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Acid mine drainage

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22: 453: 152: 877:), a neutral solute. Monosilicic acid remains in the bulk solution and play many roles in correcting the adverse effects of acidic conditions. In the bulk solution, the silicate anion is very effective in neutralizing H cations in the soil solution. While its mode-of-action is quite different from limestone, the ability of calcium silicate to neutralize acid solutions is equivalent to limestone as evidenced by its CCE value of 90–100% and its relative neutralizing value of 98%. 33: 3384: 802:. In that vessel, clean water will overflow for release, whereas settled metal precipitates (sludge) are recycled to the acid mine drainage treatment tank, with a sludge-wasting side stream. A number of variations of this process exist, as dictated by the chemistry of ARD, its volume, and other factors. Generally, the products of the HDS process also contain 971:. Generally, the wetlands receive near-neutral water, after it has been typically neutralized by a limestone-based treatment process. Metal precipitation occurs from their oxidation at near-neutral pH, complexation with organic matter, precipitation as carbonates or sulfides. The latter results from sediment-borne anaerobic bacteria capable of 127:
Historically, the acidic discharges from active or abandoned mines were called acid mine drainage, or AMD. The term acid rock drainage, or ARD, was introduced in the 1980s and 1990s to indicate that acidic drainage can originate from sources other than mines. For example, a paper presented in 1991 at
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In the presence of heavy metals, calcium silicate reacts in a different way than limestone. As limestone raises the pH of the bulk solution, when heavy metals are present, precipitation of the poorly soluble metal hydroxides is accelerated and the tendency for an impermeable metal hydroxide coating,
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after hydration) is dispersed into a tank containing acid mine drainage and recycled sludge to increase water pH to about 9. At this pH, most toxic metals become insoluble and precipitate, aided by the presence of recycled sludge. Optionally, air can be injected in the tank to oxidize iron(II) and
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Acid mine drainage also affects the wildlife living within the affected body of water. Aquatic macroinvertebrates living in streams or parts of streams affected by acid mine drainage show fewer individuals, less diversity, and lower biomass. Many species of fish also cannot tolerate the pollution.
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The attractiveness of a constructed wetlands solution lies in its relative low cost. They are limited by the metal loads they can deal with (either from high flows or metal concentrations), though current practitioners have succeeded in developing constructed wetlands that treat high volumes (see
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Less complex variants of this process, such as simple lime neutralization, may involve no more than a lime silo, a mixing tank and a settling pond. These systems are far less costly to build, but are also less efficient (longer reaction times are required, and they produce a discharge with higher
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Depending on the volume and flowrate of acid effluents to be neutralised and the scale of industrial installations, a commonly but more expensive commercial process for treating acid mine drainage is precipitation with lime in a high-density sludge (HDS) process. In this application, a slurry of
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At some mines, acidic drainage is detected within 2–5 years after mining begins, whereas at other mines, it is not detected for several decades. In addition, acidic drainage may be generated for decades or centuries after it is first detected. For this reason, acid mine drainage is considered a
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In a mining setting it is leading practice to carry out a geochemical assessment of mine materials during the early stages of a project to determine the potential for AMD. The geochemical assessment aims to map the distribution and variability of key geochemical parameters, acid generating and
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Zinck, J.M. and Griffith, W.F. (2000). An assessment of HDS-type lime treatment processes – efficiency and environmental impact. In: ICARD 2000. Proceedings from the Fifth International Conference on Acid Rock Drainage. Society for Mining, Metallurgy, and Exploration, Inc. Vol II,
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Although abandoned underground mines produce most of the acid mine drainage, some recently mined and reclaimed surface mines have produced ARD and have degraded local ground-water and surface-water resources. Acidic water produced at active mines must be neutralized to achieve
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complexes with neutral or negative surface charges. These negatively charged colloids are electrostatically repelled by each other (as well as with the negatively charged calcium silicate granules). The sequestered metal colloids are stabilized and remain in a stable
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Acid rock drainage occurs naturally within some environments as part of the rock weathering process but is exacerbated by large-scale earth disturbances characteristic of mining and other large construction activities, usually within rocks containing an abundance of
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However, although limestone is an unprocessed raw material available in large quantities and the least expensive neutralisation agent, it can suffer from a number of disadvantages possibly limiting its applications. Indeed, small
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Either of these reactions can occur spontaneously or can be catalyzed by microorganisms that derive energy from the oxidation reaction. The ferric cations produced can also oxidize additional pyrite and reduce into ferrous ions:
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Bless, Diana; Park, Brian; Nordwick, Suzzann; Zaluski, Marek; Joyce, Helen; Hiebert, Randy; Clavelot, Charles (1 December 2008). "Operational Lessons Learned During Bioreactor Demonstrations for Acid Rock Drainage Treatment".
869:, can also be used to neutralize active acidity in AMD systems by removing free hydrogen ions from the bulk solution, thereby increasing pH. As the silicate anion captures H ions (raising the pH), it forms monosilicic acid (H 143:, or was originally acidic, but has been neutralized along its flow path, then it is described as "neutral mine drainage", "mining-influenced water" or otherwise. None of these other names have gained general acceptance. 2003:
Department of Industry, Tourism and Resources - Managing Acid and Metalliferous Drainage: Leading Practice Sustainable Development Program for the Mining Industry (PDF) Australian Government handbook, 2007: pg 28 -
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S or NaHS. Solid-liquid separation after reaction would produce a base metal-free effluent that can be discharged or further treated to reduce sulfate, and a metal sulfide concentrate with possible economic value.
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Organisms which cause acid mine drainage can thrive in waters with pH very close to zero. Negative pH occurs when water evaporates from already acidic pools thereby increasing the concentration of hydrogen ions.
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P.J. Schmieder, J.R. Taylor and N. Bourgeot (2012), Oxygen Consumption Techniques to Quantify Acidity Generation Rates, 1st International Acid and Metalliferous Drainage Workshop in China – Beijing 2012,
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Mielke, R.E.; Pace, D.L.; Porter, T.; Southam, G. (2003). "A critical stage in the formation of acid mine drainage: Colonization of pyrite by Acidithiobacillus ferrooxidans under pH-neutral conditions".
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In Canada, work to reduce the effects of acid mine drainage is concentrated under the Mine Environment Neutral Drainage (MEND) program. Total liability from acid rock drainage is estimated to be between
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This list includes both mines producing acid mine drainage and river systems significantly affected by such drainage. It is by no means complete, as worldwide, several thousands of such sites exist.
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might compromise the proper functioning and the safety of some constructed wetlands if during extremely hot summer period water supply decreases and evaporation accelerates causing them to dry up.
