Knowledge

Diatomic molecule

Source đź“ť

1731:. It is also convenient, and common, to represent a diatomic molecule as two-point masses connected by a massless spring. The energies involved in the various motions of the molecule can then be broken down into three categories: the translational, rotational, and vibrational energies. The theoretical study of the rotational energy levels of the diatomic molecules can be described using the below description of the rotational energy levels. While the study of vibrational energy level of the diatomic molecules can be described using the harmonic oscillator approximation or using the quantum vibrational interaction potentials. These potentials give more accurate energy levels because they take multiple vibrational effects into account. 4034: 113: 5263: 4016: 5227: 3557: 453:'s original atomic hypothesis assumed that all elements were monatomic and that the atoms in compounds would normally have the simplest atomic ratios with respect to one another. For example, Dalton assumed water's formula to be HO, giving the atomic weight of oxygen as eight times that of hydrogen, instead of the modern value of about 16. As a consequence, confusion existed regarding atomic weights and molecular formulas for about half a century. 22: 4025: 5251: 5239: 600:, etc. (but this convention is not always followed, and sometimes lower case letters and alphabetically out-of-sequence letters are used, as in the example given below). The excitation energy must be greater than or equal to the energy of the electronic state in order for the excitation to occur. 527:
state. When a gas of diatomic molecules is bombarded by energetic electrons, some of the molecules may be excited to higher electronic states, as occurs, for example, in the natural aurora; high-altitude nuclear explosions; and rocket-borne electron gun experiments. Such excitation can also occur
1501:
emission bands (a.k.a. Vegard-Kaplan bands) are present in the spectral range from 0.14 to 1.45 ÎĽm (micrometres). A given band can be spread out over several nanometers in electromagnetic wavelength space, owing to the various transitions that occur in the molecule's rotational quantum number,
528:
when the gas absorbs light or other electromagnetic radiation. The excited states are unstable and naturally relax back to the ground state. Over various short time scales after the excitation (typically a fraction of a second, or sometimes longer than a second if the excited state is
2882: 1458:": each band corresponds to a particular transition from a higher electronic state and vibrational level to a lower electronic state and vibrational level (typically, many vibrational levels are involved in an excited gas of diatomic molecules). For example, N 448:
Diatomic elements played an important role in the elucidation of the concepts of element, atom, and molecule in the 19th century, because some of the most common elements, such as hydrogen, oxygen, and nitrogen, occur as diatomic molecules.
2488: 2351: 2910: 1430:
The "energy" units here are actually the reciprocal of the wavelength of a photon emitted in a transition to the lowest energy state. The actual energy can be found by multiplying the given statistic by the product of
2855: 3234: 487:
resurrected Avogadro's ideas and used them to produce a consistent table of atomic weights, which mostly agree with modern values. These weights were an important prerequisite for the discovery of the
1804: 1913: 440:
or distance between the two atoms. Diatomic nitrogen has a triple bond, diatomic oxygen has a double bond, and diatomic hydrogen, fluorine, chlorine, iodine, and bromine all have single bonds.
2040: 688: 1326: 1273: 1134: 1086: 2139: 1412: 1220: 1369: 1177: 472:
and the assumption of diatomic elemental molecules. However, these results were mostly ignored until 1860, partly due to the belief that atoms of one element would have no
2579:
The spacing, and the energy of a typical spectroscopic transition, between vibrational energy levels is about 100 times greater than that of a typical transition between
1644: 1592: 4576: 4346: 4306: 3798: 1693: 2379: 884: 833:,.... For example, the following table lists the common electronic states (without vibrational quantum numbers) along with the energy of the lowest vibrational level ( 771: 731: 476:
toward atoms of the same element, and also partly due to apparent exceptions to Avogadro's law that were not explained until later in terms of dissociating molecules.
2562: 2220: 2200: 831: 791: 4507: 4482: 4472: 2536: 2166: 2084: 2064: 1040: 966:
applies to molecules of identical atoms, and when reflecting the state along a plane perpendicular to the molecular axis, states that does not change are labelled
811: 1966: 1940: 857: 2514: 1847: 1827: 1664: 1612: 1560: 1540: 1520: 1499: 1479: 1004: 984: 964: 944: 924: 904: 751: 711: 598: 578: 558: 525: 4878: 4206: 4147: 4055: 4967: 4783: 4718: 4658: 4586: 4492: 4386: 4256: 4211: 3882: 277:
Other elements form diatomic molecules when evaporated, but these diatomic species repolymerize when cooled. Heating ("cracking") elemental phosphorus gives
5047: 4512: 4356: 4326: 237:. The homonuclear diatomic gases and noble gases together are called "elemental gases" or "molecular gases", to distinguish them from other gases that are 4442: 4422: 4095: 4467: 2625:, pronounced "Hofbrinkle", have been coined to aid recall of the list of diatomic elements. Another method, for English-speakers, is the sentence: " 4105: 3807: 4462: 3791: 3537: 2986: 2941: 4132: 3542: 3521: 3319: 4678: 4075: 3051:"Temperature guided behavioral transitions in confined helium: Gas-wall interaction effects on dynamics and transport in the cryogenic limit" 4226: 3495: 4137: 3593: 2937:"Franck-Condon Factors, r-Centroids, Electronic Transition Moments, and Einstein Coefficients for Many Nitrogen and Oxygen Band Systems" 1723:
is a shorthand expression of the angular momenta that characterize the electronic quantum states of a diatomic molecule, which are also
3784: 926:
determines whether reflection in a plane containing the internuclear axis introduces a sign change in the wavefunction. The sub-script
5005: 4321: 3485: 2601:
for a diatomic molecule, as well as good approximations of rotational energy levels, can be obtained by modeling the molecule using
3511: 3469: 3433: 1439:(Planck's constant); i.e., about 1.99 Ă— 10 Joule-metres, and then multiplying by a further factor of 100 to convert from cm to m. 532:), transitions occur from higher to lower electronic states and ultimately to the ground state, and in each transition results a 409: 4537: 4296: 4216: 2689: 3464: 3386: 2810: 4918: 3490: 3443: 1756: 3011: 2966: 1865: 3438: 1978:
For microscopic, atomic-level systems like a molecule, angular momentum can only have specific discrete values given by
5170: 3381: 3312: 1986: 612: 400:
at room temperature, but they form diatomic molecules when evaporated, for example gaseous MgO, SiO, and many others.
5070: 3253: 3214: 3034: 2865: 2835: 2742: 2715: 133: 3417: 5195: 3586: 3516: 1728: 428:
is the most abundant diatomic molecule in the universe. The interstellar medium is dominated by hydrogen atoms.
3407: 2638: 408:
Hundreds of diatomic molecules have been identified in the environment of the Earth, in the laboratory, and in
3182: 3084:"Morse potential specific bond volume: a simple formula with applications to dimers and soft–hard slab slider" 5120: 3459: 3305: 2758:
Lu, Z.W.; Wang, Q.; He, W.M.; Ma, Z.G. (July 1996). "New parametric emissions in diatomic sodium molecules".
416:
is composed of two species of diatomic molecules: nitrogen (78%) and oxygen (21%). The natural abundance of
5155: 1284: 1231: 507:
Diatomic molecules are normally in their lowest or ground state, which conventionally is also known as the
1097: 1049: 5298: 5288: 4351: 3560: 3391: 3291: 2368: 5293: 3579: 2102: 1380: 1188: 5110: 5105: 4286: 3412: 3360: 3273: 2730: 5303: 5150: 1451: 1337: 1145: 2982:"Improved Fits for the Vibrational and Rotational Constants of Many States of Nitrogen and Oxygen" 5230: 3365: 3204: 2539: 2483:{\displaystyle E_{\text{vib}}=\left(n+{\frac {1}{2}}\right)\hbar \omega \ \ \ \ \ n=0,1,2,....\,} 2087: 1734:
Concerning history, the first treatment of diatomic molecules with quantum mechanics was made by
1617: 1565: 2346:{\displaystyle E_{\text{rot}}={\frac {l(l+1)\hbar ^{2}}{2\mu r_{0}^{2}}}\ \ \ \ \ l=0,1,2,...\,} 1669: 5085: 4050: 3960: 3837: 3832: 3279: 461: 371: 102: 2732: 869: 756: 716: 468:
had arrived at the correct interpretation of water's composition, based on what is now called
266:) also form diatomic gases. All halogens have been observed as diatomic molecules, except for 5140: 5115: 4753: 4371: 3918: 3131:
Mensing, Lucy (1 November 1926). "Die Rotations-Schwingungsbanden nach der Quantenmechanik".
