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Lithium–sulfur battery

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1373:(6≤x≤8) is highly soluble in the common electrolytes used for Li–S batteries. They are formed and leaked from the cathode and they diffuse to the anode, where they are reduced to short-chain polysulfides and diffuse back to the cathode where long-chain polysulfides are formed again. This process results in the continuous leakage of active material from the cathode, lithium corrosion, low coulombic efficiency and low battery life. Moreover, the "shuttle" effect is responsible for the characteristic self-discharge of Li–S batteries, because of slow dissolution of polysulfide, which occurs also in rest state. The "shuttle" effect in a Li–S battery can be quantified by a factor f 2284:(HAPS) aircraft powered by solar energy during the day and by lithium sulfur batteries at night in real life conditions during an 11-day flight. The batteries used in the test flight utilized Sion Power's Li–S cells that provide 350 W⋅h/kg. Sion originally claimed to be in the process of volume manufacturing with availability by end of 2017; however more recently it can be seen that they have dropped work on their lithium sulfur battery in favor of a lithium-metal battery. 1293:°C. A carbon coating provides the missing electroconductivity. Carbon nanofibers provide an effective electron conduction path and structural integrity, at the disadvantage of higher cost. In 2024, researchers announced the discovery of a sulfur–iodine material that can dramatically increase the electrical conductivity of a lithium–sulfur battery’s cathode by 11 orders of magnitude, making it 100 billion times more conductive than crystals made of sulfur alone. 2365: 27: 2764: 2745: 2783: 2324:
Monash University's Department of Mechanical and Aerospace Engineering in Melbourne, Australia developed an ultra-high capacity Li–S battery that has been manufactured by partners at the Fraunhofer Institute for Material and Beam Technology in Germany. It is claimed the battery can provide power to
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Conventionally, Li–S batteries employ a liquid organic electrolyte, contained in the pores of PP separator. The electrolyte plays a key role in Li–S batteries, acting both on "shuttle" effect by the polysulfide dissolution and the SEI stabilization at anode surface. It has been demonstrated that the
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The main challenges of Li–S batteries is the low conductivity of sulfur and its considerable volume change upon discharging and finding a suitable cathode is the first step for commercialization of Li–S batteries. Therefore, most researchers use a carbon/sulfur cathode and a lithium anode. Sulfur is
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announced the discovery of a novel sulfur–iodine crystalline material that can drastically increase the electrical conductivity of a lithium–sulfur battery’s cathode by 11 orders of magnitude, making it 100 billion times more conductive than crystals made of sulfur alone. Moreover, the new material
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Issues that have slowed acceptance include the polysulfide "shuttle" effect that is responsible for the progressive leakage of active material from the cathode, resulting in too few recharge cycles. Also, sulfur cathodes have low conductivity, requiring extra mass for a conducting agent in order to
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in 2024. Their polysulfide shuttle free feature facilitates proper operation under lean electrolyte conditions (< 3 g·(A·h)), which was proved to be extremely crucial to attain the full potential of Li-S batteries. The researchers proposed and analyzed unconventional perspectives on how to
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produced a prototype lithium-sulfur battery that did not degrade over 4000 charge cycles. Analysis has shown that the battery contained monoclinic gamma-phase sulfur, which has been thought to be unstable below 95 degrees Celsius, and only a few studies have shown this type of sulfur to be stable
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identified the critical parameters needed for achieving commercial acceptance. Specifically, Li–S batteries need to achieve a sulfur loading of >5 mg·cm, a carbon content of <5%, electrolyte-to-sulfur ratio of <5 μL·mg, electrolyte-to-capacity ratio of <5 μL·(mA·h), and
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S conversion and the large amount of electrolyte needed are also issues. In the early 2000s, however, scientists began to make progress creating high-stability sulfurized-carbon cathodes and by 2020, scientists at Rice University had demonstrated batteries based on sulfurized carbon cathodes that
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Tao, Xinyong; Liu, Yayuan; Liu, Wei; Zhou, Guangmin; Zhao, Jie; Lin, Dingchang; Zu, Chenxi; Sheng, Ouwei; Zhang, Wenkui; Lee, Hyun-Wook; Cui, Yi (10 May 2017). "Solid-State Lithium–Sulfur Batteries Operated at 37 °C with Composites of Nanostructured Li 7 La 3 Zr 2 O 12 /Carbon Foam and Polymer".
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into electrolytes causes irreversible loss of active sulfur. Use of highly reactive lithium as a negative electrode causes dissociation of most of the commonly used other type electrolytes. Use of a protective layer in the anode surface has been studied to improve cell safety, i.e., using
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S is nearly 80% of the volume of the original sulfur. This causes large mechanical stresses on the cathode, which is a major cause of rapid degradation. This process reduces the contact between the carbon and the sulfur, and prevents the flow of lithium ions to the carbon surface.
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Yim, Taeeun; Park, Min-Sik; Yu, Ji-Sang; Kim, Ki Jae; Im, Keun Yung; Kim, Jae-Hun; Jeong, Goojin; Jo, Yong Nam; Woo, Sang-Gil (September 2013). "Effect of chemical reactivity of polysulfide toward carbonate-based electrolyte on the electrochemical performance of Li–S batteries".
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Voltage between about 1.7 and 2.5 volts, depending on charge state. Lithium bis(trifluoromethanesulfonyl)imide) dissolved in a mixture of nmethyl-(n-butyl) pyrrolidinium bis(trifluoromethanesulfonyl)-imide (PYR14TFSI), 1,3-dioxolane (DOL), dimethoxyethane (DME) with 1 M
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A free-standing CNT–S paper electrode with a high areal sulfur-loading was fabricated, in which short MWCNTs served as the short-range electrical conductive network and super-long CNTs acted as both the long-range conductive network and intercrossed binders.
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Mechanical properties of the lithiated sulfur compounds are strongly contingent on the lithium content, and with increasing lithium content, the strength of lithiated sulfur compounds improves, although this increment is not linear with lithiation.
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In 2021, researchers announced the use of a sugar-based anode additive that prevented the release of polysulfide chains from the cathodes that pollute the anode. A prototype cell demonstrated 1,000 charge cycles with a capacity of 700 mAh/g.
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in the anode and cathodes. Each sulfur atom can host two lithium ions. Typically, lithium-ion batteries accommodate only 0.5–0.7 lithium ions per host atom. Consequently, Li–S allows for a much higher lithium storage density. Polysulfides are
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In 2022, an interlayer was introduced that claimed to reduce polysulfide movement (protecting the anode) and facilitate lithium ion transfer to reduce charge/discharge times. Also that year, researchers employed aramid nanofibers (nanoscale
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Nguyen, D.-T.; Hoefling, A.; Yee, M.; Nguyen, T. H. G.; Theato, P.; Lee, Y. J.; Song, S.-W. (2019). "Enabling high-rate and safe lithium ion-sulfur battery by effective combination of sulfur-copolymer cathode and hard-carbon anode".
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Li–S batteries with up to 1,500 charge and discharge cycles were demonstrated in 2017, but cycle life tests at commercial scale and with lean electrolyte have not been completed. As of early 2021, none were commercially available.
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Chung, W. J.; Griebel, J. J.; Kim, E. T.; Yoon, H.; Simmonds, A. G.; Ji, H. J.; Dirlam, P. T.; Glass, R. S.; Wie, J. J.; Nguyen, N. A.; Guralnick, B. W.; Park, J.; Somogyi, Á. D.; Theato, P.; MacKay, M. E.; Sung, Y. E.; Char, K.;
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and mixtures of them) are not compatible with the chemistry of Li–S batteries. Long-chain polysulfides undergo nucleophilic attack on electrophilic sites of carbonates, resulting in the irreversible formation of by-products as
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fibers), fashioned into cell membrane-like networks. This prevented dendrite formation. It addressed polysulfide shuttle by using ion selectivity, by integrating tiny channels into the network and adding an electrical charge.
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In 2017: "can be cycled approximately 1500 times ... In the next 2 years, we expect this to reach 2500 cycles". In 2021: "Within the next two years we aim to double the current cycle life to achieve upwards of 500
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Jeong, S. S.; Lim, Y.; Choi, Y. T.; Kim, K. W.; Ahn, H. J.; Cho, K. K. (2006). "Electrochemical properties of lithium sulfur cells using PEO polymer electrolytes prepared under three different mixing conditions".
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Li–S batteries were invented in the 1960s, when Herbert and Ulam patented a primary battery employing lithium or lithium alloys as anodic material, sulfur as cathodic material and an electrolyte composed of
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kg and was said to be fully scalable. They claimed their Lithium-Sulfur batteries would cost about $ 200/kWh in mass production. However, the firm entered bankruptcy (insolvency) status in May 2021.
