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Electrochemical engineering

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Switzerland, Norbert Ibl contributed to experimental and theoretical studies of mass transfer and potential distribution in electrolyses, especially at porous electrodes. Fumio Hine carried out equivalent developments in Japan. In addition, several individuals, including Kuhn, Kreysa, Rousar, Fleischmann, Alkire, Coeuret, Pletcher, and Walsh established many other training centers and, with their colleagues, developed important experimental and theoretical methods of study. Currently, the main tasks of electrochemical engineering consist of the development of efficient, safe, and sustainable technologies for the production of chemicals, metal recovery, remediation, and decontamination technologies as well as the design of fuel cells, flow batteries, and industrial electrochemical reactors.
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pioneered the study of many of the physicochemical laws that govern electrochemical systems, demonstrating how complex electrochemical processes could be analysed mathematically to correctly formulate and solve problems associated with batteries, fuel cells, electrolyzer, and related technologies. In
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in 1962, who linked the hydrodynamics of a flowing electrolyte towards a rotating disc electrode with the mass transport control of the electrochemical reaction through a rigorous mathematical treatment. The same year, Wagner described "The Scope of Electrochemical Engineering" for the first time as
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developed the electrolytic refining of iron ca. 1904 and later ran a successful battery company. Burgess published one of the first texts on the field in 1920. Industrial electrochemistry followed an empirical approach during the first three decades of the 20th century.
228:, was concerned with ionic transport by diffusion, migration, and convection, exact solutions of potential and current distribution problems, conductance in heterogeneous media, quantitative description of processes in porous electrodes. Also in the 60s, 202:
in large mercury cells for the production of chlorine and caustic soda, effectively founding the chlor-alkali industry with Karl Kellner in 1892. The next year, Paul L. Hulin patented filter-press type electrochemical cells in France.
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Bebelis, S.; Bouzek, K.; Cornell, A.; Ferreira, M.G.S.; Kelsall, G.H.; Lapicque, F.; Ponce de LeĂłn, C.; Rodrigo, M.A.; Walsh, F.C. (October 2013). "Highlights during the development of electrochemical engineering".
144:, conversion efficiency, and energy efficiency. Industrial developments require further reactor and process design, fabrication methods, testing, and product development. 224:
a separate discipline from a physicochemical perspective. During the 60s and 70s Charles W. Tobias, who is regarded as the "father of electrochemical engineering" by the
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developed a cheap electrochemical process for extracting aluminium from its ore in molten salts, constituting the first true large-scale electrochemical industry. Later,
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Most electrochemical operations are performed in filter-press reactors with parallel plate electrodes or, less often, in stirred tanks with rotating cylinder electrodes.
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The established performance criteria, definitions, and nomenclature for electrochemical engineering can be found in Kreysa et al. and an IUPAC report.
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interphases with the development of practical materials and processes. Fundamental considerations include electrode materials and the kinetics of
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This branch of engineering emerged gradually from chemical engineering as electrical power sources became available in the mid-19th century.
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After the Second World War, interest focused on the fundaments of electrochemical reactions. Among other developments, the
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Electrochemical Reactors Their Science and Technology - Part A: Fundamentals, Electrolysers, Batteries, and Fuel Cells
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Lapicque, F. (2004). "Electrochemical Engineering: An Overview of its Contributions and Promising Features".
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for caustic soda and chlorine production. Other inorganic chemicals produced by electrolysis include:
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species. The development of the technology involves the study of the electrochemical reactors, their
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The history of electrochemical engineering has been summarised by Wendt, Lapicque, and Stankovic.
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in 1833, relating for the first time the amount of electrical charge and converted mass. In 1886
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More than 6% of the electricity is consumed by large-scale electrochemical operations in the US.
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Proceedings of the Douglas N. Bennon Memorial Symposium. Topics in Electrochemical Engineering
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This diagram shows the relationship between electrochemical engineering and other disciplines.
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Kreysa, G. (1985). "Performance criteria and terminology in electrochemical engineering".
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Wendt, H.; Kreysa, G. (1999). "The Scope and History of Electrochemical Engineering".
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Electrochemical Engineering: Science and Technology in Chemical and Other Industries
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stacks are types of filter-press reactors. Most of them are continuous operations.
