36:
27:
296:
646:
values, decomposing to iron(III): The reduction goes through intermediate species in which iron has oxidation states +5 and +4. These anions are even more reactive than ferrate(VI). In alkaline conditions ferrates are more stable, lasting for about 8 to 9 hours at pH 8 or 9.
346:, contributes a pale violet colour to compounds and solutions containing it and is one of the strongest water-stable oxidizing species known. Although it is classified as a
697:. They are also of interest as potential as an environmentally friendly water treatment chemical, as the byproduct of ferrate oxidation is the relatively benign iron(III).
711:) is a useful reagent with good selectivity and is stable in aqueous solution of high pH, remaining soluble in an aqueous solution saturated with sodium hydroxide.
538:
Fe(VI) is a strong oxidizing agent over the entire pH range, with a reduction potential (Fe(VI)/Fe(III) couple) varying from +2.2 V to +0.7 V versus
309:
412:
236:
1802:
1056:
650:
Aqueous solutions of ferrates are pink when dilute, and deep red or purple at higher concentrations. The ferrate ion is a stronger
1609:
1592:
110:
103:
1203:
787:
1146:
304:
2146:
975:
925:
900:
875:
847:
817:
759:
201:
316:
1789:
1637:
678:
343:
350:, concentrated solutions containing ferrate(VI) are corrosive and attack the skin and are only stable at high
1975:
1091:
385:
68:
1079:
1049:
26:
1653:
1553:
539:
384:, many of which are more commonly encountered than salts of . These include the highly reduced species
1943:
1421:
1265:
2141:
1806:
1347:
942:
1995:
1819:
1042:
1134:
150:
439:, or in the solid state by heating a mixture of iron filings and powdered potassium nitrate.
58:
1717:
1293:
1195:
451:
8:
1811:
1122:
447:
443:
332:
130:
2063:
1887:
1839:
1764:
1756:
1705:
1537:
1461:
1445:
1397:
1326:
1114:
559:
2136:
2084:
1915:
1903:
1777:
1748:
1684:
1453:
1433:
1377:
1372:
1285:
1277:
1020:
1012:
971:
921:
915:
896:
871:
843:
813:
783:
755:
725:
670:
187:
35:
1797:
1740:
1521:
1501:
1481:
1469:
1385:
1339:
1334:
1305:
1257:
1004:
993:"Ferrates: Greener Oxidants with Multimodal Action in Water Treatment Technologies"
720:
436:
339:
264:
2015:
1931:
1875:
1413:
1313:
1185:
651:
162:
2096:
1855:
1772:
1689:
1321:
1065:
837:
730:
527:
287:
2130:
1016:
992:
674:
1237:
1024:
690:
655:
355:
44:
642:
Because of this, the ferrate(VI) anion is unstable at neutral or acidic
2115:
275:
141:
1008:
1576:
485:
376:
is normally used to mean ferrate(VI), although it can refer to other
286:
Except where otherwise noted, data are given for materials in their
663:
416:
347:
916:
Kenneth
Malcolm Mackay; Rosemary Ann Mackay; W. Henderson (2002).
109:
102:
1034:
659:
432:
367:
174:
991:
Sharma, Virender K.; Zboril, Radek; Varma, Rajender S. (2015).
523:
694:
500:
428:
381:
335:
121:
92:
838:
Egon Wiberg; Nils Wiberg; Arnold
Frederick Holleman (2001).
377:
948:. Water Resources Center, Ohio State University. p. 3
411:
and salts of the iron(III) complex tetrachloroferrate in
681:, isostructural with the chromate and permanganate ions.
415:. Although rarely studied, ferrate(V) and ferrate(IV)
1968:
943:"Oxidation of Ammonia in Water by Ferrates(VI) and (IV)"
1569:
643:
351:
1194:
895:(5th ed.). Oxford University Press. p. 235.
866:
Gary M. Brittenham (1994). Raymond J. Bergeron (ed.).
749:
419:
of iron also exist. These too are called ferrates.
965:
868:The Development of Iron Chelators for Clinical Use
865:
990:
2128:
782:. Discovery Publishing House. pp. 124–125.
186:
812:. University Science Books. pp. 142–143.
807:
442:For example, ferrates are produced by heating
413:1-Butyl-3-methylimidazolium tetrachloroferrate
1050:
940:
920:(6th ed.). CRC Press. pp. 334–335.
