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Single bond

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148: 919: 237:. In contrast, the double bond consists of one sigma bond and one pi bond, and a triple bond consists of one sigma bond and two pi bonds (Moore, Stanitski, and Jurs 396). The number of component bonds is what determines the strength disparity. It stands to reason that the single bond is the weakest of the three because it consists of only a sigma bond, and the double bond or triple bond consist not only of this type of component bond but also at least one additional bond. 160: 133: 36: 913: 925: 240:
The single bond has the capacity for rotation, a property not possessed by the double bond or the triple bond. The structure of pi bonds does not allow for rotation (at least not at 298 K), so the double bond and the triple bond which contain pi bonds are held due to this property. The sigma bond is
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Another property comparison can be made in bond length. Single bonds are the longest of the three types of covalent bonds as interatomic attraction is greater in the two other types, double and triple. The increase in component bonds is the reason for this attraction increase as more electrons are
222:. A single bond is weaker than either a double bond or a triple bond. This difference in strength can be explained by examining the component bonds of which each of these types of covalent bonds consists (Moore, Stanitski, and Jurs 393). 211:, a single bond is denoted as AːA or A-A, for which A represents an element. In the first rendition, each dot represents a shared electron, and in the second rendition, the bar represents both of the electrons shared in the single bond. 432: 1012: 241:
not so restrictive, and the single bond is able to rotate using the sigma bond as the axis of rotation (Moore, Stanitski, and Jurs 396-397).
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in which it originated. Rather, both of the two electrons spend time in either of the orbitals which overlap in the bonding process. As a
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Single bonds are also seen in molecules made up of more than two atoms. Examples of this use of single bonds include:
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larger than methane. The type of covalent bonding in hydrocarbons is extremely important in the
1123: 1084: 610: 605: 302: 203:. When shared, each of the two electrons involved is no longer in the sole possession of the 1118: 1042: 933: 796: 755: 576: 8: 944: 808: 774: 696: 590: 376:"Chemistry: The Molecular Science (Moore, John W.; Stanitski, Conrad L.; Jurs, Peter C.)" 353: 278: 93: 1108: 863: 1094: 883: 843: 833: 665: 458: 397: 249: 1135: 875: 848: 387: 192: 1113: 987: 858: 615: 305:
of these molecules. Hydrocarbons containing only single bonds are referred to as
208: 136: 155:. Note depiction of the four single bonds between the carbon and hydrogen atoms. 147: 1022: 823: 558: 542: 537: 453: 204: 1150: 1071: 1031: 964: 918: 893: 766: 747: 631: 571: 566: 547: 441: 401: 200: 184: 168: 1017: 322: 410: 1103: 853: 532: 527: 298: 219: 215: 375: 514: 498: 488: 392: 334: 318: 226: 838: 813: 636: 176: 35: 912: 503: 260: 253: 196: 140: 245:
shared between the bonded atoms (Moore, Stanitski, and Jurs 343).
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where the bond forms. Therefore, a single bond is a type of
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Single bonding even appears in molecules as complex as