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are directly sequenced from the environment. The nearly full genomic constructs allows new understanding of the community and able to reconstruct their metabolic pathways. Our knowledge of
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sites for unique soil bacteria capable of producing new pharmaceutical leads. Soil microbes have long been a source for effective drugs and new research, such as that conducted at the
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Many acid rock discharges also contain elevated levels of potentially toxic metals, especially nickel and copper with lower levels of a range of trace and semi-metal ions such as
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sulfate ions into sulfide ions. These sulfide ions can then bind with heavy metal ions, precipitating heavy metals out of solution and effectively reversing the entire process.
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can be highly acidic, and in such cases it is treated as acid rock drainage. These, combined with reduced pH, have a detrimental impact on the streams' aquatic environments.
592: 2852: 2581: 1073:, which forms highly insoluble precipitates with many toxic metals. Although promising, this process has been slow in being adopted for a variety of technical reasons. 2373:
Villegas-Plazas M, et al. (1 December 2019). "A composite taxonomical and functional framework of microbiomes under acid mine drainage bioremediation systems".
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Although a host of chemical processes contribute to acid mine drainage, pyrite oxidation is by far the greatest contributor. A general equation for this process is:
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that could contribute to neutralize acid effluents are lacking, or insufficiently accessible (too short contact time with acidic waters flowing too fast, too low
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a major international conference on this subject was titled: "The Prediction of Acid Rock Drainage – Lessons from the Database". Both AMD and ARD refer to low
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Wang, X.; Elshahawi, S.I.; Shaaban, K.A.; Fang, L.; Ponomareva, L.V.; Zhang, Y.; Copley, G.C.; Hower, J.C.; Zhan, C.-G.; Kharel, M.K.; Thorson, J.S. (2014).
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Kefeni, Kebede K.; Msagati, Titus A.M.; Mamba, Bhekie B. (2017). "Acid mine drainage: Prevention, treatment options, and resource recovery: A review".
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Wang, X.; Shaaban, K.A.; Elshahawi, S.I.; Ponomareva, L.V.; Sunkara, M.; Copley, G.C.; Hower, J.C.; Morris, A.J.; Kharel, M.K.; Thorson, J.S. (2014).
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award for water management and supply (treating AMD) has developed a patented ion-exchange process that treats mine effluents (and AMD) economically.
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Among the macroinvertebrates, certain species can be found at only certain levels of pollution, while other species can be found over a wide range.
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In this case, the pyrite has dissolved away yielding a cube shape and residual gold. This break down is the main driver of acid mine drainage.
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Tyson GW, et al. (4 March 2004). "Community structure and metabolism through reconstruction of microbial genomes from the environment".
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Rasmussen, Keld; Lindegaard, Claus (1988). "Effects of Iron Compounds on Macroinvertebrate Communities in a Danish Lowland River System".
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Gusek, J.J., Wildeman, T.R. and Conroy, K.W. 2006. Conceptual methods for recovering metal resources from passive treatment systems.
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Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund site, California
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trace metal concentrations, if present). They would be suitable for relatively small flows or less complex acid mine drainage.
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As an alternative, several researchers have investigated the precipitation of metals using biogenic sulfide. In this process,
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RECOVERY OF MARKETABLE IRON OXIDE FROM MINE DRAINAGE, 2002 National Meeting of the American Society of Mining and Reclamation
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systems have been proposed during the 1980s to treat acid mine drainage generated by the abandoned coal mines in Eastern
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manganese(II) and assist in their precipitation. The resulting slurry is directed to a sludge-settling vessel, such as a
41: 921:(formation of an impervious crust around material grains preventing their dissolution and decreasing their reactivity). 3268: 2015: 948:, the exchange sites on resins must be regenerated, which typically requires acidic and basic reagents and generates a 813:) and unreacted lime, which enhance both its settleability and resistance to re-acidification and metal mobilization. 439:
The net effect of these reactions is to release H, which lowers the pH and maintains the solubility of the ferric ion.
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processes have previously been investigated as a potential treatment for acid mine drainage. The principle is that an
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Blodau, C. (2006). "A review of acidity generation and consumption in acidic coal mine lakes and their watersheds".
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Managing Acid and Metalliferous Drainage: Leading Practice Sustainable Development Program for the Mining Industry
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onto the metal hydroxide surface, the development of silica layers (mono- and bi-layers) lead to the formation of
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In the United Kingdom, many discharges from abandoned mines are exempt from regulatory control. In such cases the
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remains rudimentary: we know of many more species associated with ARD than we can establish roles and functions.
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ions, is very complex, and this complexity has considerably inhibited the design of effective treatment options.
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IMWA Symposium 2007: Water in Mining Environments, R. Cidu & F. Frau (Eds), 27–31 May 2007, Cagliari, Italy
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M. Botha, L. Bester, E. Hardwick "Removal of Uranium from Mine Water Using Ion Exchange at Driefontein Mine"
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Letterman, Raymond; Mitsch, William (1978). "Impact of Mine Drainage on a Mountain Stream in Pennsylvania".
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highly acidic nickel-rich discharges from coal stocking sites have proved to be particularly troublesome.
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layer onto the surface of limestone chips, binding the material and preventing further neutralization.
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for their ability to survive in harsh conditions, occur naturally in the rock, but limited water and
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state – effectively interrupting metal precipitation and reducing vulnerability of the material to
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Ferguson, K.D. and Morin, K.A. The Prediction of Acid Rock Drainage - Lessons from the Database.
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that contains the pollutants in a concentrated form. A South African company that won the 2013
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When the pH of acid mine drainage is raised past 3, either through contact with fresh water or
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McArthur River Mine: Toxic waste rock ongoing problem, security bond inadequate, report finds
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Water temperatures as high as 47 °C (117 °F) have been measured underground at the
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USGS > Pennsylvania Water Science Center > Coal-Mine-Drainage Projects in Pennsylvania
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greatly accelerate the decomposition of metal ions, although the reactions also occur in an
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Most base metals in acidic solution precipitate in contact with free sulfide, e.g. from H
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is a sulfide mineral or is associated with pyrite. In these cases the predominant metal
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The same type of chemical reactions and processes may occur through the disturbance of
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Trove: Australian Government Dept. of Industry, Tourism and Resources handbook, 2007.
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Jane Perlez and Raymond Bonner (2005): Below a Mountain of Wealth, a River of Waste.
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http://earthsystems.com.au/wp-content/uploads/2013/05/Schmieder-et-al-2012_OxCon.pdf
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Proceedings: Second International Conference on the Abatement of Acidic Drainage.
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in Spain presents an acid drainage of both natural and artificial origin (mining)
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Farmers 'disgusted' as proposal at abandoned central Queensland gold mine canned
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INAP: The International Network for Acid Prevention. Accessed 23 September 2013.
