2556:
233:
178:
3785:
28:
659:
2538:
3749:
671:
2547:
115:
954:
3773:
3761:
395:
444:
800:
256:
InChI=1S/C70/c1-2-22-5-6-24-13-14-26-11-9-23-4-3(21(1)51-52(22)54(24)55(26)53(23)51)33-31(1)61-35-7-8-27-15-16-29-19-20-30-18-17-28-12-10(25(7)56-57(27)59(29)60(30)58(28)56)37(35)63(33)65-36(4)40(9)67(44(17)42(12)65)69-46(11)47(14)70(50(20)49(18)69)68-43(13)39(6)66(45(16)48(19)68)64-34(5)32(2)62(61)38(8)41(15)64
266:
InChI=1/C70/c1-2-22-5-6-24-13-14-26-11-9-23-4-3(21(1)51-52(22)54(24)55(26)53(23)51)33-31(1)61-35-7-8-27-15-16-29-19-20-30-18-17-28-12-10(25(7)56-57(27)59(29)60(30)58(28)56)37(35)63(33)65-36(4)40(9)67(44(17)42(12)65)69-46(11)47(14)70(50(20)49(18)69)68-43(13)39(6)66(45(16)48(19)68)64-34(5)32(2)62(61)38(8)41(15)64
1250:
molecules form an fcc arrangement where the overall symmetry depends on their relative orientations. The low-symmetry monoclinic form is observed when molecular rotation is locked by temperature or strain. Partial rotation along one of the symmetry axes of the molecule results in the higher hexagonal
895:
In 1990, K. Fostiropoulos, W. Krätchmer and D. R. Huffman developed a simple and efficient method of producing fullerenes in gram and even kilogram amounts which boosted fullerene research. In this technique, carbon soot is produced from two high-purity graphite electrodes by
1822:
Haddon, R. C.; Hebard, A. F.; Rosseinsky, M. J.; Murphy, D. W.; Duclos, S. J.; Lyons, K. B.; Miller, B.; Rosamilia, J. M.; Fleming, R. M.; Kortan, A. R.; Glarum, S. H.; Makhija, A. V.; Muller, A. J.; Eick, R. H.; Zahurak, S. M.; Tycko, R.; Dabbagh, G.; Thiel, F. A. (1991). "Conducting films of
949:
molecule (20 hexagons and 12 pentagons), but has a belt of 5 hexagons inserted at the equator. The molecule has eight bond lengths ranging between 0.137 and 0.146 nm. Each carbon atom in the structure is bonded covalently with 3 others.
814:
Theoretical predictions of buckyball molecules appeared in the late 1960s to early 1970s, but they went largely unnoticed. In the early 1970s, the chemistry of unsaturated carbon configurations was studied by a group at the
290:
C12=C3C4=C5C6=C7C8=C9C%10=C%11C%12=C%13C%10=C%10C8=C5C1=C%10C1=C%13C5=C8C1=C2C1=C3C2=C3C%10=C%13C%14=C3C1=C8C1=C3C5=C%12C5=C8C%11=C%11C9=C7C7=C9C6=C4C2=C2C%10=C4C(=C29)C2=C6C(=C8C8=C9C6=C4C%13=C9C(=C%141)C3=C85)C%11=C27
1270:
solid contains voids at 4 octahedral and 12 tetrahedral sites. They are large enough to accommodate impurity atoms. When electron-donating elements, such as alkali metals, are doped into these voids, C
1246:, and face-centered cubic (fcc) polymorphs at room temperature. The fcc phase is more stable at temperatures above 70 °C. The presence of these phases is rationalized as follows. In a solid, C
908:. Fullerenes are extracted from the soot using a multistep procedure. First, the soot is dissolved in appropriate organic solvents. This step yields a solution containing up to 70% of C
945:
and contains 37 faces (25 hexagons and 12 pentagons) with a carbon atom at the vertices of each polygon and a bond along each polygon edge. Its structure is similar to that of C
1774:
Fabiański, Robert; Firlej, Lucyna; Zahab, Ahmed; Kuchta, Bogdan (2002). "Relationships between crystallinity, oxygen diffusion and electrical conductivity of evaporated C
3098:
2868:
2828:
2320:
3029:
3004:
2994:
3400:
2728:
2669:
2577:
3489:
3305:
3240:
3180:
3108:
3014:
2908:
2778:
2733:
2404:
3569:
3034:
2878:
2848:
2964:
2944:
2617:
1718:
Verheijen, M.A.; Meekes, H.; Meijer, G.; Bennema, P.; De Boer, J.L.; Van
Smaalen, S.; Van Tendeloo, G.; Amelinckx, S.; Muto, S.; Van Landuyt, J. (1992).
2989:
408:
1455:
2627:
2329:
2984:
2313:
2654:
1921:
1500:
Thirunavukkuarasu, K.; Long, V. C.; Musfeldt, J. L.; Borondics, F.; Klupp, G.; Kamarás, K.; Kuntscher, C. A. (2011). "Rotational
Dynamics in C
3200:
2597:
2748:
282:
2659:
2306:
480:
3527:
2843:
470:
701:
3059:
2818:
2738:
475:
1607:
Rao, C.N.R.; Seshadri, Ram; Govindaraj, A.; Sen, Rahul (1995). "Fullerenes, nanotubes, onions and related carbon structures".
1890:
1542:
1479:
737:, with a carbon atom at the vertices of each polygon and a bond along each polygon edge. A related fullerene molecule, named
3440:
403:
3692:
1914:
518:
3592:
247:
415:
3717:
1688:
819:, led by Harry Kroto and David Walton. In the 1980s a technique was developed by Richard Smalley and Bob Curl at
2244:
2239:
896:
igniting an arc discharge between them in an inert atmosphere (helium gas). Alternatively, soot is produced by
592:
1564:
3642:
1907:
612:
460:
3677:
1266:
where conductivity is attributed to oxygen diffusion into the solid from atmosphere. The unit cell of fcc C
552:
485:
173:
2873:
694:
211:
1251:
or rhombohedral symmetries, which turn into a cubic structure when the molecules start freely rotating.
