244:
151:
1077:
1084:
636:
1393:, that selectively reduces those grains which contain atoms of silver. The process, which is sensitive to temperature and concentration, completely reduces grains to silver metal, intensifying the latent image on the order of 10 to 10. This step demonstrates the advantage and superiority of silver halides over other systems: the latent image, which takes only milliseconds to form and is invisible, is sufficient to produce a full image from it.
24:
766:
981:
1238:
Studies have demonstrated that the defect concentrations are strongly affected (up to several decimal orders) by crystal size. Most defects, such as interstitial silver ion concentration and surface kinks, are inversely proportional to crystal size, although vacancy defects are directly proportional.
844:
Modern preparation of a simple, light-sensitive surface involves forming an emulsion of silver halide crystals in a gelatine, which is then coated onto a film or other support. The crystals are formed by precipitation in a controlled environment to produce small, uniform crystals (typically < 1 μm
1230:
The low activation energy in silver bromide can be attributed the silver ions' high quadrupolar polarizability; that is, it can easily deform from a sphere into an ellipsoid. This property, a result of the d electronic configuration of the silver ion, facilitates migration in both the silver ion and
1436:
of the ionic conductivity shows the value increasing and "upward-turning". Other physical properties such as elastic moduli, specific heat, and the electronic energy gap also increase, suggesting that the crystal is approaching instability. This behavior, typical for a semi-conductor, is attributed
1328:
Once the hole-complexes are formed, they diffuse to the surface of the grain as a result of the formed concentration gradient. Studies demonstrated that the lifetimes of holes near the surface of the grain are much longer than those in the bulk, and that these holes are in equilibrium with adsorbed
1286:
When a photoelectron is mobilized, a photohole h• is also formed, which also needs to be neutralized. The lifetime of a photohole, however, does not correlate with that of a photoelectron. This detail suggests a different trapping mechanism; Malinowski suggests that the hole traps may be related to
1282:
Through the defects in the crystal, the electron is able to reduce its energy and become trapped in the atom. The extent of grain boundaries and defects in the crystal affect the lifetime of the photoelectron, where crystals with a large concentration of defects traps an electron much faster than a
1104:
The larger halide ions are arranged in a cubic close-packing, while the smaller silver ions fill the octahedral gaps between them, giving a 6-coordinate structure where a silver ion Ag is surrounded by 6 Br ions, and vice versa. The coordination geometry for AgBr in the NaCl structure is unexpected
1373:
To summarize, as a photographic film is subjected to an image, photons incident on the grain produce electrons, which interact to yield silver metal. More photons hitting a particular grain produce a larger concentration of silver atoms, containing between 5 and 50 silver atoms (out of ~10 atoms),
1177:
Although photographic processes had been in use since the mid-1800s, there were no suitable theoretical explanations until 1938 with the publication of a paper by R. W. Gurney and N. F. Mott. This paper triggered a large amount of research in fields of solid-state chemistry and
1314:
Additional investigations on electron- and hole-trapping demonstrated that impurities also can be a significant trapping system. Consequently, interstitial silver ions may not be reduced. Therefore, these traps are actually loss mechanisms and are considered trapping inefficiencies. For example,
1181:
Further research into this mechanism revealed that the photographic properties of silver halides (in particular AgBr) were a result of deviations from an ideal crystal structure. Factors such as crystal growth, impurities, and surface defects all affect concentrations of point ionic defects and
1242:
Impurity concentrations can be controlled by crystal growth or direct addition of impurities to the crystal solutions. Although impurities in the silver bromide lattice are necessary to encourage
Frenkel defect formation, studies by Hamilton have shown that above a specific concentration of
1243:
impurities, the numbers of defects of interstitial silver ions and positive kinks reduce sharply by several orders of magnitude. After this point, only silver-ion vacancy defects, which actually increase by several orders of magnitude, are prominent.
1310:
lowers its energy sufficiently to stabilize the complex and reduce the probability of ejection of the hole back into the valence band (the equilibrium constant for hole-complex in the interior of the crystal is estimated at 10.
1348:
By this reaction equilibrium, the hole-complexes are constantly consumed at the surface, which acts as a sink, until removed from the crystal. This mechanism provides the counterpart to the reduction of the interstitial
1214:
are exceptionally mobile, and that its concentration in the layer below the grain surface (called the space-charge layer) far exceeds that of the intrinsic bulk. The formation energy of the
Frenkel pair is low at
1319:
species, which can interact with a hole to reverse the complex and undergo recombination. Metal ion impurities such as copper(I), iron(II), and cadmium(II) have demonstrated hole-trapping in silver bromide.
644:
1381:
While this process is occurring, bromine atoms are being produced at the surface of the crystal. To collect the bromine, a layer on top of the emulsion, called a sensitizer, acts as a bromine acceptor.
616:
1654:
Engelhardt, L. M.; Healy, P. C.; Patrick, V. A.; White, A. H. (1987). "Lewis-Base
Adducts of Group-11 Metal(I) Compounds. XXX. 3:1 Complexes of Triphenylphosphine With Silver(I) Halides".
1374:
depending on the sensitivity of the emulsion. The film now has a concentration gradient of silver atom specks based upon varying intensity light across its area, producing an invisible "
1396:
After development, the film is "fixed", during which the remaining silver salts are removed to prevent further reduction, leaving the "negative" image on the film. The agent used is
805:. This property has allowed silver halides to become the basis of modern photographic materials. AgBr is widely used in photographic films and can be found naturally as the mineral
1116:
The silver halides have a wide range of solubilities. The solubility of AgF is about 6 × 10 times that of AgI. These differences are attributed to the relative
2598:
2267:
1437:
to a temperature-dependence of
Frenkel defect formation, and, when normalized against the concentration of Frenkel defects, the Arrhenius plot linearizes.
2578:
1329:
bromine. The net effect is an equilibrium push at the surface to form more holes. Therefore, as the hole-complexes reach the surface, they disassociate:
1287:
defects as a result of impurities. Once trapped, the holes attract mobile, negatively charged defects in the lattice: the interstitial silver vacancy Ag
779:
1424:
An indefinite number of positive prints can be generated from the negative by passing light through it and undertaking the same steps outlined above.
2768:
1227:
and 0.75 eV for cationic migration). These low energies result in large defect concentrations, which can reach near 1% near the melting point.
1251:
When light is incident on the silver-halide grain surface, a photoelectron is generated when a halide loses its electron to the conduction band:
2555:
293:
3939:
1924:
1239:
This phenomenon is attributed to changes in the surface chemistry equilibrium, and thus affects each defect concentration differently.
1623:"The Solubility of Silver Chloride and Silver Bromide in Aqueous Ammonia and the Formation of Mixed Silver–Ammonia-Halide Complexes"
999:
AgF, AgCl, and AgBr all have face-centered cubic (fcc) rock-salt (NaCl) lattice structure with the following lattice parameters:
1880:
1581:
563:
4316:
774:
980:
590:
4311:
2661:
1893:
258:
1076:
2109:
786:
4306:
3932:
1105:
for Ag(I) which typically forms linear, trigonal (3-coordinated Ag) or tetrahedral (4-coordinated Ag) complexes.
