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Noble metal

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394: 457: 366: 329: 350: 475: 33: 380: 443: 494: 3921: 415: 429: 3933: 523:(iron-lovers). They tend to sink into the Earth's core because they dissolve readily in iron either as solid solutions or in the molten state. Most siderophile elements have practically no affinity whatsoever for oxygen: indeed, oxides of gold are thermodynamically unstable with respect to the elements. 2074:
Gold, Platinum, Silver, and a few rare metals. The members of this class have little or no tendency to unite with oxygen in the free state, and when placed in water at a red heat do not alter its composition. The oxides are readily decomposed by heat in consequence of the feeble affinity between the
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Such nobility is mainly associated with the relatively high electronegativity values of the noble metals, resulting in only weakly polar covalent bonding with oxygen. The table lists the melting points of the oxides of the noble metals, and for some of those of the non-noble metals, for the elements
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in aqueous solution are also a useful way of predicting the non-aqueous chemistry of the metals involved. Thus, metals with high negative potentials, such as sodium, or potassium, will ignite in air, forming the respective oxides. These fires cannot be extinguished with water, which also react with
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The expression noble metal is sometimes confined to copper, silver, and gold since their full d-subshells can contribute to their noble character. There are also known to be significant contributions from how readily there is overlap of the d-electron states with the orbitals of other elements,
1638:= 4 OH) which is 0.4 V...The...metal with...a potential less than 0.4 V acts as an anode...loses electrons...and dissolves in the aqueous medium. The noble metal (with higher electrochemical potential) acts as a cathode and, under many conditions, the reaction on this electrode is generally 666:
the metals involved to give hydrogen, which is itself explosive. Noble metals, in contrast, are disinclined to react with oxygen and, for that reason (as well as their scarcity) have been valued for millennia, and used in jewellery and coins.
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Abundance of the chemical elements in the Earth's crust as a function of atomic number. The rarest elements (shown in yellow, including the noble metals) are not the heaviest, but are rather the siderophile (iron-loving) elements in the
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The elements to the left of gold and silver have incompletely filled d-bands, which is believed to play a role in their catalytic properties. A common explanation is the d-band filling model of Hammer and
1679:(116) inclusive are expected to be "partially very noble metals"; chemical investigations of hassium has established that it behaves like its lighter congener osmium, and preliminary investigations of 542:
Noble metals tend to be resistant to oxidation and other forms of corrosion, and this corrosion resistance is often considered to be a defining characteristic. Some exceptions are described below.
587:, and is said to be tarnished by moist air. Osmium and iridium are chemically inert in ambient conditions. Platinum and gold can be dissolved in aqua regia. Mercury reacts with oxidising acids. 610:
N achieved "high dissolution rates of noble metals under mild conditions, with the added benefit of being tunable to a specific metal" for example, gold but not palladium or platinum.
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G. Wulfsberg, "Inorganic Chemistry", University Science Books, 2000, pp. 247–249 ✦ Bratsch S. G., "Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K",
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published a table in 1864, in which the "noble metals" rhodium, ruthenium, palladium; and platinum, iridium, and osmium were grouped together, and adjacent to silver and gold.
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The thick black line encloses the seven to eight metals most often to often so recognized. Silver is sometimes not recognized as a noble metal on account of its greater
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In more specialized fields of study and applications the number of elements counted as noble metals can be smaller or larger. It is sometimes used for the three metals
2462:"Surface electronic structure and reactivity of transition and noble metals1Communication presented at the First Francqui Colloquium, Brussels, 19–20 February 1996.1" 1602:
Rayner-Canham contends that, "silver is so much more chemically-reactive and has such a different chemistry, that it should not be considered as a 'noble metal'." In
474: 292:) that runs from noble to active, and allows one to predict how materials will interact in the environment used to generate the series. In this sense of the word, 2083:"There is no sharp dividing line but perhaps the best definition of a noble metal is a metal whose oxide is easily decomposed at a temperature below a red heat." 1552:
of the considered element in water. Noble metals have large positive potentials; elements not in this table have a negative standard potential or are not metals.
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vol. 18, no. 1, 1989, pp. 1–21 ✦ B. Douglas, D. McDaniel, J. Alexander, "Concepts and Models of Inorganic Chemistry", John Wiley & Sons, 1994, p. E-3
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Medici S, Peana MF, Zoroddu MA 2018, "Noble metals in pharmaceuticals: Applications and limitations", in M Rai M, Ingle, S Medici (eds.),
253:, silver is not always considered a noble metal because it is subject to corrosion when present in the mouth. All the metals are important 3015:
Brubaker PE, Moran JP, Bridbord K, Hueter FG 1975, "Noble metals: a toxicological appraisal of potential new environmental contaminants",
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The relevance of the entry for water is addressed by Li et al. in the context of galvanic corrosion. Such a process will only occur when:
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can be traced back to at least the late 14th century and has slightly different meanings in different fields of study and application.
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materials is relatively higher. Tellurium and selenium have been depleted from the crust due to formation of volatile hydrides.
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particularly for gold. Relativistic contributions are also important, playing a role in the catalytic properties of gold.
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Lal H, Bhagat SN 1985, "Gradation of the metallic character of noble metals on the basis of thermoelectric properties",
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element that does not react with a weak acid and give off hydrogen gas in the process. This broader set includes copper,
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in volts; electronegativity (revised Pauling); and electron affinity values (kJ/mol), for some metals and metalloids.
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is more noble than silver and the relative nobility of many materials is highly dependent upon context, as for
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Electronegativity is included since it is reckoned to be, "a major driver of metal nobleness and reactivity".