988: 2762:, Nole, Dominick A. & Moss, Vladimir, "Battery employing lithium – sulphur electrodes with non-aqueous electrolyte", issued 1970-10-06, assigned to Aerojet Rocketdyne Inc 388:
In analogy with lithium batteries, the dissolution / electrodeposition reaction causes over time problems of unstable growth of the solid-electrolyte interface (SEI), generating active sites for the
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a Texas-based startup announced that multiple national laboratories had independently verified that its lithium-sulfur batteries based on sulfurized-carbon cathodes were polysulfide shuttle free.
1656:, which leads to the shuttle effect and results in capacity loss over time. The operating temperature and cycling rate also play significant roles in determining the lifespan of Li-S batteries. 633: 2676: 383: 176:
The competitive advantages of sulfurized-carbon cathodes (e.g., sulfurized polyacrylonitrile, also known as SPAN) were highlighted by a quantitative analysis performed by researchers at
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Choi, Y. J.; Chung, Y. D.; Baek, C. Y.; Kim, K. W.; Ahn, J. H. (March 4, 2008). "Effects of carbon coating on the electrochemical properties of sulfur cathode for lithium/sulfur cell".
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Solid lithium polysulfidophosphate electrolyte. Half the voltage of typical LIBs. Remaining issues include low electrolyte ionic conductivity and brittleness in the ceramic structure.
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Jo, Seong-Chan; Hong, Jeong-Won; Choi, Ik-Hyeon; Kim, Min-Ju; Kim, Byung Gon; Lee, You-Jin; Choi, Hye Young; Kim, Doohun; Kim, TaeYoung; Baeg, Kang-Jun; Park, Jun-Woo (May 2022).
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Wang, Peiyu; Kateris, Nikolaos; Li, Baiheng; Zhang, Yiwen; Luo, Jianmin; Wang, Chuanlong; Zhang, Yue; Jayaraman, Amitesh S.; Hu, Xiaofei; Wang, Hai; Li, Weiyang (2023-08-17).
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Yu, Linghui; Ong, Samuel (2021). "The importance of the dissolution of polysulfides in lithium-sulfur batteries and a perspective on high-energy electrolyte/cathode design".
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Diao, Yan; Xie, Kai; Xiong, Shizhao; Hong, Xiaobin (August 2013). "Shuttle phenomenon – The irreversible oxidation mechanism of sulfur active material in Li–S battery".
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surface, dissolution of the metallic lithium occurs, with the production of electrons and lithium ions during the discharge and electrodeposition during the charge. The
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Minimal degradation during charge cycling. To retain polysulfides in the cathode, the surface was functionalized to repel (hydrophobic) polysulfides. In a test using a
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An efficient and straightforward approach to prepare a covalently sulfurized graphene cathode for Li–S batteries with high sulfur content and high cycling stability.
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Islam, Md Mahbubul; Ostadhossein, Alireza; Borodin, Oleg; Yeates, A. Todd; Tipton, William W.; Hennig, Richard G.; Kumar, Nitin; Duin, Adri C. T. van (2015-01-21).
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and dendritic growth of lithium. Dendritic growth is responsible for the internal short circuit in lithium batteries and leads to the death of the battery itself.
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models for its cells. With Lithium Balance of Denmark they built a prototype scooter battery system primarily for the Chinese market, which had a capacity of 1.2
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further improve both energy density and cycle life, highlighting the importance of a proper electrolyte (i.e., stable, lightweight, and highly Li-conductive).
3576:"ReaxFF Reactive Force Field Simulations on the Influence of Teflon on Electrolyte Decomposition during Li/SWCNT Anode Discharge in Lithium-Sulfur Batteries" 2743:, Danuta, Herbert & Juliusz, Ulam, "Electric dry cells and storage batteries", issued 1962-07-10, assigned to Electric Tech Corp 5170: 4514: 4453: 3575: 4784: 5146:"Lithium Sulfur batteries will be first commercialized by 2018 in electric bikes where energy density will be improved for eventual use in electric cars" 5328: 5028: 5006: 4840:
Tantis, Iosif; Bakandritsos, Aristides; Zaoralová, Dagmar; Medveď, Miroslav; Jakubec, Petr; Havláková, Jana; Zbořil, Radek; Otyepka, Michal (2021).
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Song, Min-Kyu; Cairns, Elton J.; Zhang, Yuegang (2013). "Lithium/sulfur batteries with high specific energy: old challenges and new opportunities".
4661:"Li–S battery company OXIS Energy reports 300 W⋅h/kg and 25 A⋅h cell, predicting 33 A⋅h by mid-2015, 500 W⋅h/kg by end of 2018" 1393: 4385: 5351: 5202: 3981: 2276:
As of 2021 few companies had been able to commercialize the technology on an industrial scale. Companies such as Sion Power have partnered with
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are respectively the kinetic constant, specific capacity contributing to the anodic plateau, the total sulfur concentration and charge current.
4302: 3075: 2781:, Mlarur, Rao & Bhaskara, Lakshmanar, "Organic electrolyte cells", issued 1968-11-26, assigned to Duracell Inc USA 4364: 2336: 2174:
ALISE H2020 project developing a Li–S battery for cars with new components and optimized regarding anode, cathode, electrolyte and separator
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Wang, J; Yang, J; Xie, J; Xu, N (2002). "A novel conductive polymer–sulfur composite cathode material for rechargeable lithium batteries".
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Ould Ely, Teyeb; Kamzabek, Dana; Chakraborty, Dhritiman (2018-05-29). "Lithium–Sulfur Batteries: State of the Art and Future Directions".
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means that Li–S batteries are relatively light (about the density of water). They were used on the longest and highest-altitude unmanned
3101: 5352:"Lyten launches San Jose pilot production for cutting-edge batteries – Company hopes lithium-sulfur batteries can revolutionize sector" 2213: 1990: 1601: 539:
Actually the sulfur reduction reaction to lithium sulphide is much more complex and involves the formation of lithium polysulphides (Li
4891:"Multimodal Capturing of Polysulfides by Phosphorus-Doped Carbon Composites for Flexible High-Energy-Density Lithium–Sulfur Batteries" 2634: 2346:
program to advance its lithium-sulfur batteries based on a sulfurized-carbon cathode and a vertically-aligned carbon nanontube anode.
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In 2022, the German company Theion claimed to introduce lithium–sulfur batteries for mobile devices in 2023 and for vehicles by 2024.
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Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng; Zu, Chenxi; Su, Yu-Sheng (2014-12-10). "Rechargeable Lithium–Sulfur Batteries".
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Ah Long Life cells, and weighed 60% less than lead acid batteries with a significant increase in range. They also built a 3U, 3,000
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yielding a 2.35–2.5 V battery. By the end of the 1980s a rechargeable Li–S battery was demonstrated employing ethers, in particular
5046: 3102:"Lithium-Sulfur Rechargeable Batteries: Characteristics, State of Development, and Applicability to Powering Portable Electronics" 639: 255:
has self-healing properties which make it possible to repair the damage caused from recharge cycling by heating the new material.
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Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng; Zu, Chenxi; Su, Yu-Sheng (2014). "Rechargeable Lithium–Sulfur Batteries".
4842:"Covalently Interlinked Graphene Sheets with Sulfur-Chains Enable Superior Lithium–Sulfur Battery Cathodes at Full-Mass Level" 4613: 2477: 1879:
shell protects the sulfur-lithium intermediate from electrolyte solvent. Each cathode particle is 800 nanometers in diameter.
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Scheers, Johan; Fantini, Sébastien; Johansson, Patrik (June 2014). "A review of electrolytes for lithium–sulphur batteries".
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One problem with the lithium–sulfur design is that when the sulfur in the cathode absorbs lithium, volume expansion of the Li
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Peled, E.; Gorenshtein, A.; Segal, M.; Sternberg, Y. (May 1989). "Rechargeable lithium–sulfur battery (extended abstract)".
3277: 177: 809: 426: 1597: 251: 4728:"Hierarchical Free-Standing Carbon-Nanotube Paper Electrodes with Ultrahigh Sulfur-Loading for Lithium–Sulfur Batteries" 2989: 1506: 2340: 5412: 5251: 561: 2431:
Zhang, Sheng S (2013). "Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions".
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Yuan, Zhe; Peng, Hong-Jie; Huang, Jia-Qi; Liu, Xin-Yan; Wang, Dai-Wei; Cheng, Xin-Bing; Zhang, Qiang (2014-10-01).
4183: 5329:"Zeta Energy: Enabling Fast Charging Batteries with 3D Lithium Metal Architectures and Sulfurized Carbon Cathodes" 4515:"Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries" 4454:"Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium–Sulfur Batteries" 4209:
Rosenberg, Sarah; Hintennach (1 April 2014). "Laser-printed lithium-sulphur micro-electrodes for Li/S batteries".
