2867:
2589:
622:
648:
585:
674:
77:
5600:
3340:
2577:
87:
64:
2448:
982:
422:
2198:
3351:
2816:
estimated world reserves at 71 billion tons, while 0.19 billion tons were mined globally in 2011. Phosphorus comprises 0.1% by mass of the average rock (while, for perspective, its typical concentration in vegetation is 0.03% to 0.2%), and consequently there are quadrillions of tons of phosphorus in
3374:
environments, whereas nitrogen is more often the limiting nutrient in marine (seawater) environments. Addition of high levels of phosphate to environments and to micro-environments in which it is typically rare can have significant ecological consequences. For example, blooms in the populations of
2551:
in the general population. The most common cause of hyperphosphatemia in people, dogs, and cats is kidney failure. In cases of hyperphosphatemia, limiting consumption of phosphate-rich foods, such as some meats and dairy items and foods with a high phosphate-to-protein ratio, such as soft drinks,
2421:
in the urinary tract, some phosphates are used. For patients who are unable to get enough phosphorus in their daily diet, phosphates are used as dietary supplements, usually because of certain disorders or diseases. Injectable phosphates can only be handled by qualified health care providers.
1903:
2821:
are mainly hydroxyapatite and fluoroapatite, phosphate minerals contain roughly 18.5% phosphorus by weight. If phosphate rock contains around 20% of these minerals, the average phosphate rock has roughly 3.7% phosphorus by weight.
3429:. Unless carefully managed, these waste products can leach heavy metals into groundwater or nearby estuaries. Uptake of these substances by plants and marine life can lead to concentration of toxic heavy metals in food products.
4359:
Gnandi, K.; Tchangbedjil, G.; Killil, K.; Babal, G.; Abbel, E. (March 2006). "The Impact of
Phosphate Mine Tailings on the Bioaccumulation of Heavy Metals in Marine Fish and Crustaceans from the Coastal Zone of Togo".
3833:
Kipton J. Powell, Paul L. Brown, Robert H. Byrne, Tamás Gajda, Glenn Hefter, Staffan Sjöberg, Hans Wanner (2005): "Chemical speciation of environmentally significant heavy metals with inorganic ligands. Part 1: The
2829:
in
Florida, are notable for their inclusion of significant quantities of radioactive uranium isotopes. This is a concern because radioactivity can be released into surface waters from application of the resulting
2811:
from
Institute for Sustainable Futures said that at "current rates, reserves will be depleted in the next 50 to 100 years". Reserves refer to the amount assumed recoverable at current market prices. In 2012 the
972:
are all water-soluble. Most other phosphates are only slightly soluble or are insoluble in water. As a rule, the hydrogen and dihydrogen phosphates are slightly more soluble than the corresponding phosphates.
1908:
1553:
1384:
1201:
2817:
Earth's 3×10-ton crust, albeit at predominantly lower concentration than the deposits counted as reserves, which are inventoried and cheaper to extract. If it is assumed that the phosphate minerals in
4173:
4316:
Schmittner KE, Giresse P (1999). "Micro-environmental controls on biomineralization: superficial processes of apatite and calcite precipitation in
Quaternary soils, Roussillon, France".
2663:, which used to have massive phosphate deposits of the best quality, have been mined excessively. Rock phosphate can also be found in Egypt, Israel, Palestine, Western Sahara,
4238:
4301:
ioavailable phosphorus – phosphorus that can be utilized by plants and bacteria – is only a fraction of the total, according to
Michael Brett, a UW engineering professor ...
5268:
5379:
5371:
5316:
5212:
4224:
5056:
4735:
3366:
In ecological terms, because of its important role in biological systems, phosphate is a highly sought after resource. Once used, it is often a limiting nutrient in
5308:
5292:
5276:
2193:{\displaystyle {\begin{aligned}{\frac {}{}}&\approx 7.5\times 10^{4}\\{\frac {}{}}&\approx 0.62\\{\frac {}{}}&\approx 2.14\times 10^{-6}\end{aligned}}}
5387:
5300:
5220:
5096:
4988:
4900:
3394:
topsoil. As clay minerals promote biomineralization, the presence of bacteria and clay minerals resulted in calcium hydroxyapatite and calcite precipitates.
1655:
This means that salts of the mono- and di-phosphate ions can be selectively crystallised from aqueous solution by setting the pH value to either 4.7 or 9.8.
4888:
4724:
5337:
5025:
4972:
4492:
3907:
5037:
435:
2803:
In 2007, at the current rate of consumption, the supply of phosphorus was estimated to run out in 345 years. However, some scientists thought that a "
2377:
An important occurrence of phosphates in biological systems is as the structural material of bone and teeth. These structures are made of crystalline
4181:
4149:
5539:
992:
In water solution, orthophosphoric acid and its three derived anions coexist according to the dissociation and recombination equilibria below
5444:
339:
2866:
177:
4288:
4041:
3780:
2874:
The three principal phosphate producer countries (China, Morocco and the United States) account for about 70% of world production.
1425:
1246:
1055:
2683:
4145:
169:
4440:
4412:
3383:, a major indicator of water quality, but not all phosphorus is in a molecular form that algae can break down and consume.
17:
2512:
76:
4409:
provides data graphics covering consumption, production, imports, exports and price for phosphate and 86 other minerals
4059:
2484:
1594:. At pH 1 or lower, the phosphoric acid is practically undissociated. Around pH 4.7 (mid-way between the first two p
4406:
3818:
3397:
Phosphate deposits can contain significant amounts of naturally occurring heavy metals. Mining operations processing
2531:
957:
430:
314:
5649:
5437:
3375:
some organisms at the expense of others, and the collapse of populations deprived of resources such as oxygen (see
2608:. In mineralogy and geology, phosphate refers to a rock or ore containing phosphate ions. Inorganic phosphates are
4203:
442:
2813:
2491:
795:
479:
35:
621:
3751:
2469:
673:
5629:
647:
584:
571:
2552:
fast food, processed foods, condiments, and other products containing phosphate-salt additives is advised.
1632:, is the only species present. At pH 13 or higher, the acid is completely dissociated as the phosphate ion,
86:
63:
5644:
5639:
3570:
2588:
2498:
291:
3932:
5430:
5228:
2858:
The largest importers in millions of metric tons of phosphate are Brazil 3.2, India 2.9 and the USA 1.6.
258:
4256:
5624:
4112:
2852:
Around 2018, Norway discovered phosphate deposits almost equal to those in the rest of Earth combined.
2465:
2480:
5284:
5244:
3802:
3367:
2656:
5236:
4766:
4433:
252:
4270:
3358:
in various regions of the ocean. Note that nitrate is more often limiting than phosphate. See the
2849:
of 531 million tons, making it the largest measured and indicated phosphate deposit in the world.
5329:
5260:
5252:
4999:
4751:
4743:
4694:
4128:
3946:
Ritz, Eberhard; Hahn, Kai; Ketteler, Markus; Kuhlmann, Martin K.; Mann, Johannes (January 2012).
3718:
2458:
2414:
2366:
2318:
1613:, is practically the only species present. Around pH 9.8 (mid-way between the second and third p
4074:
4918:
4672:
4622:
4555:
4474:
4070:
3908:"Phosphate Supplement (Oral Route, Parenteral Route) Description and Brand Names - Mayo Clinic"
3380:
2560:
2431:
2362:
2326:
1900:(pH = 7.0), the concentrations of the orthophoshoric acid and its three anions have the ratios
663:
404:
4683:
4154:
3370:, and its availability may govern the rate of growth of organisms. This is generally true of
2846:
2831:
2826:
2354:
2322:
836:
106:
5356:
4829:
4813:
4797:
4706:
4610:
4540:
4477:
4369:
4325:
4014:
3536:
3439:
2648:
637:
300:
144:
229:
8:
5634:
5085:
5006:
4926:
4789:
4638:
4588:
4426:
4174:"Updated Hinda Resource Announcement: Now world's largest phosphate deposit (04/12/2012)"
3772:
3565:
2628:
2581:
1782:
969:
788:
768:
734:
575:
134:
4373:
4329:
4018:
209:
30:
This article is about the orthophosphate ion. For the organophosphorus derivatives, see
5108:
4774:
4599:
4578:
4525:
4385:
4341:
3980:
3947:
3555:
3456:
2505:
189:
4026:
5549:
5461:
5453:
5124:
4861:
4652:
4389:
4345:
4337:
4177:
3985:
3967:
3814:
3810:
3344:
2838:
2605:
2544:
2378:
2346:
1847:
819:
701:
4116:
2667:, Tunisia, Togo, and Jordan, countries that have large phosphate-mining industries.
