1126:
33:
330:
207:
669:
664:
24:
752:
748:
975:
751:
753:
1473:
Iloukhani, H., K. Khanlarzadeh. "Densities, viscosities, and refractive indices for binary and ternary mixtures of N, N-dimethylacetamide (1)+ 2-methylbutan-2-ol (2)+ ethyl acetate (3) at 298.15 K for m liquid region and at ambient pressure". Journal of
Chemical & Engineering Data, 51.4 (2006):
769:
677:
1875:
FDA warns health care professionals not to use
Treanda Injection (solution) with closed system transfer devices, adapters, and syringes containing polycarbonate or acrylonitrile-butadiene-styrene
644:
1329:
754:
762:
1887:
Agreement of the Member State
Committee on the Identification of N,N-Dimethylacetamide (DMAC) as a Substance of Very High Concern – Adopted on 24 November 2011
1527:
1502:
882:
988:
1824:
Weiss, A. J.; Mancall, E. L.; Koltes, J. A.; White, J. C.; Jackson, L. G. (1962). "Dimethylacetamide: A Hitherto
Unrecognized Hallucinogenic Agent".
1546:
776:
1911:
369:
1927:
1246:. Unlike many other cellulose solvents, LiCl/DMAc gives a molecular dispersion, i.e. a "true solution". For this reason, it is used in
1439:
Munro, D. D.; Stoughton, R. B. (1965). "Dimethylacetamide (DMAC) and
Dimethylformamide (DMFA). Effect on Percutaneous Absorption".
1125:
32:
1328:. In 2014, the European Commission has started an investigation to restrict the use of dimethylacetamide in the EU according to
613:
983:
586:
1797:
Weiss, A. J.; Jackson, L. G.; Carabasi, R. A.; Mancall, E. L.; White, J. C. (1962). "A Phase I Study of
Dimethylacetamide".
516:
1312:. Devices (e.g. syringes) that contain polycarbonate or ABS can dissolve when coming into contact with dimethylacetamide.
1208:
However, it is resistant to bases. For this reason DMA is a useful solvent for reactions involving strong bases such as
1563:
1898:
344:
995:
23:
1699:"Incidence of dimethylacetamide induced hepatic injury among new employees in a cohort of elastane fibre workers"
1309:
238:
1321:
1886:
1247:
717:
287:
202:
1748:"Dimethylacetamide-induced occupational toxic hepatitis with a short term recurrence: a rare case report"
308:
723:
668:
164:
104:
1910:
Commission des normes, de l'équité, de la santé et de la sécurité du travail (CNESST), Quebec, Canada:
1281:
Dimethylacetamide, like most simple alkyl amides, is of low acute toxicity. Chronic exposure can cause
906:
893:
663:
1290:
214:
1582:
Grafmans, Horst; Maas, Steffen; Weck, Alexander; Rütter, Heinz; Schulz, Michael; Ross, Karl-Heinz.
799:
325:
232:
1947:
1251:
1286:
1351:
1325:
691:
656:
493:
1833:
296:
184:
45:
1285:. At high doses (400 mg/kg body mass daily), dimethylacetamide causes effects on the
1073:. Dehydration of the salt of dimethylamine and acetic acid also furnishes this compound:
8:
1952:
1452:
727:
80:
70:
1837:
329:
206:
144:
1857:
1796:
1774:
1747:
1723:
1698:
124:
1645:
1874:
1849:
1806:
1779:
1728:
1679:
1615:
1559:
1456:
1216:
1137:
1043:
954:
944:
1928:
1861:
1841:
1823:
1769:
1759:
1718:
1710:
1671:
1644:
U.S. Department of Health and Human
Services & U.S. Department of Labor (1978)
1583:
1551:
1475:
1448:
1239:
1209:
1066:
1023:
1019:
532:
482:
392:
1652:. January 1981. The National Institute for Occupational Safety and Health (NIOSH).
