51:
1698:
42:
1459:
names, are determined according to the substitutive and additive nomenclatures, respectively. The name sulfide is also used in compositional IUPAC nomenclature which does not take the nature of bonding involved. Examples of such naming include
701:
materials and most generally causes mass loss, cracking of the sewer pipes and ultimately, structural collapse. This kind of deterioration is a major process affecting sewer systems worldwide and leading to very high rehabilitation costs.
520:
sulfides typically have very low solubility in water, and many are related to minerals with the same composition (see below). One famous example is the bright yellow species CdS or "
663:
S, HS and S) are very aggressive species for the corrosion of many metals such as steel, stainless steel, and copper. Sulfides present in aqueous solution are responsible for
1730:
532:
properties, which in turn is related to the deep colors. Several have practical applications as pigments, in solar cells, and as catalysts. The fungus
651:) of their surrounding environment during their formation. Scientists use these minerals to study environments in the deep sea or in the Earth's past.
528:
S. Such species are sometimes referred to as salts. In fact, the bonding in transition metal sulfides is highly covalent, which gives rise to their
1456:
458:
697:
producing sulfide that is emitted in the air and oxidized in sulfuric acid by sulfur oxidizing bacteria. Biogenic sulfuric acid reacts with
1409:
Many metal sulfides are so insoluble in water that they are probably not very toxic. Some metal sulfides, when exposed to a strong mineral
247:
1248:. The presence of the highly toxic selenium in healthcare and cosmetics products represents a general health and environmental concern.
1793:
734:
of steel and stainless steel while the medium is also acidified by the production of sulfuric acid when oxidation is more advanced.
1800:
1035:, is used as a catalyst to remove sulfur from fossil fuels; also as lubricant for high-temperature and high-pressure applications.
1723:
76:
Sulfanediide (substitutive), not common, rarely used, sometimes generated by automated nomenclature software in organic chemistry
850:). Most often in sulfur chemistry and in biochemistry, the disulfide term is commonly ascribed to the sulfur analogue of the
1506:
1716:
1624:
1604:
222:
383:
with the chemical formula S or a compound containing one or more S ions. Solutions of sulfide salts are corrosive.
349:
1619:
Vaughan, D. J.; Craig, J. R. “Mineral chemistry of metal sulfides" Cambridge
University Press, Cambridge: 1978.
1213:
is a polymer commonly called "Sulfar". Its repeating units are bonded together by sulfide (thioether) linkages.
1180:. ZnS-doped with silver is used in alpha detectors while zinc sulfide with traces of copper has applications in
1435:
Hydrogen sulfide, some of its salts, and almost all organic sulfides have a strong and putrid stench; rotting
453:
of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur,
671:. Corrosion is a major concern in many industrial installations processing sulfides: sulfide ore mills, deep
69:
199:
830:, or S–S dianion, in association with divalent iron in the formal +2 oxidation state (ferrous ion: Fe).
2051:
690:
1224:
1220:
1114:
1702:
1281:
1256:
1192:
1151:
1042:
1015:
937:
912:
694:
664:
24:
1566:
Meyer, B; Ward, K; Koshlap, K; Peter, L (1983). "Second dissociation constant of hydrogen sulfide".
1086:
1177:
990:
668:
19:
This article is about sulfur anion in general. For the organic compound also called sulfide, see
1594:
1954:
1241:
1210:
1139:
1074:
763:
388:
334:
123:
2056:
1028:
799:
208:
163:
99:
1531:
May, P.M.; Batka, D.; Hefter, G.; Könignberger, E.; Rowland, D. (2018). "Goodbye to S2-".
8:
806:) consists of separated sulfide centers, in association with molybdenum in the formal +4
686:
373:
89:
1488:
143:
2041:
1461:
1237:
2046:
1660:
1620:
1600:
1548:
1181:
831:
743:
731:
572:
534:
502:
1650:
1575:
1540:
1465:
1418:
978:
903:
is a very toxic and corrosive gas characterised by a typical odour of "rotten egg".