2413:
Phosphates are medicinal salts of phosphorus. Some phosphates, which help cure many
783:
in such esters. Phosphates may contain sulfur in place of one or more oxygen atoms (
4960:
4570:
4514:
4377:
4333:
4022:
3975:
3959:
3886:
3549:
2338:
730:
471:
467:
367:
5604:
5580:
5572:
4875:
4507:
4463:
4159:
3651:
3599:
2804:
2559:, and a high concentration of phosphates in blood was found to be a predictor of
2386:
2382:
2342:
1855:
921:
815:
803:
713:
611:
494:
280:
241:
31:
4092:
5504:
5494:
4845:
3575:
3398:
3376:
3359:
3355:
3105:
2818:
2688:
2664:
2652:
2636:
2548:
1591:
986:
868:
832:
823:
413:
399:
42:
4381:
4225:"'Great news': EU hails discovery of massive phosphate rock deposit in Norway"
3963:
5618:
5499:
5469:
4659:
4005:
3971:
3684:
3656:
3626:
3508:
3474:
3265:
2797:
2660:
2556:
2418:
2390:
2266:
1815:
1749:
840:
784:
3890:
5489:
5479:
3989:
3339:
3185:
3153:
2808:
2742:
1818:
ions (which are usually long linear polymers) have an empirical formula of
799:
3379:) can occur. In the context of pollution, phosphates are one component of
2576:
5562:
3641:
3631:
3608:
3581:
2670:
2620:
1869:
864:
811:
46:
4239:"China issues phosphate quotas to rein in fertiliser exports - analysts"
2593:
5519:
5484:
3469:
3371:
3249:
3069:
2776:
2733:
2601:
2358:
2350:
2314:
2280:
2242:). In extracellular fluid (pH = 7.4), this proportion is inverted (61%
1590:
values where the concentration of each species is equal to that of its
949:
856:
852:
826:
487:
389:
220:
50:
4289:"Limited amount of total phosphorus actually feeds algae, study finds"
4042:"Scientists warn of lack of vital phosphorus as biofuels raise demand"
2878:
Production and global reserves of natural phosphate by country in 2019
2337:. Free orthophosphate anions can be released by the hydrolysis of the
891:, which in turn is the conjugate base of the dihydrogen phosphate ion
5585:
5557:
5529:
5524:
5474:
5422:
3617:
3590:
3350:
2925:
2785:
2696:
2644:
1729:
455:
27:
Anion, salt, functional group or ester derived from a phosphoric acid
4133:. Vol. 2. United States. Environmental Protection Agency. 1979.
3386:
Calcium hydroxyapatite and calcite precipitates can be found around
2447:
2361:
in muscle tissue. Similar reactions exist for the other nucleoside
412:
Except where otherwise noted, data are given for materials in their
5534:
5514:
5509:
4415:– The Association for Clinical Biochemistry and Laboratory Medicine
3422:
3402:
3391:
3387:
2547:, or a high blood level of phosphates, is associated with elevated
2402:
2398:
2394:
961:
4130:
Central
Florida Phosphate Industry: Environmental Impact Statement
2417:, are used to make urine more acidic. To avoid the development of
2349:
reactions are the immediate storage and source of energy for many
176:
168:
3426:
3406:
3281:
3233:
3169:
3101:
2989:
2909:
2789:
2766:
2729:
2721:
2709:
2705:
2640:
2624:
2616:
1897:
1745:
965:
807:
267:
3936:, Oxford University Hospitals NHS Foundation Trust, 2022 review
1850:, phosphorus can be found as free phosphate anions in solution (
3418:
3414:
3137:
3085:
3053:
3037:
2941:
2750:
2746:
2609:
2313:
Organic phosphates are commonly found in the form of esters as
981:
860:
570:. These names are also used for salts of those anions, such as
529:
2855:
In July 2022 China announced quotas on phosphate exportation.
1548:{\displaystyle K_{a3}={\frac {}{}}\approx 2.14\times 10^{-13}}
4418:
4358:
3201:
3005:
2973:
2957:
2793:
2754:
2717:
2713:
2692:
2632:
953:
814:
and industry. The addition and removal of phosphate groups (
475:
463:
200:
157:
2222:
ions are present in significant amounts in the cytosol (62%
1379:{\displaystyle K_{a2}={\frac {}{}}\approx 6.2\times 10^{-8}}
1196:{\displaystyle K_{a1}={\frac {}{}}\approx 7.5\times 10^{-3}}
3410:
3217:
3121:
3021:
2842:
2762:
2758:
2725:
2687:
United States, especially
Florida, with lesser deposits in
2600:
Phosphates are the naturally occurring form of the element
794:
Orthophosphates are especially important among the various
4003:
Reilly, Michael (May 26, 2007). "How Long Will it Last?".
2615:
The largest global producer and exporter of phosphates is
2612:
to obtain phosphorus for use in agriculture and industry.
2334:
2330:
2061:
1979:
1966:
1928:
1329:
1161:
1148:
1110:
4315:
3945:
2619:. Within North America, the largest deposits lie in the
2430:
Plants take up phosphorus through several pathways: the
528:
is derived from phosphoric acid by the removal of three
2408:
1873:
1587:
4148:. In Mark McGinley and C. Cleveland (Washington, DC.:
3801:
1906:
1428:
1249:
1058:
3758:. USA: National Center of Biotechnology Information.
4121:
3777:
Florida
Industrial and Phosphate Research Institute
2472:. Unsourced material may be challenged and removed.
2192:
1547:
1378:
1195:
3767:
3765:
729:where one or more hydrogen atoms are replaced by
5616:
4257:"Top countries for Phosphate Fertilizer Imports"
4150:National Council for Science and the Environment
4143:
3354:Relationship of phosphate to nitrate uptake for
2353:processes. ATP and ADP are often referred to as
279:
3809:(Seventh ed.). San Francisco, California:
3752:"Phosphates – PubChem Public Chemical Database"
855:of 94.97 g/mol, and consists of a central
716:, an ester of orthophosphoric acid of the form
143:
3762:
5438:
4434:
4311:
4309:
4117:Mass and Composition of the Continental Crust
2845:compliant resource of their Hinda project in
1841:
3948:"Phosphate additives in food--a health risk"
2265:Inorganic phosphate can also be present as
1854:) or bound to organic molecules as various
323:InChI=1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)/p-3
5445:
5431:
4441:
4427:
4306:
4286:
4115:, Fall Meeting 2007, abstract #V33A-1161.
228:
80:Aromatic ball and stick model of phosphate
4090:
4039:
3979:
2532:Learn how and when to remove this message
2437:
1861:Inorganic phosphate is generally denoted
976:
920:, which in turn is the conjugate base of
299:
4204:"EU pins hope on Norway's raw materials"
3349:
3338:
2865:
2587:
2575:
2571:
1622:values) the monohydrogen phosphate ion,
980:
4201:
2434:pathway and the direct uptake pathway.
556:while removal of two protons gives the
257:
14:
5617:
5452:
4482:
4287:Hochanadel, Dave (December 10, 2010).
4002:
3827:
2825:Some phosphate rock deposits, such as
1603:values) the dihydrogen phosphate ion,
846:
5426:
5201:
4422:
3885:, volume 77, issue 4, pages 739–800.
2684:Phosphate mining in the United States
491:
326:Key: NBIIXXVUZAFLBC-UHFFFAOYSA-K
208:
4202:Bushuev, Mikhail (26 January 2021).
4033:
3902:
3900:
3898:
3405:piles containing elevated levels of
2470:adding citations to reliable sources
2441:
2409:Medical and biological research uses
2397:calcium phosphate where some of the
810:, and their economic importance for
3783:from the original on 29 August 2017
2425:
1876:primarily consists of a mixture of
542:. Removal of one proton gives the
270:
24:
3952:Deutsches Ärzteblatt International
3779:. Florida Polytechnic University.
2639:. Smaller deposits are located in
2592:Train loaded with phosphate rock,
2372:
85:
75:
25:
5661:
4400:
3939:
3895:
2870:Phosphate imports/exports in 1937
1896:ions. At a neutral pH, as in the
1838:and are found in many compounds.
958:standard temperature and pressure
5598:
4338:10.1046/j.1365-3091.1999.00224.x
2446:
672:
646:
620:
583:
420:
90:Space-filling model of phosphate
62:
4352:
4280:
4263:
4249:
4231:
4217:
4195:
4166:
4137:
4106:
4084:
4064:
4052:
3933:Reducing phosphate in your diet
3343:Sea surface phosphate from the
2457:needs additional citations for
2279:, which give orthophosphate by
767:. The term also refers to the
416:(at 25 °C , 100 kPa).
36:phosphoric acids and phosphates
4448:
4362:Mine Water and the Environment
3996:
3924:
3795:
3744:
2807:" would occur in 30 years and
2673:mines are primarily found in:
2154:
2131:
2126:
2103:
2080:
2047:
2042:
2019:
1983:
1952:
1947:
1914:
1517:
1494:
1489:
1466:
1463:
1448:
1348:
1315:
1310:
1287:
1284:
1269:
1165:
1134:
1129:
1096:
1093:
1078:
871:of the hydrogen phosphate ion
798:because of their key roles in
347:hypervalent form: P()()=O
13:
1:
4027:10.1016/S0262-4079(07)61508-5
3737:
2655:. The small island nation of
2566:
2401:groups have been replaced by
572:ammonium dihydrogen phosphate
4413:Phosphate: analyte monograph
3571:Phosphate conversion coating
2769:, near the Jordanian border.