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Periodic table extract showing approximately how often each element tends to be recognized as a noble metal:
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The black tarnish commonly seen on silver arises from its sensitivity to sulphur containing gases such as
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Pan S et al. 2019, "Noble-noble strong union: Gold at its best to make a bond with a noble gas atom",
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Noble metals and biological systems: Their role in medicine, mineral exploration, and the environment,
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Palladium oxide PdO can be reduced to palladium metal by exposing it to hydrogen in ambient conditions
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Hämäläinen J, Ritala M, Leskelä M 2013, "Atomic layer deposition of noble metals and their oxides",
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Everett Collier, "The Boatowner's Guide to Corrosion", International Marine Publishing, 2001, p. 21
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Prior to Mendeleev's publication in 1869 of the first (eventually) widely accepted periodic table,
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Schlamp, G (2018). "Noble metals and noble metal alloys". In Warlimont, H; Martienssen, W (eds.).
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are sometimes included as noble metals, but each of these usually occurs in nature combined with
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G. Wulfsberg 2000, "Inorganic Chemistry", University Science Books, Sausalito, CA, pp. 270, 937.
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Constable EC 2019, "Evolution and understanding of the d-block elements in the periodic table",
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Rayner-Canham, G (2018). "Organizing the transition metals". In Scerri, E; Restrepo, G (eds.).
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is a hierarchy of metals (or other electrically conductive materials, including composites and
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In 2010, US researchers discovered that an organic "aqua regia" in the form of a mixture of
3570: 3254: 2858: 527: 266: 243: 152: 1691:'s behaviour seems to partly resemble both its lighter congener mercury and the noble gas 8: 3963: 3487: 2994:
Brasser R, Mojzsis SJ 2017, "A colossal impact enriched Mars' mantle with noble metals",
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or mercury sulfide (HgS) is the most common source ore for refining elemental mercury
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While lists of noble metals can differ, they tend to cluster around gold and the six
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Encyclopedia of Analytical Chemistry: Applications, Theory and Instrumentation
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Lyon SB 2010, "3.21 - Corrosion of noble metals", in B Cottis et al. (eds.),
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Mendeleev to Oganesson: A multidisciplinary perspective on the periodic table
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is a mixed oxidation state compound silver in the oxidation state of 1 and 3.
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The simplified entries in the reaction column can be read in detail from the
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All the noble metals can act as catalysts. For example, platinum is used in
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Hiorns RH 1890, Mixed metals or metallic alloys, MacMillian, New York, p. 5
2921: 2902: 2680:"Surface plasmons in metallic nanoparticles: fundamentals and applications" 2492: 2302: 2294: 2130: 627:, where the total d-bands are considered, not just the unoccupied states. 531: 335: 207: 32: 3680: 3309: 3003: 2845:
Nagame, Yuichiro; Kratz, Jens Volker; Matthias, Schädel (December 2015).
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of elements. These have been depleted by being relocated deeper into the
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Russel A 1931, "Simple deposition of reactive metals on noble metals",
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Many of the noble metals are used in alloys for jewelry or coinage. In
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Ruban, A; Hammer, B; Stoltze, P; Skriver, H.L; Nørskov, J.K (1997).
202:, while it is often used mainly for silver and gold when discussing 3502: 3459: 3138:
Wang H 2017, "Chapter 9 - Noble Metals", in LY Jiang, N Li (eds.),
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A. Holleman, N. Wiberg, "Inorganic Chemistry", Academic Press, 2001
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Gold has many industrial applications; it is used as a catalyst in
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Emerging noble metal aerogels: State of the art and a look forward
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Mewes, J.-M.; Smits, O. R.; Kresse, G.; Schwerdtfeger, P. (2019).
2799:(10th ed.). St Louis: Elsevier Health Sciences. p. 134. 3329: 3165: 2610:"Electronic factors determining the reactivity of metal surfaces" 1672: 1361: 1299: 1198: 958: 779: 631: 235: 227: 223: 172: 160: 103: 87: 1687:
have suggested but not definitively established noble behavior.
269:: ruthenium, rhodium, palladium, osmium, iridium, and platinum. 1160: 997: 857: 195: 188: 180: 176: 168: 109: 99: 2203:
Balcerzak, M (2021). "Noble Metals, Analytical Chemistry of".
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properties are also of some importance, particularly those of
3446: 2883: 1692: 120: 2847:"Chemical studies of elements with Z ≥ 104 in liquid phase" 2639:
Greeley, Jeff; Nørskov, Jens K.; Mavrikakis, Manos (2002).
701: 273: 144: 95: 210:. It is sometimes applied more broadly to any metallic or 2772:
Principles of corrosion engineering and corrosion control
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Electrochemical properties of some metals and metalloids
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Electrical conductive adhesives with nanotechnologies
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Zhang, Junxi; Zhang, Lide; Xu, Wei (March 21, 2012).
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Rhodium: 1 g powder, 1g pressed cylinder, 1 g pellet.