900:
843:
775:
751:
432:
396:
392:
267:
188:
2036:
922:
807:
547:
369:
1510:
1742:
1425:
1128:
1100:
1070:
521:
343:
301:
2030:
1739:
1664:
1165:
1132:
529:
1708:
1655:
1638:
1923:
1818:
1552:
1414:
1161:
1000:
632:
774:
S. Occasionally, the term sulfide refers to molecules containing the –SH
1770:
1245:
1032:
950:
706:
680:
592:
584:
454:
1579:
1424:
Organic sulfides are highly flammable. When a sulfide burns it produces
1908:
1901:
1544:
616:
588:
288:
154:
1077:(thioether) that was used as a chemical weapon in the First World War.
1919:
1887:
1866:
1841:
1786:
1004:
958:
954:
926:
855:
795:
747:
560:
517:
404:
306:
20:
342:
Except where otherwise noted, data are given for materials in their
2014:
1993:
1986:
1961:
1947:
1894:
1870:
1855:
1848:
1834:
1807:
1750:
1173:
851:
746:, "sulfide" usually refers to the linkage C–S–C, although the term
698:
672:
612:
608:
568:
415:
The sulfide ion does not exist in aqueous alkaline solutions of Na
330:
782:–SH. The preferred descriptor for such SH-containing compounds is
122:
2000:
1972:
1880:
1827:
1759:
1639:"Microbial Life Deep Under the Seafloor—A Story of Not Giving Up"
1436:
946:
859:
648:
644:
604:
600:
505:
470:
466:
462:
175:
2007:
1976:
1779:
1697:
1270:
1169:
1104:
863:
811:
640:
624:
596:
576:
564:
474:
380:
1682:(5th ed.). New York: W. H. Freeman & Co. p. 413.
730:), an intermediate species responsible for severe problems of
50:
1933:
1294:
Sulfide compounds can be prepared in several different ways:
1135:
783:
553:
450:
326:
134:
112:
538:
plays a role in the solubilization of heavy metal sulfides.
41:
1483:
1481:
1410:
636:
628:
620:
580:
1530:
846:
has no S–S bond, being S=C=S (linear molecule analog to CO
794:
Confusion arises from the different meanings of the term "
676:
556:
376:
320:
1478:
1184:
strips for emergency lighting and luminous watch dials.
858:
bond (–S–S–) plays a major role in the conformation of
786:
or mercaptan, i.e. methanethiol, or methyl mercaptan.
431:
Upon treatment with an acid, sulfide salts convert to
1565:
524:". The black tarnish formed on sterling silver is Ag
2028:
1493:Chemical Entities of Biological Interest (ChEBI)
187:
1592:
654:
387:also refers to large families of inorganic and
98:
750:is less ambiguous. For example, the thioether
419:S. Instead sulfide converts to hydrosulfide:
1738:
1724:
1677:
1637:Tsang, Man-Yin; Inagaki, Fumio (2020-05-29).
1636:
1244:used in anti-dandruff preparations, such as
1131:, as the hydrate, is used in manufacture of
559:are sulfides. Significant examples include:
1731:
1717:
162:
1654:
981:is a precursor to organosulfur compounds.
810:(that is, Mo and two S). Iron disulfide (
778:. For example, methyl sulfide can mean CH
407:(SH) are the conjugate acids of sulfide.
207:
1507:"SULFIDE English Definition and Meaning"
1495:. UK: European Bioinformatics Institute.
1394:
516:S) to precipitate solid sulfides. Such
74:Sulfide(2−) (additive), recommended name
1368:Precipitation of an insoluble sulfide:
766:(see below) has the empirical formula C
2029:
1599:. John Wiley & Sons. p. 509.
1596:Mycoremediation: Fungal Bioremediation
410:
1712:
667:(SCC) of steel, and is also known as
234:Key: UCKMPCXJQFINFW-UHFFFAOYSA-N
142:
16:Ion, and compounds containing the ion
1593:Harbhajan Singh (17 November 2006).
737:
496:
705:Oxidation of sulfide can also form
178:
13:
49:
40:
14:
2068:
1690:
1468:, which contain no sulfide ions.
