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Lutetium–hafnium dating

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1566: 536: 2406: 2397:, ɛHf values ranging from −31.9 to −21.9 were obtained, representing a crustal melt origin. Apatite has also promising Lu–Hf information, as apatite has high Lu content relative to Hf content. In cases where rocks are silica-poor, if more evolved rocks of the same magmatic origin can be identified, apatite could provide high Lu/Hf ratio data to produce accurate isochron, with an example from Smålands Taberg, southern Sweden, where apatite Lu/Hf age of 1204.3±1.8 million yr was identified as the lower boundary of a 1.2 billion yr magmatic event that caused the Fe–Ti mineralization at Smålands Taberg. 2484: 1551:. This also means a higher Lu/Hf ratio in sample. Positive value would be found in the residue solid after melt extraction, as the liquid would be enriched in Hf. It is worth noting that the enrichment of Hf in melt would means removing the more abundant isotopes of Hf to a larger extent than Hf, resulting in the observed Hf/Hf enrichment in residue solid. Using the same logic, a negative ɛHf value would represent the extracted melt from reservoir, forming an evolved, juvenile material. 130:, with one naturally-occurring stable isotope Lu and one naturally-occurring radioactive isotope Lu. When Lu atoms are incorporated into earth materials, such as rocks and minerals, they began to be "trapped" while starting to decay. Through radioactive decay, an unstable nucleus decays into another relatively stable one. Radiometric dating makes use of the decay relationship to calculate how long the atoms have been "trapped", i.e. the time since the earth material was formed. 1574: 1491: 2458:. With the help of garnet Lu/Hf ages, a study on Lago di Cignana, western Alps, Italy, an age of 48.8±2.1 million yr for lower boundary of garnet growth time was identified. From this, the burial rate of ultra-high-pressure rocks at Lago di Cignana was estimated to be 0.23–0.47 cm/yr, which suggest ocean floor rocks were carried down to subduction and reached ultra-high-pressure metamorphism conditions. 20: 990:. A common practice for geochronological dating is to establish an isochron plot. Multiple set of data would be measured and plotted with Hf/Hf on y-axis and Lu/Hf on x-axis. A linear relationship would be obtained. The initial ratio can either be assumed to be natural isotopic abundance ratio or, for a better approach, obtained from the y-intercept of plotted 771: 2358:
dissolution of Lu and Hf bearing materials. The technique of isotope dilution is often necessary for precise determination of concentrations. Isotope dilution is done by adding materials of known concentration of Lu and Hf into the dissolved samples. The samples can then go through TIMS for data acquisition.
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Another low-temperature, high-pressure metamorphic index mineral, lawsonite was brought into use in recent years to understand subduction metamorphism using Lu/Hf dating. A study showed that lawsonite could be significant in dating low-temperature metamorphic rocks, typically in prograde metamorphism
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The above sample preparation procedures prevent convenient analysis of Lu–Hf, thus limiting its usage in the 1980s. Also, the age determination using TIMS require samples of high Lu and Hf concentration to be successful. However, common mineral phases have low concentrations of Lu and Hf, which again
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Hf ages determined from detrital zircon can help to identify major event of crustal growth. By analyzing detrital zircon in Yangtze River sediments, a group of researchers produced a statistical distribution of Hf model ages of the sediments. The statistical peaks of age ranges were identified: 2000
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Conventional isochron ages are obtained from bulk garnet separates and are only an estimate of the average age of the overall growth of garnet. To give precise estimates of the pace of growth of a single garnet crystal, geochronologists use microsampling methods to collect and date small consecutive
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Schematic diagram showing elemental movement starting from planetesimal formation. Light blue particles represent volatile elements, which will not condense during early Earth formation. Dark brown and orange particles are both refractory elements which condense to form the solid Earth (indicated by
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The crust formation process is supposedly chemically depleting the mantle, as crust forms from partial melts originating from the mantle. However, the process and extent of depletion could not be concluded based on a few isotope characteristics, as some isotope systems are thought to be susceptible
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model age is the age at which the material, from which rock and mineral forms, leaves the chondritic uniform reservoir, i.e. the mantle, when assuming the silicate earth retained chemical signature of chondritic uniform reservoir. As described in previous section, melting will cause a fractionation
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Hf ages from detrital zircon also help tracing sediment source. A study on detrital zircon from sandstones in the Oslo Rift, Norway identified major sediment source in Fennoscandia region and also a minor source in Variscan Mountains of central Europe during Late Devonian to Late Carboniferous by
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elements and relatively immobile. However, Hf is more incompatible than Lu, and thus it is relatively enriched in the crust and in silicate melts. Thus, a higher Lu/Hf ratio (also meaning a higher Hf / Hf ratio, over time, due to Lu decay) is generally found in the residual solid during partial
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An age equation is set up for every radiometric dating technique to describe the mathematical relationship of the number of parent and daughter nuclide. In Lu–Hf system, the parent would be Lu (the radioactive isotope) and Hf as the daughter nuclide (the product after radioactive decay). The age
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to form the solid part of Earth, as opposed to volatile elements. The two elements as a result would not be found in Earth's early atmosphere. Due to these characteristics, the two elements are relatively stationary throughout planetary evolution and are thought to retain the isotopic abundance
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can be obtained through direct counting experiments and by comparing Lu–Hf ages with other isotope system ages of samples whose ages are determined. The commonly accepted decay constant has the value of 1.867 (± 0.007) × 10 yr. However, there remain discrepancies on the value of decay constant.
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in a Teflon bomb. The bomb is put in oven at 160 °C for four days. Following that comes acids treatment for purification from major elements and other undesirable trace elements. Different studies may use slightly different protocols and procedures, but all are trying to ensure complete
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of Lu and Hf in the melt and residue solid, thus resulting in Lu/Hf and Hf/Hf values deviating from chondritic uniform reservoir values. The time or age at which the Lu/Hf and Hf/Hf values from the sample and chondritic uniform reservoir matches is the chondritic uniform reservoir model age.
