325:
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146:
176:
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Tsurugi, Hayato; Mashima, Kazushi (2019). "Salt-Free
Reduction of Transition Metal Complexes by Bis(trimethylsilyl)cyclohexadiene, -dihydropyrazine, and -4,4′-bipyridinylidene Derivatives".
573:
434:
Takuya
Nakagiri; Masahito Murai; Kazuhiko Takai (2015). "Stereospecific Deoxygenation of Aliphatic Epoxides to Alkenes under Rhenium Catalysis".
211:
Phosphorus occurs in nature as oxides, so to produce elemental form of the element, deoxygenation is required. The main method involves
46:
120:
Deoxygenation is an important goal of the conversion of biomass to useful fuels and chemicals. Partial deoxygenation is effected by
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is formed quantitatively in this reaction and therefore the reagent is used for the analytical detection of many oxo compounds.
253:
main group compounds are useful reagents for certain deoxygenations conducted on laboratory scale. The highly oxophilic reagent
324:
105:
591:
511:
David P. Sebesta "Hexachlorodisilane" in
Encyclopedia of Reagents for Organic Synthesis John Wiley, London, 2001.
529:
Podyacheva, Evgeniya; Kuchuk, Ekaterina; Chusov, Denis (2019). "Reduction of phosphine oxides to phosphines".
109:
372:
Sheldon, Roger A. (2014). "Green and sustainable manufacture of chemicals from biomass: state of the art".
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A chemical reagent for the deoxygenation of many sulfur and nitrogen oxo compounds is the combination
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is based on the activation of the sulfoxide by a trifluoroacetyl group and oxidation of iodine.
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Oxygen groups can also be removed by the reductive coupling of ketones, as illustrated by the
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402:, Martha A. Umbreit (1981). "Deoxygenation of Epoxides with Lower Valent Tungsten Halides:
121:
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The main examples involving the replacement of an oxo group by two hydrogen atoms (A=O → AH
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572:(JE-2136MR) Zbigniew H. Kudzin, Marcin H. Kudzin, Józef Drabowicz, and Andrzej Kotyński
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atoms from a molecule. The term also refers to the removal of molecular oxygen (O
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Nitroaromatics are deoxygenated by strongly reducing silyl reagents such as
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Trifluoroacetic anhydride-sodium iodide reagent. Nature and applications
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can be deoxygenated using the oxophilic reagent produced by combining
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170:. This reaction can proceed with loss or retention of configuration.
49:. As applied to organic compounds, deoxygenation is a component of
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Stoichiometric reactions that effect deoxygenation include the
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as the reagent. Conditions are typically more forcing than
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group by hydrogen (A-OH → A-H) is the point of the
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Chemical reaction removing oxygen atoms from a molecule
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19:"Deoxy" redirects here. For the Pokémon species, see
183:-cyclododecene oxide, which occurs with retention.
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201:N,N'-bis(trimethylsilyl)-4,4'-bipyridinylidene
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519:Article Online Posting Date: April 15, 2001.
85:. Typical examples use metal catalysts and H
285:. For example, in the deoxygenation of the
215:(i.e., carbon is the deoxygenation agent).
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100:for aryl ketones. The replacement of a
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53:as well a type of reaction employed in
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41:) from gases and solvents, a step in
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265:) stereospecifically deoxygenates
190:Deoxygenation of S-O and P-O bonds
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343:Preparation of stable carbenes
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471:Accounts of Chemical Research
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106:Barton–McCombie deoxygenation
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483:10.1021/acs.accounts.8b00638
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448:10.1021/acs.orglett.5b01583
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65:Deoxygenation of C-O bonds
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279:trifluoroacetic anhydride
33:involving the removal of
517:10.1002/047084289X.rh007
421:10.15227/orgsyn.060.0029
592:Organic redox reactions
110:Markó–Lam deoxygenation
98:Wolff–Kishner reduction
213:carbothermic reduction
184:
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157:tungsten hexachloride
70:With replacement by H
116:Biomass valorization
531:Tetrahedron Letters
348:Ocean deoxygenation
400:K. Barry Sharpless
386:10.1039/C3GC41935E
313:reaction mechanism
255:hexachlorodisilane
239:+ 30 CO + 18 CaSiO
185:
43:air-free technique
442:(13): 3346–3349.
406:-Cyclododecene".
290:diphenylsulfoxide
179:Deoxygenation of
55:organic synthesis
31:chemical reaction
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27:Deoxygenation
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353:Oxophilicity
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235:+ 30 C → 3 P
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132:Other routes
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26:
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409:Org. Synth.
122:dehydration
586:Categories
359:References
231:F + 18 SiO
57:, e.g. of
551:104364715
436:Org. Lett
338:Degassing
287:sulfoxide
273:S=O bonds
251:Oxophilic
207:P=O bonds
195:N=O bonds
499:73505603
491:30794373
456:26065934
332:See also
153:Epoxides
108:and the
102:hydroxyl
567:Arkivoc
294:sulfide
292:to the
243:+ 2 CaF
549:
497:
489:
454:
415:: 29.
317:Iodine
168:alkene
81:) are
35:oxygen
21:Deoxys
547:S2CID
495:S2CID
404:trans
181:trans
29:is a
574:Link
570:2007
487:PMID
452:PMID
311:The
219:4 Ca
159:and
124:and
45:and
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513:doi
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257:(Si
223:(PO
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162:n
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