2287:
1463:
3632:
3627:
2808:
1337:
567:
465:
228:
3672:
2053:
1371:
872:
769:
645:
597:
3752:
1243:
875:. The discovery of buckyballs was serendipitous, as the scientists were aiming to produce carbon
587:
1719:
3607:
2572:
2482:
2359:
2354:
2113:
687:
1878:
1532:
155:
3662:
3637:
3275:
2893:
2440:
1940:
602:
91:
3723:
3707:
3332:
2703:
2674:
2555:
2379:
1991:
1930:
1840:
1787:
1738:
1660:
1406:
1091:
905:
816:
738:
640:
562:
523:
503:
40:
8:
3810:
3667:
3647:
3460:
3150:
2638:
2502:
2477:
2445:
2364:
1041:
880:
607:
572:
513:
232:
177:
81:
1844:
1791:
1742:
1664:
135:
3765:
3687:
3657:
3602:
3479:
3455:
2954:
2888:
2753:
2713:
2564:
2527:
2487:
2466:
2409:
2384:
2028:
2010:
1856:
938:
773:
729:
atoms. It is a cage-like fused-ring structure which resembles a rugby ball, made of 25
542:
1799:
1620:
3712:
3295:
3195:
3165:
3083:
2823:
2708:
2664:
2612:
2419:
2414:
2346:
1886:
1750:
1686:
Talyzin, A.V.; Engström, I. (1998). "C70 in
Benzene, Hexane, and Toluene Solutions".
1538:
1475:
884:
675:
582:
199:
2298:
1672:
1649:
Bezmel'nitsyn, V.N.; Eletskii, A.V.; Okun', M.V. (1998). "Fullerenes in solutions".
1633:
3789:
3777:
3697:
3597:
3502:
3450:
2883:
2758:
2723:
2644:
2632:
2592:
2497:
2430:
2267:
2197:
2103:
1860:
1848:
1795:
1754:
1746:
1697:
1668:
1616:
1513:
1467:
1215:
1051:
876:
363:
305:
827:
of a suitable target to produce clusters of atoms. Kroto realized that by using a
772:
for their roles in the discovery of cage-like fullerenes. The name is a homage to
3385:
3360:
2898:
2838:
2622:
2522:
2507:
2492:
2399:
2389:
2152:
2108:
2074:
2016:
1651:
1460:
Nomenclature of
Organic Chemistry: IUPAC Recommendations and Preferred Names 2013
1454:
1195:
820:
765:
761:
451:
887:
analysis of the product indicated the formation of spheroidal carbon molecules.
3622:
3587:
3370:
3260:
3225:
3210:
3145:
3140:
3039:
2939:
2858:
2833:
2798:
2743:
2718:
2587:
2435:
2249:
2058:
2022:
1275:
917:
897:
838:
was discovered in 1985 by Robert Curl, Harold Kroto and
Richard Smalley. Using
777:
753:
663:
577:
386:
1639:. University of Bristol. Chm.bris.ac.uk (1996-10-13). Retrieved on 2011-12-25.
3804:
3652:
3507:
3390:
3365:
3290:
3170:
3128:
3123:
2863:
2853:
2813:
2688:
2582:
2537:
2512:
2394:
2374:
2282:
2136:
2035:
1263:
630:
621:
557:
435:
352:
166:
3728:
3582:
3435:
3375:
3355:
3327:
3255:
3135:
3118:
3073:
3024:
2929:
2649:
2602:
2450:
2272:
824:
749:
533:
1471:
3702:
3612:
3577:
3544:
3470:
3445:
3285:
3190:
3160:
3044:
2959:
2949:
2679:
2607:
2234:
2213:
1956:
1294:
1175:
1115:
842:
805:
757:
547:
27:
3617:
3559:
3522:
3497:
3395:
3205:
3068:
1899:
1239:
1185:
321:
146:
1759:
1701:
1517:
1499:
658:
3549:
3414:
3250:
3054:
2934:
2788:
2763:
2168:
1986:
1852:
990:
986:
901:
789:
722:
494:
385:
Except where otherwise noted, data are given for materials in their
3517:
3429:
3230:
3093:
3078:
3049:
2918:
2693:
2517:
2461:
2455:
2424:
2369:
2337:
2277:
2118:
1981:
1975:
1155:
916:, as well as other fullerenes. These fractions are separated using
846:
828:
734:
635:
374:
1648:
670:
114:
3682:
3512:
3465:
3424:
3380:
3322:
3317:
3280:
3270:
3265:
3220:
3215:
3155:
3088:
2979:
2974:
2924:
2803:
2793:
2546:
2229:
1950:
1259:
1211:
1207:
1165:
1125:
1081:
1071:
989:
is irreversible. The first reduction requires around 1.0 V (
730:
342:
186:
1274:
converts into a conductor with conductivity up to around 2
953:
3733:
3554:
3536:
2999:
2969:
2471:
1145:
1135:
1105:
1061:
726:
961:
molecule. Red atoms indicate five hexagons additional to the C
2768:
2698:
839:
126:
104:
1821:
1717:
216:
443:
1773:
1504:: Temperature- and Pressure-Dependent Infrared Studies".
799:
1606:
973:
can undergo six reversible, one-electron reductions to
2328:
823:, Texas to isolate these substances. They used laser
1883:
Nanostructured materials for solar energy conversion
1627:
1222:
are a reddish brown. Millimeter-sized crystals of C
863: > 20) of which the most common were C
1206:Fullerenes are sparingly soluble in many aromatic
1456:International Union of Pure and Applied Chemistry
3802:
768:. Kroto, Curl and Smalley were awarded the 1996
198:
1879:"Fullerene Thin Films as Photovoltaic Material"
1685:
748:It was first intentionally prepared in 1985 by
90:
2314:
1915:
695:
1720:"The structure of different phases of pure C
1876:
879:to replicate and characterize unidentified
871:. For this discovery they were awarded the
2321:
2307:
1922:
1908:
1530:
702:
688:
231:
176:
154:
1758:
1929:
1567:. Nobel Prize Foundation. 9 October 1996
1534:Perspectives of fullerene nanotechnology
952:
745:fullerene) consists of 60 carbon atoms.
227:
3803:
1575:
1573:
167:
2302:
1903:
1713:
1711:
259:Key: ATLMFJTZZPOKLC-UHFFFAOYSA-N
134:
1609:Materials Science and Engineering: R
1495:
1493:
1491:
1582:
1570:
1506:The Journal of Physical Chemistry C
269:Key: ATLMFJTZZPOKLC-UHFFFAOYAA
189:
13:
3693:Nexus for Exoplanet System Science
1815:
1767:
1708:
1218:, but not in water. Solutions of C
14:
3822:
3593:Atomic and molecular astrophysics
2330:Molecules detected in outer space
1600:
1488:
1262:of 1.77 eV; they are n-type
3783:
3771:
3759:
3748:
3747:
2554:
2545:
2536:
798:
669:
657:
442:
393:
26:
3718:Polycyclic aromatic hydrocarbon
1957:Lonsdaleite (hexagonal diamond)
1870:
1806:
1689:Journal of Physical Chemistry B
1679:
1673:10.1070/PU1998v041n11ABEH000502
1642:
430:Part of a series of articles on
389:(at 25 °C , 100 kPa).