34:. For other phosphates, see
7:
3432:
3325:
3320:
3315:
3305:
3302:
3299:
3291:
3288:
3285:
3275:
3272:
3269:
3259:
3256:
3253:
3243:
3240:
3237:
3227:
3224:
3221:
3211:
3208:
3205:
3195:
3192:
3189:
3179:
3176:
3173:
3163:
3160:
3157:
3147:
3144:
3141:
3131:
3128:
3125:
3115:
3112:
3109:
3095:
3092:
3089:
3079:
3076:
3073:
3063:
3060:
3057:
3047:
3044:
3041:
3031:
3028:
3025:
3015:
3012:
3009:
2999:
2996:
2993:
2983:
2980:
2977:
2967:
2964:
2961:
2951:
2948:
2945:
2935:
2932:
2929:
2919:
2916:
2913:
2555:Phosphates induce vascular
2385:. The hard dense enamel of
2341:bonds in ATP or ADP. These
394:94.9714 g mol
71:
10:
5666:
5203:
4113:American Geophysical Union
3883:Pure and Applied Chemistry
3578:, a soda fountain beverage
3334:
2681:
1842:Biochemistry of phosphates
482:. It most commonly means
40:
29:
5594:
5571:
5548:
5460:
4484:
4456:
4382:10.1007/s10230-006-0108-4
4144:C. Michael Hogan (2010).
4075:"Phosphorus Soil Samples"
3964:10.3238/arztebl.2012.0049
3805:; Reece, Jane B. (2005).
2861:
1574:°C and 0 ionic strength.
960:. The sodium, potassium,
490:of orthophosphoric acid,
410:
360:
335:
310:
127:
115:
105:
100:
70:
61:
4040:Leo Lewis (2008-06-23).
2415:urinary tract infections
1744:Phosphate can form many
1732:because the successive p
859:atom surrounded by four
851:The phosphate ion has a
41:Not to be confused with
5650:Phosphorus(V) compounds
4407:US Minerals Databrowser
4093:"Abundance of Elements"
4058:U.S. Geological Survey
3891:10.1351/pac200577040739
3719:Sodium tripolyphosphate
2631:region of southeastern
1741:differ by more than 4.
867:arrangement. It is the
167:hypervalent form:
4271:"PHOSPHATE ROCK, usgs"
4071:U.S. Geological Survey
3930:Renal Dietitian Team,
3381:total dissolved solids
3363:
3347:
2871:
2597:
2585:
2438:Adverse health effects
2432:arbuscular mycorrhizal
2355:high-energy phosphates
2194:
1868:and at physiological (
1549:
1380:
1197:
1001:Dissociation constant
989:
977:Equilibria in solution
733:groups. An example is
405:Monohydrogen phosphate
122:Tetraoxidophosphate(V)
91:
81:
4155:Encyclopedia of Earth
3353:
3342:
2869:
2841:announced an updated
2591:
2579:
2572:Geological occurrence
2561:cardiovascular events
2195:
1550:
1381:
1198:
984:
352:ionic form: ()()
89:
79:
5630:Phosphorus oxyanions
3537:Monosodium phosphate
3440:Diammonium phosphate
2832:phosphate fertilizer
2580:Phosphate mine near
2466:improve this article
1904:
1426:
1247:
1056:
948:Many phosphates are
922:orthophosphoric acid
789:organothiophosphates
544:dihydrogen phosphate
120:Tetraoxophosphate(V)
5645:Concrete admixtures
5640:Industrial minerals
5605:Minerals portal
4374:2006MWE....25...56G
4330:1999Sedim..46..463S
4095:. Seafriends.org.nz
4019:2007NewSc.194...38R
3756:The PubChem Project
3566:triphenyl phosphate
2883:
2635:, and the coast of
2582:Flaming Gorge, Utah
2152:
2124:
2078:
2063:
2040:
1981:
1968:
1945:
1930:
1852:inorganic phosphate
1728:behave as separate
1564: = 12.37
1515:
1487:
1346:
1331:
1308:
1163:
1150:
1127:
1112:
970:ammonium phosphates
847:Chemical properties
822:) are key steps in
735:trimethyl phosphate
576:trisodium phosphate
190:Beilstein Reference
58:
18:Inorganic phosphate
5454:Phosphate minerals
3912:www.mayoclinic.org
3881:aqueous systems".
3773:"Phosphate Primer"
3560:Phosphate – OP(OR)
3556:Ouled Abdoun Basin
3457:Disodium phosphate
3364:
3348:
2877:
2872:
2837:In December 2012,
2623:region of central
2606:phosphate minerals
2598:
2586:
2190:
2188:
2135:
2107:
2064:
2051:
2023:
1969:
1956:
1931:
1918:
1848:biological systems
1545:
1498:
1470:
1395: = 7.20
1376:
1332:
1319:
1291:
1212: = 2.14
1193:
1151:
1138:
1113:
1100:
990:
558:hydrogen phosphate
443:Infobox references
92:
82:
56:
5625:Functional groups
5612:
5611:
5550:Cryptocrystalline
5420:
5419:
5414:
5413:
4178:Cominco Resources
4146:"Water pollution"
3811:Benjamin Cummings
3803:Campbell, Neil A.
3345:World Ocean Atlas
3332:
3331:
2882:
2847:Congo-Brazzaville
2839:Cominco Resources
2765:, at the town of
2659:and its neighbor
2545:Hyperphosphatemia
2542:
2541:
2534:
2516:
2379:calcium phosphate
2347:dephosphorylation
2158:
2138:
2110:
2084:
2067:
2054:
2026:
1987:
1972:
1959:
1934:
1921:
1568:
1567:
1521:
1501:
1473:
1455:
1352:
1335:
1322:
1294:
1276:
1169:
1154:
1141:
1116:
1103:
1085:
820:dephosphorylation
771:functional group
702:organic chemistry
451:Chemical compound
449:
448:
178:Interactive image
175:ionic form:
170:Interactive image
96:
95:
16:(Redirected from
5657:
5603:
5602:
5601:
5447:
5440:
5433:
5424:
5423:
4460:
4459:
4443:
4436:
4429:
4420:
4419:
4394:
4393:
4356:
4350:
4349:
4313:
4304:
4303:
4298:
4296:
4291:. Lake Scientist
4284:
4278:
4277:
4275:
4267:
4261:
4260:
4253:
4247:
4246:
4235:
4229:
4228:
4221:
4215:
4214:
4212:
4210:
4199:
4193:
4192:
4190:
4189:
4180:. Archived from
4170:
4164:
4163:
4158:. Archived from
4141:
4135:
4134:
4125:
4119:
4110:
4104:
4103:
4101:
4100:
4088:
4082:
4081:
4079:
4068:
4062:
4056:
4050:
4049:
4037:
4031:
4030:
4000:
3994:
3993:
3983:
3943:
3937:
3928:
3922:
3921:
3919:
3918:
3904:
3893:
3880:
3879:
3878:
3868:
3867:
3866:
3856:
3855:
3854:
3844:
3843:
3842:
3831:
3825:
3824:
3799:
3793:
3792:
3790:
3788:
3769:
3760:
3759:
3748:
3715:
3714:
3713:
3706:
3705:
3697:
3696:
3681:
3680:
3679:
3669:
3668:
3550:Organophosphorus
3533:
3532:
3531:
3521:
3520:
3505:
3504:
3503:
3496:
3495:
3487:
3486:
2884:
2880:
2876:
2604:, found in many
2537:
2530:
2526:
2523:
2517:
2515:
2474:
2450:
2442:
2426:Plant metabolism
2339:phosphoanhydride
2309:
2308:
2307:
2295:
2294:
2293:
2278:
2277:
2276:
2261:
2260:
2259:
2251:
2250:
2249:
2241:
2240:
2239:
2231:
2230:
2229:
2221:
2220:
2219:
2211:
2210:
2209:
2199:
2197:
2196:
2191:
2189:
2185:
2184:
2159:
2157:
2153:
2151:
2143:
2136:
2129:
2125:
2123:
2115:
2108:
2101:
2085:
2083:
2079:
2077:
2072:
2065:
2062:
2059:
2052:
2045:
2041:
2039:
2031:
2024:
2017:
2011:
2010:
1988:
1986:
1982:
1980:
1977:
1970:
1967:
1964:
1957:
1950:
1946:
1944:
1939:
1932:
1929:
1926:
1919:
1912:
1895:
1894:
1893:
1885:
1884:
1883:
1856:organophosphates
1837:
1836:
1835:
1828:
1827:
1813:
1812:
1811:
1804:
1803:
1795:
1794:
1780:
1779:
1778:
1771:
1770:
1762:
1761:
1727:
1726:
1725:
1718:
1717:
1707:
1706:
1705:
1698:
1697:
1689:
1688:
1678:
1677:
1676:
1668:
1667:
1651:
1650:
1649:
1642:
1641:
1631:
1630:
1629:
1612:
1611:
1610:
1573:
1570:Values are at 25
1554:
1552:
1551:
1546:
1544:
1543:
1522:
1520:
1516:
1514:
1506:
1499:
1492:
1488:
1486:
1478:
1471:
1462:
1461:
1460:
1453:
1446:
1441:
1440:
1420:
1418:
1417:
1414:
1409:
1408:
1405:
1385:
1383:
1382:
1377:
1375:
1374:
1353:
1351:
1347:
1345:
1340:
1333:
1330:
1327:
1320:
1313:
1309:
1307:
1299:
1292:
1283:
1282:
1281:
1274:
1267:
1262:
1261:
1241:
1239:
1238:
1235:
1230:
1229:
1226:
1202:
1200:
1199:
1194:
1192:
1191:
1170:
1168:
1164:
1162:
1159:
1152:
1149:
1146:
1139:
1132:
1128:
1126:
1121:
1114:
1111:
1108:
1101:
1092:
1091:
1090:
1083:
1076:
1071:
1070:
1050:
1048:
1047:
1044:
995:
994:
985:Phosphoric acid
944:
943:
942:
934:
933:
919:
918:
917:
910:
909:
901:
900:
890:
889:
888:
881:
880:
782:
781:
780:
766:
765:
764:
756:
755:
747:
746:
728:
726:
725:
687:
686:
685:
676:
661:
660:
659:
650:
635:
634:
633:
624:
609:
608:
607:
599:
598:
587:
569:
568:
567:
555:
554:
553:
541:
540:
539:
527:
526:
525:
506:
493:
472:functional group
433:
427:
424:
423:
383:
382:
381:
368:Chemical formula
303:
283:
272:
261:
242:Gmelin Reference
232:
212:
180:
172:
147:
72:
66:
59:
55:
21:
5665:
5664:
5660:
5659:
5658:
5656:
5655:
5654:
5615:
5614:
5613:
5608:
5599:
5597:
5590:
5581:Santabarbaraite
5567:
5544:
5456:
5451:
5421:
5416:
5415:
5391:
5383:
5375:
5364:
5360:
5349:
5345:
5341:
5333:
5320:
5312:
5304:
5296:
5288:
5280:
5272:
5264:
5256:
5248:
5240:
5232:
5224:
5216:
5128:
5120:
5116:
5112:
5104:
5100:
5089:
5060:
5049:
5045:
5041:
5033:
5029:
5010:
5005:
5003:
4992:
4984:
4980:
4976:
4968:
4964:
4938:
4934:
4930:
4922:
4912:
4908:
4904:
4896:
4892:
4865:
4857:
4853:
4849:
4841:
4837:
4833:
4825:
4821:
4817:
4809:
4805:
4801:
4793:
4788:
4786:
4782:
4778:
4770:
4765:
4763:
4759:
4755:
4747:
4739:
4728:
4718:
4714:
4710:
4702:
4698:
4693:
4691:
4687:
4682:
4680:
4676:
4658:
4656:
4642:
4634:
4630:
4626:
4618:
4614:
4609:
4607:
4603:
4598:
4596:
4592:
4569:
4567:
4563:
4559:
4554:
4552:
4548:
4544:
4539:
4537:
4533:
4529:
4518:
4513:
4511:
4500:
4496:
4476:
4473:
4471:
4467:
4452:
4447:
4403:
4398:
4397:
4357:
4353:
4314:
4307:
4294:
4292:
4285:
4281:
4273:
4269:
4268:
4264:
4255:
4254:
4250:
4245:. 15 July 2022.
