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Maillard reaction

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is an entirely different process from Maillard browning, though the results of the two processes are sometimes similar to the naked eye (and taste buds). Caramelization may sometimes cause browning in the same foods in which the Maillard reaction occurs, but the two processes are distinct. They are
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In the cooking process, Maillard reactions can produce hundreds of different flavor compounds depending on the chemical constituents in the food, the temperature, the cooking time, and the presence of air. These compounds, in turn, often break down to form yet more flavor compounds.
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Stadler, Richard H.; Robert, Fabien; Riediker, Sonja; Varga, Natalia; Davidek, Tomas; Devaud, Stéphanie; Goldmann, Till; Hau, Jörg; Blank, Imre (August 2004). "In-Depth Mechanistic Study on the Formation of Acrylamide and Other Vinylogous Compounds by the Maillard Reaction".
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The browning reactions that occur when meat is roasted or seared are complex and occur mostly by Maillard browning with contributions from other chemical reactions, including the breakdown of the tetrapyrrole rings of the muscle protein
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or browning of skin tones and can turn hair to a red or ginger tone. The chemical mechanism is the same as in the browning of food, but it develops slowly over time due to the acidic action on the
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of the amino acid and forms a complex mixture of poorly characterized molecules responsible for a range of aromas and flavors. This process is accelerated in an alkaline environment (e.g.,
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steaks, fried dumplings, cookies and other kinds of biscuits, breads, toasted marshmallows, falafel and many other foods undergo this reaction. It is named after French chemist
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Harrison, T. J.; v, G. R. (2005). "An expeditious, high-yielding construction of the food aroma compounds 6-acetyl-1,2,3,4-tetrahydropyridine and 2-acetyl-1-pyrroline".
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is responsible for the biscuit or cracker-like flavor present in baked goods such as bread, popcorn, and tortilla products. The structurally related compound
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Tareke, E.; Rydberg, P.; Karlsson, Patrik; Eriksson, Sune; Törnqvist, Margareta (2002). "Analysis of acrylamide, a carcinogen formed in heated foodstuffs".
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have used the Maillard reaction over the years to make artificial flavors, the majority of patents being related to the production of meat-like flavors.
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bodies and was described by Painter in 1991 as the interaction of anaerobic, acidic, and cold (typically 4 °C (39 °F)) sphagnum acid on the
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In a dry environment, the Maillard reaction—the same chemical process that browns a steak—causes feces to develop a protective outer shell.
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Mottram, Donald S.; Wedzicha, Bronislaw L.; Dodson, Andrew T. (October 2002). "Acrylamide is formed in the Maillard reaction".
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has a similar smell and also occurs naturally without heating. The compound gives varieties of cooked rice and the herb
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published a paper describing the reaction between amino acids and sugars at elevated temperatures. In 1953, chemist
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products undergo further dehydration and deamination to produce dicarbonyls. This is a crucial intermediate.
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call for an oven temperature high enough to ensure that a Maillard reaction occurs. At higher temperatures,
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both promoted by heating, but the Maillard reaction involves amino acids, whereas caramelization is the
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Hodge, J. E. (1953). "Dehydrated Foods, Chemistry of Browning Reactions in Model Systems".
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which typically proceeds rapidly from around 140 to 165 °C (280 to 330 °F). Many
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Champagne: The Essential Guide to the Wines, Producers, and Terroirs of the Iconic Region
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The Maillard reaction is responsible for many colors and flavors in foods, such as the
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Virk-Baker, Mandeep K.; Nagy, Tim R.; Barnes, Stephen; Groopman, John (29 May 2014).
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of the sugar reacts with the amino group of the amino acid, producing N-substituted
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The preparation of French fries at high temperature can lead to the formation of
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can form. This can be discouraged by heating at a lower temperature, adding
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In archaeology, the Maillard process occurs when bodies are preserved in
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Dicarbonyls react with amines to produce Strecker aldehydes through
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Miranda, Gonzalo; Berna, Angel; Mulet, Antonio (4 February 2019).