1555:
1335:
In 2015, the CNESST (Committee on
Standards, Equity, Health and Safety at Work in
1038:. This colorless, water-miscible, high-boiling liquid is commonly used as a polar
260:
1845:
1228:
812:
1610:
1282:
1117:
966:
506:
1932:
1498:
866:
836:
1941:
1662:
Baum, S. L.; Suruda, A. J. (1997). "Toxic
Hepatitis from Dimethylacetamide".
1519:
1305:
1294:
1113:
1062:
1046:. DMA is miscible with most other solvents, although it is poorly soluble in
567:
471:
461:
195:
1764:
1714:
1136:
in rectification columns. DMA is obtained with essentially quantitive (99%)
1132:
The separation and purification of the product is carried out by multistage
1853:
1810:
1783:
1732:
1675:
1133:
1696:
1683:
1460:
775:
1649:
1375:
May cause damage to organs through prolonged or repeated exposure (H373)
1232:
1070:
1050:
788:
761:
1262:
1161:
768:
420:
215:
175:
1479:
709:
1270:
1258:
1243:
1047:
949:
551:
1697:
Lee, C.-Y.; Jung, S.-J.; Kim, S.-A.; Park, K.-S.; Ha, B.-G. (2006).
965:
Except where otherwise noted, data are given for materials in their
1402:
Specific target organ toxicity – single exposure – narcotic effects
1298:
1266:
1224:
734:
1496:
1215:
Dimethylacetamide is commonly used as a solvent for fibers (e.g.,
103:
1543:
1220:
1039:
451:
247:
1339:) has adopted a tightened classification of dimethylacetamide:
1336:
155:
1664:
International Journal of Occupational and Environmental Health
1524:
Immediately Dangerous to Life or Health Concentrations (IDLH)
1157:
271:
135:
93:
1438:
313:
1648:. Now: Occupational Health Guideline for Chemical Hazards.
1584:"Method for the production of n,n-dimethylacetamide (DMAC)"
1364:
Suspected of damaging fertility or the unborn child (H361)
1165:
1148:
The chemical reactions of dimethylacetamide are typical of
919:
874:
701:
441:
1112:
Dimethylacetamide can also be produced by the reaction of
697:
1544:
Cheung, H.; Tanke, R. S.; Torrence, G. P. "Acetic Acid".
1320:
In 2011, dimethylacetamide was identified in the EU as a
1661:
1745:
1901:, Official Journal of the European Union, 19.08.2014.
1528:
National Institute for Occupational Safety and Health
1503:
National Institute for Occupational Safety and Health
1646:
Occupational Health Guideline for Dimethyl Acetamide
1227:industry. It is also employed in the production of
1912:WHMIS 2015 classification of N,N-Dimethylacetamide
1581:
1369:Specific target organ toxicity – repeated exposure
1939:
1061:DMA is prepared commercially by the reaction of
705:
259:
1608:
750:
79:
1547:Ullmann's Encyclopedia of Industrial Chemistry
1164:of the acyl-N bond occurs in the presence of
1143:
1933:CDC – NIOSH Pocket Guide to Chemical Hazards
1577:
1575:
1304:Dimethylacetamide may be incompatible with
1056:
476:165.1 °C; 329.1 °F; 438.2 K
1124:
328:
205:
183:
1773:
1763:
1722:
1640:
1638:
1572:
1539:
1537:
1408:May cause drowsiness or dizziness (H336)
295:
1497:NIOSH Pocket Guide to Chemical Hazards.
1703:Occupational and Environmental Medicine
324:
237:
1940:
1899:Commission Regulation (EU) No 895/2014
1650:DHHS (NIOSH) Publication Number 81-123
1635:
1534:
1514:
1512:
1492:
1490:
1488:
807:490 °C (914 °F; 763 K)
196:
1386:Causes serious eye irritation (H319)
1257:Dimethylacetamide is also used as an
793:63 °C (145 °F; 336 K)
466:−20 °C (−4 °F; 253 K)
356:Key: FXHOOIRPVKKKFG-UHFFFAOYSA-N
163:
143:
1453:10.1001/archderm.1965.01600170101020
1746:Gong, W.; Liu, X.; Zhu, B. (2016).
