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Base (chemistry)

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2640:. ... In 1754 Rouelle explicitly defined a neutral salt as the product formed by the union of an acid with any substance, be it a water-soluble alkali, a volatile alkali, an absorbent earth, a metal, or an oil, capable of serving as "a base" for the salt "by giving it a concrete or solid form." Most acids known in the 18th century were volatile liquids or "spirits" capable of distillation, whereas salts, by their very nature, were crystalline solids. Hence it was the substance that neutralized the acid which supposedly destroyed the volatility or spirit of the acid and which imparted the property of solidity (i.e., gave a concrete base) to the resulting salt. 78: 46: 3309: 2316:
catalyst. Scientists have developed two methods to measure the amount of basic sites: one, titration with benzoic acid using indicators and gaseous acid adsorption. A solid with enough basic strength will absorb an electrically neutral acidic indicator and cause the acidic indicator's color to change to the color of its conjugate base. When performing the gaseous acid adsorption method,
942: 2471: 3131: 2636:, Paracelsus had postulated that naturally occurring salts grew within the earth as a result of a universal acid or seminal principle having impregnated an earthy matrix or womb. ... Its modern meaning and general introduction into the chemical vocabulary, however, is usually attributed to the French chemist, 1559:
One advantage of this low solubility is that "many antacids were suspensions of metal hydroxides such as aluminium hydroxide and magnesium hydroxide"; compounds with low solubility and the ability to stop an increase in the concentration of the hydroxide ion, preventing the harm of the tissues in the
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Depending on a solid surface's ability to successfully form a conjugate base by absorbing an electrically neutral acid, basic strength of the surface is determined. The "number of basic sites per unit surface area of the solid" is used to express how much basic strength is found on a solid base
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A base is also defined as a molecule that has the ability to accept an electron pair bond by entering another atom's valence shell through its possession of one electron pair. There are a limited number of elements that have atoms with the ability to provide a molecule with basic properties.
2229:, when a neutral base forms a bond with a neutral acid, a condition of electric stress occurs. The acid and the base share the electron pair that formerly belonged to the base. As a result, a high dipole moment is created, which can only be decreased to zero by rearranging the molecules. 1567:." In this process, the water molecule combines with a strong base, due to the water's amphoteric ability; and, a hydroxide ion is released. Very strong bases can even deprotonate very weakly acidic C–H groups in the absence of water. Here is a list of several strong bases: 582:
donor which can share a pair of electrons with an electron acceptor which is described as a Lewis acid. The Lewis theory is more general than the Brønsted model because the Lewis acid is not necessarily a proton, but can be another molecule (or ion) with a vacant low-lying
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tend to be even stronger bases due to the extreme weakness of their conjugate acids, which are stable hydrocarbons, amines, and dihydrogen. Usually, these bases are created by adding pure alkali metals such as sodium into the conjugate acid. They are called
524:. This does include aqueous hydroxides since OH does react with H to form water, so that Arrhenius bases are a subset of Brønsted bases. However, there are also other Brønsted bases which accept protons, such as aqueous solutions of 1763:
The cations of these strong bases appear in the first and second groups of the periodic table (alkali and earth alkali metals). Tetraalkylated ammonium hydroxides are also strong bases since they dissociate completely in water.
832: 933:(the conjugate base OH) compete for the proton. As a result, bases that react with water have relatively small equilibrium constant values. The base is weaker when it has a lower equilibrium constant value. 77: 1390: 1951: 2922: 1473: 1111: 1544:) a molecule of even a very weak acid (such as water) in an acid–base reaction. Common examples of strong bases include hydroxides of alkali metals and alkaline earth metals, like NaOH and 2534: 1226: 1021: 924: 653: 2418:(or sodium hydrogen carbonate) is used as baking soda in cooking food, for making baking powders, as an antacid to cure indigestion and in soda acid fire extinguisher. 3186: 1522:, which cannot exist in a water solution due to the acidity of water. Resonance stabilization, however, enables weaker bases such as carboxylates; for example, 1984: 1556:, respectively. Due to their low solubility, some bases, such as alkaline earth hydroxides, can be used when the solubility factor is not taken into account. 540:). These bases do not contain a hydroxide ion but nevertheless react with water, resulting in an increase in the concentration of hydroxide ion. Also, some 1560:
mouth, oesophagus, and stomach. As the reaction continues and the salts dissolve, the stomach acid reacts with the hydroxide produced by the suspensions.
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Weak bases, such as baking soda or egg white, should be used to neutralize any acid spills. Neutralizing acid spills with strong bases, such as
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The following reaction represents the general reaction between a base (B) and water to produce a conjugate acid (BH) and a conjugate base (OH):
631:: bases turn red litmus paper blue, phenolphthalein pink, keep bromothymol blue in its natural colour of blue, and turn methyl orange-yellow. 489:
O) concentration in water, whereas bases reduce this concentration. A reaction between aqueous solutions of an acid and a base is called
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Bases react with acids to neutralize each other at a fast rate both in water and in alcohol. When dissolved in water, the strong base
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If equal quantities of NaOH and HCl are dissolved, the base and the acid neutralize exactly, leaving only NaCl, effectively
1831:.) For example, the ethoxide ion (conjugate base of ethanol) undergoes this reaction quantitatively in presence of water. 1246:, can cause a violent exothermic reaction, and the base itself can cause just as much damage as the original acid spill. 420:
hydroxide solutions were also described by certain characteristic properties. They are slippery to the touch, can taste
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of the base. On the basis of acidity bases can be classified into three types: monoacidic, diacidic and triacidic.
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is a special case of a species that is exceptionally stable when protonated, analogously to the reason that makes
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and high oxidation state metal ions such as Ag, Fe and Mn. Adducts involving metal ions are usually described as
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is used. The basic sites are then determined by calculating the amount of carbon dioxide that is absorbed.
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Magnesium hydroxide is used as an 'antacid' to neutralize excess acid in the stomach and cure indigestion.
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of electrons which can be shared with a low-energy vacant orbital in an acceptor molecule to form an
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Whitten, Kenneth W.; Peck, Larry; Davis, Raymond E.; Lockwood, Lisa; Stanley, George G. (2009).
