3112:. The temperatures of these moons range from 90 to 160 K, warm enough that amorphous ice is expected to crystallize on relatively short timescales. However, it was found that Europa has primarily amorphous ice, Ganymede has both amorphous and crystalline ice, and Callisto is primarily crystalline. This is thought to be the result of competing forces: the thermal crystallization of amorphous ice versus the conversion of crystalline to amorphous ice by the flux of charged particles from Jupiter. Closer to Jupiter than the other three moons, Europa receives the highest level of radiation and thus through irradiation has the most amorphous ice. Callisto is the farthest from Jupiter, receiving the lowest radiation flux and therefore maintaining its crystalline ice. Ganymede, which lies between the two, exhibits amorphous ice at high latitudes and crystalline ice at the lower latitudes. This is thought to be the result of the moon's intrinsic magnetic field, which would funnel the charged particles to higher latitudes and protect the lower latitudes from irradiation. Ganymede's interior probably includes a liquid water ocean with tens to hundreds of kilometers of ice V at its base.
2210:. The low temperature required to achieve this transition is correlated with the relatively low energy difference between the two structures. Hints of hydrogen-ordering in ice had been observed as early as 1964, when Dengel et al. attributed a peak in thermo-stimulated depolarization (TSD) current to the existence of a proton-ordered ferroelectric phase. However, they could not conclusively prove that a phase transition had taken place, and Onsager pointed out that the peak could also arise from the movement of defects and lattice imperfections. Onsager suggested that experimentalists look for a dramatic change in heat capacity by performing a careful calorimetric experiment. A phase transition to ice XI was first identified experimentally in 1972 by Shuji Kawada and others.
2268:, meaning that it has an intrinsic polarization. To qualify as a ferroelectric it must also exhibit polarization switching under an electric field, which has not been conclusively demonstrated but which is implicitly assumed to be possible. Cubic ice also has a ferrolectric phase and in this case the ferroelectric properties of the ice have been experimentally demonstrated on monolayer thin films. In a similar experiment, ferroelectric layers of hexagonal ice were grown on a platinum (111) surface. The material had a polarization that had a decay length of 30 monolayers suggesting that thin layers of ice XI can be grown on substrates at low temperature without the use of dopants. One-dimensional nano-confined ferroelectric ice XI was created in 2010.
314:
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prepared by the protocol reported previously contains both ice XV and ice beta-XV domains; (ii) upon heating, Raman spectra of ice beta-XV showed loss of H-order. In contrast, Salzmann's group again argued for the plausibility of a 'deep-glassy state' scenario based on neutron diffraction and neutron inelastic scattering experiments. Based on their experimental results, ice VI and deep-glassy ice VI share very similar features based on both elastic (diffraction) scattering and inelastic scattering experiments, and are different from the properties of ice XV.
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Centaur, and
Jupiter Family comets at heliocentric distances beyond ~6 AU. These objects are too cold for the sublimation of water ice, which drives comet activity closer to the Sun, to have much of an effect. Thermodynamic models show that the surface temperatures of those comets are near the amorphous/crystalline ice transition temperature of ~130 K, supporting this as a likely source of the activity. The runaway crystallization of amorphous ice can produce the energy needed to power outbursts such as those observed for Centaur Comet
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6314:
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2615:. The temperature in the diamond cells rose thousands of degrees, and the pressure increased to over a million times that of Earth's atmosphere. The experiment concluded that the current in the conductive water was indeed carried by ions rather than electrons and thus pointed to the water being superionic. More recent experiments from the same LLNL team used x-ray crystallography on laser-shocked water droplets to determine that the oxygen ions enter a face-centered-cubic phase, which was dubbed ice XVIII and reported in the journal
2900:, and so it may form on Earth. However, the transformation is very slow. According to one report, in Antarctic conditions it is estimated to take at least 100,000 years to form without the assistance of catalysts. Ice XI was sought and found in Antarctic ice that was about 100 years old in 1998. A further study in 2004 was not able to reproduce this finding, however, after studying Antarctic ice which was around 3000 years old. The 1998 Antarctic study also claimed that the transformation temperature (ice XI => ice I
2413:(or clathrates), they lack the cagelike structure generally found in clathrate hydrates, and are more properly referred to as filled ices. The filled ice is then placed in a vacuum, and the temperature gradually increased until the hydrogen frees itself from the crystal structure. If kept at a temperature range between 110 and 120 K (−163 and −153 °C; −262 and −244 °F), after about two hours, the structure will have emptied itself of any detectable hydrogen molecules. The resulting form is
2157:
hydrogen-ordering, orientational glass transition, and mechanical distortions. reported the DSC thermograms of HCl-doped ice IV finding an endothermic feature at about 120 K. Ten years later, Rosu-Finsen and
Salzmann (2021) reported more detailed DSC data where the endothermic feature becomes larger as the sample is quench-recovered at higher pressure. They proposed three scenarios to explain the experimental results: weak hydrogen-ordering, orientational glass transition, and mechanical distortions.
