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Hypergolic propellant

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183: 31: 2520: 387: 374:(and optional hypergolic boosters on the Ariane 3 and 4) have been retired and replaced with the Ariane 5, which uses a first stage fueled by liquid hydrogen and liquid oxygen. The Titan II, III and IV, with their hypergolic first and second stages, have also been retired. Hypergolic propellants are still widely used in upper stages when multiple burn-coast periods are required, and in 429:
As hypergolic rockets do not need an ignition system, they can fire any number of times by simply opening and closing the propellant valves until the propellants are exhausted and are therefore uniquely suited for spacecraft maneuvering and well suited, though not uniquely so, as upper stages of such
79:. The main advantages of hypergolic propellants are that they can be stored as liquids at room temperature and that engines which are powered by them are easy to ignite reliably and repeatedly. Common hypergolic propellants are difficult to handle due to their extreme 266:
as oxidizer. The hypergolic rocket motor had the advantage of fast climb and quick-hitting tactics at the cost of being very volatile and capable of exploding with any degree of inattention. Other proposed combat rocket fighters like the
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has so far limited their practical use to space launch vehicles where they need to be stored only briefly. As the largest issue with the usage of cryogenic propellants in interplanetary space is boil-off, which is largely dependent on
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are not hypergolic, but concentrated hydrogen peroxide (referred to as high-test peroxide or HTP) run over a catalyst produces free oxygen and steam at over 700 °C (1,300 °F) which is hypergolic with
947:) + all known fuels – Briefly considered as an oxidizer given its high hypergolicity with all standard fuels, but ultimately abandoned in the 70s due to the difficulty of handling the substance safely. 1402: 588:
of traditional hypergolics necessitate expensive safety precautions. Failure to follow adequate safety procedures with an exceptionally dangerous UDMH-nitric acid propellant mixture nicknamed
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Hypergolically-fueled rocket engines are usually simple and reliable because they need no ignition system. Although larger hypergolic engines in some launch vehicles use
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vertical launch expendable fighter was ever flight-tested with the Walter rocket propulsion system as its primary sustaining thrust system for military-purpose aircraft.
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substances, which ignite spontaneously in the presence of air, are also sometimes used as rocket fuels themselves or to ignite other fuels. For example a mixture of
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which required external ignition, and lithergols were solid/liquid hybrids. Hypergolic propellants (or at least hypergolic ignition) were far less prone to
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rocket engine. This propellant combination would have yielded a significant increase in performance, but was ultimately given up due to toxicity concerns.
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The trend among western space launch agencies is away from large hypergolic rocket engines and toward hydrogen/oxygen engines with higher performance.
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like liquid oxygen in a missile that had to be kept launch ready for months or years at a time led to a switch to hypergolic propellants in the U.S.
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than electric or pyrotechnic ignition. The "hypergole" terminology was coined by Dr. Wolfgang Nöggerath, at the Technical University of
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fuel offers extremely high performance, yet its density only warrants its usage in the largest of rocket stages, while mixtures of
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of 80–83%. He was probably the first to discover this phenomenon, and set to work developing a fuel. Prof. Otto Lutz assisted the
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In contemporary usage, the terms "hypergol" and "hypergolic propellant" usually mean the most common such propellant combination:
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and PBY bombers, but the project was disliked because of the toxic properties of both fuel and oxidizer, as well as the high
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Peenemünde West: Die Erprobungsstelle der Luftwaffe für geheime Fernlenkwaffen und deren Entwicklungsgeschichte
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Peenemünde West: The Luftwaffe's test center for secret guided missiles and the history of their development
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worked on aniline/nitric acid engines in the early 1940s, for small missiles and jet assisted take-off (
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Another advantage of hypergolic propellants is their high density compared to cryogenic propellants.
