765:(11). Elsevier BV: 725–727.
1728:10.1016/0038-1098(83)90620-8
1591:10.1524/zkri.1972.136.1-2.48
1043:
932:
851:
7:
1714:(2). Elsevier BV: 111–114.
1438:For IR-transmitting glasses
1356:As an inorganic photoresist
509: = 1147.5(5) pm,
10:
3951:
3597:
2109:Material Safety Data Sheet
1924:Journal of Applied Physics
1759:Solid State Communications
1708:Solid State Communications
1508:
1475:
974:
513: = 957.7(4) pm,
388:yellow or orange crystals
2734:
2715:
2617:
2592:
2470:
2294:
2246:JECFA Evaluation: Arsenic
2155:Volumes 1 to 42
1504:
1014:, which is then weighed.
770:
762:Tetraarsenic tetrasulfide
717:
668:
542:
537:
460:
343:
323:
288:
85:
65:
53:
48:
39:
30:
21:
2114:October 7, 2007, at the
1826:10.1103/physrevb.18.6915
1472:Role in ancient artistry
517: = 425.6(2) pm
1695:Arsenic sulfide (As2S3)
1466:de Havilland Firestreak
450:Magnetic susceptibility
3920:Arsenic(III) compounds
2032:Chemistry of Materials
2000:10.1002/adma.200501973
1364:of 2.45 and its large
1230:. Upon treatment with
638:
1986:(3). Wiley: 265–269.
971:Aqueous precipitation
747:Phosphorus trisulfide
637:
528:Coordination geometry
1877:10.1364/ol.29.000748
1409:Medical applications
1368:compared to organic
873:van der Waals forces
742:Arsenic tritelluride
620:(fire diamond)
77:Sulphuret of arsenic
71:Arsenic(III) sulfide
55:Preferred IUPAC name
1992:2006AdM....18..265W
1869:2004OptL...29..748Z
1818:1978PhRvB..18.6915S
1771:1986SSCom..59..725H
1720:1983SSCom..47..111M
1583:1972ZK....136...48M
752:Antimony trisulfide
737:Arsenic triselenide
425:Solubility in water
380: g·mol
18:
17:Arsenic trisulfide
2251:Arsenic trisulfide
1980:Advanced Materials
1529:Natural occurrence
1448:chalcogenide glass
1446:form is used as a
868:trigonal pyramidal
819:inorganic compound
815:Arsenic trisulfide
803:Infobox references
757:Bismuth trisulfide
718:Related compounds
709:(Immediate danger)
639:
59:Arsenic trisulfide
16:
3935:Non-oxide glasses
3930:Optical materials
3907:
3906:
3901:
3900:
2672:
2671:
2044:10.1021/cm070756y
1806:Physical Review B
1630:No 1907/2006
1389:etching chemistry
1385:photonic crystals
1351:Contemporary uses
938:From the elements
821:with the formula
811:Chemical compound
809:
808:
724:Related compounds
700:Ca C 0.002 mg/m
591:Hazard statements
468:Crystal structure
257:CompTox Dashboard
127:Interactive image
3942:
3431:
3430:
3429:
3228:
3215:
3046:
3040:
3030:
3024:
2878:
2877:
2860:
2854:
2719:
2718:
2710:
2699:
2692:
2685:
2676:
2675:
2665:
2651:
2610:
2585:
2578:
2564:
2550:
2536:
2463:
2399:
2351:
2329:
2280:
2273:
2266:
2257:
2256:
2193:
2182:
2171:
2160:
2135:
2124:
2118:
2106:
2100:
2097:
2091:
2090:
2062:
2056:
2055:
2026:
2020:
2019:
1971:
1965:
1954:
1948:
1947:
1936:10.1063/1.368915
1903:
1897:
1896:
1844:
1838:
1837:
1797:
1791:
1790:
1746:
1740:
1739:
1703:
1697:
1692:
1686:
1675:
1669:
1667:
1643:
1637:
1625:
1619:
1618:
1606:
1595:
1593:
1568:
1551:
1524:
1511:Arsenic toxicity
1433:
1422:
1403:
1382:
1362:refractive index
1360:Due to its high
1346:
1312:
1297:
1296:
1295:
1292:
1283:
1282:
1281:
1278:
1270:
1252:
1244:
1229:
1222:
1209:
1203:
1202:
1199:
1195:+ 6 NaSH → 2 AsS
1181:
1180:
1179:
1176:
1159:
1146:
1106:
1095:
1080:
1069:
1058:
1039:
1024:
1013:
998:
990:
966:
952:
921:, with a direct
900:
885:
865:
835:
793:
787:
784:
783:
732:Arsenic trioxide
659:
652:
645:
630:
610:
606:
602:
598:
570:
565:
500:Lattice constant
456:−70.0·10 cm/mol
379:
364:
358:
351:Chemical formula
281:
280:
265:
263:
247:
211:
200:
179:
171:
160:
149:
129:
105:
44:
35:
26:
19:
15:
3950:
3949:
3945:
3944:
3943:
3941:
3940:
3939:
3910:
3909:
3908:
3903:
3902:
3866:
3861:
3851:
3843:
3839:
3826:
3822:
3817:
3810:
3806:
3801:
3794:
3790:
3785:
3778:
3774:
3769:
3762:
3758:
3753:
3746:
3742:
3737:
3730:
3726:
3721:
3714:
3710:
3705:
3698:
3694:
3689:
3682:
3678:
3673:
3666:
3662:
3657:
3650:
3646:
3641:
3634:
3630:
3625:
3618:
3614:
3609:
3520:
3516:
3508:
3503:
3495:
3482:
3478:
3473:
3470:
3462:
3457:
3450:
3445:
3443:
3439:
3428:
3425:
3424:
3423:
3421:
3416:
3412:
3407:
3405:
3397:
3392:
3390:
3382:
3374:
3366:
3362:
3357:
3341:
3325:
3315:
3313:
3309:
3304:
3302:
3298:
3288:
3286:
3281:
3274:
3270:
3256:
3243:
3239:
3227:
3223:
3219:
3217:
3214:
3210:
3205:
3200:
3198:
3190:
3182:
3174:
3170:
3155:
3152:
3134:
3132:
3122:
3120:
3116:
3111:
3109:
3105:
3095:
3093:
3088:
3081:
3077:
3072:
3058:
3055:
3047:
3044:
3041:
3038:
3031:
3028:
3025:
3022:
3015:
3011:
3006:
2999:
2994:
2987:
2983:
2978:
2971:
2967:
2962:
2960:
2955:
2948:
2943:
2941:
2937:
2932:
2930:
2925:
2918:
2914:
2909:
2894:
2876:
2873:
2872:
2871:
2863:
2861:
2858:
2855:
2852:
2843:
2841:
2836:
2829:
2825:
2811:
2791:
2781:
2779:
2771:
2766:
2764:
2760:
2746:
2726:
2711:
2708:
2703:
2673:
2668:
2663:
2659:
2654:
2649:
2645:
2640:
2636:
2628:
2613:
2608:
2604:
2599:
2588:
2581:
2576:
2572:
2567:
2562:
2558:
2553:
2548:
2544:
2539:
2534:
2530:
2525:
2521:
2513:
2505:
2497:
2489:
2481:
2466:
2461:
2457:
2452:
2443:
2429:
2406:
2397:
2392:
2378:
2347:
2327:
2323:
2318:
2290:
2284:
2210:
2191:
2180:
2173:
2169:
2158:
2153:IARC Monographs
2147:
2144:
2142:Further reading
2139:
2138:
2125:
2121:
2116:Wayback Machine
2107:
2103:
2098:
2094:
2063:
2059:
2027:
2023:
1972:
1968:
1955:
1951:
1921:
1917:
1913:
1909:
1904:
1900:
1854:
1850:
1845:
1841:
1802:Nemanich, R. J.