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d = decomposes; ‡ = not a noble metal; = metalloid
3054:Kepp K 2020, "Chemical causes of metal nobleness", 2844: 435:
Pieces of pure iridium, 1 g, size: 1–3 mm each
2569:Gorin, David J.; Toste, F. Dean (March 22, 2007). 534:that occur naturally in relatively large amounts. 272:In addition to this term's function as a compound 27:Metallic elements that are nearly chemically inert 2066:As long ago as 1890, Hiorns observed as follows: 3950: 2961:The chemistry and metallurgy of dental materials 2532:"Relativistic effects and the chemistry of gold" 3181: 2989:The analytical chemistry of the noble metals, 2797:Dental materials: Properties and manipulation 2763: 2607: 2490: 2326: 2079:Smith, writing in 1946, continued the theme: 2886:"Copernicium is a Relativistic Noble Liquid" 2794: 2758:Journal of Physical Chemical Reference Data, 2708: 3070:Indian Journal of Pure and Applied Physics, 2493:"Why gold is the noblest of all the metals" 2405:W. Xing, M. Lee, Geosys. Eng. 20, 216, 2017 77:in a limited sense (Tc, Re, As, Sb, Bi, Po) 3188: 3174: 2568: 2466:Journal of Molecular Catalysis A: Chemical 342:), is the most abundant copper ore mineral 3140:Membrane-based separations in metallurgy, 2978:Noble metals dissolved without aqua regia 2911: 2901: 2657:10.1146/annurev.physchem.53.100301.131630 2429: 2427: 2202: 2819: 2529: 2413: 2411: 2184:Incipient red heat corresponds to 525 °C 492: 31: 3162:Encyclopædia Britannica, online edition 2890:Angewandte Chemie International Edition 2331:. Oxford University. pp. 195–205. 2235: 2207:. Wiley Online Library. pp. 1–36. 2096: 2093:in their most stable oxidation states. 537: 119:§ self-attacked by radiation-generated 47:most often (Ru, Rh, Pd, Os, Ir, Pt, Au) 14: 3951: 2677: 2424: 2269: 2267: 2265: 260: 139:and is usually found in nature in its 3169: 2958: 2769: 2715:Journal of Physics D: Applied Physics 2684:Journal of Physics D: Applied Physics 2408: 2399: 338:, which is copper iron sulfide (CuFeS 280:is used as an adjective for the noun 198:, silver, and gold which have filled 131:is ordinarily regarded as a metallic 2877: 2322: 2320: 2273: 3932: 2824:. New York: Springer. p. 179. 2774:. Amsterdam: Elsevier. p. 40. 2645:Annual Review of Physical Chemistry 2491:Hammer, B.; Norskov, J. K. (1995). 2262: 2238:Springer Handbook of Materials Data 644:surface-enhanced Raman spectroscopy 560:, a highly concentrated mixture of 204:surface-enhanced Raman spectroscopy 24: 3195: 3148:10.1016/B978-0-12-803410-1.00009-8 3091:Biomedical applications of metals, 3044:vol. 26, no. 1, pp. 786–801, 3017:Environmental Health Perspectives, 2970: 2608:Hammer, B.; Nørskov, J.K. (1995). 657: 526:Copper, silver, gold, and the six 25: 3980: 3153: 3072:vol. 23, no. 11, pp. 551–554 2317: 3931: 3920: 3919: 3085:10.1016/B978-044452787-5.00109-8 3058:vol. 21 no. 5. pp. 360−369, 2963:. Oxford: Blackwell. p. 40. 2213:10.1002/9780470027318.a2411.pub3 473: 455: 441: 427: 413: 392: 378: 364: 348: 327: 276:, there are circumstances where 175:) are most often so classified. 3135:Time-Life Books, Alexandria, VA 2952: 2943: 2937:Mixed metals or metallic alloys 2928: 2871:10.1016/j.nuclphysa.2015.07.013 2838: 2820:Li, Y; Lu, D; Wong, CP (2010). 2813: 2795:Powers, JM; Wataha, JE (2013). 2788: 2750: 2741: 2702: 2671: 2632: 2601: 2562: 2523: 2484: 2453: 2444:Challenging aqua regia's throne 2436: 2389:vol. 48, no. 26, pp. 9408-9421 2362:"the definition of noble metal" 2178: 2161: 2152: 135:that is generally resistant to 3250:1 (Hydrogen and alkali metals) 3079:Elsevier, pp. 2205–2223, 2727:10.1088/0022-3727/45/11/113001 2696:10.1088/0022-3727/44/28/283001 2379: 2354: 2345: 2229: 2196: 1519:standard reduction potential; 556:Ruthenium can be dissolved in 514: 13: 1: 3792:Thermal expansion coefficient 3488:Lists of metalloids by source 2998:vol. 44, pp. 5978–5985, 