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are used to model the chemistry of the silicate layers of Earth as these layers were unaffected by planetary evolution processes. To characterise the chondritic uniform reservoir composition in terms of Lu and Hf, chondrites of different petrological types are used for analysing Lu and Hf
601: 1507:(earth-loving) elements, meaning they are mainly found in the silicate fraction of Earth, i.e. the mantle and crust. During the formation of the Earth, the two elements tended not be fractionated into the core during core formation, i.e. not concentrated in the core, unlike 3563:
Schmidt, Alexander; Pourteau, Amaury; Candan, Osman; Oberhänsli, Roland (2015). "Lu–Hf geochronology on cm-sized garnets using microsampling: New constraints on garnet growth rates and duration of metamorphism during continental collision (Menderes Massif, Turkey)".
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Ur, Hafiz; Kobayashi, Katsura; Tsujimori, Tatsuki; Ota, Tsutomu; Nakamura, Eizo; Yamamoto, Hiroshi; Kaneko, Yoshiyuki; Kh, Tahseenullah (2012). "Sm-Nd and Lu-Hf Isotope Geochemistry of the Himalayan High- and Ultrahigh-Pressure Eclogites, Kaghan Valley, Pakistan".
2369:(ICP–MS). ICP–MS, with multi-collector, allow precision determination with materials with low Hf concentration, such as apatite and garnet. The amount of sample needed for determination is also smaller, facilitating utilization of zircon for Lu–Hf ages. 3351:
Hollocher, K; Robinson, P; Terry, M P; Walsh, E (2007). "Application of major- and trace-element geochemistry to re ne U-Pb zircon, and Sm/Nd or Lu/Hf sampling targets for geochronology of HP and UHP eclogites, Western Gneiss Region, Norway".
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Lapen, T J; Johnson, C M; Baumgartner, L P; Mahlen, N J; Beard, B L; Amato, J M (2003). "Burial rates during prograde metamorphism of an ultra-high-pressure terrane: an example from Lago di Cignana, western Alps, Italy".
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Lagos, Markus; Scherer, Erik E.; Tomaschek, Frank; Münker, Carsten; Keiter, Mark; Berndt, Jasper; Ballhaus, Chris (2007). "High precision Lu–Hf geochronology of Eocene eclogite-facies rocks from Syros, Cyclades, Greece".
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A schematic Hf evolution diagram.The black curve is plotted using Hf/Hf values from Patchett and Tatsumoto (1980). All other curves and values are hypothetical. 4.55 billion year was assumed to be the time of Earth
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Bouvier, A; Vervoort, J D; Patchett, P J (2008). "The Lu–Hf and Sm–Nd isotopic composition of CHUR: Constraints from unequilibrated chondrites and implications for the bulk composition of terrestrial planets".
766:{\displaystyle \left({\frac {{\ce {^{176}Hf}}}{{\ce {^{177}Hf}}}}\right)=\left({\frac {{\ce {^{176}Hf}}}{{\ce {^{177}Hf}}}}\right)_{i}+\left({\frac {{\ce {^{176}Lu}}}{{\ce {^{177}Hf}}}}\right)(e^{\lambda t}-1)} 93:(ICP–MS) with multi-collector (also known as MC–ICP–MS) in later years, the dating method is made applicable to date diverse earth materials. The Lu–Hf system is now a common tool in geological studies such as 322: 1332: 252: 3768:
Liu, X C; Wu, Y B; Fisher, C M; Hanchar, J M; Beranek, L; Gao, S; Wang, H (2017). "Tracing crustal evolution by U-Th-Pb, Sm-Nd, and Lu-Hf isotopes in detrital monazite and zircon from modern rivers".
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of 37.1 billion years, the long-living Lu–Hf decay pair survives through geological time scales, thus is useful in geological studies. Due to chemical properties of the two elements, namely their
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Gruau, G.; Rosing, M.; Bridgwater, D.; Gill, R.C.O (1996). "Resetting of Sm-Nd systematics during metamorphism of 3.7-Ga rocks: implications for isotopic models of early Earth differentiation".
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Cheng, Hao; Vervoort, Jeffrey D.; Dragovic, Besim; Wilford, Diane; Zhang, Lingmin (2018). "Coupled Lu–Hf and Sm–Nd geochronology on a single eclogitic garnet from the Huwan shear zone, China".
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Cheng, H.; King, R. L.; Nakamura, E.; Vervoort, J. D.; Zhou, Z. (2008). "Coupled Lu-Hf and Sm-Nd geochronology constrains garnet growth in ultra-high-pressure eclogites from the Dabie orogen".
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Cheng, H.; Liu, X. C.; Vervoort, J. D.; Wilford, D.; Cao, D. D. (2016-03-15). "Micro-sampling Lu-Hf geochronology reveals episodic garnet growth and multiple high-Pmetamorphic events".
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to re-setting by metamorphism. To further constrain the modelling of depleted mantle, Lu–Hf information from zircons are useful, as zircons are resistant to Lu–Hf re-equilibrating.
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Patchett, P J; Vervoort, J D; Soderlund, U; Salters, V J M (2004). "Lu–Hf and Sm–Nd isotopic systematics in chondrites and their constraints on the Lu–Hf properties of the Earth".
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Ma–1200 Ma, 2700 Ma–2400 Ma, and 3200 Ma-2900 Ma, indicating crustal growth events at ages of Paleoproterozoic to Mesoproterozoic, and of Archean in the South China Block.
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Söderlund, U; Patchett, P J; Vervoort, J; Isachsen, C (2004). "The 176Lu decay constant determined by Lu-Hf and U-Pb isotope systematics of Precambrian mafic intrusions".