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Electrochemical Process Engineering - A Guide to the Design of Electrolytic Plant
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Fuel Cell Science and Engineering: Materials, Processes, Systems and Technology
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Comprehensive Treatise of Electrochemistry. Vol. 2: Electrochemical Processing
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improved the process aluminium manufacturing and devised the electrolysis of
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Comprehensive Treatise of Electrochemistry. Vol. 6 Electrodics: Transport
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of the electro reactions to design efficient electrochemical reactors.
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Newman, John (1968). "Engineering design of electrochemical systems".
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Electrochemical Engineering: Emerging Technologies and Applications
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Tutorials in Electrochemical Engineering - Mathematical Modeling
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Electrochemical engineering combines the study of heterogeneous
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Wagner, C. (1962). "The scope of electrochemical engineering".
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Carl Wagner Medal of Excellence in Electrochemical Engineering
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Advances in Electrochemistry and Electrochemical Engineering
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Electrochemical engineering considers current distribution,
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J.O’M. Bockris, B.E. Conway, E. Yeager, R.E. White, (eds.)
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Electrosynthesis - From Laboratory, to Pilot, to Production
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Arenas, L.F.; Ponce de LeĂłn, C.; Walsh, F.C. (June 2017).
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Electrochemical engineering is applied in industrial
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Working Party on Electrochemical Engineering - WPEE
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Electrode Processes and Electrochemical Engineering
864:, The Electrochemical Consultancy, Romsey UK, 1993. 611:Journal of Electrochemical Science and Engineering 1937: 1060:IEEE H.H. Dow Memorial Student Achievement Award 1045:SCI Castner Medal on Industrial Electrochemistry 962:P. Horsman, B.E. Conway, S. Sarangapani (eds.), 829:, Pennington, The Electrochemical Society, 1999. 906:, The Electrosynthesis Company, New York, 1990. 813:Kirk-Othmer Encyclopedia of Chemical Technology 26:dealing with the technological applications of 943:Principles of Electrochemical Reactor Analysis 1080: 862:A First Course in Electrochemical Engineering 1027:The Manufacture of Chemicals by Electrolysis 1022:, American Technical Society, Chicago, 1920. 843:, Plenum Press, New York & London, 1995. 802:Un Primer Curso de IngenierĂ­a ElectroquĂ­mica 876:IntroducciĂłn a la IngenierĂ­a ElectroquĂ­mica 544: 1087: 1073: 973:, 1st ed., Chapman and Hall, London, 1982. 899:, 2nd ed., Chapman and Hall, London, 1990. 