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Historically, the "shuttle" effect is the main cause of degradation in a Li–S battery. The lithium polysulfide Li
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to test their lithium sulfur battery technology. Airbus Defense and Space successfully launched their prototype
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to over 1,000 cycles. One of the primary factors limiting the lifespan of Li-S batteries is the dissolution of
408:). During discharge, the lithium ions in the electrolyte migrate to the cathode where the sulfur is reduced to 3336:
Choi, Y.J.; Kim, K.W. (2008). "Improvement of cycle property of sulfur electrode for lithium/sulfur battery".
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Because of the high potential energy density and the nonlinear discharge and charging response of the cell, a
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exploit the contribution of active mass to the capacity. Volume expansion of the sulfur cathode during S to Li
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cells because of their higher energy density and reduced cost. This is due to two factors. First the use of
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instead of a less energy dense and more expensive substances such as cobalt and/or iron compounds found in
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Vandenberg, Aurelius; Hintennach (1 April 2014). "A novel design approach for lithium-sulphur batteries".
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One of the primary shortfalls of most Li–S cells is unwanted reactions with the electrolytes. While S and
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The SEI of hard-carbon prevents polysulphides deposition at anode and enables high-rate performance.
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Wei Seh, Z.; Li, W.; Cha, J. J.; Zheng, G.; Yang, Y.; McDowell, M. T.; Hsu, P. C.; Cui, Y. (2013).
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to a Li–S catholyte leads to the formation of complexes that accommodate the discharge product (Li
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are relatively insoluble in most electrolytes, many intermediate polysulfides are not. Dissolving
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Eftekhari, A. (2017). "Cathode Materials for Lithium–Sulfur Batteries: A Practical Perspective".
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separator layer to minimize the polysulfide shuttle effect, while creating a foldable battery.
1702: 3689: 3372: 5356: 5069:"OXIS battery powers driverless vehicle for the UK Government's Smart City Gateway programme" 4890: 4660: 2378: 1824: 5107: 4412: 4314: 4305:(2013). "The use of elemental sulfur as an alternative feedstock for polymeric materials". 4148: 3955: 3873: 3765: 3710: 3548: 3504: 3444: 3405: 3236: 2841: 2806: 2350: 2292: 1802: 1275: 202:. A few years later the technology was improved by the introduction of organic solvents as 99: 4815: 3225:"Lithium/sulfur batteries with high specific energy: old challenges and new opportunities" 8: 5277: 2248: 1740: 1693: 1559:
electrolytes based on organic carbonates commonly employed in Li-ion batteries (i.e. PC,
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Peled, E. (1989). "Lithium-Sulfur Battery: Evaluation of Dioxolane-Based Electrolytes".
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Glass coating prevents lithium polysulfides from permanently migrating to an electrode
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British firm OXIS Energy developed prototype lithium sulfur batteries. Together with
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Salvatierra, Rodrigo V; James, Dustin K; Tour, James M (2022). Gupta, Ram K (ed.).
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company Lyten started up a pilot production line making about 100 batteries a day.
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S. This contrasts with conventional lithium-ion cells, where the lithium ions are
4061:"Challenges and Solutions for Low-Temperature Lithium-Sulfur Batteries: A Review" 3885: 3672: 3076:"Healable Cathode Could Unlock Potential of Solid-state Lithium-sulfur Batteries" 1625: 1617: 1577: 103: 37: 4945: 4184:"Sulfur in hollow nanofibers overcomes challenges of lithium-ion battery design" 3796:
Pai, Rahul; Singh, Arvinder; Tang, Maureen H.; Kalra, Vibha (10 February 2022).
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Lithium-sulfur (Li-S) batteries have a shorter lifespan compared to traditional
4571:"All-solid lithium-sulfur battery stores four times the energy of lithium-ions" 3814: 3031: 2332: 2129: 1940: 1589: 1286: 278: 47: 4362: 4257: 4222: 2702: 2405:"OXIS ENERGY SET TO MAKE SOLID-STATE LITHIUM-SULFUR CELL TECHNOLOGY A REALITY" 1381:< 1), evaluated by the extension of the charge voltage plateau. The factor 5436: 4969: 4914: 4867: 4754: 3893: 3823: 3730: 3649: 3493:"ReaxFF molecular dynamics simulations on lithiated sulfur cathode materials" 3433:"ReaxFF molecular dynamics simulations on lithiated sulfur cathode materials" 2726: 2525: 2370: 1837: 1719: 1581: 294: 123: 119: 107: 3998:"Lithium-Sulfur Batteries vs. Lithium-Ion Batteries: A Comparative Analysis" 5130: 4977: 4922: 4906: 4858: 4841: 4746: 4704: 4696: 4541: 4533: 4510: 4480: 4472: 4449: 4434: 4334: 4168: 4127: 4096: 3901: 3841: 3738: 3674:
Chemically Derived Graphene: Functionalization, Properties and Applications
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10.1002/1521-4095(20020705)14:13/14<963::AID-ADMA963>3.0.CO;2-P
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Chemical processes in the Li–S cell include lithium dissolution from the
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Islam, Md Mahbubul; Bryantsev, Vyacheslav S.; van Duin, Adri CT (2014).
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during the recharge phase. The semi-reaction is therefore expressed as:
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Propp, K.; Marinescu, M.; Auger, D. J.; et al. (August 12, 2016).
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solvent, a traditional sulfur cathode lost 96% of its sulfur over 30
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Microwave processing of materials and laser-printing of electrodes.
5047:"Anesco and OXIS to Release Lithium Sulfur Battery Storage by 2016" 4129: 2526:
Automotive Li-Ion Batteries: Current Status and Future Perspectives
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Sulfur-coated, disordered carbon nanotubes made from carbohydrates
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coating showed improvement in the electrolyte stability, LIPON, Li
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on the cathode surface in sequence while the cell is discharging:
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negative-to-positive capacity ratio of <5 in pouch-type cells.
26: 5278:"'World's most efficient lithium-sulphur battery' set for launch" 4839: 3677:(illustrated ed.). Royal Society of Chemistry. p. 224. 2594:
Eftekhari, Ali (2017). "The rise of lithium–selenium batteries".
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Lithium-Sulfur Batteries: Materials, Challenges and Applications
2005:). High porosity polypropylene separator. Specific energy is 500 1501:. Elemental sulfur was deposited onto the carbon substrate (cf. 31:
Working principle of lithium-sulfur battery and "shuttle" effect
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S) and allow high cyclability and low temperature performance.
1350: 235: 199: 169:
retained >70% of their capacity after 1000 cycles. By 2023,
134: 115: 5093: 3430: 2796: 4363:
SLAC National Accelerator Laboratory (6 Posts) (2013-01-08).
1497:
In 2022, researchers reported the use of a cathode made from
1461:{\displaystyle fc={\frac {k_{\text{s}}q_{\text{up}}}{I_{c}}}} 1021: 760:{\displaystyle {\ce {Li2S8\ +\ 2Li\ ->\ Li2S6\ +\ Li2S2}}} 290: 264: 5203:"OXIS Energy Lithium-Sulfur Battery Technology Presentation" 2739: 4280:"Researchers increase lifespan of lithium-sulfur batteries" 3150: 2528:(Report). U.S. Department Of Energy. 2019-01-01. p. 26 2318: 1505:), which formed the rare and usually metastable monoclinic 1300:
S compositions occurs, and predicted volume expansion of Li
77: 2872:"Lithium-Sulfur Batteries: Attaining the Critical Metrics" 2189: 4112:
Xiulei Ji, Kyu Tae Lee, and Linda F. Nazar. (17 May 2009)
2701:
Phan, An L.; Le, Phung M.L.; Wang, Chunsheng (May 2024).
2035:
Coating prevents polysulfides from destroying the anode.
1734:
Sulfur-coated, disordered carbon hollow carbon nanofibers
983:{\displaystyle {\ce {Li2S2 \ + \ 2 Li \ -> \ 2 Li2S}}} 973: 931: 918: 876: 863: 824: 753: 740: 718: 705: 667: 654: 621: 608: 576: 518: 152:, while lithium-ion batteries are in the range of 150–260 5426: 5393: 3223:
Song, Min-Kyu; Cairns, Elton J.; Zhang, Yuegang (2013).
1620:
and other safety circuitry is sometimes used along with
1546:
Its initial capacity was 800 Ah/kg (classical LiCoO
4681: 3945: 2703:"Realizing high-energy and long-life Li/SPAN batteries" 2476:
Manthiram, Arumugam; Fu, Yongzhu; Su, Yu-Sheng (2013).
