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Siderite

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Mushet realised that he could operate the Bessemer converter for longer, burning off all the steel's impurities including the unwanted phosphorus but also the carbon (which is an essential ingredient in steel), and then re-adding carbon, along with manganese, in the form of a previously obscure ferromanganese ore with no phosphorus,
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showed that the reason for the discrepancy was the nature of the Swedish ores that Bessemer had innocently used; they were very low in phosphorus. Using a typical European high-phosphorus ore in Bessemer's converter gave a poor quality steel. To produce high quality steel from a high-phosphorus ore,
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in South Wales soon learned to make it from the spathic siderite ores. For a few decades, spathic ores were therefore in demand and this encouraged their mining. In time though, the original 'acidic' liner of the Bessemer converter, made from siliceous sandstone or
627:. His 'Iron Mill' of 1838 used a three-chambered concentric roasting furnace, before passing the ore to a separate reducing furnace for smelting. Details of this mill were the invention of Charles Sanderson, a steel maker of Sheffield, who held the patent for it. 698: 1159: 1060:
Ludvigson, G. A.; Gonzalez, L. A.; Metzger, R. A.; Witzke, B. J.; Brenner, R. L.; Murillo, A. P.; White, T. S. (1998). "Meteoric sphaerosiderite lines and their use for paleohydrology and paleoclimatology".
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Frederichs, T.; von Dobeneck, T.; Bleil, U.; Dekkers, M. J. (January 2003). "Towards the identification of siderite, rhodochrosite, and vivianite in sediments by their low-temperature magnetic properties".
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if added directly. Instead the ore must be given a preliminary roasting step. Developments of specific techniques to deal with these ores began in the early 19th century, largely with the work of
722: 641:. Although the first demonstrations by Bessemer in 1856 were successful, others' initial attempts to replicate his method infamously failed to produce good steel. Work by the metallurgist 667:
produced by chemical reaction with the liner, and no longer required spiegeleisen. From the 1880s demand for the ores fell once again and many of their mines, including those of the
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in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese.
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Siderite crystals with galena and quartz. Size: 6.2 cm × 4.1 cm × 3.6 cm (2.4 in × 1.6 in × 1.4 in).
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and pumping engine, between these bodies as each is worked out. This makes mining the ore an expensive proposition compared to typical
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than a haematite or other oxide ore. Driving off the carbonate as carbon dioxide requires more energy and so the ore 'kills' the
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Spathic iron ores are rich in manganese and have negligible phosphorus. This led to their one major benefit, connected with the
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Mozley, P. S. (1989). "Relation between depositional environment and the elemental composition of early diagenetic siderite".
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These differences between spathic ore and haematite have led to the failure of a number of mining concerns, notably the
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iron ores, such as siderite, have been economically important for steel production, they are far from ideal as an ore.
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are sedimentary formations, thus the economically viable deposits may be considerable thicker and more extensive.
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Cut siderite from Minas Gerais, Brazil. Size: 5 mm × 3.2 mm (0.20 in × 0.13 in).
293: 1222: 538:, siderite commonly forms at shallow burial depths and its elemental composition is often related to the 1237: 1217: 106: 1154: 496: 660: 485: 86: 992:"High-fidelity X-ray micro-tomography reconstruction of siderite-hosted Carboniferous arachnids" 1227: 642: 167: 788: 250: 240: 964: 824: 651: 8: 1232: 470: 462: 358: 283: 273: 968: 828: 478: 1247: 1018: 991: 842: 474: 384: 226: 976: 1134: 1109: 1023: 870: 846: 62: 1013: 1005: 972: 832: 638: 535: 458: 321: 303: 212: 69: 542:
of the enclosing sediments. In addition, a number of recent studies have used the
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Pale yellow to tan, grey, brown, green, red, black and sometimes nearly colorless
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Colorado siderite, with sharp blades of olive-brown and minor accenting quartz.
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The recovered ore also has drawbacks. The carbonate ore is more difficult to
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of 37 K (−236 °C) which can assist in its identification.
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The Brendon Hills Iron Mines and the West Somerset Mineral Railway
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Disc-shaped, brown siderite crystals perched upon chalcopyrites.
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Fossiliferous siderite concretion from the Lower Carboniferous.
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Their hydrothermal mineralisation tends to form them as small
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Garwood, Russell; Dunlop, Jason A.; Sutton, Mark D. (2009).
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commonly substitute for the iron, resulting in the siderite-
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Handbook of Mineralogy: Borates, Carbonates, Sulfates
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deposits, but these are small and economically minor.