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Bases and acids are seen as chemical opposites because the effect of an acid is to increase the
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of both bases and acids have been proposed in the past, but are not commonly used today.
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since they can accept one proton (H). Bases with more than one OH- per formula unit are
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make good catalysts, many of which form basic substances. Basic catalysts are used for
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realized that water, ammonia, and other bases can form a bond with a proton due to the
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Sodium hydroxide is used in the manufacture of soap, paper, and the synthetic fiber
827:{\displaystyle {\ce {{B}_{(aq)}+ {H2O}_{(l)}<=> {BH+}_{(aq)}+ {OH- }_{(aq)}}}} 3243: 2861: 2845: 2543: 2537: 2503: 2495: 2474: 2409: 2377: 2361: 2226: 2142: 1683: 1613: 1583: 1255: 1239: 969: 494: 417: 406: 390: 382: 112: 57: 3153: 2783: 2341: 2182:
for this reaction at 25 Â°C is 1.8 x 10, such that the extent of reaction or
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A strong base is a basic chemical compound that can remove a proton (H) from (or
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in which the salt separates into its component ions. If the aqueous solution is
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The term "base" appears to have been first used in 1717 by the French chemist,
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Calcium hydroxide (slaked lime) is used in the manufacture of bleaching powder.
2030: 1960: 1787: 1523: 1499: 1274: 584: 471: 354: 2403:, which is caused by the exhaust, that is found in power plants and factories. 401:(H according to Arrhenius) from the dissociation of acids to form water in an 3325: 3187:"Introduction to Bases: Classification, Examples with Questions & Videos" 2724: 2669: 2365: 2345: 1813: 1773: 579: 475: 455: 107: 941: 2349: 2317: 2020: 1511: 628: 429: 425: 280: 231: 226: 221: 137: 3313: 2470: 1254:
Bases are generally compounds that can neutralize an amount of acid. Both
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Charcoal that has been treated at 900 degrees Celsius or activates with N
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Petrucci, Ralph H.; Harwood, William S.; Herring, F. Geoffrey (2002).
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Strong bases hydrolyze in water almost completely, resulting in the
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higher than 7.0 at standard conditions. A soluble base is called an
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Whitten, Kenneth W.; Gailey, Kenneth D.; Davis, Raymond E. (1992).
2458:(OH) ions present in one formula unit of a base is also called the 2333: 1503: 1491: 571: 467: 370:. All definitions agree that bases are substances that react with 2633: 2617: 2357: 2150: 1507: 1259: 945: 638:
of a basic solution at standard conditions is greater than seven.
525: 502: 1482:, or acidity, can be calculated for aqueous solutions of bases. 2905: 2903: 2901: 2899: 2811: 2809: 2754: 2752: 2750: 2748: 2746: 2207: 1495: 1487: 521: 451: 38: 2390: 1385:{\displaystyle {\ce {Na2CO3 + H2O -> 2Na+ + HCO3- + OH-}}} 618:
on organic matter and react violently with acidic substances.
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which can accept a pair of electrons. One notable example is
537: 3154:"Electrophile – Nucleophile – Basicity – Acidity – pH Scale" 2896: 2884: 2806: 2764: 2743: 2731: 2664: 1946:{\displaystyle {\ce {CH3CH2O- + H2O -> CH3CH2OH + OH-}}} 624:
or molten bases dissociate in ions and conduct electricity.
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of more than about 13 are considered very weak, and their
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are bases, although neither of these substances contains
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is lower than it is in pure water, i.e., the water has a
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Strongest superbases are synthesised in only gas phase:
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Investigating chemistry: a forensic science perspective
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transfers a proton to water according to the equation