801:(AgBr) is a soft, pale-yellow, water-insoluble salt well known (along with other silver halides) for its unusual
1917:
672:
201:
146:
635:
222:
3925:
2121:
1083:
4301:
3640:
1910:
158:
2639:
3891:
3876:
3792:
2329:
1967:
1108:
Unlike the other silver halides, iodargyrite (AgI) contains a hexagonal zincite lattice structure.
239:
853:
Silver bromide reacts readily with liquid ammonia to generate a variety of ammine complexes, like
817:
Although the compound can be found in mineral form, AgBr is typically prepared by the reaction of
3884:
3799:
3717:
3701:
3663:
3219:
3204:
2882:
2875:
465:
4291:
3868:
3852:
3837:
3822:
3763:
3655:
3624:
3322:
3234:
3226:
3211:
3197:
3174:
3087:
2654:
2395:
2337:
1451:
539:
399:
4198:
3845:
3829:
3776:
3756:
3693:
3678:
3648:
3530:
3372:
3250:
3181:
3121:
3006:
2991:
2976:
2961:
2954:
2868:
2848:
2822:
2362:
658:
628:
108:
36:
1202:) in high concentration with their corresponding negatively charged silver-ion vacancies (Ag
4226:
4059:
4054:
3814:
3807:
3748:
3725:
3709:
3686:
3671:
3463:
3456:
3441:
3434:
3411:
3403:
3380:
3242:
3157:
3072:
2998:
2984:
2969:
2947:
2913:
2860:
2811:
2590:
1741:
1120:
enthalpies of the halide ions; the enthalpy of solvation of fluoride is anomalously large.
210:
128:
1621:
Leden, Ido; Persson, Göran; Sjöberg, Berndt; Dam, H.; Sjöberg, Berndt; Toft, Jens (1961).
84:
8:
4206:
4152:
4094:
3996:
3860:
3784:
3733:
3632:
3502:
3494:
3426:
3419:
3396:
3388:
3314:
3298:
3275:
3165:
3080:
3044:
2815:
2799:
2742:
2730:
2621:
2547:
2476:
2349:
2050:
2003:
74:
1745:
841:
Although less convenient, the compound can also be prepared directly from its elements.
243:
150:
4266:
4129:
4080:
3523:
3515:
3483:
3334:
3305:
3189:
3114:
3095:
3056:
3037:
3029:
2894:
2788:
2773:
2275:
2239:
2104:
2032:
2024:
1947:
1597:
1397:
1223:
is unusually low at 0.05 eV (compare to NaCl: 2.18 eV for the formation of a
970:
745:
709:
4296:
4009:
3948:
3741:
3475:
3338:
3329:
3271:
3147:
3106:
3052:
3021:
2923:
2889:
2852:
2840:
2707:
2647:
2181:
2091:
1889:
1577:
1220:
1182:
electronic traps, which affect the sensitivity to light and allow the formation of a
822:
740:
1683:"The band structures of the silver halides AgF, AgCl, and AgBr: A comparative study"
1639:
1622:
4113:
4004:
3548:
3538:
3507:
3309:
3142:
3102:
3014:
2939:
2905:
2764:
2756:
2715:
2686:
2378:
2317:
2296:
2197:
2141:
2129:
1993:
1933:
1861:
1857:
1749:
1694:
1663:
1634:
1386:
478:
387:
316:
1729:"The theory of the photolysis of silver bromide and the photographic latent image"
664:
190:
4236:
4179:
4072:
3471:
3356:
3346:
3290:
3283:
3263:
2928:
2781:
2737:
2702:
2443:
2418:
2305:
2284:
2169:
2016:
2008:
1998:
1456:
1224:
714:
503:
1178:
physics, as well more specifically in silver halide photosensitivity phenomena.
3976:
3553:
3361:
2835:
2722:
2508:
2434:
2402:
2255:
2227:
2218:
2153:
2099:
2082:
2066:
2058:
1988:
1980:
1433:
1231:
in silver-ion vacancies, thus giving the unusually low migration energy (for Ag
1195:
818:
802:
757:
346:
4285:
4064:
2749:
2042:
2037:
1782:
Hamilton, J.F. (1974). "Physical
Properties of Silver Halide Microcrystals".
1733:
1527:
719:
520:
376:
366:
139:
3967:
3064:
2209:
2074:
1810:
Slifkin, L. M. (1989). "The
Physics of Lattice Defects in Silver Halides".
1754:
1728:
1390:
1375:
1216:
1207:
1183:
806:
51:
4089:
1446:
1848:
Malinowski, J. (1968). "The Role of Holes in the
Photographic Process".
1432:
As silver bromide is heated within 100 °C of its melting point, an
4258:
4035:
418:
327:
159:
119:
1667:
3988:
2669:
1885:
1699:
1682:
1389:
the latent image is intensified by addition of a chemical, typically
1117:
3917:
756:
Except where otherwise noted, data are given for materials in their
1902:
1259:
After the electron is released, it combines with an interstitial Ag
454:
686:
107:
4218:
4160:
3962:
3129:
2671:
443:
437:
427:
356:
177:
1315:
atmospheric oxygen can interact with photoelectrons to form an O
678:
1717:, 86th Edition, The Chemical Rubber Publishing Co., Cleveland.
1189:
23:
97:
227:
1653:
1571:
431:
1567:
1368:
1235:: 0.29–0.33 eV, compared to 0.65 eV for NaCl).
731:
700:
2394:
1565:
1563:
1561:
1559:
1557:
1555:
1553:
1551:
1549:
1547:
845:
in diameter and containing ~10 Ag atoms) called grains.
1680:
1620:
1528:"Bromine | Properties, Uses, & Facts | Britannica"
1544:
1674:
1198:, where silver ions are located interstitially (Ag
1843:
1841:
1839:
1837:
1835:
1833:
1831:
1829:
1827:
1825:
4283:
1400:and reacts according to the following equation:
1246:
189:
1812:Crystal Lattice Defects and Amorphous Materials
1777:
1775:
1773:
1771:
1769:
1767:
1765:
682:
83:
1847:
1822:
1809:
1805:
1803:
1801:
1799:
1797:
1781:
1647:
1576:. New York: Permagon Press. pp. 1185–87.
3933:
2655:
1918:
1762:
1323:
973:to give a tris(triphenylphosphine) product:
381:1,502 °C (2,736 °F; 1,775 K)
1794:
1427:
1190:Frenkel defects and quadropolar deformation
3940:
3926:
2662:
2648:
1925:
1911:
1726:
1194:The major defect in silver halides is the
242:
149:
127:
1753:
1698:
1638:
209:
1614:
1065:
2670:Salts and covalent derivatives of the
1681:Glaus, S. & Calzaferri, G. (2003).