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Tabular crystals, often curved; botryoidal to massive
1193: 1178: 1166: 989: 869:. Tucson, Arizona: Mineral Data Publishing. 2003. 1153: 530:, which can encase three-dimensionally preserved 1209: 1103: 1079: 957:Physics and Chemistry of the Earth, Parts A/B/C 659:, was replaced by a 'basic' liner in the newer 663:. This removed the phosphorus impurities as 546:of sphaerosiderite (a type associated with 1104:Prothero, Donald R.; Schwab, Fred (1996). 1122: 1017: 836: 902: 900: 1097: 853: 14: 1210: 1040: 27:Mineral composed of iron(II) carbonate 1199: 1187: 1172: 1128: 1091: 925: 897: 565: 813:"IMA–CNMNC approved mineral symbols" 810: 1133:. Lightmoor Press. pp. 17–22. 24: 588:. This makes them not amenable to 514:, and others. It is also a common 25: 1259: 745: 733: 721: 709: 697: 681: 278:Vitreous, may be silky to pearly 45: 1147: 781: 764: 30:For the type of meteorite, see 1053: 1034: 983: 947: 804: 632:Brendon Hills Iron Ore Company 495:Siderite is commonly found in 407:), meaning "iron". A valuable 13: 1: 977:10.1016/S1474-7065(03)00121-9 798: 639:Bessemer steel-making process 298:Translucent to subtranslucent 7: 1243:Minerals in space group 167 544:oxygen isotopic composition 526:, where it sometimes forms 391:). Its name comes from the 10: 1264: 770:Some siderite, along with 674: 581:, often following steeply 562:shortly after deposition. 396: 29: 502:, and is associated with 367: 357: 344: 320: 312: 302: 292: 282: 272: 259: 249: 239: 225: 211: 201: 193: 188: 166: 150: 133:Hexagonal scalenohedral ( 127: 115: 105: 95: 85: 68: 58: 53: 44: 39: 757: 661:Gilchrist Thomas process 540:depositional environment 486:trigonal crystal system 484:It crystallizes in the 217:Lamellar uncommon on{01 1010:10.1098/rsbl.2009.0464 817:Mineralogical Magazine 789:banded iron formations 643:Robert Forester Mushet 1129:Jones, M. H. (2011). 934:Siderite Mineral Data 671:, closed soon after. 621:Sir Thomas Lethbridge 411:, it consists of 48% 97:Strunz classification 811:Warr, L. N. (2021). 787:Both ironstones and 692:, Cornwall, England. 245:Uneven to conchoidal 1106:Sedimentary Geology 1094:, p. 34–35,37. 1080:Sedimentary Geology 969:2003PCE....28..669F 838:10.1180/mgm.2021.43 829:2021MinM...85..291W 457:of 3.75 to 4.25, a 107:Dana classification 1223:Carbonate minerals 963:(16–19): 669–679. 566:Carbonate iron ore 385:iron(II) carbonate 313:Optical properties 1238:Trigonal minerals 1218:Iron(II) minerals 536:sedimentary rocks 475:antiferromagnetic 461:of 3.96, a white 374: 373: 180:= 15.3796 ; 63:Carbonate mineral 16:(Redirected from 1255: 1203: 1197: 1191: 1185: 1176: 1170: 1164: 1163: 1162: 1158: 1151: 1145: 1144: 1140:9781899889-5-3-2 1126: 1120: 1119: 1101: 1095: 1089: 1083: 1077: 1071: 1070: 1057: 1051: 1050: 1038: 1032: 1031: 1021: 987: 981: 980: 951: 945: 944: 943: 942: 937:, WebMineral.com 929: 923: 922: 921: 920: 904: 895: 894: 892: 891: 886:on 13 March 2022 885: 879:. Archived from 868: 857: 851: 850: 840: 808: 792: 785: 779: 774:, also forms in 768: 749: 737: 725: 713: 701: 685: 590:opencast working 479:Néel temperature 459:specific gravity 406: 400: 322:Refractive