226:
151:
35:
44:
427:
108:
776:
Mitchell, Alexander R.; Coburn, Michael D.; Schmidt, Robert D.; Pagoria, Philip F.; Lee, Gregory S. (2002). "Advances in the chemical conversion of surplus energetic materials to higher value products".
625:
651:
582:
TATB has a crystal density of 1.93 grams/cm, though most forms currently in use have no higher density than 1.80 grams/cm. TATB melts at 350 °C. The chemical formula for TATB is C
678:, is reacted with TMHI it is aminated to TATB. Thus, materials that would have to be destroyed when no longer needed are converted into a high value explosive.
440:
567:
mixtures or other use forms, the applications for such forms would be unclear since they would largely undo the insensitivity of pure TATB.
521:. Because it is so difficult to detonate by accident, even under severe conditions, it has become preferred for applications where extreme
542:
275:
529:, where accidental detonation during an airplane crash or rocket misfiring could potentially detonate the fissile core. All British
663:
557:
836:
816:
749:
240:
608:
TATB has been found to remain stable at temperatures at least as high as 250 °C for prolonged periods of time.
716:
447:
650:
Still another process has been found for the production of TATB from materials that are surplus to military use.
635:
However, it is likely that the production of TATB will be switched over to a process involving the nitration and
435:
751:
Conversion of the Rocket
Propellant UDMH to a Reagent Useful in Vicarious Nucleophilic Substitution Reactions
831:
183:
146:
204:
692:
549:
221:
621:
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534:
479:
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8:
403:
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225:
150:
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21:
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409:
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172:
530:
502:
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418:
825:
659:
368:
139:
748:
Mitchell, Alexander R.; Pagoria, P. F.; Schmidt, R. D. (10 November 1995).
346:
34:
675:
563:
Though it could theoretically be mixed with other explosive compounds in
471:
249:
InChI=1S/C6H6N6O6/c7-1-4(10(13)14)2(8)6(12(17)18)3(9)5(1)11(15)16/h7-9H2
654:(TMHI) is formed from the rocket fuel unsymmetrical dimethylhydrazine (
576:
332:
259:
InChI=1/C6H6N6O6/c7-1-4(10(13)14)2(8)6(12(17)18)3(9)5(1)11(15)16/h7-9H2
119:
697:
671:
667:
617:
510:
417:
Except where otherwise noted, data are given for materials in their
643:, since this process is milder, cheaper, and reduces the amount of
107:
475:
354:
159:
552:
compositions, such as PBX-9502, LX-17-0, and PBX-9503 (with 15%
497:
TATB is a very powerful explosive (somewhat less powerful than
43:
687:
487:
97:
775:
757:(Technical report). Lawrence Livermore National Laboratory.
209:
655:
514:
360:
17:
553:
498:
747:
575:
At a pressed density of 1.80, TATB has a velocity of
548:
TATB is normally used as the explosive ingredient in
823:
494:) groups attached, alternating around the ring.
171:
83:
728:
719:, UK MOD position statement, 23 January 2006
647:salt produced in waste effluents (greener).
525:is required, such as the explosives used in
224:
149:
127:
474:explosive, based on the basic six-carbon
191:
722:
556:). These formulations are described as
220:
824:
731:"South Africa and the Affordable Bomb"
560:(IHEs) in nuclear weapons literature.
505:), but it is extremely insensitive to
373:350 °C (662 °F; 623 K)
140:
632:with amine groups using ammonolysis.
626:1,3,5-trichloro-2,4,6-trinitrobenzene
605:Pure TATB has a bright yellow color.
252:Key: JDFUJAMTCCQARF-UHFFFAOYSA-N
545:used TATB to increase their safety.
468:2,4,6-triamino-1,3,5-trinitrobenzene
61:2,4,6-Trinitrobenzene-1,3,5-triamine
664:vicarious nucleophilic substitution
533:use TATB-based explosives in their
345:Yellow or brown powdered crystals (
262:Key: JDFUJAMTCCQARF-UHFFFAOYAO
162:
13:
14:
853:
735:Bulletin of the Atomic Scientists
652:1,1,1-trimethylhydrazinium iodide
283:c1(c(c(c(c(c1(=O))N)(=O))N)(=O))N
674:, which is easily produced from
425:
316:
310:
42:
33:
421:(at 25 °C , 100 kPa).
811:, New York: Wiley-VCH, 1996.
769:
741:
710:
628:, then the chlorine atoms are
543:South Africa's nuclear weapons
322:
304:
1:
801:
791:10.1016/S0040-6031(01)00806-1
611:
570:
729:David Albright (July 1994).
579:of 7,350 meters per second.
7:
681:
558:insensitive high explosives
10:
858:
478:ring structure with three
337:258.15 g/mol
15:
415:
377:
291:
271:
236:
67:
55:
50:
41:
32:
837:Nitrobenzene derivatives
717:Memorandum from Prospect
703:
693:Plastic bonded explosive
550:plastic bonded explosive
16:Not to be confused with
480:nitro functional groups
464:triaminotrinitrobenzene
809:Explosives Engineering
622:1,3,5-trichlorobenzene
20:, a highly sensitive
616:TATB is produced by
394:Friction sensitivity
57:Preferred IUPAC name
832:Explosive chemicals
404:Detonation velocity
29:
779:Thermochimica Acta
448:Infobox references
27:
807:Cooper, Paul W.,
765:. UCRL-JC-122489.
645:ammonium chloride
456:Chemical compound
454:
453:
384:Shock sensitivity
205:CompTox Dashboard
109:Interactive image
22:primary explosive
849:
795:
794:
785:(1–2): 205–217.
773:
767:
766:
756:
745:
739:
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662:, and acts as a
537:. According to
531:nuclear warheads
501:, but more than
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299:Chemical formula
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527:nuclear weapons
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443: ?)
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378:Explosive data
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670:reagent. When
641:phloroglucinol
637:transamination
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539:David Albright
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419:standard state
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737:. p. 44.
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369:Melting point
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486:) and three
467:
463:
459:
458:
398:Insensitive
388:Insensitive
347:rhombohedral
68:Identifiers
676:Explosive D
630:substituted
342:Appearance
292:Properties
147:100.019.362
826:Categories
802:References
612:Production
577:detonation
571:Properties
333:Molar mass
193:CJP3UNX7Z7
120:ChemSpider
96:3D model (
75:CAS Number
698:RE factor
672:picramide
668:amination
618:nitration
511:vibration
85:3058-38-6
842:Anilines
763:54794595
682:See also
565:castable
472:aromatic
476:benzene
441:what is
439: (
355:Density
160:PubChem
815:
761:
666:(VNS)
658:) and
523:safety
519:impact
470:is an
436:verify
433:
276:SMILES
51:Names
759:S2CID
755:(PDF)
704:Notes
688:FOX-7
517:, or
507:shock
488:amine
408:7350
359:1.93
241:InChI
173:18286
129:17272
98:JSmol
28:TATB
813:ISBN
656:UDMH
515:fire
460:TATB
363:/cm
184:UNII
18:TATP
787:doi
783:384
639:of
624:to
620:of
594:(NH
586:(NO
554:HMX
503:TNT
499:RDX
490:(NH
482:(NO
466:or
410:m/s
210:EPA
163:CID
828::
781:.
733:.
602:.
541:,
513:,
509:,
462:,
349:)
793:.
789::
600:3
598:)
596:2
592:3
590:)
588:2
584:6
492:2
484:2
431:N
361:g
326:6
323:O
320:6
317:N
314:6
311:H
308:6
305:C
212:)
208:(
100:)
24:.
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