238:
4284:
2692:
1572:Greenwood, N.N.; Earnshaw, A. (1984).
1369:Latent image formation and photography
989:
371:430 °C (806 °F; 703 K)
140:
3947:
3921:
3613:
2643:
1906:
1881:CRC Handbook of Chemistry and Physics
1477:
1475:
1473:
1471:
270:Key: ADZWSOLPGZMUMY-UHFFFAOYSA-M
1932:
1784:Photographic Science and Engineering
994:
1850:The Journal of Photographic Science
1727:Gurney, R. W.; Mott, N. F. (1938).
1707:
1172:
280:Key: ADZWSOLPGZMUMY-REWHXWOFAK
180:
13:
1468:
821:with an alkali bromide, typically
14:
4328:
1715:Handbook of Chemistry and Physics
1125:Silver halide solubility in water
1878:Haynes, William M., ed. (2016).
1871:
1357:, giving an overall equation of
1263:to create a silver metal atom Ag
1082:
1075:
1004:Silver halide lattice properties
979:
764:
634:
22:
1720:
1640:10.3891/acta.chem.scand.15-0607
760:(at 25 °C , 100 kPa).
1862:10.1080/00223638.1968.11737436
1590:
1520:
1511:
1502:
1493:
1484:
812:
1:
1462:
1247:Electron traps and hole traps
1206:). What is unique about AgBr
1111:
833:(aq) + KBr(aq) → AgBr(s)+ KNO
267:InChI=1S/Ag.BrH/h;1H/q+1;/p-1
848:
277:InChI=1/Ag.BrH/h;1H/q+1;/p-1
7:
4317:Rock salt crystal structure
1877:
1713:Lide, David R. (ed). (2005)
1440:
1210:is that the interstitial Ag
1066:
969:Silver bromide reacts with
10:
4335:
3615:
332:187.77 g/mol
4312:Light-sensitive chemicals
4251:
4191:
4172:
4145:
4122:
4106:
4047:
4028:
3955:
2694:
2679:
2614:
2571:
2540:
2396:Organosilver(I) compounds
1960:
1940:
1687:Photochem. Photobiol. Sci
1598:"Definition of BROMYRITE"
1574:Chemistry of the Elements
1324:Crystal surface chemistry
1306:The formation of the h.Ag
754:
692:
615:
610:
513:
496:
309:
289:
254:
67:
45:
35:
30:
21:
1428:Semiconductor properties
673:Precautionary statements
1602:www.merriam-webster.com
1361:AgBr → Ag + fraction Br
466:Magnetic susceptibility
4307:Photographic chemicals
1755:10.1098/rspa.1938.0011
1452:Science of photography
436:sparingly soluble in
1219:, and the migration
1094:rock-salt structure
1091:face-centered cubic
1038:AgCl, Chlorargyrite
803:sensitivity to light
1746:1938RSPSA.164..151G
1127:
1071:
1069:Unit cell structure
1052:AgBr, Bromargyrite
1006:
990:Physical properties
584:−100.4 kJ·mol
557:107.1 J·mol·K
388:Solubility in water
18:
1532:www.britannica.com
1398:sodium thiosulfate
1341:→ Br → fraction Br
1123:
1067:
1002:
971:triphenylphosphine
787:Infobox references
746:Mercury(I) bromide
710:Silver(I) fluoride
693:Related compounds
606:−96.9 kJ·mol
442:soluble in alkali
400:Solubility product
393:0.14 mg/L (25 °C)
16:
4279:
4278:
3949:Bromine compounds
3915:
3914:
3909:
3908:
2637:
2636:
2536:
2535:
1884:(97th ed.).
1668:10.1071/CH9871873
1662:(11): 1873–1880.
1583:978-0-08-022057-4
1221:activation energy
1170:
1169:
1134:Solubility (g/L)
1102:
1101:
1098:
1097:
995:Crystal structure
823:potassium bromide
795:Chemical compound
793:
792:
741:Copper(I) bromide
659:Hazard statements
591:Gibbs free energy
361:6.47 g/cm, solid
343:Pale yellow solid
223:CompTox Dashboard
109:Interactive image
59:Argentous bromide
40:Silver(I) bromide
4324:
4302:Silver compounds
4243:
4232:
4020:
3942:
3935:
3928:
3919:
3918:
3452:
3451:
3450:
3171:
2683:
2682:
2664:
2657:
2650:
2641:
2640:
2529:
2527:
2526:
2518:
2517:
2472:
2471:
2470:
2462:
2461:
2453:
2452:
2392:
2391:
1934:Silver compounds
1927:
1920:
1913:
1904:
1903:
1899:
1866:
1865:
1845:
1820:
1819:
1807:
1792:
1791:
1779:
1760:
1759:
1757:
1740:(917): 151–167.
1724:
1718:
1711:
1705:
1704:
1702:
1700:10.1039/b211678b
1678:
1672:
1671:
1651:
1645:
1644:
1642:
1627:Acta Chem. Scand
1618:
1612:
1611:
1609:
1608:
1594:
1588:
1587:
1569:
1542:
1541:
1539:
1538:
1524:
1518:
1515:
1509:
1506:
1500:
1499:Haynes, p. 4.130
1497:
1491:
1490:Haynes, p. 5.178
1488:
1482:
1479:
1387:film development
1173:Photosensitivity
1128:
1122:
1086:
1079:
1072:
1058:rock-salt, NaCl
1044:rock-salt, NaCl
1030:rock-salt, NaCl
1007:
1001:
983:
965:
964:
963:
953:
952:
942:
941:
931:
930:
929:
904:
903:
902:
894:
893:
885:
884:
874:
872:
871:
863:
862:
777:
771:
768:
767:
688:
684:
680:
666:
638:
602:
580:
553:
529:
514:Thermochemistry
479:Refractive index
472:−59.7·10 cm/mol
317:Chemical formula
247:
246:
231:
229:
213:
193:
182:
161:
153:
142:
131:
111:
87:
26:
19:
15:
4334:
4333:
4327:
4326:
4325:
4323:
4322:
4321:
4282:
4281:
4280:
4275:
4270:
4262:
4247:
4241:
4237:
4231:
4227:
4222:
4214:
4210:
4202:
4187:
4183:
4168:
4164:
4156:
4141:
4137:
4133:
4118:
4102:
4098:
4084:
4076:
4068:
4043:
4039:
4024:
4018:
4014:
4010:
4000:
3992:
3984:
3980:
3971:
3951:
3946:
3916:
3911:
3910:
3895:
3890:
3888:
3880:
3872:
3864:
3856:
3851:
3849:
3841:
3833:
3828:
3826:
3818:
3813:
3811:
3803:
3798:
3796:
3788:
3780:
3767:
3762:
3760:
3752:
3747:
3745:
3737:
3729:
3721:
3713:
3705:
3697:
3692:
3690:
3682:
3677:
3675:
3667:
3659:
3654:
3652:
3644:
3636:
3628:
3557:
3534:
3529:
3527:
3519:
3511:
3498:
3493:
3491:
3487:
3479:
3474:
3467:
3462:
3460:
3449:
3446:
3445:
3444:
3442:
3440:
3438:
3430:
3425:
3423:
3415:
3407:
3402:
3400:
3392:
3384:
3376:
3365:
3350:
3342:
3337:
3328:
3326:
3321:
3318:
3308:
3304:
3302:
3294:
3289:
3287:
3279:
3274:
3267:
3254:
3246:
3238:
3230:
3225:
3223:
3215:
3210:
3208:
3203:
3201:
3193:
3185:
3180:
3178:
3173:
3170:
3166:
3161:
3151:
3133:
3125:
3120:
3118:
3110:
3105:
3101:
3099:
3091:
3086:
3084:
3076:
3068:
3060:
3055:
3048:
3043:
3041:
3033:
3025:
3020:
3018:
3010:
3002:
2997:
2995:
2990:
2988:
2980:
2975:
2973:
2965:
2960:
2958:
2953:
2951:
2943:
2934:
2932:
2909:
2904:
2902:
2898:
2888:
2886:
2881:
2879:
2874:
2872:
2864:
2856:
2851:
2844:
2826:
2821:
2819:
2814:
2807:
2803:
2798:
2796:
2792:
2787:
2785:
2780:
2777:
2767:
2763:
2760:
2755:
2753:
2748:
2746:
2736:
2734:
2726:
2721:
2719:
2711:
2675:
2668:
2638:
2633:
2629:
2625:
2610:
2606:
2602:
2594:
2586:
2582:
2567:
2563:
2559:
2551:
2532:
2525:
2522:
2521:
2520:
2516:
2513:
2512:
2511:
2509:
2504:
2500:
2496:
2492:
2488:
2484:
2480:
2469:
2466:
2465:
2464:
2460:
2457:
2456:
2455:
2451:
2448:
2447:
2446:
2444:
2438:
2430:
2426:
2422:
2414:
2410:
2406:
2390:
2386:
2382:
2374:
2370:
2366:
2357:
2353:
2345:
2341:
2333:
2325:
2321:
2313:
2309:
2300:
2292:
2288:
2279:
2271:
2263:
2259:
2251:
2247:
2243:
2235:
2231:
2222:
2213:
2205:
2201:
2193:
2189:
2185:
2177:
2173:
2165:
2161:
2157:
2149:
2145:
2137:
2133:
2125:
2117:
2113:
2095:
2086:
2078:
2070:
2062:
2054:
2046:
2028:
2020:
2012:
1984:
1971:
1956:
1951:
1936:
1931:
1896:
1874:
1869:
1846:
1823:
1808:
1795:
1780:
1763:
1725:
1721:
1712:
1708:
1679:
1675:
1652:
1648:
1619:
1615:
1606:
1604:
1596:
1595:
1591:
1584:
1570:
1545:
1536:
1534:
1526:
1525:
1521:
1517:Haynes, p. 5.35
1516:
1512:
1508:Haynes, p. 9.65
1507:
1503:
1498:
1494:
1489:
1485:
1481:Haynes, p. 4.84
1480:
1469:
1465:
1457:Silver chloride
1443:
1430:
1419:
1415:
1411:
1407:
1371:
1364:
1356:
1352:
1344:
1340:
1336:
1326:
1318:
1309:
1302:
1298:
1290:
1283:purer crystal.
1278:
1274:
1266:
1262:
1249:
1234:
1213:
1205:
1201:
1192:
1175:
1114:
997:
992:
962:
957:
956:
955:
951:
946:
945:
944:
940:
937:
936:
935:
933:
928:
926:
925:
924:
922:
916:
901:
898:
897:
896:
892:
889:
888:
887:
883:
880:
879:
878:
876:
870:
867:
866:
865:
861:
858:
857:
856:
854:
851:
836:
832:
815:
796:
789:
784:
783:
782: ?)
773:
769:
765:
761:
750:
734:
724:
715:Silver chloride
703:
675:
661:
647:
631:
603:
597:
593:
581:
578:
572:
568:
565:
564:Std enthalpy of
554:
551:
544:
541:
530:
523:
506:
489:
487:
469:
449:
410:
408:
390:
351:
319:
305:
302:
297:
296:
285:
282:
281:
278:
272:
271:
268:
262:
261:
250:
232:
225:
216:
196:
183:
171:
134:
114:
101:
90:
77:
63:
62:
41:
17:Silver bromide
12:
11:
5:
4332:
4331:
4320:
4319:
4314:
4309:
4304:
4299:
4294:
4277:
4276:
4274:
4273:
4268:
4264:
4260:
4255:
4253:
4249:
4248:
4246:
4245:
4239:
4234:
4229:
4224:
4220:
4216:
4212:
4208:
4204:
4200:
4195:
4193:
4189:
4188:
4186:
4185:
4181:
4176:
4174:
4170:
4169:
4167:
4166:
4162:
4158:
4154:
4149:
4147:
4143:
4142:
4140:
4139:
4135:
4131:
4126:
4124:
4120:
4119:
4117:
4116:
4110:
4108:
4104:
4103:
4101:
4100:
4096:
4092:
4087:
4082:
4078:
4074:
4070:
4066:
4062:
4057:
4051:
4049:
4045:
4044:
4042:
4041:
4037:
4032:
4030:
4026:
4025:
4023:
4022:
4016:
4012:
4007:
4002:
3998:
3994:
3990:
3986:
3982:
3978:
3974:
3969:
3965:
3959:
3957:
3953:
3952:
3945:
3944:
3937:
3930:
3922:
3913:
3912:
3907:
3906:
3903:
3900:
3897:
3893:
3886:
3882:
3878:
3874:
3870:
3866:
3862:
3858:
3854:
3847:
3843:
3839:
3835:
3831:
3824:
3820:
3816:
3809:
3805:
3801:
3794:
3790:
3786:
3782:
3778:
3774:
3770:
3769:
3765:
3758:
3754:
3750:
3743:
3739:
3735:
3731:
3727:
3723:
3719:
3715:
3711:
3707:
3703:
3699:
3695:
3688:
3684:
3680:
3673:
3669:
3665:
3661:
3657:
3650:
3646:
3642:
3638:
3634:
3630:
3626:
3622:
3618:
3617:
3614:
3611:
3610:
3607:
3604:
3601:
3598:
3595:
3592:
3589:
3586:
3583:
3580:
3577:
3574:
3571:
3568:
3565:
3562:
3559:
3555:
3551:
3545:
3544:
3541:
3536:
3532:
3525:
3521:
3517:
3513:
3509:
3505:
3500:
3496:
3489:
3485:
3481:
3477:
3469:
3465:
3458:
3454:
3447:
3436:
3432:
3428:
3421:
3417:
3413:
3409:
3405:
3398:
3394:
3390:
3386:
3382:
3378:
3374:
3370:
3367:
3363:
3359:
3353:
3352:
3348:
3344:
3340:
3332:
3324:
3316:
3312:
3300:
3296:
3292:
3285:
3281:
3277:
3269:
3265:
3261:
3256:
3252:
3248:
3244:
3240:
3236:
3232:
3228:
3221:
3217:
3213:
3206:
3199:
3195:
3191:
3187:
3183:
3176:
3168:
3163:
3159:
3155:
3153:
3149:
3145:
3139:
3138:
3135:
3131:
3127:
3123:
3116:
3112:
3108:
3097:
3093:
3089:
3082:
3078:
3074:
3070:
3066:
3062:
3058:
3050:
3046:
3039:
3035:
3031:
3027:
3023:
3016:
3012:
3008:
3004:
3000:
2993:
2986:
2982:
2978:
2971:
2967:
2963:
2956:
2949:
2945:
2941:
2937:
2935:
2930:
2926:
2920:
2919:
2916:
2911:
2907:
2900:
2896:
2892:
2884:
2877:
2870:
2866:
2862:
2858:
2854:
2846:
2842:
2838:
2832:
2831:
2828:
2824:
2817:
2809:
2805:
2801:
2794:
2790:
2783:
2775:
2771:
2758:
2751:
2744:
2740:
2732:
2728:
2724:
2717:
2713:
2709:
2705:
2699:
2698:
2695:
2693:
2691:
2689:
2681:
2680:
2677:
2676:
2667:
2666:
2659:
2652:
2644:
2635:
2634:
2632:
2631:
2627:
2623:
2618:
2616:
2612:
2611:
2609:
2608:
2604:
2600:
2596:
2592:
2588:
2584:
2580:
2575:
2573:
2569:
2568:
2566:
2565:
2561:
2557:
2553:
2549:
2544:
2542:
2538:
2537:
2534:
2533:
2531:
2523:
2514:
2506:
2502:
2498:
2494:
2490:
2486:
2482:
2478:
2474:
2467:
2458:
2449:
2441:
2436:
2432:
2428:
2424:
2420:
2416:
2412:
2408:
2404:
2400:
2398:
2389:
2388:
2384:
2380:
2376:
2372:
2368:
2364:
2360:
2355:
2351:
2347:
2343:
2339:
2335:
2331:
2327:
2323:
2319:
2315:
2311:
2307:
2303:
2298:
2294:
2290:
2286:
2282:
2277:
2273:
2269:
2265:
2261:
2257:
2253:
2249:
2245:
2241:
2237:
2233:
2229:
2225:
2220:
2216:
2211:
2207:
2203:
2199:
2195:
2191:
2187:
2183:
2179:
2175:
2171:
2167:
2163:
2159:
2155:
2151:
2147:
2143:
2139:
2135:
2131:
2127:
2123:
2119:
2115:
2111:
2107:
2102:
2097:
2093:
2089:
2084:
2080:
2076:
2072:
2068:
2064:
2060:
2056:
2052:
2048:
2044:
2040:
2035:
2030:
2026:
2022:
2018:
2014:
2010:
2006:
2001:
1996:
1991:
1986:
1982:
1978:
1973:
1969:
1964:
1962:
1958:
1957:
1955:
1954:
1949:
1944:
1942:
1938:
1937:
1930:
1929:
1922:
1915:
1907:
1901:
1900:
1894:
1873:
1870:
1868:
1867:
1821:
1793:
1761:
1719:
1706:
1693:(4): 398–401.
1673:
1646:
1613:
1589:
1582:
1543:
1519:
1510:
1501:
1492:
1483:
1466:
1464:
1461:
1460:
1459:
1454:
1449:
1442:
1439:
1434:Arrhenius plot
1429:
1426:
1422:
1421:
1420:(aq) + NaX(aq)
1417:
1413:
1409:
1405:
1370:
1367:
1366:
1365:
1362:
1354:
1350:
1346:
1345:
1342:
1338:
1334:
1325:
1322:
1316:
1307:
1304:
1303:
1300:
1296:
1288:
1280:
1279:
1276:
1272:
1264:
1260:
1257:
1256:
1255:X + hν → X + e
1248:
1245:
1232:
1211:
1203:
1199:
1196:Frenkel defect
1191:
1188:
1174:
1171:
1168:
1167:
1164:
1160:
1159:
1156:
1152:
1151:
1148:
1144:
1143:
1140:
1136:
1135:
1132:
1113:
1110:
1100:
1099:
1096:
1095:
1092:
1088:
1087:
1080:
1063:
1062:
1059:
1056:
1053:
1049:
1048:
1045:
1042:
1039:
1035:
1034:
1031:
1028:
1025:
1021:
1020:
1019:Lattice, a /Å
1017:
1014:
1011:
996:
993:
991:
988:
987:
986:
985:
984:
967:
966:
958:
947:
938:
927:
914:
905:. In general:
899:
890:
881:
868:
859:
850:
847:
839:
838:
834:
830:
819:silver nitrate
814:
811:
799:Silver bromide
794:
791:
790:
785:
763:
762:
758:standard state
755:
752:
751:
749:
748:
743:
737:
735:
729:
726:
725:
723:
722:
717:
712:
706:
704:
698:
695:
694:
690:
689:
676:
671:
668:
667:
662:
657:
654:
653:
648:
643:
640:
639:
632:
627:
624:
623:
613:
612:
608:
607:
604:
595:
589:
586:
585:
582:
576:
570:
562:
559:
558:
555:
549:
538:
535:
534:
531:
519:
516:
515:
511:
510:
507:
502:
499:
498:
494:
493:
490:
485:
477:
474:
473:
470:
464:
461:
460:
457:
451:
450:
448:
447:
440:
434:
423:
421:
415:
414:
411:
406:
398:
395:
394:
391:
386:
383:
382:
379:
373:
372:
369:
363:
362:
359:
353:
352:
350:
349:
347:photosensitive
344:
340:
338:
334:
333:
330:
324:
323:
320:
315:
312:
311:
307:
306:
304:
303:
300:
292:
291:
290:
287:
286:
284:
283:
279:
276:
275:
273:
269:
266:
265:
257:
256:
255:
252:
251:
249:
248:
235:
233:
221:
218:
217:
215:
214:
206:
204:
198:
197:
195:
194:
186:
184:
176:
173:
172:
170:
169:
165:
163:
155:
154:
144:
136:
135:
133:
132:
124:
122:
116:
115:
113:
112:
104:
102:
95:
92:
91:
89:
88:
80:
78:
73:
70:
69:
65:
64:
61:
60:
57:
54:
48:
47:
43:
42:
39:
33:
32:
28:
27:
9:
6:
4:
3:
2:
4330:
4329:
4318:
4315:
4313:
4310:
4308:
4305:
4303:
4300:
4298:
4295:
4293:
4292:Metal halides
4290:
4289:
4287:
4272:
4265:
4263:
4257:
4256:
4254:
4250:
4244:
4235:
4233:
4225:
4223:
4217:
4215:
4205:
4203:
4197:
4196:
4194:
4190:
4184:
4178:
4177:
4175:
4171:
4165:
4159:
4157:
4151:
4150:
4148:
4144:
4138:
4128:
4127:
4125:
4121:
4115:
4112:
4111:
4109:
4105:
4099:
4093:
4091:
4088:
4086:
4079:
4077:
4071:
4069:
4063:
4061:
4058:
4056:
4053:
4052:
4050:
4046:
4040:
4034:
4033:
4031:
4027:
4021:
4008:
4006:
4003:
4001:
3995:
3993:
3987:
3985:
3975:
3973:
3966:
3964:
3961:
3960:
3958:
3954:
3950:
3943:
3938:
3936:
3931:
3929:
3924:
3923:
3920:
3904:
3901:
3898:
3896:
3889:
3883:
3881:
3875:
3873:
3867:
3865:
3859:
3857:
3850:
3844:
3842:
3836:
3834:
3827:
3821:
3819:
3812:
3806:
3804:
3797:
3791:
3789:
3783:
3781:
3775:
3772:
3771:
3768:
3761:
3755:
3753:
3746:
3740:
3738:
3732:
3730:
3724:
3722:
3716:
3714:
3708:
3706:
3700:
3698:
3691:
3685:
3683:
3676:
3670:
3668:
3662:
3660:
3653:
3647:
3645:
3639:
3637:
3631:
3629:
3623:
3620:
3619:
3612:
3608:
3605:
3602:
3599:
3596:
3593:
3590:
3587:
3584:
3581:
3578:
3575:
3572:
3569:
3566:
3563:
3560:
3558:
3552:
3550:
3547:
3546:
3542:
3540:
3537:
3535:
3528:
3522:
3520:
3514:
3512:
3506:
3504:
3501:
3499:
3492:
3482:
3480:
3473:
3470:
3468:
3461:
3455:
3453:
3439:
3433:
3431:
3424:
3418:
3416:
3410:
3408:
3401:
3395:
3393:
3387:
3385:
3379:
3377:
3371:
3368:
3366:
3360:
3358:
3355:
3354:
3351:
3345:
3343:
3336:
3333:
3331:
3327:
3320:
3313:
3311:
3307:
3303:
3297:
3295:
3288:
3282:
3280:
3273:
3270:
3268:
3262:
3260:
3257:
3255:
3249:
3247:
3241:
3239:
3233:
3231:
3224:
3218:
3216:
3209:
3202:
3196:
3194:
3188:
3186:
3179:
3172:
3164:
3162:
3156:
3154:
3152:
3146:
3144:
3141:
3140:
3136:
3134:
3128:
3126:
3119:
3113:
3111:
3104:
3100:
3094:
3092:
3085:
3079:
3077:
3071:
3069:
3063:
3061:
3054:
3051:
3049:
3042:
3036:
3034:
3028:
3026:
3019:
3013:
3011:
3005:
3003:
2996:
2989:
2983:
2981:
2974:
2968:
2966:
2959:
2952:
2946:
2944:
2938:
2936:
2933:
2927:
2925:
2922:
2921:
2917:
2915:
2912:
2910:
2903:
2893:
2891:
2887:
2880:
2873:
2867:
2865:
2859:
2857:
2850:
2847:
2845:
2839:
2837:
2834:
2833:
2829:
2827:
2820:
2813:
2810:
2808:
2797:
2786:
2779:
2772:
2770:
2766:
2762:
2754:
2747:
2741:
2739:
2735:
2729:
2727:
2720:
2714:
2712:
2706:
2704:
2701:
2700:
2696:
2690:
2688:
2685:
2684:
2678:
2673:
2665:
2660:
2658:
2653:
2651:
2646:
2645:
2642:
2630:
2620:
2619:
2617:
2615:Silver(I,III)
2613:
2607:
2597:
2595:
2589:
2587:
2577:
2576:
2574:
2570:
2564:
2554:
2552:
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2507:
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2266:
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2254:
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2238:
2236:
2226:
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2217:
2215:
2208:
2206:
2196:
2194:
2180:
2178:
2168:
2166:
2152:
2150:
2140:
2138:
2128:
2126:
2120:
2118:
2108:
2106:
2103:
2101:
2098:
2096:
2090:
2088:
2081:
2079:
2073:
2071:
2065:
2063:
2057:
2055:
2049:
2047:
2041:
2039:
2036:
2034:
2031:
2029:
2023:
2021:
2015:
2013:
2007:
2005:
2002:
2000:
1997:
1995:
1992:
1990:
1987:
1985:
1979:
1977:
1974:
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1966:
1965:
1963:
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1946:
1945:
1943:
1939:
1935:
1928:
1923:
1921:
1916:
1914:
1909:
1908:
1905:
1897:
1895:9781498754293
1891:
1887:
1883:
1882:
1876:
1875:
1872:Cited sources
1863:
1859:
1855:
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1844:
1842:
1840:
1838:
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1834:
1832:
1830:
1828:
1826:
1817:
1813:
1806:
1804:
1802:
1800:
1798:
1790:(5): 493–500.
1789:
1785:
1778:
1776:
1774:
1772:
1770:
1768:
1766:
1756:
1751:
1747:
1743:
1739:
1736:
1735:
1734:Proc. R. Soc.
1730:
1723:
1716:
1710:
1701:
1696:
1692:
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1684:
1677:
1669:
1665:
1661:
1657:
1656:Aust. J. Chem
1650:
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1448:
1445:
1444:
1438:
1435:
1425:
1404:AgX(s) + 2 Na
1403:
1402:
1401:
1399:
1394:
1392:
1388:
1383:
1379:
1377:
1360:
1359:
1358:
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1284:
1270:
1269:
1268:
1254:
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1252:
1244:
1240:
1236:
1228:
1226:
1225:Schottky pair
1222:
1218:
1209:
1208:Frenkel pairs
1197:
1187:
1185:
1179:
1165:
1162:
1161:
1157:
1154:
1153:
1149:
1146:
1145:
1141:
1138:
1137:
1133:
1130:
1129:
1126:
1121:
1119:
1109:
1106:
1093:
1090:
1089:
1085:
1081:
1078:
1074:
1073:
1070:
1064:
1060:
1057:
1054:
1051:
1050:
1046:
1043:
1040:
1037:
1036:
1032:
1029:
1026:
1023:
1022:
1018:
1015:
1012:
1009:
1008:
1005:
1000:
982:
978:
977:
976:
975:
974:
972:
961:
950:
920:
912:
908:
907:
906:
846:
842:
828:
827:
826:
824:
820:
810:
808:
804:
800:
788:
781:
776:
759:
753:
747:
744:
742:
739:
738:
736:
733:
728:
727:
721:
720:Silver iodide
718:
716:
713:
711:
708:
707:
705:
702:
697:
696:
691:
677:
674:
670:
669:
663:
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625:
621:
619:
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605:
600:
592:
588:
587:
583:
575:
567:
561:
560:
556:
548:
543:
537:
536:
533:52.4 J·mol·K
532:
527:
522:
521:Heat capacity
518:
517:
512:
508:
505:
504:Dipole moment
501:
500:
495:
491:
484:
480:
476:
475:
471:
467:
463:
462:
458:
456:
453:
452:
445:
441:
439:
435:
433:
429:
426:insoluble in
425:
424:
422:
420:
417:
416:
412:
405:
401:
397:
396:
392:
389:
385:
384:
380:
378:
377:Boiling point
375:
374:
370:
368:
367:Melting point
365:
364:
360:
358:
355:
354:
348:
345:
342:
341:
339:
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329:
326:
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318:
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288:
274:
264:
263:
260:
253:
245:
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240:DTXSID4064844
237:
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234:
224:
220:
219:
212:
208:
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188:
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185:
179:
175:
174:
167:
166:
164:
162:
157:
156:
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148:
145:
143:
141:ECHA InfoCard
138:
137:
130:
126:
125:
123:
121:
118:
117:
110:
106:
105:
103:
99:
94:
93:
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82:
81:
79:
76:
72:
71:
66:
58:
55:
53:
50:
49:
44:
38:
34:
29:
25:
20:
3258:
1975:
1879:
1856:(2): 57–62.