1509:
1485:
353:InChI=1S/C4H9NO/c1-4(6)5(2)3/h1-3H3
250:
13:
746:
14:
1964:
1921:
1380:Serious eye damage/eye irritation
1242:in DMAc (LiCl/DMAc) can dissolve
973:
667:
662:
410:
404:
31:
22:
1904:
1892:
1880:
1868:
1817:
1790:
1739:
1690:
969:(at 25 °C , 100 kPa).
1655:
1602:
1467:
1432:
1322:Substance of very high concern
413:
398:
1:
1556:10.1002/14356007.a01_045.pub2
1425:
1315:
1248:gel permeation chromatography
887:(US health exposure limits):
855:4.62 g/kg (oral, mouse)
1846:10.1126/science.136.3511.151
1140:referred to methyl acetate.
7:
1799:Cancer Chemotherapy Reports
1752:Journal of Thoracic Disease
1391:Acute toxicity – inhalation
1276:
913:TWA 10 ppm (35 mg/m)
900:TWA 10 ppm (35 mg/m)
825:or concentration (LD, LC):
10:
1969:
1805:(February 1962): 477–485.
1630:, vol. 6, p. 503
1609:Zen, S.; Kaji, E. (1977).
1419:Combustible liquid (H227)
1144:Reactions and applications
1611:"Dimethyl nitrosuccinate"
1261:in drugs, e.g. in Vumon (
963:
930:
881:
853:4.8 g/kg (oral, rat)
821:
643:
638:
560:
385:
365:
340:
63:
44:
39:
30:
21:
1397:Toxic if inhaled (H331)
1057:Synthesis and production
718:Precautionary statements
1765:10.21037/jtd.2016.04.44
1715:10.1136/oem.2005.023580
1550:. Weinheim: Wiley-VCH.
1441:Archives of Dermatology
1252:molar mass distribution
1235:as a reaction medium.
634:−2.5835–−2.5805 MJ/mol
1676:10.1179/oeh.1997.3.1.1
1324:(SVHC) because of its
1287:central nervous system
1254:of cellulose samples.
873:2475 ppm (rat, 1
757:
1358:Reproductive toxicity
1326:reproductive toxicity
756:
1520:"Dimethyl acetamide"
1352:GHS hazard statement
867:median concentration
739:(fire diamond)
46:Preferred IUPAC name
1838:1962Sci...136..151W
483:Solubility in water
428: g·mol
125:Beilstein Reference
18:
996:Infobox references
931:Related compounds
922:(Immediate danger)
758:
57:-Dimethylacetamide
17:Dimethylacetamide
16:
1832:(3511): 151–152.
1628:Collected Volumes
1616:Organic Syntheses
1480:10.1021/je050538q
1423:
1422:
1250:to determine the
1217:polyacrylonitrile
1044:organic synthesis
1008:Dimethylacetamide
1004:Chemical compound
1002:
1001:
955:methylpyrrolidone
945:dimethylformamide
937:Related compounds
851:
846:
692:Hazard statements
436:Colorless liquid
309:CompTox Dashboard
239:dimethylacetamide
105:Interactive image
1960:
1915:
1908:
1902:
1896:
1890:
1884:
1878:
1877:. 10 March 2015.
1872:
1866:
1865:
1821:
1815:
1814:
1794:
1788:
1787:
1777:
1767:
1758:(6): E408–E411.