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Nursten, Harry (2007). "The Chemistry of Nonenzymic Browning".
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Several ways are known for the ketosamines to react further:
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The Maillard reaction also contributes to the preservation of
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of various meats when seared or grilled, the browning and
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On Food and Cooking: The Science and Lore of the Kitchen
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Danehy, James P. (May 19, 1986). Chicester, C.O. (ed.).
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and other crisps, browning of malted barley as found in
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industry's recipes. At high temperatures, a probable
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The acidic peat environment causes a 1902: 1187:. Cancer.org. Retrieved on 2016-07-24. 1059: 864: 803: 697: 1347: 931: 837: 759: 713:International Journal of Food Science 435:The unstable glycosylamine undergoes 418: 219: 77: 1085: 1007: 1302:Nutritional Ecology of the Ruminant 648: 354:. Maillard reactions also occur in 306:6-Acetyl-2,3,4,5-tetrahydropyridine 228:6-Acetyl-2,3,4,5-tetrahydropyridine 13: 1293: 14: 1926: 1325: 867:"The Maillard Reaction Turns 100" 865:Everts, Sarah (October 1, 2012). 1884: 1883: 1464: 1331: 533: 519: 491: 477: 448:Produce two water molecules and 326:below 0.06 nanograms per liter. 144:applied to darken pretzels; see 41: 1239: 1190: 1178: 1142: 1109: 1086:Dove, Alan (11 February 2016). 1079: 1053: 1012:. Ten Speed Press. p. 66. 1001: 950: 889: 871:Chemical & Engineering News 707:Tamanna, N; Mahmood, N (2015). 624:Chichester, C. O., ed. (1986). 465:fission products can be formed. 188:, or injecting carbon dioxide. 797: 668: 642: 617: 555:Advanced glycation end-product 383: 214:U.S. Department of Agriculture 168:, and hence have an increased 1: 1033:Krystal, Becky (2020-01-31). 580: 133:of the sugar reacts with the 1299:Van Soest, Peter J. (1982). 1215:10.1080/01635581.2014.916323 682:. 2021-09-06. Archived from 260:, the golden-brown color of 110:. The reaction is a form of 7: 1126:10.1039/9781847552570-00005 1060:Cooper, Phil (2 May 2017). 570: 550:Akabori amino-acid reaction 526: 10: 1931: 883:10.1021/cen-09040-scitech2 649:Bui, Andrew (2017-09-29). 400:. It is typically seen on 199: 1881: 1800: 1759: 1698: 1635:Chorleywood bread process 1610: 1544: 1473: 1462: 1381: 1373: 813:Advances in Food Research 626:Advances in Food Research 461:, and other short-chain 148:), as the amino groups ( 319:Pandanus amaryllifolius 1088:"Hard-core sequencing" 932:McGee, Harold (2004). 