706: 178:Cell room of a chlor-alkali plant ca. 1920 1018:C.F. Burgess, H.B. Pulsifer, B.B. Freud, 929:Principles of Electrochemical Engineering 724: 622: 604: 580:Chemical Engineering Research and Design 577: 460:Chemical Engineering Research and Design 173: 99: 1020:Applied Electrochemistry and Metallurgy 1015:, 2nd ed., McGraw-Hill, New York, 1940. 1008:, 4th ed., McGraw-Hill, New York, 1960. 1938: 1867:Electrical and electronics engineering 890:Electrochemical Engineering Principles 855:Electrochemical Engineering and Energy 834:Electrochemical Engineering Principles 671: 525: 487:Industrial & Engineering Chemistry 484: 1068: 992:Trattato di Ingegneria Elettrochimica 987:, 2nd ed., Elsevier, Amsterdam, 1979. 878:, Editorial RevertĂ©, Barcelona, 1992. 809:Electrochemical Processing, Inorganic 1900: 999:Industrial Electrochemical Processes 918:Industrial Electrochemical Processes 883:Electrochemical Reaction Engineering 853:F. Lapicque, A. Storck, A.A. Wragg, 1910: 1029:, Van Nostrand Co., New York, 1919. 791:Industrial Electroorganic Chemistry 764:D.D. Macdonald, P. Schmuki (eds.), 674:Journal of Applied Electrochemistry 69:, which comprises small batteries, 13: 784:Elektrochemische Verfahrenstechnik 14: 1992: 1033: 869:ElĂ©ments de GĂ©nie Électrochimique 392:Electrochemical energy conversion 1919: 1909: 1899: 1890: 1889: 1759: 770:Encyclopedia of Electrochemistry 1094: 980:, Plenum Press, New York, 1981. 966:, Plenum Press, New York, 1983. 934:I. Roušar, A. Kimla, K. Micka, 885:, Academic Press, London, 1991. 737: 700: 239: 985:Electrochemical Reactor Design 931:, John Wiley & Sons, 1986. 922:Techniques of Electrochemistry 846:J. Newman, R.E. White (eds.), 775:J. Newman, K.E. Thomas-Alyea, 761:, John Wiley & Sons, 2012. 747:, John Wiley & Sons, 2018. 665: 631: 598: 571: 538: 519: 515:. The Electrochemical Society. 505: 478: 450: 346: 16:Branch of chemical engineering 1: 592:10.1205/cerd.82.12.1571.58046 443: 1117:List of engineering branches 1001:, Elsevier, Amsterdam, 1971. 945:, Elsevier, Amsterdam, 1985. 938:, Elsevier, Amsterdam, 1986. 913:, Elsevier, Amsterdam, 1989. 7: 1946:Electrochemical engineering 1013:Industrial Electrochemistry 1006:Electrochemical Engineering 971:Industrial Electrochemistry 957:Electrochemical Cell Design 936:Electrochemical Engineering 902:J.D. Genders, D. Pletcher, 897:Industrial Electrochemistry 766:Electrochemical Engineering 745:Electrochemical Engineering 743:T.F. Fuller, John N. Harb, 555:10.1007/978-3-662-03851-2_1 547:Electrochemical Engineering 472:10.1016/j.cherd.2013.08.029 374: 59:electrochemical engineering 20:Electrochemical engineering 10: 1997: 1055:ECS Vittorio de Nora Award 772:, Vol. 5, Wiley-VCH, 2007. 713:Pure and Applied Chemistry 169: 1885: 1832: 1816: 1768: 1757: 1532: 1474: 1393: 1318: 1245: 1138: 1125: 1102: 994:, Tamburini, Milan, 1973. 952:, Springer, Boston, 1985. 895:D. Pletcher, F.C. Walsh, 707:Gritzner, G.; Kreysa, G. 659:10.1016/j.est.2017.02.007 647:Journal of Energy Storage 354: 205:Charles Frederick Burgess 151:, mass transfer, and the 89:at disc electrodes, etc. 38:and refining of metals, 822:, Springer, Berlin 1999. 795:Organic Electrochemistry 427:Isotope electrochemistry 95: 67:applied electrochemistry 1778:Bachelor of Engineering 1620:Engineering mathematics 867:F. Coeuret, A. Storck, 777:Electrochemical Systems 757:D. Stolten, B. Emonts, 754:, Willford Press, 2016. 726:10.1351/pac199365051009 432:Magnetoelectrochemistry 226:Electrochemical Society 1877:Structural engineering 1872:Mechanical engineering 1615:Engineering management 892:, Prentice Hall, 1991. 