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Crystal optics

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cause a variation of a medium's permittivity tensor when an external electric field is applied, proportional (to lowest order) to the strength of the field. This causes a rotation of the principal axes of the medium and alters the behaviour of light travelling through it; the effect can be used to
426: 907:{\displaystyle {\begin{pmatrix}P_{x}\\P_{y}\\P_{z}\end{pmatrix}}=\varepsilon _{0}{\begin{pmatrix}\chi _{xx}&\chi _{xy}&\chi _{xz}\\\chi _{yx}&\chi _{yy}&\chi _{yz}\\\chi _{zx}&\chi _{zy}&\chi _{zz}\end{pmatrix}}{\begin{pmatrix}E_{x}\\E_{y}\\E_{z}\end{pmatrix}}} 1440:{\displaystyle \mathbf {D} =\varepsilon _{0}\mathbf {E} +\mathbf {P} =\varepsilon _{0}\mathbf {E} +\varepsilon _{0}{\boldsymbol {\chi }}\mathbf {E} =\varepsilon _{0}(I+{\boldsymbol {\chi }})\mathbf {E} =\varepsilon _{0}{\boldsymbol {\varepsilon }}\mathbf {E} .} 1018: 326: 604: 555:. In a physical picture, this can be thought of as the dipoles induced in the medium by the electric field having certain preferred directions, related to the physical structure of the crystal. This can be written as: 1711: 1592: 204: 1803:. Light polarised at some angle to the axes will experience a different phase velocity for different polarization components, and cannot be described by a single index of refraction. This is often depicted as an 301: 480: 1270: 1206: 1142: 537: 1850:
A dielectric tensor that is not Hermitian gives rise to complex eigenvalues, which corresponds to a material with gain or absorption at a particular frequency.
421:{\displaystyle \mathbf {D} =\varepsilon _{0}\mathbf {E} +\chi \varepsilon _{0}\mathbf {E} =\varepsilon _{0}(1+\chi )\mathbf {E} =\varepsilon \mathbf {E} } 922: 561: 1843:
are complex-valued vectors, corresponding to elliptically polarized light, and time-reversal symmetry can be broken. This can be used to design
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present in the medium). Physically, the polarization field can be regarded as the response of the medium to the electric field of the light.
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Amnon Yariv, Pochi Yeh. (2006). Photonics optical electronics in modern communications (6th ed.). Oxford University Press. pp. 30-31.
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Thus these waves will see two different refractive indices and travel at different speeds. This phenomenon is known as
1919: 68: 46: 133:, which means that light behaves the same way no matter which direction it is travelling in the medium. In terms of 39: 1840: 222: 1066:
the tensor by choosing the appropriate set of coordinate axes, zeroing all components of the tensor except χ
107:. The index of refraction depends on both composition and crystal structure and can be calculated using the 506: 142: 108: 1470:
such the electric field of the wave is parallel to the x-axis. The wave experiences a susceptibility χ
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of the medium must also be a tensor. Consider a light wave propagating along the z principal axis
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tensor are real, corresponding to a case in which the refractive index is real in all directions.