2478:10.1016/S1381-1169(96)00348-2 2276:"Chemical causes of nobility" 2190: 663:Standard reduction potentials 613: 488: 462: 448: 434: 420: 399: 385: 371: 334: 3142:Elsevier, pp. 249–272, 3121:vol. 127, pp. 273–274, 2991:Elsevier Science, Burlington 2626:10.1016/0039-6028(96)80007-0 2246:10.1007/978-3-319-69743-7_14 1543:standard reduction potential 1406:+ 12 e → 4 As + 6  355:One half of a ruthenium bar. 7: 3531:Platinum-group metals (PGM) 3234:By periodic table structure 3099:10.1007/978-3-319-74814-6_1 2421:Longman, London, p. 53, 115 2119: 1477:+ 6 e → 2 Sb + 3  357:Size ~ 40 × 15 × 10 mm 10: 3985: 3676:Goldschmidt classification 648:localized surface plasmons 500:Goldschmidt classification 467:, nearly 9,000 g or 317 oz 3914: 3876: 3809: 3689: 3646: 3607: 3598: 3523: 3501: 3478: 3445: 3435: 3413: 3343: 3255:2 (Alkaline earth metals) 3240: 3233: 3224: 3203: 3019:vol. 10, pp. 39–56, 2059: 1704:Oxide melting points, °C 1698: 1541:The adjacent table lists 1532: 1502: 1335:+ 4 e → Re + 2  1273:+ 4 e → Tc + 2  894:+ 4 e → Os + 2  449:Crystals of pure platinum 304:in conditions of varying 3131:St. John J et al. 1984, 2146: 598:and the organic solvent 3894:systematic element name 3866:in East Asian languages 3216:Extended periodic table 3160:Noble metal – chemistry 3042:Chemistry of Materials, 2530:Bartlett, Neil (1998). 545:Copper is dissolved by 403:, or silver sulfide (Ag 255:heterogeneous catalysts 3737:Electron configuration 3727:Electrical resistivity 3666:Electron configuration 3470:Post-transition metals 3113:10.1002/open.201800257 3064:10.1002/cphc.202000013 3037:vol. 1, pp. 39–56 3008:Brooks RR (ed.) 1992, 2903:10.1002/anie.201906966 2419:The metallic elements, 2295:10.1002/cphc.202000013 511: 421:Osmium crystals, 2.2 g 124: 3959:Chemical nomenclature 3571:Transuranium elements 3107:vol. 8, p. 173, 3012:CRC Press, Boca Raton 528:platinum group metals 519:The noble metals are 506:. Their abundance in 496: 267:platinum group metals 244:platinum group metals 153:platinum group metals 35: 3787:Thermal conductivity 3762:Heat of vaporization 3204:Periodic table forms 3004:10.1002/2017GL074002 2996:Geophys. Res. Lett., 2678:Garcia, M A (2011). 2387:Dalton Transactions, 2103:catalytic converters 2097:Catalytic properties 579:Rhenium reacts with 538:Corrosion resistance 98:solution containing 3819:Element discoveries 3576:Superheavy elements 3536:Rare-earth elements 3077:Shreir's Corrosion, 3029:Du R et al. 2019, " 2896:(50): 17964–17968. 2863:2015NuPhA.944..614N 2587:10.1038/nature05592 1705: 1669:superheavy elements 1523:electronegativity; 671: 261:Meaning and history 3025:10.1289/ehp.751039 2959:Smith, JC (1946). 2548:10.1007/BF03215471 2442:Urquhart J 2010, " 2395:10.1039/C9DT00765B 2075:metal and oxygen." 1703: 669: 642:nanoparticles for 512: 125: 67:sometimes (Cu, Hg) 3946: 3945: 3805: 3804: 3767:Ionization energy 3742:Electronegativity 3732:Electron affinity 3671:Electronegativity 3661:Crystal structure 3656:Aqueous chemistry 3633:Nuclear stability 3628:Atomic properties 3594: 3593: 3541:Refractory metals 3519: 3518: 3465:Transition metals 3431: 3430: 2987:Beamish FE 2012, 2976:Balshaw L 2020, " 2851:Nuclear Physics A 2831:978-0-387-88782-1 2770:Ahmad, Z (2006). 2581:(7134): 395–403. 2503:(6537): 238–240. 2274:Kepp, KP (2020). 2255:978-3-319-69741-3 2064: 2063: 1675:(element 108) to 1550:Pourbaix diagrams 1539: 1538: 1535: 1528: 1527:electron affinity 585:hydrogen peroxide 562:hydrochloric acid 551:potassium cyanide 463:Gold nugget from 16:(Redirected from 3976: 3935: 3934: 3923: 3922: 3906:Dmitri Mendeleev 3834:1869 predictions 3824:Dmitri Mendeleev 3605: 3604: 3443: 3442: 3423:Aufbau principle 3335:18 (Noble gases) 3238: 3237: 3231: 3230: 3226:Sets of elements 3190: 3183: 3176: 3167: 3166: 3127:10.1038/127273b0 3050:10.1021/cm402221 2982:Chemistry World, 2965: 2964: 2956: 2950: 2947: 2941: 2934:Hiorns AH 