1885:. Elsevier. pp. 361–443.
1591:
1558:
1524:
1464:The Royal Society of Chemistry
1448:
1258:form brownish crystals with a
311:
1:
3643:Extraterrestrial liquid water
1800:10.1016/S1293-2558(02)01358-4
1621:10.1016/S0927-796X(95)00181-6
1442:
923:
873:1996 Nobel Prize in Chemistry
1751:10.1016/0301-0104(92)87026-6
1226:can be grown from solution.
890:
7:
2874:Protonated hydrogen cyanide
1537:. Springer. pp. 275–.
1011:
928:
10:
3827:
2288:Aggregated diamond nanorod
787:
783:
780:these molecules resemble.
725:molecule consisting of 70
337:Dark needle-like crystals
3742:
3633:Earliest known life forms
3628:Diffuse interstellar band
3568:
3488:
3413:
3304:
3239:
3179:
3107:
3099:Protonated cyanoacetylene
3013:
2907:
2869:Protonated carbon dioxide
2829:Hydromagnesium isocyanide
2777:
2563:
2534:
2345:
2336:
2258:
2188:
2127:
2094:
2086:(cyclo[18]carbon)
2044:
1965:
1937:
1881:. In SĹŤga, Tetsuo (ed.).
1831:by alkali-metal doping".
1017:Saturated solubility of C
1008:is an electron acceptor.
383:
298:
278:
243:
74:
62:
39:
34:
25:
3678:Iron–sulfur world theory
3673:Photodissociation region
3376:Methyl-cyano-diacetylene
2070:(cyclo[6]carbon)
2054:Linear acetylenic carbon
1229:
770:Nobel Prize in Chemistry
646:Nanocrystalline material
622:Nanostructured materials
3753:Category:Astrochemistry
3343:, fullerene, buckyball)
3030:Cyanobutadiynyl radical
3005:Silicon-carbide cluster
2995:Protonated formaldehyde
1634:Buckminsterfullerene, C
3766:Outer space portal
3608:Circumstellar envelope
2573:Aluminium(I) hydroxide
2483:Phosphorus mononitride
2360:Aluminium monofluoride
2355:Aluminium monochloride
2114:Carbide-derived carbon
1996:(buckminsterfullerene)
966:
357:sublimates at ~850 °C
3663:Interplanetary medium
3638:Extraterrestrial life
3276:Octatetraynyl radical
2894:Tricarbon monosulfide
2441:Magnesium monohydride
1472:10.1039/9781849733069
956:
906:aromatic hydrocarbons
676:Technology portal
471:Mechanical properties
3790:Chemistry portal
3778:Astronomy portal
3724:RNA world hypothesis
3708:PAH world hypothesis
3401:Heptatrienyl radical
3333:Buckminsterfullerene
3221:Methylcyanoacetylene
2729:Silicon carbonitride
2704:Methylidynephosphane
2670:Magnesium isocyanide
2578:Aluminium isocyanide
2380:Carbon monophosphide
1931:Allotropes of carbon
1877:Katz, E. A. (2006).
1780:Solid State Sciences
1092:carbon tetrachloride
1004:), indicating that C
817:University of Sussex
739:buckminsterfullerene
641:Nanoporous materials
504:Buckminsterfullerene
41:Preferred IUPAC name
3668:Interstellar medium
3648:Forbidden mechanism
3461:Hydrogen isocyanide
3151:Hexatriynyl radical
2734:c-Silicon dicarbide
2639:Hydrogen isocyanide
2503:Silicon monosulfide
2478:Phosphorus monoxide
2446:Methylidyne radical
2405:Fluoromethylidynium
2365:Aluminium(II) oxide
1845:1991Natur.350..320H
1792:2002SSSci...4.1009F
1743:1992CP....166..287V
1665:1998PhyU...41.1091B
1531:Eiji ĹŚsawa (2002).
1287:
1042:1,2-dichlorobenzene
1026:
881:interstellar matter
855:clusters (for even
543:Carbon quantum dots
369:insoluble in water
364:Solubility in water
329: g·mol
22:
3688:Molecules in stars
3658:Intergalactic dust
3603:Circumstellar dust
3545:Naphthalene cation
3480:Trihydrogen cation
3456:Hydrogen deuteride
3381:Methyltriacetylene
3216:Hexapentaenylidene
3035:E-Cyanomethanimine
2955:Cyclopropenylidene
2889:Tricarbon monoxide
2879:Silicon tricarbide
2849:Methylene amidogen
2839:Isothiocyanic acid
2754:Thioxoethenylidene
2714:Trihydrogen cation
2528:Titanium(II) oxide
2488:Potassium chloride
2467:Sulfur mononitride
2410:Helium hydride ion
2385:Carbon monosulfide
2209:(cyclopropatriene)
2190:hypothetical forms
2011:Fullerene whiskers
1281:
1016:
967:
957:The structure of C
774:Buckminster Fuller
664:Science portal
476:Optical properties
416:Infobox references
16:
3798:
3797:
3713:Pseudo-panspermia
3409:
3408:
3356:Cyanodecapentayne
3296:N-Methylformamide
3271:Methyldiacetylene
3196:Aminoacetonitrile
3166:Methyl isocyanate
3084:Methyl isocyanide
2965:Isocyanoacetylene
2945:Cyanoformaldehyde
2824:Hydrogen peroxide
2709:Potassium cyanide
2665:Magnesium cyanide
2618:Disilicon carbide
2613:Dicarbon monoxide
2420:Hydrogen fluoride
2415:Hydrogen chloride
2296:
2295:
2164:(diatomic carbon)
2096:mixed sp/sp forms
1892:978-0-444-52844-5
1839:(6316): 320–322.
1702:10.1021/jp9815255
1544:978-0-7923-7174-8
1518:10.1021/jp200036t
1481:978-0-85404-182-4
1440:
1439:
1204:
1203:
885:Mass spectrometry
712:
711:
524:Carbon allotropes
424:Chemical compound
422:
421:
212:CompTox Dashboard
116:Interactive image
3818:
3788:
3787:
3786:
3776:
3775:
3774:
3764:
3763:
3762:
3751:
3750:
3698:Organic compound
3598:Chemical formula
3503:Dihydroxyacetone
3451:Hydrogen cyanide
3136:Cyanodiacetylene
2990:Propadienylidene
2884:Thioformaldehyde
2759:Titanium dioxide
2724:Sodium hydroxide
2645:Hydrogen sulfide
2633:Hydrogen cyanide
2593:Carbonyl sulfide
2558:
2549:
2540:
2498:Silicon monoxide
2431:Hydroxyl radical
2343:
2342:
2323:
2316:
2309:
2300:
2299:
2268:Activated carbon
2224:
2223:
2222:
2208:
2207:
2206:
2179:
2178:
2177:
2163:
2162:
2161:
2147:
2146:
2145:
2104:Amorphous carbon
2085:
2084:
2083:
2069:
2068:
2067:
1924:
1917:
1910:
1901:
1900:
1896:
1865:
1864:
1853:10.1038/350320a0
1819:
1813:
1810:
1804:
1803:
1786:(8): 1009–1015.