1853:
1849:
1815:
1811:
1787:
1783:
1737:
1732:
1722:
1714:
1709:
1690:
1686:
1676:
1659:
1655:
1649:
1630:
1626:
1616:
1605:. Retrieved
1601:
1592:
1573:
1535:. Retrieved
1531:
1522:
1513:
1504:
1495:
1486:
1431:
1423:
1395:
1391:hydroquinone
1384:
1380:
1376:latent image
1372:
1347:
1327:
1313:
1305:
1285:
1281:
1258:
1250:
1241:
1237:
1229:
1193:
1184:latent image
1180:
1176:
1124:
1115:
1107:
1103:
1068:
1003:
998:
968:
959:
948:
918:
910:
852:
843:
840:
816:
807:bromargyrite
798:
797:
650:
617:
598:
573:
546:
525:
482:
403:
68:Identifiers
52:Bromargyrite
46:Other names
2572:Silver(III)
2439:CH(OH)COOAg
1941:Silver(0,I)
1633:: 607–614.
1447:Photography
813:Preparation
645:Signal word
413:5.35 × 10
337:Appearance
322:AgBr
310:Properties
147:100.029.160
4286:Categories
2541:Silver(II)
1607:2023-01-20
1537:2023-01-20
1463:References
1215:1.16
1112:Solubility
1016:Structure
629:Pictograms
497:Structure
419:Solubility
328:Molar mass
211:NHQ37BJZ2Z
120:ChemSpider
96:3D model (
75:CAS Number
37:IUPAC name
1961:Silver(I)
1886:CRC Press
1416:(aq) → Na
1337:→ h• + Ag
1131:Compound
1118:solvation
1010:Compound
849:Reactions
620:labelling
566:formation
540:Std molar
446:solutions
168:232-076-8
160:EC Number
85:7785-23-1
56:Bromyrite
4297:Bromides
4029:Br(−I,I)
1818:: 81–96.
1441:See also
1166:0.00003
1158:0.00014
1013:Crystal
611:Hazards
468:(χ)
455:Band gap
4252:Br(VII)
4146:Br(III)
4123:Br(I,V)
3616:
2672:bromide
2330:KAg(CN)
1742:Bibcode
1385:During
1295:h• + Ag
1150:0.0019
1061:5.7745
1047:5.5491
909:AgBr +
780:what is
778: (
732:cations
651:Warning
594:(Δ
542:entropy
509:5.62 D
459:2.5 eV
444:cyanide
438:ammonia
430:, most
428:alcohol
357:Density
178:PubChem
4173:Br(IV)
4107:Br(II)
3956:Br(−I)
1892:
1580:
1299:⇌ h.Ag
1271:e + Ag
1033:4.936
775:verify
772:
730:Other
701:anions
699:Other
492:2.253
294:SMILES
31:Names
4192:Br(V)
4048:Br(I)
2350:Ag(NH
2268:AgHSO
2105:AgSCN
2100:AgOCN
2092:AgReO
2051:AgMnO
2025:AgClO
2017:AgClO
2009:AgClO
2004:AgClO
1994:AgCNO
1981:AgBrO
1353:to Ag
1155:AgBr
1147:AgCl
1142:1720
934:Ag(NH
921:− 1)
877:Ag(NH
855:Ag(NH
432:acids
259:InChI
191:66199
129:59584
98:JSmol
4228:BrOF
4073:BrNO
4055:BrCl
3989:CHBr
3892:EsBr
3885:EsBr
3877:CfBr
3869:BkBr
3861:CmBr
3853:AmBr
3846:AmBr
3838:PuBr
3830:NpBr
3823:NpBr
3800:PaBr
3793:PaBr
3785:ThBr
3777:AcBr
3764:YbBr
3757:YbBr
3749:TmBr
3742:TmBr
3734:ErBr
3726:HoBr
3718:DyBr
3710:TbBr
3702:GdBr
3694:EuBr
3687:EuBr
3679:SmBr
3672:SmBr
3664:PmBr
3656:NdBr
3649:NdBr
3641:PrBr
3633:CeBr
3625:LaBr
3554:RaBr
3549:FrBr
3539:AtBr
3531:PoBr
3524:PoBr
3516:BiBr
3508:PbBr
3503:TlBr
3495:HgBr
3476:AuBr
3472:AuBr
3464:PtBr
3457:PtBr
3443:IrBr
3435:IrBr
3427:OsBr
3420:OsBr
3412:ReBr
3389:TaBr
3381:HfBr
3373:LuBr
3362:BaBr
3357:CsBr
3347:XeBr
3323:TeBr
3299:SbBr
3291:SnBr
3284:SnBr
3276:InBr
3272:InBr
3264:CdBr
3259:AgBr
3251:PdBr
3243:RhBr
3235:RuBr
3227:TcBr
3220:TcBr
3212:MoBr
3205:MoBr
3198:MoBr
3190:NbBr
3182:ZrBr
3175:ZrBr
3167:ZrBr
3148:SrBr
3143:RbBr
3122:SeBr
3115:SeBr
3107:+AsO
3096:AsBr
3088:GeBr
3081:GeBr
3073:GaBr
3065:ZnBr
3057:CuBr
3053:CuBr
3045:NiBr
3038:NiBr
3030:CoBr
3022:FeBr
3015:FeBr
3007:MnBr
2999:CrBr
2992:CrBr
2985:CrBr
2962:TiBr
2955:TiBr
2948:TiBr
2940:ScBr
2929:CaBr
2914:BrCl
2861:SiBr
2853:AlBr
2849:AlBr
2841:MgBr
2836:NaBr
2765:NOBr
2708:BeBr
2703:LiBr
2338:RbAg
2122:AgPF
2110:AgCF
2067:AgNO
2059:AgNO
2043:AgIO
1999:AgCl
1989:AgCN
1976:AgBr
1968:AgBF
1890:ISBN
1738:A164
1578:ISBN
1333:h.Ag
1275:→ Ag
1163:AgI
1139:AgF
1055:fcc
1041:fcc
1027:fcc
1024:AgF
875:and
837:(aq)
829:AgNO
687:P501
683:P391
679:P273
665:H410
202:UNII
4267:BrO
4259:BrO
4238:BrO
4219:BrO
4199:BrF
4180:BrO
4161:BrO
4153:BrF
4114:BrO
4095:NBr
4090:BrO
4065:BrN
4060:BrF
4005:HBr
3997:CBr
3905:No
3902:Md
3899:Fm
3815:UBr
3808:UBr
3773:**
3609:Og
3606:Ts
3603:Lv
3600:Mc
3597:Fl
3594:Nh
3591:Cn
3588:Rg
3585:Ds
3582:Mt
3579:Hs
3576:Bh
3573:Sg
3570:Db
3567:Rf
3564:Lr
3561:**
3543:Rn
3404:WBr
3397:WBr
3339:IBr
3335:IBr
3330:+Te
3310:-Sb
3306:+Sb
3158:YBr
3137:Kr
3103:+As
2977:VBr
2970:VBr
2924:KBr
2918:Ar
2906:SBr
2883:PBr
2876:PBr
2869:PBr
2830:Ne
2823:BrF
2816:BrF
2812:BrF
2782:BrO
2750:BrN
2743:NBr
2731:CBr
2723:+BO
2716:BBr
2697:He
2687:HBr
2674:ion
2591:AgF
2548:AgF
2528:COO
2510:AgC
2489:NSO
2477:AgC
2463:AgO
2419:AgC
2403:AgC
2310:AsO
2289:SeO
2202:MoO
2174:CrO
2075:AgN
2038:AgI
2033:AgF
1858:doi
1750:doi
1695:doi
1664:doi
1635:doi
1378:".
