606:
213:
594:
27:
568:
582:
785:
Geng, Shi-Kui; Zheng, Yao; Li, Shan-Qing; Su, Hui; Zhao, Xu; Hu, Jun; Shu, Hai-Bo; Jaroniec, Mietek; Chen, Ping; Liu, Qing-Hua; Qiao, Shi-Zhang (2021). "Nickel ferrocyanide as a high-performance urea oxidation electrocatalyst".
545:, ferrocyanide should be called "hexacyanidoferrate(II)". Cyanides as a chemical class were named because they were discovered in ferrocyanide. Ferrocyanide in turn was named in Latin to mean "blue substance with iron." The dye
1531:
1733:
1782:
1769:
1477:
1276:
1823:
1759:
1749:
1515:
854:
1792:
1614:
1057:
1833:
1714:
1599:
1468:
1267:
1723:
1576:
1343:
1286:
697:
Gail, E.; Gos, S.; Kulzer, R.; Lorösch, J.; Rubo, A.; Sauer, M.; Kellens, R.; Reddy, J.; Steier, N.; Hasenpusch, W. (2011). "Cyano
Compounds, Inorganic".
1704:
1368:
1234:
930:
1458:
1147:
1448:
1380:
699:
822:
1846:
1555:
1438:
1334:
74:
940:
1604:
1012:
252:
855:
http://arpa-e.energy.gov/sites/default/files/documents/files/HarvardFlowBattery_OPEN2012_ExternalProjectImpactSheet_FINAL.pdf
389:
are less toxic because they tend not to release free cyanide. It is of commercial interest as a precursor to the pigment
884:
716:
678:
227:
1396:
1163:
338:
480:. Ferricyanide is consumed in the process, thus any increase in ferrocyanide can be attributed to secretions of
460:. Specialized applications involves their use as precipitating agents for production of citric acid and wine.
378:
472:. For this reason ferrocyanide has been used as a probe of extracellular electron acceptor in the study of
170:
1914:
191:
862:
1929:
1909:
208:
549:
had been first made in the early 18th century. The word "cyanide" used in the name is from κύανος
1924:
1568:
635:
1808:
1066:
877:
641:
611:
362:
605:
114:
1081:
632: – Prussian blue deposit formed in soils contaminated by effluents of chemical industry
440:, since ferrocyanide has negligible absorption at this wavelength while ferricyanide has an
405:
Treatment of ferrocyanide with ferric-containing salts gives the intensely coloured pigment
1257:
795:
523:
358:
179:
50:
8:
1589:
1413:
1309:
1205:
646:
512:
433:
212:
40:
799:
1196:
762:
733:
593:
542:
441:
94:
1242:
1130:
1120:
1047:
1037:
1022:
948:
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830:
767:
712:
674:
567:
500:
457:
159:
1363:
1353:
1218:
1174:
1110:
977:
967:
955:
909:
803:
757:
749:
704:
504:
394:
275:
823:"Holy Grail of energy policy in sight as battery technology smashes the old order"
708:
468:
Ferrocyanide and its oxidized product ferricyanide cannot freely pass through the
1919:
1564:
1497:
1487:
1428:
1295:
1135:
925:
469:
581:
1548:
1502:
1423:
1227:
1097:
1032:
991:
981:
807:
516:
477:
473:
332:
1903:
1328:
834:
573:
546:
453:
406:
390:
1247:
1188:
1101:
771:
624:
530:
421:
386:
323:
1091:
374:
26:
1008:
629:
300:
105:
753:
892:
481:
437:
696:
331:
Except where otherwise noted, data are given for materials in their
853:
Developing
Organic Flow Batteries for Energy Storage (arpa-e.gov)
496:
134:
73:
1002:
894:
414:
382:
146:
410:
354:
85:
63:
196:
508:
361:
give yellow solutions. It is usually available as the salt
125:
452:
The dominant use of ferrocyanides is as precursors to the
420:
Ferrocyanide reversibly oxidized by one electron, giving
484:
or transplasma membrane electron transport activity.
738:
of baker's yeast: Purification and crystallization"
529:Ferrocyanide is also studied as an electrolyte in
377:species, featuring low-spin iron(II) center in an
16:Anion in which a Fe ion is complexed by 6 CN ions
1901:
158:
820:
49:
700:Ullmann's Encyclopedia of Industrial Chemistry
668:
878:
784:
731:
885:
871:
456:pigments. Sodium ferrocyanide is a common
211:
113:
761:
692:
690:
178:
821:Evans-Pritchard, Ambrose (2016-08-10).
