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Glass coloring and color marking

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because of this chemical change; and such glass panes are prized as antiques. This process is widely confused with the formation of "desert amethyst glass", in which glass exposed to desert sunshine with a high ultraviolet component develops a delicate violet tint. Details of the process and the
840: 528:, giving yellows to oranges on stained glass. All of these are fired in a kiln or furnace to fix them, and can be extremely durable when properly applied. This is not true of "cold-painted" glass, using oil paint or other mixtures, which rarely last more than a few centuries. 847: 463:, in very small concentrations (around 0.001%, or 10 ppm), produces a rich ruby-colored glass ("Ruby Gold" or "Rubino Oro"), while lower concentrations produces a less intense red, often 715:
Bernard H. W. S. De Jong, Ruud G. C. Beerkens, Peter A. van Nijnatten: "Glass", in: "Ullmann's Encyclopedia of Industrial Chemistry"; Wiley-VCH Verlag GmbH & Co. KGaA, 2002,
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and results in deep yellow color, often used in glazes. However, cadmium is toxic. Together with selenium and sulphur it yields shades of bright red and orange.
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can be added to glass during its manufacture to change its color which can enhance its aesthetic appeal. Examples of these additives are listed below:
524:, essentially a technique for painting patterns or images, used for both glass vessels and on stained glass, and glass paint, typically in black, and 325:
is a very powerful colorizing agent, yielding dark green or in higher concentrations even black color. Together with tin oxide and arsenic it yields
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composition of the glass vary and so do the results, because it is not a simple matter to obtain or produce properly controlled specimens.
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Dichroic glass has one or several coatings in the nanometer-range (for example metals, metal oxides, or nitrides) which give the glass
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Werner Vogel: "Glass Chemistry"; Springer-Verlag Berlin and Heidelberg GmbH & Co. K; 2nd revised edition (November 1994),
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may be based on dark-colored inclusions, but with ionic coloring it is also possible to produce dark colors (see above).
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color. Manganese is one of the oldest glass additives, and purple manganese glass was used since early Egyptian history.
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with added nickel acquires purplish color. Nickel together with a small amount of cobalt was used for decolorizing of
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glass. Titanium, rarely used on its own, is more often employed to intensify and brighten other colorizing additives.
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and iron salts, is used to form iron polysulfides and produce amber glass ranging from yellowish to almost black. In
433:, like manganese, can be used in small concentrations to decolorize glass, or in higher concentrations to impart a 341:
plates during cooling, is made from glass with added chromium oxide in amount above its solubility limit in glass.
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enough to be dangerous, but if ground into a powder, such as by polishing with sandpaper, and inhaled, it can be
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produces a very dark red, opaque glass, which is sometimes used as a substitute for gold in the production of
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may be added to glass resulting in bluish-green glass which is frequently used in beer bottles. Together with
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dispersed in glass. It is a very important agent to make pink and red glass. When used together with
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tint which can be viewed in thick pieces or with the aid of scientific instruments. Further
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some houses built more than 300 years ago have window glass which is lightly tinted
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is a purple pigment formed by the reaction of gold salts with tin(II) chloride.
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to the naked eye when it is thin, although iron oxide impurities produce a
