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175:. Additionally, corroles and their metal complexes have been demonstrated to be useful as imaging agents in tumor detection, oxygen sensing, for prevention of heart disease, in synthetic chemistry as oxo, imido, and nitrido transfer agents, and as catalysts for the catalytic reduction of oxygen to water, and hydrogen production form water under aerobic conditions.
236:
Thomas, Kolle E.; Alemayehu, Abraham B.; Conradie, Jeanet; Beavers, Christine M.; Ghosh, Abhik (2012-08-21). "The
Structural Chemistry of Metallocorroles: Combined X-ray Crystallography and Quantum Chemistry Studies Afford Unique Insights".
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differ in several ways. Corroles are triprotic, whereas porphyrins are diprotic. Because of the 3- charge of the triply deprotonated ligand, metallocorroles are formally high-valent. Several are
280:
Ghosh, Abhik (2017-02-22). "Electronic
Structure of Corrole Derivatives: Insights from Molecular Structures, Spectroscopy, Electrochemistry, and Quantum Chemical Calculations".
127:, with a corrole radical-dianion ligand. A second difference between corroles and porphyrins is the size of the metal-binding cavity, i.e., 17- vs 18-membered rings. See
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Dogutan, D. K.; Stoian, S. A.; McGuire, R.; Schwalbe, M.; Teets, T. S.; Nocera, D. G. (2011). "Hangman
Corroles: Efficient Synthesis and Oxygen Reaction Chemistry".
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Haber, Adi; Ali, A. A.-Y.; Aviram, M.; Gross, Z. (2013). "Allosteric inhibitors of HMG-CoA reductase, the key enzyme involved in cholesterol biosynthesis".
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Teh, James; Kauwe, Lali Medina (2021). "Chapter 10. Magnetic
Resonance Contrast Enhancement and Therapeutic Properties of Corrole Nanoparticles".
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Ward, A. L.; Buckley, H. L.; Lukens, W. W.; Arnold, J. (2013). "Synthesis and
Characterization of Thorium(IV) and Uranium(IV) Corrole Complexes".
506:"Osmium-nitrido corroles as NIR indicators for oxygen sensors and triplet sensitizers for organic upconversion and singlet oxygen generation"
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Buckley, H. L.; Anstey, M. R.; Gryko, D. T.; Arnold, J. (2013). "Lanthanide corroles: a new class of macrocyclic lanthanide complexes".
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Aviv-Harel, I.; Gross, Z. (2010). "Coordination chemistry of corroles with focus on main group elements".
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Orłowski, Rafał; Gryko, Dorota; Gryko, Daniel T. (2017). "Synthesis of
Corroles and Their Heteroanalogs".
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Schweyen P, Brandhorst K, Wicht R, Wolfram B, Bröring M (2015). "The
Corrole Radical".
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Teo, Ruijie D.; Hwang, Jae Youn; Termini, John; Gross, Zeev; Gray, Harry B. (2017).
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atoms in the core of the molecule. In this sense, corrole is very similar to
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Palmer, J. H. (2012). "Transition Metal
Corrole Coordination Chemistry".
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Corroles can be prepared by a two-step process, beginning with the
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Protein-corrole particles have been investigated as carriers of
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Molecular
Electronic Structures of Transition Metal Complexes I
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Borisov, Sergey M.; Alemayehu, Abraham; Ghosh, Abhik (2016).
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96:(or tetrapyrrane), is cyclized by oxidation, typically with
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594:. Structure and Bonding. Vol. 142. pp. 49–90.
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155:Corroles have been attached to a wide range of
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135:for more about these side by side images of
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171:. and the diprotonated, neutral corrole
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129:"Porphyrins and similar compounds"
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26:structure includes a deprotonated
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60:). The ring consists of nineteen
510:Journal of Materials Chemistry C
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457:"Fighting Cancer with Corroles"
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239:Accounts of Chemical Research
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92:. The open-ring product, a
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215:10.1021/acs.chemrev.6b00434
182:cargo for tumor targeting.
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115:Comparison with porphyrins
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49:ring is also present in
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151:Coordination complexes
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82:condensation reaction
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16:Aromatic tetrapyrrole
422:Angew. Chem. Int. Ed
600:10.1007/430_2011_52
563:(93): 10917–10919.
393:(37): 13965–13971.
569:10.1039/c3cc44740e
523:10.1039/C6TC01126H
364:10.1039/c3cc38806a
133:conjugated systems
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609:978-3-642-27369-8
516:(24): 5822–5828.
428:(28): 8213–8216.
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358:(30): 3104–3106.
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157:transition metals
125:redox-noninnocent
110:Corrole synthesis
64:atoms, with four
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86:benzaldehyde
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43:tetrapyrrole
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725:Macrocycles
533:10037/24918
180:theranostic
165:lanthanides
76:Preparation
30:macrocycle.
709:Categories
186:References
161:main group
121:porphyrins
101:-chloranil
696:233677374
628:ignored (
618:cite book
542:2050-7534
302:0009-2665
259:0001-4842
169:actinides
137:porphyrin
70:porphyrin
55:vitamin B
51:cobalamin
24:Cobalamin
665:21142043
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310:28191934
267:22444488
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66:nitrogen
40:aromatic
482:6357784
173:radical
141:chlorin
90:pyrrole
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