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is the basic ion species which accepts protons from NH
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New Solid Acids and Bases: their catalytic properties
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Tanabe, K.; Misono, M.; Ono, Y.; Hattori, H. (1990).
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General Chemistry. Principles and Modern Applications
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is used as washing soda and for softening hard water.
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A weak base is one which does not fully ionize in an
1840: 1399: 1286: 1156: 1039: 981: 847: 656: 645: 3079: 3077: 3075: 3073: 3071: 3069: 3067: 3269: 3215: 2947: 2428: 2279:on alumina; NaOH, KOH mounted on silica on alumina 2214:(Lewis acids) include neutral molecules such as BF 1945: 1468:{\displaystyle {\ce {NH3 + H2O -> NH4+ + OH-}}} 1467: 1384: 1273:groups. Both compounds accept H when dissolved in 1220: 1106:{\displaystyle {\ce {HCl + H2O -> H3O+ + Cl-}}} 1105: 1015: 918: 826: 442:, bases yield solutions in which the hydrogen ion 3035:Solid Acids and Bases: their catalytic properties 3002:(2nd ed.). Prentice-Hall. pp. 157–159. 2915: 929:In this equation, the base (B) and the extremely 749: 748: 731: 730: 405:. A base was therefore a metal hydroxide such as 3323: 3064: 2709:(2nd ed.). New York: W. H. Freeman and Co. 1514:. Bases of carbon, nitrogen and oxygen without 1249: 3290: 3267: 2909: 2890: 2815: 2770: 2758: 2737: 516:(1923), a base is a substance that can accept 1221:{\displaystyle {\ce {H3O+ + OH- -> 2H2O}}} 325: 2997: 2977:(8th ed.). Prentice Hall. p. 678. 2672:(used in ecology, referring to environments) 2632:term "matrix." In keeping with 16th-century 2488:ion, the base is said to be a monoacidic or 2424:is used to remove grease stains from clothes 2399:Calcium hydroxide is also used to clean the 2076:) (the strongest superbase ever synthesized) 1016:{\displaystyle {\ce {NaOH -> Na+ + OH-}}} 2998:Miessler, Gary L.; Tarr, Donald A. (1999). 2202:is a molecule with one or more high-energy 2590:ions, the base is said to be triacidic or 1518:stabilization are usually very strong, or 936: 385:proposed that a base is a substance which 332: 318: 3291:Zumdahl, Steven; DeCoste, Donald (2013). 3027: 3025: 3023: 3021: 3019: 2840: 2838: 2836: 2834: 2832: 2830: 2828: 2826: 2824: 2526:ions, the base is said to be diacidic or 2480:When one molecule of a base via complete 2340:. Some examples are metal oxides such as 2225:According to the original formulation of 1339: 1200: 52:are weak bases formed by the reaction of 3181: 3179: 2616:The concept of base stems from an older 2611: 2532: 2492:base. Examples of monoacidic bases are: 2469: 972:ionizes into hydroxide and sodium ions: 940: 544:contain Brønsted bases which react with 44: 2704: 2582:When one molecule of base via complete 2518:When one molecule of base via complete 724: 14: 3324: 3209: 3031: 3016: 2821: 1147:ions combine to form water molecules: 1116:When the two solutions are mixed, the 560:, the acidic species in this solvent. 493:, producing a solution of water and a 3176: 2844: 2440:(OH) ion per formula unit are called 2323: 610:General properties of bases include: 2872:from the original on 2 November 2021 454:if it contains and releases OH ions 3134:from the original on 9 January 2022 3104:from the original on 8 October 2022 3052:from the original on 8 October 2022 2594:. Examples of triacidic bases are: 2465: 1956:Examples of common superbases are: 1030:forms hydronium and chloride ions: 397:ions OH. These ions can react with 24: 2794:from the original on 21 March 2018 2577: 2530:. Examples of diacidic bases are: 2374:Meerwein-Ponndorf-Verley reduction 919:{\displaystyle K_{b}={\frac {}{}}} 25: 3348: 3301: 3228:The Journal of Chemical Education 3193:. 2 February 2018. Archived from 3164:from the original on 30 June 2016 2854:Journal of the Franklin Institute 2513: 2237:Examples of solid bases include: 1026:and similarly, in water the acid 646:Reactions between bases and water 614:Concentrated or strong bases are 290: 3307: 2383: 2328:Basic substances can be used as 2037:Lithium bis(trimethylsilyl)amide 76: 3221:"The origin of the term 'base'" 3146: 3116: 2991: 2966: 2941: 2648:, The origin of the term "base" 2429:Monoprotic and polyprotic bases 2282:Inorganic chemicals: BaO, KNaCO 1533: 574:that the bases possess. In the 514:Brønsted–Lowry acid–base theory 3124:"Polyprotic Acids & Bases" 2776: 2698: 2232: 2189: 2098:) (second strongest superbase) 2058:Ortho-diethynylbenzene dianion 1897: 1433: 1333: 1194: 1063: 986: 910: 904: 899: 883: 880: 864: 814: 808: 781: 775: 751: 726: 711: 705: 672: 666: 13: 1: 3312:The dictionary definition of 3038:. Academic Press. p. 2. 