Knowledge

Sulfoxidation

Source 📝

138: 223: 250: 283:
Parrino, Francesco; Ramakrishnan, Ayyappan; Kisch, Horst (2008). "Semiconductor-Photocatalyzed Sulfoxidation of Alkanes".
60: 319: 267: 168: 362: 357: 320:"Metal-Catalyzed Asymmetric Sulfoxidation, Epoxidation and Hydroxylation by Hydrogen Peroxide" 147:
mechanism. Mixtures are produced. Semiconductor-sensitized variants have been reported.
8: 367: 43: 300: 263: 229: 334: 292: 255: 35: 338: 351: 259: 318:
Srour, Hassan; Le Maux, Paul; Chevance, Soizic; Simonneaux, Gérard (2013).
304: 296: 144: 51: 47: 159: 155: 151: 20: 39: 31: 317: 143:
The reaction favors secondary positions in accord with its
208: 183: 123: 107: 81: 282: 30:
In one meaning, sulfoxidation refers to the reaction of
87: 171: 133:{\displaystyle {\ce {RH + SO2 + 1/2 O2 -> RSO3H}}} 63: 42:. This reaction is employed industrially to produce 248:Kosswig, Kurt (2000). "Sulfonic Acids, Aliphatic". 217: 132: 16:Type of chemical reactions involving sulfur oxides 349: 251:Ullmann's Encyclopedia of Industrial Chemistry 218:{\displaystyle {\ce {R2S + O -> R2SO}}} 285:Angewandte Chemie International Edition 247: 350: 150:Sulfoxidation can also refer to the 27:refers to two distinct reactions. 13: 14: 379: 327:Coordination Chemistry Reviews 311: 276: 241: 195: 110: 1: 235: 7: 228:A typical source of "O" is 10: 384: 339:10.1016/j.ccr.2013.05.010 50:. The reaction requires 260:10.1002/14356007.a25_503 254:. Weinheim: Wiley-VCH. 297:10.1002/anie.200800326 219: 134: 220: 135: 333:(21–22): 3030–3050. 169: 61: 46:, which are used as 44:alkyl sulfonic acids 210: 185: 125: 109: 83: 215: 198: 173: 130: 113: 97: 96: 71: 34:with a mixture of 291:(37): 7107–7109. 230:hydrogen peroxide 213: 201: 194: 188: 176: 128: 116: 100: 95: 74: 67: 375: 343: 342: 324: 315: 309: 308: 280: 274: 273: 245: 224: 222: 221: 216: 214: 211: 209: 206: 199: 192: 186: 184: 181: 174: 139: 137: 136: 131: 129: 126: 124: 121: 114: 108: 105: 98: 88: 82: 79: 72: 65: 383: 382: 378: 377: 376: 374: 373: 372: 348: 347: 346: 322: 316: 312: 281: 277: 270: 246: 242: 238: 207: 202: 182: 177: 172: 170: 167: 166: 122: 117: 106: 101: 80: 75: 64: 62: 59: 58: 17: 12: 11: 5: 381: 371: 370: 365: 363:Photochemistry 360: 358:Sulfonic acids 345: 344: 310: 275: 268: 239: 237: 234: 226: 225: 205: 197: 191: 180: 141: 140: 120: 112: 104: 94: 91: 86: 78: 70: 36:sulfur dioxide 15: 9: 6: 4: 3: 2: 380: 369: 366: 364: 361: 359: 356: 355: 353: 340: 336: 332: 328: 321: 314: 306: 302: 298: 294: 290: 286: 279: 271: 265: 261: 257: 253: 252: 244: 240: 233: 231: 203: 189: 178: 165: 164: 163: 161: 157: 153: 148: 146: 118: 102: 92: 89: 84: 76: 68: 57: 56: 55: 53: 49: 45: 41: 37: 33: 28: 26: 25:sulfoxidation 22: 330: 326: 313: 288: 284: 278: 249: 243: 227: 149: 145:free-radical 142: 52:UV-radiation 29: 24: 18: 48:surfactants 368:Sulfoxides 352:Categories 269:3527306730 236:References 196:⟶ 160:sulfoxide 156:thioether 152:oxidation 111:⟶ 21:chemistry 305:18683178 32:alkanes 303:  266:  40:oxygen 323:(PDF) 158:to a 154:of a 301:PMID 264:ISBN 38:and 335:doi 331:257 293:doi 256:doi 115:RSO 19:in 354:: 329:. 325:. 299:. 289:47 287:. 262:. 232:. 212:SO 162:. 73:SO 66:RH 54:. 23:, 341:. 337:: 307:. 295:: 272:. 258:: 204:2 200:R 193:O 190:+ 187:S 179:2 175:R 127:H 119:3 103:2 99:O 93:2 90:1 85:+ 77:2 69:+

Index

chemistry
alkanes
sulfur dioxide
oxygen
alkyl sulfonic acids
surfactants
UV-radiation
free-radical
oxidation
thioether
sulfoxide
hydrogen peroxide
Ullmann's Encyclopedia of Industrial Chemistry
doi
10.1002/14356007.a25_503
ISBN
3527306730
doi
10.1002/anie.200800326
PMID
18683178
"Metal-Catalyzed Asymmetric Sulfoxidation, Epoxidation and Hydroxylation by Hydrogen Peroxide"
doi
10.1016/j.ccr.2013.05.010
Categories
Sulfonic acids
Photochemistry
Sulfoxides

Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.