5331:. United States Department of Energy. January 13, 2023 3754:"Polysulfide Shuttle Study in the Li/S Battery System" 3573: 3180:"Lithium–sulfur batteries: from liquid to solid cells" 3100:
Tudron, F.B., Akridge, J.R., and Puglisi, V.J. (2004)
2620: 2478:"Challenges and Prospects of Lithium–Sulfur Batteries" 489: 332: 1396: 906: 883:{\displaystyle {\ce {S8 \ + \ 8 Li \ -> 4 Li2S2}}} 812: 774: 642: 564: 528:{\displaystyle {\ce {S + 2Li+ + 2e- <=> Li2S}}} 429: 306: 4243: 2360: 1592:) as well as the family of glycol ethers, including 4299: 4208: 1522:without the formation of intermediate polysulfides 4943: 3627: 3371:(third ed.). New York: McGraw-Hill. pp.  3364: 2902: 1460: 1360: 982: 882: 788: 759: 627: 527: 400:In Li–S batteries, energy is stored in the sulfur 377: 84:V during discharge; batteries often packaged for 3 4398: 3795: 3114:Kumar, Rudra; Liu, Jie; Hwang, Jang-Yeon (2018). 2548:"OXIS Energy's Lithium-Sulfur Battery Technology" 628:{\displaystyle {\ce {S8 \ + \ 2 Li -> Li2S8}}} 497: 496: 479: 478: 340: 339: 322: 321: 5434: 4785:"Glass coating for improved battery performance" 4725: 3751: 2566: 1726:, while the experimental cathode lost only 25%. 1644:formulations have shown potential to extend its 5343: 4350:"Radical approach to turn sulfur into polymers" 3752:Mikhaylik, Yuriy V.; Akridge, James R. (2004). 3700: 3537: 3222: 2399: 2397: 2395: 2393: 1509:allotrope. This allotrope reversibly reacts to 4508: 4447: 4347: 4132:; Seung Sae Hong; Yi Cui (14 September 2011). 3070: 3068: 1266:These reactions are analogous to those in the 553:≤ 8) at decreasing chain length according to: 5252:"Sony battery to offer 40% longer phone life" 4888: 3862: 3335: 3113: 2869: 2475: 2311:W⋅h Rack-Mounted Battery that weighed only 25 1608:as additive for lithium surface passivation. 995:The final product is actually a mixture of Li 378:{\displaystyle {\ce {Li <=> Li+ + e-}}} 4816:"Glass coating improves battery performance" 3982:"Lithium Sulfur Rechargeable Battery Safety" 3914: 2390: 1126:Across a porous diffusion separator, sulfur 5049:(press release). OXIS Energy. July 14, 2015 4384:: CS1 maint: numeric names: authors list ( 3065: 1011:S, due to the slow reduction kinetics at Li 3116:"Recent research trends in Li–S batteries" 2700: 2518: 2214:Korea Electrotechnology Research Institute 1991:lithium bis-(trifluoromethylsulfonyl)imide 1711:mA⋅h/g after 20 cycles at a current of 168 25: 5129: 5119: 4857: 4424: 4086: 4076: 4043: 3831: 3813: 3777: 3362: 3308: 3040: 3030: 2887: 2865: 2863: 2655:. Amsterdam: Elsevier. pp. 241–270. 2593: 2043:Sulfur/Lithium-sulfide passivation layer 962: 946: 852: 839: 682: 591: 457: 440: 5411:. En.winston-battery.com. Archived from 4950:Journal of the American Chemical Society 3177: 2646: 2644: 2128:Glass-coated sulfur with mildly reduced 1357:N also exhibited promising performance. 277:) during discharge, and reverse lithium 4663:. Green Car Congress. November 12, 2014 4522:Angewandte Chemie International Edition 4461:Angewandte Chemie International Edition 4058: 3985:Battery Power Products & Technology 3791: 3789: 2066:Passivation layer prevents sulfur loss 1640:. Recent advancements in materials and 472: 315: 80:varies nonlinearly in the range 2.5–1.7 5435: 5349: 4813: 4782: 4611: 4182:Keller, Sarah Jane (October 4, 2011). 4181: 4175: 3995: 3941: 3939: 3758:Journal of the Electrochemical Society 3583:Journal of the Electrochemical Society 3275: 2987: 2962: 2937: 2860: 2834:Journal of the Electrochemical Society 1604:in DOL:DME 1:1 vol. with 1%w/w di LiNO 129:Lithium–sulfur batteries may displace 5429:. EEMB Battery. Retrieved 2018-04-13. 5223: 4108: 4106: 4021: 3670: 3623: 3621: 3619: 3490: 3278:"Revisiting Lithium-Sulfur Batteries" 2831: 2696: 2694: 2641: 2430: 2028:Pacific Northwest National Laboratory 1958:Lawrence Berkeley National Laboratory 182:Pacific Northwest National Laboratory 3786: 2870:Bhargav, Amruth; Jiarui, He (2020). 2471: 2469: 2426: 2424: 2422: 2271: 2138:University of California, Riverside 1805:for Material and Beam Technology IWS 1756:An electrolyte additive boosted the 178:University of Maryland, College Park 4246:Russian Journal of Electrochemistry 4211:Russian Journal of Electrochemistry 3936: 3012: 2109:mA·h⋅cm at a sulfur loading of 17.3 1274:very cheap, but has practically no 13: 5302: 5226:"Oxis Energy files for bankruptcy" 4612:Lavars, Nick (February 20, 2014). 4103: 3616: 3216: 3178:Lin, Zhan; Liang, Chengdu (2015). 3144: 2691: 2554:from the original on 28 June 2017. 2341:United States Department of Energy 1859:-encapsulated sulfur nanoparticles 122:aeroplane flight (at the time) by 14: 5464: 5367: 2466: 2459:"Solar plane makes record flight" 2419: 2074:Sulfur-copolymer (poly(S-co-DVB)) 4995:Sion Power Company Press Release 3311:Journal of Materials Chemistry A 3184:Journal of Materials Chemistry A 3120:Journal of Materials Chemistry A 2363: 2237:Lithium thiophosphate catholyte 1696:coated, pitted mesoporous carbon 1682:Specific capacity after cycling 267:surface (and incorporation into 5321: 5296: 5270: 5244: 5231:Chemical & Engineering News 5217: 5195: 5163: 5138: 5087: 5061: 5039: 5021: 4999: 4984: 4937: 4882: 4833: 4807: 4776: 4719: 4675: 4653: 4627: 4605: 4594:. NewAtlas.com. 2 December 2013 4584: 4563: 4502: 4441: 4392: 4356: 4341: 4293: 4272: 4237: 4202: 4121: 4052: 4036:10.1016/j.electacta.2021.139013 4015: 3989: 3974: 3930:10.1016/j.electacta.2013.06.039 3908: 3856: 3745: 3694: 3664: 3567: 3531: 3484: 3471: 3424: 3389: 3356: 3338:Journal of Alloys and Compounds 3329: 3302: 3269: 3171: 3107: 3094: 3006: 2981: 2956: 2931: 2896: 2825: 2790: 2771: 2752: 2733: 2669: 2339:was awarded $ 4 million by the 2207:Sulfur-loaded carbon nanotubes 2013:W⋅h/kg at 1,500 cycles (C=1.0) 1993:(LiTFSI), and lithium nitrate ( 1749:mA⋅h/g after 150 cycles (at 0.5 1600:. One common electrolyte is 1M 535:(E ° ≈ 2.15 V vs Li / Li ) 416:. The sulfur is reoxidized to S 5377:. Polyplus.com. Archived from 5121:10.1016/j.jpowsour.2016.07.090 4814:Nealon, Sean (March 2, 2015). 3968:10.1016/j.jpowsour.2014.01.023 3561:10.1016/j.jpowsour.2007.06.108 3418:10.1016/j.jpowsour.2008.02.053 3276:Bullis, Kevin (May 22, 2009). 