61:
168:
104:, . The second kind of nickel site consists of groups that are connected to the Ni-CN nitrogens. Thus cyanide serves as a
199:
Büttner, H. G.; Kearley, G. J.; Howard, C. J.; Fillaux, F. (1994). "Structure of the
Hofmann Clathrates Ni(NH
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281:
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124:
Many variations of
Hofmann clathrates have been reported. The ammonia ligands can be replaced by
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100:) reflects the presence of two types of nickel(II) centers, one of which is the square-planar
186:
Introduction to
Reticular Chemistry: Metal-Organic Frameworks and Covalent Organic Frameworks
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41:
8:
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17:
112:- subunits results in a sheet-like polymer. Voids between these sheets, defined by the
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48:. On a conceptual level, Hofmann clathrates can be viewed as forerunners to
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44:. They have attracted attention because they can be used to separate
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O. M. Yaghi; M. J. Kalmutzki; C. S. Diercks (2019).
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24:refers to materials with the formula Ni(CN)
128:. Tetracyanonickelate can be replaced by
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264:
116:, are occupied by benzene molecules.
13:
40:). These materials are a type of
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177:
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80:). Some N-H bonds are omitted.
1:
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136:can occupy the benzene site.
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55:
84:The empirical formula Ni(CN)
7:
108:. The linking of the and
10:
298:
253:10.1107/S0108768193013539
157:Chemistry of the Elements
155:; Earnshaw, Alan (1997).
50:metal-organic frameworks
188:. Weinheim: Wiley-VCH.
81:
161:Butterworth-Heinemann
153:Greenwood, Norman N.
63:
42:coordination polymer
132:. A wide range of
130:tetracyanopalladate
102:tetracyanonickelate
64:Structure of Ni(CN)
18:inorganic chemistry
82:
22:Hofmann clathrates
170:978-0-08-037941-8
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272:Nickel complexes
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163:. p. 1161.
159:(2nd ed.).
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282:Cyanometallates
277:Cyano complexes
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114:ammonia ligands
106:bridging ligand
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247:(4): 431–435.
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266:Categories
140:References
120:Variations
56:Structures
219:and Zn(NH
126:diamines
52:(MOFs).
46:xylenes
227:Ni(CN)
207:Ni(CN)
167:
134:arenes
110:trans
165:ISBN
249:doi
239:".
92:)(C
88:(NH
72:)(C
68:(NH
32:)(C
28:(NH
16:In
268::
245:50
243:.
231:2C
211:2C
20:,
255:.
251::
237:6
235:H
233:6
229:4
225:2
223:)
221:3
217:6
215:D
213:6
209:4
205:2
203:)
201:3
173:.
98:6
96:H
94:6
90:3
86:2
78:6
76:H
74:6
70:3
66:2
38:6
36:H
34:6
30:3
26:2
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
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