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Natural acid rock drainage and its impact upon background metal concentrations
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produced by organic matter oxidation, which can neutralize water acidity, and
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In cases where drainage from a mine is not acidic and has dissolved metals or
3403: 3022: 2947: 1786:"Negative pH and Extremely Acidic Mine Waters from Iron Mountain, California" 1771: 1741: 1603:
Proceedings of the 7th International Conference on Acid Rock Drainage (ICARD)
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PNAS, vol. 96 no. 7, pp 3455–3462, 30 March 1999. Retrieved 4 February 2016.
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of New Zealand, considered to be the most contaminated site in the country
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grains of crushed limestone can be prone to the formation of a coating of
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Bucknell University > News, September 2007. Accessed 4 January 2012.
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dissolution and prevents the limestone grains from releasing additional
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MiWER - Mine Water and Environment Research Centre (based in Australia)
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World's Most Acidic Waters are Found Near Redding, California (pH -3.6)
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Yellow boy in a stream receiving acid drainage from surface coal mining
218: 194: 89:. Areas where the earth has been disturbed (e.g. construction sites or 2496: 1809: 1387: 1124: 346:
The oxidation of the sulfide to sulfate solubilizes the ferrous iron (
3158: 3105: 2957: 1886: 1431: 1299: 1250: 1172: 799: 699: 553: 549: 529: 491: 472: 351: 198: 182: 175: 140: 101: 3085: 2977: 2912: 2582:"Overview of acid mine drainage impacts in the West Rand Goldfield" 2144:"The Use of Steel Slag in Acid Mine Drainage Treatment and Control" 1491: 1477: 1473: 1418: 1405: 1295: 1182: 992: 905: 522: 347: 167: 2066:
Hammarstrom, Jane M.; Philip L. Sibrell; Harvey E. Belkin (2003).
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D. K. Nordstrom; C. N. Alpers; C. J. Ptacek; D. W. Blowes (2000).
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formed under coastal or estuarine conditions after the last major
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Overview of acid mine drainage impacts in the West Rand Goldfield
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Scientists have recently begun to explore acid mine drainage and
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have pH under 5. However, a portion of mine drainage in both the
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DMITRE Minerals >...> Former Mines > Brukunga mine site
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serious long-term environmental problem associated with mining.
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supplies usually keep their numbers low. Extremophiles known as
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Rocks stained by ferrous precipitate from acid mine drainage on
3027: 3017: 2068:"Characterization of limestone reacted with acid-mine drainage" 1340: 1094: 1058: 953: 803: 722: 526: 289: 255: 251: 214: 190: 74: 2827: 2527: 2372: 2321: 2932: 2857: 2426:"A Historical Overview of Natural Products in Drug Discovery" 2218:"Overview of Passive Systems for Treating Acid Mine Drainage" 2194:. Wetlands for the Treatment of Mine Drainage. Archived from 1043: 984: 972: 949: 764: 604:
Modelling of oxidation, pollutant generation and release; and
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before discharge from a mine site to a stream is permitted.
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Metal mines may generate highly acidic discharges where the
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PADRE – Partnership for Acid Drainage Remediation in Europe
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minerals, previously soluble iron(III) ions precipitate as
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Johnson, D. Barrie; Hallberg, Kevin B. (1 February 2005).
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and remobilised when exposed to atmospheric oxygen (e.g.,
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An example of an effective constructed wetland is on the
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The chemistry of oxidation of pyrites, the production of
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The Science of Acid Mine Drainage and Passive Treatment
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Marychurch, Judith; Natalie Stoianoff (4–7 July 2006).
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A general equation for this neutralisation process is:
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stocks, coal handling facilities, coal washeries, and
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are also an important source of acid mine drainage.
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Professor paints a bright picture with 'yellow boy'
