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Miscibility

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Miscibility of two materials is often determined optically. When the two miscible liquids are combined, the resulting liquid is clear. If the mixture is cloudy the two materials are immiscible. Care must be taken with this determination. If the
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with each other. Typically, a mixture will be possible in the molten state, but upon freezing, the metals separate into layers. This property allows solid
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of the two materials are similar, an immiscible mixture may be clear and give an incorrect determination that the two liquids are miscible.
703: 258:; the very long carbon chains of lipids cause them almost always to be immiscible with water. Analogous situations occur for other 525: 748: 660: 633: 606: 579: 552: 498: 471: 444: 417: 230:, with eight carbons, is practically insoluble in water, and its immiscibility leads it to be used as a standard for 696: 290:
to be formed by rapidly freezing a molten mixture of immiscible metals. One example of immiscibility in metals is
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than the components, they are likely to be immiscible in one another even in the liquid state.
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Ability of two substances to form a homogeneous solution when mixed regardless of concentration
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Some metals are immiscible in the liquid state. One with industrial importance is that liquid
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chain often determines the compound's miscibility with water. For example, among the
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is not soluble in water, so these two solvents are immiscible. As another example,
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if the mixture does not form a solution for certain proportions. For one example,
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Binary Systems: Solubilities of Inorganic and Organic Compounds, Volume 1P1
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Octanol-Water Partition Coefficients: Fundamentals and Physical Chemistry
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Magneto-Resistive and Spin Valve Heads: Fundamentals and Applications
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Experimental Organic Chemistry: A Miniscale and Microscale Approach
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Knoll, Wolfgang; Advincula, Rigoberto C. (2013-02-12).
317:, while silver is miscible in zinc. This leads to the 77: 68: 1002:
List of boiling and freezing information of solvents
98: 92: 86: 514:Gilbert, John C.; Martin, Stephen F. (2010-01-19). 250:(with six) is practically insoluble, as are longer 83: 71: 242:(with four carbon atoms) are miscible with water, 1054: 649:Olabisi, Olagoke; Adewale, Kolapo (1997-03-19). 142:(etymologically equivalent to the common term " 648: 621: 432: 158:. An example in liquids is the miscibility of 51:. The bright rainbow pattern is the result of 697: 513: 459: 601:. Royal Society of Chemistry. p. 328. 460:Barber, Jill; Rostron, Chris (2013-07-25). 246:(with five carbons) is partly soluble, and 704: 690: 540: 486: 401: 39: 574:. Woodhead Publishing. pp. 51–52. 433:Stephen, H.; Stephen, T. (2013-10-22). 169:By contrast, substances are said to be 14: 1055: 711: 628:. John Wiley & Sons. p. 690. 625:Functional Polymer Films, 2 Volume Set 146:"). The term is most often applied to 685: 594: 567: 407: 328: 222:and is miscible with water, whereas 190: 24: 412:. Pearson Education. p. 412. 