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the black circle). Dark brown particles represent siderophile elements that sink to the centre of Earth during core formation while the orange lithophile elements do not.
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Anczkiewicz, Robert; Thirlwall, Matthew F. (2003). "Improving precision of Sm-Nd garnet dating by H2SO4leaching: a simple solution to the phosphate inclusion problem".
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The trace concentration of the Lu and Hf in earth materials posed some technological difficulties in using Lu–Hf dating extensively in the 1980s. With the use of
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Larsson, D; Söderlund, U (2005). "Lu–Hf apatite geochronology of mafic cumulates: An example from a Fe–Ti mineralization at Smålands Taberg, southern Sweden".
1897: 1346: 1144:. The usage of ɛHf value is a common practice in Hf studies. ɛHf has a range of value from +15 to -70 at present. ɛHf is expressed in the following equation: 2249:
ratios yielded varies by 14 ɛHf units. One later study focused on chondrites of petrological types 1 to 3, which are unequilibrated, show variation of 3% in
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Smit, M A; Scherer, E E; Mezger, K (2013). "Lu–Hf and Sm–Nd garnet geochronology: Chronometric closure and implications for dating petrological processes".
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Kristoffersen, M; Andersen, T; Andersen, A (2014). "U–Pb age and Lu–Hf signatures of detrital zircon from Palaeozoic sandstones in the Oslo Rift, Norway".
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in a subduction zone settings, as garnets are formed after lawsonite is stabilized, so that lawsonite can be enriched in Lu for radiometric dating.
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Vervoort, J D; Patchett, P J; Gehrels, G E; Nutman, A P (1996). "Constraints on early Earth differentiation from hafnium and neodymium isotopes".
2450:. This means garnets generally have high Lu/Hf ratios. Dating of garnets with Lu–Hf could provide information of history of garnet growth during 1598: 986:
The two isotopes, Lu and Hf, in the system are measured as ratio to the reference stable isotope of Hf. The measured ratio can be obtained from
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Mulcahy, S R; Vervoort, J D; Renne, P R (2014). "Dating subduction-zone metamorphism with combined garnet and lawsonite Lu–Hf geochronology".
1341:"0" in the bracket denoting time = 0, meaning present day. Numbers in bracket can represent any time in the past up to the formation of Earth. 2366: 90: 2385:
Lu–Hf isotope system can provide information on where and when a magmatic body originate. By applying Hf concentration determination to
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melting and removal of a liquid from a geochemical reservoir. It is worth noting that variation in Lu/Hf ratio is usually very small.
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Mulcahy, S R; King, R L; Vervoort, J D (2009). "Lawsonite Lu-Hf geochronology: A new geochronometer for subduction zone processes".
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Blichert-Toft, J; Albarède, F (1997). "The Lu-Hf isotope geochemistry of chondrites and the evolution of the mantle-crust system".
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In the earliest years, at around the 1980s, age acquisition based on Lu–Hf system make use of chemical dissolution of sample and
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Selective dissolution, i.e. dissolving the garnet but leaving the refractory inclusions intact, is applied to the Lu–Hf system.
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concentration is low is the two eclogites, Lu/Hf ratios is high, therefore enabling concentration determination of Lu and Hf.
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Garnets play an important role in Lu/Hf applications, as they are common metamorphic minerals while having high affinity to
433:, a lighter element. However, as the major mode of decay is by β emission, i.e. release of electron (e), as in the case for 2350: 3092:
Patchett, P J; Tatsumoto, M (1980). "A routine high-precision method for Lu-Hf isotope geochemistry and chronology".
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Goodge, J W; Vervoort, J D (2006). "Origin of Mesoproterozoic A-type granites in Laurentia: Hf isotope evidence".
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were formed from ocean-island basalt with contamination from sediments to produce the intermediate ɛHf values.
1512: 2298: 2252: 2206: 2160: 2114: 2068: 1097: 1051: 2885:; Vervoort, J; Albarède, F (2006). "Effects of impacts on Sm-Nd and Lu-Hf internal isochrons of eucrites". 2405: 2058: 2042: 2029: 1886: 1588: 1548: 1544: 1521: 1478: 1141: 502: 469: 436: 403: 366: 333: 156: 3865: 1500: 1001: 951: 557: 2413:
In understanding metamorphic rocks, Lu–Hf can still provide information of origin. In cases where
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The original figure 9 from Rehman et al. (2012) showed an intermedia, mixed ɛHf trend for the
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is the Hf-176 to Hf-177 ratio in the sample. For t = 0, it represent the ratio at present.
1402:{\displaystyle \left({\frac {{\ce {^{176}Hf}}}{{\ce {^{177}Hf}}}}\right)_{{\ce {sample}}}} 8: 2882: 1516: 1508: 51: 3819: 3781: 3733: 3698: 3655: 3620: 3533: 3482: 3365: 3329: 3251: 3199: 3148: 3105: 2021:{\displaystyle \left({\frac {{\ce {^{176}Hf}}}{{\ce {^{177}Hf}}}}\right)_{{\ce {CHUR}}}} 1470:{\displaystyle \left({\frac {{\ce {^{176}Hf}}}{{\ce {^{177}Hf}}}}\right)_{{\ce {CHUR}}}} 3841: 3745: 3667: 3502: 3377: 3219: 3168: 3117: 2447: 2440: 2157:
ratios remain. Earlier studies experimented on chondrites of all petrologic types. The
1504: 127: 118: 67: 59: 3706: 3455: 3037: 2933: 3870: 3845: 3671: 3589: 3545: 3506: 3494: 3381: 3263: 3223: 3211: 3207: 3172: 3160: 3121: 2989: 2863: 2758: 2706: 2569: 987: 549: 145: 35: 3053: 1547:. A positive ɛHf value means that Hf concentration in sample is larger than that of 1543:ɛHf values are closely related to the enrichment or depletion of Hf relative to the 16:
Gochronological dating method utilizing the radioactive decay system of lutetium–176
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Dixon, D; McNair, A; Curran, S C (1954). "The natural radioactivity of lutetium".