2614: 2596:Sustainable Energy & Fuels 2587: 2581:10.1016/j.jpowsour.2013.01.132 2560: 2540: 2451: 2445:10.1016/j.jpowsour.2012.12.102 2282:High Altitude Pseudo-Satellite 2085:400 mAh/g for 500 cycles at 3C 1553: 1442: 1429: 953: 846: 689: 595: 499: 474: 342: 317: 247:longer than 20 to 30 minutes. 218:, as the electrolyte solvent. 114:and moderate atomic weight of 1: 5350:Avalos, George (2023-06-14). 5176:. OXIS Energy. Archived from 4846:Advanced Functional Materials 4735:Advanced Functional Materials 4348:Caryl Richards (2013-04-16). 4128:Guangyuan, Zheng; Yuan Yang; 3996:Trento, Chin (Dec 27, 2023). 3980:Akridge, J.R. (October 2001) 3367:Lange's Handbook of Chemistry 3350:10.1016/j.jallcom.2006.02.098 2384: 1897:Oak Ridge National Laboratory 1781:mA⋅h/g after 400 cycles (at 1 1624:to manage cell operation and 281:to the anode while charging. 242:Also in 2022, Researchers at 102:. It is notable for its high 3886:10.1021/acs.nanolett.7b00221 3153:ACS Applied Energy Materials 2819:10.1016/0378-7753(89)80133-8 2325:a smartphone for five days. 2081:Chungnam National University 1966:mA·h/g at 1,500 cycles (0.05 1588:) or short-chain ethers (as 1388:is given by the expression: 258: 98:(Li–S battery) is a type of 16:Type of rechargeable battery 7: 5171:"OXIS Rack-Mounted Battery" 4990:Kopera, J (September 2014) 4783:Nealon, Sean (2015-03-03). 4573:. NewAtlas.com. 7 June 2013 4002:Stanford Advanced Materials 3491:Islam; et al. (2015). 3481:, NewAtlas, 1 December 2013 2988:Lavars, Nick (2022-01-17). 2963:Lavars, Nick (2022-02-28). 2938:Lavars, Nick (2021-09-13). 2889:10.1016/j.joule.2020.01.001 2719:10.1016/j.joule.2024.04.003 2356: 2188:CATRIN, Palacký University 1976:mA·h/g at 1,500 cycles (0.5 1872:mA⋅h/g at 1,000 cycles (0.5 1659: 1631: 789:{\displaystyle {\ce {...}}} 57:Charge/discharge efficiency 10: 5469: 5224:Scott, Alex (2021-06-26). 4509:Lin, Z.; Liu, Z.; Fu, W.; 4282:. Gizmag.com. 4 April 2013 3815:10.1038/s42004-022-00626-2 3032:10.1038/s42004-022-00626-2 2679:. PR Newswire. May 1, 2023 2457:Amos, J. (24 August 2008) 2297:equivalent-circuit-network 1919:mA·h/g at 300 cycles at 60 1905:mA·h/g at 300 cycles at 60 395: 188: 5409:"Winston Battery Limited" 5375:"PolyPlus Lithium Sulfur" 5205:. OXIS Energy. 2016-11-03 4258:10.1134/S102319351306013X 4223:10.1134/S1023193514040065 3013:Pai, Rahul (2022-02-10). 2254:1271 mA⋅h⋅g (200 cycles) 2093:Lithium sulfur batteries 1611: 1503:physical vapor deposition 72: 64: 56: 46: 36: 24: 4059:Liu, Y; Wang, T (2023). 3948:Journal of Power Sources 3802:Communications Chemistry 3104:(Tucson, AZ: Sion Power) 3019:Communications Chemistry 2799:Journal of Power Sources 2569:Journal of Power Sources 2433:Journal of Power Sources 2278:Airbus Defence and Space 2225:Uses a phosphorus-doped 2009:W⋅h/kg (initial) and 250 284: 250:In 2024, researchers at 4448:Lin, Z; Liu, Z; Fu, W; 3363:J.A. Dean, ed. (1985). 2289:Imperial College London 2259:phosphorus pentasulfide 2132:for structural support 2096:Carbon nanotube/Sulfur 1949:carboxymethyl cellulose 1765:Silicon nanowire/carbon 1626:prevent rapid discharge 5448:Metal-sulfur batteries 5443:Rechargeable batteries 4907:10.1002/smll.202200326 4859:10.1002/adfm.202101326 4747:10.1002/adfm.201401501 4697:10.1002/cssc.201802430 4635:"A whiff of brimstone" 4534:10.1002/anie.201300680 4473:10.1002/anie.201300680 3671:Zhang, Kintao (2018). 3497:Phys. Chem. Chem. Phys 3437:Phys. Chem. Chem. Phys 3165:10.1021/acsaem.7b00153 2071:Lithiated hard-carbon 1760:from 85% to over 99%. 1703:University of Waterloo 1462: 984: 884: 790: 761: 629: 529: 379: 96:lithium–sulfur battery 20:Lithium–sulfur battery 5453:Lithium-ion batteries 5357:San Jose Mercury News 4405:Nature Communications 4190:. Stanford University 2779:US patent 3413154 2760:US patent 3532543 2741:US patent 3043896 2379:List of battery types 2056:mA·h/g (1000 cycles) 1825:University of Arizona 1808:? after 1,400 cycles 1463: 1361:Polysulfide "shuttle" 1268:sodium–sulfur battery 1134:as the cell charges: 1007:S rather than pure Li 985: 885: 791: 762: 630: 530: 380: 139:lithium-ion batteries 4962:10.1021/jacs.3c05209 4513:; Liang, C. (2013). 2407:(pdf). 20 April 2021 2351:San Jose, California 2293:Cranfield University 2222:mA⋅h⋅g (100 cycles) 2197:mA⋅h⋅g (250 cycles) 2182:Sulfurized graphene 2102:Tsinghua University 1833:mA⋅h/g at 100 cycles 1803:Fraunhofer Institute 1394: 904: 895:And the final step: 810: 772: 640: 562: 427: 410:lithium sulphide (Li 304: 100:rechargeable battery 73:Nominal cell voltage 5258:. December 17, 2015 5256:Nikkei Asian Review 5112:2016JPS...328..289P 4956:(34): 18865–18876. 4452:; Liang, C (2013). 4417:2013NatCo...4.1331W 4319:2013NatCh...5..518C 4153:2011NanoL..11.4462Z 4024:Electrochimica Acta 3960:2014JPS...255..204S 3918:Electrochimica Acta 3878:2017NanoL..17.2967T 3770:2004JElS..151A1969M 3715:2013Nanos...5.2186S 3690:Extract of page 224 3636:(23): 11751–11787. 3595:10.1149/2.005408jes 3553:2007JPS...174..745J 3509:2015PCCP...17.3383I 3449:2015PCCP...17.3383I 3410:2008JPS...184..548C 3317:(34): 17734–17776. 3241:2013Nanos...5.2186S 3126:(25): 11582–11605. 2911:(23): 11751–11787. 2846:1989JElS..136.1621P 2811:1989JPS....26..269P 2249:Stanford University 2145:mA⋅h⋅g (50 cycles) 2040:Lithiated graphene 2018:Lithiated graphite 1943:nanocomposite with 1865:Stanford University 1741:Stanford University 1694:Polyethylene glycol 1666: 1276:electroconductivity 975: 933: 920: 878: 865: 826: 755: 742: 720: 707: 669: 656: 623: 610: 578: 520: 485: 328: 21: 5183:on August 26, 2018 4426:10.1038/ncomms2327 4327:10.1038/nchem.1624 4078:10.3390/ma16124359 3723:10.1039/c2nr33044j 3589:(8): E3009–E3014. 3517:10.1039/C4CP04532G 3457:10.1039/c4cp04532g 3323:10.1039/C7TA00799J 3249:10.1039/c2nr33044j 3196:10.1039/C4TA04727C 3132:10.1039/C8TA01483C 3080:US San Diego Today 2629:(13–14): 963–965. 2623:Advanced Materials 2608:10.1039/C6SE00094K 1881:Faraday efficiency 1758:faraday efficiency 1664: 1622:voltage regulators 1458: 980: 963: 921: 908: 880: 866: 853: 814: 786: 757: 743: 730: 708: 695: 657: 644: 625: 611: 598: 566: 525: 508: 504: 375: 347: 19: 5284:. January 6, 2020 5150:nextbigfuture.com 4741:(39): 6105–6112. 