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List of selected acid mine drainage sites worldwide
633:have provided some innovative solutions, including 2286: 2061: 2059: 2057: 1710:"Acid mine drainage remediation options: a review" 1099:microorganisms in the acid mine drainage community 1081:Many technologies exist for the treatment of AMD. 1025: 350:), which is subsequently oxidized to ferric iron ( 2423: 1831:Lim, Kieran F. (2006). "Negative pH Does Exist". 1119:Center for Pharmaceutical Research and Innovation 3401: 576: 266:are often major culprits of acid mine drainage. 16:Outflow of acidic water from metal or coal mines 2813:INAP – International Network of Acid Prevention 2054: 1929: 1707: 1322:The Irwin Syncline in Southwestern Pennsylvania 595:(e.g. acid-base accounting, sulfur speciation); 2622:"Old Forge borehole drains mines for 50 years" 2477:"Ruthmycin, a new tetracyclic polyketide from 1916:, Lexington KY, June 9–13, 2002. Published by 1108: 567: 517:, a yellow-orange solid colloquially known as 2873: 2619: 2137: 2135: 1476:, an abandoned mine on the western slopes of 1257:and 50,000 acres (200 km) in and around 1018:where highly ferruginous discharges from the 2689:, 21 December 2017. Retrieved 20 April 2018. 2424:Dias, D.A.; Urban, S.; Roessner, U. (2012). 2189: 1590:Global Acid Rock Drainage Guide (GARD Guide) 1227:mining, have to deal with acid mine drainage 132:or acidic waters caused by the oxidation of 2808:IMWA – International Mine Water Association 774: 2880: 2866: 2707: 2132: 1920:, 3134 Montavesta Rd., Lexington, KY 40502 1658: 231:is a key contributor to pyrite oxidation. 225:levels of abandoned mines. In particular, 2798:OrangeWaterNetwork.org (EPCAMR's Website) 2704:, 16 March 2018. Retrieved 24 March 2018. 2613: 2557: 2504: 2451: 2441: 258:. The most commonly mined ore of copper, 649:and the constructed wetland next to the 536:Trace metal and semi-metal contamination 451: 150: 31: 20: 2823:Overview of chemical processes involved 2141: 1530:Environmental impact of iron ore mining 959: 925:Removal of toxic metals by ion exchange 136:, though ARD is the more generic name. 3402: 2818:INAP – Global Acid Rock Drainage Guide 1990: 1988: 1790:Environmental Science & Technology 1585: 1583: 1577:Sept 16 to 18, 1991, Montreal, Quebec. 181:After being exposed to air and water, 2861: 2803:Assessment of treatment methods (PDF) 2732:, Victoria, Australia. Archived from 2724:Australasian Law Teachers Association 1770:Nordstrom, D.K. & Alpers, C. N.: 1388:Davis Pyrite Mine in NW Massachusetts 900:in solution. In the calcium silicate 865:feedstock, made from processed steel 694:Neutralization with calcium carbonate 1515:International Mine Water Association 1084: 857:Neutralization with calcium silicate 464:, and the pH can be as low as −3.6. 209:environment. These microbes, called 2375:Journal of Environmental Management 1985: 1830: 1580: 1373:Copperas Brook Watershed, from the 42:Northumberland County, Pennsylvania 13: 3269:Ultraviolet germicidal irradiation 2620:David Falchek (26 December 2012). 2169:Calcium Silicon-Based Mineral CSA. 1605:, March 26–30, 2006, St. Louis MO. 745:the limestone surface, preventing 629:working with partners such as the 607:Modelling of material composition. 582:element leaching characteristics. 14: 3426: 3139:Agricultural wastewater treatment 2772: 2588:. 2 February 2009. Archived from 1282:Britannia Beach, British Columbia 1103:acidophiles in acid mine drainage 1091:large-scale sequencing strategies 280:Acidophiles in acid mine drainage 3383: 3382: 1714:Science of the Total Environment 1661:Science of the Total Environment 1638:10.1046/j.1472-4669.2003.00005.x 1510:Environmental issues with mining 1231: 1022:have been successfully treated. 447: 3199:Industrial wastewater treatment 3169:Decentralized wastewater system 2751: 2692: 2676: 2660: 2641: 2604: 2574: 2521: 2468: 2417: 2366: 2315: 2280: 2236: 2210: 2183: 2174: 2162: 2106: 2096: 2077:(18): 1710–1714. Archived from 2037: 2020: 2007: 1950: 1923: 1899: 1879: 1867: 1824: 1777: 1734:10.1016/j.scitotenv.2004.09.002 1681:10.1016/j.scitotenv.2006.05.004 1223:, both the product of open pit 1076: 1026:Precipitation of metal sulfides 501:before the drainage emanates. 197:generates acidity. Colonies of 122: 52:acid and metalliferous drainage 3410:Environmental impact of mining 2887: 2730:Victoria University, Melbourne 2246:Mine Water and the Environment 1764: 1701: 1695: 1652: 1608: 1595: 1567: 1541: 1457:Ok Tedi environmental disaster 904:, as silicic acid species are 228:Acidithiobacillus ferrooxidans 1: 3219:Rotating biological contactor 2395:10.1016/j.jenvman.2019.109581 2309:10.1016/j.jclepro.2017.03.082 2289:Journal of Cleaner Production 1833:Journal of Chemical Education 1564:. Accessed 23 September 2013. 