4237:
4236:
4232:
4227:. 29 June 2023.
4223:
4222:
4218:
4208:
4206:
4200:
4196:
4187:
4185:
4172:
4171:
4167:
4142:
4138:
4127:
4126:
4122:
4111:
4107:
4098:
4096:
4091:Floor Anthoni.
4089:
4085:
4077:
4073:
4069:
4065:
4057:
4053:
4038:
4034:
4001:
3997:
3944:
3940:
3929:
3925:
3916:
3914:
3906:
3905:
3896:
3877:
3874:
3873:
3872:
3870:
3865:
3862:
3861:
3860:
3858:
3853:
3850:
3849:
3848:
3846:
3841:
3839:
3838:
3837:
3835:
3832:
3828:
3821:
3800:
3796:
3786:
3784:
3771:
3770:
3763:
3750:
3749:
3745:
3740:
3735:
3732:
3728:
3724:
3712:
3710:
3709:
3708:
3704:
3701:
3700:
3699:
3695:
3692:
3691:
3690:
3688:
3678:
3673:
3672:
3671:
3667:
3664:
3663:
3662:
3660:
3652:Phosphorylation
3647:
3637:
3623:
3614:
3605:
3600:Phosphine oxide
3596:
3587:
3563:
3546:
3542:
3530:
3525:
3524:
3523:
3519:
3516:
3515:
3514:
3512:
3502:
3500:
3499:
3498:
3494:
3491:
3490:
3489:
3485:
3482:
3481:
3480:
3478:
3466:
3462:
3453:
3449:
3445:
3435:
3337:
3297:Other countries
2903:
2898:
2896:
2891:
2879:
2864:
2805:peak phosphorus
2686:
2596:, Tunisia, 2012
2574:
2569:
2538:
2527:
2521:
2518:
2475:
2473:
2463:
2451:
2440:
2428:
2411:
2387:mammalian teeth
2381:in the form of
2375:
2373:Bones and teeth
2343:phosphorylation
2306:
2304:
2303:
2302:
2301:
2299:
2292:
2290:
2289:
2288:
2287:
2275:
2273:
2272:
2271:
2270:
2258:
2256:
2255:
2254:
2253:
2248:
2246:
2245:
2244:
2243:
2238:
2236:
2235:
2234:
2233:
2228:
2226:
2225:
2224:
2223:
2218:
2216:
2215:
2214:
2213:
2208:
2206:
2205:
2204:
2203:
2187:
2186:
2177:
2173:
2160:
2144:
2139:
2134:
2130:
2116:
2111:
2106:
2102:
2100:
2097:
2096:
2086:
2073:
2068:
2060:
2055:
2050:
2046:
2032:
2027:
2022:
2018:
2016:
2013:
2012:
2006:
2002:
1989:
1978:
1973:
1965:
1960:
1955:
1951:
1940:
1935:
1927:
1922:
1917:
1913:
1911:
1907:
1905:
1902:
1901:
1892:
1890:
1889:
1888:
1887:
1882:
1880:
1879:
1878:
1877:
1866:
1844:
1834:
1832:
1831:
1830:
1826:
1823:
1822:
1821:
1819:
1810:
1808:
1807:
1806:
1802:
1799:
1798:
1797:
1793:
1790:
1789:
1788:
1786:
1777:
1775:
1774:
1773:
1769:
1766:
1765:
1764:
1760:
1757:
1756:
1755:
1753:
1740:
1724:
1722:
1721:
1720:
1716:
1713:
1712:
1711:
1709:
1704:
1702:
1701:
1700:
1696:
1693:
1692:
1691:
1687:
1684:
1683:
1682:
1680:
1675:
1672:
1671:
1670:
1666:
1663:
1662:
1661:
1659:
1648:
1646:
1645:
1644:
1640:
1637:
1636:
1635:
1633:
1628:
1626:
1625:
1624:
1623:
1621:
1609:
1607:
1606:
1605:
1604:
1602:
1592:conjugate bases
1586:values are the
1585:
1571:
1563:
1536:
1532:
1507:
1502:
1497:
1493:
1479:
1474:
1469:
1456:
1452:
1451:
1447:
1445:
1433:
1429:
1427:
1424:
1423:
1415:
1412:
1411:
1406:
1403:
1402:
1400:
1394:
1367:
1363:
1341:
1336:
1328:
1323:
1318:
1314:
1300:
1295:
1290:
1277:
1273:
1272:
1268:
1266:
1254:
1250:
1248:
1245:
1244:
1236:
1233:
1232:
1227:
1224:
1223:
1221:
1217:
1211:
1184:
1180:
1160:
1155:
1147:
1142:
1137:
1133:
1122:
1117:
1109:
1104:
1099:
1086:
1082:
1081:
1077:
1075:
1063:
1059:
1057:
1054:
1053:
1045:
1042:
1041:
1039:
1035:
1034:
1029:
1028:
1023:
1018:
1007:
979:
941:
938:
937:
936:
932:
929:
928:
927:
925:
916:
914:
913:
912:
908:
905:
904:
903:
899:
896:
895:
894:
892:
887:
885:
884:
883:
879:
876:
875:
874:
872:
849:
833:Orthophosphates
816:phosphorylation
804:biogeochemistry
779:
776:
775:
774:
772:
763:
760:
759:
758:
754:
751:
750:
749:
745:
742:
741:
740:
738:
724:
721:
720:
719:
717:
714:organophosphate
696:
688:
684:
682:
681:
680:
679:
677:
668:
665:
662:
658:
656:
655:
654:
653:
651:
642:
639:
636:
632:
630:
629:
628:
627:
625:
616:
613:
610:
606:
603:
602:
601:
597:
594:
593:
592:
590:
588:
566:
564:
563:
562:
561:
552:
550:
549:
548:
547:
538:
536:
535:
534:
532:
524:
522:
521:
520:
519:
505:
501:
497:
495:phosphoric acid
480:phosphoric acid
478:derived from a
452:
445:
440:
439:
438: ?)