1890, 2932: 2926: 2925: 2915: 2905: 2881: 2875: 2874: 2842: 2836: 2835: 2817: 2811: 2810: 2792: 2786: 2785: 2767: 2761: 2754: 2748: 2745: 2739: 2738: 2706: 2700: 2699: 2675: 2669: 2668: 2636: 2630: 2629: 2605: 2599: 2598: 2566: 2560: 2559: 2527: 2521: 2520: 2509:10.1038/376238a0 2488: 2482: 2481: 2457: 2451: 2448:Chemistry World, 2440: 2434: 2431: 2422: 2417:Parish RV 1977, 2415: 2406: 2403: 2397: 2383: 2377: 2376: 2374: 2372: 2358: 2352: 2349: 2343: 2342: 2338:978-0-190-668532 2324: 2315: 2314: 2280: 2271: 2260: 2259: 2233: 2227: 2226: 2200: 2185: 2182: 2176: 2165: 2159: 2156: 1706: 1702: 1662: 1661: 1660: 1650: 1648: 1647: 1637: 1636: 1635: 1625: 1623: 1622: 1585: 1583: 1582: 1579: 1576: 1560:hydrogen sulfide 1533: 1503: 1489: 1487: 1486: 1476: 1475: 1474: 1465: 1464: 1463: 1455: 1454: 1418: 1416: 1415: 1405: 1404: 1403: 1394: 1393: 1392: 1384: 1383: 1347: 1345: 1344: 1334: 1333: 1332: 1323: 1322: 1321: 1285: 1283: 1282: 1272: 1271: 1270: 1261: 1260: 1259: 1221: 1220: 1219: 1183: 1182: 1181: 1147: 1146: 1145: 1135: 1133: 1132: 1099: 1098: 1097: 1060: 1059: 1058: 1021: 1020: 1019: 982: 981: 980: 943: 942: 941: 906: 904: 903: 893: 892: 891: 882: 881: 880: 842: 841: 840: 804:+ 3 e → Ir 803: 802: 801: 764: 763: 762: 725: 724: 723: 672: 668: 592:thionyl chloride 477: 459: 445: 431: 417: 396: 382: 368: 352: 331: 242:, gold, the six 206:involving metal 151:, and the other 123: 116: 114:hydrogen sulfide 90:in moist air or 78: 76: 68: 66: 58: 56: 48: 46: 21: 3984: 3983: 3979: 3978: 3977: 3975: 3974: 3973: 3949: 3948: 3947: 3942: 3910: 3872: 3801: 3777:Oxidation state 3685: 3642: 3590: 3586:Minor actinides 3581:Major actinides 3546:Precious metals 3515: 3497: 3474: 3427: 3409: 3339: 3325:16 (Chalcogens) 3320:15 (Pnictogens) 3220: 3199: 3194: 3156: 2973: 2971:Further reading 2968: 2957: 2953: 2948: 2944: 2933: 2929: 2882: 2878: 2843: 2839: 2832: 2818: 2814: 2807: 2793: 2789: 2782: 2768: 2764: 2755: 2751: 2746: 2742: 2707: 2703: 2676: 2672: 2637: 2633: 2614:Surface Science 2606: 2602: 2567: 2563: 2528: 2524: 2489: 2485: 2458: 2454: 2441: 2437: 2432: 2425: 2416: 2409: 2404: 2400: 2384: 2380: 2370: 2368: 2360: 2359: 2355: 2350: 2346: 2339: 2325: 2318: 2278: 2272: 2263: 2256: 2234: 2230: 2223: 2201: 2197: 2193: 2188: 2183: 2179: 2174: 2170: 2166: 2162: 2157: 2153: 2149: 2126:Galvanic series 2122: 2114:water gas shift 2099: 1701: 1659: 1656: 1655: 1654: 1652: 1646: 1643: 1642: 1641: 1639: 1634: 1631: 1630: 1629: 1627: 1621: 1618: 1617: 1616: 1614: 1597: 1593: 1589: 1580: 1577: 1574: 1573: 1571: 1569: 1507:atomic number; 1485: 1482: 1481: 1480: 1478: 1473: 1471: 1470: 1469: 1467: 1462: 1459: 1458: 1457: 1453: 1450: 1449: 1448: 1446: 1414: 1411: 1410: 1409: 1407: 1402: 1400: 1399: 1398: 1396: 1391: 1388: 1387: 1386: 1382: 1379: 1378: 1377: 1375: 1343: 1340: 1339: 1338: 1336: 1331: 1329: 1328: 1327: 1325: 1320: 1317: 1316: 1315: 1313: 1281: 1278: 1277: 1276: 1274: 1269: 1267: 1266: 1265: 1263: 1258: 1255: 1254: 1253: 1251: 1222:+ 3 e → Bi 1218: 1216: 1215: 1214: 1212: 1184:+ 2 e → Cu 1180: 1178: 1177: 1176: 1174: 1144: 1141: 1140: 1139: 1137: 1131: 1128: 1127: 1126: 1124: 1100:+ 2 e → Po 1096: 1094: 1093: 1092: 1090: 1061:+ 3 e → Ru 1057: 1055: 1054: 1053: 1051: 1018: 1016: 1015: 1014: 1012: 983:+ 3 e → Rh 979: 977: 976: 975: 973: 944:+ 2 e → Hg 940: 938: 937: 936: 934: 902: 899: 898: 897: 895: 890: 888: 887: 886: 884: 879: 876: 875: 874: 872: 843:+ 2 e → Pd 839: 837: 836: 835: 833: 800: 798: 797: 796: 794: 765:+ 2 e → Pt 761: 759: 758: 757: 755: 726:+ 3 e → Au 722: 720: 719: 718: 716: 660: 658:Electrochemical 630:The low-energy 616: 609: 605: 597: 581:oxidizing acids 574:silver chloride 540: 517: 491: 484: 478: 469: 468: 460: 451: 450: 446: 437: 436: 432: 423: 422: 418: 409: 408: 406: 397: 388: 387: 383: 374: 373: 369: 360: 358: 356: 353: 344: 343: 341: 332: 302:stainless steel 286:galvanic series 263: 246:, and silver. 