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Apollo 11 Mission Report - Performance of the Command and Service Module Reaction Control System
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of aniline. The second problem was eventually solved by the addition of small quantities of
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were meant to use the Walter 509 series of rocket motors, but besides the Me 163, only the
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Hypergolic propellants were discovered independently, for the second time, in the U.S. by
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Lutz, O. (1957). "BMW Developments". In Benecke, T. H.; Quick, A.W.; Schulz, W. (eds.).
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Command and control: nuclear weapons, the Damascus Accident, and the illusion of safety
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and Navy Annapolis researchers in 1940. They developed engines powered by aniline and
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History of German Guided Missiles Development (Guided Missiles Seminar. 1956. Munich)
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has a density of 1.14 g/ml, while on the other hand, hypergolic oxidizers such as
260:, a rocket motor which consumed methanol/hydrazine as fuel and high test peroxide 2117: 1921: 1887: 1728: 1461: 1319: 1198: 1181: 1032: 558: 542: 526: 494: 305: 156: 107: 316:. Although they are preferred in space launchers, the difficulties of storing a 30: 2450: 2385: 2086: 1926: 1718: 1024: 978: 970: 707: 691: 347:, employed hypergolic fuels in both the descent and ascent rocket engines. The 344: 325: 268: 230: 211: 172: 160: 152: 1378: 2538: 2460: 2380: 2235: 2204: 1984: 1974: 1969: 1892: 1882: 845: 699: 685: 666: 570: 562: 514: 498: 356: 313: 279: 186:
An early hypergolic-propellant rocket engine, the Walter 109-509A of 1942–45.
84: 61: 1302:"Fuel Propellants - Storable, and Hypergolic vs. Ignitable by Mike Schooley" 489:. They are suitable for use in spacecraft missions lasting many years. The 2465: 2424: 2397: 2156: 1952: 1947: 1596:"Project SPECTRA - Experimental evaluation of a Liquid storable propellant" 919: 857: 841: 761: 592:, for example, resulted in the deadliest rocketry accident in history, the 553:
Relative to their mass, traditional hypergolic propellants possess a lower
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A Summary of NASA and USAF Hypergolic Propellant Related Spills and Fires
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have a density at least ten times higher. This is of great importance in
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Modern Engineering for Design of Liquid-Propellant Rocket Engines
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Ignition! An Informal History of Liquid Rocket Propellants
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Ignition! An Informal History of Liquid Rocket Propellants
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3rd International Hydrogen Peroxide Propulsion Conference
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Less-common or obsolete hypergolic propellants include:
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have a density of 1.55 g/ml and 1.45 g/ml respectively.
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The only rocket-powered fighter ever deployed was the