2547: 2177: 1720: 1708: 816: 776: 604: 464:
showed that water is formed of two volumes of hydrogen and one volume of oxygen, and by 1811
413: 2521: 2367:—along the line connecting the two atoms. The vibrational energy is approximately that of a 2150: 2069: 5201: 5185: 4810: 4181: 4152: 4033: 3857: 3140: 3095: 2995: 2950: 2894: 2767: 2049: 1018: 121: 82: 2629:" as a representation of Nitrogen, Hydrogen, Fluorine, Oxygen, Iodine, Chlorine, Bromine. 796: 8: 5145: 5125: 4938: 4628: 4116: 3980: 3955: 3923: 3842: 3344: 2598: 1950: 1924: 1696: 836: 733:
is the total electronic angular momentum quantum number along the internuclear axis, and
26: 3144: 3099: 2999: 2954: 2898: 2771: 5243: 5165: 5135: 5080: 4957: 4933: 4432: 4366: 4231: 4191: 4042: 4005: 3965: 3944: 3887: 3862: 3328: 3164: 2851: 2783: 2499: 1832: 1812: 1649: 1597: 1545: 1525: 1505: 1484: 1464: 989: 969: 949: 929: 909: 889: 886:
give additional quantum mechanical details about the electronic state. The superscript
736: 696: 583: 563: 543: 510: 480: 436:
All diatomic molecules are linear and characterized by a single parameter which is the
5190: 4773: 4673: 4643: 4561: 4301: 4186: 4142: 4090: 3897: 3892: 3249: 3210: 3168: 3156: 3113: 3030: 2861: 2831: 2806: 2787: 2738: 2711: 2648: 2580: 2565: 1969: 1455: 473: 469: 386: 367: 238: 3776: 2678: 773:
takes on values 0, 1, 2, ..., which are represented by the electronic state symbols
603:
In quantum theory, an electronic state of a diatomic molecule is represented by the
112: 5267: 5255: 5175: 5075: 4980: 4928: 4361: 4236: 4201: 4122: 4110: 4070: 3975: 3908: 3605: 3148: 3103: 3062: 3003: 2958: 2902: 2775: 2731:
Whitten, Kenneth W.; Davis, Raymond E.; Peck, M. Larry; Stanley, George G. (2010).
1943: 1522:. These are classified into distinct sub-band branches, depending on the change in 492: 129: 56: 4863: 4838: 4376: 4316: 4100: 4000: 3985: 3970: 3877: 3867: 3721: 2602: 2592: 465: 393: 378: 86: 2981: 2936: 2574: 5100: 5065: 4848: 4738: 4703: 4688: 4623: 4618: 4517: 4417: 4336: 4311: 4276: 4221: 4196: 4065: 3913: 3108: 3083: 3067: 3050: 2658: 2363:
Another type of motion of a diatomic molecule is for each atom to oscillate—or
1747: 137: 117: 40: 5282: 5130: 4985: 4868: 4843: 4824: 4768: 4648: 4606: 4601: 4341: 4331: 4291: 4166: 4060: 4015: 3990: 3872: 3852: 3571: 3236:
Molecular Spectra and Molecular Structure IV. Constants of Diatomic Molecules
3160: 2803:
Molecular Spectra and Molecular Structure IV. Constants of Diatomic Molecules
2653: 2202:
is the average distance between the centers of the two atoms in the molecule.
529: 344: 85:. Otherwise, if a diatomic molecule consists of two different atoms, such as 59:. If a diatomic molecule consists of two atoms of the same element, such as 5206: 5060: 4913: 4853: 4833: 4805: 4733: 4613: 4596: 4551: 4502: 4407: 4127: 4080: 3928: 3731: 3701: 3339: 3117: 2169: 1735: 1700: 1447: 537: 496: 488: 382: 278: 94: 424:
in the Earth's atmosphere is only of the order of parts per million, but H
5180: 5090: 5055: 5022: 4948: 4923: 4763: 4668: 4638: 4522: 4437: 4427: 4157: 4085: 450: 437: 5095: 5037: 5000: 4975: 4873: 4683: 4546: 3761: 3152: 2779: 2643: 1724: 484: 457: 348: 333: 271: 2621:, pronounced "Honkelbrif", “HOBrFINCl”, pronounced “Hoberfinkel”, and 5027: 4892: 4728: 4532: 4412: 4266: 4241: 3751: 3297: 3007: 2962: 2906: 2364: 300: 234: 206: 106: 2212:, the rotational energy levels of a diatomic molecule are given by: 21: 4995: 4907: 4708: 4571: 4556: 4527: 4396: 4171: 3995: 3939: 3933: 3902: 3847: 3815: 3741: 3660: 3650: 3630: 3620: 1704: 417: 322: 311: 289: 267: 181: 170: 152: 60: 48: 2208:
So, substituting the angular momentum and moment of inertia into E
5160: 4990: 4943: 4902: 4858: 4800: 4795: 4758: 4748: 4743: 4698: 4693: 4633: 4566: 4457: 4452: 4402: 4281: 4271: 4024: 3711: 3670: 2737:(9th ed.). Brooks/Cole, Cengage Learning. pp. 337–338. 540:. Successively higher electronic states are conventionally named 397: 245: 222: 192: 5211: 5032: 5014: 4477: 4447: 3949: 3680: 3640: 2679:"Section 4: Properties of the Elements and Inorganic Compounds" 533: 256: 210: 71: 2935:
Gilmore, Forrest R.; Laher, Russ R.; Espy, Patrick J. (1992).
4246: 4176: 2575:
Comparison between rotational and vibrational energy spacings
370:
of two different elements. Many elements can combine to form
230: 226: 218: 374:
diatomic molecules, depending on temperature and pressure.
214: 52: 3183:"Mnemonic BrINClHOF (pronounced Brinklehoff) in Chemistry" 3285: 1746:
The translational energy of the molecule is given by the
141: 3232: 2800: 2094:
Also, for a diatomic molecule the moment of inertia is
124:
diatomic molecules under typical laboratory conditions.
1707:. The spectral resolution depends on the instrument's 396:
are not normally considered diatomic because they are
3806: 2550: 2524: 2502: 2382: 2223: 2180: 2153: 2105: 2072: 2052: 1989: 1953: 1927: 1868: 1835: 1815: 1799:{\displaystyle E_{\text{trans}}={\frac {1}{2}}mv^{2}} 1759: 1672: 1652: 1620: 1600: 1568: 1548: 1528: 1508: 1487: 1467: 1383: 1340: 1287: 1234: 1191: 1148: 1100: 1052: 1021: 992: 972: 952: 932: 912: 892: 872: 863:), the most abundant gas in the Earth's atmosphere. 839: 819: 799: 779: 759: 739: 719: 699: 615: 586: 566: 546: 513: 2883:"The Karlsruhe Congress: A centennial retrospective" 1908:{\displaystyle E_{\text{rot}}={\frac {L^{2}}{2I}}\,} 1695:. Bands are spread out even further by the limited 986:(gerade), and states that change sign are labelled 132:that form stable homonuclear diatomic molecules at 2556: 2530: 2508: 2482: 2345: 2194: 2160: 2133: 2078: 2058: 2034: 1960: 1934: 1907: 1841: 1821: 1798: 1687: 1658: 1638: 1606: 1586: 1554: 1534: 1514: 1493: 1473: 1406: 1363: 1320: 1267: 1214: 1171: 1128: 1080: 1034: 998: 978: 958: 938: 918: 898: 878: 851: 825: 805: 785: 765: 745: 725: 705: 682: 592: 572: 552: 519: 2830:(2nd ed.). Prentice Hall. pp. 123–125. 