2866:10.1016/S0016-0032(38)91691-6 2691: 2628:, as a synonym for the older 2354:potassium fluoride on alumina 2210:. In addition to H, possible 2130: 2120:) (third strongest superbase) 2102:Para-diethynylbenzene dianion 2080:Meta-diethynylbenzene dianion 1793: 1704:Tetramethylammonium hydroxide 1490:can act as a base as well as 952:(in test tube) reacting with 605: 2910:Zumdahl & DeCoste (2013) 2891:Zumdahl & DeCoste (2013) 2816:Zumdahl & DeCoste (2013) 2759:Zumdahl & DeCoste (2013) 2705:Johlubl, Matthew E. (2009). 2149:is incomplete. For example, 1250:Alkalinity of non-hydroxides 374:, as originally proposed by 7: 3295:(7th ed.). Mary Finch. 2653: 834:The equilibrium constant, K 505:, any additional such salt 10: 3353: 2638:Guillaume-François Rouelle 2134: 1797: 435:In water, by altering the 36: 29: 27:Type of chemical substance 2929:. LibreText. 16 July 2015 548:protons. For example, in 378:in the mid-18th century. 3090:. Elsevier. p. 14. 2620:notion of "the matrix": 1975:Lithium diisopropylamide 424:and change the color of 168:Self-ionization of water 153:Hammett acidity function 2923:"10.4.1. Alkoxide Ions" 2788:www.merriam-webster.com 2212:electron-pair acceptors 937:Neutralization of acids 520:(H)—otherwise known as 2651: 2540: 2477: 2220:coordination complexes 2124:Lithium monoxide anion 1947: 1469: 1386: 1222: 1107: 1017: 965: 920: 828: 65: 3032:Tanabe, Kozo (1970). 2771:Whitten et al. (2009) 2738:Whitten et al. (2009) 2681:Lewis acids and bases 2622: 2612:Etymology of the term 2536: 2473: 2289:Anion exchange resins 1948: 1470: 1387: 1223: 1108: 1018: 944: 921: 829: 509:out of the solution. 183:Frustrated Lewis pair 143:Equilibrium chemistry 133:Dissociation constant 103:Acid–base homeostasis 48: 32:Base (disambiguation) 3128:Chemistry LibreTexts 2927:Chemistry Libretexts 2784:"Definition of BASE" 2572:copper(II) hydroxide 2433:Bases with only one 2286:, BeO, MgO, CaO, KCN 2184:degree of ionization 2180:equilibrium constant 1985:Lithium diethylamide 1838: 1397: 1284: 1154: 1037: 979: 845: 654: 542:non-aqueous solvents 512:In the more general 178:Lewis acid catalysis 30:For other uses, see 3293:Chemical Principles 3240:2006JChEd..83.1130J 3000:Inorganic Chemistry 2660:Acid–base reactions 2598:Aluminium hydroxide 2548:magnesium hydroxide 2500:potassium hydroxide 2368:, the migration of 2263:Mounted bases: LiCO 2241:Oxide mixtures: SiO 2200:electron-pair donor 1925: 1912: 1893: 1867: 1854: 1776:very strong acids. 1664:Strontium hydroxide 1624:Magnesium hydroxide 1594:Potassium hydroxide 1450: 1429: 1413: 1367: 1329: 1313: 1300: 1244:potassium hydroxide 1213: 1170: 1078: 1059: 948:fumes from aqueous 822: 789: 737: 719: 698: 680: 62:potassium hydroxide 3337:Chemical compounds 3248:10.1021/ed083p1130 3217:Jensen, William B. 2848:(September 1938). 2568:lead(II) hydroxide 2560:iron(II) hydroxide 2541: 2508:ammonium hydroxide 2478: 2422:Ammonium hydroxide 2416:Sodium bicarbonate 2338:chemical reactions 2324:Bases as catalysts 1943: 1913: 1900: 1881: 1855: 1842: 1790:are strong bases. 1604:Rubidium hydroxide 1465: 1436: 1417: 1401: 1382: 1353: 1317: 1301: 1288: 1218: 1201: 1158: 1103: 1066: 1047: 1013: 966: 950:ammonium hydroxide 916: 824: 793: 760: 756: 686: 684: 658: 501:with a given salt 403:acid–base reaction 98:Acid–base reaction 66: 3332:Bases (chemistry) 3283:978-0-495-39163-0 2950:General Chemistry 2850:"Acids and Bases" 2846:Lewis, Gilbert N. 2646:William B. Jensen 2606:Gold Trihydroxide 2602:ferrous hydroxide 2564:tin(II) hydroxide 2552:calcium hydroxide 2362:transition metals 1935: 1928: 1916: 1903: 1896: 1884: 1871: 1858: 1845: 1804:Group 1 salts of 1761: 1760: 1644:Calcium hydroxide 1574:Lithium hydroxide 1457: 1439: 1432: 1420: 1404: 1374: 1356: 1343: 1332: 1320: 1304: 1291: 1216: 1204: 1187: 1174: 1161: 1095: 1082: 1069: 1062: 1050: 1043: 1028:hydrogen chloride 1005: 992: 985: 962:ammonium chloride 954:hydrochloric acid 914: 813: 798: 780: 765: 758: 710: 701: 689: 671: 662: 641:Bases are bitter. 622:Aqueous solutions 600:other definitions 589:boron trifluoride 532:) or its organic 466:, and especially 393:solution to form 342: 341: 188:Chiral Lewis acid 16:(Redirected from 3344: 3311: 3296: 3287: 3276:(9th ed.). 3275: 3259: 3258: 3257:on 4 March 2016. 