429:
425:
421:
417:
380:
377:
376:
375:
373:
370:
356:
353:
348:
343:
342:
331:
328:
327:
324:
318:
317:
306:
286:
273:
244:
235:
215:
192:
183:
161:
150:
137:
123:
121:
119:
111:
54:
39:
32:Organophosphate
28:
23:
22:
15:
12:
11:
5:
5663:
5653:
5652:
5647:
5642:
5637:
5632:
5627:
5610:
5609:
5595:
5592:
5591:
5589:
5588:
5583:
5577:
5575:
5569:
5568:
5566:
5565:
5560:
5554:
5552:
5546:
5545:
5543:
5542:
5537:
5532:
5527:
5522:
5517:
5512:
5507:
5505:Metatorbernite
5502:
5497:
5495:Hydroxyapatite
5492:
5487:
5482:
5477:
5472:
5466:
5464:
5458:
5457:
5450:
5449:
5442:
5435:
5427:
5418:
5417:
5412:
5411:
5408:
5405:
5402:
5399:
5396:
5393:
5389:
5385:
5381:
5377:
5373:
5369:
5366:
5362:
5358:
5354:
5351:
5347:
5343:
5339:
5335:
5331:
5327:
5323:
5322:
5318:
5314:
5310:
5306:
5302:
5298:
5294:
5290:
5286:
5282:
5278:
5274:
5270:
5266:
5262:
5258:
5254:
5250:
5246:
5242:
5238:
5234:
5230:
5226:
5222:
5218:
5214:
5210:
5206:
5205:
5202:
5199:
5198:
5195:
5192:
5189:
5186:
5183:
5180:
5177:
5174:
5171:
5168:
5165:
5162:
5159:
5156:
5153:
5150:
5147:
5144:
5140:
5139:
5136:
5133:
5130:
5126:
5122:
5118:
5114:
5110:
5106:
5102:
5098:
5094:
5091:
5087:
5083:
5080:
5077:
5074:
5071:
5068:
5065:
5062:
5058:
5054:
5051:
5047:
5043:
5039:
5035:
5031:
5027:
5022:
5021:
5018:
5015:
5012:
5008:
5001:
4997:
4994:
4990:
4986:
4982:
4978:
4974:
4970:
4966:
4962:
4958:
4955:
4952:
4949:
4946:
4943:
4940:
4936:
4932:
4928:
4924:
4920:
4916:
4914:
4910:
4906:
4902:
4898:
4894:
4890:
4885:
4884:
4881:
4878:
4873:
4870:
4867:
4863:
4859:
4855:
4851:
4847:
4843:
4839:
4835:
4831:
4827:
4823:
4819:
4815:
4811:
4807:
4803:
4799:
4795:
4791:
4784:
4780:
4776:
4772:
4768:
4761:
4757:
4753:
4749:
4745:
4741:
4737:
4733:
4730:
4726:
4722:
4720:
4716:
4712:
4708:
4704:
4700:
4696:
4689:
4685:
4678:
4674:
4669:
4668:
4665:
4662:
4654:
4650:
4647:
4644:
4640:
4636:
4632:
4628:
4624:
4620:
4616:
4612:
4605:
4601:
4594:
4590:
4585:
4584:
4581:
4576:
4573:
4565:
4561:
4557:
4550:
4546:
4542:
4535:
4531:
4527:
4523:
4520:
4516:
4509:
4505:
4502:
4498:
4494:
4489:
4488:
4485:
4483:
4481:
4479:
4469:
4465:
4458:
4457:
4454:
4453:
4446:
4445:
4438:
4431:
4423:
4417:
4416:
4410:
4402:
4401:External links
4399:
4396:
4395:
4351:
4305:
4279:
4262:
4248:
4230:
4216:
4194:
4165:
4162:on 2010-09-16.
4136:
4120:
4105:
4083:
4063:
4060:Phosphate Rock
4051:
4032:
4013:(2605): 38–9.
3995:
3938:
3923:
3894:
3875:
3863:
3851:
3840:
3826:
3819:
3813:. p. 65.
3794:
3761:
3742:
3741:
3739:
3736:
3734:
3733:
3730:
3726:
3722:
3716:
3711:
3702:
3693:
3682:
3674:
3665:
3654:
3649:
3645:
3639:
3635:
3629:
3624:
3621:
3615:
3612:
3606:
3603:
3597:
3594:
3588:
3585:
3579:
3576:Phosphate soda
3573:
3568:
3561:
3558:
3553:
3547:
3544:
3540:
3534:
3526:
3517:
3506:
3501:
3492:
3483:
3472:
3467:
3464:
3460:
3454:
3451:
3447:
3443:
3436:
3434:
3431:
3399:phosphate rock
3377:eutrophication
3360:Redfield ratio
3356:photosynthesis
3336:
3333:
3330:
3329:
3324:
3319:
3314:
3308:
3307:
3304:
3301:
3298:
3294:
3293:
3290:
3287:
3284:
3278:
3277:
3274:
3271:
3268:
3262:
3261:
3258:
3255:
3252:
3246:
3245:
3242:
3239:
3236:
3230:
3229:
3226:
3223:
3220:
3214:
3213:
3210:
3207:
3204:
3198:
3197:
3194:
3191:
3188:
3182:
3181:
3178:
3175:
3172:
3166:
3165:
3162:
3159:
3156:
3150:
3149:
3146:
3143:
3140:
3134:
3133:
3130:
3127:
3124:
3118:
3117:
3114:
3111:
3108:
3106:Western Sahara
3098:
3097:
3094:
3091:
3088:
3082:
3081:
3078:
3075:
3072:
3066:
3065:
3062:
3059:
3056:
3050:
3049:
3046:
3043:
3040:
3034:
3033:
3030:
3027:
3024:
3018:
3017:
3014:
3011:
3008:
3002:
3001:
2998:
2995:
2992:
2986:
2985:
2982:
2979:
2976:
2970:
2969:
2966:
2963:
2960:
2954:
2953:
2950:
2947:
2944:
2938:
2937:
2934:
2931:
2928:
2922:
2921:
2918:
2915:
2912:
2906:
2905:
2904:(millions kg)
2900:
2899:production (%)
2893:
2888:
2863:
2860:
2819:phosphate rock
2801:
2800:
2779:
2770:
2736:
2699:
2689:North Carolina
2682:Main article:
2665:Navassa Island
2653:South Carolina
2637:North Carolina
2573:
2570:
2568:
2565:
2540:
2539:
2454:
2452:
2445:
2439:
2436:
2427:
2424:
2419:calcium stones
2410:
2407:
2383:hydroxyapatite
2374:
2371:
2311:
2310:
2305:
2297:
2291:
2274:
2257:
2247:
2237:
2227:
2217:
2207:
2183:
2180:
2176:
2172:
2169:
2166:
2163:
2161:
2156:
2150:
2147:
2142:
2133:
2128:
2122:
2119:
2114:
2105:
2099:
2098:
2095:
2092:
2089:
2087:
2082:
2076:
2071:
2058:
2049:
2044:
2038:
2035:
2030:
2021:
2015:
2014:
2009:
2005:
2001:
1998:
1995:
1992:
1990:
1985:
1976:
1963:
1954:
1949:
1943:
1938:
1925:
1916:
1910:
1909:
1891:
1881:
1864:
1843:
1840:
1833:
1824:
1814:. The various
1809:
1800:
1791:
1776:
1767:
1758:
1736:
1723:
1714:
1703:
1694:
1685:
1673:
1664:
1647:
1638:
1627:
1617:
1608:
1598:
1581:
1566:
1565:
1561:
1555:
1542:
1539:
1535:
1531:
1528:
1525:
1519:
1513:
1510:
1505:
1496:
1491:
1485:
1482:
1477:
1468:
1465:
1459:
1450:
1444:
1439:
1436:
1432:
1421:
1397:
1396:
1392:
1386:
1373:
1370:
1366:
1362:
1359:
1356:
1350:
1344:
1339:
1326:
1317:
1312:
1306:
1303:
1298:
1289:
1286:
1280:
1271:
1265:
1260:
1257:
1253:
1242:
1219:
1214:
1213:
1209:
1203:
1190:
1187:
1183:
1179:
1176:
1173:
1167:
1158:
1145:
1136:
1131:
1125:
1120:
1107:
1098:
1095:
1089:
1080:
1074:
1069:
1066:
1062:
1051:
1037:
1032:
1031:
1026:
1025:
1020:
1019:
1014:
1008:
1005:
999:
978:
975:
939:
930:
915:
906:
897:
886:
877:
869:conjugate base
848:
845:
841:pyrophosphates
785:thiophosphates
777:
761:
752:
743:
722:
710:orthophosphate
698:
697:
694:orthophosphate
683:
678:
671:
669:
657:
652:
645:
643:
631:
626:
619:
617:
604:
595:
589:
582:
565:
551:
537:
523:
516:orthophosphate
503:
499:
484:orthophosphate
450:
447:
446:
441:
419:
418:
414:standard state
411:
408:
407:
402:
400:Conjugate acid
396:
395:
392:
386:
385:
378:
371:
366:
363:
362:
358:
357:
355:
354:
351:
349:
346:
338:
337:
336:
333:
332:
330:
329:
325:
322:
321:
313:
312:
311:
308:
307:
305:
304:
296:
294:
288:
287:
285:
284:
276:
274:
266:
263:
262:
255:
249:
248:
245:
240:
237:
236:
234:
233:
225:
223:
217:
216:
214:
213:
205:
203:
197:
196:
193:
188:
185:
184:
182:
181:
173:
164:
162:
155:
152:
151:
149:
148:
140:
138:
133:
130:
129:
125:
124:
118:Orthophosphate
117:
113:
112:
109:
103:
102:
98:
97:
94:
93:
83:
68:
67:
43:phosphate soda
26:
9:
6:
4:
3:
2:
5662:
5651:
5648:
5646:
5643:
5641:
5638:
5636:
5633:
5631:
5628:
5626:
5623:
5622:
5620:
5607:
5606:
5593:
5587:
5584:
5582:
5579:
5578:
5576:
5574:
5570:
5564:
5561:
5559:
5556:
5555:
5553:
5551:
5547:
5541:
5540:Wycheproofite
5538:
5536:
5533:
5531:
5528:
5526:
5523:
5521:
5518:
5516:
5513:
5511:
5508:
5506:
5503:
5501:
5500:Lithiophilite
5498:
5496:
5493:
5491:
5488:
5486:
5483:
5481:
5478:
5476:
5473:
5471:
5470:Allanpringite
5468:
5467:
5465:
5463:
5459:
5455:
5448:
5443:
5441:
5436:
5434:
5429:
5428:
5425:
5409:
5406:
5403:
5400:
5397:
5394:
5392:
5386:
5384:
5378:
5376:
5370:
5367:
5365:
5355:
5352:
5350:
5336:
5334:
5328:
5325:
5324:
5321:
5315:
5313:
5307:
5305:
5299:
5297:
5291:
5289:
5283:
5281:
5275:
5273:
5267:
5265:
5259:
5257:
5251:
5249:
5243:
5241:
5235:
5233:
5227:
5225:
5219:
5217:
5211:
5208:
5207:
5200:
5196:
5193:
5190:
5187:
5184:
5181:
5178:
5175:
5172:
5169:
5166:
5163:
5160:
5157:
5154:
5151:
5148:
5145:
5142:
5141:
5137:
5134:
5131:
5129:
5123:
5121:
5107:
5105:
5095:
5092:
5090:
5084:
5081:
5078:
5075:
5072:
5069:
5066:
5063:
5061:
5055:
5052:
5050:
5036:
5034:
5024:
5023:
5019:
5016:
5013:
5011:
5004:
4998:
4995:
4993:
4987:
4985:
4971:
4969:
4959:
4956:
4953:
4950:
4947:
4944:
4941:
4939:
4925:
4923:
4917:
4915:
4913:
4899:
4897:
4887:
4886:
4882:
4879:
4877:
4874:
4871:
4868:
4866:
4860:
4858:
4844:
4842:
4828:
4826:
4812:
4810:
4796:
4794:
4787:
4773:
4771:
4764:
4750:
4748:
4742:
4740:
4734:
4731:
4729:
4723:
4721:
4719:
4705:
4703:
4692:
4681:
4671:
4670:
4666:
4663:
4661:
4657:
4651:
4648:
4645:
4643:
4637:
4635:
4621:
4619:
4608:
4597:
4587:
4586:
4582:
4580:
4577:
4574:
4572:
4568:
4553:
4538:
4524:
4521:
4519:
4512:
4506:
4503:
4501:
4491:
4490:
4486:
4480:
4478:
4475:
4472:
4462:
4461:
4455:
4451:
4444:
4439:
4437:
4432:
4430:
4425:
4424:
4421:
4414:
4411:
4408:
4405:
4404:
4391:
4387:
4383:
4379:
4375:
4371:
4367:
4363:
4355:
4347:
4343:
4339:
4335:
4331:
4327:
4324:(3): 463–76.