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model are tightly constrained in order to use Lu–Hf system for age determination.
3719: 3432: 995: 991: 2948:"Hf analytical methods at the Arizona LaserChron Center (University of Arizona)" 2880: 3585: 3416: 3302: 3075: 2911: 2831: 2806: 2780:
The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science
2636: 2390: 3827: 2791: 3859: 3593: 3549: 3498: 3267: 3215: 3164: 2433: 2422: 1531: 31: 3684: 1862:{\displaystyle t_{{\ce {CHUR}}}=\left({\frac {1}{\lambda }}\right)\ln \left} 539:
Original figure 2 from Debaille et al. (2017); An example of Lu/Hf isochron.
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Arizona Laserchron Center, Department of Geosciences, University of Arizona
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The most common analytical methods for Lu–Hf determination nowadays is by
3373: 3350: 1573: 79: 2353:(TIMS). Generally, rock samples are powdered and treated with HF and HNO 3836: 3113: 2400: 3805: 3767: 3663: 3628: 3490: 2804: 2705:. John Wiley & Sons, Inc., Hoboken, New Jersey. pp. 284–296. 2057:, and to further extent meaning the primitive undifferentiated Earth. 1490: 3789: 3741: 2425: 2394: 2046: 397: 83: 71: 47: 2613: 1569:
Original figure 9 from Rehman et al. (2012); An example of ɛHf plot.
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is the initial ratio of the two isotopes when the sample is formed.
327: 151: 123: 39: 3606: 2985: 2429: 317:{\displaystyle {\ce {{^{176}_{71}Lu}+e^{-}->{^{176}_{70}Yb}}}} 43: 1327:{\displaystyle \varepsilon _{{\ce {Hf}}(0)}=\left\times 10\,000} 3562: 2807:"The role of phosphates for the Lu–Hf chronology of meteorites" 2414: 2386: 247:{\displaystyle {\ce {^{176}_{71}Lu->{^{176}_{72}Hf}+e^{-}}}} 75: 63: 19: 3394: 2496:
U–Pb and Lu–Hf characteristics of source rocks and sediments.
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Vervoort J (2014). "Lu-Hf Dating: The Lu-Hf Isotope System".
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Garnet, a common metamorphic mineral target for Lu/Hf dating.
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that was studied. The experimental result indicate that the
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is the measured ratio of the two isotopes of the sample.
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is the measured ratio of the two isotopes of the sample.
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can be candidate for Hf analysis. Although the overall
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characteristics of primitive planetary material, i.e.
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Debaille, V; Van Orman, J; Yin, Q; Amelin, Y (2017).
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Metamorphic rock petrogenesis and metamorphic events
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elements (iron-loving elements). Lu and Hf are also
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is of negligible effect to Lu–Hf age determination.
2417:phase is absent or very low in abundance, such as 2333: 2287: 2241: 2203:ratios yielded varies by 18%, or even by 28%. The 2195: 2149: 2103: 2020: 1952: 1861: 1515:elements, meaning they quickly condensed from the 1469: 1401: 1326: 1132: 1086: 1032: 971: 934: 880: 823: 765: 577: 524: 491: 458: 425: 388: 355: 316: 246: 178: 150:The only natural occurring radioactive isotope of 2478: 2036: 3857: 3137:Geological Society, London, Special Publications 105:, early earth mantle-crust differentiation, and 1481:. For t = 0, it represent the ratio at present. 543: 70:, while Hf is usually found in trace amount in 2846:Luo, J; Kong, X (2006). "Half-life of 176Lu". 2845: 881:{\displaystyle {\ce {(^{176}Hf/^{177}Hf)_i}}} 2380: 2367:inductively coupled plasma mass spectrometry 1960:is the Hf-176 to Hf-177 ratio in the sample. 