778:
511:. Aspirational applications range from
207:
1902:
915:
893:Salts and covalent derivatives of the
734:"Lactic dehydrogenase and cytochrome b
732:Appleby, C. A.; Morton, R. K. (1959).
687:
664:
662:
1693:
866:
239:Key: UETZVSHORCDDTH-UHFFFAOYSA-N
93:
669:Holleman, A. F.; Wiberg, E. (2001).
541:According to the recommendations of
659:
149:
133:
13:
14:
1941:
604:
592:
580:
566:
432:This conversion can be followed
290:
236:InChI=1S/6CN.Fe/c6*1-2;/q6*-1;+2
25:
536:
447:
393:and, as its potassium salt, an
335:(at 25 °C , 100 kPa).
847:
814:
725:
515:for cleaner energy with lower
281:
1:
709:10.1002/14356007.a08_159.pub3
673:. San Diego: Academic Press.
652:
385:are highly toxic, ferro- and
379:octahedral ligand environment
400:
287:
7:
618:
553:, Greek for "(dark) blue."
463:
10:
1946:
1695:
808:10.1038/s41560-021-00899-2
556:
260:N#C(C#N)(C#N)(C#N)(C#N)C#N
917:
902:
562:Common ferrocyanide salts
381:. Although many salts of
365:, which has the formula K
329:
312:
268:
248:
223:
33:
24:
444:of 1040 M cm.
703:. Weinheim: Wiley-VCH.
487:Nickel ferrocyanide (Ni
642:Potassium ferrocyanide
442:extinction coefficient
363:potassium ferrocyanide
636:Perls' Prussian blue
524:wastewater treatment
359:coordination complex
800:2021NatEn...6..904G
671:Inorganic Chemistry
647:Sodium ferrocyanide
638:- a histology stain
513:hydrogen production
353:is the name of the
308: g·mol
21:
1915:Iron(II) compounds
495:) is also used as
409:(sometimes called
339:Infobox references
313:Related compounds
19:
1897:
1896:
1891:
1890:
754:10.1042/bj0710492
501:electro-oxidation
458:anti-caking agent
434:spectroscopically
413:ferrocyanide and
347:Chemical compound
345:
344:
319:Related compounds
192:CompTox Dashboard
75:Interactive image
20:Ferrocyanide ion
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505:anodic oxidation
395:anticaking agent
357:. Salts of this
307:
292:
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276:Chemical formula
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182:
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137:
117:
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53:
29:
22:
18:
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1930:Cyanometallates
1910:Cyano complexes
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1038:
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474:redox reactions
470:plasma membrane
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417:ferricyanide).
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1925:Iron complexes
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794:(9): 904–912.
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531:flow batteries
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828:
827:The Telegraph
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788:Nature Energy
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680:0-12-352651-5
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547:Prussian blue
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454:Prussian blue
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407:Prussian blue
398:
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391:Prussian blue
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387:ferricyanides
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838:. Retrieved
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727:
698:
670:
625:Ferricyanide
550:
540:
537:Nomenclature
528:
522:emission to
486:
467:
451:
448:Applications
436:at 420
431:
422:ferricyanide
419:
404:
351:Ferrocyanide
350:
349:
324:Ferricyanide
34:Identifiers
375:diamagnetic
269:Properties
1904:Categories
840:2023-06-28
742:Biochem. J
653:References
630:Blue billy
587:Ag4Fe(CN)6
482:reductants
301:Molar mass
180:FLX0VIC39Y
106:ChemSpider
95:CHEBI:5032
62:3D model (
51:13408-63-4
41:CAS Number
835:0307-1235
401:Reactions
772:13638255
619:See also
497:catalyst
464:Research
373:. is a
115:10446887
1696:
895:cyanide
796:Bibcode
763:1196822
557:Gallery
415:ferrous
383:cyanide
306:211.955
160:9552077
147:PubChem
1920:Anions
1835:Th(CN)
1825:Ac(CN)
1810:Yb(CN)
1794:Ho(CN)
1784:Dy(CN)
1771:Gd(CN)
1761:Eu(CN)
1751:Sm(CN)
1735:Pr(CN)
1725:Ce(CN)
1716:Ce(CN)
1706:La(CN)
1616:Bi(CN)
1606:Pb(CN)
1591:Hg(CN)
1569:Au(CN)
1556:Pt(CN)
1549:Pt(CN)
1517:Lu(CN)
1504:Ba(CN)
1479:Te(CN)
1470:Te(CN)
1460:Sb(CN)
1450:Sn(CN)
1440:In(CN)
1430:Cd(CN)
1415:Pd(CN)
1397:Mo(CN)
1370:Sr(CN)
1345:Se(CN)
1336:(SeCN)
1288:As(CN)
1278:Ge(CN)
1269:Ge(CN)
1259:Ga(CN)
1249:Zn(CN)
1235:Ni(CN)
1228:Ni(CN)
1220:Ni(CN)
1206:Co(CN)
1198:Co(CN)
1189:Fe(CN)
1182:Fe(CN)
1175:Fe(CN)
1164:Cr(CN)
1149:Sc(CN)
1137:Ca(CN)
1059:Si(CN)
1049:Al(CN)
1039:Mg(CN)
932:Be(CN)
833:
770:
760:
715:
677:
551:kyanos
491:Fe(CN)
428:⇌ + e
411:ferric
369:Fe(CN)
253:SMILES
135:C01913
1532:W(CN)
1382:Y(CN)
1112:S(CN)
1103:(SCN)
1083:P(CN)
1014:O(CN)
949:C(CN)
941:B(CN)
543:IUPAC
507:) of
478:cells
355:anion
228:InChI
86:ChEBI
64:JSmol
1852:(CN)
1600:TlCN
1582:(CN)
1565:AuCN
1498:CsCN
1424:AgCN
1364:RbCN
1354:BrCN
1330:SeCN
1323:AsCN
1305:AsCN
1243:CuCN
1121:ClCN
1098:-NCS
1076:SiCN
1033:NaCN
1009:-NCO
978:ONCN
960:(CN)
926:LiCN
831:ISSN
768:PMID
713:ISBN
675:ISBN
599:Ni42
574:Fe43
509:urea
171:UNII
126:KEGG
1887:No
1884:Md
1881:Fm
1878:Es
1875:Cf
1872:Bk
1869:Cm
1866:Am
1863:Pu
1860:Np
1843:Pa
1820:**
1805:Tm
1802:Er
1779:Tb
1746:Pm
1743:Nd
1689:Og
1686:Ts
1683:Lv
1680:Mc
1677:Fl
1674:Nh
1671:Cn
1668:Rg
1665:Ds
1662:Mt
1659:Hs
1656:Bh
1653:Sg
1650:Db
1647:Rf
1644:Lr
1641:**
1638:Ra
1635:Fr
1630:Rn
1627:At
1624:Po
1545:Ir
1542:Os
1539:Re
1528:Ta
1525:Hf
1492:Xe
1488:ICN
1410:Rh
1407:Ru
1404:Tc
1393:Nb
1390:Zr
1358:Kr
1297:(CH
1171:Mn
1157:Ti
1131:KCN
1125:Ar
1093:SCN
1068:(CH
1027:Ne
1023:FCN
1004:OCN
987:NCN
920:He
910:HCN
897:ion
804:doi
758:PMC
750:doi
705:doi
499:in
476:in
197:EPA
150:CID
1906::
1848:UO
1701:*
1578:Hg
1512:*
1311:(C
1160:V
997:CN
973:CN
969:NH
829:.
825:.
802:.
790:.
766:.
756:.
746:71
744:.
740:.
711:.
689:^
661:^
612:K4
533:.
526:.
517:CO
438:nm
424::
397:.
288:Fe
1854:2
1850:2
1837:4
1827:3
1812:3
1796:3
1786:3
1773:3
1763:3
1753:3
1737:3
1727:4
1718:3
1708:3
1618:3
1608:2
1593:2
1584:2
1580:2
1571:2
1558:6
1551:4
1534:8
1519:3
1506:2
1481:4
1472:2
1462:3
1452:2
1442:3
1432:2
1417:2
1399:8
1384:3
1372:2
1347:2
1338:2
1321:2
1319:)
1317:5
1315:H
1313:6
1303:2
1301:)
1299:3
1290:3
1280:4
1271:2
1261:3
1251:2
1237:4
1230:4
1222:2
1211:5
1200:2
1191:6
1184:6
1177:2
1166:6
1151:3
1139:2
1114:2
1105:2
1085:3
1074:3
1072:)
1070:3
1061:4
1051:3
1041:2
1016:2
995:3
993:N
985:2
983:O
971:4
962:2
958:2
956:C
951:4
943:3
934:2
886:e
879:t
872:v
843:.
810:.
806::
798::
792:6
774:.
752::
736:2
721:.
707::
683:.
519:2
503:(
493:6
489:2
371:6
367:4
294:6
291:N
285:6
282:C
199:)
195:(
66:)
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