1800:Street, R. A.;
1798:
1794:
1756:
1752:
1747:
1743:
1704:
1700:
1693:
1689:
1676:
1672:
1665:
1650:
1644:
1640:
1626:
1622:
1607:
1598:
1571:Z. Kristallogr.
1566:
1563:
1559:
1552:
1548:
1543:
1531:
1523:
1519:
1515:
1513:
1507:
1488:
1480:
1474:
1440:
1432:
1428:
1424:
1421:
1417:
1413:
1411:
1402:
1398:
1394:
1381:
1377:
1373:
1358:
1353:
1345:
1341:
1337:
1333:
1329:
1325:
1321:
1311:
1307:
1303:
1293:
1290:
1289:
1287:
1279:
1276:
1275:
1273:
1269:
1265:
1261:
1250:
1246:
1243:
1239:
1235:
1228:
1224:
1221:
1217:
1213:
1207:
1200:
1197:
1196:
1194:
1190:
1186:
1177:
1174:
1173:
1171:
1166:trithioarsenite
1158:
1154:
1150:
1145:
1141:
1133:
1127:
1123:
1119:
1114:
1110:
1105:
1101:
1097:
1094:
1090:
1086:
1079:
1075:
1071:
1068:
1064:
1060:
1057:
1053:
1049:
1046:
1038:
1034:
1030:
1023:
1019:
1015:
1012:
1008:
1004:
996:
992:
989:
985:
981:
979:
973:
965:
961:
958:2 As + 3 S → As
957:
951:
947:
943:
940:
935:
915:
899:
895:
891:
884:
880:
876:
864:
860:
856:
854:
834:
828:
822:
812:
805:
800:
799:
798: ?)
789:
785:
781:
777:
766:
725:
710:
697:
687:TWA 0.010 mg/m
684:
664:
663:
662:
661:
654:
647:
640:
636:
628:
593:
579:
558:
533:pyramidal (As)
530:
521:
518:
502:
488:
482:
470:
453:
427:
377:
367:
361:
353:
339:
336:
331:
330:
319:
316:
315:
312:
306:
305:
302:
296:
295:
284:
266:
259:
250:
230:
214:
201:
189:
152:
132:
119:
108:
95:
81:
80:
61:
60:
12:
11:
5:
3948:
3938:
3937:
3932:
3927:
3925:Sesquisulfides
3922:
3905:
3904:
3899:
3898:
3895:
3892:
3889:
3886:
3883:
3880:
3877:
3874:
3871:
3868:
3864:
3856:
3853:
3849:
3845:
3841:
3837:
3833:
3829:
3828:
3824:
3820:
3812:
3808:
3804:
3796:
3792:
3788:
3780:
3776:
3772:
3764:
3760:
3756:
3748:
3744:
3740:
3732:
3728:
3724:
3716:
3712:
3708:
3700:
3696:
3692:
3684:
3680:
3676:
3668:
3664:
3660:
3652:
3648:
3644:
3636:
3632:
3628:
3620:
3616:
3612:
3604:
3600:
3599:
3596:
3593:
3592:
3589:
3586:
3583:
3580:
3577:
3574:
3571:
3568:
3565:
3562:
3559:
3556:
3553:
3550:
3547:
3544:
3541:
3538:
3534:
3533:
3530:
3527:
3522:
3518:
3514:
3510:
3506:
3498:
3493:
3489:
3484:
3480:
3476:
3468:
3464:
3460:
3452:
3448:
3441:
3437:
3433:
3426:
3418:
3414:
3410:
3403:
3399:
3395:
3388:
3384:
3380:
3376:
3372:
3368:
3364:
3360:
3352:
3349:
3344:
3339:
3334:
3333:
3330:
3327:
3323:
3319:
3311:
3307:
3300:
3296:
3292:
3284:
3276:
3272:
3268:
3264:
3259:
3254:
3250:
3245:
3241:
3237:
3233:
3230:
3225:
3221:
3212:
3207:
3203:
3196:
3192:
3188:
3184:
3180:
3176:
3172:
3168:
3164:
3162:
3157:
3154:
3150:
3145:
3144:
3141:
3138:
3130:
3126:
3118:
3114:
3107:
3103:
3099:
3091:
3083:
3079:
3075:
3067:
3062:
3053:
3049:
3043:
3037:
3033:
3027:
3021:
3017:
3013:
3009:
3001:
2997:
2989:
2985:
2981:
2973:
2969:
2965:
2958:
2950:
2946:
2939:
2935:
2928:
2920:
2916:
2912:
2904:
2902:
2897:
2892:
2887:
2886:
2883:
2880:
2874:
2867:
2857:
2851:
2847:
2839:
2831:
2827:
2823:
2819:
2814:
2809:
2804:
2803:
2800:
2797:
2794:
2789:
2785:
2777:
2773:
2769:
2762:
2758:
2754:
2749:
2744:
2739:
2738:
2735:
2733:
2731:
2729:
2724:
2717:
2716:
2713:
2712:
2702:
2701:
2694:
2687:
2679:
2670:
2669:
2667:
2666:
2661:
2657:
2652:
2647:
2643:
2638:
2634:
2630:
2626:
2621:
2619:
2615:
2614:
2612:
2611:
2606:
2602:
2596:
2594:
2590:
2589:
2587:
2586:
2579:
2574:
2570:
2565:
2560:
2556:
2551:
2546:
2542:
2537:
2532:
2528:
2523:
2519:
2515:
2511:
2507:
2503:
2499:
2495:
2491:
2487:
2483:
2479:
2474:
2472:
2468:
2467:
2465:
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2450:
2445:
2441:
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2427:
2423:
2418:
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2408:
2404:
2400:
2395:
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2385:
2380:
2376:
2372:
2367:
2362:
2357:
2352:
2345:
2340:
2335:
2330:
2325:
2321:
2316:
2311:
2306:
2300:
2298:
2292:
2291:
2283:
2282:
2275:
2268:
2260:
2254:
2253:
2248:
2243:
2238:
2227:
2216:
2209:
2208:External links
2206:
2205:
2204:
2195:
2189:
2167:
2143:
2140:
2137:
2136:
2119:
2101:
2092:
2057:
2021:
1966:
1949:
1919:
1915:
1911:
1907:
1898:
1857:Optics Letters
1852:
1848:
1839:
1792:
1754:
1750:
1741:
1698:
1687:
1670:
1663:
1638:
1620:
1596:
1577:(1–2): 48–65,
1561:
1557:
1545:
1544:
1542:
1539:
1530:
1527:
1521:
1517:
1506:
1503:
1487:
1484:
1476:Main article:
1473:
1470:
1439:
1436:
1430:
1426:
1419:
1415:
1410:
1407:
1400:
1396:
1379:
1375:
1366:Knoop hardness
1357:
1354:
1352:
1349:
1348:
1347:
1343:
1339:
1335:
1331:
1327:
1323:
1309:
1305:
1267:
1263:
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1237:
1226:
1219:
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1125:
1121:
1112:
1108:
1103:
1099:
1092:
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1077:
1073:
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1021:
1017:
1010:
1006:
994:
987:
983:
972:
969:
968:
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963:
959:
949:
945:
939:
936:
934:
931:
914:
911:
897:
893:
882:
878:
862:
858:
853:
850:
832:
826:
810:
807:
806:
801:
779:
778:
774:standard state
771:
768:
767:
765:
764:
759:
754:
749:
744:
739:
734:
728:
726:
723:
720:
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559:
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531:
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382:
381:
375:
369:
368:
365:
359:
354:
349:
346:
345:
341:
340:
338:
337:
335:S13S2S(S1S2)S3
334:
326:
325:
324:
321:
320:
318:
317:
313:
310:
309:
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303:
300:
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274:DTXSID50274153
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194:
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173:
172:
162:
154:
153:
151:
150:
142:
140:
134:
133:
131:
130:
122:
120:
113:
110:
109:
107:
106:
98:
96:
91:
88:
87:
83:
82:
79:
78:
75:
72:
68:
67:
63:
62:
58:
57:
51:
50:
46:
45:
37:
36:
28:
27:
9:
6:
4:
3:
2:
3947:
3936:
3933:
3931:
3928:
3926:
3923:
3921:
3918:
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3915:
3896:
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3511:
3509:
3502:
3499:
3497:
3490:
3488:
3485:
3483:
3472:
3465:
3463:
3456:
3453:
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3444:
3434:
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3419:
3417:
3406:
3400:
3398:
3391:
3385:
3383:
3377:
3375:
3369:
3367:
3356:
3353:
3350:
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3345:
3343:
3336:
3335:
3331:
3328:
3326:
3320:
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3303:
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3110:
3100:
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3063:
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3034:
3032:
3018:
3016:
3005:
3002:
3000:
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2990:
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2721:
2720:
2714:
2707:
2700:
2695:
2693:
2688:
2686:
2681:
2680:
2677:
2664:
2653:
2650:
2639:
2637:
2631:
2629:
2623:
2622:
2620:
2616:
2609:
2598:
2597:
2595:
2591:
2584:
2580:
2577:
2566:
2563:
2552:
2549:
2538:
2535:
2524:
2522:
2516:
2514:
2508:
2506:
2500:
2498:
2492:
2490:
2484:
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2476:
2475:
2473:
2469:
2462:
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2449:
2446:
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2433:
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2412:
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2368:
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2363:
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2242:
2239:
2237:
2236:G042: Arsenic
2234:
2231:
2228:
2226:
2223:
2220:
2217:
2215:
2212:
2211:
2202:
2201:
2196:
2192:
2190:92-832-1284-3
2186:
2179:
2178:
2170:
2168:92-832-1411-0
2164:
2157:
2156:
2152:
2146:
2145:
2133:
2129:
2123:
2117:
2113:
2110:
2105:
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2088:
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2080:
2076:
2072:
2068:
2061:
2053:
2049:
2045:
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2037:
2033:
2025:
2017:
2013:
2009:
2005:
2001:
1997:
1993:
1989:
1985:
1981:
1977:
1970:
1963:
1962:0-12-352651-5
1959:
1953:
1945:
1941:
1937:
1933:
1929:
1925:
1902:
1894:
1890:
1886:
1882:
1878:
1874:
1870:
1866:
1862:
1858:
1855:thin films".
1843:
1835:
1831:
1827:
1823:
1819:
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1803:
1796:
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1709:
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1696:
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1683:0-19-855370-6
1680:
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1666:
1664:9780160727511
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1499:
1497:
1493:
1486:Miscellaneous
1483:
1479:
1469:
1467:
1462:
1460:
1459:acousto-optic
1456:
1453:
1449:
1445:
1435:
1406:
1392:
1390:
1386:
1371:
1367:
1363:
1320:
1319:
1318:
1316:
1300:
1298:
1284:
1259:
1256:
1233:
1185:
1184:
1183:
1170:
1167:
1163:
1137:
1132:
1118:
1117:
1116:
1115:polymerizes:
1084:
1041:
1028:
1002:
1001:precipitation
978:
956:
955:
954:
930:
928:
924:
920:
919:semiconductor
910:
908:
907:phase diagram
904:
889:
874:
869:
849:
847:
846:semiconductor
843:
839:
831:
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816:
804:
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708:
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696:(Recommended)
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683:(Permissible)
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159:ECHA InfoCard
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2198:
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1370:photoresists
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1149:
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1130:
1047:
980:
941:
916:
903:glass former
855:
814:
813:
670:
616:
582:
544:
514:
510:
506:
490:
220:RTECS number
86:Identifiers
66:Other names
1302:"Roasting"
1232:polysulfide
1081:adopts the
577:Signal word
480:Space group
473:monoclinic
440:soluble in
385:Appearance
344:Properties
165:100.013.744
3914:Categories
1541:References
1509:See also:
1496:indigo dye
1461:material.