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World War II German rocket fighter aircraft, for its
359:(among others) used hypergolic propellants for their 860:derivatives (AK-2x group in the Soviet Union) e.g. 609:Common hypergolic propellant combinations include: 71:The two propellant components usually consist of a 1096:Melof, Brian M.; Grubelich, Mark C. (2000-11-15). 1666:"European space-rocket liquid-propellant engines" 1492:. Archived from the original on February 2, 2013. 1464:Development of the Shuttle, 1972–1981 - Volume 2. 2536: 221:or oil, later influenced by the chemical suffix 959:) presents the same hazards, but offers higher 930:Upper Stages, Isayev-built maneuvering engines. 1095: 336:and then in land-based U.S. and Soviet ICBMs. 1848: 194:, rocket propellants were broadly classed as 68:when they come into contact with each other. 557:than cryogenic propellant combinations like 1793:History of Liquid Propellant Rocket Engines 1510: 1200:History of Liquid Propellant Rocket Engines 934: 128:which contained 30% hydrazine hydrate, 57% 1855: 1841: 1490:"Space Launch Report: Ariane 5 Data Sheet" 1135: 1133: 1131: 1129: 1127: 1125: 1123: 1121: 1119: 744: 599: 38:due to the hazards of the hypergolic fuel 1862: 1251: 985:, was studied by Soviet Rocket Scientist 890:(methanol, hydrazine, water, catalyst) – 2267:Atmosphere-breathing electric propulsion 1340: 506:of spacecraft, for larger craft such as 385: 181: 29: 1116: 908:(flown in French Diamant A first-stage) 14: 2537: 1781:, Huzel & Huang, pub. AIAA, 1992. 1196: 1173: 1007:– A sightly less toxic alternative to 951:is known to burn concrete and gravel. 190:In Germany from the mid-1930s through 1836: 1744: 1405:from the original on 15 November 2014 1223: 1190: 1139: 1015: 334:submarine-launched ballistic missiles 324:and in most Soviet ICBMs such as the 274:and reconnaissance aircraft like the 1584:from the original on 7 January 2022. 1459: 1334: 1179: 1256:. New York, NY: The Penguin Press. 760:(unstable, explosive), used in the 390:Hypergolic propellant tanks of the 370:1 through 4, with their hypergolic 24: 2172:Field-emission electric propulsion 1774:from the original on 10 July 2022. 1712: 1672:from the original on 23 July 2021. 1320:"PROPERTIES OF ROCKET PROPELLANTS" 1308:from the original on 24 July 2021. 1169:from the original on 10 July 2022. 469:The most common hypergolic fuels, 381: 351:used the same combination for the 25: 2561: 2246:Microwave electrothermal thruster 1808: 1708:from the original on 1 July 2022. 1690:from the original on 12 May 2022. 1468:. Smithsonian Institution Press. 1330:from the original on 26 May 2022. 660:Apollo command and service module 2518: 886:(stabilized >80% peroxide) + 548: 1694: 1676: 1658: 1634: 1612: 1588: 1570: 1539: 1482: 1453: 1427: 1409: 1398:The Nedelin Catastrophe, Part 1 1389: 1372: 1357: 1312: 714:Unsymmetrical dimethylhydrazine 479:unsymmetrical dimethylhydrazine 2376:Pulsed nuclear thermal rocket‎ 2272:High Power Electric Propulsion 1578:"WAC Corporal Sounding Rocket" 1294: 1270: 1245: 1217: 1089: 1063: 989:for usage in combination with 13: 1: 2231:Helicon double-layer thruster 2200:Electrodeless plasma thruster 2195:Magnetoplasmadynamic thruster 1795:, G. Sutton, pub. AIAA 2005. 1078: 401: 42:, here being loaded onto the 1821:The Periodic Table of Videos 1555:. 2014-03-23. Archived from 1524:. 2007-12-10. Archived from 1152:. Rutgers University Press. 