136:). Such substances are said to be 25: 1074: 677: 541:Mallinson, John C. (2001-09-27). 520:. Cengage Learning. p. 841. 350: 166:as they mix in all proportions. 64: 672: 642: 615: 588: 561: 547:. Academic Press. p. 47. 534: 507: 480: 453: 426: 13: 1: 395: 992:Inorganic nonaqueous solvent 571:The International Lead Trade 568:Rich, Vincent (2014-03-14). 7: 487:Sangster, J. (1997-05-28). 363: 10: 1079: 977:Acid dissociation constant 655:. CRC Press. p. 170. 652:Handbook of Thermoplastics 598:Nuclear Magnetic Resonance 332: 226:with four carbons is not. 29: 960: 892: 822: 719: 493:. John Wiley & Sons. 313:are immiscible in liquid 273: 109:) is the property of two 463:Pharmaceutical Chemistry 323:liquid-liquid extraction 942:Solubility table (data) 809:Apparent molar property 408:Wade, Leroy G. (2003). 345:configurational entropy 907:Total dissolved solids 902:Solubility equilibrium 827:and related quantities 56: 53:thin-film interference 1007:Partition coefficient 987:Polar aprotic solvent 358:indices of refraction 234:. The straight-chain 121:in each other at any 43: 922:Enthalpy of solution 849:Volume concentration 844:Number concentration 595:Webb, G. A. (2007). 232:partition equilibria 150:but also applies to 1063:Chemical properties 834:Molar concentration 804:Dilution (equation) 282:are unable to form 117:(that is, to fully 874:Isotopic abundance 839:Mass concentration 713:Chemical solutions 390:Multiphasic liquid 335:Hydrophobic effect 57: 1050: 1049: 410:Organic Chemistry 329:Effect of entropy 260:functional groups 197:organic compounds 191:Organic compounds 47:is immiscible in 16:(Redirected from 1070: 947:Solubility chart 774:Phase separation 734:Aqueous solution 706: 699: 692: 683: 682: 667: 666: 646: 640: 639: 619: 613: 612: 592: 586: 585: 565: 559: 558: 538: 532: 531: 511: 505: 504: 484: 478: 477: 457: 451: 450: 430: 424: 423: 405: 339:If a mixture of 321:, an example of 236:carboxylic acids 108: 107: 104: 103: 100: 97: 94: 91: 88: 85: 82: 79: 76: 73: 70: 21: 1078: 1077: 1073: 1072: 1071: 1069: 1068: 1067: 1053: 1052: 1051: 1046: 956: 917:Solvation shell 888: 826: 818: 814:Miscibility gap 799:Serial dilution 794:Supersaturation 744:Buffer solution 715: 710: 680: 675: 670: 663: 647: 643: 636: 620: 616: 609: 593: 589: 582: 566: 562: 555: 539: 535: 528: 512: 508: 501: 485: 481: 474: 458: 454: 447: 431: 427: 420: 406: 402: 398: 385:Miscibility gap 375:Heteroazeotrope 366: 353: 337: 331: 276: 193: 67: 63: 38: 28: 23: 22: 15: 12: 11: 5: 1076: 1066: 1065: 1048: 1047: 1045: 1044: 1039: 1034: 1029: 1024: 1019: 1014: 1009: 1004: 999: 994: 989: 984: 982:Protic solvent 979: 974: 966: 964: 958: 957: 955: 954: 949: 944: 939: 934: 929: 927:Lattice energy 924: 919: 914: 909: 904: 898: 896: 890: 889: 887: 886: 881: 876: 871: 866: 861: 856: 851: 846: 841: 836: 830: 828: 820: 819: 817: 816: 811: 806: 801: 796: 791: 786: 781: 779:Eutectic point 776: 771: 766: 761: 756: 751: 746: 741: 739:Solid solution 736: 731: 729:Ideal solution 725: 723: 717: 716: 709: 708: 701: 694: 686: 679: 678:External links 676: 674: 671: 669: 668: 661: 641: 634: 614: 607: 587: 580: 560: 553: 533: 527:978-1439049143 526: 506: 499: 479: 472: 466:. OUP Oxford. 