4323:
4319:
4318:Sedimentology
4312:
4310:
4302:
4290:
4283:
4272:
4266:
4258:
4252:
4244:
4240:
4234:
4226:
4220:
4205:
4198:
4184:on 2016-10-05
4183:
4179:
4175:
4169:
4161:
4157:
4156:
4151:
4147:
4140:
4132:
4131:
4124:
4118:
4114:
4109:
4094:
4087:
4076:
4072:
4067:
4061:
4055:
4047:
4043:
4036:
4028:
4024:
4020:
4016:
4012:
4008:
4007:
4006:New Scientist
3999:
3991:
3987:
3982:
3977:
3973:
3969:
3965:
3961:
3957:
3953:
3949:
3942:
3935:
3934:
3927:
3913:
3909:
3903:
3901:
3899:
3892:
3888:
3884:
3830:
3822:
3820:0-8053-7171-0
3816:
3812:
3808:
3804:
3798:
3782:
3778:
3774:
3768:
3766:
3757:
3753:
3747:
3743:
3720:
3717:
3686:
3685:Pyrophosphate
3683:
3677:
3658:
3657:Polyphosphate
3655:
3653:
3650:
3643:
3640:
3633:
3630:
3628:
3627:Phosphogypsum
3625:
3619:
3616:
3610:
3607:
3601:
3598:
3592:
3589:
3583:
3580:
3577:
3574:
3572:
3569:
3567:
3559:
3557:
3554:
3551:
3548:
3538:
3535:
3529:
3510:
3509:Metaphosphate
3507:
3476:
3475:Hypophosphite
3473:
3471:
3468:
3458:
3455:
3441:
3438:
3437:
3430:
3428:
3424:
3420:
3416:
3412:
3408:
3404:
3400:
3395:
3393:
3389:
3384:
3382:
3378:
3373:
3369:
3361:
3357:
3352:
3346:
3341:
3328:
3323:
3318:
3313:
3310:
3309:
3296:
3295:
3283:
3280:
3279:
3267:
3266:United States
3264:
3263:
3251:
3248:
3247:
3235:
3232:
3231:
3219:
3216:
3215:
3203:
3200:
3199:
3187:
3184:
3183:
3171:
3168:
3167:
3155:
3152:
3151:
3139:
3136:
3135:
3123:
3120:
3119:
3107:
3103:
3100:
3099:
3087:
3084:
3083:
3071:
3068:
3067:
3055:
3052:
3051:
3039:
3036:
3035:
3023:
3020:
3019:
3007:
3004:
3003:
2991:
2988:
2987:
2975:
2972:
2971:
2959:
2956:
2955:
2943:
2940:
2939:
2927:
2924:
2923:
2911:
2908:
2907:
2901:
2894:
2892:(millions kg)
2889:
2886:
2885:
2875:
2868:
2859:
2856:
2853:
2850:
2848:
2844:
2840:
2835:
2833:
2828:
2823:
2820:
2815:
2810:
2806:
2799:
2798:Banaba Island
2795:
2791:
2787:
2783:
2780:
2778:
2774:
2771:
2768:
2764:
2760:
2756:
2752:
2748:
2744:
2740:
2737:
2735:
2731:
2727:
2723:
2719:
2715:
2711:
2707:
2703:
2700:
2698:
2694:
2690:
2685:
2679:
2678:North America
2676:
2675:
2674:
2672:
2668:
2666:
2662:
2661:Banaba Island
2658:
2654:
2650:
2646:
2642:
2638:
2634:
2630:
2626:
2622:
2618:
2613:
2611:
2607:
2603:
2595:
2590:
2583:
2578:
2564:
2562:
2558:
2557:calcification
2553:
2550:
2546:
2536:
2533:
2525:
2514:
2511:
2507:
2504:
2500:
2497:
2493:
2490:
2486:
2483: –
2482:
2478:
2477:Find sources:
2471:
2467:
2461:
2460:
2455:This article
2453:
2449:
2444:
2443:
2435:
2433:
2423:
2420:
2416:
2406:
2404:
2400:
2396:
2392:
2391:fluoroapatite
2388:
2384:
2380:
2370:
2368:
2367:triphosphates
2364:
2360:
2357:, as are the
2356:
2352:
2348:
2344:
2340:
2336:
2332:
2328:
2324:
2320:
2316:
2286:
2285:
2284:
2282:
2268:
2267:pyrophosphate
2263:
2200:
2181:
2178:
2174:
2170:
2167:
2164:
2162:
2148:
2145:
2140:
2120:
2117:
2112:
2093:
2090:
2088:
2074:
2069:
2056:
2036:
2033:
2028:
2007:
2003:
1999:
1996:
1993:
1991:
1974:
1961:
1941:
1936:
1923:
1899:
1875:
1871:
1867:
1859:
1857:
1853:
1849:
1839:
1817:
1816:metaphosphate
1784:
1751:
1750:pyrophosphate
1748:ions such as
1747:
1742:
1739:
1735:
1731:
1656:
1653:
1620:
1616:
1601:
1597:
1593:
1589:
1584:
1580:
1575:
1560:
1556:
1540:
1537:
1533:
1529:
1526:
1523:
1511:
1508:
1503:
1483:
1480:
1475:
1457:
1442:
1437:
1434:
1430:
1422:
1399:
1398:
1391:
1387:
1371:
1368:
1364:
1360:
1357:
1354:
1342:
1337:
1324:
1304:
1301:
1296:
1278:
1263:
1258:
1255:
1251:
1243:
1216:
1215:
1208:
1204:
1188:
1185:
1181:
1177:
1174:
1171:
1156:
1143:
1123:
1118:
1105:
1087:
1072:
1067:
1064:
1060:
1052:
1022:
1021:
1017:
1013:
1009:
1004:
1000:
997:
996:
993:
988:
983:
974:
971:
967:
963:
959:
955:
951:
946:
923:
870:
866:
862:
858:
854:
844:
842:
838:
834:
830:
828:
825:
821:
817:
813:
809:
805:
801:
797:
792:
790:
786:
770:
736:
732:
715:
711:
707:
703:
695:
691:
675:
670:
667:
649:
644:
641:
623:
618:
615:
586:
581:
580:
579:
577:
573:
559:
545:
531:
517:
513:
508:
496:
489:
485:
481:
477:
473:
469:
465:
461:
457:
444:
437:
432:
415:
409:
406:
403:
401:
398:
397:
393:
391:
388:
387:
372:
369:
365:
364:
359:
350:
345:
344:
341:
334:
320:
319:
316:
309:
302:
298:
297:
295:
293:
290:
289:
282:
278:
277:
275:
269:
265:
264:
260:
256:
254:
251:
250:
246:
243:
239:
238:
231:
227:
226:
224:
222:
219:
218:
211:
207:
206:
204:
202:
199:
198:
194:
191:
187:
186:
179:
174:
171:
166:
165:
163:
159:
154:
153:
146:
142:
141:
139:
136:
132:
131:
126:
114:
108:
104:
99:
88:
84:
78:
74:
73:
69:
65:
60:
52:
48:
44:
37:
33:
19:
5596:
5490:Fluorapatite
5480:Brazilianite
4449:
4368:(1): 56–62.