index 304:Specific gravity 265: 234: 220: 161: 145: 136: 75: 74:(repeating unit) 49: 37: 36: 21: 18:Spathic iron ore 1263: 1262: 1258: 1257: 1256: 1254: 1253: 1252: 1208: 1207: 1206: 1198: 1194: 1186: 1179: 1171: 1167: 1160: 1152: 1148: 1141: 1127: 1123: 1116: 1102: 1098: 1090: 1086: 1078: 1074: 1058: 1054: 1039: 1035: 997:Biology Letters 988: 984: 952: 948: 940: 938: 931: 930: 926: 918: 916: 906: 905: 898: 889: 887: 883: 877: 866: 859: 858: 854: 809: 805: 801: 796: 795: 786: 782: 769: 765: 760: 753: 750: 741: 738: 729: 726: 717: 714: 705: 702: 693: 686: 677: 568: 558:composition of 467:vitreous lustre 443:, and siderite- 390: 339: 333: 331: 263: 232: 218: 176: 159: 143: 138: 134: 81: 73: 72: 35: 28: 23: 22: 15: 12: 11: 5: 1261: 1251: 1250: 1245: 1240: 1235: 1230: 1225: 1220: 1205: 1204: 1202:, p. 158. 1192: 1177: 1165: 1146: 1139: 1121: 1114: 1096: 1084: 1082:, p. 304. 1072: 1052: 1033: 1004:(6): 841–844. 982: 946: 924: 896: 875: 852: 823:(3): 291–320. 802: 800: 797: 794: 793: 780: 762: 761: 759: 756: 755: 754: 751: 744: 742: 739: 732: 730: 727: 720: 718: 715: 708: 706: 703: 696: 694: 688:Siderite from 687: 680: 676: 673: 598:winding engine 586:bedding planes 567: 564: 560:meteoric water 473:. Siderite is 448:solid solution 388: 372: 371: 369: 365: 364: 361: 355: 354: 348: 342: 341: 337: 329: 324: 318: 317: 314: 310: 309: 306: 300: 299: 296: 290: 289: 286: 280: 279: 276: 270: 269: 266: 257: 256: 253: 247: 246: 243: 237: 236: 231:Perfect on {01 229: 223: 222: 215: 209: 208: 205: 199: 198: 195: 191: 190: 189:Identification 186: 185: 184: = 6 170: 164: 163: 154: 148: 147: 131: 125: 124: 119: 117:Crystal system 113: 112: 109: 103: 102: 99: 93: 92: 89: 83: 82: 79: 76: 66: 65: 60: 56: 55: 51: 50: 42: 41: 32:Iron meteorite 26: 9: 6: 4: 3: 2: 1260: 1249: 1246: 1244: 1241: 1239: 1236: 1234: 1231: 1229: 1228:Calcite group 1226: 1224: 1221: 1219: 1216: 1215: 1213: 1201: 1196: 1190:, p. 16. 1189: 1184: 1182: 1175:, p. 99. 1174: 1169: 1156: 1150: 1142: 1136: 1132: 1125: 1117: 1115:0-7167-2726-9 1111: 1107: 1100: 1093: 1088: 1081: 1076: 1068: 1064: 1056: 1048: 1044: 1037: 1029: 1025: 1020: 1015: 1011: 1007: 1003: 999: 998: 993: 986: 978: 974: 970: 966: 962: 958: 950: 936: 935: 928: 915: 911: 910: 903: 901: 882: 878: 876:9780962209741 872: 865: 864: 856: 848: 844: 839: 834: 830: 826: 822: 818: 814: 807: 803: 790: 784: 777: 773: 767: 763: 748: 743: 736: 731: 724: 719: 712: 707: 700: 695: 691: 684: 679: 678: 672: 670: 669:Brendon Hills 666: 662: 658: 653: 649: 644: 640: 635: 633: 628: 626: 622: 618: 617:blast furnace 614: 609: 607: 603: 599: 595: 591: 587: 584: 580: 575: 573: 563: 561: 557: 553: 549: 545: 541: 537: 533: 529: 525: 521: 517: 513: 509: 505: 501: 498: 493: 491: 487: 482: 480: 476: 472: 468: 464: 460: 456: 455:Mohs hardness 453:Siderite has 451: 449: 446: 445:rhodochrosite 442: 438: 434: 430: 426: 422: 418: 414: 410: 405: 399: 394: 393:Ancient Greek 386: 382: 378: 370: 366: 362: 360: 356: 352: 349: 347: 346:Birefringence 343: 336: 328: 325: 323: 319: 315: 311: 307: 305: 301: 297: 295: 291: 287: 285: 281: 277: 275: 271: 267: 262: 258: 254: 252: 248: 244: 242: 238: 230: 228: 224: 216: 214: 210: 206: 204: 203:Crystal habit 200: 196: 192: 187: 183: 179: 174: 171: 169: 165: 158: 155: 153: 149: 141: 132: 130: 129:Crystal class 126: 123: 120: 118: 114: 110: 108: 104: 100: 98: 94: 90: 88: 84: 77: 71: 67: 64: 61: 57: 52: 48: 43: 38: 33: 19: 1200:Jones (2011) 1195: 1188:Jones (2011) 1173:Jones (2011) 1168: 1149: 1130: 1124: 1105: 1099: 1092:Jones (2011) 1087: 1075: 1069:: 1039–1042. 