1547:Dowding, B. & Mills, C,: 1535: 979:description of Campbell Mine 577:Identification and prediction 504: 146: 2726:– Refereed Conference Papers 1979:10.1016/0043-1354(88)90004-8 1944:10.1016/0013-9327(78)90055-1 1341:North Fork of Kentucky River 1221:Central German Lake District 944:. Once the contaminants are 616: 611: 599:Kinetic geochemical testwork 585:The assessment may include: 273: 115:, and constitutes a similar 7: 1498: 1269:Rio Grande County, Colorado 1109:Microbes and drug discovery 752:and the further release of 593:Static geochemical testwork 568:Effects on aquatic wildlife 162:often progresses below the 10: 3431: 3415:Water management in mining 3284:Wastewater treatment plant 3051:Adsorbable organic halides 2627:The Scranton Times Tribune 2586:Presentation to DG of DWAF 1525:Uranium acid mine drainage 1412: 1055:terminal electron acceptor 759:This might explain why at 688: 442: 277: 3378: 3292: 3119: 3056:Biochemical oxygen demand 3041: 2895: 2766:Accessed 6 December 2011. 2762:27 September 2007 at the 2673:Accessed 6 December 2011. 2657:Accessed 6 December 2011. 2266:10.1007/s10230-008-0052-6 1555:15 September 2014 at the 1488:West Coast mineral fields 1419:Brukunga, South Australia 1327:Pronto mine tailings site 1310:Shasta County, California 1152: 1132: 1040:sulfate-reducing bacteria 637:solutions such as on the 221:especially favor the low 1912:21 November 2008 at the 1520:Passive treatment system 1437:McArthur River zinc mine 1362:18 February 2020 at the 775:Neutralization with lime 681:, from an investment of 3244:Sewage sludge treatment 3184:Fecal sludge management 3144:API oil–water separator 3111:Wastewater surveillance 1932:Environmental Pollution 1876:Accessed 17 April 2012. 1275:, which flows into the 1242:Idaho Springs, Colorado 936:can remove potentially 627:Natural Resources Wales 488:regions of Pennsylvania 3101:Total suspended solids 3096:Total dissolved solids 3061:Chemical oxygen demand 1217:Lusatian Lake District 457: 288:ions and subsequently 156: 44: 29: 2968:Industrial wastewater 2789:Accessed 21 May 2016. 2443:10.3390/metabo2020303 2031:23 April 2008 at the 1357:Cheat River Watershed 711:specific surface area 702:rocks or appropriate 641:in the valley of the 490:is alkaline, because 455: 278:Further information: 172:mine waste rock dumps 154: 35: 24: 3310:Groundwater recharge 2793:AMRClearinghouse.org 2653:2 April 2011 at the 2075:Applied Geochemistry 1893:14 July 2014 at the 1265:The Summitville Mine 1089:With the advance of 965:Constructed wetlands 960:Constructed wetlands 117:environmental hazard 91:highway construction 66:) is the outflow of 3224:Secondary treatment 3209:Membrane bioreactor 3164:Constructed wetland 2963:Infiltration/Inflow 2387:2019JEnvM.25109581V 2344:10.1038/nature02340 2336:2004Natur.428...37T 2301:2017JCPro.151..475K 2258:2008MWE....27..241B 2224:on 6 September 2009 2142:Ziemkiewicz, Paul. 2048:4 June 2008 at the 1999:15 May 2013 at the 1971:1988WatRe..22.1101R 1885:Sam Alcorn (2007): 1845:2006JChEd..83.1465L 1802:2000EnST...34..254N 1726:2005ScTEn.338....3J 1673:2006ScTEn.369..307B 1630:2003Gbio....1...81M 1383:Ompompanoosuc River 1253:site, covering the 1139:West Rand Goldfield 981:constructed wetland 635:constructed wetland 515:iron(III) hydroxide 3389:Category: Sewerage 3350:Septic drain field 3315:Infiltration basin 3259:Stabilization pond 3179:Facultative lagoon 3043:Quality indicators 2923:Blackwater (waste) 2903:Acid mine drainage 2838:USGS Mine Drainage 2671:, 27 December 2005 2669:The New York Times 2550:10.1038/ja.2014.37 2381:(109581): 109581. 2190:André Sobolewski. 1853:10.1021/ed083p1465 1441:Northern Territory 1379:Strafford, Vermont 1306:Iron Mountain Mine 934:ion-exchange resin 623:Environment Agency 471:About half of the 462:Iron Mountain Mine 458: 160:Sub-surface mining 157: 109:acid sulfate soils 60:acid rock drainage 48:Acid mine drainage 45: 30: 3397: 3396: 3174:Extended aeration 3121:Treatment options 3071:Oxygen saturation 2918:Blackwater (coal) 2896:Sources and types 2739:on 7 October 2011 2497:10.1021/ol4033418 1810:10.1021/es990646v 1447:Mount Morgan Mine 1085:Metagenomic study 1065:products include 719:calcium carbonate 3422: 3386: 3385: 3305:Evaporation pond 3293:Disposal options 3264:Trickling filter 3249:Sewage treatment 3149:Carbon filtering 3129:Activated sludge 2882: 2875: 2868: 2859: 2858: 2767: 2755: 2749: 2748: 2746: 2744: 2738: 2720: 2711: 2705: 2696: 2690: 2680: 2674: 2664: 2658: 2645: 2639: 2638: 2636: 2634: 2617: 2611: 2608: 2602: 2601: 2599: 2597: 2592:on 13 March 2012 2578: 2572: 2571: 2561: 2525: 2519: 2518: 2508: 2472: 2466: 2465: 2455: 2445: 2421: 2415: 2414: 2370: 2364: 2363: 2319: 2313: 2312: 2284: 2278: 2277: 2240: 2234: 2233: 2231: 2229: 2220:. Archived from 2214: 2208: 2207: 2205: 2203: 2198:on 23 April 2015 2187: 2181: 2178: 2172: 2171:Harsco Minerals. 2166: 2160: 2159: 2157: 2155: 2146:. Archived from 2139: 2130: 2129: 2127: 2125: 2116:. Archived from 2110: 2104: 2100: 2094: 2093: 2091: 2089: 2083: 2072: 2063: 2052: 2041: 2035: 2024: 2018: 2011: 2005: 1992: 1983: 1982: 1965:(9): 1101–1108. 1954: 1948: 1947: 1927: 1921: 1905:Robert S Hedin, 1903: 1897: 1883: 1877: 1871: 1865: 1864: 1828: 1822: 1821: 1781: 1775: 1768: 1762: 1761: 1705: 1699: 1693: 1692: 1667:(1–3): 307–332. 