105:. The bond in a homonuclear diatomic molecule is 5280: 2934: 2035:{\displaystyle L^{2}=\ell (\ell +1)\hbar ^{2}\,} 683:{\displaystyle ^{2S+1}\Lambda (v)_{(g/u)}^{+/-}} 244:At slightly elevated temperatures, the halogens 136:(STP) (or at typical laboratory conditions of 1 3294:– Indiana University Molecular Structure Center 2987:Journal of Physical and Chemical Reference Data 2942:Journal of Physical and Chemical Reference Data 1857:Classically, the kinetic energy of rotation is 3601: 2880: 3792: 3587: 3313: 3276:– Rotational Spectra of Rigid Rotor Molecules 2930: 2928: 2850: 713:is the total electronic spin quantum number, 3246:Physics For Scientists and Engineers: Vol. 1 3243: 3055:Chemical Thermodynamics and Thermal Analysis 2980:Laher, Russ R.; Gilmore, Forrest R. (1991). 2979: 502: 2710:. Oxford: Clarendon Press. pp. 22–23. 3799: 3785: 3594: 3580: 3320: 3306: 3018: 2925: 2757: 443: 361: 3288:– Chemistry, Structures, and 3D Molecules 3107: 3066: 3029:, John Wiley & Sons, pp. 508–9, 2973: 2825: 2479: 2342: 2191: 2157: 2130: 2031: 1957: 1931: 1904: 1741: 3081: 3075: 2854:; Beebe, Ralph Alonzo (1 January 1995). 2724: 111: 20: 3202: 3196: 3130: 2676: 2358: 5281: 3327: 3048: 3024: 2857:The Development of Chemical Principles 2705: 2695:from the original on 11 November 2011. 1852: 866:The subscripts and superscripts after 536:is emitted. This emission is known as 233:) are also gases at STP, but they are 29:of the diatomic molecule dinitrogen, N 3780: 3575: 3301: 3042: 1321:{\displaystyle a'^{1}\Sigma _{u}^{-}} 1268:{\displaystyle B'^{3}\Sigma _{u}^{-}} 431: 3088:Journal of Physics: Condensed Matter 2805:. New York: Van Nostrand: Reinhold. 1129:{\displaystyle A^{3}\Sigma _{u}^{+}} 1081:{\displaystyle X^{1}\Sigma _{g}^{+}} 3239:. New York: Van Nostrand: Reinhold. 3233:Huber, K. P.; Herzberg, G. (1979). 2801:Huber, K. P.; Herzberg, G. (1979). 753:is the vibrational quantum number. 120:showing the elements that exist as 13: 5171:Nexus for Exoplanet System Science 3226: 2826:Brown, Catrin; Ford, Mike (2014). 1673: 1621: 1569: 1450:occurs in distinct regions of the 1395: 1352: 1304: 1251: 1203: 1160: 1112: 1064: 873: 820: 800: 780: 760: 720: 634: 16:Molecule composed of any two atoms 14: 5315: 5071:Atomic and molecular astrophysics 3808:Molecules detected in outer space 3267: 3014:from the original on 2 June 2018. 2969:from the original on 9 July 2017. 2686:Handbook of Chemistry and Physics 2422: 2134:{\displaystyle I=\mu r_{0}^{2}\,} 366:All other diatomic molecules are 134:standard temperature and pressure 5261: 5249: 5237: 5226: 5225: 4032: 4023: 4014: 3556: 3555: 3206:Chemistry and Our Changing World 2627:Never Have Fear of Ice Cold Beer 1829:is the mass of the molecule and 1714: 1407:{\displaystyle w^{1}\Delta _{u}} 1215:{\displaystyle W^{3}\Delta _{u}} 321:) are known in the gas phase. Di 5196:Polycyclic aromatic hydrocarbon 3248:(4th ed.). W. H. Freeman. 3175: 3124: 2586: 1424: 2874: 2844: 2819: 2794: 2751: 2699: 2670: 2639:Symmetry of diatomic molecules 2255: 2243: 2066:is a non-negative integer and 2018: 2006: 662: 648: 644: 637: 101:), the molecule is said to be 1: 5121:Extraterrestrial liquid water 3282:– Quantum Harmonic Oscillator 3209:. Prentice Hall. p. 82. 2887:Journal of Chemical Education 2664: 1364:{\displaystyle a^{1}\Pi _{g}} 1172:{\displaystyle B^{3}\Pi _{g}} 403: 3538:Tricapped trigonal prismatic 2608: 1727:of the electronic molecular 1703:that is used to measure the 7: 4352:Protonated hydrogen cyanide 3543:Capped square antiprismatic 3522:Bicapped trigonal prismatic 2632: 2617:, pronounced "Brinklehof", 2369:quantum harmonic oscillator 1639:{\displaystyle \Delta J=-1} 1587:{\displaystyle \Delta J=+1} 55:, of the same or different 10: 5320: 3068:10.1016/j.ctta.2022.100073 2590: 1688:{\displaystyle \Delta J=0} 288:). Sulfur vapor is mostly 5220: 5111:Earliest known life forms 5106:Diffuse interstellar band 5046: 4966: 4891: 4782: 4717: 4657: 4585: 4577:Protonated cyanoacetylene 4491: 4385: 4347:Protonated carbon dioxide 4307:Hydromagnesium isocyanide 4255: 4041: 4012: 3823: 3814: 3693: 3612: 3551: 3530: 3504: 3496:Capped trigonal prismatic 3478: 3452: 3426: 3400: 3374: 3353: 3335: 3082:Al-Raeei, Marwan (2022). 1435:(the speed of light) and 859:) of diatomic nitrogen (N 503:Excited electronic states 81:), then it is said to be 5156:Iron–sulfur world theory 5151:Photodissociation region 4854:Methyl-cyano-diacetylene 3109:10.1088/1361-648X/ac6a9b 2828:Standard Level Chemistry 1452:electromagnetic spectrum 879:{\displaystyle \Lambda } 766:{\displaystyle \Lambda } 726:{\displaystyle \Lambda } 140:and 25 Â°C) are the 5231:Category:Astrochemistry 4821:, fullerene, buckyball) 4508:Cyanobutadiynyl radical 4483:Silicon-carbide cluster 4473:Protonated formaldehyde 3025:Levine, Ira N. (1975), 2881:Ihde, Aaron J. (1961). 2860:. Courier Corporation. 2852:Langford, Cooper Harold 2557:{\displaystyle \omega } 2540:reduced Planck constant 2195:{\displaystyle r_{0}\,} 2088:reduced Planck constant 826:{\displaystyle \Delta } 786:{\displaystyle \Sigma } 444:Historical significance 362:Heteronuclear molecules 274:, which are uncertain. 5244:Outer space portal 5086:Circumstellar envelope 4051:Aluminium(I) hydroxide 3961:Phosphorus mononitride 3838:Aluminium monofluoride 3833:Aluminium monochloride 3486:Pentagonal bipyramidal 3203:Sherman, Alan (1992). 3133:Zeitschrift fĂĽr Physik 3049:Mishra, Swati (2022). 3027:Molecular Spectroscopy 2677:Hammond, C.R. (2012). 2558: 2532: 2531:{\displaystyle \hbar } 2510: 2484: 2347: 2196: 2162: 2161:{\displaystyle \mu \,} 2135: 2080: 2079:{\displaystyle \hbar } 2060: 2036: 1962: 1936: 1909: 1843: 1823: 1800: 1742:Translational energies 1689: 1660: 1640: 1608: 1588: 1562:branch corresponds to 1556: 1536: 1516: 1495: 1475: 1408: 1365: 1322: 1269: 1216: 1173: 1130: 1082: 1036: 1000: 980: 960: 940: 920: 900: 880: 853: 827: 807: 787: 767: 747: 727: 707: 684: 594: 574: 554: 521: 125: 33: 5141:Interplanetary medium 5116:Extraterrestrial life 4754:Octatetraynyl radical 4372:Tricarbon monosulfide 3919:Magnesium monohydride 3531:Coordination number 9 3505:Coordination number 8 3479:Coordination number 7 3453:Coordination number 6 3427:Coordination number 5 3401:Coordination number 4 3375:Coordination number 3 3354:Coordination number 2 3244:Tipler, Paul (1998). 