346: 334: 237: 229: 206:Louis Camille Maillard 112:non-enzymatic browning 104:Louis Camille Maillard 32: 1118:The Maillard Reaction 819:. Academic Press: 107 437:Amadori rearrangement 340: 332: 235: 227: 22: 1340:at Wikimedia Commons 1203:Nutrition and Cancer 1008:Liem, Peter (2017). 976:10.3390/foods8020056 500:Strecker degradation 310:2-acetyl-1-pyrroline 296:toasted marshmallows 1260:2002Natur.419..448M 1040:The Washington Post 852:10.1021/jf60015a004 771:J. Agric. Food Chem 726:10.1155/2015/526762 508:, a possible human 373:of certain sugars. 362:ages in the bottle 23:The crusts of most 1491:Calcium propanoate 419:Chemical mechanism 347: 335: 238: 230: 220:Foods and products 33: 1897: 1896: 1813:Brand name breads 1650:Maillard reaction 1496:Dough conditioner 1338:Maillard reaction 1336:Media related to 1254:(6906): 448–449. 1164:10.1021/jf0495486 1158:(17): 5550–5558. 1135:978-0-85404-964-6 1120:. pp. 5–30. 943:978-0-684-80001-1 911:10.1021/jo051940a 783:10.1021/jf020302f 777:(17): 4998–5006. 236:2-Acetylpyrroline 194:Flavor scientists 108:protein synthesis 84:chemical reaction 37:Maillard reaction 1922: 1887: 1886: 1858:Sourdough breads 1848:Pakistani breads 1792:History of bread 1777:Baker percentage 1675:Sponge and dough 1468: 1368: 1361: 1354: 1345: 1344: 1335: 1288: 1287: 1243: 1237: 1236: 1226: 1194: 1188: 1182: 1176: 1175: 1146: 1140: 1139: 1113: 1107: 1106: 1101: 1099: 1083: 1077: 1076: 1074: 1072: 1066:Farm Consultancy 1057: 1051: 1050: 1048: 1047: 1030: 1024: 1023: 1005: 999: 998: 988: 978: 954: 948: 947: 929: 923: 922: 905:(26): 10872–74. 893: 887: 886: 862: 856: 855: 835: 829: 828: 826: 824: 810: 801: 795: 794: 766: 757: 756: 746: 728: 704: 695: 694: 692: 691: 672: 666: 665: 663: 661: 646: 640: 639: 621: 615: 614: 593: 575: 543: 538: 537: 523: 495: 481: 163: 158: 157: 154: 81: 76: 70: 64: 63: 60: 59: 56: 53: 50: 47: 1930: 1929: 1925: 1924: 1923: 1921: 1920: 1919: 1900: 1899: 1898: 1893: 1877: 1808:American breads 1796: 1787:Bread in Europe 1755: 1694: 1612: 1606: 1602:Weighing scales 1540: 1516:Leavening agent 1469: 1460: 1377: 1372: 1328: 1296: 1294:Further reading 1291: 1268:10.1038/419448a 1244: 1240: 1195: 1191: 1183: 1179: 1147: 1143: 1136: 1114: 1110: 1097: 1095: 1084: 1080: 1070: 1068: 1058: 1054: 1045: 1043: 1031: 1027: 1020: 1006: 1002: 955: 951: 944: 930: 926: 894: 890: 863: 859: 836: 832: 822: 820: 808: 802: 798: 767: 760: 705: 698: 689: 687: 680:Home Cook World 674: 673: 669: 659: 657: 647: 643: 636: 622: 618: 597:Maillard, L. C. 594: 587: 583: 578: 539: 532: 529: 484:The open-chain 421: 406:polysaccharides 386: 324:odor thresholds 300:roasted peanuts 254:coffee roasting 222: 202: 170:nucleophilicity 162: 155: 152: 151: 149: 92:reducing sugars 79:[majaʁ] 74: 68: 44: 40: 27:, such as this 17: 12: 11: 5: 1928: 1918: 1917: 1915:Name reactions 1912: 1910:Food chemistry 1895: 1894: 1882: 1879: 1878: 1876: 1875: 1870: 1865: 1860: 1855: 1850: 1845: 1840: 1835: 1830: 1828:British breads 1825: 1820: 1815: 1810: 1804: 