1750: 308: 1063: 230: 134: 50: 1836: 1820: 1467: 8: 486: 1869: 1844: 1816: 1463: 1059: 1055: 494: 104: 1013:{\displaystyle P_{i}=\varepsilon _{0}\sum _{j\in \{x,y,z\}}\chi _{ij}E_{j}\quad .} 1904: 1864: 1804: 1874: 1828: 599:{\displaystyle \mathbf {P} =\varepsilon _{0}{\boldsymbol {\chi }}\mathbf {E} .} 149: 112: 103:) in which light behaves differently depending on which direction the light is 1780:) for light polarised in the x or y directions, and an "extraordinary" index ( 115:) it is possible to induce anisotropy by applying an external electric field. 1913: 1859: 1718: 1279:
of the medium. Note that these axes will be orthogonal if all entries in the
1787:) for polarisation in the z direction. A uniaxial crystal is "positive" if n 1773:. A uniaxial crystal exhibits two refractive indices, an "ordinary" index ( 226: 214: 94: 138: 111:. Crystals are often naturally anisotropic, and in some media (such as 1706:{\displaystyle n_{yy}=(1+\chi _{yy})^{1/2}=(\varepsilon _{yy})^{1/2}.} 1587:{\displaystyle n_{xx}=(1+\chi _{xx})^{1/2}=(\varepsilon _{xx})^{1/2}.} 199:{\displaystyle \mathbf {D} =\varepsilon _{0}\mathbf {E} +\mathbf {P} } 1832: 242: 129: 547:
In an anisotropic medium, such as a crystal, the polarisation field
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is not necessarily aligned with the electric field of the light
1727: 614: 246: 85: 1831:, some materials can have a dielectric tensor that is complex- 296:{\displaystyle \mathbf {P} =\chi \varepsilon _{0}\mathbf {E} } 124: 89: 1275:
The directions x, y and z are in this case known as the
855: 702: 635: 475:{\displaystyle \varepsilon =\varepsilon _{0}(1+\chi )} 1606: 1487: 1303: 1265:{\displaystyle P_{z}=\varepsilon _{0}\chi _{zz}E_{z}} 1215: 1201:{\displaystyle P_{y}=\varepsilon _{0}\chi _{yy}E_{y}} 1151: 1137:{\displaystyle P_{x}=\varepsilon _{0}\chi _{xx}E_{x}} 1087: 925: 629: 564: 509: 440: 329: 266: 164: 253:is proportional and parallel to the electric field 1705: 1586: 1439: 1264: 1200: 1136: 1012: 906: 598: 531: 474: 420: 295: 198: 1911: 978: 960: 489:of the medium. The value 1+χ is called the 1722:and occurs in some common crystals such as 1038:In nonmagnetic and transparent materials, χ 621:. In terms of components in 3 dimensions: 236: 1597:For a wave polarised in the y direction: 69:Learn how and when to remove this message 141:, this gives a relationship between the 32:This article includes a list of general 1425: 1399: 1367: 584: 1912: 493:of the medium, and is related to the 1835:; this is called a gyro-magnetic or 542: 312:of the medium. The relation between 18: 1078:. This gives the set of relations: 916:or using the summation convention: 532:{\displaystyle n={\sqrt {1+\chi }}} 13: 123:Typical transparent media such as 118: 38:it lacks sufficient corresponding 14: 1941: 1905:A virtual polarization microscope 1898: 1031:is not necessarily colinear with 1810: 1478:. The refractive index is thus: 1430: 1407: 1372: 1349: 1331: 1323: 1305: 613:is not a number as before but a 589: 566: 414: 403: 370: 349: 331: 289: 268: 249:medium, this polarization field 192: 184: 166: 88:that describes the behaviour of 23: 1006: 1886: 1683: 1666: 1646: 1623: 1564: 1547: 1527: 1504: 1403: 1389: 1294:are also related by a tensor: 619:electric susceptibility tensor 469: 457: 399: 387: 1: 1880: 500:, for non-magnetic media, by 16:Sub-branch of Optical Physics 1456:relative permittivity tensor 7: 1853: 143:electric displacement field 10: 1946: 1824:produce light modulators. 