2559: 2533: 2511: 2485: 2348: 2197: 2163: 2136: 2081: 2061: 2059:{\displaystyle \ell } 2037: 1963: 1937: 1910: 1844: 1824: 1801: 1721:molecular term symbol 1709:point spread function 1690: 1661: 1641: 1609: 1589: 1557: 1537: 1517: 1496: 1476: 1409: 1366: 1323: 1270: 1217: 1174: 1131: 1083: 1037: 1035:{\displaystyle T_{0}} 1001: 981: 961: 941: 921: 901: 881: 854: 828: 808: 788: 768: 748: 728: 708: 685: 605:molecular term symbol 595: 575: 555: 522: 115: 51:composed of only two 24: 5268:Chemistry portal 5256:Astronomy portal 5202:RNA world hypothesis 5186:PAH world hypothesis 4879:Heptatrienyl radical 4811:Buckminsterfullerene 4699:Methylcyanoacetylene 4207:Silicon carbonitride 4182:Methylidynephosphane 4148:Magnesium isocyanide 4056:Aluminium isocyanide 3858:Carbon monophosphide 3512:Square antiprismatic 3470:Pentagonal pyramidal 3434:Trigonal bipyramidal 2913:on 28 September 2007 2599:good quantum numbers 2548: 2522: 2500: 2380: 2359:Vibrational energies 2221: 2178: 2151: 2103: 2070: 2050: 1987: 1951: 1925: 1866: 1833: 1813: 1757: 1670: 1650: 1618: 1598: 1566: 1546: 1526: 1506: 1485: 1465: 1381: 1338: 1285: 1232: 1189: 1146: 1098: 1050: 1019: 990: 970: 950: 930: 910: 890: 870: 837: 817: 806:{\displaystyle \Pi } 797: 777: 757: 737: 717: 697: 613: 584: 564: 544: 511: 5146:Interstellar medium 5126:Forbidden mechanism 4939:Hydrogen isocyanide 4629:Hexatriynyl radical 4212:c-Silicon dicarbide 4117:Hydrogen isocyanide 3981:Silicon monosulfide 3956:Phosphorus monoxide 3924:Methylidyne radical 3883:Fluoromethylidynium 3843:Aluminium(II) oxide 3345:Coordination number 3145:1926ZPhy...36..814M 3100:2022JPCM...34B4001A 3000:1991JPCRD..20..685L 2955:1992JPCRD..21.1005G 2899:1961JChEd..38...83I 2772:1996ApPhB..63...43L 2706:Emsley, J. (1989). 2290: 2172:of the molecule and 2129: 1961:{\displaystyle I\,} 1935:{\displaystyle L\,} 1853:Rotational energies 1697:spectral resolution 1446:The aforementioned 1317: 1264: 1125: 1077: 852:{\displaystyle v=0} 679: 483:on atomic weights, 412:. About 99% of the 377:Examples are gases 27:space-filling model 5299:Molecular geometry 5289:Diatomic molecules 5166:Molecules in stars 5136:Intergalactic dust 5081:Circumstellar dust 5023:Naphthalene cation 4958:Trihydrogen cation 4934:Hydrogen deuteride 4859:Methyltriacetylene 4694:Hexapentaenylidene 4513:E-Cyanomethanimine 4433:Cyclopropenylidene 4367:Tricarbon monoxide 4357:Silicon tricarbide 4327:Methylene amidogen 4317:Isothiocyanic acid 4232:Thioxoethenylidene 4192:Trihydrogen cation 4006:Titanium(II) oxide 3966:Potassium chloride 3945:Sulfur mononitride 3888:Helium hydride ion 3863:Carbon monosulfide 3465:Trigonal prismatic 3387:Trigonal pyramidal 3329:Molecular geometry 3153:10.1007/BF01400216 3061:(August): 100073. 2780:10.1007/BF01112836 2554: 2528: 2506: 2480: 2343: 2276: 2192: 2158: 2131: 2115: 2076: 2056: 2032: 1958: 1932: 1905: 1839: 1819: 1796: 1685: 1656: 1636: 1604: 1584: 1552: 1532: 1512: 1491: 1471: 1404: 1361: 1318: 1303: 1265: 1250: 1212: 1169: 1126: 1111: 1078: 1063: 1032: 996: 976: 956: 936: 916: 896: 876: 849: 823: 803: 783: 763: 743: 723: 703: 680: 643: 590: 570: 550: 517: 481:Karlsruhe Congress 456:As early as 1805, 432:Molecular geometry 414:Earth's atmosphere 410:interstellar space 368:chemical compounds 347:in the gas phase. 239:chemical compounds 191:), and the liquid 126: 37:Diatomic molecules 34: 5294:General chemistry 5276: 5275: 5191:Pseudo-panspermia 4887: 4886: 4834:Cyanodecapentayne 4774:N-Methylformamide 4749:Methyldiacetylene 4674:Aminoacetonitrile 4644:Methyl isocyanate 4562:Methyl isocyanide 4443:Isocyanoacetylene 4423:Cyanoformaldehyde 4302:Hydrogen peroxide 4187:Potassium cyanide 4143:Magnesium cyanide 4096:Disilicon carbide 4091:Dicarbon monoxide 3898:Hydrogen fluoride 3893:Hydrogen chloride 3774: 3773: 3606:chemical elements 3569: 3568: 3491:Capped octahedral 3444:Pentagonal planar 2812:978-0-442-23394-5 2760:Applied Physics B 2649:Octatomic element 2581:rotational energy 2568:of the vibration. 2566:angular frequency 2509:{\displaystyle n} 2442: 2439: 2436: 2433: 2430: 2415: 2390: 2308: 2305: 2302: 2299: 2296: 2292: 2231: 1970:moment of inertia 1902: 1876: 1849:is its velocity. 1842:{\displaystyle v} 1822:{\displaystyle m} 1781: 1767: 1659:{\displaystyle Q} 1607:{\displaystyle P} 1555:{\displaystyle R} 1535:{\displaystyle J} 1515:{\displaystyle J} 1494:{\displaystyle X} 1474:{\displaystyle A} 1420: 1419: 999:{\displaystyle u} 979:{\displaystyle g} 959:{\displaystyle u} 939:{\displaystyle g} 919:{\displaystyle -} 899:{\displaystyle +} 746:{\displaystyle v} 706:{\displaystyle S} 593:{\displaystyle C} 573:{\displaystyle B} 553:{\displaystyle A} 520:{\displaystyle X} 474:chemical affinity 387:hydrogen chloride 130:chemical elements 57:chemical elements 47: 'two') are 5311: 5266: 5265: 5264: 5254: 5253: 5252: 5242: 5241: 5240: 5229: 5228: 5176:Organic compound 5076:Chemical formula 4981:Dihydroxyacetone 4929:Hydrogen cyanide 4614:Cyanodiacetylene 4468:Propadienylidene 4362:Thioformaldehyde 4237:Titanium dioxide 4202:Sodium hydroxide 4123:Hydrogen sulfide 4111:Hydrogen cyanide 4071:Carbonyl sulfide 4036: 4027: 4018: 3976:Silicon monoxide 3909:Hydroxyl radical 3821: 3820: 3801: 3794: 3787: 3778: 3777: 3767: 3757: 3747: 3737: 3727: 3717: 3707: 3686: 3676: 3666: 3656: 3646: 3636: 3626: 3596: 3589: 3582: 3573: 3572: 3559: 3558: 3439:Square pyramidal 3322: 3315: 3308: 3299: 3298: 3259: 3240: 3221: 3220: 3200: 3194: 3193: 3191: 3189: 3179: 3173: 3172: 3128: 3122: 3121: 3111: 3079: 3073: 3072: 3070: 3046: 3040: 3039: 3022: 3016: 3015: 3008:10.1063/1.555892 2977: 2971: 2970: 2963:10.1063/1.555910 2949:(5): 1005–1107. 