60:. Unsourced material may be challenged and removed. 1148: 252:. Examples of this use of single bonds include 732: 426: 440: 739: 725: 433: 419: 391: 120:Learn how and when to remove this message 1131:Polyhedral skeletal electron pair theory 373: 158: 146: 131: 195:. That is, the atoms share one pair of 14: 1149: 720: 414: 167:. Note that all the bonds are single 143:. Note depiction of the single bond. 58:adding citations to reliable sources 29: 374:Steehler, Jack K. (December 2001). 24: 746: 325:(Moore, Stanitski, and Jurs 335). 25: 1168: 464:Introduction to quantum mechanics 354:"covalent bonding - single bonds" 923: 917: 911: 34: 248:Single bonds are often seen in 45:needs additional citations for 27:Chemical bond between two atoms 367: 346: 214:A covalent bond can also be a 13: 1: 380:Journal of Chemical Education 340: 225:Usually, a single bond is a 7: 328: 10: 1173: 829:Metal–ligand multiple bond 1093: 1070: 1001: 963: 943: 932: 909: 892: 874: 765: 754: 684: 658: 649: 624: 598: 589: 556: 512: 481: 474: 449: 651:Molecular orbital theory 163:Lewis structure for an 229:. An exception is the 172: 156: 144: 162: 150: 135: 819:Coordinate (dipolar) 151:Lewis structure for 54:improve this article 993:C–H···O interaction 775:Electron deficiency 591:Valence bond theory 313:. Examples include 978:Resonance-assisted 393:10.1021/ed078p1598 250:diatomic molecules 173: 157: 145: 1144: 1143: 1095:Electron counting 1066: 1065: 955:London dispersion 907: 906: 884:Metal aromaticity 714: 713: 710: 709: 685:Constituent units 666:Molecular orbital 645: 644: 625:Constituent units 585: 584: 459:Quantum mechanics 356:. Chemguide.co.uk 193:valence electrons 130: 129: 122: 104: 16:(Redirected from 1164: 1157:Chemical bonding 1136:Jemmis mno rules 988:Dihydrogen bonds 941: 940: 927: 921: 915: 849:Hyperconjugation 763: 762: 741: 734: 727: 718: 717: 656: 655: 596: 595: 577:Exchange-coupled 479: 478: 442:Chemical bonding 435: 428: 421: 412: 411: 406: 405: 395: 371: 365: 364: 362: 361: 350: 125: 118: 114: 111: 105: 103: 62: 38: 30: 21: 1172: 1171: 1167: 1166: 1165: 1163: 1162: 1161: 1147: 1146: 1145: 1140: 1089: 1062: 1005: 997: 959: 946: 936: 928: 922: 916: 903: 888: 870: 758: 750: 745: 715: 706: 680: 641: 620: 616:Lewis structure 581: 552: 508: 470: 445: 439: 409: 372: 368: 359: 357: 352: 351: 347: 343: 331: 292: 287:All 4 bonds in 282: 264: 257: 231:bond in diboron 209:Lewis structure 137:Lewis structure 126: 115: 109: 106: 63: 61: 51: 39: 28: 23: 22: 15: 12: 11: 5: 1170: 1160: 1159: 1142: 1141: 1139: 1138: 1133: 1128: 1127: 1126: 1121: 1116: 1111: 1100: 1098: 1091: 1090: 1088: 1087: 1082: 1076: 1074: 1068: 1067: 1064: 1063: 1061: 1060: 1055: 1050: 1045: 1040: 1035: 1025: 1020: 1015: 1009: 1007: 999: 998: 996: 995: 990: 985: 980: 975: 969: 967: 961: 960: 958: 957: 951: 949: 938: 934:Intermolecular 930: 929: 910: 908: 905: 904: 902: 901: 898: 896: 890: 889: 887: 886: 880: 878: 872: 871: 869: 868: 867: 866: 861: 851: 846: 841: 836: 831: 826: 821: 816: 811: 806: 805: 804: 794: 793: 792: 787: 782: 771: 769: 760: 756:Intramolecular 752: 751: 748:Chemical bonds 744: 743: 736: 729: 721: 712: 711: 708: 707: 705: 704: 702:Antibonding MO 699: 697:Non-bonding MO 694: 688: 686: 682: 681: 679: 678: 673: 668: 662: 660: 653: 647: 646: 643: 642: 640: 639: 634: 628: 626: 622: 621: 619: 618: 613: 608: 606:Hybrid orbital 602: 600: 593: 587: 586: 583: 582: 580: 579: 574: 569: 563: 561: 554: 553: 551: 550: 545: 540: 535: 530: 525: 519: 517: 510: 509: 507: 506: 501: 496: 491: 485: 483: 476: 475:Types of bonds 472: 471: 469: 468: 467: 466: 456: 454:Atomic orbital 450: 447: 446: 438: 437: 430: 423: 415: 408: 407: 366: 344: 342: 339: 338: 337: 330: 327: 319:2-methylbutane 295: 294: 290: 285: 280: 277:Both bonds in 262: 255: 233:, which is a 191:involving two 169:covalent bonds 139:for molecular 128: 127: 110:September 2023 42: 40: 33: 26: 9: 6: 4: 3: 2: 1169: 1158: 1155: 1154: 1152: 1137: 1134: 1132: 1129: 1125: 1122: 1120: 1117: 1115: 1112: 1110: 1109:Hückel's rule 1107: 1106: 1105: 1102: 1101: 1099: 1096: 1092: 1086: 1083: 1081: 1078: 1077: 1075: 1073: 1072:Bond cleavage 1069: 1059: 