1745:, the crystal is known as 99:, that is, media (such as 1062:, it is thus possible to 1058:. In accordance with the 1920:Condensed matter physics 1751:Optic axis of a crystal 309:electric susceptibility 237:Electric susceptibility 231:electric dipole moments 109:Gladstone–Dale relation 53:more precise citations. 1819:phenomena such as the 1769:the crystal is called 1707: 1588: 1441: 1266: 1202: 1138: 1014: 908: 600: 533: 476: 422: 297: 200: 1839:. In this case, the 1708: 1589: 1442: 1267: 1203: 1139: 1015: 909: 601: 534: 491:relative permittivity 477: 423: 298: 201: 1837:magneto-optic effect 1821:electro-optic effect 1604: 1485: 1474:and a permittivity ε 1462:. Consequently, the 1301: 1213: 1149: 1085: 923: 627: 562: 507: 438: 327: 264: 162: 1795:and "negative" if n 1054:tensor is real and 487:dielectric constant 135:Maxwell's equations 1703: 1584: 1437: 1262: 1198: 1134: 1010: 982: 904: 898: 844: 678: 596: 529: 472: 418: 293: 217:of free space and 196: 1845:optical isolators 1827:In response to a 1817:nonlinear optical 1460:dielectric tensor 949: 543:Anisotropic media 527: 229:corresponding to 84:is the branch of 79: 78: 71: 1937: 1930:Nonlinear optics 1893: 1890: 1870:Optical rotation 1712: 1710: 1709: 1704: 1699: 1698: 1694: 1681: 1680: 1662: 1661: 1657: 1644: 1643: 1619: 1618: 1593: 1591: 1590: 1585: 1580: 1579: 1575: 1562: 1561: 1543: 1542: 1538: 1525: 1524: 1500: 1499: 1464:refractive index 1454:is known as the 1446: 1444: 1443: 1438: 1433: 1428: 1423: 1422: 1410: 1402: 1388: 1387: 1375: 1370: 1365: 1364: 1352: 1347: 1346: 1334: 1326: 1321: 1320: 1308: 1286:It follows that 1271: 1269: 1268: 1263: 1261: 1260: 1251: 1250: 1238: 1237: 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1805:index ellipsoid 1802: 1798: 1794: 1790: 1786: 1779: 1768: 1764: 1760: 1756: 1744: 1740: 1736: 1690: 1686: 1682: 1673: 1669: 1653: 1649: 1645: 1636: 1632: 1611: 1607: 1605: 1602: 1601: 1571: 1567: 1563: 1554: 1550: 1534: 1530: 1526: 1517: 1513: 1492: 1488: 1486: 1483: 1482: 1477: 1473: 1429: 1424: 1418: 1414: 1406: 1398: 1383: 1379: 1371: 1366: 1360: 1356: 1348: 1342: 1338: 1330: 1322: 1316: 1312: 1304: 1302: 1299: 1298: 1256: 1252: 1243: 1239: 1233: 1229: 1220: 1216: 1214: 1211: 1210: 1192: 1188: 1179: 1175: 1169: 1165: 1156: 1152: 1150: 1147: 1146: 1128: 1124: 1115: 1111: 1105: 1101: 1092: 1088: 1086: 1083: 1082: 1077: 1073: 1069: 1049: 1043: 1000: 996: 987: 983: 953: 943: 939: 930: 926: 924: 921: 920: 897: 896: 890: 886: 883: 882: 876: 872: 869: 868: 862: 858: 851: 850: 843: 842: 833: 829: 827: 818: 814: 812: 803: 799: 796: 795: 786: 782: 780: 771: 767: 765: 756: 752: 749: 748: 739: 735: 733: 724: 720: 718: 709: 705: 698: 697: 691: 687: 677: 676: 670: 666: 663: 662: 656: 652: 649: 648: 642: 638: 631: 630: 628: 625: 624: 617:of rank 2, the 588: 583: 577: 573: 565: 563: 560: 559: 545: 516: 508: 505: 504: 451: 447: 439: 436: 435: 413: 402: 381: 377: 369: 363: 359: 348: 342: 338: 330: 328: 325: 324: 306:where χ is the 288: 282: 278: 267: 265: 262: 261: 239: 212: 191: 183: 177: 173: 165: 163: 160: 159: 121: 119:Isotropic media 113:liquid crystals 75: 64: 58: 55: 45:Please help to 44: 28: 24: 17: 12: 11: 5: 1943: 1933: 1932: 1927: 1922: 1908: 1907: 1900: 1899:External links 1897: 1895: 1894: 1884: 1882: 1879: 1878: 1877: 