2932: 2923: 2922: 2920: 2918: 2909:. Archived from 2907:10.1021/ed038p83 2878: 2872: 2871: 2848: 2842: 2841: 2823: 2817: 2816: 2798: 2792: 2791: 2755: 2749: 2748: 2728: 2722: 2721: 2703: 2697: 2696: 2694: 2683: 2674: 2563: 2561: 2560: 2555: 2537: 2535: 2534: 2529: 2515: 2513: 2512: 2507: 2489: 2487: 2486: 2481: 2440: 2437: 2434: 2431: 2428: 2421: 2417: 2416: 2408: 2392: 2391: 2388: 2352: 2350: 2349: 2344: 2306: 2303: 2300: 2297: 2294: 2293: 2291: 2289: 2284: 2268: 2267: 2266: 2238: 2233: 2232: 2229: 2201: 2199: 2198: 2193: 2190: 2189: 2167: 2165: 2164: 2159: 2140: 2138: 2137: 2132: 2128: 2123: 2085: 2083: 2082: 2077: 2065: 2063: 2062: 2057: 2041: 2039: 2038: 2033: 2030: 2029: 1999: 1998: 1967: 1965: 1964: 1959: 1944:angular momentum 1941: 1939: 1938: 1933: 1914: 1912: 1911: 1906: 1903: 1901: 1893: 1892: 1883: 1878: 1877: 1874: 1848: 1846: 1845: 1840: 1828: 1826: 1825: 1820: 1805: 1803: 1802: 1797: 1795: 1794: 1782: 1774: 1769: 1768: 1765: 1694: 1692: 1691: 1686: 1665: 1663: 1662: 1657: 1645: 1643: 1642: 1637: 1613: 1611: 1610: 1605: 1593: 1591: 1590: 1585: 1561: 1559: 1558: 1553: 1541: 1539: 1538: 1533: 1521: 1519: 1518: 1513: 1500: 1498: 1497: 1492: 1480: 1478: 1477: 1472: 1440: 1428: 1413: 1411: 1410: 1405: 1403: 1402: 1393: 1392: 1370: 1368: 1367: 1362: 1360: 1359: 1350: 1349: 1327: 1325: 1324: 1319: 1316: 1311: 1302: 1301: 1300: 1274: 1272: 1271: 1266: 1263: 1258: 1249: 1248: 1247: 1221: 1219: 1218: 1213: 1211: 1210: 1201: 1200: 1178: 1176: 1175: 1170: 1168: 1167: 1158: 1157: 1135: 1133: 1132: 1127: 1124: 1119: 1110: 1109: 1087: 1085: 1084: 1079: 1076: 1071: 1062: 1061: 1041: 1039: 1038: 1033: 1031: 1030: 1009: 1008: 1005: 1003: 1002: 997: 985: 983: 982: 977: 965: 963: 962: 957: 945: 943: 942: 937: 925: 923: 922: 917: 905: 903: 902: 897: 885: 883: 882: 877: 858: 856: 855: 850: 832: 830: 829: 824: 812: 810: 809: 804: 792: 790: 789: 784: 772: 770: 769: 764: 752: 750: 749: 744: 732: 730: 729: 724: 712: 710: 709: 704: 689: 687: 686: 681: 678: 674: 665: 658: 633: 632: 599: 597: 596: 591: 579: 577: 576: 571: 559: 557: 556: 551: 526: 524: 523: 518: 493:Dmitri Mendeleev 394:binary compounds 357: 342: 331: 320: 309: 298: 287: 265: 254: 201: 190: 179: 168: 161: 150: 100: 92: 80: 69: 5319: 5318: 5314: 5313: 5312: 5310: 5309: 5308: 5304:Stereochemistry 5279: 5278: 5277: 5272: 5262: 5260: 5250: 5248: 5238: 5236: 5216: 5042: 5018: 5009: 4962: 4952: 4895: 4883: 4864:Propionaldehyde 4839:Ethylene glycol 4828: 4820: 4816: 4787: 4785: 4778: 4734:Cyanohexatriyne 4720: 4713: 4660: 4653: 4588: 4581: 4541: 4494: 4487: 4458:Methoxy radical 4388: 4381: 4377:Thiocyanic acid 4258: 4251: 4161: 4101:Ethynyl radical 4037: 4031: 4030: 4029: 4028: 4022: 4021: 4020: 4019: 4010: 4001:Sulfur monoxide 3986:Sodium chloride 3971:Silicon carbide 3878:Diatomic carbon 3868:Carbon monoxide 3810: 3805: 3775: 3770: 3765: 3760: 3755: 3750: 3745: 3740: 3735: 3730: 3725: 3720: 3715: 3710: 3705: 3700: 3689: 3684: 3679: 3674: 3669: 3664: 3659: 3654: 3649: 3644: 3639: 3634: 3629: 3624: 3619: 3608: 3600: 3570: 3565: 3547: 3526: 3500: 3474: 3448: 3422: 3396: 3382:Trigonal planar 3370: 3349: 3331: 3326: 3270: 3256: 3229: 3227:Further reading 3224: 3217: 3201: 3197: 3187: 3185: 3181: 3180: 3176: 3139:(11): 814–823. 3129: 3125: 3080: 3076: 3047: 3043: 3037: 3023: 3019: 2978: 2974: 2933: 2926: 2916: 2914: 2879: 2875: 2868: 2849: 2845: 2838: 2824: 2820: 2813: 2799: 2795: 2756: 2752: 2745: 2729: 2725: 2718: 2704: 2700: 2692: 2681: 2675: 2671: 2667: 2635: 2611: 2595: 2589: 2577: 2549: 2546: 2545: 2523: 2520: 2519: 2501: 2498: 2497: 2407: 2400: 2396: 2387: 2383: 2381: 2378: 2377: 2361: 2285: 2280: 2269: 2262: 2258: 2239: 2237: 2228: 2224: 2222: 2219: 2218: 2211: 2185: 2181: 2179: 2176: 2175: 2152: 2149: 2148: 2124: 2119: 2104: 2101: 2100: 2071: 2068: 2067: 2051: 2048: 2047: 2025: 2021: 1994: 1990: 1988: 1985: 1984: 1972:of the molecule 1952: 1949: 1948: 1926: 1923: 1922: 1894: 1888: 1884: 1882: 1873: 1869: 1867: 1864: 1863: 1855: 1834: 1831: 1830: 1814: 1811: 1810: 1790: 1786: 1773: 1764: 1760: 1758: 1755: 1754: 1744: 1717: 1671: 1668: 1667: 1651: 1648: 1647: 1619: 1616: 1615: 1599: 1596: 1595: 1567: 1564: 1563: 1547: 1544: 1543: 1527: 1524: 1523: 1507: 1504: 1503: 1486: 1483: 1482: 1466: 1463: 1462: 1461: 1444: 1443: 1429: 1425: 1398: 1394: 1388: 1384: 1382: 1379: 1378: 1355: 1351: 1345: 1341: 1339: 1336: 1335: 1312: 1307: 1296: 1292: 1288: 1286: 1283: 1282: 1259: 1254: 1243: 1239: 1235: 1233: 1230: 1229: 1206: 1202: 1196: 1192: 1190: 1187: 1186: 1163: 1159: 1153: 1149: 1147: 1144: 1143: 1120: 1115: 1105: 1101: 1099: 1096: 1095: 1072: 1067: 1057: 1053: 1051: 1048: 1047: 1026: 1022: 1020: 1017: 1016: 991: 988: 987: 971: 968: 967: 951: 948: 947: 931: 928: 927: 911: 908: 907: 891: 888: 887: 871: 868: 867: 862: 838: 835: 834: 818: 815: 814: 798: 795: 794: 778: 775: 774: 758: 755: 754: 738: 735: 734: 718: 715: 714: 698: 695: 694: 670: 666: 654: 647: 619: 616: 614: 611: 610: 585: 582: 581: 565: 562: 561: 545: 542: 541: 512: 509: 508: 505: 466:Amedeo Avogadro 446: 434: 427: 421: 406: 379:carbon monoxide 364: 358:) is diatomic. 356: 352: 341: 337: 330: 326: 319: 315: 308: 304: 297: 293: 286: 282: 264: 260: 253: 249: 200: 196: 189: 185: 178: 174: 167: 163: 160: 156: 149: 145: 98: 90: 87:carbon monoxide 79: 75: 68: 64: 32: 17: 12: 11: 5: 5317: 5307: 5306: 5301: 5296: 5291: 5274: 5273: 5271: 5270: 5258: 5246: 5234: 5221: 5218: 5217: 5215: 5214: 5209: 5204: 5199: 5193: 5188: 5183: 5178: 5173: 5168: 5163: 5158: 5153: 5148: 5143: 5138: 5133: 5128: 5123: 5118: 5113: 5108: 5103: 5101:Cosmochemistry 5098: 5093: 5088: 5083: 5078: 5073: 5068: 5066:Astrochemistry 5063: 5058: 5052: 5050: 5044: 5043: 5041: 5040: 5035: 5030: 5025: 5020: 5016: 5012: 5007: 5003: 4998: 4993: 4988: 4983: 4978: 4972: 4970: 4964: 4963: 4961: 4960: 4955: 4950: 4946: 4941: 4936: 4931: 4926: 4921: 4919:Formyl radical 4916: 4911: 4905: 4899: 4897: 4889: 4888: 4885: 4884: 4882: 4881: 4876: 4871: 4866: 4861: 4856: 4851: 4849:Methyl acetate 4846: 4841: 4836: 4831: 4826: 4822: 4818: 4814: 4808: 4803: 4798: 4792: 4790: 4780: 4779: 4777: 4776: 4771: 4766: 4761: 4756: 4751: 4746: 4741: 4739:Dimethyl ether 4736: 4731: 4725: 4723: 4715: 4714: 4712: 4711: 4706: 4704:Methyl formate 4701: 4696: 4691: 4689:Glycolaldehyde 4686: 4681: 4676: 4671: 4665: 4663: 4655: 4654: 4652: 4651: 4646: 4641: 4636: 4631: 4626: 4624:Glycolonitrile 4621: 4619:Ethylene oxide 4616: 4611: 4610: 4609: 4599: 4593: 4591: 4583: 4582: 4580: 4579: 4574: 4569: 4564: 4559: 4554: 4549: 4544: 4539: 4535: 4530: 4525: 4520: 4518:Cyclopropenone 4515: 4510: 4505: 4499: 4497: 4489: 4488: 4486: 4485: 4480: 4475: 4470: 4465: 4460: 4455: 4450: 4445: 4440: 4435: 4430: 4425: 4420: 4418:Cyanoacetylene 4415: 4410: 4405: 4400: 4393: 4391: 4383: 4382: 4380: 4379: 4374: 4369: 4364: 4359: 4354: 4349: 4344: 4339: 4337:Methyl radical 4334: 4329: 4324: 4319: 4314: 4312:Isocyanic acid 4309: 4304: 4299: 4294: 4289: 4284: 4279: 4277:Isocyanic acid 4274: 4269: 4263: 4261: 4253: 4252: 4250: 4249: 4244: 4239: 4234: 4229: 4224: 4222:Sulfur dioxide 4219: 4214: 4209: 4204: 4199: 4197:Sodium cyanide 4194: 4189: 4184: 4179: 4174: 4169: 4164: 4159: 4155: 4150: 4145: 4140: 4135: 4130: 4125: 4120: 4114: 4108: 