1771:
1765:
1764:
1762:
1737:(1–2): 287–297.
1731:Chemical Physics
1728:
1715:
1706:
1705:
1683:
1677:
1676:
1646:
1640:
1631:
1625:
1624:
1604:
1598:
1595:
1589:
1586:
1580:
1577:
1568:
1562:
1556:
1555:
1553:
1551:
1528:
1522:
1521:
1512:(9): 3646–3653.
1497:
1486:
1485:
1452:
1414:
1288:
1280:
1238:crystallizes in
1216:carbon disulfide
1214:and others like
1052:carbon disulfide
1027:
1015:
1003:
1002:
1001:
984:
983:
982:
802:
756:, Sean O'Brien,
704:
697:
690:
674:
673:
662:
661:
613:Titanium dioxide
452:Carbon nanotubes
446:
427:
426:
406:
400:
397:
396:
328:
313:
306:Chemical formula
236:
235:
220:
218:
202:
191:
180:
169:
158:
138:
118:
94:
30:
23:
15:
3826:
3825:
3821:
3820:
3819:
3817:
3816:
3815:
3801:
3800:
3799:
3794:
3784:
3782:
3772:
3770:
3760:
3758:
3738:
3564:
3540:
3531:
3484:
3474:
3417:
3405:
3386:Propionaldehyde
3361:Ethylene glycol
3350:
3342:
3338:
3309:
3307:
3300:
3256:Cyanohexatriyne
3242:
3235:
3182:
3175:
3110:
3103:
3063:
3016:
3009:
2980:Methoxy radical
2910:
2903:
2899:Thiocyanic acid
2780:
2773:
2683:
2623:Ethynyl radical
2559:
2553:
2552:
2551:
2550:
2544:
2543:
2542:
2541:
2532:
2523:Sulfur monoxide
2508:Sodium chloride
2493:Silicon carbide
2400:Diatomic carbon
2390:Carbon monoxide
2332:
2327:
2297:
2292:
2254:
2245:Metallic carbon
2221:
2218:
2217:
2216:
2214:
2205:
2202:
2201:
2200:
2198:
2184:
2176:
2173:
2172:
2171:
2169:
2160:
2157:
2156:
2155:
2153:
2148:(atomic carbon)
2144:
2141:
2140:
2139:
2137:
2123:
2109:Carbon nanofoam
2090:
2082:
2079:
2078:
2077:
2075:
2066:
2063:
2062:
2061:
2059:
2040:
2005:
1995:
1961:
1951:Diamond (cubic)
1933:
1928:
1893:
1873:
1868:
1830:
1826:
1820:
1816:
1811:
1807:
1777:
1772:
1768:
1726:
1723:
1716:
1709:
1684:
1680:
1652:Physics-Uspekhi
1647:
1643:
1637:
1632:
1628:
1605:
1601:
1596:
1592:
1587:
1583:
1578:
1571:
1563:
1559:
1549:
1547:
1545:
1529:
1525:
1503:
1498:
1489:
1482:
1466:. p. 325.
1453:
1449:
1445:
1412:
1379:
1345:
1331:
1303:
1285:
1273:
1269:
1257:
1254:All phases of C
1249:
1237:
1232:
1225:
1221:
1196:dichloromethane
1020:
1014:
1007:
1000:
998:
997:
996:
994:
981:
978:
977:
976:
974:
972:
964:
960:
948:
942:
937:molecule has a
936:
931:
926:
915:
911:
900:of graphite or
893:
870:
866:
854:
837:
821:Rice University
812:
811:
810:
809:
808:
803:
792:
786:
766:Rice University
762:Richard Smalley
744:
718:
708:
668:
656:
553:Aluminium oxide
425:
418:
413:
412:
411: ?)
402:
398:
394:
390:
366:
326:
316:
308:
294:
291:
286:
285:
274:
271:
270:
267:
261:
260:
257:
251:
250:
239:
221:
214:
205:
192:
161:
141:
121:
108:
97:
84:
70:
68:
58:
57:
55:
48:
20:
12:
11:
5:
3824:
3814:
3813:
3796:
3795:
3793:
3792:
3780:
3768:
3756:
3743:
3740:
3739:
3737:
3736:
3731:
3726:
3721:
3715:
3710:
3705:
3700:
3695:
3690:
3685:
3680:
3675:
3670:
3665:
3660:
3655:
3650:
3645:
3640:
3635:
3630:
3625:
3623:Cosmochemistry
3620:
3615:
3610:
3605:
3600:
3595:
3590:
3588:Astrochemistry
3585:
3580:
3574:
3572:
3566:
3565:
3563:
3562:
3557:
3552:
3547:
3542:
3538:
3534:
3529:
3525:
3520:
3515:
3510:
3505:
3500:
3494:
3492:
3486:
3485:
3483:
3482:
3477:
3472:
3468:
3463:
3458:
3453:
3448:
3443:
3441:Formyl radical
3438:
3433:
3427:
3421:
3419:
3411:
3410:
3407:
3406:
3404:
3403:
3398:
3393:
3388:
3383:
3378:
3373:
3371:Methyl acetate
3368:
3363:
3358:
3353:
3348:
3344:
3340:
3336:
3330:
3325:
3320:
3314:
3312:
3302:
3301:
3299:
3298:
3293:
3288:
3283:
3278:
3273:
3268:
3263:
3261:Dimethyl ether
3258:
3253:
3247:
3245:
3237:
3236:
3234:
3233:
3228:
3226:Methyl formate
3223:
3218:
3213:
3211:Glycolaldehyde
3208:
3203:
3198:
3193:
3187:
3185:
3177:
3176:
3174:
3173:
3168:
3163:
3158:
3153:
3148:
3146:Glycolonitrile
3143:
3141:Ethylene oxide
3138:
3133:
3132:
3131:
3121:
3115:
3113:
3105:
3104:
3102:
3101:
3096:
3091:
3086:
3081:
3076:
3071:
3066:
3061:
3057:
3052:
3047:
3042:
3040:Cyclopropenone
3037:
3032:
3027:
3021:
3019:
3011:
3010:
3008:
3007:
3002:
2997:
2992:
2987:
2982:
2977:
2972:
2967:
2962:
2957:
2952:
2947:
2942:
2940:Cyanoacetylene