1743:
1737:
1736:
1726:
1694:
1688:
1687:
1659:
1653:
1642:
1633:
1631:
1624:
1606:
1600:
1599:
1597:
1595:
1579:
1570:
1569:
1541:
1532:
1531:
1516:
1507:
1506:
1494:
1483:
1471:
1465:
1464:
1436:
1413:Flammable liquid
1342:
1341:
1240:lithium chloride
1210:sodium hydroxide
1128:
1067:acetic anhydride
1020:organic compound
986:
980:
977:
976:
849:
845:(dermal, rabbit)
844:
813:Explosive limits
778:
771:
764:
749:
729:
725:
711:
707:
703:
699:
671:
666:
630:
603:
580:178.2 J/(K·mol)
576:
561:Thermochemistry
533:Refractive index
427:
415:
412:
406:
400:
393:Chemical formula
333:
332:
317:
315:
299:
263:
252:
241:
217:
209:
198:
187:
167:
147:
118:DMA, DMAC, DMAc
107:
83:
35:
26:
19:
15:
1968:
1967:
1963:
1962:
1961:
1959:
1958:
1957:
1938:
1937:
1924:
1919:
1918:
1909:
1905:
1897:
1893:
1885:
1881:
1873:
1869:
1822:
1818:
1795:
1791:
1744:
1740:
1709:(10): 688–693.
1695:
1691:
1660:
1656:
1643:
1636:
1626:
1607:
1603:
1593:
1591:
1580:
1573:
1566:
1542:
1535:
1518:
1517:
1510:
1495:
1486:
1472:
1468:
1437:
1433:
1428:
1318:
1279:
1269:) or Amsidine (
1229:pharmaceuticals
1203:
1199:
1195:
1191:
1187:
1183:
1179:
1175:
1156:-disubstituted
1146:
1108:
1104:
1100:
1096:
1092:
1088:
1084:
1080:
1059:
1037:
1033:
1029:
1005:
998:
993:
992:
991: ?)
982:
978:
974:
970:
959:
938:
923:
910:
897:
870:
864:
854:
852:
847:
843:2.24 g/kg
840:
834:
804:
801:
783:
782:
781:
780:
773:
766:
759:
755:
747:
720:
694:
680:
659:
631:
628:
622:
618:
615:
614:Std enthalpy of
604:
601:
595:
591:
588:
587:Std enthalpy of
577:
570:
543:
541:
522:
485:
425:
409:
403:
395:
381:
378:
373:
372:
361:
358:
357:
354:
348:
347:
336:
318:
311:
302:
282:
266:
253:
227:
190:
170:
150:
127:
110:
97:
86:
73:
59:
58:
12:
11:
5:
1966:
1956:
1955:
1950:
1948:Amide solvents
1936:
1935:
1930:
1923:
1922:External links
1920:
1917:
1916:
1903:
1891:
1879:
1867:
1816:
1789:
1738:
1689:
1654:
1634:
1601:
1588:Google Patents
1571:
1565:978-3527306732
1564:
1533:
1508:
1484:
1466:
1447:(5): 585–586.