4106:Formyl radical 4103: 4098: 4093: 4088: 4083: 4078: 4073: 4068: 4066:Carbon dioxide 4063: 4058: 4053: 4047: 4045: 4039: 4038: 4013: 4011: 4009: 4008: 4003: 3998: 3993: 3988: 3983: 3978: 3973: 3968: 3963: 3958: 3953: 3947: 3942: 3937: 3931: 3926: 3921: 3916: 3914:Iron(II) oxide 3911: 3906: 3900: 3895: 3890: 3885: 3880: 3875: 3870: 3865: 3860: 3855: 3850: 3845: 3840: 3835: 3829: 3827: 3818: 3812: 3811: 3804: 3803: 3796: 3789: 3781: 3772: 3771: 3769: 3768: 3763: 3758: 3753: 3748: 3743: 3738: 3733: 3728: 3723: 3718: 3713: 3708: 3703: 3697: 3695: 3691: 3690: 3688: 3687: 3682: 3677: 3672: 3667: 3662: 3657: 3652: 3647: 3642: 3637: 3632: 3627: 3622: 3616: 3614: 3610: 3609: 3599: 3598: 3591: 3584: 3576: 3567: 3566: 3564: 3563: 3552: 3549: 3548: 3546: 3545: 3540: 3534: 3532: 3528: 3527: 3525: 3524: 3519: 3514: 3508: 3506: 3502: 3501: 3499: 3498: 3493: 3488: 3482: 3480: 3476: 3475: 3473: 3472: 3467: 3462: 3456: 3454: 3450: 3449: 3447: 3446: 3441: 3436: 3430: 3428: 3424: 3423: 3421: 3420: 3415: 3410: 3404: 3402: 3398: 3397: 3395: 3394: 3389: 3384: 3378: 3376: 3372: 3371: 3369: 3368: 3363: 3357: 3355: 3351: 3350: 3348: 3347: 3342: 3336: 3333: 3332: 3325: 3324: 3317: 3310: 3302: 3296: 3295: 3289: 3283: 3277: 3269: 3268:External links 3266: 3265: 3264: 3262: 3260: 3254: 3241: 3228: 3225: 3223: 3222: 3215: 3195: 3174: 3123: 3094:(28): 284001. 3074: 3041: 3035: 3017: 2994:(4): 685–712. 2972: 2924: 2873: 2866: 2843: 2836: 2818: 2811: 2793: 2750: 2743: 2723: 2716: 2698: 2668: 2666: 2663: 2662: 2661: 2659:Industrial gas 2656: 2651: 2646: 2641: 2634: 2631: 2613:The mnemonics 2610: 2607: 2591:Main article: 2588: 2585: 2576: 2573: 2572: 2571: 2570: 2569: 2553: 2543: 2527: 2517: 2505: 2492: 2491: 2490: 2478: 2475: 2472: 2469: 2466: 2463: 2460: 2457: 2454: 2451: 2448: 2445: 2427: 2424: 2420: 2414: 2411: 2406: 2403: 2399: 2395: 2386: 2360: 2357: 2356: 2355: 2354: 2353: 2341: 2338: 2335: 2332: 2329: 2326: 2323: 2320: 2317: 2314: 2311: 2288: 2283: 2279: 2275: 2272: 2265: 2261: 2257: 2254: 2251: 2248: 2245: 2242: 2236: 2227: 2209: 2206: 2205: 2204: 2203: 2188: 2184: 2173: 2156: 2143: 2142: 2141: 2127: 2122: 2118: 2114: 2111: 2108: 2092: 2091: 2075: 2055: 2044: 2043: 2042: 2028: 2024: 2020: 2017: 2014: 2011: 2008: 2005: 2002: 1997: 1993: 1976: 1975: 1974: 1973: 1956: 1946: 1930: 1917: 1916: 1915: 1900: 1897: 1891: 1887: 1881: 1872: 1854: 1851: 1838: 1818: 1807: 1806: 1793: 1789: 1785: 1780: 1777: 1772: 1763: 1748:kinetic energy 1743: 1740: 1716: 1713: 1684: 1681: 1678: 1675: 1655: 1635: 1632: 1629: 1626: 1623: 1603: 1583: 1580: 1577: 1574: 1571: 1551: 1531: 1511: 1490: 1470: 1459: 1456:emission bands 1442: 1441: 1422: 1421: 1418: 1417: 1414: 1401: 1397: 1391: 1387: 1375: 1374: 1371: 1358: 1354: 1348: 1344: 1332: 1331: 1328: 1315: 1310: 1306: 1299: 1295: 1291: 1279: 1278: 1275: 1262: 1257: 1253: 1246: 1242: 1238: 1226: 1225: 1222: 1209: 1205: 1199: 1195: 1183: 1182: 1179: 1166: 1162: 1156: 1152: 1140: 1139: 1136: 1123: 1118: 1114: 1108: 1104: 1092: 1091: 1088: 1075: 1070: 1066: 1060: 1056: 1044: 1043: 1029: 1025: 1013: 995: 975: 955: 935: 915: 895: 875: 860: 848: 845: 842: 822: 802: 782: 762: 742: 722: 702: 691: 690: 677: 673: 669: 664: 661: 657: 653: 650: 646: 642: 639: 636: 631: 628: 625: 622: 618: 589: 569: 549: 516: 504: 501: 470:Avogadro's law 445: 442: 433: 430: 425: 419: 405: 402: 363: 360: 354: 345:sextuple bonds 339: 328: 317: 306: 295: 284: 262: 251: 198: 187: 176: 165: 158: 147: 118:periodic table 77: 66: 30: 15: 9: 6: 4: 3: 2: 5316: 5305: 5302: 5300: 5297: 5295: 5292: 5290: 5287: 5286: 5284: 5269: 5259: 5257: 5247: 5245: 5235: 5233: 5232: 5223: 5222: 5219: 5213: 5210: 5208: 5205: 5203: 5200: 5197: 5194: 5192: 5189: 5187: 5184: 5182: 5179: 5177: 5174: 5172: 5169: 5167: 5164: 5162: 5159: 5157: 5154: 5152: 5149: 5147: 5144: 5142: 5139: 5137: 5134: 5132: 5131:Homochirality 5129: 5127: 5124: 5122: 5119: 5117: 5114: 5112: 5109: 5107: 5104: 5102: 5099: 5097: 5094: 5092: 5089: 5087: 5084: 5082: 5079: 5077: 5074: 5072: 5069: 5067: 5064: 5062: 5059: 5057: 5054: 5053: 5051: 5049: 5045: 5039: 5036: 5034: 5031: 5029: 5026: 5024: 5021: 5019: 5013: 5011: 5004: 5002: 4999: 4997: 4994: 4992: 4989: 4987: 4986:Methoxyethane 4984: 4982: 4979: 4977: 4974: 4973: 4971: 4969: 4965: 4959: 4956: 4954: 4947: 4945: 4942: 4940: 4937: 4935: 4932: 4930: 4927: 4925: 4922: 4920: 4917: 4915: 4912: 4909: 4906: 4904: 4901: 4900: 4898: 4894: 4890: 4880: 4877: 4875: 4872: 4870: 4869:Butyronitrile 4867: 4865: 4862: 4860: 4857: 4855: 4852: 4850: 4847: 4845: 4844:Ethyl formate 4842: 4840: 4837: 4835: 4832: 4830: 4823: 4812: 4809: 4807: 4804: 4802: 4799: 4797: 4794: 4793: 4791: 4789: 4781: 4775: 4772: 4770: 4769:Propionitrile 4767: 4765: 4762: 4760: 4757: 4755: 4752: 4750: 4747: 4745: 4742: 4740: 4737: 4735: 4732: 4730: 4727: 4726: 4724: 4722: 4716: 4710: 4707: 4705: 4702: 4700: 4697: 4695: 4692: 4690: 4687: 4685: 4682: 4680: 4677: 4675: 4672: 4670: 4667: 4666: 4664: 4662: 4656: 4650: 4649:Vinyl alcohol 4647: 4645: 4642: 4640: 4637: 4635: 4632: 4630: 4627: 4625: 4622: 4620: 4617: 4615: 4612: 4608: 4607:Vinyl cyanide 4605: 4604: 4603: 4602:Acrylonitrile 4600: 4598: 4595: 4594: 4592: 4590: 4584: 4578: 4575: 4573: 4570: 4568: 4567:Pentynylidyne 4565: 4563: 4560: 4558: 4555: 4553: 4550: 4548: 4545: 4543: 4536: 4534: 4531: 4529: 4526: 4524: 4521: 4519: 4516: 4514: 4511: 4509: 4506: 4504: 4501: 4500: 4498: 4496: 4490: 4484: 4481: 4479: 4476: 4474: 4471: 4469: 4466: 4464: 4463:Methylenimine 4461: 4459: 4456: 4454: 4451: 4449: 4446: 4444: 4441: 4439: 4436: 4434: 4431: 4429: 4426: 4424: 4421: 4419: 4416: 4414: 4411: 4409: 4406: 4404: 4401: 4398: 4395: 4394: 4392: 4390: 4384: 4378: 4375: 4373: 4370: 4368: 4365: 4363: 4360: 4358: 4355: 4353: 4350: 4348: 4345: 4343: 4342:Propynylidyne 4340: 4338: 4335: 4333: 4332:Methyl cation 4330: 4328: 4325: 4323: 4320: 4318: 4315: 4313: 4310: 4308: 4305: 4303: 4300: 4298: 4295: 4293: 4292:Fulminic acid 4290: 4288: 4285: 4283: 4280: 4278: 4275: 4273: 4270: 4268: 4265: 4264: 4262: 4260: 4254: 4248: 4245: 4243: 4240: 4238: 4235: 4233: 4230: 4228: 4225: 4223: 4220: 4218: 4215: 4213: 4210: 4208: 4205: 4203: 4200: 4198: 4195: 4193: 4190: 4188: 4185: 4183: 4180: 4178: 4175: 4173: 4170: 4168: 4167:Nitrous oxide 4165: 4163: 4156: 4154: 4151: 4149: 4146: 