1872: 1867: 1862: 1855: 1852: 1841:principal axes 1829:magnetic field 1812: 1809: 1800: 1796: 1792: 1788: 1784: 1777: 1766: 1762: 1758: 1754: 1742: 1738: 1734: 1714: 1713: 1702: 1697: 1693: 1689: 1685: 1679: 1676: 1672: 1668: 1665: 1660: 1656: 1652: 1648: 1642: 1639: 1635: 1631: 1628: 1625: 1622: 1617: 1614: 1610: 1595: 1594: 1583: 1578: 1574: 1570: 1566: 1560: 1557: 1553: 1549: 1546: 1541: 1537: 1533: 1529: 1523: 1520: 1516: 1512: 1509: 1506: 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1416:ε 1400:χ 1381:ε 1368:χ 1358:ε 1340:ε 1314:ε 1241:χ 1231:ε 1177:χ 1167:ε 1113:χ 1103:ε 1056:symmetric 985:χ 958:∈ 951:∑ 941:ε 831:χ 816:χ 801:χ 784:χ 769:χ 754:χ 737:χ 722:χ 707:χ 689:ε 585:χ 575:ε 525:χ 467:χ 449:ε 442:ε 411:ε 397:χ 379:ε 361:ε 357:χ 340:ε 320:is thus: 280:ε 276:χ 243:isotropic 175:ε 130:isotropic 1854:See also 1815:Certain 1749:. (See 1747:uniaxial 148:and the 101:crystals 1771:biaxial 1753:.) If χ 1724:calcite 485:is the 213:is the 209:where ε 125:glasses 47:improve 1799:< n 1791:> n 1728:quartz 1023:Since 615:tensor 431:where 247:linear 241:In an 86:optics 36:, but 1875:Prism 1761:and χ 1450:Here 1074:and χ 609:Here 225:(the 137:in a 97:media 90:light 1733:If χ 1726:and 1290:and 316:and 245:and 127:are 1765:≠ χ 1757:≠ χ 1741:≠ χ 1737:= χ 1458:or 1070:, χ 1044:= χ 92:in 1916:: 1807:. 1767:zz 1763:yy 1759:yy 1755:xx 1743:zz 1739:yy 1735:xx 1730:. 1476:xx 1472:xx 1076:zz 1072:yy 1068:xx 1047:ji 1041:ij 1035:. 257:: 155:: 1801:o 1797:e 1793:o 1789:e 1785:e 1782:n 1778:o 1775:n 1701:. 1696:2 1692:/ 1688:1 1684:) 1678:y 1675:y 1667:( 1664:= 1659:2 1655:/ 1651:1 1647:) 1641:y 1638:y 1630:+ 1627:1 1624:( 1621:= 1616:y 1613:y 1609:n 1582:. 1577:2 1573:/ 1569:1 1565:) 1559:x 1556:x 1548:( 1545:= 1540:2 1536:/ 1532:1 1528:) 1522:x 1519:x 1511:+ 1508:1 1505:( 1502:= 1497:x 1494:x 1490:n 1452:ε 1435:. 1431:E 1420:0 1412:= 1408:E 1404:) 1396:+ 1393:I 1390:( 1385:0 1377:= 1373:E 1362:0 1354:+ 1350:E 1344:0 1336:= 1332:P 1328:+ 1324:E 1318:0 1310:= 1306:D 1292:E 1288:D 1281:χ 1258:z 1254:E 1248:z 1245:z 1235:0 1227:= 1222:z 1218:P 1194:y 1190:E 1184:y 1181:y 1171:0 1163:= 1158:y 1154:P 1130:x 1126:E 1120:x 1117:x 1107:0 1099:= 1094:x 1090:P 1052:χ 1033:E 1029:P 1025:χ 1008:. 1002:j 998:E 992:j 989:i 979:} 976:z 973:, 970:y 967:, 964:x 961:{ 955:j 945:0 937:= 932:i 928:P 900:) 892:z 888:E 878:y 874:E 864:x 860:E 853:( 846:) 838:z 835:z 823:y 820:z 808:x 805:z 791:z 788:y 776:y 773:y 761:x 758:y 744:z 741:x 729:y 726:x 714:x 711:x 700:( 693:0 685:= 680:) 672:z 668:P 658:y 654:P 644:x 640:P 633:( 611:χ 594:. 590:E 579:0 571:= 567:P 553:E 549:P 522:+ 519:1 514:= 511:n 498:n 470:) 464:+ 461:1 458:( 453:0 445:= 415:E 408:= 404:E 400:) 394:+ 391:1 388:( 383:0 375:= 371:E 365:0 354:+ 350:E 344:0 336:= 332:D 318:E 314:D 290:E 284:0 273:= 269:P 255:E 251:P 219:P 211:0 193:P 189:+ 185:E 179:0 171:= 167:D 153:E 146:D 72:) 66:( 61:) 57:( 43:.

Index

references
inline citations
improve
introducing
Learn how and when to remove this message
optics
light
anisotropic
crystals
propagating
Gladstone–Dale relation
liquid crystals
glasses
isotropic
Maxwell's equations
dielectric
electric displacement field
electric field
permittivity
polarization
vector field
electric dipole moments
isotropic
linear
electric susceptibility
dielectric constant
refractive index
tensor
symmetric
spectral theorem

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