91:inductively coupled plasma mass spectrometry 935:{\displaystyle {\ce {(^{176}Lu/^{177}Hf)}}} 824:{\displaystyle {\ce {(^{176}Hf/^{177}Hf)}}} 2752: 2555: 23:Zircon, a common target for Lu–Hf analysis 3835: 3094:Contributions to Mineralogy and Petrology 2830: 2558:Encyclopedia of Scientific Dating Methods 2334:{\displaystyle {\ce {^{176}Hf/^{177}Hf}}} 2288:{\displaystyle {\ce {^{176}Lu/^{177}Hf}}} 2242:{\displaystyle {\ce {^{176}Hf/^{177}Hf}}} 2196:{\displaystyle {\ce {^{176}Lu/^{177}Hf}}} 2150:{\displaystyle {\ce {^{176}Hf/^{177}Hf}}} 2104:{\displaystyle {\ce {^{176}Lu/^{177}Hf}}} 1538: 1320: 1133:{\displaystyle {\ce {^{176}Hf/^{177}Hf}}} 1087:{\displaystyle {\ce {^{176}Hf/^{177}Hf}}} 982:t is the time since the sample is formed. 58:, Lu is usually found in trace amount in 2482: 2470:Early Earth mantle-crust differentiation 2404: 1572: 1564: 1489: 595:equation to Lu–Hf system is as follows: 534: 18: 2978:Geochemistry - Earth's System Processes 3858: 2970: 2968: 1043: 3801: 3799: 3763: 3761: 3759: 3428: 3426: 3087: 3085: 3049: 3047: 3011: 3009: 3007: 3005: 2748: 2746: 2744: 2742: 2696: 2694: 2692: 2690: 2688: 2686: 2684: 2682: 2680: 2678: 2676: 2674: 2672: 2670: 2668: 2666: 2609: 2607: 2605: 2551: 2549: 2547: 2545: 2543: 2541: 2539: 2537: 2535: 2533: 2531: 2529: 2487:Oslo Rift, also known as Oslo Graben. 2344: 2028:is the Hf-176 to Hf-177 ratio in the 1477:is the Hf-176 to Hf-177 ratio in the 525:{\displaystyle {\ce {^{176}_{70}Yb}}} 492:{\displaystyle {\ce {^{176}_{72}Hf}}} 459:{\displaystyle {\ce {^{176}_{71}Lu}}} 426:{\displaystyle {\ce {^{176}_{70}Yb}}} 389:{\displaystyle {\ce {^{176}_{72}Hf}}} 356:{\displaystyle {\ce {^{176}_{71}Lu}}} 179:{\displaystyle {\ce {^{176}_{71}Lu}}} 112: 2740: 2738: 2736: 2734: 2732: 2730: 2728: 2726: 2724: 2722: 2703:Isotopes: Principles and application 2664: 2662: 2660: 2658: 2656: 2654: 2652: 2650: 2648: 2646: 2603: 2601: 2599: 2597: 2595: 2593: 2591: 2589: 2587: 2585: 2527: 2525: 2523: 2521: 2519: 2517: 2515: 2513: 2511: 2509: 2351:thermal ionization mass spectrometry 1486:Geochemistry of lutetium and hafnium 589: 3566:Earth and Planetary Science Letters 3436:Earth and Planetary Science Letters 3397:Earth and Planetary Science Letters 3283:Earth and Planetary Science Letters 3056:Earth and Planetary Science Letters 3018:Earth and Planetary Science Letters 2965: 2914:Earth and Planetary Science Letters 2887:Meteoritics & Planetary Science 2811:Earth and Planetary Science Letters 2617:Earth and Planetary Science Letters 2049:represent primitive materials from 13: 3796: 3756: 3423: 3082: 3044: 3002: 1094:ratio of a sample with respect to 186:decays in the following two ways: 14: 3887: 2719: 2643: 2582: 2506: 1582: 1033:{\displaystyle (e^{\lambda t}-1)} 133: 3208:10.1111/j.1525-1314.2008.00785.x 972:{\displaystyle {\ce {^{176}Lu}}} 578:{\displaystyle {\ce {^{176}Lu}}} 3713: 3678: 3635: 3600: 3556: 3513: 3462: 3388: 3344: 3309: 3274: 3230: 3179: 3128: 2940: 2701:Faure, G; Mensing, T M (2005). 2375: 46:–176. With a commonly accepted 3644:Journal of Metamorphic Geology 3471:Journal of Metamorphic Geology 3188:Journal of Metamorphic Geology 2905: 2874: 2860:10.1016/j.apradiso.2005.11.013 2848:Applied Radiation and Isotopes 2839: 2798: 2771: 2566:10.1007/978-94-007-6326-5_46-1 2479:Detrital zircon and provenance 2037:Lu/Hf and Hf/Hf ratios of CHUR 1296: 1290: 1238: 1232: 1170: 1164: 1048:ɛHf value is an expression of 1027: 1005: 927: 900: 870: 843: 816: 789: 760: 738: 294: 211: 1: 3707:10.1016/S0009-2541(96)00092-7 3542:10.1016/j.chemgeo.2017.11.018 3456:10.1016/S0012-821X(03)00455-2 3338:10.1016/j.chemgeo.2005.07.007 3260:10.1016/j.chemgeo.2007.04.008 3157:10.1144/gsl.sp.2003.220.01.05 3038:10.1016/S0012-821X(97)00040-X 2934:10.1016/S0012-821X(04)00012-3 2499: 2059:Chondritic uniform reservoir 2053:which later accrete to form 2043:chondritic uniform reservoir 2030:chondritic uniform reservoir 1887:chondritic uniform reservoir 1589:chondritic uniform reservoir 1549:chondritic uniform reservoir 1545:chondritic uniform reservoir 1522:chondritic uniform reservoir 1479:chondritic uniform reservoir 1142:chondritic uniform reservoir 544:Decay constant determination 34:dating method utilizing the 7: 2295:ratios, and 4 ɛHf units in 2065:However, discrepancies of 1503:scheme, Lu and Hf are both 994:. The slope of the plotted 10: 3892: 3586:10.1016/j.epsl.2015.09.015 3417:10.1016/j.epsl.2013.08.046 3303:10.1016/j.epsl.2006.01.040 3076:10.1016/j.epsl.2004.02.030 2832:10.1016/j.epsl.2017.05.039 2637:10.1016/j.epsl.2008.06.010 2462:zones of garnet crystals. 