890:
810:Principles of descriptive inorganic chemistry
754:(5th ed.). Nelson Thornes. p. 202.
693:, and are capable of removing and destroying
777:
354:. It is similar to the somewhat more stable
803:
801:
799:
522:The anion is typically precipitated as the
220:InChI=1/Fe.4O/q;;;2*-1/rFeO4/c2-1(3,4)5/q-2
1057:
1043:
918:Introduction to modern inorganic chemistry
861:
859:
435:medium with strong oxidizing agents under
149:
970:(8th ed.). CRC Press. p. 234.
833:
831:
829:
796:
773:
771:
542:in acidic and basic media respectively.
856:
2129:
842:. Academic Press. pp. 1457–1458.
1038:
909:
826:
768:
213:Key: XGBDPAYTQGQHEW-UHFFFAOYSA-N
129:
780:Text Book Of Coordination Chemistry
743:
223:Key: XGBDPAYTQGQHEW-WTZHFVRHAI
177:
13:
1064:
14:
2158:
750:Graham Hill; John Holman (2000).
427:Ferrate(VI) salts are formed by
294:
34:
25:
984:
684:
361:
290:(at 25 °C , 100 kPa).
959:
934:
893:Oxford dictionary of chemistry
884:
679:tetrahedral molecular geometry
1:
997:Accounts of Chemical Research
870:. CRC Press. pp. 37–38.
736:
533:
386:disodium tetracarbonylferrate
669:The ferrate(VI) ion has two
422:
7:
966:Stanley E. Manahan (2005).
941:Karlis Svanks (June 1976).
891:John Daintith, ed. (2004).
714:
280:119.843 g mol
41:Solutions of ferrate (left)
10:
2163:
2147:Transition metal oxyanions
365:
2108:
2077:
2056:
1969:Organoiron(III) compounds
1733:
1698:
1677:
1250:
1230:
1178:
1107:
1072:
588:= +2.20 V (acidic medium)
284:
257:
232:
197:
84:
79:
67:
57:
52:
33:
24:
1570:Organoiron(II) compounds
638:= +0.72 V (basic medium)
968:Environmental chemistry
808:Gary Wulfsberg (1991).
689:Ferrates are excellent
210:InChI=1S/Fe.4O/q;;;2*-1
73:Tetraoxoironbis(olate)
778:R. K. Sharma (2007).
69:Systematic IUPAC name
2116:Hemolithin (protein)
752:Chemistry in context
840:Inorganic chemistry
448:sodium hypochlorite
444:iron(III) hydroxide
437:alkaline conditions
21:
671:unpaired electrons
317:Infobox references
19:
2124:
2123:
2052:
2051:
1673:
1672:
1226:
1225:
1009:10.1021/ar5004219
789:978-81-8356-223-2
726:Potassium ferrate
325:Chemical compound
323:
322:
111:Interactive image
104:Interactive image
2154:
2142:Oxidizing agents
2069:
2044:
2043:
2042:
2034:
2033:
2025:
2024:
1966:
1965:
1567:
1566:
1192:
1191:
1059:
1052:
1045:
1036:
1035:
1029:
1028:
988:
982:
981:
963:
957:
956:
954:
953:
947:
938:
932:
931:
913:
907:
906:
888:
882:
881:
863:
854:
853:
835:
824:
823:
805:
794:
793:
775:
766:
765:
747:
721:High-valent iron
710:
700:Sodium ferrate (
630:
629:
628:
619:
618:
617:
607:
599:
598:
597:
580:
572:
571:
570:
558:
554:
553:
552:
518:
517:
516:
507:
497:
496:
495:
484:
480:
479:
478:
469:
468:
467:
410:
398:
340:chemical formula
307:
301:
298:
297:
265:Chemical formula
190:
179:
163:Gmelin Reference
153:
133:
113:
106:
38:
29:
22:
18:
2162:
2161:
2157:
2156:
2155:
2153:
2152:
2151:
2127:
2126:
2125:
2120:
2104:
2100:
2092:
2088:
2073:
2068:
2064:
2048:
2041:
2038:
2037:
2036:
2032:
2029:
2028:
2027:
2023:
2020:
2019:
2018:
2016:
2011:
2007:
2003:
1999:
1991:
1987:
1983:
1979:
1964:
1959:
1955:
1951:
1947:
1939:
1935:
1927:
1923:
1919:
1911:
1907:
1899:
1895:
1891:
1883:
1879:
1871:
1867:
1863:
1859:
1851:
1847:
1843:
1835:
1831:
1827:
1823:
1815:
1793:
1785:
1781:
1768:
1760:
1752:
1744:
1729:
1725:
1721:
1713:
1709:
1694:
1669:
1665:
1661:
1657:
1649:
1645:
1641:
1633:
1629:
1625:
1621:
1617:
1613:
1604:
1600:
1596:
1588:
1584:
1580:
1565:
1561:
1557:
1549:
1545:
1541:
1533:
1529:
1525:
1517:
1513:
1509:
1505:
1497:
1493:
1489:
1485:
1477:
1473:
1465:
1457:
1449:
1441:
1437:
1429:
1425:
1417:
1409:
1405:
1401:
1393:
1389:
1381:
1367:
1363:
1359:
1355:
1351:
1343:
1330:
1317:
1309:
1301:
1297:
1289:
1281:
1273:
1269:
1261:
1246:
1241:
1222:
1219:
1215:
1211:
1207:
1190:
1174:
1170:
1166:
1162:
1158:
1154:
1150:
1142:
1138:
1130:
1126:
1118:
1103:
1099:
1095:
1087:
1083:
1068:
1063:
1033:
1032:
989:
985:
978:
964:
960:
951:
949:
945:
939:
935:
928:
914:
910:
903:
889:
885:
878:
864:
857:
850:
836:
827:
820:
806:
797:
790:
776:
769:
762:
748:
744:
739:
717:
709:
705:
701:
687:
658:, and oxidizes
652:oxidizing agent
637:
627:
625:
624:
623:
621:
616:
613:
612:
611:
609:
605:
601:
596:
594:
593:
592:
591:
587:
578:
574:
569:
567:
566:
565:
563:
556:
551:
549:
548:
547:
546:
536:
515:
513:
512:
511:
509:
504:
499:
494:
492:
491:
490:
489:
482:
477:
475:
474:
473:
471:
466:
463:
462:
461:
459:
425:
408:
404:
400:
396:
392:
388:
370:
364:
326:
319:
314:
313:
312: ?)
303:
299:
295:
291:
267:
253:
250:
245:
240:
239:
228:
225:
224:
221:
215:
214:
211:
205:
204:
193:
180:
165:
156:
136:
116:
96:
75:
74:
63:
48:
42:
39:
17:
12:
11:
5:
2160:
2150:
2149:
2144:
2139:
2122:
2121:
2119:
2118:
2112:
2110:
2106:
2105:
2103:
2102:
2098:
2094:
2090:
2086:
2081:
2079:
2075:
2074:
2072:
2071:
2066:
2060:
2058:
2054:
2053:
2050:
2049:
2047:
2046:
2039:
2030:
2021:
2013:
2009:
2005:
2001:
1997:
1993:
1989:
1985:
1981:
1977:
1972:
1970:
1963:
1962:
1957:
1953:
1949:
1945:
1941:
1937:
1933:
1929:
1925:
1921:
1917:
1913:
1909:
1905:
1901:
1897:
1893:
1889:
1885:
1881:
1877:
1873:
1869:
1865:
1861:
1857:
1853:
1849:
1845:
1841:
1837:
1833:
1829:
1825:
1821:
1817:
1813:
1809:
1804:
1800:
1795:
1791:
1787:
1783:
1779:
1775:
1770:
1766:
1762:
1758:
1754:
1750:
1746:
1742:
1737:
1735:
1731:
1730:
1728:
1727:
1723:
1719:
1715:
1711:
1707:
1702:
1700:
1696:
1695:
1693:
1692:
1687:
1681:
1679:
1675:
1674:
1671:
1670:
1668:
1667:
1663:
1659:
1655:
1651:
1647:
1643:
1639:
1635:
1631:
1627:
1623:
1619:
1615:
1611:
1607:
1602:
1598:
1594:
1590:
1586:
1582:
1578:
1573:
1571:
1564:
1563:
1559:
1555:
1551:
1547:
1543:
1539:
1535:
1531:
1527:
1523:
1519:
1515:
1511:
1507:
1503:
1499:
1495:
1491:
1487:
1483:
1479:
1475:
1471:
1467:
1463:
1459:
1455:
1451:
1447:
1443:
1439:
1435:
1431:
1427:
1423:
1419:
1415:
1411:
1407:
1403:
1399:
1395:
1391:
1387:
1383:
1379:
1375:
1370:
1365:
1361:
1357:
1353:
1349:
1345:
1341:
1337:
1332:
1328:
1324:
1319:
1315:
1311:
1307:
1303:
1299:
1295:
1291:
1287:
1283:
1279:
1275:
1271:
1267:
1263:
1259:
1254:
1252:
1248:
1247:
1245:
1244:
1239:
1234:
1232:
1228:
1227:
1224:
1223:
1221:
1217:
1213:
1209:
1205:
1201:
1199:
1189:
1188:
1182:
1180:
1176:
1175:
1173:
1172:
1168:
1164:
1160:
1156:
1152:
1148:
1144:
1140:
1136:
1132:
1128:
1124:
1120:
1116:
1111:
1109:
1105:
1104:
1102:
1101:
1097:
1093:
1089:
1085:
1081:
1076:
1074:
1070:
1069:
1066:Iron compounds
1062:
1061:
1054:
1047:
1039:
1031:
1030:
1003:(2): 182–191.
