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cis,cis-1,3,5-Triaminocyclohexane

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Schwarzenbach, Gerold; Bürgi, Hans-Beat; Jensen, William P.; Lawrance, Geoffrey A.; Mønsted, Lene; Sargeson, Alan M. (1983). "Acid cleavage of nickel(II) complexes containing
123: 207: 438:-1,3,5-triaminocyclohexane. Synthesis of novel hexadentate ligand derivatives for the preparation of gallium radiopharmaceuticals". 182: 297: 513: 394: 363: 143: 374: 99: 43: 8: 518: 481:, and a correlation between the structure and reactivity of nickel–polyamine complexes". 89: 451: 310: 430:
Bowen, Tom; Planalp, Roy P.; Brechbiel, Martin W. (1996). "An improved synthesis of
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Structure of (color code: blue = nitrogen, red = oxygen; dark blue = nickel).
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Except where otherwise noted, data are given for materials in their
30: 343: 122: 354:-1,3,5-derivative has attracted attention because it is a common 155: 464: 362:. It is a colorless oil. It is a popular tridentate ligand in 191:
InChI=1S/C6H15N3/c7-4-1-5(8)3-6(9)2-4/h4-6H,1-3,7-9H2/t4-,5+,6-
112: 346:. Of the many isomers possible for triaminocyclohexane, the 473:-1,3,5-cyclohexanetriamine (TACH), crystal structure of (NO 380: 429: 505: 373:of cyclohexane. The latter is generated via the 167: 377:starting from cyclohexanetricarboxylic acid. 98: 440:Bioorganic & Medicinal Chemistry Letters 142: 379: 506: 284:285 Â°C (545 Â°F; 558 K) 194:Key: UYAUGHKQCCCFDK-FPFOFBBKSA-N 158: 13: 388: 14: 530: 248: 242: 29: 397:, another tripodal triamine (CH 294:(at 25 Â°C , 100 kPa). 458: 423: 236: 1: 417: 452:10.1016/0960-894X(96)00110-2 369:It is prepared from the tris 60:)-Cyclohexane-1,3,5-triamine 7: 77:-Cyclohexane-1,3,5-triamine 24:-1,3,5-Triaminocyclohexane 10: 535: 324:-1,3,5-Triaminocyclohexane 308: 288: 223: 203: 178: 82: 66: 42: 37: 28: 309:Not to be confused with 395:Tris(aminomethyl)ethane 385: 364:coordination chemistry 383: 375:Curtius rearrangement 330:with the formula (CH 44:Preferred IUPAC name 495:10.1021/ic00168a042 483:Inorganic Chemistry 266: g·mol 25: 386: 298:Infobox references 16: 489:(26): 4029–4038. 358:, abbreviated as 311:triazacyclohexane 306:Chemical compound 304: 303: 274:Colorless liquid 124:Interactive image 526: 514:Tripodal ligands 499: 498: 462: 456: 455: 427: 328:organic compound 265: 250: 244: 238: 231:Chemical formula 171: 160: 146: 126: 102: 33: 26: 15: 534: 533: 529: 528: 527: 525: 524: 523: 504: 503: 502: 480: 476: 463: 459: 428: 424: 420: 412: 408: 404: 400: 391: 389:Related ligands 356:tripodal ligand 341: 337: 333: 314: 307: 300: 295: 263: 253: 247: 241: 233: 219: 216: 211: 210: 199: 196: 195: 192: 186: 185: 174: 161: 149: 129: 116: 105: 92: 78: 62: 61: 12: 11: 5: 532: 522: 521: 516: 501: 500: 478: 474: 457: 446:(7): 807–810. 421: 419: 416: 415: 414: 410: 406: 402: 398: 390: 387: 339: 335: 331: 305: 302: 301: 296: 292:standard state 289: 286: 285: 282: 276: 275: 272: 268: 267: 261: 255: 254: 251: 245: 239: 234: 229: 226: 225: 221: 220: 218: 217: 214: 206: 205: 204: 201: 200: 198: 197: 193: 190: 189: 181: 180: 179: 176: 175: 173: 172: 164: 162: 154: 151: 150: 148: 147: 139: 137: 131: 130: 128: 127: 119: 117: 110: 107: 106: 104: 103: 95: 93: 88: 85: 84: 80: 79: 68: 64: 63: 47: 46: 40: 39: 35: 34: 9: 6: 4: 3: 2: 531: 520: 517: 515: 512: 511: 509: 496: 492: 488: 484: 472: 468: 461: 453: 449: 445: 441: 437: 433: 426: 422: 396: 393: 392: 382: 378: 376: 372: 367: 365: 361: 357: 353: 349: 345: 329: 325: 323: 319: 312: 299: 293: 287: 283: 281: 280:Boiling point 278: 277: 273: 270: 269: 262: 260: 257: 256: 235: 232: 228: 227: 222: 213: 212: 209: 202: 188: 187: 184: 177: 170: 166: 165: 163: 157: 153: 152: 145: 141: 140: 138: 136: 133: 132: 125: 121: 120: 118: 114: 109: 108: 101: 97: 96: 94: 91: 87: 86: 81: 76: 72: 65: 59: 55: 51: 45: 41: 36: 32: 27: 23: 19: 486: 482: 470: 466: 460: 443: 439: 435: 431: 425: 368: 359: 351: 347: 321: 317: 316: 315: 215:C1(C(C1N)N)N 83:Identifiers 74: 70: 67:Other names 57: 53: 49: 21: 17: 342:. It is a 271:Appearance 224:Properties 519:Polyamines 508:Categories 418:References 259:Molar mass 135:ChemSpider 111:3D model ( 100:26150-46-9 90:CAS Number 371:carbamate 344:triamine 144:19549297 264:129.207 156:PubChem 326:is an 208:SMILES 169:427712 69:TACH; 38:Names 183:InChI 113:JSmol 401:C(CH 360:tach 334:CHNH 491:doi 471:cis 467:cis 448:doi 436:cis 432:cis 352:cis 348:cis 322:cis 318:cis 159:CID 75:cis 71:cis 22:cis 18:cis 510:: 487:22 485:. 442:. 405:NH 366:. 246:15 56:,5 52:,3 48:(1 497:. 493:: 479:2 477:) 475:3 469:, 454:. 450:: 444:6 434:, 413:) 411:3 409:] 407:2 403:2 399:3 350:, 340:3 338:) 336:2 332:2 320:, 313:. 252:3 249:N 243:H 240:6 237:C 115:) 73:, 58:s 54:s 50:s 20:,

Index


Preferred IUPAC name
CAS Number
26150-46-9
JSmol
Interactive image
ChemSpider
19549297
PubChem
427712
InChI
SMILES
Chemical formula
Molar mass
Boiling point
standard state
Infobox references
triazacyclohexane
organic compound
triamine
tripodal ligand
coordination chemistry
carbamate
Curtius rearrangement

Tris(aminomethyl)ethane
doi
10.1016/0960-894X(96)00110-2
doi
10.1021/ic00168a042

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