4641:. January 3, 2015 4528:(29): 7460–7463. 4467:(29): 7460–7463. 4161:10.1021/nl2027684 4147:(10): 4462–4467. 3779:10.1149/1.1806394 3684:978-1-78801-080-1 3642:10.1021/cr500062v 3382:978-0-07-016192-4 3290:on April 15, 2012 3283:Technology Review 2917:10.1021/cr500062v 2854:10.1149/1.2096981 2662:978-0-323-91934-0 2497:10.1021/ar300179v 2331:In January 2023, 2295:, they published 2272:Commercialization 2269: 2268: 2244:Dartmouth College 1945:styrene-butadiene 1499:carbon nanofibers 1456: 1439: 1426: 1416: 978: 966: 958: 952: 949: 942: 936: 924: 911: 869: 856: 845: 842: 835: 829: 817: 746: 733: 729: 723: 711: 698: 694: 688: 685: 678: 672: 660: 647: 614: 601: 594: 587: 581: 569: 523: 511: 506: 461: 444: 433: 367: 354: 349: 310: 297:is expressed as: 244:Drexel University 92: 91: 5460: 5423: 5421: 5420: 5404: 5402: 5401: 5389: 5387: 5386: 5362: 5361: 5347: 5341: 5340: 5338: 5336: 5325: 5319: 5318: 5316: 5315: 5300: 5294: 5293: 5291: 5289: 5274: 5268: 5267: 5265: 5263: 5248: 5242: 5241: 5239: 5238: 5221: 5215: 5214: 5212: 5210: 5199: 5193: 5192: 5190: 5188: 5182: 5175: 5167: 5161: 5160: 5158: 5157: 5142: 5136: 5135: 5133: 5123: 5100:J. Power Sources 5091: 5085: 5084: 5082: 5080: 5065: 5059: 5058: 5056: 5054: 5043: 5037: 5036: 5025: 5019: 5018: 5016: 5014: 5003: 4997: 4988: 4982: 4981: 4941: 4935: 4934: 4886: 4880: 4879: 4861: 4837: 4831: 4830: 4828: 4826: 4811: 4805: 4804: 4802: 4800: 4791:. Archived from 4780: 4774: 4773: 4771: 4765:. Archived from 4732: 4723: 4717: 4716: 4679: 4673: 4672: 4670: 4668: 4657: 4651: 4650: 4648: 4646: 4631: 4625: 4624: 4622: 4620: 4609: 4603: 4602: 4600: 4599: 4588: 4582: 4581: 4579: 4578: 4567: 4561: 4560: 4558: 4552:. Archived from 4519: 4506: 4500: 4499: 4497: 4491:. Archived from 4458: 4445: 4439: 4438: 4428: 4396: 4390: 4389: 4383: 4375: 4373: 4372: 4360: 4354: 4353: 4345: 4339: 4338: 4307:Nature Chemistry 4297: 4291: 4290: 4288: 4287: 4276: 4270: 4269: 4241: 4235: 4234: 4206: 4200: 4199: 4197: 4195: 4179: 4173: 4172: 4138: 4125: 4119: 4117:Nature Materials 4110: 4101: 4100: 4090: 4080: 4056: 4050: 4049: 4047: 4019: 4013: 4012: 4010: 4008: 3993: 3987: 3978: 3972: 3971: 3943: 3934: 3933: 3912: 3906: 3905: 3872:(5): 2967–2972. 3860: 3854: 3853: 3835: 3817: 3793: 3784: 3783: 3781: 3749: 3743: 3742: 3698: 3692: 3688: 3668: 3662: 3661: 3630:Chemical Reviews 3625: 3614: 3613: 3611: 3605:. Archived from 3580: 3571: 3565: 3564: 3541:J. Power Sources 3535: 3529: 3528: 3503:(5): 3383–3393. 3488: 3482: 3475: 3469: 3468: 3443:(5): 3383–3393. 3428: 3422: 3421: 3398:J. Power Sources 3393: 3387: 3386: 3370: 3360: 3354: 3353: 3344:(1–2): 313–316. 3333: 3327: 3326: 3306: 3300: 3299: 3297: 3295: 3286:. Archived from 3273: 3267: 3266: 3264: 3263: 3220: 3214: 3213: 3211: 3210: 3175: 3169: 3168: 3159:(5): 1783–1814. 3148: 3142: 3141: 3139: 3138: 3111: 3105: 3098: 3092: 3091: 3089: 3087: 3072: 3063: 3062: 3044: 3034: 3010: 3004: 3003: 3001: 3000: 2985: 2979: 2978: 2976: 2975: 2960: 2954: 2953: 2951: 2950: 2935: 2929: 2928: 2905:Chemical Reviews 2900: 2894: 2893: 2891: 2867: 2858: 2857: 2840:(6): 1621–1625. 2829: 2823: 2822: 2805:(3–4): 269–271. 2794: 2788: 2787: 2786: 2782: 2775: 2769: 2768: 2767: 2763: 2756: 2750: 2749: 2748: 2744: 2737: 2731: 2730: 2713:(6): 1601–1618. 2698: 2689: 2688: 2686: 2684: 2673: 2667: 2666: 2648: 2639: 2638: 2618: 2612: 2611: 2591: 2585: 2584: 2564: 2558: 2555: 2544: 2538: 2537: 2535: 2533: 2522: 2516: 2515: 2513: 2507:. Archived from 2491:(5): 1125–1134. 2482: 2473: 2464: 2455: 2449: 2448: 2428: 2417: 2416: 2414: 2412: 2401: 2373: 2368: 2367: 2314: 2310: 2306: 2302: 2227:activated carbon 2221: 2196: 2170: 2144: 2112: 2108: 2061: 2055: 2012: 2008: 2004: 2003: 2002: 1983: 1979: 1975: 1969: 1965: 1951:copolymer binder 1926: 1922: 1918: 1912: 1908: 1904: 1875: 1871: 1858: 1857: 1856: 1832: 1784: 1780: 1752: 1748: 1714: 1710: 1667: 1663: 1638:Li-ion batteries 1542: 1541: 1540: 1532: 1531: 1521: 1519: 1518: 1467: 1465: 1464: 1459: 1457: 1455: 1454: 1445: 1441: 1440: 1437: 1428: 1427: 1424: 1418: 1417: 1414: 1407: 1347: 1346: 1345: 1335: 1334: 1324: 1322: 1321: 1292: 1285: 1281: 1262: 1261: 1260: 1252: 1251: 1250: 1242: 1241: 1231: 1230: 1229: 1221: 1220: 1210: 1209: 1208: 1200: 1199: 1189: 1188: 1187: 1179: 1178: 1168: 1167: 1166: 1158: 1157: 1147: 1146: 1122: 1121: 1120: 1112: 1111: 1101: 1100: 1099: 1091: 1090: 1080: 1079: 1078: 1070: 1069: 1059: 1058: 1057: 1049: 1048: 1038: 1037: 1036: 989: 987: 986: 981: 979: 976: 974: 971: 964: 956: 950: 947: 940: 934: 932: 929: 922: 919: 916: 909: 889: 887: 886: 881: 879: 877: 874: 867: 864: 861: 854: 843: 840: 833: 827: 825: 822: 815: 795: 793: 792: 787: 785: 766: 764: 763: 758: 756: 754: 751: 744: 741: 738: 731: 727: 721: 719: 716: 709: 706: 703: 696: 692: 686: 683: 676: 670: 668: 665: 658: 655: 652: 645: 634: 632: 631: 626: 624: 622: 619: 612: 609: 606: 599: 592: 585: 579: 577: 574: 567: 534: 532: 531: 526: 524: 521: 519: 516: 509: 507: 505: 503: 502: 495: 487: 486: 484: 477: 469: 467: 466: 459: 450: 449: 442: 431: 384: 382: 381: 376: 374: 373: 372: 365: 360: 359: 352: 350: 348: 346: 345: 338: 330: 329: 327: 320: 312: 308: 155: 144: 126:in August 2008. 87: 83: 65:Cycle durability 29: 22: 18: 5468: 5467: 5463: 5462: 5461: 5459: 5458: 5457: 5433: 5432: 5418: 5416: 5407: 5399: 5397: 5392: 5384: 5382: 5373: 5370: 5365: 5348: 5344: 5334: 5332: 5327: 5326: 5322: 5313: 5311: 5303:Morris, James. 5301: 5297: 5287: 5285: 5276: 5275: 5271: 5261: 5259: 5250: 5249: 5245: 5236: 5234: 5222: 5218: 5208: 5206: 5201: 5200: 5196: 5186: 5184: 5180: 5173: 5169: 5168: 5164: 5155: 5153: 5144: 5143: 5139: 5092: 5088: 5078: 5076: 5067: 5066: 5062: 5052: 5050: 5045: 5044: 5040: 5027: 5026: 5022: 5012: 5010: 5005: 5004: 5000: 4989: 4985: 4942: 4938: 4901:(21): 2200326. 4887: 4883: 4852:(30): 2101326. 