3256: 3250:. Archived from 3225: 3213: 3207: 3206: 3204: 3202: 3183: 3174: 3173: 3171: 3169: 3150: 3144: 3143: 3141: 3139: 3130:. 13 July 2016. 3120: 3114: 3113: 3111: 3109: 3081: 3062: 3061: 3059: 3057: 3029: 3014: 3013: 2995: 2989: 2988: 2970: 2964: 2963: 2945: 2939: 2938: 2936: 2934: 2919: 2913: 2907: 2894: 2888: 2882: 2881: 2879: 2877: 2842: 2819: 2813: 2804: 2803: 2801: 2799: 2780: 2774: 2768: 2762: 2756: 2741: 2735: 2729: 2728: 2702: 2649: 2544:Barium hydroxide 2538:Barium hydroxide 2504:silver hydroxide 2496:Sodium hydroxide 2475:Sodium hydroxide 2466:Monoacidic bases 2410:Sodium carbonate 2378:Michael reaction 2186:is quite small. 2173: 2172: 2143:aqueous solution 2049: 2047: 2046: 2017: 2015: 2014: 2006: 2005: 1997: 1996: 1952: 1950: 1949: 1944: 1942: 1941: 1940: 1933: 1926: 1924: 1921: 1914: 1911: 1908: 1901: 1894: 1892: 1889: 1882: 1877: 1876: 1869: 1866: 1863: 1856: 1853: 1850: 1843: 1757: 1756: 1755: 1747: 1746: 1728: 1726: 1725: 1717: 1716: 1698: 1697: 1696: 1684:Barium hydroxide 1678: 1677: 1676: 1658: 1657: 1656: 1638: 1637: 1636: 1614:Cesium hydroxide 1584:Sodium hydroxide 1570: 1569: 1555: 1554: 1553: 1474: 1472: 1471: 1466: 1464: 1463: 1462: 1455: 1449: 1444: 1437: 1430: 1428: 1425: 1418: 1412: 1409: 1402: 1391: 1389: 1388: 1383: 1381: 1380: 1379: 1372: 1366: 1361: 1354: 1349: 1348: 1341: 1330: 1328: 1325: 1318: 1312: 1309: 1302: 1299: 1296: 1289: 1272: 1271: 1270: 1256:sodium carbonate 1240:sodium hydroxide 1227: 1225: 1224: 1219: 1217: 1214: 1212: 1209: 1202: 1193: 1192: 1185: 1180: 1179: 1172: 1169: 1166: 1159: 1146: 1145: 1144: 1135: 1134: 1133: 1126: 1125: 1112: 1110: 1109: 1104: 1102: 1101: 1100: 1093: 1088: 1087: 1080: 1077: 1074: 1067: 1060: 1058: 1055: 1048: 1041: 1022: 1020: 1019: 1014: 1012: 1011: 1010: 1003: 998: 997: 990: 983: 970:sodium hydroxide 925: 923: 922: 917: 915: 913: 902: 898: 897: 879: 878: 862: 857: 856: 833: 831: 830: 825: 823: 821: 818: 817: 811: 805: 804: 803: 796: 788: 785: 784: 778: 772: 771: 770: 763: 759: 757: 755: 754: 747: 739: 738: 736: 729: 721: 718: 715: 714: 708: 702: 699: 697: 694: 687: 679: 676: 675: 669: 663: 660: 518:hydrogen cations 478:are weak bases. 428:(e.g., turn red 383:Svante Arrhenius 334: 327: 320: 301:Non-nucleophilic 128:Buffer solutions 113:Acidity function 80: 68: 67: 58:sodium hydroxide 21: 3352: 3351: 3347: 3346: 3345: 3343: 3342: 3341: 3322: 3321: 3304: 3299: 3284: 3263: 3262: 3254: 3223: 3214: 3210: 3200: 3198: 3197:on 26 July 2020 3185: 3184: 3177: 3167: 3165: 3158:City Collegiate 3152: 3151: 3147: 3137: 3135: 3122: 3121: 3117: 3107: 3105: 3098: 3082: 3065: 3055: 3053: 3046: 3030: 3017: 3010: 2996: 2992: 2985: 2971: 2967: 2960: 2946: 2942: 2932: 2930: 2921: 2920: 2916: 2908: 2897: 2889: 2885: 2875: 2873: 2843: 2822: 2814: 2807: 2797: 2795: 2782: 2781: 2777: 2769: 2765: 2757: 2744: 2736: 2732: 2717: 2703: 2699: 2694: 2656: 2650: 2644: 2614: 2586:produces three 2580: 2578:Triacidic bases 2516: 2468: 2431: 2386: 2342:magnesium oxide 2326: 2311: 2307: 2303: 2299: 2295: 2285: 2278: 2274: 2270: 2266: 2260: 2256: 2252: 2248: 2244: 2235: 2217: 2192: 2171: 2168: 2167: 2166: 2165:O(l) → NH 2164: 2160: 2139: 2133: 2119: 2115: 2111: 2107: 2097: 2093: 2089: 2085: 2075: 2071: 2067: 2063: 2045: 2042: 2041: 2040: 2039: 2026: 2013: 2010: 2009: 2008: 2004: 2001: 2000: 1999: 1995: 1992: 1991: 1990: 1988: 1980: 1970: 1966: 1936: 1932: 1922: 1917: 1909: 1904: 1890: 1885: 1872: 1868: 1864: 1859: 1851: 1846: 1841: 1839: 1836: 1835: 1829:leveling effect 1802: 1796: 1788:conjugate bases 1784: 1770:perchloric acid 1754: 1751: 1750: 1749: 1745: 1742: 1741: 1740: 1738: 1724: 1721: 1720: 1719: 1715: 1712: 1711: 1710: 1708: 1695: 1692: 1691: 1690: 1688: 1675: 1672: 1671: 1670: 1668: 1655: 1652: 1651: 1650: 1648: 1635: 1632: 1631: 1630: 1628: 1565:leveling effect 1552: 1549: 1548: 1547: 1545: 1536: 1458: 1454: 1445: 1440: 1426: 1421: 1410: 1405: 1400: 1398: 1395: 1394: 1375: 1371: 1362: 1357: 1344: 1340: 1326: 1321: 1310: 1305: 1297: 1292: 1287: 1285: 1282: 1281: 1277:such as water: 1275:protic solvents 1269: 1267: 1266: 1265: 1263: 1252: 1235:, in solution. 