200:
24:
333:
The dinitrogen ligand is not reduced by aqueous sodium borohydride. Nearly all known reactions of this compound are displacement reactions. Pentaamine(halogen)ruthenium(II) halides can be synthesized by treating with halide sources:
86:
207:
313:
complex is stable in aqueous solution and has a relatively low ligand exchange rate with water. Being a d complex, the Ru-N bond is stabilized by the
458:
Allen, A. D., Bottomley, F., Harris, R. O., Reinsalu, V. P., Senoff, C. V. "Pentaammine(Nitrogen)Ruthenium(II) Salts and Other
Ammines of Ruthenium"
125:
423:
Fergusson, J. E.; Love, J. L.; Robinson, Ward T. (1972). "Crystal and
Molecular Structure of Dinitrogenpentaammineosmium(II) chloride, Cl
237:. It is a nearly white solid, but its solutions are yellow. The cationic complex is of historic significance as the first compound with N
257:
Pentaamine(nitrogen)ruthenium(II) chloride is synthesized in an aqueous solution from pentaamminechlororuthenium(III) chloride,
346:
100:
622:
214:
612:
519:
Harrison, D. F.; Weissberger, E.; Taube, H. (1968). "Binuclear Ion
Containing Nitrogen as a Bridging Group".
242:
602:
627:
617:
498:
J. Chatt, R. L. Richards, J. F. Fergusson and J. L. Love, "The reduction of nitrogen complexes"
388:
Senoff, Caesar V. (1990). "The
Discovery of : A Case of Serendipity and the Scientific Method".
289:, the cation can be made more conveniently from ruthenium(III) chloride and hydrazine hydrate:
36:
528:
397:
322:
262:
62:
8:
52:
532:
401:
607:
552:
230:
544:
556:
579:
536:
503:
483:
463:
436:
405:
370:
148:
365:
Allen, A. D.; Senoff, C. V. (1965). "Nitrogenopentammineruthenium(II) Complexes".
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191:
467:
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583:
487:
258:
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Except where otherwise noted, data are given for materials in their
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InChI=1S/2ClH.N2.5H3N.Ru/c;;1-2;;;;;;/h2*1H;;5*1H3;/q;;;;;;;;+2/p-2
85:
478:
Taube, H. "Chemistry of
Ruthenium(II) and Osmium(II) Ammines"
75:
23:
518:
422:
570:
Chatt, J. (1970). "Molecular
Nitrogen as a Ligand".
17:Pentaamine(dinitrogen)ruthenium(II) chloride
594:
61:
317:, the donation of metal d-electrons into the N
345:forms the symmetrically bridging symmetrical
252:
40:pentaamminedinitrogenruthenium (II) chloride
364:
227:Pentaamine(nitrogen)ruthenium(II) chloride
454:
452:
450:
595:
387:
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112:Key: VLZPOOHIDLPMKN-UHFFFAOYSA-L
447:
427:, and Related Ruthenium Complexes".
241:bound to a metal center. adopts an
13:
14:
639:
198:
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194:(at 25 °C , 100 kPa).
563:
512:
492:
482:, 1979, volume 51, p. 901–12.
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1:
390:Journal of Chemical Education
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541:10.1126/science.159.3812.320
462:, 2007, volume 12, pp. 2-8.
328:
7:
10:
644:
572:Pure and Applied Chemistry
480:Pure and Applied Chemistry
321:π* orbitals. The related
253:Preparation and properties
176:285.14 g/mol
468:10.1002/9780470132432.ch1
188:
141:
121:
96:
45:
35:
30:
21:
623:Ruthenium(II) compounds
584:10.1351/pac197024020425
488:10.1351/pac197951040901
367:Chemical Communications
613:Coordination complexes
508:10.1039/C19680001522
375:10.1039/C19650000621
323:metal ammine complex
285:If it is to be used
263:methanesulfonic acid
243:octahedral structure
603:Ruthenium complexes
533:1968Sci...159..320H
460:Inorganic Syntheses
441:10.1021/ic50113a042
429:Inorganic Chemistry
402:1990JChEd..67..368S
233:with the formula Cl
18:
628:Nitrogen compounds
347:dinitrogen complex
231:inorganic compound
215:Infobox references
16:
527:(3812): 320–322.
410:10.1021/ed067p368
223:Chemical compound
221:
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87:Interactive image
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618:Ammine complexes
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435:(7): 1662–1666.
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184:colorless solid
149:Chemical formula
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325:is also known.
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578:(2): 425–442.
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315:pi backbonding
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192:standard state
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500:Chem. Commun.
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259:sodium azide
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133:.N#()()()().
46:Identifiers
369:(24): 621.
181:Appearance
142:Properties
597:Categories
396:(5): 368.
353:References
338:+ X → + N
249:symmetry.
172:Molar mass
74:3D model (
63:15392-92-4
53:CAS Number
37:IUPAC name
608:Chlorides
329:Reactions
166:Ru
557:39569679
305:→ + ...
549:5634502
529:Bibcode
521:Science
398:Bibcode
287:in situ
208:what is
206: (
555:
547:
309:This N
261:, and
245:with C
229:is an
126:SMILES
31:Names
553:S2CID
297:+ 4 N
281:+ ...
273:+ NaN
101:InChI
76:JSmol
545:PMID
293:RuCl
277:→ Cl
580:doi
537:doi
525:159
504:doi
484:doi
464:doi
437:doi
406:doi
371:doi
599::
576:24
574:.
551:.
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535:.
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449:^
433:11
431:.
404:.
394:67
392:.
349:.
269:Cl
265::
247:4v
162:Cl
156:15
586:.
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425:2
412:.
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377:.
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340:2
319:2
311:2
303:4
301:H
299:2
295:3
279:2
275:3
271:2
239:2
235:2
204:N
164:2
160:7
158:N
154:H
78:)
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