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Formation of Gold Nanoparticles in Gold Ruby Glass: The influence of Tin
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www.glassassociation.org.uk (Barrie Skelcher). Retrieved 3 August 2006
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glass: it appears blue from the side, but orange light shines through.
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pore-size gradient (large pores on the right); coloring based on the
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1st-glass.1st-things.com (David M Issitt). Retrieved 9 April 2014
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glass. The best results are achieved when using glass containing
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tint given by iron, or in higher concentrations to give glass an
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optical properties. Also the blue appearance of some automobile
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The physics and chemistry of color: the fifteen causes of color
556: 482: 449: 372:(0.1 to 2%) can be added to give glass a fluorescent yellow or 359: 300: 283: 275: 259: 219: 215: 37: 548: 373: 363: 308: 251: 237: 160: 156: 152: 148: 460: 445:, it yields a brilliant red color known as "Selenium Ruby". 279: 34: 476: 434: 58:
by precipitation of nanometer-sized colloids (so-called
915:"Why is the sky blue, and sunsets red?: Blue and Red" 394:
gives green color (used in UV filters) or lilac red.
303:, depending on the concentration, produces blue, or 286:. Very small amounts can be used for decolorizing. 226:rich in boron, sulfur imparts a blue color. With 938: 921:. Institute for Dynamic Educational Advancement 764:Substances Used in the Making of Coloured Glass 574: 62:such as "gold ruby" or red "selenium ruby"), 236:can be added in small amounts to remove the 834: 832: 515: 841:"Glassblowing for Laboratory Technicians" 776: 711: 709: 829: 826:www.speclab.com. Retrieved 3 August 2006 643: 594: 578: 413: 402: 337:is achieved by growth of large parallel 208:it gives a richer green color, used for 188: 173: 165: 134: 63: 29: 732: 730: 728: 14: 939: 838: 782: 706: 891:. www.glassonline.com. Archived from 531: 725: 493:can produce a range of colors from 398: 24: 520:The principal methods of this are 25: 963: 633: 47:may be obtained in several ways. 846:. wiredfreak.com. Archived from 130: 45:Glass coloring and color marking 907: 679:Color of medieval stained glass 675:- physical explanation coloring 877: 865: 817:Chemical Fact Sheet - Chromium 810: 757: 746: 230:it yields a deep yellow color. 13: 1: 947:Glass engineering and science 699: 610:Glass containing two or more 889:Illustrated Glass Dictionary 618:shows coloring based on the 421:. The coloring is caused by 347:together with sulphur forms 7: 666: 628:wavelength of visible light 10: 968: 637: 575:Color caused by scattering 437:color, caused by selenium 419:Photochromic eyeglass lens 547:oxides produce an opaque 721:10.1002/14356007.a12_365 663:is caused by dichroism. 559:to produce an imitation 274:Small concentrations of 689:Hydroxyl ion absorption 516:Coloring added to glass 652: 607: 592: 426: 411: 278:(0.025 to 0.1%) yield 197: 186: 171: 140: 76: 41: 783:Nassau, Kurt (2001). 694:Transparent materials 647: 622:and explained by the 598: 582: 417: 406: 192: 177: 169: 138: 104:phase separated glass 67: 33: 673:Crystal field theory 648:A pendant made from 565:painted with enamels 505:are based on silver. 503:photosensitive glass 423:silver nanoparticles 224:borosilicate glasses 139:Iron(II) oxide glass 499:photochromic lenses 339:chromium(III) oxide 256:sodium permanganate 51:by the addition of 40:of different colors 822:2017-08-15 at the 769:2010-04-02 at the 684:Hydrogen darkening 653: 616:refractive indices 608: 593: 567:. Similarly, some 563:, very often then 532:Colored inclusions 485:compounds such as 427: 412: 198: 187: 172: 141: 82:colored inclusions 77: 42: 27:Production methods 895:on 1 October 2011 796:978-0-471-39106-7 555:), first used in 509:Purple of Cassius 380:is typically not 248:Manganese dioxide 16:(Redirected from 959: 931: 930: 928: 926: 911: 905: 904: 902: 900: 881: 875: 869: 863: 862: 860: 858: 853:on 26 March 2012 852: 845: 836: 827: 814: 808: 807: 805: 803: 780: 774: 761: 755: 750: 744: 734: 723: 713: 399:Striking glasses 329:glass. Chromium 218:, together with 125:colored coatings 60:striking glasses 21: 967: 966: 962: 961: 960: 958: 957: 956: 952:Glass chemistry 937: 936: 935: 934: 924: 922: 919:Causes of Color 913: 912: 908: 898: 896: 883: 882: 878: 870: 866: 856: 854: 850: 843: 837: 830: 824:Wayback Machine 815: 811: 801: 799: 797: 781: 777: 771:Wayback Machine 762: 758: 751: 747: 735: 726: 714: 707: 702: 669: 642: 636: 614:with different 577: 534: 522:enamelled glass 518: 456:-colored glass. 