1802: 1798: 1797: 1795: 1794: 1789: 1784: 1782:Bread and salt 1779: 1774: 1769: 1763: 1761: 1757: 1756: 1754: 1753: 1748: 1743: 1738: 1733: 1728: 1723: 1718: 1713: 1708: 1702: 1700: 1696: 1695: 1693: 1692: 1690:Vienna process 1687: 1685:Straight dough 1682: 1677: 1672: 1667: 1662: 1657: 1655:No-knead bread 1652: 1647: 1642: 1637: 1632: 1627: 1622: 1616: 1614: 1608: 1607: 1605: 1604: 1599: 1594: 1589: 1584: 1579: 1574: 1569: 1564: 1559: 1554: 1548: 1546: 1542: 1541: 1539: 1538: 1533: 1528: 1523: 1518: 1513: 1508: 1503: 1498: 1493: 1488: 1483: 1477: 1475: 1471: 1470: 1463: 1461: 1459: 1458: 1453: 1448: 1443: 1438: 1433: 1428: 1426:Sandwich bread 1423: 1418: 1413: 1408: 1403: 1398: 1393: 1387: 1385: 1379: 1378: 1371: 1370: 1363: 1356: 1348: 1342: 1341: 1327: 1326:External links 1324: 1323: 1322: 1295: 1292: 1290: 1289: 1238: 1209:(5): 774–790. 1189: 1177: 1141: 1134: 1108: 1078: 1052: 1025: 1019:978-1784724474 1018: 1000: 949: 942: 924: 888: 857: 846:(15): 928–43. 830: 796: 758: 696: 667: 641: 634: 616: 606:Comptes Rendus 584: 582: 579: 577: 576: 567: 565:Caramelization 562: 557: 552: 546: 545: 544: 528: 525: 475: 474: 473: 472: 466: 452: 443: 433: 426:carbonyl group 420: 417: 385: 382: 366:Caramelization 279:dulce de leche 274:condensed milk 221: 218: 201: 198: 160: 131:carbonyl group 120:caramelization 15: 9: 6: 4: 3: 2: 1927: 1916: 1913: 1911: 1908: 1907: 1905: 1892: 1891: 1880: 1874: 1871: 1869: 1866: 1864: 1861: 1859: 1856: 1854: 1851: 1849: 1846: 1844: 1843:Indian breads 1841: 1839: 1838:French breads 1836: 1834: 1831: 1829: 1826: 1824: 1821: 1819: 1816: 1814: 1811: 1809: 1806: 1805: 1803: 1801:List articles 1799: 1793: 1790: 1788: 1785: 1783: 1780: 1778: 1775: 1773: 1770: 1768: 1765: 1764: 1762: 1758: 1752: 1749: 1747: 1744: 1742: 1739: 1737: 1734: 1732: 1729: 1727: 1724: 1722: 1721:Bread pudding 1719: 1717: 1714: 1712: 1709: 1707: 1704: 1703: 1701: 1697: 1691: 1688: 1686: 1683: 1681: 1678: 1676: 1673: 1671: 1668: 1666: 1663: 1661: 1658: 1656: 1653: 1651: 1648: 1646: 1643: 1641: 1638: 1636: 1633: 1631: 1628: 1626: 1623: 1621: 1618: 1617: 1615: 1611:Processes and 1609: 1603: 1600: 1598: 1595: 1593: 1590: 1588: 1585: 1583: 1580: 1578: 1575: 1573: 1570: 1568: 1567:Dough scraper 1565: 1563: 1560: 1558: 1557:Bread machine 1555: 1553: 1550: 1549: 1547: 1543: 1537: 1534: 1532: 1529: 1527: 1524: 1522: 1519: 1517: 1514: 1512: 1509: 1507: 1504: 1502: 1499: 1497: 1494: 1492: 1489: 1487: 1484: 1482: 1481:Baker's yeast 1479: 1478: 1476: 1472: 1467: 1457: 1454: 1452: 1449: 1447: 1444: 1442: 1439: 1437: 1434: 1432: 1429: 1427: 1424: 1422: 1419: 1417: 1414: 1412: 1409: 1407: 1404: 1402: 1399: 1397: 1394: 1392: 1389: 1388: 1386: 1384: 1380: 1376: 1369: 1364: 1362: 1357: 1355: 1350: 1349: 1346: 1339: 1334: 1330: 1329: 1320: 1316: 1312: 1311:9780801427725 1308: 1304: 1303: 1298: 1297: 1285: 1281: 1277: 1273: 1269: 1265: 1261: 1257: 1253: 1249: 1242: 1234: 1230: 1225: 1220: 1216: 1212: 1208: 1204: 1200: 1193: 1186: 1181: 1173: 1169: 1165: 1161: 1157: 1153: 1145: 1137: 1131: 1127: 1123: 1119: 1112: 1105: 1093: 1089: 1082: 1067: 1063: 1056: 1042: 1041: 1036: 1029: 1021: 1015: 1011: 1004: 996: 992: 987: 982: 977: 972: 968: 964: 960: 953: 945: 939: 935: 928: 920: 916: 912: 908: 904: 901: 900: 899:J. Org. Chem. 892: 884: 880: 877:(40): 58–60. 