1501:Goldschmidt classification 547: 143: 137: 116: 3828:10.1017/S0016756813000885 2792:10.1080/14786440708520476 2381:Igneous rock petrogenesis 2314: 2268: 2222: 2176: 2130: 2084: 2002: 1988: 1934: 1920: 1837: 1823: 1787: 1773: 1738: 1724: 1688: 1674: 1451: 1437: 1383: 1369: 1276: 1262: 1218: 1204: 1113: 1067: 967: 948:is the decay constant of 730: 716: 681: 667: 637: 623: 573: 520: 487: 454: 421: 384: 351: 311: 279: 228: 210: 174: 62:loving minerals, such as 2309: 2303: 2263: 2257: 2217: 2211: 2171: 2165: 2125: 2119: 2079: 2073: 1997: 1991: 1983: 1977: 1929: 1923: 1915: 1909: 1892:λ is the decay constant. 1832: 1826: 1818: 1812: 1782: 1776: 1768: 1762: 1733: 1727: 1719: 1713: 1683: 1677: 1669: 1663: 1446: 1440: 1432: 1426: 1378: 1372: 1364: 1358: 1271: 1265: 1257: 1251: 1213: 1207: 1199: 1193: 1108: 1102: 1062: 1056: 962: 956: 725: 719: 711: 705: 676: 670: 662: 656: 632: 626: 618: 612: 568: 562: 513: 507: 480: 474: 447: 441: 414: 408: 396:, a heavier element, or 377: 371: 344: 338: 304: 298: 272: 266: 221: 215: 203: 197: 167: 161: 74:-rich minerals, such as 3578:2015E&PSL.432...24S 3448:2003E&PSL.215...57L 3409:2013E&PSL.381..222S 3295:2006E&PSL.243..711G 3068:2004E&PSL.222...29P 3030:1997E&PSL.148..243B 2926:2004E&PSL.219..311S 2899:2006M&PSA..41.5348B 2823:2017E&PSL.473...52D 2629:2008E&PSL.273...48B 28:Lutetium–hafnium dating 2488: 2410: 2335: 2289: 2243: 2197: 2151: 2105: 2022: 1954: 1863: 1579: 1570: 1539:ɛHf value implications 1496: 1471: 1403: 1328: 1134: 1088: 1034: 973: 936: 882: 825: 767: 579: 554:The decay constant of 540: 526: 493: 460: 427: 390: 357: 318: 248: 180: 24: 3354:American Mineralogist 2486: 2452:prograde metamorphism 2408: 2336: 2290: 2244: 2198: 2152: 2106: 2023: 1955: 1864: 1576: 1568: 1493: 1472: 1404: 1329: 1135: 1089: 1035: 974: 937: 883: 826: 768: 580: 538: 527: 494: 461: 428: 391: 358: 319: 249: 181: 22: 3374:10.2138/am.2007.2405 3360:(11–12): 1919–1924. 2299: 2253: 2207: 2161: 2115: 2069: 1966: 1898: 1599: 1415: 1347: 1151: 1098: 1052: 1002: 952: 894: 837: 783: 602: 558: 503: 470: 437: 404: 367: 334: 261: 193: 157: 140:Isotopes of lutetium 3820:2014GeoM..151..816K 3808:Geological Magazine 3782:2017Geo....45..103L 3734:1996Natur.379..624V 3699:1996ChGeo.133..225G 3656:2014JMetG..32..515M 3621:2009Geo....37..987M 3534:2018ChGeo.476..208C 3483:2016JMetG..34..363C 3366:2007AmMin..92.1919H 3330:2005ChGeo.224..201L 3252:2007ChGeo.243...16L 3200:2008JMetG..26..741C 3149:2003GSLSP.220...83A 3106:1981CoMP...75..263P 2757:. Wiley-Blackwell. 2753:White, W M (2003). 2456:peak P-T conditions 2362:limits Lu–Hf uses. 1527:Both Lu and Hf are 1517:protoplanetary disk 1044:Epsilon (ɛHf value) 3866:Radiometric dating 3114:10.1007/BF01166766 2489: 2448:rare-earth element 2441:rare-earth element 2411: 2345:Analytical methods 2331: 2285: 2239: 2193: 2147: 2101: 2018: 1950: 1859: 1580: 1571: 1497: 1467: 1399: 1324: 1130: 1084: 1030: 969: 932: 878: 821: 763: 575: 541: 522: 499:, the presence of 489: 456: 423: 386: 353: 314: 244: 176: 128:rare-earth element 119:Radiometric dating 113:Radiometric dating 60:rare-earth element 25: 3728:(6566): 624–627. 3664:10.1111/jmg.12092 3629:10.1130/G30292A.1 3491:10.1111/jmg.12185 2995:978-953-51-0586-2 2764:978-0-470-65668-6 2712:978-0-471-38437-3 2575:978-94-007-6326-5 2560:. pp. 1–20. 