7: 1460:T.A., Heppenheimer (2002). 773:(dust-sensitive, explosive) 720:(NTO) – frequently used by 704:SpaceX Merlin Engine Family 487:storable liquid propellants 355:. Those spacecraft and the 332:boosters, first in Western 233:, while non-hypergols were 34:The attendant wears a full 10: 2566: 1380:"Toxic Propellant Hazards" 1043:rocket and is used in the 1001:Tetramethylethylenediamine 852:) typically oxidized with 510:this is less of an issue. 392:Orbital Maneuvering System 101: 27:Type of rocket engine fuel 2516: 2433: 2412: 2356: 2303: 2294: 2259: 2213: 2190:Pulsed inductive thruster 2182: 2144: 2135: 2105: 2074: 2031: 2005: 1998: 1935: 1870: 1547:"ISRO tests Vikas engine" 1502:: CS1 maint: unfit URL ( 1071:Oxford English Dictionary 604: 353:Service Propulsion System 2364:Nuclear pulse propulsion 2123:Electric-pump-fed engine 2023:Hybrid-propellant rocket 2013:Liquid-propellant rocket 1826:University of Nottingham 1341:Linstrom, Peter (2021). 1252:Schlosser, Eric (2013). 1057: 935:Proposed, remain unflown 803:white fuming nitric acid 361:reaction control systems 122:with the development of 2420:Beam-powered propulsion 2393:Fission-fragment rocket 2348:Nuclear photonic rocket 2316:Nuclear electric rocket 2082:Staged combustion cycle 2018:Solid-propellant rocket 1620:"Nitric acid/Hydrazine" 745:Less common or obsolete 600:Hypergolic combinations 466:can also be restarted. 430:space launchers as the 372:first and second stages 2471:Non-rocket spacelaunch 2321:Nuclear thermal rocket 2221:Pulsed plasma thruster 1343:NIST Chemistry WebBook 1197:Sutton, G. P. (2006). 953:Chlorine pentafluoride 789:Copenhagen Suborbitals 785:red fuming nitric acid 726:Proton (rocket family) 684:thrusters used by the 398: 187: 149:red fuming nitric acid 60:combination used in a 49: 2137:Electrical propulsion 1864:Spacecraft propulsion 1816:"Hypergolic Reaction" 1224:Botho, Stüwe (1998), 624:; all engines in the 389: 376:launch escape systems 292:, such as the Soviet 185: 54:hypergolic propellant 33: 2369:Antimatter-catalyzed 2167:Hall-effect thruster 1980:Solar thermal rocket 1642:"High Test Peroxide" 1417:"ROCKET PROPELLANTS" 1011:and its derivatives. 949:Chlorine trifluoride 941:Chlorine trifluoride 892:Messerschmitt Me 163 844:(TG-02, approx. 50% 632:is a mixture of 50% 250:Messerschmitt Me 163 210:is a combination of 114:was hypergolic with 92:dinitrogen tetroxide 66:spontaneously ignite 2311:Direct Fusion Drive 2226:Vacuum arc thruster 2113:Pressure-fed engine 2092:Gas-generator cycle 1999:Chemical propulsion 1936:Physical propulsion 1608:on 4 November 2013. 1401:, 28 October 2014, 652:Monomethylhydrazine 626:Apollo Lunar Module 594:Nedelin catastrophe 475:monomethylhydrazine 341:Apollo Lunar Module 217:or work, and Latin 64:, whose components 2525:Spaceflight portal 2491:Reactionless drive 2456:Aerogravity assist 2296:Nuclear propulsion 1727:2009-04-30 at the 1702:"Nitric Acid/UDMH" 1528:on January 4, 2011 1016:Related technology 991:nitrogen tetroxide 975:nitrogen tetroxide 823:high-test peroxide 718:nitrogen tetroxide 656:nitrogen tetroxide 618:nitrogen tetroxide 523:nitrogen tetroxide 483:nitrogen tetroxide 399: 290:ballistic missiles 256:. The Komet had a 229:. Monergols were 188: 116:high-test peroxide 50: 2550:Soviet inventions 2532: 2531: 2486:Atmospheric entry 2441:Orbital mechanics 2408: 2407: 2290: 2289: 2241:Resistojet rocket 2131: 2130: 2106:Intake