1430:
1429:
1427:
1424:
1421:
1420:
1417:
1414:
1410:
1409:
1406:
1403:
1399:
1398:
1395:
1392:
1388:
1387:
1384:
1381:
1377:
1376:
1373:
1370:
1366:
1365:
1362:
1359:
1355:
1354:
1349:
1346:
1317:
1314:
1295:hallucinations
1283:hepatotoxicity
1278:
1275:
1238:A solution of
1206:
1205:
1201:
1197:
1193:
1189:
1185:
1181:
1177:
1173:
1145:
1142:
1130:
1129:
1118:methyl acetate
1110:
1109:
1106:
1102:
1098:
1094:
1090:
1086:
1082:
1078:
1058:
1055:
1035:
1031:
1027:
1003:
1000:
999:
994:
972:
971:
967:standard state
964:
961:
960:
958:
957:
952:
947:
941:
939:
936:
933:
932:
928:
927:
924:
918:
915:
914:
911:
905:
902:
901:
898:
892:
889:
888:
879:
878:
871:
862:
860:
857:
856:
848:4.3 g/kg
841:
832:
830:
827:
826:
819:
818:
815:
809:
808:
805:
798:
795:
794:
791:
785:
784:
774:
767:
760:
745:
744:
743:
742:
740:
731:
730:
721:
716:
713:
712:
695:
690:
687:
686:
681:
676:
673:
672:
660:
655:
652:
651:
641:
640:
636:
635:
632:
626:
620:
612:
609:
608:
607:−300.1 kJ/mol
605:
599:
593:
585:
582:
581:
578:
566:
563:
562:
558:
557:
554:
548:
547:
544:
539:
531:
528:
527:
524:
520:
513:
512:
509:
507:Vapor pressure
503:
502:
499:
490:
489:
486:
481:
478:
477:
474:
468:
467:
464:
458:
457:
454:
448:
447:
444:
438:
437:
434:
430:
429:
423:
417:
416:
407:
401:
396:
391:
388:
387:
383:
382:
380:
379:
376:
368:
367:
366:
363:
362:
360:
359:
355:
352:
351:
343:
342:
341:
338:
337:
335:
334:
321:
319:
307:
304:
303:
301:
300:
292:
290:
284:
283:
281:
280:
276:
274:
268:
267:
265:
264:
256:
254:
246:
243:
242:
235:
229:
228:
226:
225:
221:
219:
211:
210:
200:
192:
191:
189:
188:
180:
178:
172:
171:
169:
168:
160:
158:
152:
151:
149:
148:
140:
138:
132:
131:
128:
123:
120:
119:
116:
115:Abbreviations
112:
111:
109:
108:
100:
98:
91:
88:
87:
85:
84:
76:
74:
69:
66:
65:
61:
60:
49:
48:
42:
41:
37:
36:
28:
27:
9:
6:
4:
3:
2:
1965:
1954:
1951:
1949:
1946:
1945:
1943:
1934:
1931:
1929:
1926:
1925:
1913:
1907:
1900:
1895:
1888:
1883:
1876:
1871:
1863:
1859:
1855:
1851:
1847:
1843:
1839:
1835:
1831:
1827:
1820:
1812:
1808:
1804:
1800:
1793:
1785:
1781:
1776:
1771:
1766:
1761:
1757:
1753:
1749:
1742:
1734:
1730:
1725:
1720:
1716:
1712:
1708:
1704:
1700:
1693:
1685:
1681:
1677:
1673:
1669:
1665:
1658:
1651:
1647:
1641:
1639:
1629:
1622:
1618:
1617:
1612:
1605:
1589:
1585:
1578:
1576:
1567:
1561:
1557:
1553:
1549:
1548:
1540:
1538:
1529:
1525:
1521:
1515:
1513:
1504:
1500:
1493:
1491:
1489:
1481:
1477:
1470:
1462:
1458:
1454:
1450:
1446:
1442:
1435:
1431:
1418:
1415:
1412:
1411:
1407:
1404:
1401:
1400:
1396:
1393:
1390:
1389:
1385:
1382:
1379:
1378:
1374:
1371:
1368:
1367:
1363:
1360:
1357:
1356:
1353:
1350:
1347:
1344:
1343:
1340:
1338:
1333:
1331:
1327:
1323:
1313:
1311:
1307:
1306:polycarbonate
1302:
1300:
1296:
1292:
1288:
1284:
1274:
1272:
1268:
1265:), Busulfex (
1264:
1260:
1255:
1253:
1249:
1245:
1241:
1236:
1234:
1230:
1226:
1222:
1218:
1213:
1211:
1188:O + HCl → CH
1171:
1170:
1169:
1167:
1163:
1159:
1155:
1151:
1141:
1139:
1135:
1127:
1123:
1122:
1121:
1119:
1115:
1114:dimethylamine
1076:
1075:
1074:
1072:
1068:
1064:
1063:dimethylamine
1054:
1052:
1049:
1045:
1041:
1025:
1021:
1017:
1013:
1009:
997:
990:
985:
968:
962:
956:
953:
951:
948:
946:
943:
942:
940:
935:
934:
929:
925:
921:
917:
916:
912:
909:(Recommended)
908:
904:
903:
899:
896:(Permissible)
895:
891:
890:
886:
885:
880:
876:
872:
868:
859:
858:
842:
838:
829:
828:
824:
820:
816:
814:
811:
810:
806:
803:
797:
796:
792:
790:
787:
786:
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556:0.945 mPa·s
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1233:plasticizers
1223:) or in the
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1134:distillation
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1051:hydrocarbons
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800:Autoignition
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683:
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536:
495:
272:RTECS number
64:Identifiers
54:
50:
1474:1226–1231.