2329: 2310: 2308: 2307: 2306: 2283: 2264: 2262: 2261: 2260: 2237: 2218: 2216: 2215: 2214: 2191: 2172: 2170: 2169: 2168: 2145: 2126: 2124: 2123: 2122: 2099: 2080: 2078: 2077: 2076: 2014: 2004: 1998: 1996: 1995: 1994: 1984: 1982: 1981: 1980: 1946: 1936: 1930: 1928: 1927: 1926: 1916: 1914: 1913: 1912: 1852: 1848: 1839: 1833: 1831: 1830: 1829: 1819: 1817: 1816: 1815: 1798: 1789: 1783: 1781: 1780: 1779: 1769: 1767: 1766: 1765: 1749: 1740: 1734: 1732: 1731: 1730: 1720: 1718: 1717: 1716: 1699: 1690: 1684: 1682: 1681: 1680: 1670: 1668: 1667: 1666: 1629: 1610: 1499:According to the 1463: 1453: 1447: 1445: 1444: 1443: 1433: 1431: 1430: 1429: 1395: 1385: 1379: 1377: 1376: 1375: 1365: 1363: 1362: 1361: 1301: 1288: 1278: 1272: 1270: 1269: 1268: 1258: 1256: 1255: 1254: 1230: 1220: 1214: 1212: 1211: 1210: 1200: 1198: 1197: 1196: 1162: 1128: 1109: 1107: 1106: 1105: 1082: 1063: 1061: 1060: 1059: 988:mass spectrometry 963: 961: 960: 959: 926: 911: 876: 869: 854: 815: 800: 732: 726: 724: 723: 722: 712: 710: 709: 708: 683: 677: 675: 674: 673: 663: 661: 660: 659: 639: 633: 631: 630: 629: 619: 617: 616: 615: 590:Age determination 569: 567: 566: 565: 550:Exponential decay 512: 511: 510: 479: 478: 477: 446: 445: 444: 413: 412: 411: 376: 375: 374: 343: 342: 341: 303: 302: 301: 287: 271: 270: 269: 236: 220: 219: 218: 202: 201: 200: 166: 165: 164: 146:Radioactive decay 36:radioactive decay 3883: 3850: 3849: 3839: 3803: 3794: 3793: 3790:10.1130/G38720.1 3765: 3754: 3753: 3742:10.1038/379624a0 3717: 3711: 3710: 3687:Chemical Geology 3682: 3676: 3675: 3639: 3633: 3632: 3604: 3598: 3597: 3560: 3554: 3553: 3522:Chemical Geology 3517: 3511: 3510: 3466: 3460: 3459: 3430: 3421: 3420: 3392: 3386: 3385: 3348: 3342: 3341: 3318:Chemical Geology 3313: 3307: 3306: 3289:(3–4): 711–731. 3278: 3272: 3271: 3240:Chemical Geology 3234: 3228: 3227: 3183: 3177: 3176: 3132: 3126: 3125: 3089: 3080: 3079: 3051: 3042: 3041: 3024:(1–2): 243–258. 3013: 3000: 2999: 2972: 2963: 2962: 2960: 2958: 2944: 2938: 2937: 2920:(3–4): 311–324. 2909: 2903: 2902: 2883:Blichert-Toft, J 2878: 2872: 2871: 2843: 2837: 2836: 2834: 2802: 2796: 2795: 2786:(366): 683–694. 2775: 2769: 2768: 2750: 2717: 2716: 2698: 2641: 2640: 2611: 2580: 2579: 2553: 2340: 2338: 2337: 2332: 2330: 2327: 2326: 2325: 2320: 2304: 2294: 2292: 2291: 2286: 2284: 2281: 2280: 2279: 2274: 2258: 2248: 2246: 2245: 2240: 2238: 2235: 2234: 2233: 2228: 2212: 2202: 2200: 2199: 2194: 2192: 2189: 2188: 2187: 2182: 2166: 2156: 2154: 2153: 2148: 2146: 2143: 2142: 2141: 2136: 2120: 2110: 2108: 2107: 2102: 2100: 2097: 2096: 2095: 2090: 2074: 2062:concentrations. 2027: 2025: 2024: 2019: 2017: 2016: 2015: 2012: 2009: 2005: 2003: 1992: 1989: 1978: 1975: 1959: 1957: 1956: 1951: 1949: 1948: 1947: 1944: 1941: 1937: 1935: 1924: 1921: 1910: 1907: 1868: 1866: 1865: 1860: 1858: 1854: 1853: 1851: 1850: 1849: 1846: 1844: 1840: 1838: 1827: 1824: 1813: 1810: 1800: 1799: 1796: 1794: 1790: 1788: 1777: 1774: 1763: 1760: 1752: 1751: 1750: 1747: 1745: 1741: 1739: 1728: 1725: 1714: 1711: 1701: 1700: 1697: 1695: 1691: 1689: 1678: 1675: 1664: 1661: 1653: 1634: 1630: 1622: 1613: 1612: 1611: 1608: 1476: 1474: 1473: 1468: 1466: 1465: 1464: 1461: 1458: 1454: 1452: 1441: 1438: 1427: 1424: 1408: 1406: 1405: 1400: 1398: 1397: 1396: 1393: 1390: 1386: 1384: 1373: 1370: 1359: 1356: 1333: 1331: 1330: 1325: 1313: 1309: 1302: 1300: 1299: 1289: 1286: 1283: 1279: 1277: 1266: 1263: 1252: 1249: 1242: 1241: 1231: 1228: 1225: 1221: 1219: 1208: 1205: 1194: 1191: 1184: 1174: 1173: 1163: 1160: 1139: 1137: 1136: 1131: 1129: 1126: 1125: 1124: 1119: 1103: 1093: 1091: 1090: 1085: 1083: 1080: 1079: 1078: 1073: 1057: 1039: 1037: 1036: 1031: 1020: 1019: 998:would represent 978: 976: 975: 970: 968: 957: 947: 941: 939: 938: 933: 931: 930: 924: 923: 922: 917: 909: 908: 907: 887: 885: 884: 879: 877: 874: 873: 867: 866: 865: 860: 852: 851: 850: 830: 828: 827: 822: 820: 819: 813: 812: 811: 806: 798: 797: 796: 772: 770: 769: 764: 753: 752: 737: 733: 731: 720: 717: 706: 703: 694: 693: 688: 684: 682: 671: 668: 657: 654: 644: 640: 638: 627: 624: 613: 610: 584: 582: 581: 576: 574: 563: 531: 529: 528: 523: 521: 508: 498: 496: 495: 490: 488: 475: 465: 463: 462: 457: 455: 442: 432: 430: 429: 424: 422: 409: 395: 393: 392: 387: 385: 372: 362: 360: 359: 354: 352: 339: 323: 321: 320: 315: 313: 312: 299: 293: 292: 285: 280: 267: 253: 251: 250: 245: 243: 242: 241: 234: 229: 216: 198: 185: 183: 182: 177: 175: 162: 32:geochronological 3891: 3890: 3886: 3885: 3884: 3882: 3881: 3880: 3856: 3855: 3854: 3853: 3804: 3797: 3766: 3757: 3718: 3714: 3683: 3679: 3640: 3636: 3615:(11): 987–990. 