452: 445: 425: 418: 399: 397: 394: 393: 392: 387: 382: 377: 372: 365: 362: 352: 349: 333:Main article: 330: 327: 319:Parkes process 275: 272: 244:pentanoic acid 201:weight percent 192: 189: 113:to mix in all 26: 9: 6: 4: 3: 2: 1075: 1064: 1061: 1060: 1058: 1043: 1040: 1038: 1035: 1033: 1030: 1028: 1025: 1023: 1020: 1018: 1015: 1013: 1010: 1008: 1005: 1003: 1000: 998: 995: 993: 990: 988: 985: 983: 980: 978: 975: 972: 968: 967: 965: 963: 959: 953: 950: 948: 945: 943: 940: 938: 935: 933: 930: 928: 925: 923: 920: 918: 915: 913: 910: 908: 905: 903: 900: 899: 897: 895: 891: 885: 882: 880: 877: 875: 872: 870: 869:Mass fraction 867: 865: 864:Mole fraction 862: 860: 857: 855: 852: 850: 847: 845: 842: 840: 837: 835: 832: 831: 829: 825: 824:Concentration 821: 815: 812: 810: 807: 805: 802: 800: 797: 795: 792: 790: 787: 785: 782: 780: 777: 775: 772: 770: 769:Phase diagram 767: 765: 762: 760: 757: 755: 752: 750: 749:Flory–Huggins 747: 745: 742: 740: 737: 735: 732: 730: 727: 726: 724: 722: 718: 714: 707: 702: 700: 695: 693: 688: 687: 684: 664: 662:9780824797973 658: 654: 653: 645: 637: 635:9783527638499 631: 627: 626: 618: 610: 608:9780854043620 604: 600: 599: 591: 583: 581:9780857099945 577: 573: 572: 564: 556: 554:9780080510637 550: 546: 545: 537: 529: 523: 519: 518: 510: 502: 500:9780471973973 496: 492: 491: 483: 475: 473:9780199655304 469: 465: 464: 456: 448: 446:9781483147123 442: 438: 437: 429: 421: 419:0-13-033832-X 415: 411: 404: 400: 391: 388: 386: 383: 381: 378: 376: 373: 371: 368: 367: 361: 359: 351:Determination 348: 346: 342: 336: 326: 324: 320: 316: 312: 308: 303: 301: 297: 293: 289: 285: 281: 271: 269: 265: 261: 257: 253: 249: 248:hexanoic acid 245: 241: 240:butanoic acid 237: 233: 229: 225: 221: 218: 214: 210: 206: 202: 198: 188: 186: 182: 178: 174: 173: 167: 165: 161: 157: 153: 149: 145: 141: 140: 135: 131: 128: 125:), forming a 124: 123:concentration 120: 116: 112: 106: 61: 54: 50: 46: 42: 37: 33: 19: 951: 932:Raoult's law 884:Ternary plot 879:Mixing ratio 673:Bibliography 651: 644: 624: 617: 597: 590: 570: 563: 543: 536: 516: 509: 489: 482: 462: 455: 439:. Elsevier. 435: 428: 409: 403: 354: 338: 304: 300:granular GMR 288:precipitates 277: 194: 170: 168: 137: 59: 58: 1037:Lyonium ion 952:Miscibility 937:Henry's law 309:and liquid 302:materials. 278:Immiscible 252:fatty acids 205:hydrocarbon 127:homogeneous 115:proportions 60:Miscibility 45:Diesel fuel 1032:Amphiphile 1027:Lipophilic 1022:Hydrophile 1017:Hydrophobe 894:Solubility 789:Saturation 759:Suspension 396:References 343:has lower 254:and other 172:immiscible 111:substances 36:Solubility 30:See also: 1042:Lyate ion 997:Solvation 912:Solvation 854:Normality 264:aldehydes 228:1-Octanol 224:1-butanol 1057:Category 1012:Polarity 971:Category 859:Molality 721:Solution 370:Emulsion 364:See also 341:polymers 262:such as 215:has two 209:alcohols 181:butanone 139:miscible 134:solution 119:dissolve 18:Miscible 962:Solvent 764:Colloid 754:Mixture 268:ketones 213:ethanol 164:ethanol 148:liquids 144:mixable 130:mixture 32:Mixture 659:  632:  605:  578:  551:  524:  497:  470:  443:  416:  311:silver 296:cobalt 292:copper 284:alloys 280:metals 274:Metals 256:lipids 238:up to 217:carbon 199:, the 185:phases 152:solids 784:Alloy 380:ITIES 220:atoms 160:water 156:gases 49:water 657:ISBN 630:ISBN 603:ISBN 576:ISBN 549:ISBN 522:ISBN 495:ISBN 468:ISBN 441:ISBN 414:ISBN 315:lead 307:zinc 294:and 266:and 162:and 154:and 34:and 203:of 195:In 177:oil 132:(a 1059:: 270:. 211:, 187:. 973:) 969:( 705:e 698:t 691:v 665:. 638:. 611:. 584:. 557:. 530:. 503:. 476:. 449:. 422:. 105:/ 102:i 99:t 96:ɪ 93:l 90:ɪ 87:b 84:ˈ 81:ɪ 78:s 75:ɪ 72:m 69:ˌ 66:/ 62:( 55:. 20:)

Index

Miscible
Mixture
Solubility

Diesel fuel
water
thin-film interference
/ˌmɪsɪˈbɪlɪti/
substances
proportions
dissolve
concentration
homogeneous
mixture
solution
miscible
mixable
liquids
solids
gases
water
ethanol
immiscible
oil
butanone
phases
organic compounds
weight percent
hydrocarbon
alcohols

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