1656: 1650: 1649: 1612: 1606: 1599: 1593: 1587: 1578: 1571: 1565: 1545: 1469:Papua New Guinea 1393:Hughes bore hole 1381:, impacting the 1351:Lackawanna River 1255:Clark Fork River 1169:Aznalcollar mine 1115:mine reclamation 1071:hydrogen sulfide 895: 863:calcium silicate 835: 795: 736: 684: 683:CA$ 17.5 million 680: 676: 672: 664: 499:neutralizes acid 435: 427: 426: 423: 386: 342: 334: 333: 330: 170:piles or ponds, 134:sulfide minerals 87:sulfide minerals 3430: 3429: 3425: 3424: 3423: 3421: 3420: 3419: 3400: 3399: 3398: 3393: 3374: 3340:Reclaimed water 3288: 3214:Reverse osmosis 3115: 3037: 3003:Reverse osmosis 2928:Boiler blowdown 2891: 2886: 2775: 2770: 2764:Wayback Machine 2756: 2752: 2742: 2740: 2736: 2718: 2712: 2708: 2697: 2693: 2681: 2677: 2665: 2661: 2655:Wayback Machine 2646: 2642: 2632: 2630: 2618: 2614: 2609: 2605: 2595: 2593: 2580: 2579: 2575: 2526: 2522: 2473: 2469: 2422: 2418: 2371: 2367: 2330:(6978): 37–43. 2320: 2316: 2285: 2281: 2241: 2237: 2227: 2225: 2216: 2215: 2211: 2201: 2199: 2188: 2184: 2179: 2175: 2167: 2163: 2153: 2151: 2150:on 20 July 2011 2140: 2133: 2123: 2121: 2112: 2111: 2107: 2101: 2097: 2087: 2085: 2081: 2070: 2064: 2055: 2050:Wayback Machine 2042: 2038: 2033:Wayback Machine 2025: 2021: 2012: 2008: 2001:Wayback Machine 1993: 1986: 1955: 1951: 1928: 1924: 1914:Wayback Machine 1904: 1900: 1895:Wayback Machine 1884: 1880: 1872: 1868: 1829: 1825: 1782: 1778: 1769: 1765: 1706: 1702: 1696: 1657: 1653: 1613: 1609: 1600: 1596: 1588: 1581: 1572: 1568: 1557:Wayback Machine 1546: 1542: 1538: 1501: 1415: 1364:Wayback Machine 1312:, United States 1277:San Luis Valley 1234: 1155: 1135: 1127: 1111: 1087: 1079: 1033: 1028: 1001:climate warming 962: 930:Cation exchange 927: 894: 890: 876: 872: 859: 847: 842: 834: 830: 827: 823: 811: 794: 790: 777: 769:calcium sulfate 734: 730: 726: 696: 691: 682: 679:CA$ 400 million 678: 674: 670: 662: 619: 614: 579: 570: 560:valleys in the 538: 507: 450: 445: 434: 430: 424: 421: 420: 418: 414: 410: 406: 402: 399: 395: 385: 381: 377: 373: 369: 366: 362: 358: 341: 337: 331: 328: 327: 325: 321: 317: 313: 310: 306: 303: 299: 282: 276: 149: 125: 17: 12: 11: 5: 3428: 3418: 3417: 3412: 3395: 3394: 3392: 3391: 3379: 3376: 3375: 3373: 3372: 3367: 3365:Surface runoff 3362: 3357: 3352: 3347: 3345:Sanitary sewer 3342: 3337: 3335:Marine outfall 3332: 3330:Marine dumping 3327: 3322: 3320:Injection well 3317: 3312: 3307: 3302: 3300:Combined sewer 3296: 3294: 3290: 3289: 3287: 3286: 3281: 3276: 3271: 3266: 3261: 3256: 3251: 3246: 3241: 3239:Settling basin 3236: 3231: 3226: 3221: 3216: 3211: 3206: 3201: 3196: 3191: 3186: 3181: 3176: 3171: 3166: 3161: 3156: 3151: 3146: 3141: 3136: 3134:Aerated lagoon 3131: 3125: 3123: 3117: 3116: 3114: 3113: 3108: 3103: 3098: 3093: 3088: 3083: 3078: 3073: 3068: 3066:Coliform index 3063: 3058: 3053: 3047: 3045: 3039: 3038: 3036: 3035: 3030: 3025: 3020: 3015: 3010: 3008:Sanitary sewer 3005: 3000: 2995: 2993:Produced water 2990: 2985: 2980: 2975: 2970: 2965: 2960: 2955: 2950: 2945: 2940: 2938:Combined sewer 2935: 2930: 2925: 2920: 2915: 2910: 2905: 2899: 2897: 2893: 2892: 2885: 2884: 2877: 2870: 2862: 2856: 2855: 2850: 2845: 2840: 2835: 2830: 2825: 2820: 2815: 2810: 2805: 2800: 2795: 2790: 2774: 2773:External links 2771: 2769: 2768: 2750: 2706: 2691: 2675: 2659: 2640: 2612: 2603: 2573: 2544:(8): 571–575. 2520: 2491:(2): 456–459. 2467: 2436:(4): 303–336. 2416: 2365: 2314: 2279: 2252:(4): 241–250. 2235: 2209: 2182: 2173: 2161: 2131: 2120:on 24 May 2011 2105: 2095: 2084:on 5 June 2013 2053: 2036: 2019: 2006: 1984: 1959:Water Research 1949: 1922: 1898: 1878: 1866: 1823: 1796:(2): 254–258. 1776: 1763: 1700: 1694: 1651: 1607: 1594: 1579: 1566: 1539: 1537: 1534: 1533: 1532: 1527: 1522: 1517: 1512: 1507: 1500: 1497: 1496: 1495: 1485: 1478:Mount Te Aroha 1471: 1454: 1444: 1434: 1428:Papua province 1421: 1414: 1411: 1410: 1409: 1402:Gold King Mine 1399: 1390: 1385: 1375:Elizabeth Mine 1371: 1354: 1344: 1343:, Kentucky, US 1338: 1324: 1319: 1313: 1303: 1285: 1279: 1262: 1259:Butte, Montana 1245: 1233: 1230: 1229: 1228: 1213: 1207: 1204:Libiola's mine 1201: 1195: 1189: 1176: 1166: 1163:County Wicklow 1154: 1151: 1150: 1149: 1134: 1131: 1126: 1123: 1110: 1107: 1086: 1083: 1078: 1075: 1047:organic matter 1031: 1027: 1024: 1020:Whitworth mine 989:copper sulfide 961: 958: 926: 923: 892: 874: 870: 858: 855: 850: 849: 845: 840: 832: 825: 821: 809: 792: 776: 773: 732: 728: 695: 692: 690: 687: 631:Coal Authority 618: 615: 613: 610: 609: 608: 605: 602: 596: 590: 578: 575: 569: 566: 537: 534: 506: 503: 475:discharges in 449: 446: 444: 441: 437: 436: 432: 428: 416: 412: 408: 404: 400: 397: 388: 387: 383: 379: 375: 371: 367: 364: 360: 344: 343: 339: 335: 323: 319: 315: 311: 308: 304: 301: 275: 272: 148: 145: 124: 121: 113:sea level rise 38:Shamokin Creek 15: 9: 6: 4: 3: 2: 3427: 3416: 3413: 3411: 3408: 3407: 3405: 3390: 3381: 3380: 3377: 3371: 3368: 3366: 3363: 3361: 3358: 3356: 3353: 3351: 3348: 3346: 3343: 3341: 3338: 3336: 3333: 3331: 3328: 3326: 3323: 3321: 3318: 3316: 3313: 3311: 3308: 3306: 3303: 3301: 3298: 3297: 3295: 3291: 3285: 3282: 3280: 3277: 3275: 3272: 3270: 3267: 3265: 3262: 3260: 3257: 3255: 3252: 3250: 3247: 3245: 3242: 3240: 3237: 3235: 3232: 3230: 3229:Sedimentation 3227: 3225: 3222: 3220: 3217: 3215: 3212: 3210: 3207: 3205: 3202: 3200: 3197: 3195: 3192: 3190: 3187: 3185: 3182: 3180: 3177: 3175: 3172: 3170: 3167: 3165: 3162: 3160: 3157: 3155: 3152: 3150: 3147: 3145: 3142: 3140: 3137: 3135: 3132: 3130: 3127: 3126: 3124: 3122: 3118: 3112: 3109: 3107: 3104: 3102: 3099: 3097: 3094: 3092: 3089: 3087: 3084: 3082: 3079: 3077: 3074: 3072: 3069: 3067: 3064: 3062: 3059: 3057: 3054: 3052: 3049: 3048: 3046: 