862:and in the catalytic activity of
1696:
1298:Direct combination of elements:
818:) on the other hand consists of
675:, pipelines transporting soured
1442:
1378:
1359:
346:(at 25 °C , 100 kPa).
1671:
1630:
1613:
1586:
1559:
1524:
1499:
1289:
1:
1471:
1386:
1351:
1343:
1335:
1320:
1312:
1304:
789:
687:Microbially-induced corrosion
508:react with sulfide sources (H
1509:. Lexico.com. Archived from
655:Corrosion induced by sulfide
469:. Metal sulfides react with
7:
1489:"sulfide(2−) (CHEBI:15138)"
869:
834:has the chemical binding CH
647:recorded information (like
36:
10:
2073:
691:biogenic sulfide corrosion
659:Dissolved free sulfides (H
545:
541:
18:
1971:
1918:
1865:
1817:
1769:
1749:
1643:Frontiers for Young Minds
1404:
695:sulfate reducing bacteria
665:stress corrosion cracking
340:
312:
260:
243:
218:
82:
68:
63:
35:
25:Sulphide (disambiguation)
1678:Atkins; Shriver (2010).
1329:Reduction of a sulfate:
1269:Known as "fool's gold",
391:, e.g. lead sulfide and
1656:10.3389/frym.2020.00070
669:sulfide stress cracking
643:sulfide). This sulfide
1273:, is a common mineral.
1140:organosulfur compounds
1138:and as a precursor to
54:
45:
23:. For other uses, see
1447:The systematic names
1417:, will release toxic
1211:Polyphenylene sulfide
1075:organosulfur compound
764:Polyphenylene sulfide
501:Aqueous solutions of
481:8 MgS + 8 I
70:Systematic IUPAC name
53:
44:
1705:at Wikimedia Commons
1073:(mustard gas) is an
1029:Molybdenum disulfide
953:") is a traditional
800:Molybdenum disulfide
1680:Inorganic Chemistry
1580:10.1021/ic00158a027
1568:Inorganic Chemistry
693:are also caused by
411:Chemical properties
296: g·mol
32:
1545:10.1039/c8cc00187a
1462:selenium disulfide
1238:Selenium disulfide
1103:is a component of
885:Boiling point (°C)
882:Melting point (°C)
350:Infobox references
313:Related compounds
55:
46:
30:
2052:Functional groups
2024:
2023:
1701:Media related to
1539:(16): 1980–1983.
1513:on August 2, 2019
1287:
1286:
832:Dimethyldisulfide
744:organic chemistry
738:Organic chemistry
732:pitting corrosion
535:Aspergillus niger
503:transition metals
497:Metal derivatives
477:and metal salts.
389:organic compounds
358:Chemical compound
356:
355:
124:Interactive image
59:
58:
2064:
2017:
2010:
2003:
1996:
1989:
1964:
1957:
1950:
1943:
1936:
1911:
1904:
1897:
1890:
1883:
1858:
1851:
1844:
1837:
1830:
1810:
1803:
1796:
1789:
1782:
1762:
1733:
1726:
1719:
1710:
1709:
1700:
1684:
1683:
1675:
1669:
1668:
1658:
1634:
1628:
1617:
1611:
1610:
1590:
1584:
1583:
1563:
1557:
1556:
1528:
1522:
1521:
1519:
1518:
1503:
1497:
1496:
1485:
1466:titanium sulfide
1439:releases these.