4144: 4141: 4139: 4136: 4134: 4131: 4129: 4126: 4124: 4121: 4118: 4115: 4112: 4109: 4107: 4104: 4102: 4099: 4097: 4094: 4092: 4089: 4087: 4084: 4082: 4079: 4077: 4074: 4072: 4069: 4067: 4064: 4062: 4061:Amino radical 4059: 4057: 4054: 4052: 4049: 4048: 4046: 4044: 4040: 4035: 4026: 4017: 4007: 4004: 4002: 3999: 3997: 3994: 3992: 3991:Sodium iodide 3989: 3987: 3984: 3982: 3979: 3977: 3974: 3972: 3969: 3967: 3964: 3962: 3959: 3957: 3954: 3951: 3948: 3946: 3943: 3941: 3938: 3935: 3932: 3930: 3927: 3925: 3922: 3920: 3917: 3915: 3912: 3910: 3907: 3904: 3901: 3899: 3896: 3894: 3891: 3889: 3886: 3884: 3881: 3879: 3876: 3874: 3873:Cyano radical 3871: 3869: 3866: 3864: 3861: 3859: 3856: 3854: 3853:Carbon cation 3851: 3849: 3846: 3844: 3841: 3839: 3836: 3834: 3831: 3830: 3828: 3826: 3822: 3819: 3817: 3813: 3809: 3802: 3797: 3795: 3790: 3788: 3783: 3782: 3779: 3766: 3759: 3756: 3749: 3746: 3739: 3736: 3729: 3726: 3719: 3716: 3709: 3706: 3699: 3698: 3696: 3692: 3685: 3678: 3675: 3668: 3665: 3658: 3655: 3648: 3645: 3638: 3635: 3628: 3625: 3618: 3617: 3615: 3611: 3607: 3604: 3597: 3592: 3590: 3585: 3583: 3578: 3577: 3574: 3562: 3554: 3553: 3550: 3544: 3541: 3539: 3536: 3535: 3533: 3529: 3523: 3520: 3518: 3515: 3513: 3510: 3509: 3507: 3503: 3497: 3494: 3492: 3489: 3487: 3484: 3483: 3481: 3477: 3471: 3468: 3466: 3463: 3461: 3458: 3457: 3455: 3451: 3445: 3442: 3440: 3437: 3435: 3432: 3431: 3429: 3425: 3419: 3418:Square planar 3416: 3414: 3411: 3409: 3406: 3405: 3403: 3399: 3393: 3390: 3388: 3385: 3383: 3380: 3379: 3377: 3373: 3367: 3364: 3362: 3359: 3358: 3356: 3352: 3346: 3343: 3341: 3338: 3337: 3334: 3330: 3323: 3318: 3316: 3311: 3309: 3304: 3303: 3300: 3293: 3290: 3287: 3284: 3281: 3278: 3275: 3272: 3271: 3263: 3261: 3257: 3255:1-57259-491-8 3251: 3247: 3242: 3238: 3237: 3231: 3230: 3218: 3216:9780131315419 3212: 3208: 3207: 3199: 3184: 3178: 3170: 3166: 3162: 3158: 3154: 3150: 3146: 3142: 3138: 3135:(in German). 3134: 3127: 3119: 3115: 3110: 3105: 3101: 3097: 3093: 3089: 3085: 3078: 3069: 3064: 3060: 3056: 3052: 3045: 3038: 3036:0-471-53128-6 3032: 3028: 3021: 3013: 3009: 3005: 3001: 2997: 2993: 2989: 2988: 2983: 2976: 2968: 2964: 2960: 2956: 2952: 2948: 2944: 2943: 2938: 2931: 2929: 2912: 2908: 2904: 2900: 2896: 2892: 2888: 2884: 2877: 2869: 2867:9780486683591 2863: 2859: 2858: 2853: 2847: 2839: 2837:9781447959069 2833: 2829: 2822: 2814: 2808: 2804: 2797: 2789: 2785: 2781: 2777: 2773: 2769: 2765: 2761: 2754: 2746: 2744:9780495391630 2740: 2736: 2735: 2727: 2719: 2717:9780198555681 2713: 2709: 2702: 2691: 2687: 2680: 2673: 2669: 2660: 2657: 2655: 2654:Covalent bond 2652: 2650: 2647: 2645: 2642: 2640: 2637: 2636: 2630: 2628: 2624: 2620: 2616: 2606: 2604: 2600: 2594: 2584: 2582: 2567: 2551: 2544: 2541: 2525: 2518: 2516:is an integer 2503: 2496: 2495: 2493: 2476: 2473: 2470: 2467: 2464: 2461: 2458: 2455: 2452: 2449: 2446: 2443: 2425: 2418: 2412: 2409: 2404: 2401: 2397: 2393: 2384: 2376: 2375: 2374: 2373: 2372: 2370: 2366: 2339: 2336: 2333: 2330: 2327: 2324: 2321: 2318: 2315: 2312: 2309: 2286: 2281: 2277: 2273: 2270: 2263: 2259: 2252: 2249: 2246: 2240: 2234: 2225: 2217: 2216: 2215: 2214: 2213: 2186: 2182: 2174: 2171: 2154: 2147: 2146: 2144: 2125: 2120: 2116: 2112: 2109: 2106: 2099: 2098: 2097: 2096: 2095: 2089: 2073: 2053: 2045: 2026: 2022: 2015: 2012: 2009: 2003: 2000: 1995: 1991: 1983: 1982: 1981: 1980: 1979: 1971: 1954: 1947: 1945: 1928: 1921: 1920: 1918: 1898: 1895: 1889: 1885: 1879: 1870: 1862: 1861: 1860: 1859: 1858: 1850: 1836: 1816: 1791: 1787: 1783: 1778: 1775: 1770: 1761: 1753: 1752: 1751: 1749: 1739: 1737: 1732: 1730: 1726: 1722: 1715:Energy levels 1712: 1710: 1706: 1702: 1698: 1682: 1679: 1676: 1653: 1633: 1630: 1627: 1624: 1601: 1581: 1578: 1575: 1572: 1549: 1529: 1509: 1488: 1468: 1457: 1453: 1449: 1438: 1434: 1427: 1423: 1415: 1399: 1389: 1385: 1377: 1376: 1372: 1356: 1346: 1342: 1334: 1333: 1329: 1313: 1308: 1297: 1293: 1289: 1281: 1280: 1276: 1260: 1255: 1244: 1240: 1236: 1228: 1227: 1223: 1207: 1197: 1193: 1185: 1184: 1180: 1164: 1154: 1150: 1142: 1141: 1137: 1121: 1116: 1106: 1102: 1094: 1093: 1089: 1073: 1068: 1058: 1054: 1046: 1045: 1027: 1023: 1014: 1011: 1010: 1007: 993: 973: 953: 933: 913: 893: 864: 846: 843: 840: 740: 700: 675: 671: 667: 659: 655: 651: 640: 629: 626: 623: 620: 617: 609: 608: 607: 606: 601: 587: 567: 547: 539: 535: 531: 514: 500: 498: 494: 490: 486: 482: 477: 475: 471: 467: 463: 459: 454: 452: 441: 439: 429: 423: 415: 411: 401: 399: 395: 390: 388: 384: 380: 375: 373: 372:heteronuclear 369: 359: 350: 346: 335: 324: 313: 302: 291: 280: 275: 273: 269: 258: 247: 242: 240: 236: 232: 228: 224: 220: 216: 212: 208: 203: 194: 183: 172: 154: 143: 139: 135: 131: 123: 119: 114: 110: 108: 104: 103:heteronuclear 96: 88: 84: 73: 62: 58: 54: 50: 46: 42: 38: 28: 23: 19: 5224: 5207:Spectroscopy 5061:Astrobiology 4914:Formaldehyde 4806:Benzonitrile 4597:Acetaldehyde 4552:Methanethiol 4503:Acetonitrile 4408:Carbodiimide 4287:Formaldehyde 4282:Cyanoethynyl 4133:Iron cyanide 4128:Hydroperoxyl 3929:Nitric oxide 3824: 3602: 3517:Dodecahedral 3340:VSEPR theory 3280:Hyperphysics 3274:Hyperphysics 3245: 3235: 3205: 3198: 3186:. Retrieved 3177: 3136: 3132: 3126: 3091: 3087: 3077: 3058: 3054: 3044: 3026: 3020: 2991: 2985: 2975: 2946: 2940: 2915:. Retrieved 2911:the original 2893:(2): 83–86. 2890: 2886: 2876: 2856: 2846: 2827: 2821: 2802: 2796: 2766:(1): 43–46. 2763: 2759: 2753: 2733: 2726: 2708:The Elements 2707: 2701: 2685: 2672: 2626: 2622: 2618: 2614: 2612: 2603:Hund's cases 2596: 2593:Hund's cases 2587:Hund's cases 2578: 2362: 2207: 2170:reduced mass 2093: 1977: 1856: 1808: 1750:expression: 1745: 1736:Lucy Mensing 1733: 1718: 1701:spectrometer 1448:fluorescence 1445: 1436: 1432: 1426: 1006:(ungerade). 