1210: 1205: 1188: 1184: 1175: 1171: 1167: 1162: 1157: 1155: 1152: 1151: 1143: 1141: 1140: 1139: 1137: 1132: 1130: 1129: 1128: 1124: 1121: 1120: 1119: 1117: 1096: 1092: 1083: 1079: 1075: 1070: 1056: 1051: 1040: 1038: 1035: 1034: 1006: 1002: 993: 989: 982: 980: 977: 976: 939: 903: 893: 889: 874: 870: 863: 861: 852: 848: 846: 843: 842: 837: 819: 807: 806: 799: 795: 794: 786: 774: 773: 766: 762: 761: 750: 743: 742: 740: 732: 725: 723: 722: 720: 716: 704: 703: 695: 690: 685: 677: 665: 664: 659: 657: 655: 652: 651: 648: 627:Reactions with 608: 594: 578:, a base is an 559: 555: 531: 488: 472:conjugate bases 470:are basic, and 414: 355:Arrhenius bases 338: 163:Proton affinity 88:Acceptor number 71:Acids and bases 41: 35: 28: 23: 22: 15: 12: 11: 5: 3350: 3340: 3339: 3334: 3320: 3319: 3303: 3302:External links 3300: 3298: 3297: 3288: 3282: 3264: 3261: 3260: 3208: 3175: 3145: 3115: 3096: 3063: 3044: 3015: 3008: 2990: 2983: 2965: 2958: 2940: 2914: 2912:, p. 256. 2895: 2893:, p. 255. 2883: 2860:(3): 293–313. 2820: 2818:, p. 258. 2805: 2775: 2773:, p. 349. 2763: 2761:, p. 257. 2742: 2740:, p. 363. 2730: 2716:978-1429209892 2715: 2696: 2695: 2693: 2690: 2689: 2688: 2683: 2678: 2676:Conjugate base 2673: 2667: 2662: 2655: 2652: 2642: 2613: 2610: 2579: 2576: 2556:zinc hydroxide 2515: 2514:Diacidic bases 2512: 2467: 2464: 2451:The number of 2430: 2427: 2426: 2425: 2419: 2413: 2407: 2404: 2401:sulfur dioxide 2397: 2394: 2385: 2382: 2332:heterogeneous 2325: 2322: 2313: 2312: 2309: 2305: 2301: 2297: 2293: 2290: 2287: 2283: 2280: 2276: 2272: 2268: 2264: 2261: 2258: 2254: 2250: 2246: 2242: 2234: 2231: 2215: 2191: 2188: 2176: 2175: 2169: 2162: 2158: 2145:, or in which 2135:Main article: 2132: 2129: 2128: 2127: 2121: 2117: 2113: 2109: 2105: 2099: 2095: 2091: 2087: 2083: 2077: 2073: 2069: 2065: 2061: 2051: 2050: 2043: 2034: 2031:Sodium hydride 2028: 2024: 2018: 2011: 2002: 1993: 1982: 1978: 1972: 1968: 1964: 1954: 1953: 1939: 1931: 1920: 1907: 1899: 1888: 1880: 1875: 1862: 1849: 1798:Main article: 1795: 1792: 1782: 1779:Acids with a p 1759: 1758: 1752: 1743: 1736: 1730: 1729: 1722: 1713: 1706: 1700: 1699: 1693: 1686: 1680: 1679: 1673: 1666: 1660: 1659: 1653: 1646: 1640: 1639: 1633: 1626: 1620: 1619: 1616: 1610: 1609: 1606: 1600: 1599: 1596: 1590: 1589: 1586: 1580: 1579: 1576: 1550: 1535: 1532: 1524:sodium acetate 1476: 1475: 1461: 1453: 1448: 1443: 1435: 1424: 1416: 1408: 1392: 1378: 1370: 1365: 1360: 1352: 1347: 1338: 1335: 1324: 1316: 1308: 1295: 1268: 1251: 1248: 1229: 1228: 1208: 1199: 1196: 1191: 1183: 1178: 1165: 1142: 1131: 1122: 1114: 1113: 1099: 1091: 1086: 1073: 1065: 1054: 1046: 1024: 1023: 1009: 1001: 996: 988: 964:(white smoke). 938: 935: 927: 926: 912: 909: 906: 901: 896: 892: 888: 885: 882: 877: 873: 869: 866: 860: 855: 851: 835: 816: 810: 802: 792: 783: 777: 769: 753: 746: 735: 728: 713: 707: 693: 683: 674: 668: 647: 644: 643: 642: 639: 632: 625: 619: 607: 604: 592: 557: 553: 550:liquid ammonia 529: 491:neutralization 486: 456:quantitatively 437:autoionization 412: 361:Brønsted bases 340: 339: 337: 336: 329: 322: 314: 311: 310: 309: 308: 303: 298: 293: 288: 283: 278: 273: 271:Brønsted–Lowry 265: 264: 257: 256: 255: 254: 249: 244: 239: 234: 229: 224: 219: 214: 212:Brønsted–Lowry 206: 205: 198: 197: 196: 195: 190: 185: 180: 175: 170: 165: 160: 155: 150: 145: 140: 135: 130: 125: 120: 115: 110: 105: 100: 95: 90: 82: 81: 73: 72: 26: 9: 6: 4: 3: 2: 3349: 3338: 3335: 3333: 3330: 3329: 3327: 3318:at Wiktionary 3317: 3316: 3310: 3306: 3305: 3294: 3289: 3285: 3279: 3274: 3273: 3266: 3265: 3253: 3249: 3245: 3241: 3237: 3233: 3229: 3222: 3218: 3212: 3196: 3192: 3188: 3182: 3180: 3163: 3159: 3155: 3149: 3133: 3129: 3125: 3119: 3103: 3099: 3097:9780080887555 3093: 3089: 3088: 3080: 3078: 3076: 3074: 3072: 3070: 3068: 3051: 3047: 3045:9780323160582 3041: 3037: 3036: 3028: 3026: 3024: 3022: 3020: 3011: 3009:0-13-841891-8 3005: 3001: 2994: 2986: 2984:0-13-014329-4 2980: 2976: 2969: 2961: 2959:0-03-072373-6 2955: 2951: 2944: 2928: 2924: 2918: 2911: 2906: 2904: 2902: 2900: 2892: 2887: 2871: 2867: 2863: 2859: 2855: 2851: 2847: 2841: 2839: 2837: 2835: 2833: 2831: 2829: 2827: 2825: 2817: 2812: 2810: 2793: 2789: 2785: 2779: 2772: 2767: 2760: 2755: 2753: 2751: 2749: 2747: 2739: 2734: 2726: 2722: 2718: 2712: 2708: 2701: 2697: 2687: 2684: 2682: 2679: 2677: 2674: 2671: 2670:Base-richness 2668: 2666: 2663: 2661: 2658: 2657: 2647: 2641: 2639: 2635: 2631: 2627: 2621: 2619: 2609: 2607: 2603: 2599: 2595: 2593: 2589: 2585: 2575: 2573: 2569: 2565: 2561: 2557: 2553: 2549: 2545: 2539: 2535: 2531: 2529: 2525: 2522:produces two 2521: 2511: 2509: 2505: 2501: 2497: 2493: 2491: 2487: 2484:produces one 2483: 2476: 2472: 2463: 2461: 2457: 2454: 2449: 2447: 2443: 2439: 2436: 2423: 2420: 2417: 2414: 2411: 2408: 2405: 2402: 2398: 2395: 2392: 2388: 2387: 2384:Uses of bases 2381: 2379: 2375: 2371: 2367: 2366:hydrogenation 2363: 2359: 2355: 2351: 2347: 2346:calcium