983:
976:
958:
933:
926:
908:
901:
883:
876:
855:
848:
825:
818:
795:
788:
767:
760:
741:
740:
738:
735:
734:
733:
731:Barium ferrate
728:
723:
716:
713:
707:
703:
686:
683:
640:
639:
635:
626:
614:
603:
595:
589:
585:
576:
568:
550:
535:
532:
528:barium ferrate
526:salt, forming
520:
519:
514:
502:
493:
476:
464:
424:
421:
406:
402:
394:
390:
363:
360:
344:photosensitive
324:
321:
320:
315:
293:
292:
288:standard state
285:
282:
281:
278:
272:
271:
268:
263:
260:
259:
255:
254:
252:
251:
248:
246:
243:
235:
234:
233:
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227:
226:
222:
219:
218:
216:
212:
209:
208:
200:
199:
198:
195:
194:
192:
191:
183:
181:
173:
170:
169:
166:
161:
158:
157:
155:
154:
146:
144:
138:
137:
135:
134:
126:
124:
118:
117:
115:
114:
107:
99:
97:
90:
87:
86:
82:
81:
77:
76:
72:
71:
65:
64:
61:
55:
54:
50:
49:
40:
31:
30:
15:
9:
6:
4:
3:
2:
2159:
2148:
2145:
2143:
2140:
2138:
2135:
2134:
2132:
2117:
2114:
2113:
2111:
2107:
2101:
2095:
2093:
2083:
2082:
2080:
2076:
2070:
2062:
2061:
2059:
2055:
2045:
2014:
2012:
1994:
1992:
1974:
1973:
1971:
1967:
1961:
1942:
1940:
1930:
1928:
1914:
1912:
1902:
1900:
1886:
1884:
1874:
1872:
1854:
1852:
1838:
1836:
1818:
1816:
1810:
1808:
1805:
1803:
1801:
1799:
1796:
1794:
1788:
1786:
1776:
1774:
1771:
1769:
1763:
1761:
1755:
1753:
1747:
1745:
1739:
1738:
1736:
1732:
1726:
1716:
1714:
1704:
1703:
1701:
1697:
1691:
1688:
1686:
1683:
1682:
1680:
1676:
1666:
1652:
1650:
1636:
1634:
1608:
1606:
1591:
1589:
1575:
1574:
1572:
1568:
1562:
1552:
1550:
1536:
1534:
1520:
1518:
1500:
1498:
1480:
1478:
1468:
1466:
1460:
1458:
1452:
1450:
1444:
1442:
1432:
1430:
1420:
1418:
1412:
1410:
1396:
1394:
1384:
1382:
1376:
1374:
1371:
1369:
1346:
1344:
1338:
1336:
1333:
1331:
1325:
1323:
1320:
1318:
1312:
1310:
1304:
1302:
1292:
1290:
1284:
1282:
1276:
1274:
1264:
1262:
1256:
1255:
1253:
1249:
1243:
1236:
1235:
1233:
1229:
1220:
1202:
1200:
1198:(I) compounds
1197:
1193:
1187:
1184:
1183:
1181:
1177:
1171:
1145:
1143:
1133:
1131:
1121:
1119:
1113:
1112:
1110:
1106:
1100:
1090:
1088:
1078:
1077:
1075:
1071:
1067:
1060:
1055:
1053:
1048:
1046:
1041:
1040:
1037:
1026:
1022:
1018:
1014:
1010:
1006:
1002:
998:
994:
987:
979:
977:1-56670-633-5
973:
969:
962:
944:
937:
929:
927:0-7487-6420-8
923:
919:
912:
904:
902:0-19-860918-3
898:
894:
887:
879:
877:0-8493-8679-9
873:
869:
862:
860:
851:
849:0-12-352651-5
845:
841:
834:
832:
830:
821:
819:0-935702-66-0
815:
811:
804:
802:
800:
791:
785:
781:
774:
772:
763:
761:0-17-448276-0
757:
753:
746:
742:
732:
729:
727:
724:
722:
719:
718:
712:
698:
696:
692:
691:disinfectants
682:
680:
676:
672:
667:
665:
662:to molecular
661:
657:
653:
648:
645:
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986:
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950:. Retrieved
936:
917:
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886:
867:
839:
809:
779:
751:
745:
699:
688:
685:Applications
675:paramagnetic
673:and is thus
668:
656:permanganate
649:
641:
632:
582:
537:
521:
450:in alkaline
441:
426:
380:-containing
373:
371:
362:Nomenclature
356:permanganate
328:
327:
85:Identifiers
80:Other names
45:permanganate
20:Ferrate(VI)
677:. It has a
431:iron in an
405:[Fe(CO)
393:[Fe(CO)
329:Ferrate(VI)
258:Properties
131:CHEBI:30992
62:Ferrate(VI)
2131:Categories
1699:Fe(II,III)
1196:Organoiron
952:2010-05-04
737:References
534:Properties
524:barium(II)
366:See also:
276:Molar mass
142:ChemSpider
91:3D model (
59:IUPAC name
2109:Purported
1678:Fe(0,III)
1017:0001-4842
429:oxidizing
423:Synthesis
417:oxyanions
372:The term
348:weak base
338:with the
333:inorganic
2137:Ferrates
2008:⋅xFe⋅yNH
1790:Fe(acac)
1231:Fe(0,II)
1025:25668700
715:See also
664:nitrogen
608:+ 3 e ⇌
562:+ 3 e ⇌
452:solution
342:. It is
249:(=O)(=O)
244:()(=O)=O
188:25000034
151:21865127
1807:FeO(OH)
1734:Fe(III)
1073:Fe(-II)
695:viruses
660:ammonia
557:
483:
433:aqueous
374:ferrate
368:Ferrate
331:is the
310:what is
308: (
270:
175:PubChem
47:(right)
2078:Fe(VI)
2057:Fe(IV)
1662:Fe(CO)
1646:Fe(CO)
1327:Fe(OH)
1294:Fe(ClO
1251:Fe(II)
1147:Fe(CO)
1115:Fe(CO)
1096:Fe(CO)
1084:Fe(CO)
1023:
1015:
974:
924:
899:
874:
846:
816:
786:
758:
610:Fe(OH)
460:Fe(OH)
382:anions
305:verify
302:
237:SMILES
53:Names
2097:BaFeO
1948:Fe(SO
1798:FeOCl
1778:Fe(NO
1601:)(CO)
1454:FeTiO
1446:FeMoO
1422:Fe(BF
1386:Fe(NO
1378:FeSeO
1356:Fe(SO
1212:FeCO)
1179:Fe(I)
1108:Fe(0)
946:(PDF)
654:than
446:with
336:anion
202:InChI
168:2055
122:ChEBI
93:JSmol
1976:Fe(C
1956:·12H
1932:Fe(N
1892:(SeO
1844:(CrO
1812:FePO
1757:FeCl
1749:FeBr
1690:FeGe
1685:FeSi
1610:Fe(C
1593:Fe(C
1577:Fe(C
1558:(CO)
1502:Fe(C
1482:Fe(C
1462:FeCO
1434:FeCr
1414:FeSi
1373:FeSe
1340:FeSO
1306:FeBr
1286:FeCl
1216:(CO)
1139:(CO)
1127:(CO)
1021:PMID
1013:ISSN
972:ISBN
922:ISBN
897:ISBN
872:ISBN
844:ISBN
814:ISBN
784:ISBN
756:ISBN
620:+ 5
600:+ 4
573:+ 4
555:+ 8
508:+ 3
498:+ 5
488:→ 2
481:+ 4
470:+ 3
378:iron
43:and
2089:FeO
2065:FeF
2035:FeO
2031:105
1920:(SO
1773:FeP
1765:FeF
1741:FeI
1618:P(C
1554:FeI
1538:FeC
1522:FeC
1470:FeC
1402:(PO
1364:·6H
1348:(NH
1335:FeS
1322:FeO
1314:FeI
1278:FeF
1270:FeH
1258:FeH
1186:FeH
1155:COC
1005:doi
706:FeO
540:SHE
472:OCl
178:CID
16:Ion
2133::
2022:54
1988:BF
1944:NH
1916:Fe
1904:Fe
1888:Fe
1876:Fe
1860:(C
1856:Fe
1840:Fe
1824:(P
1820:Fe
1718:Fe
1706:Fe
1548:14
1544:22
1540:12
1398:Fe
1266:Mg
1238:Fe
1204:(C
1151:CH
1141:12
1135:Fe
1123:Fe
1092:Na
1019:.