876: 872: 868: 861: 853: 849: 845: 841: 834: 818: 814: 807: 800: 792: 788: 784: 780: 776: 772: 765: 763: 754: 750: 745: 740: 736: 732: 727: 722: 718: 714: 710: 703: 701: 686:on 2022-01-27 685: 681: 677: 671: 656: 655:Tasting Table 652: 645: 637: 635:0-12-016430-2 631: 627: 620: 612: 609:(in French). 608: 607: 602: 598: 592: 590: 585: 574: 573: 568: 566: 563: 561: 558: 556: 553: 551: 548: 547: 542: 536: 531: 524: 522: 517: 515: 511: 507: 503: 501: 496: 494: 489: 487: 482: 480: 471: 467: 464: 460: 459:pyruvaldehyde 456: 453: 451: 447: 446: 444: 442: 438: 434: 431: 430:glycosylamine 427: 423: 422: 416: 414: 409: 407: 403: 399: 395: 391: 381: 379: 374: 372: 367: 363: 361: 357: 353: 344: 339: 331: 327: 325: 321: 320: 315: 311: 307: 303: 301: 297: 293: 289: 285: 281: 280: 275: 271: 267: 263: 259: 255: 251: 247: 243: 234: 226: 217: 215: 211: 210:John E. Hodge 207: 197: 195: 189: 187: 183: 179: 175: 171: 167: 147: 143: 139: 136: 132: 129:The reactive 127: 125: 121: 117: 113: 109: 105: 101: 97: 93: 89: 85: 80: 72: 71: 62: 38: 30: 26: 21: 1888: 1873:Toast dishes 1868:Swiss breads 1863:Sweet breads 1853:Quick breads 1818:Bread dishes 1731:French toast 1716:Bread pakora 1706:Bread crumbs 1649: 1301: 1251: 1247: 1241: 1206: 1202: 1192: 1180: 1155: 1151: 1144: 1117: 1111: 1103: 1096:. Retrieved 1091: 1081: 1069:. Retrieved 1065: 1055: 1044:. Retrieved 1038: 1028: 1009: 1003: 966: 962: 952: 933: 927: 902: 897: 891: 874: 870: 860: 843: 839: 833: 821:. Retrieved 816: 812: 799: 774: 770: 716: 712: 688:. Retrieved 684:the original 679: 670: 658:. Retrieved 654: 644: 625: 619: 610: 604: 518: 504: 497: 490: 483: 476: 410: 387: 375: 364: 348: 317: 313: 304: 288:black garlic 277: 262:French fries 250:fried onions 239: 203: 190: 186:asparaginase 166:deprotonated 135:nucleophilic 128: 36: 34: 1823:Bread rolls 1772:Breadmaking 1670:Pre-slicing 1665:Pre-ferment 1587:Stand mixer 1572:Farinograph 1474:Ingredients 1456:Whole wheat 1451:White bread 1421:Salt-rising 1391:Brown bread 541:Food portal 470:melanoidins 441:ketosamines 384:Archaeology 356:dried fruit 258:baked goods 138:amino group 96:melanoidins 88:amino acids 1904:Categories 1746:Sandwiches 1711:Bread bowl 1613:techniques 1446:Unleavened 1431:Soda bread 1406:Multigrain 1185:Acrylamide 1046:2022-07-28 719:: 526762. 690:2022-01-27 660:6 November 581:References 514:asparagine 510:carcinogen 506:Acrylamide 463:hydrolytic 450:reductones 439:, forming 413:paleofeces 376:In making 343:acrylamide 182:acrylamide 178:carcinogen 94:to create 1645:Leavening 1620:Autolysis 1562:Bread pan 1545:Equipment 1436:Sourdough 1416:Rye bread 1401:Flatbread 969:(2): 56. 