118: 117: 107: 106: 70: 69: 60: 59: 50: 49: 40: 39: 28: 23: 22: 15: 12: 11: 5: 3982: 3972: 3971: 3966: 3961: 3944: 3943: 3941: 3940: 3928: 3915: 3912: 3911: 3909: 3908: 3903: 3898: 3897: 3896: 3891: 3880: 3878: 3874: 3873: 3871: 3870: 3869: 3868: 3863: 3858: 3853: 3848: 3838: 3837: 3836: 3831: 3826: 3815: 3813: 3807: 3806: 3803: 3802: 3800: 3799: 3797:Vapor pressure 3794: 3789: 3784: 3782:Speed of sound 3779: 3774: 3769: 3764: 3759: 3757:Heat of fusion 3754: 3749: 3744: 3739: 3734: 3729: 3724: 3719: 3714: 3712:Critical point 3709: 3704: 3699: 3693: 3691: 3687: 3686: 3684: 3683: 3678: 3673: 3668: 3663: 3658: 3652: 3650: 3644: 3643: 3641: 3640: 3635: 3630: 3625: 3613: 3611: 3602: 3596: 3595: 3592: 3591: 3589: 3588: 3583: 3578: 3573: 3568: 3563: 3558: 3553: 3551:Coinage metals 3548: 3543: 3538: 3533: 3527: 3525: 3521: 3520: 3517: 3516: 3514: 3513: 3507: 3505: 3499: 3498: 3496: 3495: 3490: 3484: 3482: 3476: 3475: 3473: 3472: 3467: 3462: 3457: 3451: 3449: 3440: 3433: 3432: 3429: 3428: 3426: 3425: 3419: 3417: 3411: 3410: 3408: 3407: 3406: 3405: 3400: 3395: 3385: 3380: 3375: 3370: 3365: 3360: 3355: 3349: 3347: 3341: 3340: 3338: 3337: 3332: 3327: 3322: 3317: 3312: 3307: 3302: 3297: 3292: 3287: 3282: 3277: 3272: 3267: 3262: 3257: 3252: 3246: 3244: 3235: 3228: 3222: 3221: 3219: 3218: 3213: 3207: 3205: 3201: 3200: 3197:Periodic table 3193: 3192: 3185: 3178: 3170: 3164: 3163: 3155: 3154:External links 3152: 3151: 3150: 3136: 3129: 3115: 3105:ChemistryOpen, 3101: 3087: 3073: 3066: 3052: 3038: 3027: 3013: 3006: 2992: 2985: 2972: 2969: 2967: 2966: 2951: 2942: 2927: 2876: 2837: 2830: 2812: 2805: 2787: 2780: 2762: 2749: 2740: 2721:(11): 113001. 2701: 2690:(28): 283001. 2670: 2651:(1): 319–348. 2631: 2620:(3): 211–220. 2600: 2561: 2522: 2483: 2472:(3): 421–429. 2452: 2435: 2423: 2407: 2398: 2378: 2366:Dictionary.com 2353: 2344: 2337: 2316: 2289:(5): 360–369. 2261: 2254: 2228: 2221: 2194: 2192: 2189: 2187: 2186: 2177: 2172: 2168: 2160: 2150: 2148: 2145: 2144: 2143: 2141:Precious metal 2138: 2133: 2128: 2121: 2118: 2098: 2095: 2090: 2089: 2085: 2084: 2077: 2076: 2062: 2061: 2057: 2056: 2054: 2052: 2050: 2048: 2045: 2043: 2041: 2037: 2036: 2034: 2032: 2030: 2028: 2025: 2023: 2021: 2017: 2016: 2014: 2012: 2010: 2008: 2005: 2003: 2001: 1997: 1996: 1994: 1992: 1989: 1987: 1985: 1983: 1981: 1977: 1976: 1974: 1972: 1970: 1968: 1966: 1963: 1961: 1957: 1956: 1954: 1952: 1950: 1948: 1946: 1943: 1941: 1937: 1936: 1934: 1932: 1930: 1928: 1925: 1923: 1921: 1917: 1916: 1914: 1912: 1910: 1907: 1905: 1903: 1901: 1897: 1896: 1894: 1892: 1890: 1887: 1885: 1883: 1881: 1877: 1876: 1873: 1871: 1869: 1866: 1864: 1862: 1860: 1856: 1855: 1853: 1850: 1847: 1844: 1842: 1840: 1838: 1834: 1833: 1831: 1829: 1827: 1825: 1823: 1820: 1817: 1813: 1812: 1810: 1808: 1806: 1804: 1802: 1799: 1797: 1793: 1792: 1790: 1788: 1785: 1782: 1780: 1778: 1774: 1773: 1770: 1768: 1766: 1763: 1761: 1759: 1757: 1753: 1752: 1750: 1748: 1746: 1744: 1742: 1739: 1736: 1732: 1731: 1728: 1725: 1722: 1719: 1716: 1713: 1710: 1700: 1697: 1665: 1664: 1657: 1644: 1632: 1619: 1600: 1599: 1595: 1591: 1587: 1567: 1537: 1536: 1530: 1529: 1500: 1499: 1496: 1493: 1490: 1483: 1472: 1460: 1451: 1444: 1441: 1438: 1435: 1429: 1428: 1425: 1422: 1419: 1412: 1401: 1389: 1380: 1373: 1370: 1367: 1364: 1358: 1357: 1354: 1351: 1348: 1341: 1330: 1318: 1311: 1308: 1305: 1302: 1296: 1295: 1292: 1289: 1286: 1279: 1268: 1256: 1249: 1246: 1243: 1240: 1233: 1232: 1229: 1226: 1223: 1217: 1210: 1207: 1204: 1201: 1195: 1194: 1191: 1188: 1185: 1179: 1172: 1169: 1166: 1163: 1157: 1156: 1154: 1152: 1149: 1142: 1129: 1121: 1119: 1117: 1115: 1111: 1110: 1107: 1104: 1101: 1095: 1088: 1085: 1082: 1079: 1072: 1071: 1068: 1065: 1062: 1056: 1049: 1046: 1043: 1040: 1033: 1032: 1029: 1026: 1023: 1017: 1010: 1007: 1004: 1001: 994: 993: 990: 987: 984: 978: 971: 968: 965: 962: 955: 954: 951: 948: 945: 939: 932: 929: 926: 923: 917: 