4838: 4834: 4824: 4822: 4812: 4808: 4798: 4796: 4781: 4777: 4769: 4730: 4724: 4720: 4680: 4676: 4666: 4664: 4659: 4658: 4654: 4644: 4642: 4633: 4632: 4628: 4618: 4616: 4610: 4606: 4597: 4595: 4590: 4589: 4585: 4576: 4574: 4569: 4568: 4564: 4556: 4517: 4507: 4503: 4495: 4456: 4446: 4442: 4397: 4393: 4377: 4376: 4370: 4368: 4367:. CleanTechnica 4361: 4357: 4346: 4342: 4298: 4294: 4285: 4283: 4278: 4277: 4273: 4242: 4238: 4207: 4203: 4193: 4191: 4180: 4176: 4136: 4126: 4122: 4111: 4104: 4057: 4053: 4020: 4016: 4006: 4004: 3994: 3990: 3979: 3975: 3944: 3937: 3913: 3909: 3861: 3857: 3794: 3787: 3750: 3746: 3709:(6): 2186–204. 3699: 3695: 3685: 3669: 3665: 3626: 3617: 3609: 3578: 3572: 3568: 3536: 3532: 3489: 3485: 3476: 3472: 3429: 3425: 3394: 3390: 3383: 3361: 3357: 3334: 3330: 3307: 3303: 3293: 3291: 3274: 3270: 3261: 3259: 3235:(6): 2186–204. 3221: 3217: 3208: 3206: 3176: 3172: 3149: 3145: 3136: 3134: 3112: 3108: 3099: 3095: 3085: 3083: 3074: 3073: 3066: 3011: 3007: 2998: 2996: 2986: 2982: 2973: 2971: 2961: 2957: 2948: 2946: 2936: 2932: 2901: 2897: 2868: 2861: 2830: 2826: 2795: 2791: 2784: 2776: 2772: 2765: 2757: 2753: 2746: 2738: 2734: 2699: 2692: 2682: 2680: 2675: 2674: 2670: 2663: 2649: 2642: 2619: 2615: 2592: 2588: 2565: 2561: 2546: 2545: 2541: 2531: 2529: 2524: 2523: 2519: 2511: 2480: 2474: 2467: 2456: 2452: 2429: 2420: 2410: 2408: 2403: 2402: 2391: 2387: 2369: 2362: 2359: 2312: 2308: 2304: 2300: 2274: 2264: 2219: 2194: 2168: 2142: 2116: 2110: 2106: 2059: 2053: 2010: 2006: 2001: 1998: 1997: 1996: 1994: 1981: 1977: 1973: 1967: 1963: 1924: 1920: 1916: 1910: 1906: 1902: 1873: 1869: 1855: 1852: 1851: 1850: 1848: 1830: 1782: 1778: 1750: 1746: 1712: 1708: 1662: 1634: 1618:microcontroller 1614: 1607: 1578:ethylene glycol 1556: 1549: 1539: 1536: 1535: 1534: 1530: 1527: 1526: 1525: 1523: 1517: 1514: 1513: 1512: 1510: 1492: 1482: 1475: 1450: 1446: 1436: 1432: 1423: 1419: 1413: 1409: 1408: 1406: 1395: 1392: 1391: 1386: 1380: 1376: 1372: 1368: 1363: 1356: 1344: 1339: 1338: 1337: 1333: 1330: 1329: 1328: 1326: 1320: 1317: 1316: 1315: 1313: 1303: 1299: 1290: 1283: 1279: 1259: 1256: 1255: 1254: 1249: 1246: 1245: 1244: 1240: 1237: 1236: 1235: 1233: 1228: 1225: 1224: 1223: 1219: 1216: 1215: 1214: 1212: 1207: 1204: 1203: 1202: 1198: 1195: 1194: 1193: 1191: 1186: 1183: 1182: 1181: 1177: 1174: 1173: 1172: 1170: 1165: 1162: 1161: 1160: 1156: 1153: 1152: 1151: 1149: 1145: 1142: 1141: 1140: 1138: 1119: 1116: 1115: 1114: 1110: 1107: 1106: 1105: 1103: 1098: 1095: 1094: 1093: 1089: 1086: 1085: 1084: 1082: 1077: 1074: 1073: 1072: 1068: 1065: 1064: 1063: 1061: 1056: 1053: 1052: 1051: 1047: 1044: 1043: 1042: 1040: 1035: 1032: 1031: 1030: 1028: 1014: 1010: 1006: 1002: 998: 972: 967: 930: 925: 917: 912: 907: 905: 902: 901: 875: 870: 862: 857: 823: 818: 813: 811: 808: 807: 775: 773: 770: 769: 752: 747: 739: 734: 717: 712: 704: 699: 666: 661: 653: 648: 643: 641: 638: 637: 620: 615: 607: 602: 575: 570: 565: 563: 560: 559: 548: 542: 517: 512: 498: 491: 490: 488: 480: 473: 471: 470: 468: 462: 458: 445: 441: 430: 428: 425: 424: 419: 413: 407: 398: 368: 364: 355: 351: 341: 334: 333: 331: 323: 316: 314: 313: 311: 307: 305: 302: 301: 287: 261: 191: 167: 153: 142: 104:specific energy 85: 81: 38:Specific energy 32: 17: 12: 11: 5: 5466: 5456: 5455: 5450: 5445: 5431: 5430: 5427:"EEMB Battery" 5424: 5405: 5390: 5369: 5368:External links 5366: 5364: 5363: 5342: 5320: 5295: 5269: 5243: 5216: 5194: 5162: 5137: 5086: 5060: 5038: 5020: 4998: 4983: 4936: 4881: 4832: 4806: 4775: 4772:on 2020-01-03. 4718: 4691:(2): 480–486. 4674: 4652: 4626: 4604: 4583: 4562: 4559:on 2016-09-10. 4501: 4498:on 2016-09-10. 4440: 4391: 4355: 4340: 4313:(6): 518–524. 4292: 4271: 4252:(4): 317–326. 4236: 4217:(4): 327–335. 4201: 4174: 4120: 4102: 4051: 4014: 3988: 3973: 3935: 3907: 3855: 3785: 3744: 3693: 3683: 3663: 3615: 3612:on 2019-02-21. 3566: 3547:(2): 745–750. 3530: 3483: 3477:Brian Dodson, 3470: 3423: 3404:(2): 548–552. 3388: 3381: 3355: 3328: 3301: 3268: 3215: 3170: 3143: 3106: 3093: 3082:. 6 March 2024 3064: 3005: 2980: 2955: 2930: 2895: 2882:(2): 285–291. 2859: 2824: 2789: 2770: 2751: 2732: 2690: 2668: 2661: 2640: 2613: 2586: 2559: 2539: 2517: 2514:on 2020-01-03. 2485:Acc. Chem. Res 2465: 2450: 2418: 2388: 2386: 2383: 2382: 2381: 2375: 2374: 2358: 2355: 2349:In June 2023, 2333:Houston, Texas 2273: 2270: 2267: 2266: 2262: 2255: 2252: 2241: 2238: 2235: 2234:Lithium metal 2231: 2230: 2223: 2216: 2211: 2208: 2205: 2202: 2201: 2198: 2191: 2186: 2183: 2180: 2179:Lithium metal 2176: 2175: 2172: 2165: 2160: 2157: 2154: 2150: 2149: 2146: 2139: 2136: 2133: 2130:graphene oxide 2126: 2123: 2122: 2118: 2114: 2103: 2100: 2097: 2094: 2090: 2089: 2086: 2083: 2078: 2075: 2072: 2068: 2067: 2064: 2050: 2047: 2044: 2041: 2037: 2036: 2033: 2030: 2025: 2022: 2019: 2015: 2014: 1999: 1986: 1960: 1955: 1952: 1941:graphene oxide 1937: 1933: 1932: 1929: 1899: 1894: 1891: 1888: 1885: 1884: 1877: 1866: 1863: 1860: 1853: 1845: 1842: 1841: 1836:Uses "inverse 1834: 1827: 1822: 1819: 1813: 1810: 1809: 1806: 1800: 1797: 1794: 1793:Silicon carbon 1790: 1789: 1786: 1775: 1772: 1769: 1766: 1762: 1761: 1754: 1743: 1738: 1735: 1732: 1728: 1727: 1716: 1705: 1700: 1697: 1691: 1687: 1686: 1683: 1680: 1677: 1674: 1671: 1661: 1658: 1633: 1630: 1613: 1610: 1605: 1582:thiocarbonates 1555: 1552: 1547: 1537: 1528: 1515: 1490: 1480: 1473: 1453: 1449: 1444: 1435: 1431: 1422: 1412: 1405: 1402: 1399: 1384: 1378: 1374: 1370: 1366: 1362: 1359: 1354: 1340: 1331: 1318: 1301: 1297: 1264: 1263: 1257: 1247: 1238: 1226: 1217: 1205: 1196: 1184: 1175: 1163: 1154: 1143: 1124: 1123: 1117: 1108: 1096: 1087: 1075: 1066: 1054: 1045: 1033: 1012: 1008: 1004: 1000: 996: 993: 992: 991: 990: 970: 961: 955: 945: 939: 928: 915: 893: 892: 891: 890: 873: 860: 851: 848: 838: 832: 821: 799: 798: 797: 796: 784: 781: 778: 767: 750: 737: 726: 715: 702: 691: 681: 675: 664: 651: 635: 618: 605: 597: 590: 584: 573: 544: 540: 537: 536: 515: 501: 494: 483: 476: 465: 456: 453: 448: 439: 436: 417: 411: 405: 397: 394: 386: 385: 371: 363: 358: 344: 337: 326: 319: 286: 283: 260: 257: 190: 187: 165: 90: 89: 74: 70: 69: 66: 62: 61: 58: 54: 53: 50: 48:Energy density 44: 43: 42:450 Wh/kg 40: 34: 33: 30: 15: 9: 6: 4: 3: 2: 5465: 5454: 5451: 5449: 5446: 5444: 5441: 5440: 5438: 5428: 5425: 5415:on 2014-03-25 5414: 5410: 5406: 5395: 5391: 5381:on 