1083:adamantane
975:See also:
942:Amorphous
913:Properties
901:is a good
556:Pictograms
461:Structure
436:Solubility
430:insoluble
398:3.43 g/cm
373:Molar mass
245:44SIJ800OX
138:ChemSpider
114:3D model (
93:CAS Number
2593:As(III,V)
2296:Arsenides
2289:compounds
2087:0022-3093
2052:0897-4756
2008:0935-9648
1944:0021-8979
1885:0146-9592
1834:0163-1829
1787:0038-1098
1736:0038-1098
1468:missile.
1444:amorphous
1255:exocyclic
1044:Reactions
933:Synthesis
852:Structure
842:intrinsic
547:labelling
493:(No. 11)
227:CG2638000
186:215-117-4
178:EC Number
103:1303-33-9
2706:Sulfides
2112:Archived
2016:53527218
1922:films".
1893:15072379
1617:(NIOSH).
1478:orpiment
1452:infrared
927:infrared
923:band gap
917:It is a
838:orpiment
617:NFPA 704
538:Hazards
452:(χ)
147:21241348
74:Orpiment
3598:
2471:As(III)
2287:Arsenic
1988:Bibcode
1865:Bibcode
1814:Bibcode
1767:Bibcode
1716:Bibcode
1611:"#0038"
1579:Bibcode
1535:realgar
1492:tanning
1258:sulfido
1162:sulfide
888:glasses
844:p-type
817:is the
796:what is
794: (
442:ammonia
394:Density
209:4093503
196:PubChem
2187:
2165:
2085:
2050:
2014:
2006:
1960:
1942:
1914:and As
1891:
1883:
1832:
1785:
1734:
1681:
1661:
1505:Safety
1455:optics
1342:+ 6 SO
1234:ions,
1225:As(SH)
791:verify
788:
583:Danger
378:246.02
328:SMILES
49:Names
2618:As(V)
2181:(PDF)
2159:(PDF)
2012:S2CID
1920:100−x
1912:100−x
1567:(PDF)
1330:+ 9 O
1204:+ 3 H
1169:anion
1120:2 (As
1029:HCl.
671:NIOSH
293:InChI
116:JSmol
2633:AsCl
2494:AsCl
2486:AsCl
2478:AsBr
2435:TaAs
2421:SmAs
2416:PuAs
2411:PrAs
2403:PdAs
2394:NpAs
2388:NpAs
2383:MnAs
2375:MoAs
2370:LiAs
2360:InAs
2355:GaAs
2349:HoAs
2343:DyAs
2338:CoAs
2333:CaAs
2314:BiAs
2304:AlAs
2230:IPCS
2219:IPCS
2185:ISBN
2163:ISBN
2083:ISSN
2048:ISSN
2004:ISSN
1958:ISBN
1940:ISSN
1889:PMID
1881:ISSN
1830:ISSN
1783:ISSN
1732:ISSN
1679:ISBN
1659:ISBN
1634:OJEU
1450:for
1423:and
1334:→ As
1322:2 As
1315:ores
1285:and
1251:As−S
1096:and
713:Ca
707:IDLH
609:H411
605:H400
601:H331
597:H300
236:UNII
3897:No
3894:Md
3891:Fm
3888:Es
3885:Cf
3882:Bk
3879:Cm
3876:Am
3873:Pu
3870:Np
3855:Pa
3848:ThS
3832:**
3815:YbS
3799:TmS
3783:ErS
3767:HoS
3751:DyS
3735:TbS
3719:GdS
3703:EuS
3687:SmS
3671:PmS
3655:NdS
3639:PrS
3623:CeS
3607:LaS
3591:Og
3588:Ts
3585:Lv
3582:Mc
3579:Fl
3576:Nh
3573:Cn
3570:Rg
3567:Ds
3564:Mt
3561:Hs
3558:Bh
3555:Sg
3552:Db
3549:Rf
3546:Lr
3543:**