3605: 3601: 3561: 3557: 3518: 3514: 3467: 3463: 3431: 3424: 3393: 3389: 3349: 3345: 3314: 3310: 3279: 3275: 3235: 3231: 3184: 3180: 3133: 3129: 3090: 3083: 3052: 3045: 3014: 3003: 2996: 2973: 2966: 2956: 2954: 2946: 2945: 2941: 2910: 2906: 2879: 2875: 2844: 2840: 2803: 2799: 2776: 2772: 2765: 2751: 2720: 2713: 2699: 2644: 2612: 2583: 2576: 2554: 2507: 2502: 2481: 2472: 2403: 2391:A-type granites 2383: 2378: 2356: 2347: 2321: 2316: 2315: 2302: 2300: 2297: 2296: 2275: 2270: 2269: 2256: 2254: 2251: 2250: 2229: 2224: 2223: 2210: 2208: 2205: 2204: 2183: 2178: 2177: 2164: 2162: 2159: 2158: 2137: 2132: 2131: 2118: 2116: 2113: 2112: 2091: 2086: 2085: 2072: 2070: 2067: 2066: 2039: 2011: 2010: 1990: 1976: 1974: 1970: 1969: 1967: 1964: 1963: 1943: 1942: 1922: 1908: 1906: 1902: 1901: 1899: 1896: 1895: 1884: 1845: 1825: 1811: 1809: 1805: 1804: 1795: 1775: 1761: 1759: 1755: 1754: 1753: 1746: 1726: 1712: 1710: 1706: 1705: 1696: 1676: 1662: 1660: 1656: 1655: 1654: 1652: 1645: 1641: 1621: 1617: 1607: 1606: 1602: 1600: 1597: 1596: 1585: 1541: 1488: 1460: 1459: 1439: 1425: 1423: 1419: 1418: 1416: 1413: 1412: 1392: 1391: 1371: 1357: 1355: 1351: 1350: 1348: 1345: 1344: 1285: 1284: 1264: 1250: 1248: 1244: 1243: 1227: 1226: 1206: 1192: 1190: 1186: 1185: 1183: 1182: 1178: 1159: 1158: 1154: 1152: 1149: 1148: 1120: 1115: 1114: 1101: 1099: 1096: 1095: 1074: 1069: 1068: 1055: 1053: 1050: 1049: 1046: 1012: 1008: 1003: 1000: 999: 955: 953: 950: 949: 945: 918: 913: 912: 903: 899: 898: 897: 895: 892: 891: 861: 856: 855: 846: 842: 841: 840: 838: 835: 834: 807: 802: 801: 792: 788: 787: 786: 784: 781: 780: 745: 741: 718: 704: 702: 698: 689: 669: 655: 653: 649: 648: 625: 611: 609: 605: 603: 600: 599: 592: 561: 559: 556: 555: 552: 546: 506: 504: 501: 500: 473: 471: 468: 467: 440: 438: 435: 434: 407: 405: 402: 401: 370: 368: 365: 364: 363:can decay into 337: 335: 332: 331: 297: 288: 284: 265: 264: 262: 259: 258: 237: 233: 214: 196: 194: 191: 190: 160: 158: 155: 154: 148: 142: 136: 121: 115: 17: 12: 11: 5: 3889: 3879: 3878: 3873: 3868: 3852: 3851: 3814:(5): 816–829. 3795: 3776:(2): 103–106. 3755: 3712: 3693:(1): 225–240. 3677: 3650:(5): 515–533. 3634: 3599: 3555: 3512: 3477:(4): 363–377. 3461: 3442:(1–2): 57–72. 3422: 3387: 3343: 3324:(4): 201–211. 3308: 3273: 3246:(1–2): 16–35. 3229: 3194:(7): 741–758. 3178: 3127: 3100:(3): 263–267. 3081: 3043: 3001: 2994: 2964: 2939: 2904: 2873: 2854:(5): 588–590. 2838: 2797: 2770: 2763: 2718: 2711: 2642: 2623:(1–2): 48–57. 2581: 2574: 2504: 2503: 2501: 2498: 2480: 2477: 2471: 2468: 2402: 2399: 2382: 2379: 2377: 2374: 2354: 2346: 2343: 2324: 2319: 2313: 2278: 2273: 2267: 2232: 2227: 2221: 2186: 2181: 2175: 2140: 2135: 2129: 2094: 2089: 2083: 2038: 2035: 2034: 2033: 2008: 2001: 1987: 1973: 1961: 1940: 1933: 1919: 1905: 1893: 1890: 1882: 1877: 1870: 1869: 1857: 1843: 1836: 1822: 1808: 1803: 1793: 1786: 1772: 1758: 1744: 1737: 1723: 1709: 1704: 1694: 1687: 1673: 1659: 1651: 1648: 1644: 1640: 1637: 1633: 1628: 1625: 1620: 1616: 1605: 1584: 1583:CHUR model age 1581: 1540: 1537: 1487: 1484: 1483: 1482: 1457: 1450: 1436: 1422: 1410: 1389: 1382: 1368: 1354: 1342: 1335: 1334: 1323: 1319: 1316: 1312: 1308: 1305: 1298: 1295: 1292: 1282: 1275: 1261: 1247: 1240: 1237: 1234: 1224: 1217: 1203: 1189: 1181: 1177: 1172: 1169: 1166: 1157: 1123: 1118: 1112: 1077: 1072: 1066: 1045: 1042: 1029: 1026: 1023: 1018: 1015: 1011: 1007: 984: 983: 980: 966: 943: 929: 921: 916: 906: 902: 889: 872: 864: 859: 849: 845: 832: 818: 810: 805: 795: 791: 774: 773: 762: 759: 756: 751: 748: 744: 740: 736: 729: 715: 701: 697: 692: 687: 680: 666: 652: 647: 643: 636: 622: 608: 591: 588: 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Index


geochronological
radioactive decay
lutetium
hafnium
half-life
valences
ionic radii
rare-earth element
garnet
phosphates
zirconium
zircon
baddeleyite
zirkelite
inductively coupled plasma mass spectrometry
igneous
metamorphic
petrogenesis
provenance
Radiometric dating
Lutetium
rare-earth element
Isotopes of lutetium
Radioactive decay
lutetium
Lutetium
ytterbium

Exponential decay

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