1345:Description
1071:acetic acid
850:(oral, rat)
837:median dose
823:Lethal dose
802:temperature
789:Flash point
678:Signal word
456:0.937 g/mL
446:Ammoniacal
433:Appearance
386:Properties
377:CN(C)C(C)=O
203:100.004.389
165:ChEMBL11873
145:CHEBI:84254
1953:Acetamides
1942:Categories
1670:(1): 1–4.
1426:References
1316:Regulation
1291:depression
1263:teniposide
1192:COOH + (CH
1162:Hydrolysis
817:1.8–11.5%
657:Pictograms
616:combustion
421:Molar mass
297:JCV5VDB3HY
176:ChemSpider
92:3D model (
71:CAS Number
1590:. BASF SE
1271:amsacrine
1259:excipient
1244:cellulose
1048:aliphatic
1022:with the
1018:) is the
950:acetamide
728:P308+P313
648:labelling
589:formation
552:Viscosity
488:Miscible
279:AB7700000
224:204-826-4
216:EC Number
1862:20098340
1854:14005854
1811:14005853
1784:27293868
1733:16728503
1530:(NIOSH).
1505:(NIOSH).
1348:Category
1299:delusion
1277:Toxicity
1267:busulfan
1225:adhesive
1030:C(O)N(CH
926:300 ppm
736:NFPA 704
639:Hazards
130:1737614
81:127-19-5
1834:Bibcode
1826:Science
1775:4885965
1724:2078052
1684:9891094
1594:18 July
1499:"#0218"
1461:5844405
1221:spandex
1085:H·HN(CH
1040:solvent
1024:formula
989:what is
987: (
546:1.4375
526:270 nm
511:300 Pa
501:−0.253
452:Density
248:PubChem
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1337:Quebec
1289:(e.g.
1176:CON(CH
1158:amides
1101:CON(CH
1097:O + CH
984:verify
981:
684:Danger
517:UV-vis
426:87.122
370:SMILES
156:ChEMBL
40:Names
1858:S2CID
1330:REACH
1166:acids
1138:yield
1116:with
1065:with
884:NIOSH
345:InChI
261:31374
185:29107
136:ChEBI
94:JSmol
1850:PMID
1807:PMID
1780:PMID
1729:PMID
1680:PMID
1623:: 60
1596:2019
1560:ISBN
1457:PMID
1297:and
1231:and
1012:DMAc
920:IDLH
724:P280
710:H360
706:H332
702:H319
698:H312
494:log
442:Odor
288:UNII
233:MeSH
1842:doi
1830:136
1770:PMC
1760:doi
1719:PMC
1711:doi
1672:doi
1552:doi
1476:doi
1449:doi
1310:ABS
1308:or
1301:).
1273:).
1184:+ H
1093:→ H
1069:or
1042:in
1016:DMA
1014:or
907:REL
894:PEL
646:GHS
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314:EPA
251:CID
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1200:NH
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863:50
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414:O
411:N
408:9
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399:C
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55:N
53:,
51:N
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