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2085:
below −70 °C without it changing into ice II. Conversely, however, any superheating of ice II was not possible in regards to retaining the same form. Bridgman found that the equilibrium curve between ice II and ice IV was much the same as with ice III, having the same stability properties and small volume change. The curve between ice II and ice V was extremely different, however, with the curve's bubble being essentially a straight line and the volume difference being almost always
2179:
2170:
ice VII has the largest stability field of all of the molecular phases of ice. The cubic oxygen sub-lattices that form the backbone of the ice VII structure persist to pressures of at least 128 GPa; this pressure is substantially higher than that at which water loses its molecular character entirely, forming ice X. In high pressure ices, protonic diffusion (movement of protons around the oxygen lattice) dominates molecular diffusion, an effect which has been measured directly.
405:
78:
2047:
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12416:
469:
1049:
3124:" cracks on the surface and more amorphous ice between these regions. The crystalline ice near the tiger stripes could be explained by higher temperatures caused by geological activity that is the suspected cause of the cracks. The amorphous ice might be explained by flash freezing from cryovolcanism, rapid condensation of molecules from water geysers, or irradiation of high-energy particles from Saturn. Similarly, one of the inner layers of
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155:
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2904:) is −36 °C (237 K), which is far higher than the temperature of the expected triple point mentioned above (72 K, ~0 Pa). Ice XI was also found in experiments using pure water at very low temperature (~10 K) and low pressure – conditions thought to be present in the upper atmosphere. Recently, small domains of ice XI were found to form in pure water; its phase transition back to ice I
3190:. The possible roles of ice XI in interstellar space and planet formation have been the subject of several research papers. Until observational confirmation of ice XI in outer space is made, the presence of ice XI in space remains controversial owing to the aforementioned criticism raised by Iitaka. The infrared absorption spectra of ice XI was studied in 2009 in preparation for searches for ice XI in space.
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36:
167:
2854:, a rare ring that occurs near 28 degrees from the Sun or the Moon. However, many atmospheric samples which were previously described as cubic ice were later shown to be stacking disordered ice with trigonal symmetry, and it has been dubbed the ″most faceted ice phase in a literal and a more general sense.″ The first true samples of cubic ice were only reported in 2020.
214:
the large hexagonal rings leave almost enough room for another water molecule to exist inside. This gives naturally occurring ice its rare property of being less dense than its liquid form. The tetrahedral-angled hydrogen-bonded hexagonal rings are also the mechanism that causes liquid water to be densest at 4 °C. Close to 0 °C, tiny hexagonal ice I
3012:
low temperatures where other indicators (such as the 3.1 and 12 μm bands) fail. This is useful studying ice in the interstellar medium and circumstellar disks. However, observing these features is difficult because the atmosphere is opaque at these wavelengths, requiring the use of space-based infrared observatories.
2963:). The latter process can occur within ice XVII. In physisorption, there is no chemical reaction, and the chemical bond between the two atoms within a hydrogen molecule remains intact. Because of this, the number of adsorption–desorption cycles ice XVII can withstand is "theoretically infinite".