3044: 3040: 3034: 3031: 3029: 3026: 3024: 3023:Sewage sludge 3021: 3019: 3016: 3014: 3011: 3009: 3006: 3004: 3001: 2999: 2996: 2994: 2991: 2989: 2986: 2984: 2981: 2979: 2976: 2974: 2971: 2969: 2966: 2964: 2961: 2959: 2956: 2954: 2951: 2949: 2948:Cooling water 2946: 2944: 2943:Cooling tower 2941: 2939: 2936: 2934: 2931: 2929: 2926: 2924: 2921: 2919: 2916: 2914: 2911: 2909: 2908:Ballast water 2906: 2904: 2901: 2900: 2898: 2894: 2890: 2883: 2878: 2876: 2871: 2869: 2864: 2863: 2860: 2854: 2851: 2849: 2846: 2844: 2841: 2839: 2836: 2834: 2831: 2829: 2826: 2824: 2821: 2819: 2816: 2814: 2811: 2809: 2806: 2804: 2801: 2799: 2796: 2794: 2791: 2788: 2784: 2780: 2777: 2776: 2765: 2761: 2758: 2754: 2735: 2731: 2727: 2725: 2717: 2710: 2703: 2700: 2695: 2688: 2684: 2679: 2672: 2670: 2663: 2656: 2652: 2649: 2644: 2629: 2628: 2623: 2616: 2607: 2591: 2587: 2583: 2577: 2569: 2565: 2560: 2555: 2551: 2547: 2543: 2539: 2535: 2534:sp. RM-27-46" 2533: 2524: 2516: 2512: 2507: 2502: 2498: 2494: 2490: 2486: 2482: 2480: 2471: 2463: 2459: 2454: 2449: 2444: 2439: 2435: 2431: 2427: 2420: 2412: 2408: 2404: 2400: 2396: 2392: 2388: 2384: 2380: 2376: 2369: 2361: 2357: 2353: 2349: 2345: 2341: 2337: 2333: 2329: 2325: 2318: 2310: 2306: 2302: 2298: 2294: 2290: 2283: 2275: 2271: 2267: 2263: 2259: 2255: 2251: 2247: 2239: 2223: 2219: 2213: 2197: 2193: 2186: 2177: 2170: 2165: 2149: 2145: 2138: 2136: 2119: 2115: 2109: 2099: 2080: 2076: 2069: 2062: 2060: 2058: 2051: 2047: 2044: 2040: 2034: 2030: 2027: 2023: 2017: 2010: 2002: 1998: 1995: 1991: 1989: 1980: 1976: 1972: 1968: 1964: 1960: 1953: 1945: 1941: 1937: 1933: 1926: 1919: 1915: 1911: 1908: 1902: 1896: 1892: 1888: 1882: 1875: 1870: 1862: 1858: 1854: 1850: 1846: 1842: 1838: 1834: 1827: 1819: 1815: 1811: 1807: 1803: 1799: 1795: 1791: 1787: 1780: 1773: 1767: 1759: 1755: 1751: 1747: 1743: 1739: 1735: 1731: 1727: 1723: 1719: 1715: 1711: 1704: 1698: 1690: 1686: 1682: 1678: 1674: 1670: 1666: 1662: 1655: 1647: 1643: 1639: 1635: 1631: 1627: 1623: 1619: 1611: 1604: 1598: 1591: 1586: 1584: 1576: 1570: 1563: 1559: 1558: 1554: 1551: 1544: 1540: 1531: 1528: 1526: 1523: 1521: 1518: 1516: 1513: 1511: 1508: 1506: 1503: 1502: 1493: 1489: 1486: 1483: 1479: 1475: 1472: 1470: 1466: 1465:Ok Tedi River 1462: 1458: 1455: 1452: 1448: 1445: 1442: 1438: 1435: 1433: 1429: 1425: 1424:Grasberg mine 1422: 1420: 1417: 1416: 1407: 1403: 1400: 1398: 1394: 1391: 1389: 1386: 1384: 1380: 1376: 1372: 1369: 1368:West Virginia 1365: 1361: 1358: 1355: 1352: 1348: 1345: 1342: 1339: 1336: 1332: 1328: 1325: 1323: 1320: 1317: 1314: 1311: 1307: 1304: 1301: 1297: 1293: 1289: 1286: 1283: 1280: 1278: 1274: 1273:Alamosa River 1270: 1266: 1263: 1260: 1256: 1252: 1249: 1246: 1243: 1239: 1236: 1235: 1232:North America 1226: 1222: 1218: 1214: 1211: 1208: 1205: 1202: 1199: 1196: 1193: 1190: 1188: 1184: 1180: 1177: 1174: 1170: 1167: 1164: 1160: 1157: 1156: 1148: 1144: 1143:Witwatersrand 1140: 1137: 1136: 1130: 1122: 1120: 1116: 1106: 1104: 1100: 1096: 1092: 1082: 1074: 1072: 1068: 1064: 1060: 1057:, instead of 1056: 1052: 1048: 1045: 1041: 1036: 1023: 1021: 1017: 1014:valley above 1013: 1009: 1004: 1002: 998: 994: 991:or elemental 990: 986: 982: 976: 974: 970: 966: 957: 955: 951: 947: 943: 939: 935: 931: 922: 920: 916: 911: 907: 903: 899: 888: 884: 878: 868: 864: 854: 843: 836: 819: 818: 817: 814: 812: 805: 801: 796: 787: 783: 772: 770: 766: 762: 757: 756:in solution. 755: 751: 748: 744: 740: 724: 720: 714: 712: 708: 705: 701: 686: 675:CA$ 5 billion 671:CA$ 2 billion 666: 658: 656: 652: 648: 644: 640: 639:River Pelenna 636: 632: 628: 624: 606: 603: 600: 597: 594: 591: 588: 587: 586: 583: 574: 565: 563: 559: 555: 551: 547: 543: 533: 531: 528: 524: 520: 516: 512: 502: 500: 497: 493: 489: 486: 482: 478: 474: 469: 465: 463: 454: 448:Effects on pH 440: 394: 393: 392: 357: 356: 355: 353: 349: 298: 297: 296: 293: 291: 287: 281: 271: 267: 265: 261: 257: 253: 249: 245: 241: 237: 232: 230: 229: 224: 220: 216: 212: 211:extremophiles 208: 204: 200: 196: 192: 188: 184: 179: 177: 173: 169: 165: 161: 153: 144: 142: 137: 135: 131: 120: 118: 114: 110: 105: 103: 100: 96: 92: 88: 82: 80: 76: 73: 69: 65: 61: 57: 53: 49: 43: 39: 34: 27: 23: 19: 3370:Vacuum sewer 3254:Sewer mining 3204:Ion exchange 3154:Chlorination 3076:Heavy metals 3033:Urban runoff 2973:Ion exchange 2953:Fecal sludge 2902: 2753: 2741:. 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Antibiot 2430:Metabolites 2295:: 475–493. 2202:12 December 1720:(1): 3–14. 1505:Bioleaching 1494:, Australia 1453:, Australia 1443:, Australia 1331:Elliot Lake 1238:Argo Tunnel 1210:Spree River 1198:Odiel River 1192:Tinto River 1067:bicarbonate 1016:Port Talbot 1008:Afon Pelena 761:Cwm Rheidol 754:bicarbonate 750:dissolution 663:pH 6–9 651:River Neath 647:Port Talbot 246:but rather 242:may not be 219:acidophiles 176:coal spoils 164:water table 70:water from 3404:Categories 3325:Irrigation 3189:Filtration 2889:Wastewater 2787:0642725128 2743:6 December 1618:Geobiology 1536:References 1459:caused by 1451:Queensland 1349:borehole, 1318:, Ohio, US 1179:Wheal Jane 1012:River Afan 999:caused by 969:Appalachia 942:mine water 902:aggregates 898:alkalinity 889:slows the 743:passivates 704:calcareous 643:River Afan 530:ecosystems 519:yellow boy 505:Yellow boy 496:overburden 485:anthracite 481:bituminous 195:overburden 147:Occurrence 141:metalloids 99:coal waste 79:coal mines 3159:Clarifier 3106:Turbidity 2958:Greywater 2485:Org. Lett 2411:203592485 2274:108962729 2103:1027–1034 1938:: 53–73. 