839:F. Goodrige, K. Scott 836:, Prentice Hall, 1997. 624:10.5599/jese.2012.0011 605:Stankovic, V. (2012). 369:Vittorio de Nora Award 341:(Basic lead carbonate) 314:Potassium permanganate 179: 105: 1857:Aerospace engineering 1770:Engineering education 927:E. Heitz, G. Kreysa, 818:H. Wendt, G. Kreysa, 437:Photoelectrochemistry 177: 103: 1976:Industrial processes 1956:Chemical engineering 1798:Graduate certificate 387:Electrochemical cell 309:Potassium dichromate 252:, electrosynthesis, 188:laws of electrolysis 24:chemical engineering 1971:Hydrogen production 1783:Bachelor of Science 1625:Engineering physics 1609:Engineering drawing 1131:Interdisciplinarity 955:R.E. White, (ed.), 499:10.1021/ie50700a005 397:Electrodeionization 382:Chloralkali process 324:Sodium hypochlorite 274:Ammonium persulfate 266:Chloralkali process 192:Charles Martin Hall 30:phenomena, such as 1961:Chemical processes 1385:Telecommunications 1290:Naval architecture 786:, Wiley-VCH, 2003. 686:10.1007/BF00620931 246:water electrolysis 180: 106: 1933: 1932: 1862:Civil engineering 1808:Licensed engineer 1803:Engineer's degree 1755: 1754: 1587:Building services 1570:Health technology 1431:Chemical reaction 1380:Signal processing 959:, Springer, 1984. 857:, Springer, 1994. 750:H. Wright (ed.), 586:(12): 1571–1574. 564:978-3-642-08406-5 466:(10): 1998–2020. 407:Electrofiltration 365:Carl Wagner Medal 329:Sodium persulfate 299:Manganese dioxide 294:Hydrogen peroxide 53:According to the 22:is the branch of 1988: 1981:Industrial gases 1951:Electrochemistry 1923: 1913: 1912: 1903: 1902: 1893: 1892: 1763: 1350:Electromechanics 1136: 1135: 1089: 1082: 1075: 1066: 1065: 731: 730: 728: 719:(5): 1009–1020. 704: 698: 697: 669: 663: 662: 644: 635: 629: 628: 626: 602: 596: 595: 575: 569: 568: 549:. pp. 1–7. 542: 536: 535: 523: 517: 516: 509: 503: 502: 482: 476: 475: 454: 196:Hamilton Castner 61:is reserved for 32:electrosynthesis 1996: 1995: 1991: 1990: 1989: 1987: 1986: 1985: 1936: 1935: 1934: 1929: 1881: 1828: 1812: 1788:Master's degree 1764: 1751: 1665:Instrumentation 1528: 1470: 1436:Electrochemical 1389: 1375:Radio frequency 1314: 1241: 1205:Municipal/Urban 1129: 1127: 1121: 1098: 1093: 1036: 825:R.F. Savinell, 807:M.P. 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Geoffrey, 831: 828: 824: 821: 817: 814: 810: 806: 803: 799: 796: 792: 788: 785: 781: 778: 774: 771: 767: 763: 760: 756: 753: 749: 746: 742: 741: 727: 722: 718: 714: 710: 703: 695: 691: 687: 683: 679: 675: 668: 660: 656: 652: 648: 641: 634: 625: 620: 616: 612: 608: 601: 593: 589: 585: 581: 574: 566: 560: 556: 552: 548: 541: 533: 529: 522: 514: 508: 500: 496: 492: 488: 481: 473: 469: 465: 461: 453: 449: 438: 435: 433: 430: 428: 425: 423: 422:Galvanic cell 420: 418: 415: 413: 410: 408: 405: 403: 400: 398: 395: 393: 390: 388: 385: 383: 380: 379: 370: 367: 364: 362: 361:Castner Medal 359: 358: 352: 340: 337: 335: 332: 330: 327: 325: 322: 320: 317: 315: 312: 310: 307: 305: 302: 300: 297: 295: 292: 290: 287: 285: 282: 280: 277: 275: 272: 271: 269: 267: 263: 259: 255: 251: 247: 237: 234: 231: 227: 222: 218: 214: 209: 206: 201: 197: 193: 189: 185: 176: 167: 165: 161: 156: 154: 150: 145: 143: 139: 138:hydrodynamics 135: 131: 127: 123: 119: 115: 111: 102: 93: 90: 88: 84: 80: 76: 72: 68: 64: 60: 56: 51: 49: 45: 41: 37: 33: 29: 25: 21: 1966:Electrolysis 1841:Engineering 1687:Mechatronics 1540:Agricultural 1435: 1190:Geotechnical 1158:Construction 1026: 1019: 1012: 1005: 998: 991: 990:P. Gallone, 984: 977: 970: 963: 956: 949: 942: 935: 928: 921: 917: 910: 903: 896: 889: 882: 875: 874:F. Coeuret, 868: 861: 860:F.C. Walsh, 854: 847: 840: 833: 826: 819: 812: 808: 801: 800:F.C. Walsh, 794: 790: 783: 776: 769: 765: 758: 751: 744: 738:Bibliography 716: 712: 702: 677: 673: 667: 650: 646: 633: 614: 610: 600: 583: 579: 573: 546: 540: 531: 527: 521: 507: 493:(4): 12–27. 