1011:.
1001:48
999:.
995:.
858:^
828:^
798:^
770:^
702:Na
666:.
644:pH
631:;
622:OH
581:;
564:Fe
530:.
510:Cl
486:OH
458:2
454::
399:,
389:Na
358:.
352:pH
2099:4
2091:4
2087:2
2085:K
2067:4
2040:6
2026:H
2017:C
2010:3
2006:7
2004:O
2002:8
2000:H
1998:6
1996:C
1990:4
1986:2
1984:)
1982:5
1980:H
1978:5
1960:O
1958:2
1954:2
1952:)
1950:4
1946:4
1938:3
1936:)
1934:3
1926:3
1924:)
1922:4
1918:2
1910:3
1908:S
1906:2
1898:3
1896:)
1894:3
1890:2
1882:3
1880:O
1878:2
1870:3
1868:)
1866:4
1864:O
1862:2
1858:2
1850:3
1848:)
1846:4
1842:2
1834:3
1832:)
1830:7
1828:O
1826:2
1822:4
1814:4
1792:3
1784:3
1782:)
1780:3
1767:3
1759:3
1751:3
1743:3
1724:4
1722:S
1720:3
1712:4
1710:O
1708:3
1664:3
1660:6
1658:H
1656:4
1654:C
1648:3
1644:4
1642:H
1640:4
1638:C
1632:2
1630:)
1628:2
1626:)
1624:5
1622:H
1620:6
1616:4
1614:H
1612:5
1605:I
1603:2
1599:5
1597:H
1595:5
1587:2
1585:)
1583:5
1581:H
1579:5
1560:4
1556:2
1546:O
1542:H
1532:7
1530:O
1528:6
1526:H
1524:6
1516:2
1514:)
1512:3
1510:O
1508:5
1506:H
1504:3
1496:2
1494:)
1492:2
1490:O
1488:3
1486:H
1484:2
1476:4
1474:O
1472:2
1464:3
1456:3
1448:4
1440:4
1438:O
1436:2
1428:2
1426:)
1424:4
1416:2
1408:2
1406:)
1404:4
1400:3
1392:2
1390:)
1388:3
1380:4
1368:O
1366:2
1362:2
1360:)
1358:4
1354:2
1352:)
1350:4
1342:4
1329:2
1316:2
1308:2
1300:2
1298:)
1296:4
1288:2
1280:2
1272:6
1268:2
1260:2
1242:C
1240:3
1218:2
1214:2
1210:5
1208:H
1206:5
1169:6
1167:H
1165:6
1163:C
1161:2
1159:H
1157:2
1153:3
1149:3
1137:3
1129:9
1125:2
1117:5
1098:4
1094:2
1086:4
1082:2
1080:H
1058:e
1051:t
1044:v
1027:.
1007::
980:.
955:.
930:.
905:.
880:.
852:.
822:.
792:.
764:.
708:4
704:2
636:0
633:E
615:3
606:O
604:2
602:H
586:0
583:E
579:O
577:2
575:H
560:H
505:O
503:2
501:H
465:3
409:]
407:4
403:2
401:K
397:]
395:4
391:2
300:Y
95:)
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