917:+ (
618:GHS
577:298
550:298
228:EPA
181:CID
4288::
4207:Br
4130:Br
4081:Br
4036:Br
4019:Br
3981:Br
3977:CH
3972:Br
3968:CH
3963:Br
3621:*
3488:Br
3484:Hg
3369:*
3319:Br
3315:Te
3130:Br
2899:Br
2890:+P
2800:Br
2789:Br
2774:Br
2769:+N
2761:Br
2757:NH
2738:+C
2622:Ag
2599:Ag
2579:Ag
2524:23
2515:11
2501:NH
2459:36
2450:18
2435:CH
2425:43
2421:22
2383:WO
2379:Ag
2363:Ag
2358:OH
2322:PO
2318:Ag
2306:Ag
2301:Te
2297:Ag
2285:Ag
2280:Se
2276:Ag
2260:SO
2256:Ag
2240:Ag
2232:SO
2228:Ag
2219:Ag
2210:Ag
2198:Ag
2186:Cr
2182:Ag
2170:Ag
2154:Ag
2142:Ag
2134:CO
2130:Ag
2114:SO
2083:Ag
1948:Ag
1888:.
1854:16
1852:.
1824:^
1816:18
1814:.
1796:^
1788:18
1786:.
1764:^
1748:.
1731:.
1689:.
1685:.
1660:40
1658:.
1631:15
1629:.
1625:.
1600:.
1546:^
1530:.
1470:^
1349:Ag
1291::
1267::
1217:eV
1186:.
954:Br
932:→
923:Br
913:NH
895:Br
873:Br
825::
809:.
685:,
681:,
622::
569:(Δ
409:)
407:sp
301:Br
4271:F
4269:3
4261:4
4242:F
4240:2
4230:3
4221:3
4213:5
4211:O
4209:2
4201:5
4182:2
4163:2
4155:3
4136:3
4134:O
4132:2
4097:3
4085:O
4083:2
4075:3
4067:3
4038:3
4017:5
4015:H
4013:3
4011:C
3999:4
3991:3
3983:2
3979:2
3970:3
3941:e
3934:t
3927:v
3894:3
3887:2
3879:3
3871:3
3863:3
3855:3
3848:2
3840:3
3832:4
3825:3
3817:5
3810:4
3802:5
3795:4
3787:4
3779:3
3766:3
3759:2
3751:3
3744:2
3736:3
3728:3
3720:3
3712:3
3704:3
3696:3
3689:2
3681:3
3674:2
3666:3
3658:3
3651:2
3643:3
3635:3
3627:3
3556:2
3533:4
3526:2
3518:3
3510:2
3497:2
3490:2
3486:2
3478:3
3466:4
3459:2
3448:4
3437:3
3429:4
3422:3
3414:3
3406:6
3399:5
3391:5
3383:4
3375:3
3364:2
3349:2
3341:3
3325:4
3317:2
3301:3
3293:4
3286:2
3278:3
3266:2
3253:2
3245:3
3237:3
3229:4
3222:3
3214:4
3207:3
3200:2
3192:5
3184:4
3177:3
3169:2
3160:3
3150:2
3132:2
3124:4
3117:2
3109:3
3098:3
3090:4
3083:2
3075:3
3067:2
3059:2
3047:4
3040:2
3032:2
3024:3
3017:2
3009:2
3001:4
2994:3
2987:2
2979:3
2972:2
2964:4
2957:3
2950:2
2942:3
2931:2
2908:2
2901:2
2897:2
2895:S
2885:7
2878:5
2871:3
2863:4
2855:3
2843:2
2825:5
2818:3
2806:5
2804:O
2802:2
2795:3
2793:O
2791:2
2784:2
2778:O
2776:2
2759:4
2752:3
2745:3
2733:4
2725:3
2718:3
2710:2
2663:e
2656:t
2649:v
2628:4
2626:O
2624:4
2605:3
2603:S
2601:2
2593:3
2585:3
2583:O
2581:2
2562:8
2560:O
2558:2
2556:S
2550:2
2519:H
2503:2
2499:4
2497:H
2495:6
2493:C
2491:2
2487:2
2485:N
2483:3
2481:H
2479:4
2468:2
2454:H
2445:C
2437:3
2429:2
2427:O
2423:H
2413:2
2411:O
2409:3
2407:H
2405:2
2385:4
2381:2
2373:2
2371:O
2369:2
2367:N
2365:2
2356:2
2354:)
2352:3
2344:5
2342:I
2340:4
2332:2
2324:4
2320:3
2312:4
2308:3
2299:2
2291:3
2287:2
2278:2
2270:4
2262:4
2258:2
2250:3
2248:O
2246:2
2244:S
2242:2
2234:3
2230:2
2223:S
2221:2
2214:O
2212:2
2204:4
2200:2
2192:7
2190:O
2188:2
2184:2
2176:4
2172:2
2164:4
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960:n
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939:3
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