2937:
2932:
2927:
2922:
2915:
2913:
2905:
2904:
2902:
2901:
2896:
2891:
2886:
2881:
2876:
2871:
2866:
2861:
2859:Methyl radical
2856:
2851:
2846:
2841:
2836:
2834:Isocyanic acid
2831:
2826:
2821:
2816:
2811:
2806:
2801:
2799:Isocyanic acid
2796:
2791:
2785:
2783:
2775:
2774:
2772:
2771:
2766:
2761:
2756:
2751:
2746:
2744:Sulfur dioxide
2741:
2736:
2731:
2726:
2721:
2719:Sodium cyanide
2716:
2711:
2706:
2701:
2696:
2691:
2686:
2681:
2677:
2672:
2667:
2662:
2657:
2652:
2647:
2642:
2636:
2630:
2628:Formyl radical
2625:
2620:
2615:
2610:
2605:
2600:
2595:
2590:
2588:Carbon dioxide
2585:
2580:
2575:
2569:
2567:
2561:
2560:
2535:
2533:
2531:
2530:
2525:
2520:
2515:
2510:
2505:
2500:
2495:
2490:
2485:
2480:
2475:
2469:
2464:
2459:
2453:
2448:
2443:
2438:
2436:Iron(II) oxide
2433:
2428:
2422:
2417:
2412:
2407:
2402:
2397:
2392:
2387:
2382:
2377:
2372:
2367:
2362:
2357:
2351:
2349:
2340:
2334:
2333:
2326:
2325:
2318:
2311:
2303:
2294:
2293:
2291:
2290:
2285:
2280:
2275:
2270:
2264:
2262:
2256:
2255:
2253:
2252:
2250:Penta-graphene
2247:
2242:
2237:
2232:
2227:
2219:
2211:
2203:
2194:
2192:
2186:
2185:
2183:
2182:
2174:
2166:
2158:
2150:
2142:
2133:
2131:
2125:
2124:
2122:
2121:
2116:
2111:
2106:
2100:
2098:
2092:
2091:
2089:
2088:
2080:
2072:
2064:
2056:
2050:
2048:
2042:
2041:
2039:
2038:
2033:
2003:
1993:
1984:
1979:
1971:
1969:
1963:
1962:
1960:
1959:
1954:
1946:
1944:
1935:
1934:
1927:
1926:
1919:
1912:
1904:
1898:
1897:
1891:
1872:
1869:
1867:
1866:
1828:
1824:
1814:
1805:
1775:
1766:
1721:
1707:
1678:
1641:
1635:
1626:
1615:(6): 209–262.
1599:
1590:
1581:
1569:
1557:
1543:
1523:
1501:
1487:
1480:
1446:
1444:
1441:
1438:
1437:
1434:
1431:
1428:
1425:
1422:
1419:
1416:
1409:
1403:
1402:
1399:
1396:
1393:
1390:
1387:
1384:
1381:
1377:
1374:
1368:
1367:
1365:
1362:
1359:
1356:
1353:
1350:
1347:
1343:
1340:
1334:
1333:
1328:
1323:
1317:
1311:
1305:
1300:
1297:
1292:
1283:
1271:
1267:
1264:semiconductors
1255:
1247:
1235:
1231:
1228:
1223:
1219:
1202:
1201:
1198:
1192:
1191:
1188:
1182:
1181:
1178:
1172:
1171:
1168:
1162:
1161:
1158:
1152:
1151:
1148:
1142:
1141:
1138:
1132:
1131:
1128:
1122:
1121:
1118:
1112:
1111:
1108:
1098:
1097:
1094:
1088:
1087:
1084:
1078:
1077:
1074:
1068:
1067:
1064:
1058:
1057:
1054:
1048:
1047:
1044:
1038:
1037:
1031:
1018:
1013:
1010:
1005:
999:
979:
970:
962:
958:
946:
940:
934:
930:
927:
925:
922:
918:chromatography
913:
909:
898:laser ablation
892:
889:
868:
864:
850:
835:
804:
797:
796:
795:
794:
793:
788:Main article:
785:
782:
778:geodesic domes
754:James R. Heath
742:
716:
710:
709:
707:
706:
699:
692:
684:
681:
680:
679:
678:
666:
651:
650:
649:
648:
643:
638:
633:
625:
624:
618:
617:
616:
615:
610:
605:
600:
595:
590:
585:
580:
575:
570:
565:
560:
555:
550:
545:
537:
536:
529:
528:
527:
526:
521:
516:
511:
506:
498:
497:
491:
490:
489:
488:
483:
478:
473:
468:
463:
455:
454:
448:
447:
439:
438:
432:
431:
423:
420:
419:
414:
392:
391:
387:standard state
384:
381:
380:
377:
371:
370:
367:
362:
359:
358:
355:
349:
348:
345:
339:
338:
335:
331:
330:
324:
318:
317:
314:
309:
304:
301:
300:
296:
295:
293:
292:
289:
281:
280:
279:
276:
275:
273:
272:
268:
265:
264:
262:
258:
255:
254:
246:
245:
244:
241:
240:
238:
237:
229:DTXSID90151050
224:
222:
210:
207:
206:
204:
203:
195:
193:
185:
182:
181:
171:
163:
162:
160:
159:
151:
149:
143:
142:
140:
139:
131:
129:
123:
122:
120:
119:
111:
109:
102:
99:
98:
96:
95:
87:
85:
80:
77:
76:
72:
71:
69:, rugbyballene
66:
64:
60:
59:
53:
46:
44:
43:
37:
36:
32:
31:
18:
9:
6:
4:
3:
2:
3823:
3812:
3809:
3808:
3806:
3791:
3781:
3779:
3769:
3767:
3757:
3755:
3754:
3745:
3744:
3741:
3735:
3732:
3730:
3727:
3725:
3722:
3719:
3716:
3714:
3711:
3709:
3706:
3704:
3701:
3699:
3696:
3694:
3691:
3689:
3686:
3684:
3681:
3679:
3676:
3674:
3671:
3669:
3666:
3664:
3661:
3659:
3656:
3654:
3653:Homochirality
3651:
3649:
3646:
3644:
3641:
3639:
3636:
3634:
3631:
3629:
3626:
3624:
3621:
3619:
3616:
3614:
3611:
3609:
3606:
3604:
3601:
3599:
3596:
3594:
3591:
3589:
3586:
3584:
3581:
3579:
3576:
3575:
3573:
3571:
3567:
3561:
3558:
3556:
3553:
3551:
3548:
3546:
3543:
3541:
3535:
3533:
3526:
3524:
3521:
3519:
3516:
3514:
3511:
3509:
3508:Methoxyethane
3506:
3504:
3501:
3499:
3496:
3495:
3493:
3491:
3487:
3481:
3478:
3476:
3469:
3467:
3464:
3462:
3459:
3457:
3454:
3452:
3449:
3447:
3444:
3442:
3439:
3437:
3434:
3431:
3428:
3426:
3423:
3422:
3420:
3416:
3412:
3402:
3399:
3397:
3394:
3392:
3391:Butyronitrile
3389:
3387:
3384:
3382:
3379:
3377:
3374:
3372:
3369:
3367:
3366:Ethyl formate
3364:
3362:
3359:
3357:
3354:
3352:
3345:
3334:
3331:
3329:
3326:
3324:
3321:
3319:
3316:
3315:
3313:
3311:
3303:
3297:
3294:
3292:
3291:Propionitrile
3289:
3287:
3284:
3282:
3279:
3277:
3274:
3272:
3269:
3267:
3264:
3262:
3259:
3257:
3254:
3252:
3249:
3248:
3246:
3244:
3238:
3232:
3229:
3227:
3224:
3222:
3219:
3217:
3214:
3212:
3209:
3207:
3204:
3202:
3199:
3197:
3194:
3192:
3189:
3188:
3186:
3184:
3178:
3172:
3171:Vinyl alcohol
3169:
3167:
3164:
3162:
3159:
3157:
3154:
3152:
3149:
3147:
3144:
3142:
3139:
3137:
3134:
3130:
3129:Vinyl cyanide
3127:
3126:
3125:
3124:Acrylonitrile
3122:
3120:
3117:
3116:
3114:
3112:
3106:
3100:
3097:
3095:
3092:
3090:
3089:Pentynylidyne
3087:
3085:
3082:
3080:
3077:
3075:
3072:
3070:
3067:
3065:
3058:
3056:
3053:
3051:
3048:
3046:
3043:
3041:
3038:
3036:
3033:
3031:
3028:
3026:
3023:
3022:
3020:
3018:
3012:
3006:
3003:
3001:
2998:
2996:
2993:
2991:
2988:
2986:
2985:Methylenimine
2983:
2981:
2978:
2976:
2973:
2971:
2968:
2966:
2963:
2961:
2958:
2956:
2953:
2951:
2948:
2946:
2943:
2941:
2938:
2936:
2933:
2931:
2928:
2926:
2923:
2920:
2917:
2916:
2914:
2912:
2906:
2900:
2897:
2895:
2892:
2890:
2887:
2885:
2882:
2880:
2877:
2875:
2872:
2870:
2867:
2865:
2864:Propynylidyne
2862:
2860:
2857:
2855:
2854:Methyl cation
2852:
2850:
2847:
2845:
2842:
2840:
2837:
2835:
2832:
2830:
2827:
2825:
2822:
2820:
2817:
2815:
2814:Fulminic acid
2812:
2810:
2807:
2805:
2802:
2800:
2797:
2795:
2792:
2790:
2787:
2786:
2784:
2782:
2776:
2770:
2767:
2765:
2762:
2760:
2757:
2755:
2752:
2750:
2747:
2745:
2742:
2740:
2737:
2735:
2732:
2730:
2727:
2725:
2722:
2720:
2717:
2715:
2712:
2710:
2707:
2705:
2702:
2700:
2697:
2695:
2692:
2690:
2689:Nitrous oxide
2687:
2685:
2678:
2676:
2673:
2671:
2668:
2666:
2663:
2661:
2658:
2656:
2653:
2651:
2648:
2646:
2643:
2640:
2637:
2634:
2631:
2629:
2626:
2624:
2621:
2619:
2616:
2614:
2611:
2609:
2606:
2604:
2601:
2599:
2596:
2594:
2591:
2589:
2586:
2584:
2583:Amino radical
2581:
2579:
2576:
2574:
2571:
2570:
2568:
2566:
2562:
2557:
2548:
2539:
2529:
2526:
2524:
2521:
2519:
2516:
2514:
2513:Sodium iodide
2511:
2509:
2506:
2504:
2501:
2499:
2496:
2494:
2491:
2489:
2486:
2484:
2481:
2479:
2476:
2473:
2470:
2468:
2465:
2463:
2460:
2457:
2454:
2452:
2449:
2447:
2444:
2442:
2439:
2437:
2434:
2432:
2429:
2426:
2423:
2421:
2418:
2416:
2413:
2411:
2408:
2406:
2403:
2401:
2398:
2396:
2395:Cyano radical
2393:
2391:
2388:
2386:
2383:
2381:
2378:
2376:
2375:Carbon cation
2373:
2371:
2368:
2366:
2363:
2361:
2358:
2356:
2353:
2352:
2350:
2348:
2344:
2341:
2339:
2335:
2331:
2324:
2319:
2317:
2312:
2310:
2305:
2304:
2301:
2289:
2286:
2284:
2281:
2279:
2276:
2274:
2271:
2269:
2266:
2265:
2263:
2261:
2257:
2251:
2248:
2246:
2243:
2241:
2238:
2236:
2233:
2231:
2228:
2226:
2225:(prismane C8)
2212:
2210:
2196:
2195:
2193:
2191:
2187:
2181:
2167:
2165:
2151:
2149:
2135:
2134:
2132:
2130:
2126:
2120:
2117:
2115:
2112:
2110:
2107:
2105:
2102:
2101:
2099:
2097:
2093:
2087:
2073:
2071:
2057:
2055:
2052:
2051:
2049:
2047:
2043:
2037:
2036:Glassy carbon
2034:
2031:
2030:
2025:
2024:
2019:
2018:
2013:
2012:
2007:
2006:
1998:
1997:
1988:
1985:
1983:
1980:
1978:
1977:
1973:
1972:
1970:
1968:
1964:
1958:
1955:
1953:
1952:
1948:
1947:
1945:
1943:
1942:
1936:
1932:
1925:
1920:
1918:
1913:
1911:
1906:
1905:
1902:
1894:
1888:
1884:
1880:
1875:
1874:
1862:
1858:
1854:
1850:
1846:
1842:
1838:
1834:
1818:
1809:
1801:
1797:
1793:
1789:
1785:
1781:
1778:thin films".