oxide 2343: 2339: 2335: 2331: 2321: 2319: 2291: 2288: 2281: 2267:on silica; NR 2262: 2240: 2239: 2238: 2230: 2228: 2223: 2221: 2213: 2209: 2205: 2201: 2197: 2187: 2185: 2181: 2174:(aq) + OH(aq) 2156: 2155: 2154: 2152: 2148: 2144: 2138: 2125: 2122: 2103: 2100: 2081: 2078: 2059: 2056: 2055: 2054: 2038: 2035: 2032: 2029: 2022: 2019: 1986: 1983: 1976: 1973: 1962: 1961:Butyl lithium 1959: 1958: 1957: 1937: 1929: 1918: 1905: 1886: 1878: 1873: 1860: 1847: 1834: 1833: 1832: 1830: 1827:ion (See the 1826: 1822: 1821: 1815: 1811: 1807: 1801: 1791: 1789: 1785: 1777: 1775: 1774:sulfuric acid 1771: 1767: 1737: 1735: 1732: 1731: 1707: 1705: 1702: 1701: 1687: 1685: 1682: 1681: 1667: 1665: 1662: 1661: 1647: 1645: 1642: 1641: 1627: 1625: 1622: 1621: 1617: 1615: 1612: 1611: 1607: 1605: 1602: 1601: 1597: 1595: 1592: 1591: 1587: 1585: 1582: 1581: 1577: 1575: 1572: 1571: 1568: 1566: 1561: 1557: 1543: 1542: 1531: 1529: 1525: 1521: 1517: 1513: 1509: 1505: 1501: 1500:butyl lithium 1497: 1493: 1489: 1483: 1481: 1478:From this, a 1459: 1451: 1446: 1441: 1422: 1414: 1406: 1393: 1376: 1368: 1363: 1358: 1350: 1345: 1336: 1322: 1314: 1306: 1293: 1280: 1279: 1278: 1276: 1261: 1257: 1247: 1245: 1241: 1236: 1234: 1206: 1197: 1189: 1181: 1176: 1163: 1150: 1149: 1148: 1097: 1089: 1084: 1071: 1052: 1044: 1033: 1032: 1031: 1029: 1007: 999: 994: 975: 974: 973: 971: 963: 960:) to produce 959: 955: 951: 947: 943: 934: 932: 907: 894: 890: 886: 875: 871: 867: 858: 853: 849: 841: 840: 839: 800: 790: 767: 744: 733: 691: 681: 640: 637: 633: 630: 626: 623: 620: 617: 613: 612: 611: 603: 601: 596: 590: 586: 581: 580:electron pair 577: 573: 569: 568:unshared pair 565: 561: 551: 547: 543: 539: 535: 527: 523: 519: 515: 510: 508: 504: 500: 496: 492: 484: 479: 477: 473: 469: 465: 461: 457: 453: 449: 445: 441: 438: 433: 431: 427: 426:pH indicators 423: 419: 415: 408: 404: 400: 399:hydrogen ions 396: 392: 388: 384: 379: 377: 376:G.-F. Rouelle 373: 369: 368: 363: 362: 357: 356: 351: 347: 335: 330: 328: 323: 321: 316: 315: 313: 312: 307: 304: 302: 299: 297: 294: 292: 289: 287: 284: 282: 279: 277: 274: 272: 269: 268: 267: 266: 262: 259: 258: 253: 250: 248: 245: 243: 240: 238: 235: 233: 230: 228: 225: 223: 220: 218: 215: 213: 210: 209: 208: 207: 203: 200: 199: 194: 191: 189: 186: 184: 181: 179: 176: 174: 171: 169: 166: 164: 161: 159: 156: 154: 151: 149: 146: 144: 141: 139: 136: 134: 131: 129: 126: 124: 121: 119: 116: 114: 111: 109: 108:Acid strength 106: 104: 101: 99: 96: 94: 91: 89: 86: 85: 84: 83: 79: 75: 74: 70: 69: 63: 59: 55: 51: 47: 43: 40: 33: 19: 3314: 3292: 3271: 3252:the original 3231: 3227: 3211: 3199:. Retrieved 3195:the original 3191:Toppr-guides 3190: 3166:. Retrieved 3157: 3148: 3136:. Retrieved 3127: 3118: 3106:. Retrieved 3086: 3054:. Retrieved 3034: 2999: 2993: 2974: 2968: 2949: 2943: 2931:. Retrieved 2926: 2917: 2886: 2874:. Retrieved 2857: 2853: 2796:. Retrieved 2787: 2778: 2766: 2733: 2706: 2700: 2626:Louis LĂ©mery 2623: 2615: 2596: 2591: 2581: 2542: 2527: 2517: 2494: 2489: 2479: 2459: 2450: 2445: 2441: 2432: 2370:double bonds 2350:barium oxide 2327: 2318:nitric oxide 2314: 2236: 2224: 2211: 2199: 2193: 2177: 2140: 2052: 2021:Sodium amide 1955: 1818: 1803: 1780: 1778: 1762: 1562: 1558: 1539: 1537: 1534:Strong bases 1512:sodium amide 1508:metal amides 1484: 1477: 1253: 1237: 1230: 1115: 1025: 967: 928: 649: 609: 597: 576:Lewis theory 562: 511: 507:precipitates 480: 460:Metal oxides 434: 430:litmus paper 380: 365: 359: 353: 349: 343: 260: 138:Donor number 122: 42: 3234:(8): 1130. 3108:19 February 3056:19 February 2876:3 September 2630:Paracelsian 2352:as well as 2233:Solid bases 2190:Lewis bases 2147:protonation 1541:deprotonate 931:strong base 564:G. N. Lewis 534:derivatives 440:equilibrium 387:dissociates 367:Lewis bases 118:Amphoterism 54:fatty acids 3326:Categories 2933:28 October 2692:References 2618:alchemical 2584:ionization 2520:ionization 2490:monoprotic 2482:ionization 2446:polyprotic 2442:monoprotic 2257:; CaO, SiO 2253:; MgO, SiO 2204:lone pairs 2196:Lewis base 2131:Weak bases 1820:superbases 1810:amide ions 1806:carbanions 1794:Superbases 1520:superbases 1233:table salt 629:indicators 606:Properties 476:weak acids 464:hydroxides 296:Superbases 242:Superacids 148:Extraction 37:See also: 3272:Chemistry 3138:9 January 2725:392223218 2686:Titration 2592:triprotic 2588:hydroxide 2524:hydroxide 2486:hydroxide 2456:hydroxide 2453:ionizable 2438:hydroxide 2435:ionizable 2372:, in the 2356:and some 2334:catalysts 2330:insoluble 2137:weak base 1938:− 1898:⟶ 1874:− 1825:hydroxide 1800:Superbase 1766:Guanidine 1734:Guanidine 1528:weak base 1516:resonance 1504:alkoxides 1460:− 1434:⟶ 1377:− 1364:− 1334:⟶ 1195:⟶ 1190:− 1098:− 1064:⟶ 1008:− 987:⟶ 895:− 801:− 752:⇀ 745:− 734:− 727:↽ 572:electrons 499:saturated 483:hydronium 468:alkoxides 395:hydroxide 381:In 1884, 346:chemistry 193:ECW model 173:Titration 3219:(2006). 