mechanisms 2039:Liquid propellant 1943:Cold gas thruster 1622:. Astronautix.com 1263:978-1-59420-227-8 1210:978-1-56347-649-5 1159:978-0-8135-0725-5 1029:triethylaluminium 856:or its anhydrous 831:hydrogen peroxide 771:hydrogen peroxide 724:, such as in the 696:triethylaluminium 636:and 50% straight 394:of Space Shuttle 349:Apollo spacecraft 134:hydrogen peroxide 112:hydrazine hydrate 58:rocket propellant 16:(Redirected from 2557: 2522: 2506:Alcubierre drive 2496:Field propulsion 2446:Orbital maneuver 2434:Related concepts 2301: 2300: 2152:Colloid thruster 2142: 2141: 2003: 2002: 1905:Specific impulse 1857: 1850: 1843: 1834: 1833: 1829: 1775: 1773: 1756: 1732: 1716: 1710: 1709: 1698: 1692: 1691: 1680: 1674: 1673: 1662: 1656: 1655: 1653: 1651: 1646: 1638: 1632: 1631: 1629: 1627: 1616: 1610: 1609: 1607: 1601:. 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Walter 104: 28: 23: 22: 15: 12: 11: 5: 2563: 2553: 2552: 2547: 2530: 2529: 2517: 2514: 2513: 2511: 2510: 2509: 2508: 2503: 2493: 2488: 2483: 2478: 2473: 2468: 2463: 2458: 2453: 2451:Gravity assist 2448: 2443: 2437: 2435: 2431: 2430: 2428: 2427: 2422: 2416: 2414: 2413:External power 2410: 2409: 2406: 2405: 2403: 2402: 2401: 2400: 2390: 2389: 2388: 2386:Bussard ramjet 2378: 2373: 2372: 2371: 2360: 2358: 2354: 2353: 2351: 2350: 2345: 2344: 2343: 2338: 2333: 2328: 2318: 2313: 2307: 2305: 2298: 2292: 2291: 2288: 2287: 2285: 2284: 2279: 2274: 2269: 2263: 2261: 2257: 2256: 2254: 2253: 2248: 2243: 2238: 2233: 2228: 2223: 2217: 2215: 2214:Electrothermal 2211: 2210: 2208: 2207: 2202: 2197: 2192: 2186: 2184: 2180: 2179: 2177: 2176: 2175: 2174: 2169: 2164: 2154: 2148: 2146: 2139: 2133: 2132: 2129: 2128: 2126: 2125: 2120: 2115: 2109: 2107: 2103: 2102: 2100: 2099: 2094: 2089: 2087:Expander cycle 2084: 2078: 2076: 2072: 2071: 2069: 2068: 2063: 2058: 2056:Monopropellant 2053: 2052: 2051: 2046: 2035: 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692:Triethylborane 689: 649: 645: 641: 606: 603: 601: 598: 550: 547: 403: 400: 383: 380: 343:, used in the 296:that launched 173:freezing point 161:Curtiss-Wright 153:Robert Goddard 120:Walter Company 103: 100: 26: 9: 6: 4: 3: 2: 2562: 2551: 2548: 2546: 2543: 2542: 2540: 2527: 2526: 2521: 2515: 2507: 2504: 2502: 2499: 2498: 2497: 2494: 2492: 2489: 2487: 2484: 2482: 2479: 2477: 2474: 2472: 2469: 2467: 2464: 2462: 2461:Oberth effect 2459: 2457: 2454: 2452: 2449: 2447: 2444: 2442: 2439: 2438: 2436: 2432: 2426: 2423: 2421: 2418: 2417: 2415: 2411: 2399: 2396: 2395: 2394: 2391: 2387: 2384: 2383: 2382: 2381:Fusion rocket 2379: 2377: 2374: 2370: 2367: 2366: 2365: 2362: 2361: 2359: 2355: 2349: 2346: 2342: 2339: 2337: 2334: 2332: 2329: 2327: 2324: 2323: 2322: 2319: 2317: 2314: 2312: 2309: 2308: 2306: 2304:Closed system 2302: 2299: 2297: 2293: 2283: 2280: 2278: 2275: 2273: 2270: 2268: 2265: 2264: 2262: 2258: 2252: 2249: 2247: 2244: 2242: 2239: 2237: 2236:Arcjet rocket 2234: 2232: 2229: 2227: 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Index

Hypergolic

hazmat suit
hydrazine
MESSENGER
rocket propellant
rocket engine
spontaneously ignite
fuel
oxidizer
toxicity
corrosiveness
dinitrogen tetroxide
hydrazine
Hellmuth Walter
hydrazine hydrate
high-test peroxide
Walter Company
C-Stoff
methanol
hydrogen peroxide
anilines
GALCIT
red fuming nitric acid
Robert Goddard
Reaction Motors
Curtiss-Wright
JATO
Martin PBM
freezing point

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