443:cadmium sulfide 408:Cranberry glass 401: 349:cadmium sulfide 145:soda-lime glass 133: 72:, 1st century, 70:enamelled glass 28: 23: 22: 15: 12: 11: 5: 965: 955: 954: 949: 933: 932: 906: 876: 864: 828: 809: 795: 775: 756: 745: 724: 704: 703: 701: 698: 697: 696: 691: 686: 681: 676: 668: 665: 650:dichroic glass 640:Dichroic glass 638:Main article: 635: 634:Dichroic glass 632: 620:Tyndall effect 604:Tyndall effect 585:Tyndall effect 576: 573: 569:smoked glasses 533: 530: 517: 514: 513: 512: 506: 491:silver halides 487:silver nitrate 480: 457: 448:Pure metallic 446: 400: 397: 396: 395: 389: 367: 352: 342: 335:aventurescence 320: 298: 287: 272: 245: 231: 213: 202:Iron(II) oxide 196:for decoration 181:glowing under 132: 129: 128: 127: 121: 118:dichroic glass 107: 93: 78: 68:Ancient Roman 56: 26: 9: 6: 4: 3: 2: 964: 953: 950: 948: 945: 944: 942: 920: 916: 910: 894: 890: 886: 880: 873: 872:Uranium Glass 868: 849: 842: 835: 833: 825: 821: 818: 813: 798: 792: 788: 787: 779: 772: 768: 765: 760: 754: 749: 743: 742:3-540-57572-3 739: 733: 731: 729: 722: 718: 712: 710: 705: 695: 692: 690: 687: 685: 682: 680: 677: 674: 671: 670: 664: 662: 658: 651: 646: 641: 631: 629: 625: 621: 617: 613: 605: 601: 597: 590: 586: 581: 572: 570: 566: 562: 558: 554: 550: 546: 542: 538: 529: 527: 523: 510: 507: 504: 500: 496: 492: 488: 484: 481: 478: 474: 470: 466: 462: 458: 455: 451: 447: 444: 440: 439:nanoparticles 436: 432: 429: 428: 424: 420: 416: 409: 405: 393: 390: 387: 383: 379: 378:Uranium glass 375: 371: 368: 365: 361: 357: 353: 350: 346: 343: 340: 336: 332: 328: 327:emerald green 324: 321: 318: 314: 310: 306: 302: 299: 296: 292: 288: 285: 281: 277: 273: 269: 265: 262:compound. In 261: 257: 253: 249: 246: 243: 239: 235: 232: 229: 225: 221: 217: 214: 211: 207: 203: 200: 199: 195: 191: 184: 180: 179:Uranium glass 176: 168: 164: 162: 158: 154: 150: 146: 137: 131:Coloring ions 126: 122: 119: 115: 113: 108: 105: 101: 100: 94: 91: 87: 83: 79: 75: 71: 66: 61: 57: 54: 53:coloring ions 50: 49: 48: 46: 39: 36: 32: 19: 18:Colored glass 923:. Retrieved 918: 909: 897:. Retrieved 893:the original 888: 879: 867: 855:. Retrieved 848:the original 839:R. Barbour. 812: 800:. Retrieved 785: 778: 759: 748: 654: 609: 600:Porous glass 535: 526:silver stain 519: 386:carcinogenic 313:Lead crystal 291:copper oxide 210:wine bottles 194:Cobalt glass 142: 124: 110: 96: 90:smoked glass 81: 74:Begram Hoard 59: 52: 44: 43: 661:windshields 475:with added 382:radioactive 333:, in which 293:produces a 289:2 to 3% of 264:New England 250:, which is 183:ultraviolet 170:Amber Glass 941:Categories 885:"Selenium" 700:References 624:Mie theory 589:opalescent 553:milk glass 473:lead glass 331:aventurine 317:lead glass 307:, or even 159:and metal 99:scattering 86:milk glass 789:. Wiley. 561:porcelain 537:Tin oxide 469:cranberry 459:Metallic 360:yellowish 358:produces 295:turquoise 258:, a dark 234:Manganese 185:radiation 149:colorless 143:Ordinary 925:23 April 820:Archived 767:Archived 667:See also 657:dichroic 541:antimony 465:marketed 431:Selenium 392:Didymium 356:titanium 323:Chromium 242:amethyst 206:chromium 147:appears 114:coatings 112:dichroic 899:9 April 857:9 April 802:4 April 551:glass ( 545:arsenic 435:reddish 376:color. 370:Uranium 354:Adding 345:Cadmium 311:glass. 228:calcium 102:(as in 84:(as in 38:bottles 793:  740:  612:phases 557:Venice 495:orange 483:Silver 450:copper 305:violet 301:Nickel 297:color. 284:potash 276:cobalt 268:violet 260:purple 220:carbon 216:Sulfur 161:oxides 157:metals 97:light 851:(PDF) 844:(PDF) 549:white 539:with 374:green 364:brown 309:black 252:black 238:green 153:green 120:), or 116:(see 927:2014 901:2014 859:2014 804:2013 791:ISBN 738:ISBN 583:The 543:and 501:and 489:and 467:as " 461:gold 454:ruby 410:bowl 280:blue 88:and 35:Beer 717:doi 587:in 477:tin 123:by 109:by 95:by 80:by 943:: 917:. 887:. 831:^ 727:^ 708:^ 929:. 903:. 861:. 806:. 719:: 606:. 479:. 425:. 362:- 319:. 212:. 106:) 92:) 55:, 20:)

Index

Colored glass

Beer
bottles

enamelled glass
Begram Hoard
milk glass
smoked glass
scattering
phase separated glass
dichroic
dichroic glass

soda-lime glass
colorless
green
metals
oxides


Uranium glass
ultraviolet

Cobalt glass
Iron(II) oxide
chromium
wine bottles
Sulfur
carbon

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