4365:
4361:
4354:
4321:
4317:
4300:
4293:. Retrieved
4282:
4265:
4251:
4242:
4233:
4219:
4207:. Retrieved
4197:
4186:. Retrieved
4182:the original
4168:
4160:the original
4153:
4139:
4129:
4123:
4108:
4097:. Retrieved
4086:
4066:
4054:
4045:
4035:
4010:
4004:
3998:
3958:(4): 49–55.
3955:
3951:
3941:
3931:
3926:
3915:. Retrieved
3911:
3882:
3829:
3806:
3797:
3785:. Retrieved
3776:
3755:
3746:
3675:
3527:
3396:
3385:
3368:environments
3365:
3326:
3321:
3316:
3311:
3186:South Africa
3154:Saudi Arabia
2881:(USGS, 2021)
2873:
2857:
2854:
2851:
2836:
2824:
2809:Dana Cordell
2802:
2781:
2773:Central Asia
2772:
2743:Saudi Arabia
2738:
2701:
2677:
2669:
2629:Soda Springs
2614:
2599:
2554:
2543:
2528:
2519:
2509:
2502:
2495:
2488:
2476:
2464:Please help
2459:verification
2456:
2429:
2412:
2389:may contain
2376:
2363:diphosphates
2312:
2264:
2201:
1862:
1860:
1851:
1845:
1783:triphosphate
1743:
1737:
1733:
1657:
1654:
1618:
1614:
1599:
1595:
1582:
1578:
1576:
1569:
1558:
1389:
1206:
1015:
1011:
1002:
998:Equilibrium
991:
947:
850:
831:
800:biochemistry
793:
709:
705:
699:
693:
689:
557:
543:
515:
511:
509:
483:
459:
453:
128:Identifiers
116:Other names
5563:Whitlockite
5462:Crystalline
3642:Phosphonite
3632:Phosphonate
3609:Phosphinite
3582:Phosphinate
3116:50,000,000
2890:Production
2739:Middle East
2671:Phosphorite
2621:Bone Valley
2481:"Phosphate"
2359:phosphagens
2315:nucleotides
2202:Thus, only
1870:homeostatic
1658:In effect,
865:tetrahedral
863:atoms in a
812:agriculture
361:Properties
210:CHEBI:18367
47:phosphonate
5635:Phosphates
5619:Categories
5520:Taranakite
5485:Eosphorite
4450:Phosphates
4188:2013-05-03
4099:2013-01-10
3917:2020-11-20
3845:, Cl, OH,
3738:References
3564:, such as
3470:Fertilizer
3401:can leave
3372:freshwater
3327:71,000,000
3276:1,000,000
3250:Uzbekistan
3212:1,800,000
3196:1,400,000
3164:1,400,000
3070:Kazakhstan
3000:1,000,000
2984:2,800,000
2968:3,200,000
2952:1,600,000
2936:1,100,000
2920:2,200,000
2777:Kazakhstan
2734:Mauritania
2602:phosphorus
2584:, US, 2008
2567:Production
2492:newspapers
2281:hydrolysis
1730:weak acids
987:speciation
857:phosphorus
853:molar mass
827:metabolism
796:phosphates
638:Dihydrogen
612:Phosphoric
488:derivative
390:Molar mass
301:NK08V8K8HR
259:Phosphates
221:ChemSpider
156:3D model (
145:14265-44-2
135:CAS Number
107:IUPAC name
57:Phosphate
51:phosphorus
5586:Scorodite
5573:Amorphous
5558:Turquoise
5530:Wavellite
5525:Variscite
5475:Beraunite
4390:129497587
4346:140680495
4152:) (ed.).
4046:The Times
3972:1866-0452
3618:Phosphite
3591:Phosphine
3584:– OP(OR)R
3552:compounds
2926:Australia
2895:Share of
2786:Australia
2697:Tennessee
2645:Tennessee
2549:mortality
2522:July 2022
2351:metabolic
2329:) and in
2179:−
2171:×
2165:≈
2149:−
2121:−
2091:≈
2075:−
2037:−
2000:×
1994:≈
1942:−
1746:polymeric
1538:−
1530:×
1524:≈
1512:−
1484:−
1369:−
1361:×
1355:≈
1343:−
1305:−
1186:−
1178:×
1172:≈
1124:−
769:trivalent
706:phosphate
690:Phosphate
666:phosphate
640:phosphate
512:phosphate
460:phosphate
456:chemistry
110:Phosphate
5535:Xenotime
5515:Struvite
5510:Monazite
4295:June 10,
3990:22334826
3787:30 March
3781:Archived
3634:– OP(OR)
3611:– P(OR)R
3433:See also
3423:chromium
3403:tailings
3392:alluvial
3388:bacteria
3306:840,000
3260:100,000
3244:100,000
3148:600,000
3132:210,000
3080:260,000
3064:800,000
3032:430,000
2902:Reserves
2827:Mulberry
2594:Métlaoui
2403:fluoride
2399:hydroxyl
962:rubidium
839:to form
837:condense
664:Hydrogen
195:3903772
5204:
4370:Bibcode
4326:Bibcode
4243:Reuters
4015:Bibcode
3981:3278747
3807:Biology
3644:– P(OR)
3620:– P(OR)
3427:uranium
3407:cadmium
3335:Ecology
3317:227,000
3292:30,000
3282:Vietnam
3234:Tunisia
3228:30,000
3180:50,000
3170:Senegal
3102:Morocco
3096:30,000
3048:57,000
3016:46,000
2990:Finland
2910:Algeria
2897:global
2887:Country
2790:Makatea
2782:Oceania
2767:Akashat
2730:Tunisia
2722:Senegal
2710:Algeria
2706:Morocco
2649:Georgia
2641:Montana
2625:Florida
2617:Morocco
2506:scholar
2395:hydroxy
2269:anions
1898:cytosol
966:caesium
950:soluble
808:ecology
731:organic
530:protons
436:what is
434: (
384:
268:PubChem
4388:
4344:
4209:2 July
3988:
3978:
3970:
3869:, and
3817:
3425:, and
3419:copper
3415:nickel
3270:23,300
3142:13,100
3138:Russia
3110:35,500
3086:Mexico
3054:Jordan
3038:Israel
2962:95,000
2942:Brazil
2862:Mining
2796:, and
2751:Israel
2747:Jordan
2702:Africa
2695:, and
2651:, and
2627:, the
2508:
2501:
2494:
2487:
2479:
2405:ions.
2325:, and
2317:(e.g.
2300:O ⇌ 2
2252:, 39%
2232:, 38%
1781:, and
1572:
1231:⇌ HPO
968:, and
861:oxygen
806:, and
773:OP(O-)
712:is an
492:a.k.a.
462:is an
431:verify
428:
340:SMILES
101:Names
4386:S2CID
4342:S2CID
4274:(PDF)
4078:(PDF)
3602:– OPR
3539:– NaH
3442:- (NH
3312:Total
3300:1,140
3286:4,650
3273:12.37
3238:4,110
3206:2,000
3202:Syria
3190:2,100
3174:3,420
3158:6,500
3126:4,000
3113:13.45
3074:1,500
3058:9,220
3042:2,810
3010:1,480
3006:India
2978:5,000
2974:Egypt
2965:44.83
2958:China
2946:4,700
2930:2,700
2914:1,300
2794:Nauru
2755:Syria
2718:Niger
2714:Egypt
2693:Idaho
2657:Nauru
2633:Idaho
2610:mined
2513:JSTOR
2499:books
1577:The p
1410:⇌ PO
954:water
727:RR′R″
476:ester
464:anion
315:InChI
247:1997
201:ChEBI
158:JSmol
49:, or
5388:CmPO
5380:AmPO
5372:PuPO
5357:U(PO
5330:AcPO
5317:YbPO
5309:TmPO
5301:ErPO
5293:HoPO
5285:DyPO
5277:TbPO
5269:GdPO
5261:EuPO
5253:SmPO
5245:PmPO
5237:NdPO
5229:PrPO
5221:CePO
5213:LaPO
5125:BiPO
5086:AuPO
5057:LuPO
5007:-SbO
5000:SbPO
4989:InPO
4862:GaPO
4790:FePO
4767:MnPO
4744:CrPO
4725:ScPO
4639:AlPO
4297:2012
4211:2023
3986:PMID
3968:ISSN
3815:ISBN
3789:2018
3721:– Na
3661:(HPO
3593:– PR
3459:– Na
3411:lead
3303:1.17
3289:1.21
3241:1.79
3225:0.45
3218:Togo
3209:0.34
3193:0.99
3177:0.45
3161:1.48
3145:5.60
3129:1.79
3122:Peru
3104:and
3093:0.76
3077:0.72
3061:3.36
3045:1.48
3029:0.09
3022:Iraq
3013:0.49
2981:2.47
2949:3.00
2933:1.17
2917:0.54
2843:JORC
2814:USGS
2763:Iraq
2761:and
2759:Iran
2726:Togo
2485:news
2393:, a
2365:and
2345:and
2333:and
2212:and
2168:2.14
2094:0.62
1886:and
1710:H(PO
1708:and
1527:2.14
1036:⇌ H
873:H(PO
835:can
824:cell
818:and
787:and
614:acid
574:and
560:ion
546:ion
518:ion
510:The
486:, a
468:salt
458:, a
292:UNII
281:1061
253:MeSH
230:1032
5410:No
5407:Md
5404:Fm
5401:Es
5398:Cf
5395:Bk
5368:Np
5353:Pa
5342:(PO
5326:**
5197:Og
5194:Ts
5191:Lv
5188:Mc
5185:Fl
5182:Nh
5179:Cn
5176:Rg
5173:Ds
5170:Mt
5167:Hs
5164:Bh
5161:Sg
5158:Db
5155:Rf
5152:Lr
5149:**
5146:Ra
5143:Fr
5138:Rn
5135:At
5132:Po
5113:(PO
5093:Hg
5082:Pt
5079:Ir
5076:Os
5073:Re
5067:Ta
5064:Hf
5042:(PO
5020:Xe
5014:Te
4996:Sn
4977:(PO
4957:Pd
4954:Rh
4951:Ru
4948:Tc
4945:Mo
4942:Nb
4931:(PO
4919:YPO
4905:(PO
4883:Kr
4880:Br
4876:-Se
4872:As
4869:Ge
4850:(PO
4834:(PO
4818:(PO
4802:(PO
4779:(PO
4756:(PO
4736:VPO
4732:Ti
4711:(PO
4688:HPO
4667:Ar
4664:Cl
4653:+SO
4646:Si
4627:(PO
4611:NaH
4604:HPO
4583:Ne
4549:HPO
4541:(NH
4526:(NH
4515:+BO
4508:BPO
4504:Be
4487:He
4378:doi
4334:doi
4023:doi
4011:194
3976:PMC
3960:doi
3956:109
3887:doi
3513:(PO
3488:(PO
3463:HPO
3450:HPO
3390:in
3322:100
3254:900
3222:800
3090:558
3026:200
2994:995
2468:by
2335:RNA
2331:DNA
2327:ATP
2323:ADP
2319:AMP
2296:+ H
2262:).