3540:Ra
3537:Fr
3532:Rn
3529:At
3525:PoS
3505:PbS
3501:PbS
3487:HgS
3459:PtS
3455:PtS
3447:IrS
3422:OsS
3402:ReS
3379:TaS
3371:HfS
3355:LuS
3347:BaS
3332:Xe
3322:TeS
3317:-Sb
3290:-Sn
3283:SnS
3279:SnS
3262:CdS
3248:PdS
3232:Ru
3211:TcS
3202:MoS
3195:MoS
3187:NbS
3179:ZrS
3160:SrS
3143:Kr
3140:Br
3136:+Se
3129:SeS
3124:-As
3097:-Ge
3090:GeS
3086:GeS
3070:GaS
3065:ZnS
3060:CuS
3004:FeS
2996:MnS
2992:MnS
2976:CrS
2945:TiS
2927:TiS
2923:TiS
2907:ScS
2900:CaS
2885:Ar
2882:Cl
2845:-Si
2838:SiS
2834:SiS
2817:MgS
2802:Ne
2792:)SH
2788:(NH
2783:COS
2768:+BO
2752:BeS
2737:He
2709:(S)
2625:AsF
2583:AsP
2518:AsI
2510:AsH
2502:AsF
2448:YAs
2440:WAs
2365:YAs
2309:BAs
2128:doi
2075:doi
2040:doi
1996:doi
1932:doi
1873:doi
1822:doi
1775:doi
1724:doi
1587:doi
1575:136
1288:AsO
1274:AsS
1172:AsS
1003:of
694:REL
681:PEL
545:GHS
262:EPA
199:CID
3916::
3863:US
3859:US
3836:Ac
3819:Yb
3803:Tm
3787:Er
3771:Ho
3755:Dy
3739:Tb
3723:Gd
3707:Eu
3691:Sm
3675:Pm
3659:Nd
3643:Pr
3627:Ce
3611:La
3603:*
3513:Bi
3492:Tl
3475:Au
3467:Au
3436:Ir
3409:Re
3394:WS
3387:WS
3359:Lu
3351:*
3338:Cs
3329:I
3306:Sb
3295:Sb
3267:In
3253:Ag
3236:Rh
3220:Tc
3149:Rb
3113:As
3102:As
3074:Ga
3052:Cu
3036:Ni
3020:Co
3008:Fe
2980:Cr
2957:VS
2953:VS
2934:Ti
2911:Sc
2870:-S
2865:-P
2822:Al
2808:Na
2799:F
2796:O
2776:CS
2743:Li
2656:As
2642:As
2601:As
2569:As
2559:Se
2555:As
2541:As
2527:As
2458:As
2454:Zn
2430:As
2426:Na
2324:As
2320:Cd
2172:.
2081:.
2071:90
2069:.
2046:.
2036:19
2034:.
2010:.
2002:.
1994:.
1984:18
1982:.
1978:.
1938:.
1928:84
1926:.
1918:Se
1887:.
1879:.
1871:.
1861:29
1859:.
1828:.
1820:.
1810:18
1808:.
1781:.
1773:.
1763:59
1761:.
1730:.
1722:.
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1710:.
1632:.
1613:.
1599:^
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1425:As
1414:As
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1374:As
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1291:3−
1277:3−
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485:P2
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3805:2
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3324:2
3312:5
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644:3
515:c
511:b
507:a
491:n
489:/
487:1
366:3
363:S
360:2
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260:(
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