916: 913: 910: 907: 900: 889: 877: 870: 867: 864: 861: 854: 853: 850: 847: 844: 838: 831: 828: 825: 822: 815: 814: 811: 808: 805: 799: 792: 789: 786: 783: 776: 775: 772: 769: 766: 760: 753: 750: 747: 744: 737: 736: 733: 730: 727: 721: 714: 711: 708: 705: 698: 697: 694: 691: 688: 685: 682: 679: 676: 659: 656: 615: 612: 607: 603: 595: 539: 536: 516: 513: 490: 487: 486: 485: 479: 472: 470: 461: 454: 452: 447: 440: 438: 433: 426: 424: 419: 412: 410: 404: 398: 391: 389: 384: 377: 375: 370: 363: 361: 354: 347: 345: 339: 333: 326: 262: 259: 108:† attacked by 85: 79: 38: 36: 26: 9: 6: 4: 3: 2: 3981: 3970: 3967: 3965: 3962: 3960: 3957: 3956: 3954: 3939: 3938: 3929: 3927: 3926: 3917: 3916: 3913: 3907: 3904: 3902: 3899: 3895: 3892: 3890: 3887: 3886: 3885: 3882: 3881: 3879: 3875: 3867: 3864: 3862: 3859: 3857: 3854: 3852: 3851:controversies 3849: 3847: 3844: 3843: 3842: 3839: 3835: 3832: 3830: 3827: 3825: 3822: 3821: 3820: 3817: 3816: 3814: 3812: 3808: 3798: 3795: 3793: 3790: 3788: 3785: 3783: 3780: 3778: 3775: 3773: 3772:Melting point 3770: 3768: 3765: 3763: 3760: 3758: 3755: 3753: 3752:Heat capacity 3750: 3748: 3745: 3743: 3740: 3738: 3735: 3733: 3730: 3728: 3725: 3723: 3720: 3718: 3715: 3713: 3710: 3708: 3707:Boiling point 3705: 3703: 3702:Atomic radius 3700: 3698: 3695: 3694: 3692: 3688: 3682: 3679: 3677: 3674: 3672: 3669: 3667: 3664: 3662: 3659: 3657: 3654: 3653: 3651: 3649: 3645: 3639: 3636: 3634: 3631: 3629: 3626: 3623: 3619: 3615: 3614: 3612: 3610: 3606: 3603: 3601: 3597: 3587: 3584: 3582: 3579: 3577: 3574: 3572: 3569: 3567: 3566:Native metals 3564: 3562: 3559: 3557: 3554: 3552: 3549: 3547: 3544: 3542: 3539: 3537: 3534: 3532: 3529: 3528: 3526: 3522: 3512: 3509: 3508: 3506: 3504: 3500: 3494: 3493:Dividing line 3491: 3489: 3486: 3485: 3483: 3481: 3477: 3471: 3468: 3466: 3463: 3461: 3458: 3456: 3453: 3452: 3450: 3448: 3444: 3441: 3439: 3434: 3424: 3421: 3420: 3418: 3416: 3412: 3404: 3401: 3399: 3396: 3394: 3391: 3390: 3389: 3386: 3384: 3381: 3379: 3376: 3374: 3371: 3369: 3366: 3364: 3361: 3359: 3356: 3354: 3351: 3350: 3348: 3346: 3342: 3336: 3333: 3331: 3330:17 (Halogens) 3328: 3326: 3323: 3321: 3318: 3316: 3313: 3311: 3308: 3306: 3303: 3301: 3298: 3296: 3293: 3291: 3288: 3286: 3283: 3281: 3278: 3276: 3273: 3271: 3268: 3266: 3263: 3261: 3258: 3256: 3253: 3251: 3248: 3247: 3245: 3243: 3239: 3236: 3232: 3229: 3227: 3223: 3217: 3214: 3212: 3209: 3208: 3206: 3202: 3198: 3191: 3186: 3184: 3179: 3177: 3172: 3171: 3168: 3161: 3158: 3157: 3149: 3145: 3141: 3137: 3134: 3133:Noble metals, 3130: 3128: 3124: 3120: 3116: 3114: 3110: 3106: 3102: 3100: 3096: 3092: 3088: 3086: 3082: 3078: 3074: 3071: 3067: 3065: 3061: 3057: 3056:ChemPhysChem, 3053: 3051: 3047: 3043: 3039: 3036: 3032: 3028: 3026: 3022: 3018: 3014: 3011: 3007: 3005: 3001: 2997: 2993: 2990: 2986: 2983: 2979: 2975: 2974: 2962: 2955: 2946: 2939: 2938: 2931: 2923: 2919: 2914: 2909: 2904: 2899: 2895: 2891: 2887: 2880: 2872: 2868: 2864: 2860: 2856: 2852: 2848: 2841: 2833: 2827: 2823: 2816: 2808: 2806:9780323291507 2802: 2798: 2791: 2783: 2781:9780080480336 2777: 2773: 2766: 2759: 2753: 2744: 2736: 2732: 2728: 2724: 2720: 2716: 2712: 2705: 2697: 2693: 2689: 2685: 2681: 2674: 2666: 2662: 2658: 2654: 2650: 2646: 2642: 2635: 2627: 2623: 2619: 2615: 2611: 2604: 2596: 2592: 2588: 2584: 2580: 2576: 2572: 2565: 2557: 2553: 2549: 2545: 2541: 2537: 2536:Gold Bulletin 2533: 2526: 2518: 2514: 2510: 2506: 2502: 2498: 2494: 2487: 2479: 2475: 2471: 2467: 2463: 2456: 2449: 2445: 2439: 2430: 2428: 2420: 2414: 2412: 2402: 2396: 2392: 2388: 2382: 2367: 2363: 2357: 2348: 2340: 2334: 2330: 2323: 2321: 2312: 2308: 2304: 2300: 2296: 2292: 2288: 2284: 2277: 2270: 2268: 2266: 2257: 2251: 2247: 2243: 2239: 2232: 2224: 2222:9780471976707 2218: 2214: 2210: 2206: 2199: 2195: 2181: 2164: 2155: 2151: 2142: 2139: 2137: 2134: 2132: 2129: 2127: 2124: 2123: 2117: 2115: 2111: 2110:hydrogenation 2106: 2104: 2094: 2087: 2086: 2082: 2081: 2080: 2073: 2072:Noble Metals. 