490: 486: 480: 463: 459: 452: 412:Flow battery 350: 250:electrolysis 243: 240:Applications 235: 213:potentiostat 210: 181: 164:flow battery 157: 146: 136:conditions, 112:transfer at 107: 91: 75:microfluidic 71:amperometric 66: 58: 52: 19: 18: 1915:Wikiproject 1670:and Control 1660:Information 1484:Biomaterial 1414:Bioresource 1405:/Bioprocess 1403:Biochemical 1355:Electronics 1126:Specialties 1096:Engineering 1025:A.J. Hale, 916:T.R. Beck, 789:H. PĂĽtter, 653:: 119–153. 347:Conventions 230:John Newman 217:Carl Wagner 118:electrolyte 87:voltammetry 83:solid-state 63:electricity 57:, the term 1940:Categories 1834:Glossaries 1655:Industrial 1635:Facilities 1630:Explosives 1555:Biomedical 1550:Automation 1499:Metallurgy 1409:Biological 1360:Microwaves 1320:Electrical 1265:Automotive 1247:Mechanical 1220:Structural 1185:Geological 1173:Ecological 1163:Earthquake 881:K. Scott, 444:References 339:White lead 258:fuel cells 149:fluid flow 44:fuel cells 1793:Doctorate 1707:Packaging 1677:Logistics 1650:Geomatics 1611:/graphics 1504:Molecular 1494:Corrosion 1476:Materials 1456:Petroleum 1446:Molecular 1328:Broadcast 1310:Tribology 1260:Aerospace 1195:Hydraulic 997:A. Kuhn, 948:F. Hine, 694:106022706 417:Fuel cell 160:Fuel cell 126:potential 114:electrode 85:devices, 77:devices, 73:sensors, 48:corrosion 1895:Category 1824:Engineer 1732:Software 1727:Security 1702:Ontology 1692:Military 1682:Robotics 1645:Forensic 1565:Clinical 1524:Surfaces 1514:Polymers 1489:Ceramics 1466:Reaction 1395:Chemical 1333:Computer 1255:Acoustic 1210:Offshore 1178:Sanitary 617:: 1–14. 375:See also 289:Fluorine 279:Chlorine 153:kinetics 1905:Commons 1747:Textile 1742:Systems 1712:Privacy 1697:Nuclear 1461:Process 1419:Genetic 1365:Optical 1345:Control 1338:outline 1305:Thermal 1295:Railway 1235:Railway 1230:Traffic 1153:Coastal 1112:Outline 1107:History 534:: 1–14. 170:History 130:current 1925:Portal 1722:Survey 1717:Safety 1604:Design 1424:Tissue 1300:Sports 1285:Marine 1275:Energy 1200:Mining 692:  561:  355:Awards 110:charge 1545:Audio 1533:Other 1451:Paper 1370:Power 1215:River 1140:Civil 920:, in 811:, in 793:, in 768:, in 690:S2CID 643:(PDF) 304:Ozone 200:brine 122:redox 96:Scope 55:IUPAC 1640:Fire 1441:Food 559:ISBN 219:and 162:and 128:and 42:and 1850:M–Z 1845:A–L 1592:MEP 1128:and 721:doi 682:doi 655:doi 619:doi 588:doi 551:doi 495:doi 468:doi 1942:: 717:65 715:. 711:. 688:. 678:15 676:. 651:11 649:. 645:. 613:. 609:. 584:82 582:. 557:. 530:. 491:60 489:. 464:91 462:. 260:, 256:, 248:, 81:, 50:. 1088:e 1081:t 1074:v 729:. 723:: 696:. 684:: 661:. 657:: 627:. 621:: 615:2 594:. 590:: 567:. 553:: 532:2 501:. 497:: 474:. 470:: 116:/

Index

chemical engineering
electrochemical
electrosynthesis
electrowinning
flow batteries
fuel cells
corrosion
IUPAC
electricity
amperometric
microfluidic
microelectrodes
solid-state
voltammetry

charge
electrode
electrolyte
redox
potential
current
mass transport
hydrodynamics
reaction yield
fluid flow
kinetics
Fuel cell
flow battery

Michael Faraday

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