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The introduction of an ether function to a perfluoro-polymer chain also provides thermoplastic properties to the polymer, making thermal forming possible. This is a great technological advantage for producing a large variety of shapes (e.g., beakers, funnels, flasks for laboratory uses, etc...) and
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137:(PTFE). Methylfluoroalkoxy (MFA) is a polytetrafluoroethylene perfluoro methylvinylether prepared with a different ratio of PTFE and MVE monomers to that used for PFA. In these materials, the ether groups are pendant from the polymer backbone.
99:
212:
Günter
Siegemund; Werner Schwertfeger; Andrew Feiring; Bruce Smart; Fred Behr; Herward Vogel; Blaine McKusick (2002). "Fluorine Compounds, Organic".
30:. In general these compounds are structurally analogous to the related hydrocarbon ethers, except for the distinctive properties of
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330:
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248:, John Ferguson Harris, Jr. & Donald Irwin McCane, "Fluorocarbon ethers", issued 1965-04-27
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are two of the simplest cyclic perfluoroethers. These are precursors of perfluoro(methyl vinyl ether) (CF
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of highly chemically-resistant tubing. It also confers on the polymer a translucent appearance.
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Michael G. Costello; Richard M. Flynn; John G. Owens (2001). "Fluoroethers and
Fluoroamines".
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8:
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is a grease generated by the polymerization of hexafluoropropylene oxide. Its
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At high temperatures or in a fire, perfluoroethers decompose and may release
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More interesting and more useful are the cyclic ethers, especially, the
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is a fluoroether with strongly acidic sulfonic acid substituents
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50:
24:
195:. Any residue must be handled using protective equipment.
61:
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91:, such perfluoro(2-ethoxyethane)sulfonic acid (PFEESA).
169:. The ether groups are integral to the polymer chain.
57:
tubing is commonly used to handle aggressive chemicals
114:) and perfluoro(propyl vinyl ether), and are used as
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266:Kirk-Othmer Encyclopedia of Chemical Technology
214:Ullmann's Encyclopedia of Industrial Chemistry
274:10.1002/0471238961.0612211506122514.a01.pub2
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175:is a perfluorinated polyether with pendant
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46:Low molecular weight fluorinated ethers
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75:perfluoroethers are analogues of
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186:
1:
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7:
133:with properties similar to
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118:with tetrafluoroethylene.
122:Polymeric perfluoroethers
104:hexafluoropropylene oxide
100:Tetrafluoroethylene oxide
331:Perfluorinated compounds
268:. Weinstein: Wiley-VCH.
222:10.1002/14356007.a11_349
216:. Weinheim: Wiley-VCH.
135:polytetrafluoroethylene
127:Perfluoroalkoxy alkanes
23:containing one or more
21:organofluorine compound
246:US patent 3180895A
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193:hydrogen fluoride
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28:functional group
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321:Thermoplastics
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316:Fluoropolymers
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301:MFA Properties
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295:External links
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77:diethylether
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187:Precautions
179:groups (RSO
147:is F−(CF(CF
129:(PFAs) are
310:Categories
199:References
116:comonomers
79:, e.g. O(C
40:extrusion
96:epoxides
73:Acyclic
38:allows
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173:Nafion
141:Krytox
110:=CFOCF
66:Nafion
25:ether
278:ISBN
226:ISBN
183:H).
151:)−CF
102:and
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218:doi
161:−CF
155:−O)
55:PFA
312::
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165:CF
98:.
34:.
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272::
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220::
181:3
167:3
163:2
158:n
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149:3
112:3
108:2
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85:5
83:F
81:2
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