865: 692: 602: 538:fluorescence 506: 497:Lothar Meyer 489:periodic law 479:At the 1860 478: 462:von Humboldt 455: 447: 435: 407: 391: 383:nitric oxide 376: 365: 343:) form with 279:diphosphorus 276: 243: 204: 127: 95:nitric oxide 44: 36: 35: 18: 5181:Outer space 5091:Cosmic dust 5056:Abiogenesis 4968:Unconfirmed 4924:Heavy water 4764:Ethanethiol 4679:Cyanoallene 4669:Acetic acid 4639:Methylamine 4523:Diacetylene 4438:Formic acid 4428:Cyanomethyl 4086:Diazenylium 4076:CCP radical 3952:(molecular) 3936:(molecular) 3905:(molecular) 3408:Tetrahedral 1729:Hamiltonian 1725:eigenstates 451:John Dalton 438:bond length 418:hydrogen (H 207:noble gases 162:), oxygen ( 122:homonuclear 83:homonuclear 5283:Categories 5096:Cosmic ray 5038:Silylidyne 5001:Hemolithin 4976:Anthracene 4893:Deuterated 4874:Pyrimidine 4684:Ethanimine 4547:Ketenimine 4403:Butadiynyl 4227:Thioformyl 4081:Chloronium 3460:Octahedral 2665:References 2644:AXE method 1666:branch to 1646:, and the 1614:branch to 1454:, called " 530:metastable 485:Cannizzaro 458:Gay-Lussac 404:Occurrence 385:(NO), and 349:Dirubidium 334:molybdenum 272:tennessine 144:hydrogen ( 39:(from 5028:Phosphine 4896:molecules 4829:fullerene 4729:Acetamide 4533:Formamide 4413:Cyanamide 4267:Acetylene 4242:Tricarbon 4153:Methylene 4138:Isoformyl 4043:Triatomic 3816:Molecules 3169:123240532 3161:0044-3328 2917:24 August 2788:120378643 2734:Chemistry 2623:HOFBrINCl 2619:HONClBrIF 2615:BrINClHOF 2609:Mnemonics 2552:ω 2526:ℏ 2426:ω 2423:ℏ 2274:μ 2260:ℏ 2155:μ 2113:μ 2074:ℏ 2054:ℓ 2023:ℏ 2010:ℓ 2004:ℓ 1738:in 1926. 1674:Δ 1631:− 1622:Δ 1570:Δ 1396:Δ 1353:Π 1314:− 1305:Σ 1261:− 1252:Σ 1204:Δ 1161:Π 1113:Σ 1065:Σ 914:− 874:Λ 821:Δ 801:Π 781:Σ 761:Λ 721:Λ 676:− 635:Λ 398:polymeric 392:Many 1:1 301:Dilithium 235:monatomic 128:The only 107:non-polar 49:molecules 5015:Linear C 4996:Graphene 4908:Ammonium 4709:Acrolein 4572:Propynal 4557:Methanol 4528:Ethylene 4397:Ammonium 4172:Nitroxyl 3996:Sulfanyl 3940:Imidogen 3934:Nitrogen 3903:Hydrogen 3848:Argonium 3825:Diatomic 3603:Diatomic 3561:Category 3392:T-shaped 3118:35544352 3012:Archived 2967:Archived 2690:Archived 2633:See also 2583:levels. 1705:spectrum 1416:71698.4 1373:68951.2 1330:67739.3 1294:′ 1277:65851.3 1241:′ 1224:59380.2 1181:59306.8 1138:49754.8 1015:Energy ( 332:) and di 323:tungsten 312:disodium 290:disulfur 268:astatine 182:chlorine 171:fluorine 153:nitrogen 61:hydrogen 5161:Kerogen 5048:Related 4991:Glycine 4944:Propyne 4903:Ammonia 4801:Benzene 4796:Acetone 4788:or more 4759:Propene 4744:Ethanol 4634:Propyne 4453:Methane 4322:Ketenyl 4272:Ammonia 3286:3D Chem 3141:Bibcode 3096:Bibcode 2996:Bibcode 2951:Bibcode 2895:Bibcode 2768:Bibcode 2564:is the 2538:is the 2365:vibrate 2168:is the 2086:is the 1968:is the 1942:is the 1699:of the 389:(HCl). 246:bromine 223:krypton 193:bromine 180:), and 5212:Tholin 5033:Pyrene 4478:Silane 4448:Ketene 3950:Oxygen 3613:Common 3413:Seesaw 3361:Linear 3252:  3213:  3188:1 June 3167:  3159:  3116:  3033:  2864:  2834:  2809:  2786:  2741:  2714:  2494:where 2441:  2438:  2435:  2432:  2429:  2307:  2304:  2301:  2298:  2295:  2145:where 2046:where 1919:where 1809:where 1594:, the 1542:. The 1042:, cm) 693:where 534:photon 381:(CO), 310:) and 257:iodine 255:) and 229:, and 211:helium 72:oxygen 5198:(PAH) 4786:atoms 4721:atoms 4661:atoms 4659:Eight 4589:atoms 4587:Seven 4495:atoms 4389:atoms 4259:atoms 4247:Water 4177:Ozone 4119:(HNC) 4113:(HCN) 3694:Other 3292:IUMSC 3165:S2CID 2784:S2CID 2693:(PDF) 2682:(PDF) 1766:trans 1012:State 231:radon 227:xenon 219:argon 142:gases 93:) or 70:) or 53:atoms 43: 41:Greek 4719:Nine 4387:Five 4297:HCCN 4257:Four 4217:SiNC 3366:Bent 3250:ISBN 3211:ISBN 3190:2019 3157:ISSN 3114:PMID 3031:ISBN 2919:2007 2862:ISBN 2832:ISBN 2807:ISBN 2739:ISBN 2712:ISBN 2597:The 1719:The 1090:0.0 495:and 460:and 270:and 215:neon 205:The 5010:NCO 4910:ion 4817:, C 4784:Ten 4493:Six 4399:ion 3149:doi 3104:doi 3063:doi 3004:doi 2959:doi 2903:doi 2776:doi 2542:and 2389:vib 2230:rot 2210:rot 1875:rot 946:or 906:or 491:by 299:). 202:). 169:), 151:), 138:bar 45:di- 5285:: 4827:70 4819:60 4815:60 4813:(C 4538:HC 3762:Rb 3752:Li 3712:Ar 3702:He 3671:Br 3661:Cl 3163:. 3155:. 3147:. 3137:36 3112:. 3102:. 3092:34 3090:. 3086:. 3057:. 3053:. 3010:. 3002:. 2992:20 2990:. 2984:. 2965:. 2957:. 2947:21 2945:. 2939:. 2927:^ 2901:. 2891:38 2889:. 2885:. 2782:. 2774:. 2764:63 2762:. 2688:. 2684:. 2605:. 2371:: 1711:. 813:, 793:, 580:, 560:, 499:. 353:Rb 338:Mo 316:Na 305:Li 250:Br 241:. 225:, 221:, 217:, 213:, 197:Br 186:Cl 116:A 109:. 99:NO 91:CO 25:A 5017:5 5008:2 5006:H 4953:D 4951:2 4949:N 4825:C 4542:N 4540:4 4162:H 4160:2 4158:N 3800:e 3793:t 3786:v 3764:2 3754:2 3744:2 3742:S 3734:2 3732:P 3724:2 3722:C 3714:2 3704:2 3683:2 3681:I 3673:2 3663:2 3653:2 3651:F 3643:2 3641:O 3633:2 3631:N 3623:2 3621:H 3595:e 3588:t 3581:v 3321:e 3314:t 3307:v 3258:. 3219:. 3192:. 3171:. 3151:: 3143:: 3120:. 3106:: 3098:: 3071:. 3065:: 3059:7 3006:: 2998:: 2961:: 2953:: 2921:. 2905:: 2897:: 2870:. 2840:. 2815:. 2790:. 2778:: 2770:: 2747:. 2720:. 2504:n 2477:. 2474:. 2471:. 2468:. 2465:, 2462:2 2459:, 2456:1 2453:, 2450:0 2447:= 2444:n 2419:) 2413:2 2410:1 2405:+ 2402:n 2398:( 2394:= 2385:E 2340:. 2337:. 2334:. 2331:, 2328:2 2325:, 2322:1 2319:, 2316:0 2313:= 2310:l 2287:2 2282:0 2278:r 2271:2 2264:2 2256:) 2253:1 2250:+ 2247:l 2244:( 2241:l 2235:= 2226:E 2187:0 2183:r 2126:2 2121:0 2117:r 2110:= 2107:I 2090:. 2027:2 2019:) 2016:1 2013:+ 2007:( 2001:= 1996:2 1992:L 1955:I 1929:L 1899:I 1896:2 1890:2 1886:L 1880:= 1871:E 1837:v 1817:m 1792:2 1788:v 1784:m 1779:2 1776:1 1771:= 1762:E 1683:0 1680:= 1677:J 1654:Q 1634:1 1628:= 1625:J 1602:P 1582:1 1579:+ 1576:= 1573:J 1550:R 1530:J 1510:J 1489:X 1481:- 1469:A 1460:2 1437:h 1433:c 1400:u 1390:1 1386:w 1357:g 1347:1 1343:a 1309:u 1298:1 1290:a 1256:u 1245:3 1237:B 1208:u 1198:3 1194:W 1165:g 1155:3 1151:B 1122:+ 1117:u 1107:3 1103:A 1074:+ 1069:g 1059:1 1055:X 1028:0 1024:T 994:u 974:g 954:u 934:g 894:+ 861:2 847:0 844:= 841:v 741:v 701:S 672:/ 668:+ 663:) 660:u 656:/ 652:g 649:( 645:) 641:v 638:( 630:1 627:+ 624:S 621:2 588:C 568:B 548:A 515:X 426:2 422:) 420:2 355:2 351:( 340:2 336:( 329:2 327:W 325:( 318:2 314:( 307:2 303:( 296:2 294:S 292:( 285:2 283:P 281:( 263:2 261:I 259:( 252:2 248:( 209:( 199:2 195:( 188:2 184:( 177:2 175:F 173:( 166:2 164:O 159:2 157:N 155:( 148:2 146:H 97:( 89:( 78:2 76:O 74:( 67:2 65:H 63:( 31:2

Index


space-filling model
Greek
molecules
atoms
chemical elements
hydrogen
oxygen
homonuclear
carbon monoxide
nitric oxide
heteronuclear
non-polar

periodic table
homonuclear
chemical elements
standard temperature and pressure
bar
gases
nitrogen
fluorine
chlorine
bromine
noble gases
helium
neon
argon
krypton
xenon

Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.

↑