2069: 2068: 2067: 2058: 2055: 2053: 2051: 2049: 2046: 2044: 2042: 2039: 2038: 2035: 2033: 2031: 2029: 2026: 2024: 2022: 2019: 2018: 2015: 2013: 2011: 2009: 2006: 2004: 2002: 1999: 1998: 1995: 1993: 1990: 1988: 1986: 1984: 1982: 1979: 1978: 1975: 1973: 1971: 1969: 1967: 1964: 1962: 1959: 1958: 1955: 1953: 1951: 1949: 1947: 1944: 1942: 1939: 1938: 1935: 1933: 1931: 1929: 1926: 1924: 1922: 1919: 1918: 1915: 1913: 1911: 1908: 1906: 1904: 1902: 1899: 1898: 1895: 1893: 1891: 1888: 1886: 1884: 1882: 1879: 1878: 1874: 1872: 1870: 1867: 1865: 1863: 1861: 1858: 1857: 1854: 1851: 1848: 1845: 1843: 1841: 1839: 1836: 1835: 1832: 1830: 1828: 1826: 1824: 1821: 1818: 1815: 1814: 1811: 1809: 1807: 1805: 1803: 1800: 1798: 1795: 1794: 1791: 1789: 1786: 1783: 1781: 1779: 1776: 1775: 1771: 1769: 1767: 1764: 1762: 1760: 1758: 1755: 1754: 1751: 1749: 1747: 1745: 1743: 1740: 1737: 1734: 1733: 1729: 1726: 1723: 1720: 1717: 1714: 1711: 1708: 1707: 1696: 1694: 1690: 1686: 1682: 1678: 1674: 1670: 1651:− 4 e − 1612: 1611: 1610: 1607: 1605: 1565: 1564: 1563: 1561: 1556: 1553: 1551: 1546: 1544: 1531: 1526: 1522: 1518: 1514: 1510: 1506: 1501: 1497: 1494: 1491: 1445: 1442: 1439: 1436: 1434: 1431: 1430: 1426: 1423: 1420: 1374: 1371: 1368: 1365: 1363: 1360: 1359: 1355: 1352: 1349: 1312: 1309: 1306: 1303: 1301: 1298: 1297: 1293: 1290: 1287: 1250: 1247: 1244: 1241: 1238: 1235: 1234: 1230: 1227: 1224: 1211: 1208: 1205: 1202: 1200: 1197: 1196: 1192: 1189: 1186: 1173: 1170: 1167: 1164: 1162: 1159: 1158: 1155: 1153: 1150: 1122: 1120: 1118: 1116: 1113: 1112: 1108: 1105: 1102: 1089: 1086: 1083: 1080: 1077: 1074: 1073: 1069: 1066: 1063: 1050: 1047: 1044: 1041: 1038: 1035: 1034: 1030: 1027: 1024: 1011: 1008: 1005: 1002: 999: 996: 995: 991: 988: 985: 972: 969: 966: 963: 960: 957: 956: 952: 949: 946: 933: 930: 927: 924: 922: 919: 918: 914: 911: 908: 871: 868: 865: 862: 859: 856: 855: 851: 848: 845: 832: 829: 826: 823: 820: 817: 816: 812: 809: 806: 793: 790: 787: 784: 781: 778: 777: 773: 770: 767: 754: 751: 748: 745: 742: 739: 738: 734: 731: 728: 715: 712: 709: 706: 703: 700: 699: 695: 692: 689: 686: 683: 680: 677: 674: 673: 667: 664: 655: 654:properties. 653: 649: 645: 641: 637: 633: 628: 626: 620: 611: 601: 593: 588: 586: 582: 577: 576:precipitate. 575: 571: 567: 563: 559: 554: 552: 548: 543: 535: 533: 532:native metals 530:are the only 529: 524: 522: 509: 505: 501: 495: 482: 476: 471: 466: 458: 453: 444: 439: 430: 425: 416: 411: 402: 395: 390: 381: 376: 367: 362: 351: 346: 337: 330: 325: 324: 323: 321: 316: 314: 309: 307: 303: 299: 295: 291: 287: 283: 279: 275: 270: 268: 258: 256: 252: 247: 245: 241: 237: 233: 229: 225: 221: 217: 213: 209: 208:nanoparticles 205: 201: 197: 192: 190: 186: 182: 178: 174: 170: 166: 162: 158: 154: 150: 146: 142: 138: 134: 130: 122: 115: 111: 105: 101: 97: 93: 89: 83: 74: 64: 54: 44: 34: 30: 19: 3969:Noble metals 3930: 3918: 3901:Trivial name 3889:nomenclature 3561:Heavy metals 3556:Noble metals 3555: 3315:14 (Tetrels) 3211:Alternatives 3139: 3132: 3118: 3104: 3090: 3076: 3069: 3055: 3041: 3034: 3016: 3009: 2995: 2988: 2981: 2960: 2954: 2945: 2935: 2930: 2893: 2889: 2879: 2854: 2850: 2840: 2821: 2815: 2796: 2790: 2771: 2765: 2757: 2752: 2743: 2718: 2714: 2704: 2687: 2683: 2673: 2648: 2644: 2634: 2617: 2613: 2603: 2578: 2574: 2564: 2542:(1): 22–25. 2539: 2535: 2525: 2500: 2496: 2486: 2469: 2465: 2455: 2450:24 September 2447: 2438: 2418: 2401: 2386: 2381: 2369:. 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Index

Noble metals

reactivity
tarnished
corrode
acidic
oxygen
oxidant
sulfur
hydrogen sulfide
ozone
element
corrosion
raw form
Gold
platinum
platinum group metals
ruthenium
rhodium
palladium
osmium
iridium
Silver
copper
mercury
sulfur
copper
d-bands
surface-enhanced Raman spectroscopy
nanoparticles

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