1056: 1054: 1051: 1049: 1046: 1044: 1041: 1039: 1038:Intercalation 1036: 1033: 1029: 1028:Metallophilic 1026: 1024: 1021: 1019: 1016: 1014: 1011: 1010: 1008: 1004: 1000: 994: 991: 989: 986: 984: 981: 979: 976: 974: 971: 970: 968: 966: 962: 956: 953: 952: 950: 948: 945:Van der Waals 942: 939: 935: 931: 926: 920: 914: 900: 899: 897: 895: 891: 885: 882: 881: 879: 877: 873: 865: 862: 860: 857: 856: 855: 852: 850: 847: 845: 842: 840: 837: 835: 832: 830: 827: 825: 822: 820: 817: 815: 812: 810: 807: 803: 800: 799: 798: 795: 791: 788: 786: 783: 781: 778: 777: 776: 773: 772: 770: 768: 764: 761: 757: 753: 749: 742: 737: 735: 730: 728: 723: 722: 719: 703: 700: 698: 695: 693: 690: 689: 687: 683: 677: 674: 672: 669: 667: 664: 663: 661: 657: 654: 652: 648: 638: 635: 633: 632:Covalent bond 630: 629: 627: 623: 617: 614: 612: 609: 607: 604: 603: 601: 597: 594: 592: 588: 578: 575: 573: 570: 568: 565: 564: 562: 560: 555: 549: 546: 544: 543:5 (quintuple) 541: 539: 538:4 (quadruple) 536: 534: 531: 529: 526: 524: 521: 520: 518: 516: 511: 505: 502: 500: 497: 495: 492: 490: 487: 486: 484: 480: 477: 473: 465: 462: 461: 460: 457: 455: 452: 451: 448: 443: 436: 431: 429: 424: 422: 417: 416: 413: 403: 399: 394: 389: 385: 381: 377: 370: 355: 349: 345: 336: 333: 332: 326: 324: 320: 316: 312: 308: 304: 300: 293: 286: 284: 276: 275: 274: 271: 269: 265: 258: 251: 246: 242: 238: 236: 232: 228: 223: 221: 217: 212: 210: 206: 202: 201:covalent bond 198: 194: 190: 186: 185:chemical bond 182: 178: 170: 166: 161: 154: 149: 142: 138: 134: 124: 121: 113: 102: 99: 95: 92: 88: 85: 81: 78: 74: 71: –  70: 69:"Single bond" 66: 65:Find sources: 59: 55: 49: 48: 43:This article 41: 37: 32: 31: 19: 1114:Baird's rule 834:Charge-shift 797:Hypervalence 548:6 (sextuple) 522: 515:multiplicity 386:(12): 1598. 383: 379: 369: 358:. Retrieved 348: 323:cyclopentane 303:nomenclature 299:hydrocarbons 296: 272: 247: 243: 239: 224: 213: 187:between two 180: 174: 116: 107: 97: 90: 83: 76: 64: 52:Please help 47:verification 44: 1104:Aromaticity 1080:Heterolysis 1058:Salt bridge 1003:Noncovalent 973:Low-barrier 854:Aromaticity 844:Conjugation 824:Pi backbond 482:By symmetry 220:triple bond 216:double bond 181:single bond 18:Single-bond 1032:aurophilic 1013:Mechanical 692:Bonding MO 676:MO diagram 533:3 (triple) 528:2 (double) 523:1 (single) 360:2012-08-12 341:References 335:Bond order 227:sigma bond 80:newspapers 1124:spherical 1085:Homolysis 1048:Cation–pi 1023:Chalcogen 983:Symmetric 839:Hapticity 637:Lone pair 611:Resonance 499:Delta (δ) 489:Sigma (σ) 402:0021-9584 197:electrons 177:chemistry 1151:Category 1053:Anion–pi 1043:Stacking 965:Hydrogen 876:Metallic 767:Covalent 759:(strong) 659:Concepts 599:Concepts 329:See also 141:hydrogen 1018:Halogen 864:bicyclo 809:Agostic 572:Singlet 567:Triplet 504:Phi (φ) 307:alkanes 235:pi bond 205:orbital 153:methane 94:scholar 1119:Möbius 947:forces 937:(weak) 494:Pi (π) 444:theory 400:  321:, and 315:ethane 266:, and 165:alkane 96:  89:  82:  75:  67:  1097:rules 1006:other 894:Ionic 802:3c–4e 790:8c–2e 785:4c–2e 780:3c–2e 218:or a 189:atoms 183:is a 101:JSTOR 87:books 859:homo 814:Bent 671:LCAO 559:spin 398:ISSN 311:-ane 179:, a 73:news 557:By 513:By 388:doi 268:HCl 175:In 56:by 1153:: 396:. 384:78 382:. 378:. 317:, 289:CH 270:. 259:, 1034:) 1030:( 740:e 733:t 726:v 434:e 427:t 420:v 404:. 390:: 363:. 291:4 283:O 281:2 279:H 263:2 261:F 256:2 254:H 171:. 123:) 117:( 112:) 108:( 98:· 91:· 84:· 77:· 50:. 20:)

Index

Single-bond

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Lewis structure for molecular hydrogen.
Lewis structure
hydrogen
Lewis structure for methane.
methane
Lewis structure for an alkane.
alkane
covalent bonds
chemistry
chemical bond
atoms
valence electrons
electrons
covalent bond
orbital
Lewis structure
double bond
triple bond

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