1419:hydrogen sulfide
1396:
1388:
1380:
1361:
1353:
1345:
1337:
1322:
1314:
1306:
1182:photoluminescent
1067:
979:Carbon disulfide
901:Hydrogen sulfide
874:
873:
854:–O–O– bond. The
844:carbon disulfide
829:
828:
827:
776:functional group
752:dimethyl sulfide
729:
728:
727:
719:
718:
631:disulfide), and
433:hydrogen sulfide
397:Hydrogen sulfide
393:dimethyl sulfide
295:
282:
281:
280:
268:Chemical formula
211:
191:
180:
166:
146:
126:
102:
37:
33:
29:
2072:
2071:
2067:
2066:
2065:
2063:
2062:
2061:
2027:
2026:
2025:
2020:
2013:
2006:
1999:
1992:
1985:
1967:
1960:
1953:
1946:
1939:
1932:
1914:
1907:
1900:
1893:
1886:
1879:
1861:
1854:
1847:
1840:
1833:
1826:
1813:
1806:
1799:
1792:
1785:
1778:
1765:
1758:
1745:
1740:Monatomic anion
1737:
1693:
1688:
1687:
1676:
1672:
1635:
1631:
1618:
1614:
1607:
1591:
1587:
1564:
1560:
1529:
1525:
1516:
1514:
1505:
1504:
1500:
1487:
1486:
1479:
1474:
1445:
1431:
1407:
1398:
1390:
1382:
1374:
1363:
1355:
1347:
1339:
1324:
1316:
1308:
1292:
1266:
1234:
1223:
1206:
1202:
1172:devices in the
1124:
1096:
1065:
1061:
1057:
1053:
1049:
1025:
975:
925:can be used in
923:Cadmium sulfide
896:
872:
849:
841:
837:
826:
823:
822:
821:
819:
817:
808:oxidation state
805:
792:
781:
773:
769:
761:
757:
740:
726:
723:
722:
721:
717:
714:
713:
712:
710:
662:
657:
623:sulfide), and
607:sulfide), and
552:Many important
550:
548:sulfide mineral
544:
527:
515:
511:
499:
492:
488:
484:
445:
426:
418:
413:
402:
370:British English
359:
352:
347:
333:
329:
323:
293:
279:
277:
276:
275:
273:
270:
256:
251:
250:
239:
236:
235:
232:
226:
225:
214:
194:
181:
169:
149:
129:
116:
105:
92:
78:
77:
75:
28:
17:
12:
11:
5:
2070:
2060:
2059:
2054:
2049:
2044:
2039:
2022:
2021:
2019:
2018:
2011:
2004:
1997:
1990:
1982:
1980:
1969:
1968:
1966:
1965:
1958:
1951:
1944:
1937:
1929:
1927:
1916:
1915:
1913:
1912:
1905:
1898:
1891:
1884:
1876:
1874:
1863:
1862:
1860:
1859:
1852:
1845:
1838:
1831:
1823:
1821:
1815:
1814:
1812:
1811:
1804:
1797:
1790:
1783:
1775:
1773:
1767:
1766:
1764:
1763:
1755:
1753:
1747:
1746:
1736:
1735:
1728:
1721:
1713:
1707:
1706:
1692:
1691:External links
1689:
1686:
1685:
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1612:
1605:
1585:
1558:
1523:
1498:
1476:
1475:
1473:
1470:
1444:
1441:
1429:
1426:sulfur dioxide
1406:
1403:
1402:
1401:
1400:
1399:
1392:
1384:
1376:
1372:
1371:Example: M + H
1366:
1365:
1364:
1357:
1349:
1341:
1333:
1327:
1326:
1325:
1318:
1310:
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1196:
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1190:
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1185:
1159:
1155:
1154:
1149:
1146:
1143:
1129:Sodium sulfide
1126:
1122:
1118:
1117:
1112:
1110:
1108:
1101:Silver sulfide
1098:
1094:
1090:
1089:
1084:
1081:
1078:
1071:Sulfur mustard
1068:
1063:
1059:
1055:
1051:
1046:
1045:
1040:
1038:
1036:
1031:, the mineral
1026:
1023:
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994:
993:
988:
985:
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968:
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964:
962:
949:polysulfide ("
944:
941:
940:
935:
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930:
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907:
904:
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894:
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868:
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839:
835:
824:
815:
803:
791:
788:
779:
771:
767:
759:
755:
739:
736:
724:
715:
660:
656:
653:
546:Main article:
543:
540:
525:
522:cadmium yellow
513:
509:
498:
495:
494:
493:
490:
486:
482:
448:
447:
443:
440:
429:
428:
427:O → SH + OH
424:
416:
412:
409:
400:
357:
354:
353:
348:
344:standard state
341:
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302:Conjugate acid
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231:InChI=1S/S/q-2
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212:
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1984:
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1981:
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1963:
1959:
1956:
1952:
1949:
1945:
1942:
1938:
1935:
1931:
1930:
1928:
1925:
1924:Chalcogenides
1921:
1917:
1910:
1906:
1903:
1899:
1896:
1892:
1889:
1885:
1882:
1878:
1877:
1875:
1872:
1868:
1864:
1857:
1853:
1850:
1846:
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1839:
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1625:0-521-21489-0
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1606:9780470050583
1602:
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1577:
1573:
1569:
1562:
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1546:
1542:
1538:
1534:
1527:
1512:
1508:
1502:
1494:
1490:
1484:
1482:
1477:
1469:
1467:
1463:
1458:
1454:
1450:
1440:
1438:
1433:
1427:
1422:
1420:
1416:
1415:gastric acids
1412:
1370:
1369:
1367:
1332:Example: MgSO
1331:
1330:
1328:
1300:
1299:
1297:
1296:
1295:
1283:
1280:
1278:
1275:
1272:
1268:
1262:
1261:
1258:
1255:
1253:
1250:
1247:
1243:
1239:
1236:
1230:
1229:
1226:
1222:
1219:
1217:
1215:
1212:
1209:
1198:
1197:
1194:
1191:
1188:
1186:
1183:
1179:
1175:
1171:
1167:
1163:
1160:
1157:
1156:
1153:
1150:
1147:
1144:
1141:
1137:
1134:
1130:
1127:
1120:
1119:
1116:
1113:
1111:
1109:
1106:
1102:
1099:
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530:semiconductor
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459:polythionates
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1574:(16): 2345.
1571:
1567:
1561:
1536:
1532:
1526:
1515:. Retrieved
1511:the original
1501:
1492:
1452:
1449:sulfanediide
1448:
1446:
1443:Nomenclature
1434:
1423:
1413:, including
1408:
1293:
1176:part of the
1164:is used for
1162:Zinc sulfide
1001:Lead sulfide
793:
741:
704:
685:
658:
633:chalcopyrite
551:
533:
500:
489:+ 8 MgI
455:polysulfides
449:
439:S + H → SH
430:
414:
384:
365:
361:
360:
83:Identifiers
2057:Sulfur ions
1453:sulfide(2−)
1301:Example: Fe
1290:Preparation
1246:Selsun Blue
1033:molybdenite
1003:is used in
951:lime sulfur
888:CAS number
707:thiosulfate
683:factories.
681:Kraft paper
593:pentlandite
585:molybdenite
583:sulfide),
512:S, NaHS, Na
442:SH + H → H
261:Properties
144:CHEBI:15138
2031:Categories
1533:Chem. Comm
1517:2022-08-24
1472:References
1242:antifungal
1225:25212-74-2
1221:26125-40-6
1168:and other
1115:21548-73-2
927:photocells
842:, whereas
790:Disulfides
617:sphalerite
615:sulfide),
599:sulfide),
591:sulfide),
589:molybdenum
575:sulfide),
567:sulfide),
473:, forming
289:Molar mass
209:G15I91XETI
155:ChemSpider
111:3D model (
100:18496-25-8
90:CAS Number
2042:Corrosion
1871:Pnictides
1743:compounds
1665:2296-6846
1282:1317-66-4
1257:7488-56-4
1193:1314-98-3
1152:1313-82-2
1043:1317-33-5
1016:1314-87-0
1005:infra-red
959:gardening
955:fungicide
938:1306-23-6
913:7783-06-4
856:disulfide
796:disulfide
748:thioether
689:(MIC) or
673:oil wells
561:argentite
518:inorganic
451:Oxidation
405:bisulfide
374:inorganic
335:Telluride
307:Bisulfide
21:thioether
2047:Sulfides
1973:Group 17
1920:Group 16
1867:Group 15
1819:Group 14
1771:Group 13
1703:Sulfides
1553:29404555
1455:, valid
1178:spectrum
1174:infrared
1107:tarnish.
1087:505-60-2
1007:sensors.