3201:14 March 3162:Archived 3132:Archived 3102:Archived 3050:Archived 2870:Archived 2792:Archived 2654:See also 2643:—  2528:diprotic 2358:zeolites 2161:(aq) + H 1814:hydrides 1510:such as 1492:nitrogen 546:solvated 444:activity 18:Basicity 3236:Bibcode 3168:20 June 2634:animism 2574:, etc. 2510:, etc. 2460:acidity 2360:. Many 2151:ammonia 1987:(LDEA) 1260:ammonia 946:Ammonia 616:caustic 585:orbital 526:ammonia 522:protons 432:blue). 418:aqueous 416:. Such 391:aqueous 281:Organic 227:Organic 222:Mineral 3280:  3094:  3042:  3006:  2981:  2956:  2723:  2713:  2376:, the 2348:, and 2300:, ZnCl 2208:adduct 1977:(LDA) 1812:, and 1739:HNC(NH 1689:Ba(OH) 1669:Sr(OH) 1649:Ca(OH) 1629:Mg(OH) 1546:Ca(OH) 1506:, and 1496:oxygen 1488:Carbon 958:beaker 538:amines 503:solute 452:alkali 422:bitter 411:Ca(OH) 364:, and 291:Strong 237:Strong 39:Alkali 3255:(PDF) 3224:(PDF) 2798:3 May 2665:Acids 2391:rayon 2308:Cl-CO 2296:O, NH 2275:, KNH 2227:Lewis 2033:(NaH) 2023:(NaNH 1618:CsOH 1608:RbOH 1588:NaOH 1578:LiOH 1526:is a 598:Some 372:acids 286:Oxide 276:Lewis 263:types 252:Solid 232:Oxide 217:Lewis 204:types 56:with 50:Soaps 3315:base 3278:ISBN 3203:2019 3170:2016 3140:2022 3110:2015 3092:ISBN 3058:2015 3040:ISBN 3004:ISBN 2979:ISBN 2954:ISBN 2935:2022 2878:2020 2800:2018 2721:OCLC 2711:ISBN 2336:for 2271:, NH 2245:, Al 2178:The 1963:(n-C 1772:and 1709:N(CH 1598:KOH 1494:and 1258:and 1136:and 984:NaOH 956:(in 634:The 552:, NH 495:salt 407:NaOH 350:base 306:Weak 261:Base 247:Weak 202:Acid 123:Base 93:Acid 3244:doi 2862:doi 2858:226 2304:-NH 2198:or 2048:NLi 2016:NLi 1981:NLi 1971:Li) 1355:HCO 1242:or 1042:HCl 595:). 591:(BF 570:of 528:(NH 474:of 409:or 389:in 352:": 344:In 60:or 3328:: 3242:. 3232:83 3230:. 3226:. 3189:. 3178:^ 3160:. 3156:. 3126:. 3100:. 3066:^ 3048:. 3018:^ 2925:. 2898:^ 2868:. 2856:. 2852:. 2823:^ 2808:^ 2790:. 2786:. 2745:^ 2719:. 2608:, 2604:, 2600:, 2570:, 2566:, 2562:, 2558:, 2554:, 2550:, 2546:, 2506:, 2502:, 2498:, 2448:. 2344:, 2222:. 2194:A 2157:NH 2112:(C 2104:(C 2090:(C 2082:(C 2068:(C 2060:(C 1989:(C 1934:OH 1927:OH 1915:CH 1902:CH 1857:CH 1844:CH 1808:, 1727:OH 1530:. 1502:, 1480:pH 1456:OH 1438:NH 1403:NH 1373:OH 1342:Na 1303:CO 1290:Na 1264:OH 1186:OH 1138:OH 1094:Cl 1004:OH 991:Na 812:aq 797:OH 779:aq 764:BH 670:aq 636:pH 485:(H 462:, 458:. 448:pH 358:, 158:pH 3286:. 3246:: 3238:: 3205:. 3172:. 3142:. 3112:. 3060:. 3012:. 2987:. 2962:. 2937:. 2880:. 2864:: 2802:. 2727:. 2393:. 2310:2 2306:4 2302:2 2298:3 2294:2 2284:3 2277:2 2273:3 2269:3 2265:3 2259:2 2255:2 2251:3 2249:O 2247:2 2243:2 2216:3 2170:4 2163:2 2159:3 2118:2 2116:) 2114:2 2110:4 2108:H 2106:6 2096:2 2094:) 2092:2 2088:4 2086:H 2084:6 2074:2 2072:) 2070:2 2066:4 2064:H 2062:6 2044:2 2027:) 2025:2 2012:2 2007:) 2003:5 1998:H 1994:2 1979:2 1969:9 1967:H 1965:4 1930:+ 1919:2 1906:3 1895:O 1887:2 1883:H 1879:+ 1870:O 1861:2 1848:3 1783:a 1781:K 1753:2 1748:) 1744:2 1723:4 1718:) 1714:3 1694:2 1674:2 1654:2 1634:2 1551:2 1452:+ 1447:+ 1442:4 1431:O 1423:2 1419:H 1415:+ 1407:3 1369:+ 1359:3 1351:+ 1346:+ 1337:2 1331:O 1323:2 1319:H 1315:+ 1307:3 1294:2 1215:O 1207:2 1203:H 1198:2 1182:+ 1177:+ 1173:O 1164:3 1160:H 1127:O 1123:3 1118:H 1090:+ 1085:+ 1081:O 1072:3 1068:H 1061:O 1053:2 1049:H 1045:+ 1000:+ 995:+ 911:] 908:B 905:[ 900:] 891:H 887:O 884:[ 881:] 876:+ 872:H 868:B 865:[ 859:= 854:b 850:K 836:b 815:) 809:( 791:+ 782:) 776:( 768:+ 712:) 709:l 706:( 700:O 692:2 688:H 682:+ 673:) 667:( 661:B 593:3 558:4 554:2 536:( 530:3 487:3 413:2 333:e 326:t 319:v 64:. 34:. 20:)

Index

Basicity
Base (disambiguation)
Alkali

Soaps
fatty acids
sodium hydroxide
potassium hydroxide
Diagrammatic representation of the dissociation of acetic acid in aqueous solution to acetate and hydronium ions.
Acceptor number
Acid
Acid–base reaction
Acid–base homeostasis
Acid strength
Acidity function
Amphoterism
Base
Buffer solutions
Dissociation constant
Donor number
Equilibrium chemistry
Extraction
Hammett acidity function
pH
Proton affinity
Self-ionization of water
Titration
Lewis acid catalysis
Frustrated Lewis pair
Chiral Lewis acid

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