2013-04-20 5380: 5376: 5372: 5371: 5359: 5358: 5353: 5346: 5335:September 28, 5330: 5324: 5310: 5306: 5299: 5283: 5279: 5273: 5257: 5253: 5247: 5233: 5232: 5227: 5220: 5204: 5198: 5179: 5172: 5166: 5151: 5147: 5141: 5132: 5131:10044/1/39221 5127: 5122: 5117: 5113: 5109: 5105: 5101: 5097: 5090: 5075:on 2016-04-29 5074: 5070: 5064: 5048: 5042: 5034: 5033:sionpower.com 5030: 5024: 5008: 5002: 4996: 4993: 4987: 4979: 4975: 4971: 4967: 4963: 4959: 4955: 4951: 4947: 4940: 4932: 4928: 4924: 4920: 4916: 4912: 4908: 4904: 4900: 4896: 4892: 4885: 4877: 4873: 4869: 4865: 4860: 4855: 4851: 4847: 4843: 4836: 4821: 4817: 4810: 4795:on 2015-03-07 4794: 4790: 4786: 4779: 4768: 4764: 4760: 4756: 4752: 4748: 4744: 4740: 4736: 4729: 4722: 4714: 4710: 4706: 4702: 4698: 4694: 4690: 4686: 4678: 4662: 4656: 4640: 4636: 4630: 4615: 4608: 4593: 4587: 4572: 4566: 4555: 4551: 4547: 4543: 4539: 4535: 4531: 4527: 4523: 4516: 4512: 4511:Dudney, N. J. 4505: 4494: 4490: 4486: 4482: 4478: 4474: 4470: 4466: 4462: 4455: 4451: 4444: 4436: 4432: 4427: 4422: 4418: 4414: 4410: 4406: 4402: 4395: 4387: 4381: 4366: 4359: 4351: 4344: 4336: 4332: 4328: 4324: 4320: 4316: 4312: 4308: 4304: 4296: 4281: 4275: 4267: 4263: 4259: 4255: 4251: 4247: 4240: 4232: 4228: 4224: 4220: 4216: 4212: 4205: 4189: 4188:Stanford News 4185: 4178: 4170: 4166: 4162: 4158: 4154: 4150: 4146: 4142: 4135: 4131: 4124: 4118: 4115: 4109: 4107: 4098: 4094: 4089: 4084: 4079: 4074: 4070: 4066: 4062: 4055: 4046: 4041: 4037: 4033: 4029: 4025: 4018: 4003: 3999: 3992: 3986: 3983: 3977: 3969: 3965: 3961: 3957: 3953: 3949: 3942: 3940: 3931: 3927: 3923: 3919: 3911: 3903: 3899: 3895: 3891: 3887: 3883: 3879: 3875: 3871: 3867: 3859: 3851: 3847: 3843: 3839: 3834: 3829: 3825: 3821: 3816: 3811: 3807: 3803: 3799: 3792: 3790: 3780: 3775: 3771: 3767: 3764:(11): A1969. 3763: 3759: 3755: 3748: 3740: 3736: 3732: 3728: 3724: 3720: 3716: 3712: 3708: 3704: 3697: 3691: 3686: 3680: 3676: 3675: 3667: 3659: 3655: 3651: 3647: 3643: 3639: 3635: 3631: 3624: 3622: 3620: 3608: 3604: 3600: 3596: 3592: 3588: 3584: 3577: 3570: 3562: 3558: 3554: 3550: 3546: 3542: 3534: 3526: 3522: 3518: 3514: 3510: 3506: 3502: 3498: 3494: 3487: 3480: 3474: 3466: 3462: 3458: 3454: 3450: 3446: 3442: 3438: 3434: 3427: 3419: 3415: 3411: 3407: 3403: 3399: 3392: 3384: 3378: 3374: 3369: 3368: 3359: 3351: 3347: 3343: 3339: 3332: 3324: 3320: 3316: 3312: 3305: 3289: 3285: 3284: 3279: 3272: 3258: 3254: 3250: 3246: 3242: 3238: 3234: 3230: 3226: 3219: 3205: 3201: 3197: 3193: 3189: 3185: 3181: 3174: 3166: 3162: 3158: 3154: 3147: 3133: 3129: 3125: 3121: 3117: 3110: 3103: 3097: 3081: 3077: 3071: 3069: 3060: 3056: 3052: 3048: 3043: 3038: 3033: 3028: 3024: 3020: 3016: 3009: 2995: 2991: 2984: 2970: 2966: 2959: 2945: 2941: 2934: 2926: 2922: 2918: 2914: 2910: 2906: 2899: 2890: 2885: 2881: 2877: 2873: 2866: 2864: 2855: 2851: 2847: 2843: 2839: 2835: 2828: 2820: 2816: 2812: 2808: 2804: 2800: 2793: 2780: 2774: 2761: 2755: 2742: 2736: 2728: 2724: 2720: 2716: 2712: 2708: 2704: 2697: 2695: 2678: 2672: 2664: 2658: 2654: 2647: 2645: 2636: 2632: 2628: 2624: 2617: 2609: 2605: 2601: 2597: 2590: 2582: 2578: 2574: 2570: 2563: 2553: 2549: 2543: 2527: 2521: 2510: 2506: 2502: 2498: 2494: 2490: 2486: 2479: 2472: 2470: 2463: 2460: 2454: 2446: 2442: 2438: 2434: 2427: 2425: 2423: 2406: 2400: 2398: 2396: 2394: 2389: 2380: 2377: 2376: 2372: 2371:Energy portal 2366: 2361: 2354: 2352: 2347: 2345: 2342: 2338: 2334: 2329: 2326: 2322: 2320: 2316: 2298: 2294: 2290: 2285: 2283: 2279: 2260: 2256: 2253: 2251: 2250: 2245: 2242: 2239: 2236: 2233: 2232: 2228: 2224: 2217: 2215: 2212: 2209: 2206: 2204: 2203: 2199: 2192: 2190: 2187: 2184: 2181: 2178: 2177: 2173: 2166: 2164: 2161: 2158: 2155: 2152: 2151: 2147: 2140: 2137: 2134: 2131: 2127: 2125: 2124: 2119: 2104: 2101: 2098: 2095: 2092: 2091: 2087: 2084: 2082: 2079: 2076: 2073: 2070: 2069: 2065: 2063: 2051: 2048: 2045: 2042: 2039: 2038: 2034: 2031: 2029: 2026: 2024:February 2014 2023: 2020: 2017: 2016: 1992: 1987: 1985: 1984:C discharge) 1970:C discharge) 1961: 1959: 1956: 1953: 1950: 1946: 1942: 1938: 1935: 1934: 1930: 1928: 1900: 1898: 1895: 1892: 1889: 1887: 1886: 1882: 1878: 1867: 1864: 1861: 1846: 1844: 1843: 1839: 1838:vulcanization 1835: 1828: 1826: 1823: 1820: 1817: 1816:Copolymerized 1814: 1812: 1811: 1807: 1804: 1801: 1798: 1795: 1792: 1791: 1787: 1776: 1773: 1770: 1767: 1764: 1763: 1759: 1755: 1744: 1742: 1739: 1736: 1733: 1731:Lithium metal 1730: 1729: 1725: 1721: 1717: 1706: 1704: 1701: 1698: 1695: 1692: 1690:Lithium metal 1689: 1688: 1684: 1681: 1678: 1675: 1672: 1669: 1668: 1657: 1655: 1651: 1647: 1643: 1639: 1629: 1627: 1623: 1619: 1609: 1603: 1599: 1595: 1591: 1587: 1583: 1579: 1575: 1571: 1566: 1562: 1551: 1544: 1508: 1504: 1500: 1495: 1493: 1486: 1483: 1476: 1468: 1451: 1447: 1433: 1420: 1410: 1403: 1400: 1397: 1389: 1387: 1358: 1352: 1343: 1310: 1306: 1294: 1288: 1277: 1271: 1269: 1137: 1136: 1135: 1133: 1129: 1027: 1026: 1025: 1023: 1018: 968: 959: 943: 937: 926: 913: 900: 899: 898: 897: 896: 871: 858: 849: 836: 830: 819: 806: 805: 804: 803: 802: 782: 779: 776: 768: 748: 735: 724: 713: 700: 679: 673: 662: 649: 636: 616: 603: 588: 582: 571: 558: 557: 556: 555: 554: 552: 547: 513: 492: 481: 463: 454: 451: 446: 437: 434: 423: 422: 421: 415: 403: 393: 391: 369: 361: 356: 335: 324: 300: 299: 298: 296: 295:half-reaction 292: 282: 280: 276: 273: 270: 266: 256: 253: 248: 245: 240: 237: 231: 227: 224: 219: 217: 213: 209: 205: 201: 197: 186: 183: 179: 174: 172: 161: 157: 151: 147: 140: 136: 132: 127: 125: 121: 120:solar-powered 117: 113: 109: 108:atomic weight 105: 101: 97: 79: 75: 71: 67: 63: 59: 55: 52:550 Wh/L 51: 49: 45: 41: 39: 35: 28: 23: 5417:. 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Index


Specific energy
Energy density
voltage
rechargeable battery
specific energy
atomic weight
lithium
sulfur
solar-powered
Zephyr 6
lithium-ion
sulfur
lithium-ion batteries
Wh
kg
Zeta Energy
University of Maryland, College Park
Pacific Northwest National Laboratory
aliphatic
amines
PC
DMSO
DMF
DOL
Manthiram
Kevlar
Drexel University
UC San Diego
anode

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