870:Examples
860:proteins
852:peroxide
699:sewerage
649:isotopes
645:minerals
613:antimony
609:stibnite
569:cinnabar
471:halogens
372:) is an
366:sulphide
331:selenide
31:Sulfide
1977:Halides
1751:Group 1
1437:biomass
1432:) gas.
1251:<100
1170:optical
991:75-15-0
947:Calcium
877:Formula
864:enzymes
838:–S–S–CH
605:arsenic
601:realgar
573:mercury
542:Geology
506:cations
467:sulfate
463:sulfite
403:S) and
385:Sulfide
362:Sulfide
283:
176:PubChem
2037:Anions
1663:
1649:: 70.
1623:
1603:
1551:
1405:Safety
1271:pyrite
1240:is an
1166:lenses
1105:silver
984:−111.6
909:−60.20
812:pyrite
641:copper
625:pyrite
597:nickel
577:galena
565:silver
475:sulfur
423:S + H
381:sulfur
364:(also
321:anions
319:Other
248:SMILES
64:Names
1457:IUPAC
1356:+ 4CO
1348:→ MgS
1317:→ FeS
1136:paper
1133:kraft
1080:13–14
1058:–S–CH
1050:Cl–CH
906:−85.7
814:, FeS
784:thiol
758:–S–CH
754:is CH
554:metal
465:, or
377:anion
327:oxide
294:32.06
223:InChI
189:29109
164:27079
135:ChEBI
113:JSmol
1661:ISSN
1621:ISBN
1601:ISBN
1549:PMID
1464:and
1451:and
1411:acid
1391:+ 2H
1383:→ MS
1340:+ 4C
1189:1850
1148:1180
1010:1114
932:1750
802:(MoS
679:and
637:iron
629:iron
621:zinc
581:lead
557:ores
200:UNII
1651:doi
1576:doi
1541:doi
1428:(SO
1309:+ S
1276:600
1263:FeS
1231:SeS
1158:ZnS
1145:920
1083:217
1066:–Cl
1022:MoS
997:PbS
957:in
919:CdS
798:".
742:In
677:oil
485:→ S
379:of
368:in
179:CID
2033::
2015:At
2001:Br
1994:Cl
1962:Po
1955:Te
1948:Se
1909:Bi
1902:Sb
1895:As
1856:Pb
1849:Sn
1842:Ge
1835:Si
1808:Tl
1801:In
1794:Ga
1787:Al
1659:.
1645:.
1641:.
1572:22
1570:.
1547:.
1537:54
1535:.
1491:.
1480:^
1421:.
1395:aq
1334:4(
1121:Na
1093:Ag
1062:CH
1054:CH
987:46
972:CS
866:.
762:.
461:,
457:,
435::
399:(H
395:.
2008:I
1987:F
1979:)
1975:(
1941:S
1934:O
1926:)
1922:(
1888:P
1881:N
1873:)
1869:(
1828:C
1780:B
1760:H
1732:e
1725:t
1718:v
1667:.
1653::
1647:8
1627:.
1609:.
1582:.
1578::
1555:.
1543::
1520:.
1430:2
1397:)
1393:(
1389:)
1387:s
1385:(
1381:)
1379:g
1377:(
1375:S
1373:2
1362:)
1360:g
1358:(
1354:)
1352:s
1350:(
1346:)
1344:s
1342:(
1338:)
1336:s
1323:)
1321:s
1319:(
1315:)
1313:s
1311:(
1307:)
1305:s
1303:(
1265:2
1233:2
1207:S
1205:4
1203:H
1201:6
1199:C
1142:.
1125:S
1123:2
1097:S
1095:2
1064:2
1060:2
1056:2
1052:2
1024:2
974:2
961:.
929:.
897:S
895:2
893:H
848:2
840:3
836:3
825:2
820:S
816:2
804:2
780:3
772:4
770:H
768:6
760:3
756:3
725:3
720:O
716:2
711:S
709:(
661:2
639:-
635:(
627:(
619:(
611:(
603:(
595:(
587:(
579:(
571:(
563:(
526:2
514:2
510:2
491:2
487:8
483:2
446:S
444:2
425:2
417:2
401:2
274:S
115:)
27:.
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