22:
38:
263:
Ice core samples from a single spot in
Antarctica were found to have tiny inclusions of magnesium methanesulfonate dodecahydrate. This natural phase is recognized as the mineral
383:
Valerie
Vaillancourt, Michele M. Cudahy, Matthew M. Kreilein and Danielle L. Jacobs "Methanesulfonyl Chloride" in E-EROS Encyclopedia for Reagents in Organic Synthesis.
401:
264:
359:; Yeun-Min Tsai; David M. Fink (1966). "A General Method for the Synthesis of Allenylsilanes: 1-Methyl-1-(trimethylsilyl)allene".
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Güner, Fatma Elif
Genceli; Sakurai, Toshimitsu; Hondoh, Takeo (2013).
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is often referred to as mesyl chloride. Whereas mesylates are often
281:
276:
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117:
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Mesylate esters are generally prepared by treating an alcohol and
402:"Ernstburkeite, Mg(CH3SO3)2·12H2O, a new mineral from Antarctica"
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216:
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108:
containing the group or anion, the spelling used is sometimes
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62:
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335:(6th ed.). John Wiley & Sons. p. 497.
374:. (a procedure illustrating the use of mesylates).
215:appears in a variety of medications, particularly
16:Salt or ester of methanesulfonic acid (CH₃–SO₂–OH)
449:
312:. February 2006. INN Working Document 05.167/3
81:). In salts, the mesylate is present as the
303:International Nonproprietary Names Modified
330:
331:Smith, Michael B.; March, Jerry (2007).
36:
20:
207:labile, mesyl groups, when attached to
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284:, the fluorinated analog of mesylate.
258:
211:, are resistant to hydrolysis. This
13:
333:March's Advanced Organic Chemistry
14:
474:
102:international nonproprietary name
426:10.1127/0935-1221/2013/0025-2257
123:Mesylate esters are a group of
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406:European Journal of Mineralogy
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1:
389:10.1002/047084289X.rm070.pub2
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191:(Ms) or methanesulfonyl (CH
187:Related to mesylate is the
151:. Mesylate is considered a
131:with the general structure
10:
479:
310:World Health Organization
227:moiety. Examples include
157:nucleophilic substitution
371:10.15227/orgsyn.066.0001
267:. It is extremely rare.
201:Methanesulfonyl chloride
182:
169:methanesulfonyl chloride
147:, where R is an organic
106:pharmaceutical substance
116:, the mesylate salt of
51:organosulfur chemistry
46:
34:
171:in the presence of a
100:. When modifying the
40:
24:
199:) functional group.
127:that share a common
67:methanesulfonic acid
43:ball-and-stick model
418:2013EJMin..25...78G
259:Natural occurrence
47:
35:
31:structural formula
362:Organic Syntheses
357:Rick L. Danheiser
342:978-0-471-72091-1
125:organic compounds
114:imatinib mesilate
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213:functional group
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129:functional group
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41:Mesylate anion (
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458:Leaving groups
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223:) drugs, as a
221:antiarrhythmic
205:hydrolytically
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143:, abbreviated
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439:Ernstburkeite
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265:ernstburkeite
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190:
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177:triethylamine
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153:leaving group
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412:(1): 78–83.
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314:. Retrieved
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262:
188:
186:
166:
122:
113:
109:
54:
48:
18:
241:dronedarone
225:sulfonamide
163:Preparation
159:reactions.
149:substituent
463:Sulfonates
452:Categories
316:5 December
308:(Report).
289:References
253:bitopertin
245:dofetilide
237:sematilide
175:, such as
233:ibutilide
25:Mesylate
441:, Mindat
282:Triflate
277:Tosylate
271:See also
209:nitrogen
118:imatinib
110:mesilate
55:mesylate
414:Bibcode
229:sotalol
217:cardiac
112:(as in
57:is any
339:
251:, and
249:E-4031
306:(PDF)
189:mesyl
183:Mesyl
145:MsO−R
104:of a
98:anion
63:ester
27:anion
337:ISBN
318:2008
173:base
59:salt
53:, a
422:doi
385:doi
367:doi
155:in
141:O−R
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65:of
61:or
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410:25
408:.
404:.
365:.
255:.
247:,
243:,
239:,
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231:,
195:SO
179:.
137:SO
133:CH
87:SO
83:CH
75:SO
71:CH
428:.
424::
416::
387::
369::
345:.
320:.
219:(
197:2
193:3
139:2
135:3
93:3
90:−
85:3
79:H
77:3
73:3
69:(
45:)
33:)
29:(
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