735:2314-5765 432:and water 390:peat bogs 371:pyrolysis 360:champagne 358:and when 352:myoglobin 292:chocolate 248:taste in 212:with the 204:In 1912, 174:flavoring 124:pyrolysis 1890:Category 1741:Stuffing 1726:Croutons 1680:Steaming 1660:Proofing 1640:Kneading 1441:Sprouted 1319:29909839 1276:12368844 1233:24875401 1172:15315399 1071:2 August 995:30720722 919:16356012 823:15 March 791:12166997 753:26904661 613:: 66–68. 599:(1912). 527:See also 455:Diacetyl 402:Iron Age 398:bog body 242:browning 146:lye roll 86:between 1597:Toaster 1284:4360610 1256:Bibcode 1224:4164905 1098:16 June 1092:Science 986:6406843 744:4745522 572:Wok hei 486:Amadori 394:tanning 200:History 180:called 116:recipes 82:) is a 75:French: 29:brioche 1767:Bakery 1625:Baking 1592:Warmer 1317:  1309:  1282:  1274:  1248:Nature 1231:  1221:  1170:  1132:  1016:  993:  983:  940:  917:  789:  751:  741:  733:  632:  560:Baking 378:silage 314:pandan 298:, and 284:toffee 164:) are 100:Seared 25:breads 1760:Other 1751:Toast 1736:Rusks 1536:Water 1531:Sugar 1511:Flour 1411:Quick 1383:Types 1375:Bread 1280:S2CID 963:Foods 809:(PDF) 270:dried 246:umami 159:→ RNH 1833:Buns 1699:Uses 1630:Biga 1582:Peel 1577:Lame 1552:Oven 1526:Salt 1521:Milk 1501:Eggs 1486:Barm 1315:OCLC 1307:ISBN 1272:PMID 1229:PMID 1168:PMID 1130:ISBN 1100:2021 1073:2022 1014:ISBN 991:PMID 938:ISBN 915:PMID 825:2024 787:PMID 749:PMID 731:ISSN 717:2015 662:2017 630:ISBN 424:The 272:and 266:malt 252:and 90:and 35:The 1506:Fat 1396:Bun 1264:doi 1252:419 1219:PMC 1211:doi 1160:doi 1122:doi 981:PMC 971:doi 907:doi 879:doi 848:doi 779:doi 739:PMC 721:doi 611:154 150:RNH 142:lye 69:YAR 67:my- 58:ɑːr 1906:: 1313:. 1278:. 1270:. 1262:. 1250:. 1227:. 1217:. 1207:66 1205:. 1201:. 1166:. 1156:52 1154:. 1128:. 1102:. 1090:. 1064:. 1037:. 989:. 979:. 965:. 961:. 913:. 903:70 875:90 873:. 869:. 842:. 817:30 815:. 811:. 785:. 775:50 773:. 761:^ 747:. 737:. 729:. 715:. 711:. 699:^ 678:. 653:. 588:^ 502:. 457:, 415:. 408:. 302:. 294:, 290:, 286:, 282:, 276:, 73:; 49:aɪ 1367:e 1360:t 1353:v 1321:. 1286:. 1266:: 1258:: 1235:. 1213:: 1174:. 1162:: 1138:. 1124:: 1075:. 1049:. 1022:. 997:. 973:: 967:8 946:. 921:. 909:: 885:. 881:: 854:. 850:: 844:1 827:. 793:. 781:: 755:. 723:: 693:. 664:. 638:. 345:. 316:( 161:2 156:3 153:+ 61:/ 55:j 52:ˈ 46:m 43:/ 39:(

Index


breads
brioche
/mˈjɑːr/
my-YAR
[majaʁ]
chemical reaction
amino acids
reducing sugars
melanoidins
Seared
Louis Camille Maillard
protein synthesis
non-enzymatic browning
recipes
caramelization
pyrolysis
carbonyl group
nucleophilic
amino group
lye
lye roll
deprotonated
nucleophilicity
flavoring
carcinogen
acrylamide
asparaginase
Flavor scientists
Louis Camille Maillard

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