1066: 1062: 1055: 1046: 1042: 1036: 1001: 995: 985: 960: 956: 949: 939:, retrieved 933: 927: 917:, retrieved 908: 888:. Retrieved 881:the original 862: 860:"Siderite". 855: 820: 816: 806: 783: 766: 648:spiegeleisen 636: 629: 610: 576: 569: 497:hydrothermal 494: 490:rhombohedral 483: 452: 403: 383:composed of 376: 375: 350: 334: 326: 316:Uniaxial (−) 181: 177: 172: 156: 608:opencasts. 528:concretions 518:mineral in 439:, siderite- 437:smithsonite 294:Diaphaneity 152:Space group 111:14.01.01.03 1233:Carbonates 1212:Categories 1049:: 704–706. 941:2022-11-30 919:2022-11-30 914:Mindat.org 890:2022-11-30 799:References 579:ore lenses 524:sandstones 516:diagenetic 488:, and are 477:below its 469:or pearly 421:phosphorus 415:and lacks 368:References 359:Dispersion 261:Mohs scale 140:H-M symbol 87:IMA symbol 1248:Iron ores 847:235729616 652:Ebbw Vale 606:haematite 602:ironstone 572:carbonate 570:Although 441:magnesite 433:manganese 429:magnesium 268:3.75–4.25 175:= 4.6916 168:Unit cell 1028:19656861 909:Siderite 776:bog iron 772:goethite 657:ganister 625:Somerset 556:isotopic 554:for the 508:fluorite 450:series. 409:iron ore 377:Siderite 332:= 1.875 264:hardness 251:Tenacity 241:Fracture 227:Cleavage 213:Twinning 122:Trigonal 59:Category 40:Siderite 1155:GB 7828 1063:Geology 1043:Geology 1019:2828000 965:Bibcode 825:Bibcode 690:Redruth 675:Gallery 583:dipping 550:) as a 532:fossils 404:sídēros 398:σίδηρος 381:mineral 353:= 0.242 340:= 1.633 255:Brittle 101:5.AB.05 70:Formula 54:General 1161:  1137:  1112:  1026:  1016:  873:  845:  594:stopes 520:shales 512:galena 504:barite 471:luster 465:and a 463:streak 431:, and 417:sulfur 363:Strong 284:Streak 274:Luster 884:(PDF) 867:(PDF) 843:S2CID 758:Notes 613:smelt 552:proxy 548:soils 534:. In 500:veins 395:word 387:(FeCO 379:is a 288:White 194:Color 1135:ISBN 1110:ISBN 1024:PMID 871:ISBN 665:slag 522:and 425:Zinc 419:and 413:iron 308:3.96 146:2/m) 78:FeCO 1014:PMC 1006:doi 973:doi 833:doi 623:in 604:or 142:: ( 137:m) 1214:: 1180:^ 1067:26 1065:. 1047:17 1045:. 1022:. 1012:. 1000:. 994:. 971:. 961:28 959:. 912:, 899:^ 841:. 831:. 821:85 819:. 815:. 634:. 510:, 506:, 427:, 423:. 235:1} 221:2} 91:Sd 1143:. 1118:. 1030:. 1008:: 1002:5 979:. 975:: 967:: 893:. 849:. 835:: 827:: 401:( 389:3 351:δ 338:ε 335:n 330:ω 327:n 233:1 219:1 182:Z 178:c 173:a 162:c 160:3 157:R 144:3 135:3 80:3 34:. 20:)

Index

Spathic iron ore
Iron meteorite

Carbonate mineral
Formula
IMA symbol
Strunz classification
Dana classification
Crystal system
Trigonal
Crystal class
H-M symbol
Space group
Unit cell
Crystal habit
Twinning
Cleavage
Fracture
Tenacity
Mohs scale
Luster
Streak
Diaphaneity
Specific gravity
Refractive index
Birefringence
Dispersion
mineral
iron(II) carbonate
Ancient Greek

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