1742:0048-9697 1646:129323041 1432:Indonesia 1347:Old Forge 1300:Tennessee 1251:superfund 1212:, Germany 1173:Guadiamar 1165:, Ireland 1063:metabolic 915:dispersed 910:colloidal 800:clarifier 700:limestone 655:Ynysarwed 617:Oversight 612:Treatment 589:Sampling; 554:manganese 550:aluminium 492:limestone 473:coal mine 352:iron(III) 274:Chemistry 185:of metal 183:oxidation 26:Rio Tinto 3086:Salinity 2978:Leachate 2913:Bathroom 2760:Archived 2702:ABC News 2687:ABC News 2651:Archived 2633:18 March 2568:24713874 2515:24341358 2462:24957513 2403:31563048 2352:14961025 2154:25 April 2088:30 March 2046:Archived 2029:Archived 1997:Archived 1910:Archived 1891:Archived 1861:94970470 1818:95350834 1758:24245069 1750:15680622 1689:16806405 1553:Archived 1499:See also 1492:Tasmania 1474:Tui mine 1406:Colorado 1360:Archived 1337:, Canada 1296:Virginia 1294:system, 1284:, Canada 1219:and the 1183:Cornwall 1061:. Their 997:droughts 993:selenium 985:oxidised 973:reducing 946:adsorbed 919:armoring 906:adsorbed 887:Armoring 883:armoring 731:·2H 523:jarosite 415:→ 15 Fe 348:iron(II) 199:bacteria 187:sulfides 168:Tailings 3013:Septage 2559:4146655 2506:3964319 2453:3901206 2383:Bibcode 2360:4420754 2332:Bibcode 2297:Bibcode 2254:Bibcode 2228:13 July 2124:13 July 1967:Bibcode 1841:Bibcode 1798:Bibcode 1722:Bibcode 1669:Bibcode 1626:Bibcode 1480:in the 1413:Oceania 1335:Ontario 1225:lignite 1206:, Italy 1200:, Spain 1194:, Spain 1187:England 1175:, Spain 1171:on the 1095:genomes 1051:sulfate 1044:oxidize 1010:in the 881:termed 763:in mid 747:calcite 698:Often, 689:Methods 546:arsenic 494:in the 443:Effects 403:+ 14 Fe 374:→ 4 Fe 322:→ 2 Fe 286:ferrous 207:abiotic 203:archaea 189:(often 3387:  3028:Toilet 3018:Sewage 2983:Manure 2785:  2596:2 July 2566:  2556:  2513:  2503:  2460:  2450:  2409:  2401:  2358:  2350:  2324:Nature 2272:  1859:  1816:  1756:  1748:  1740:  1687:  1644:  1377:in S. 1333:area, 1288:Clinch 1153:Europe 1133:Africa 1059:oxygen 1049:using 1042:(SRB) 954:IChemE 831:Ca(OH) 804:gypsum 791:Ca(OH) 723:gypsum 707:strata 552:, and 527:stream 431:+ 16 H 419:+ 2 SO 326:+ 4 SO 290:ferric 256:nickel 252:copper 215:oxygen 191:pyrite 174:, and 68:acidic 58:), or 2933:Brine 2737:(PDF) 2719:(PDF) 2407:S2CID 2356:S2CID 2270:S2CID 2082:(PDF) 2071:(PDF) 1857:S2CID 1814:S2CID 1754:S2CID 1642:S2CID 1159:Avoca 950:brine 844:+ 2 H 765:Wales 739:armor 645:near 558:Wales 407:+ 8 H 378:+ 2 H 370:+ 4 H 338:+ 4 H 314:+ 2 H 307:+ 7 O 300:2 FeS 254:, or 75:mines 72:metal 3274:UASB 2783:ISBN 2745:2011 2635:2013 2598:2014 2564:PMID 2511:PMID 2458:PMID 2399:PMID 2348:PMID 2230:2009 2204:2010 2156:2011 2126:2009 2090:2011 1918:ASMR 1746:PMID 1738:ISSN 1685:PMID 1408:, US 1370:, US 1302:, US 1298:and 1261:, US 1244:, US 1215:The 891:CaCO 867:slag 839:CaSO 808:CaSO 782:lime 727:CaSO 673:and 625:and 542:lead 483:and 433:(aq) 429:(aq) 417:(aq) 405:(aq) 376:(aq) 372:(aq) 361:(aq) 359:4 Fe 340:(aq) 336:(aq) 324:(aq) 248:zinc 244:iron 201:and 102:tips 95:coal 77:and 2554:PMC 2546:doi 2501:PMC 2493:doi 2448:PMC 2438:doi 2391:doi 2379:251 2340:doi 2328:428 2305:doi 2293:151 2262:doi 1975:doi 1940:doi 1849:doi 1806:doi 1730:doi 1718:338 1677:doi 1665:369 1634:doi 1267:in 1097:of 1053:as 873:SiO 786:CaO 653:at 413:(l) 401:(s) 396:FeS 384:(l) 368:(g) 363:+ O 354:): 320:(l) 312:(g) 305:(s) 240:ion 236:ore 64:ARD 56:AMD 40:in 3406:: 3081:pH 2728:. 2721:. 2685:, 2624:. 2584:. 2562:. 2552:. 2542:67 2540:. 2536:. 2509:. 2499:. 2489:16 2487:. 2483:. 2456:. 2446:. 2432:. 2428:. 2405:. 2397:. 2389:. 2377:. 2354:. 2346:. 2338:. 2326:. 2303:. 2291:. 2268:. 2260:. 2250:27 2248:. 2134:^ 2073:. 2056:^ 2004:40 1987:^ 1973:. 1963:22 1961:. 1936:17 1934:. 1855:. 1847:. 1837:83 1835:. 1812:. 1804:. 1794:34 1792:. 1788:. 1752:. 1744:. 1736:. 1728:. 1712:. 1683:. 1675:. 1663:. 1640:. 1632:. 1620:. 1582:^ 1560:, 1490:, 1467:, 1463:, 1449:, 1439:, 1430:, 1426:, 1404:, 1395:, 1366:, 1329:, 1308:, 1240:, 1185:, 1181:, 1161:, 1145:, 1141:, 1093:, 861:A 837:→ 828:+ 824:SO 788:– 685:. 657:. 562:UK 548:, 544:, 422:2− 329:2− 250:, 223:pH 130:pH 119:. 81:. 50:, 2881:e 2874:t 2867:v 2747:. 2637:. 2600:. 2570:. 2548:: 2517:. 2495:: 2464:. 2440:: 2434:2 2413:. 2393:: 2385:: 2362:. 2342:: 2334:: 2311:. 2307:: 2299:: 2276:. 2264:: 2256:: 2232:. 2206:. 2158:. 2128:. 2092:. 1981:. 1977:: 1969:: 1946:. 1942:: 1863:. 1851:: 1843:: 1820:. 1808:: 1800:: 1760:. 1732:: 1724:: 1691:. 1679:: 1671:: 1648:. 1636:: 1628:: 1622:1 1290:- 1032:2 893:3 875:4 871:4 848:O 846:2 841:4 833:2 826:4 822:2 820:H 810:4 806:( 793:2 784:( 735:O 733:2 729:4 725:( 425:4 411:O 409:2 398:2 382:O 380:2 365:2 332:4 318:O 316:2 309:2 302:2 62:( 54:(

Index


Rio Tinto

Shamokin Creek
Northumberland County, Pennsylvania
acidic
metal
mines
coal mines
sulfide minerals
highway construction
coal
coal waste
tips
acid sulfate soils
sea level rise
environmental hazard
pH
sulfide minerals
metalloids

Sub-surface mining
water table
Tailings
mine waste rock dumps
coal spoils
oxidation
sulfides
pyrite
overburden

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