1770:
1761:
1756:
1752:
1748:
1744:
1740:
1736:
1732:
1725:
1714:
1712:
1703:
1699:
1695:
1691:
1690:
1682:
1674:
1670:
1666:
1662:
1658:
1654:
1653:
1645:
1638:
1630:
1622:
1618:
1614:
1610:
1603:
1597:Katz, 369–370
1594:
1585:
1576:
1574:
1566:
1565:Press Release
1561:
1546:
1540:
1536:
1535:
1527:
1519:
1515:
1511:
1507:
1496:
1494:
1492:
1483:
1477:
1473:
1469:
1465:
1461:
1457:
1451:
1447:
1435:
1432:
1429:
1426:
1423:
1420:
1417:
1410:
1408:
1405:
1404:
1400:
1397:
1394:
1391:
1388:
1385:
1382:
1375:
1373:
1370:
1369:
1366:
1363:
1360:
1357:
1354:
1351:
1348:
1341:
1339:
1336:
1335:
1329:
1327:
1324:
1321:
1318:
1315:
1312:
1309:
1306:
1301:
1298:
1296:
1293:
1290:
1289:
1286:solid phases
1282:Some of the C
1279:
1277:
1265:
1261:
1252:
1245:
1242:, hexagonal,
1241:
1227:
1217:
1213:
1209:
1199:
1197:
1194:
1193:
1189:
1187:
1184:
1183:
1179:
1177:
1174:
1173:
1169:
1167:
1164:
1163:
1159:
1157:
1154:
1153:
1149:
1147:
1144:
1143:
1139:
1137:
1134:
1133:
1129:
1127:
1124:
1123:
1119:
1117:
1114:
1113:
1109:
1107:
1103:
1100:
1099:
1095:
1093:
1090:
1089:
1085:
1083:
1080:
1079:
1075:
1073:
1070:
1069:
1065:
1063:
1060:
1059:
1055:
1053:
1050:
1049:
1045:
1043:
1040:
1039:
1035:
1032:
1029:
1028:
1024:
1009:
992:
988:
955:
951:
944:
921:
919:
907:
903:
899:
888:
886:
882:
878:
874:
862:
858:
853:
848:
844:
841:
832:
830:
826:
822:
818:
807:
801:
791:
781:
779:
775:
771:
767:
763:
759:
755:
751:
746:
740:
736:
732:
728:
724:
720:
705:
700:
698:
693:
691:
686:
685:
683:
682:
677:
672:
667:
665:
660:
655:
654:
653:
652:
647:
644:
642:
639:
637:
634:
632:
631:Nanocomposite
629:
628:
627:
626:
623:
620:
619:
614:
611:
609:
606:
604:
601:
599:
596:
594:
593:Iron–platinum
591:
589:
586:
584:
581:
579:
576:
574:
571:
569:
566:
564:
561:
559:
556:
554:
551:
549:
546:
544:
541:
540:
539:
538:
535:
534:nanoparticles
531:
530:
525:
522:
520:
519:Health impact
517:
515:
512:
510:
509:C70 fullerene
507:
505:
502:
501:
500:
499:
496:
493:
492:
487:
484:
482:
479:
477:
474:
472:
469:
467:
464:
462:
459:
458:
457:
456:
453:
450:
449:
445:
441:
440:
437:
436:Nanomaterials
434:
433:
429:
428:
417:
410:
405:
388:
382:
378:
376:
373:
372:
368:
365:
361:
360:
356:
354:
353:Melting point
351:
350:
346:
344:
341:
340:
336:
333:
332:
325:
323:
320:
319:
310:
307:
303:
302:
297:
288:
287:
284:
277:
263:
253:
252:
249:
242:
234:
230:
226:
225:
223:
213:
209:
208:
201:
197:
196:
194:
188:
184:
183:
179:
175:
172:
170:
168:ECHA InfoCard
165:
164:
157:
153:
152:
150:
148:
145:
144:
137:
133:
132:
130:
128:
125:
124:
117:
113:
112:
110:
106:
101:
100:
93:
89:
88:
86:
83:
79:
78:
73:
61:
52:
42:
38:
33:
29:
24:
3746:
3729:Spectroscopy
3583:Astrobiology
3436:Formaldehyde
3346:
3328:Benzonitrile
3119:Acetaldehyde
3074:Methanethiol
3025:Acetonitrile
2930:Carbodiimide
2809:Formaldehyde
2804:Cyanoethynyl
2655:Iron cyanide
2650:Hydroperoxyl
2451:Nitric oxide
2283:Carbon fiber
2273:Carbon black
2259:
2240:Cubic carbon
2189:
2128:
2095:
2045:
2027:
2021:
2015:
2009:
2001:
2000:
1990:
1989:, including
1974:
1966:
1949:
1938:
1882:
1871:Bibliography
1836:
1832:
1817:
1808:
1783:
1779:
1769:
1734:
1730:
1696:(34): 6477.
1693:
1687:
1681:
1659:(11): 1091.
1656:
1650:
1644:
1629:
1612:
1608:
1602:
1593:
1584:
1560:
1548:. Retrieved
1533:
1526:
1509:
1505:
1459:
1450:
1325:
1319:
1313:
1307:
1253:
1244:rhombohedral
1233:
1205:
1101:
1033:
1022:
968:
932:
912:and 15% of C
894:
860:
856:
851:
849:they found C
833:
825:vaporization
813:
806:Harold Kroto
750:Harold Kroto
747:
714:
713:
568:Cobalt oxide
548:Quantum dots
508:
481:Applications
75:Identifiers
63:Other names
50:
3703:Outer space
3613:Cosmic dust
3578:Abiogenesis
3490:Unconfirmed
3446:Heavy water
3286:Ethanethiol
3201:Cyanoallene
3191:Acetic acid
3161:Methylamine
3045:Diacetylene
2960:Formic acid
2950:Cyanomethyl
2608:Diazenylium
2598:CCP radical
2474:(molecular)
2458:(molecular)
2427:(molecular)
2235:Haeckelites
2180:(tricarbon)
2129:other forms
2029:Nanoscrolls
1550:26 December
1295:Space group
1176:isopropanol
1116:cyclohexane
843:evaporation
758:Robert Curl
334:Appearance
299:Properties
174:100.162.223
136:CHEBI:33195
92:115383-22-7
65:Fullerene-C
3811:Fullerenes
3618:Cosmic ray
3560:Silylidyne
3523:Hemolithin
3498:Anthracene
3415:Deuterated
3396:Pyrimidine
3206:Ethanimine
3069:Ketenimine
2925:Butadiynyl
2749:Thioformyl
2603:Chloronium
1987:Fullerenes
1760:2066/99047
1443:References
1338:Monoclinic
1240:monoclinic
1186:mesitylene
985:, whereas
965:molecule.