2137:HPO
2025:HPO
1997:7.5
1846:In
1820:(PO
1690:(PO
1634:(PO
1500:HPO
1419:+ H
1401:HPO
1358:6.2
1293:HPO
1240:+ H
1175:7.5
1049:+ H
956:at
952:in
902:(PO
791:).
739:(CH
708:or
700:In
692:or
514:or
474:or
454:In
271:CID
5621::
5338:Th
5209:*
5109:Pb
5101:PO
5097:Tl
5070:W
5053:*
5038:Ba
5030:PO
5026:Cs
5017:I
4973:Cd
4965:PO
4961:Ag
4927:Zr
4901:Sr
4893:PO
4889:Rb
4846:Zn
4830:Cu
4814:Ni
4798:Co
4775:Fe
4752:Mn
4707:Ca
4699:PO
4695:KH
4677:PO
4660:-S
4649:P
4623:Mg
4615:PO
4600:Na
4593:PO
4589:Na
4579:+F
4575:O
4571:-N
4564:PO
4556:NH
4534:PO
4522:C
4497:PO
4493:Li
4468:PO
4384:.
4376:.
4366:25
4364:.
4340:.
4332:.
4322:46
4320:.
4308:^
4299:.
4241:.
4176:.
4044:.
4021:.
4009:.
3984:.
3974:.
3966:.
3954:.
3950:.
3910:.
3897:^
3871:PO
3859:SO
3857:,
3847:CO
3836:Hg
3775:.
3764:^
3754:.
3731:10
3689:(P
3687:–
3659:–
3543:PO
3511:–
3477:–
3421:,
3417:,
3413:,
3409:,
2834:.
2792:,
2788:,
2784::
2775::
2757:,
2753:,
2749:,
2745:,
2741::
2732:,
2728:,
2724:,
2720:,
2716:,
2712:,
2708:,
2704::
2691:,
2680::
2647:,
2643:,
2563:.
2369:.
2321:,
2283::
2175:10
2109:PO
2066:PO
2004:10
1971:PO
1933:PO
1874:pH
1872:)
1858:.
1801:10
1787:(P
1785:,
1754:(P
1752:,
1679:,
1669:PO
1652:.
1588:pH
1562:a3
1541:13
1534:10
1472:PO
1413:3−
1404:2−
1393:a2
1365:10
1334:PO
1234:2−
1222:PO
1210:a1
1182:10
1153:PO
1115:PO
1040:PO
1030:PO
964:,
945:.
935:PO
924:,
843:.
829:.
802:,
757:PO
737:,
718:PO
704:,
600:PO
578:.
507:.
502:PO
470:,
466:,
374:PO
45:,
5446:e
5439:t
5432:v
5390:4
5382:4
5374:4
5363:2
5361:)
5359:4
5348:4
5346:)
5344:4
5340:3
5332:4
5319:4
5311:4
5303:4
5295:4
5287:4
5279:4
5271:4
5263:4
5255:4
5247:4
5239:4
5231:4
5223:4
5215:4
5127:4
5119:2
5117:)
5115:4
5111:3
5103:4
5099:3
5088:4
5059:4
5048:2
5046:)
5044:4
5040:3
5032:4
5028:3
5009:4
5002:4
4991:4
4983:2
4981:)
4979:4
4975:3
4967:4
4963:3
4937:4
4935:)
4933:4
4929:3
4921:4
4911:2
4909:)
4907:4
4903:3
4895:4
4891:3
4864:4
4856:2
4854:)
4852:4
4848:3
4840:2
4838:)
4836:4
4832:3
4824:2
4822:)
4820:4
4816:3
4808:2
4806:)
4804:4
4800:3
4792:4
4785:2
4783:)
4781:4
4777:3
4769:4
4762:2
4760:)
4758:4
4754:3
4746:4
4738:4
4727:4
4717:2
4715:)
4713:4
4709:3
4701:4
4697:2
4690:4
4686:2
4684:K
4679:4
4675:3
4673:K
4655:4
4641:4
4633:2
4631:)
4629:4
4625:3
4617:4
4613:2
4606:4
4602:2
4595:4
4591:3
4566:4
4562:2
4560:H
4558:4
4551:4
4547:2
4545:)
4543:4
4536:4
4532:3
4530:)
4528:4
4517:3
4510:4
4499:4
4495:3
4470:4
4466:3
4464:H
4442:e
4435:t
4428:v
4392:.
4380::
4372::
4348:.
4336::
4328::
4276:.
4259:.
4213:.
4191:.
4102:.
4080:.
4048:.
4029:.
4025::
4017::
3992:.
3962::
3920:.
3889::
3876:4
3864:4
3852:3
3823:.
3791:.
3729:O
3727:3
3725:P
3723:5
3707:)
3703:7
3698:O
3694:2
3676:n
3670:)
3666:3
3648:R
3646:2
3638:R
3636:2
3622:3
3613:2
3604:3
3595:3
3586:2
3562:3
3545:4
3541:2
3528:n
3522:)
3518:3
3497:)
3493:2
3484:2
3479:H
3465:4
3461:2
3452:4
3448:2
3446:)
3444:4
3362:.
3257:-
2997:-
2535:)
2529:(
2524:)
2520:(
2510:·
2503:·
2496:·
2489:·
2462:.
2298:2
2182:6
2155:]
2146:2
2141:4
2132:[
2127:]
2118:3
2113:4
2104:[
2081:]
2070:4
2057:2
2053:H
2048:[
2043:]
2034:2
2029:4
2020:[
2008:4
1984:]
1975:4
1962:3
1958:H
1953:[
1948:]
1937:4
1924:2
1920:H
1915:[
1865:i
1863:P
1829:)
1825:3
1805:)
1796:O
1792:3
1772:)
1768:7
1763:O
1759:2
1738:a
1734:K
1719:)
1715:4
1699:)
1695:4
1686:2
1681:H
1674:4
1665:3
1660:H
1643:)
1639:4
1619:a
1615:K
1600:a
1596:K
1583:a
1579:K
1559:K
1557:p
1518:]
1509:2
1504:4
1495:[
1490:]
1481:3
1476:4
1467:[
1464:]
1458:+
1454:H
1449:[
1443:=
1438:3
1435:a
1431:K
1416:4
1407:4
1390:K
1388:p
1372:8
1349:]
1338:4
1325:2
1321:H
1316:[
1311:]
1302:2
1297:4
1288:[
1285:]
1279:+
1275:H
1270:[
1264:=
1259:2
1256:a
1252:K
1237:4
1228:4
1225:−
1220:2
1218:H
1207:K
1205:p
1189:3
1166:]
1157:4
1144:3
1140:H
1135:[
1130:]
1119:4
1106:2
1102:H
1097:[
1094:]
1088:+
1084:H
1079:[
1073:=
1068:1
1065:a
1061:K
1046:4
1043:−
1038:2
1033:4
1027:3
1024:H
1016:a
1012:K
1010:p
1006:a
1003:K
940:4
931:3
926:H
911:)
907:4
898:2
893:H
882:)
878:4
778:3
762:4
753:3
748:)
744:3
723:4
605:4
596:3
591:H
533:H
504:4
500:3
498:H
426:Y
379:4
160:)
53:.
38:.
20:)
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