924:Properties
588:Iron oxide
495:Fullerenes
322:Molar mass
147:ChemSpider
103:3D model (
82:CAS Number
56:)Fullerene
21:fullerene
3550:Phosphine
3418:molecules
3351:fullerene
3251:Acetamide
3055:Formamide
2935:Cyanamide
2789:Acetylene
2764:Tricarbon
2675:Methylene
2660:Isoformyl
2565:Triatomic
2338:Molecules
2017:Nanotubes
1812:Katz, 372
1724:crystals"
1588:Katz, 368
1579:Katz, 363
1372:Hexagonal
1025:, mg/mL)
987:oxidation
902:pyrolysis
891:Synthesis
790:Fullerene
735:pentagons
723:fullerene
719:fullerene
558:Cellulose
514:Chemistry
466:Chemistry
461:Synthesis
347:1.7 g/cm
3805:Category
3537:Linear C
3518:Graphene
3430:Ammonium
3231:Acrolein
3094:Propynal
3079:Methanol
3050:Ethylene
2919:Ammonium
2694:Nitroxyl
2518:Sulfanyl
2462:Imidogen
2456:Nitrogen
2425:Hydrogen
2370:Argonium
2347:Diatomic
2278:Charcoal
2119:Q-carbon
2046:sp forms
2023:Nanobuds
1982:Graphene
1976:Graphite
1967:sp forms
1458:(2014).
1302:Pearson
1291:Symmetry
1210:such as
1208:solvents
1156:dodecane
1036:(mg/mL)
1030:Solvent
1012:Solution
943:symmetry
929:Molecule
847:graphite
831:target.
829:graphite
776:, whose
731:hexagons
636:Nanofoam
603:Platinum
486:Timeline
379:1.77 eV
375:Band gap
200:16131935
156:17288599
3683:Kerogen
3570:Related
3513:Glycine
3466:Propyne
3425:Ammonia
3323:Benzene
3318:Acetone
3310:or more
3281:Propene
3266:Ethanol
3156:Propyne
2975:Methane
2844:Ketenyl
2794:Ammonia
2260:related
2230:Chaoite
1861:4331074
1841:Bibcode
1788:Bibcode
1739:Bibcode
1661:Bibcode
1332:(g/cm)
1330:Density
1260:bandgap
1234:Solid C
1212:toluene
1180:0.0021
1166:heptane
1126:pentane
1082:benzene
1072:toluene
877:plasmas
784:History
733:and 12
721:is the
563:Ceramic
409:what is
407: (
343:Density
327:840.770
187:PubChem
3734:Tholin
3555:Pyrene
3000:Silane
2970:Ketene
2472:Oxygen
1889:
1859:
1833:Nature
1541:
1478:
1304:symbol
1200:0.080
1190:1.472
1170:0.047
1160:0.098
1150:0.053
1146:decane
1140:0.042
1136:octane
1130:0.002
1110:0.013
1106:hexane
1096:0.121
1076:1.406
1066:3.985
1062:xylene
1056:9.875
727:carbon
608:Silver
573:Copper
532:Other
404:verify
401:
283:SMILES
35:Names
3720:(PAH)
3308:atoms
3243:atoms
3183:atoms
3181:Eight
3111:atoms
3109:Seven
3017:atoms
2911:atoms
2781:atoms
2769:Water
2699:Ozone
2641:(HNC)
2635:(HCN)
1941:forms
1857:S2CID
1827:and C
1727:(PDF)
1436:1.67
1430:1.496
1427:1.496
1424:1.496
1421:cF280
1407:Cubic
1401:1.70
1395:1.858
1392:1.011
1389:1.011
1386:hP140
1361:1.996
1358:1.851
1355:1.996
1352:mP560
1278:/cm.
1230:Solid
1120:0.08
1046:36.2
933:The C
867:and C
859:with
840:laser
741:(or C
598:Lipid
248:InChI
127:ChEBI
105:JSmol
54:5h(6)
3241:Nine
2909:Five
2819:HCCN
2779:Four
2739:SiNC
1887:ISBN
1552:2011
1539:ISBN
1476:ISBN
1380:/mmc
1322:(nm)
1316:(nm)
1310:(nm)
1086:1.3
760:and
583:Iron
578:Gold
3532:NCO
3432:ion
3339:, C
3306:Ten
3015:Six
2921:ion
1939:sp
1849:doi
1837:350
1796:doi
1755:hdl
1747:doi
1735:166
1698:doi
1694:102
1669:doi
1617:doi
1514:doi
1510:115
1468:doi
1418:225
1383:194
904:of
845:of
764:at
217:EPA
190:CID
3807::
3349:70
3341:60
3337:60
3335:(C
3060:HC
2081:18
2026:,
2020:,
2014:,
2008:,
2004:70
1999:,
1994:60
1855:.
1847:.
1835:.
1829:70
1825:60
1794:.
1782:.
1776:70
1753:.
1745:.
1733:.
1729:.
1722:70
1710:^
1692:.
1667:.
1657:41
1655:.
1636:60
1613:15
1611:.
1572:^
1508:.
1502:70
1490:^
1474:.
1462:.
1411:Fm
1376:P6
1349:11
1346:/m
1342:P2
1299:No
1284:70
1272:70
1268:70
1256:70
1248:70
1236:70
1224:70
1220:70
1019:70
1006:70
995:Fc
991:Fc
980:70
971:70
963:60
959:70
947:60
941:5h
935:70
920:.
914:70
910:60
883:.
869:70
865:60
836:70
752:,
743:60
717:70
315:70
67:70
47:70
45:(C
19:70
3539:5
3530:2
3528:H
3475:D
3473:2
3471:N
3347:C
3064:N
3062:4
2684:H
2682:2
2680:N
2322:e
2315:t
2308:v
2220:6
2215:C
2204:3
2199:C
2175:3
2170:C
2159:2
2154:C
2143:1
2138:C
2076:C
2065:6
2060:C
2032:)
2002:C
1992:C
1923:e
1916:t
1909:v
1895:.
1863:.
1851::
1843::
1823:C
1802:.
1798::
1790::
1784:4
1763:.
1757::
1749::
1741::
1704:.
1700::
1675:.
1671::
1663::
1623:.
1619::
1554:.
1520:.
1516::
1484:.
1470::
1433:4
1415:m
1413:3
1398:2
1378:3
1364:8
1344:1
1326:Z
1320:c
1314:b
1308:a
1276:S
1104:-
1102:n
1034:S
1023:S
1021:(
993:/
975:C
969:C
939:D
861:n
857:n
852:n
834:C
715:C
703:e
696:t
689:v
399:Y
312:C
219:)
215:(
107:)
51:D
49:-
17:C
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