2664:
Distinguishing between the two scenarios (new hydrogen-ordered phase vs. deep-glassy disordered ice VI) became an open question and the debate between the two groups has continued. Thoeny et al. (Loerting's group) collected another series of Raman spectra of ice beta-XV, and reported that (i) ice XV
2121:
1981 research by
Engelhardt and Kamb elucidated crystal structure of ice IV through a low-temperature single-crystal X-ray diffraction, describing it as a rhombohedral unit cell with a space group of R-3c. This research mentioned that the structure of ice IV could be derived from the structure of ice
3131:
Medium-density amorphous ice may be present on Europa, as the experimental conditions of its formation are expected to occur there as well. It is possible that the MDA ice's unique property of releasing a large amount of heat energy after being released from compression could be responsible for 'ice
3065:
For the primordial solar nebula, there is much uncertainty as to the crystallinity of water ice during the circumstellar disk and planet formation phases. If the original amorphous ice survived the molecular cloud collapse, then it should have been preserved at heliocentric distances beyond Saturn's
3025:
exist. These low temperatures are readily achieved in astrophysical environments such as molecular clouds, circumstellar disks, and the surfaces of objects in the outer Solar System. In the laboratory, amorphous ice transforms into crystalline ice if it is heated above 130 K, although the exact
2084:
between the two. The curve showed that the structural change from ice III to ice II was more likely to happen if the medium had previously been in the structural conformation of ice II. However, if a sample of ice III that had never been in the ice II state was obtained, it could be supercooled even
2063:
in 1900 during his experiments with ice under high pressure and low temperatures. Having produced ice III, Tammann then tried condensing the ice at a temperature between −70 and −80 °C (203 and 193 K; −94 and −112 °F) under 200 MPa (2,000 atm) of pressure. Tammann noted that
436:
in the crystal lattice. The latent heat of melting is much smaller, partly because liquid water near 0 °C also contains a significant number of hydrogen bonds. By contrast, the structure of ice II is hydrogen-ordered, which helps to explain the entropy change of 3.22 J/mol when the crystal
213:
This tetrahedral bonding angle of the water molecule essentially accounts for the unusually low density of the crystal lattice – it is beneficial for the lattice to be arranged with tetrahedral angles even though there is an energy penalty in the increased volume of the crystal lattice. As a result,
3179:
Small domains of ice XI could exist in the atmospheres of
Jupiter and Saturn as well. The fact that small domains of ice XI can exist at temperatures up to 111 K has some scientists speculating that it may be fairly common in interstellar space, with small 'nucleation seeds' spreading through
3087:
With radiation equilibrium temperatures of 40–50 K, the objects in the Kuiper Belt are expected to have amorphous water ice. While water ice has been observed on several objects, the extreme faintness of these objects makes it difficult to determine the structure of the ices. The signatures of
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powder neutron diffraction experiments of ice XIX. In a change from their previous reports, they accepted the idea of the new phase (ice XIX) as they observed similar features to the previous two reports. However, they refined their diffraction profiles based on a disordered structural model (Pbcn)
2732:
Gasser et al. also collected powder neutron diffractograms of quench-recovered ices VI, XV, and XIX and found similar crystallographic features to those reported by Yamane et al., concluding that P-4 and Pcc2 are the plausible space group candidates. Both Yamane et al.'s and Gasser et al.'s results
2169:
theoretically transforms into proton-ordered ice XI on geologic timescales, in practice it is necessary to add small amounts of KOH catalyst.) It forms (ordered) ice VIII below 273 K up to ~8 GPa. Above this pressure, the VII–VIII transition temperature drops rapidly, reaching 0 K at ~60 GPa. Thus,
2156:
The ordered counterpart of ice IV has never been reported yet. 2011 research by
Salzmann's group reported more detailed DSC data where the endothermic feature becomes larger as the sample is quench-recovered at higher pressure. They proposed three scenarios to explain the experimental results: weak
2138:
Several organic nucleating reagents had been proposed to selectively crystallize ice IV from liquid water, but even with such reagents, the crystallization of ice IV from liquid water was very difficult and seemed to be a random event. In 2001, Salzmann and his coworkers reported a whole new method
562:
of water molecules in an ice lattice. To compute its residual entropy, we need to count the number of configurations that the lattice can assume. The oxygen atoms are fixed at the lattice points, but the hydrogen atoms are located on the lattice edges. The problem is to pick one end of each lattice
3011:
At longer IR wavelengths, amorphous and crystalline ice have characteristically different absorption bands at 44 and 62 μm in that the crystalline ice has significant absorption at 62 μm while amorphous ice does not. In addition, these bands can be used as a temperature indicator at very
3074:
The possibility of the presence of amorphous water ice in comets and the release of energy during the phase transition to a crystalline state was first proposed as a mechanism for comet outbursts. Evidence of amorphous ice in comets is found in the high levels of activity observed in long-period,
3061:
isn't expected to rise above 120 K, indicating that the majority of the ice should remain in an amorphous state. However, if the temperature rises high enough to sublimate the ice, then it can re-condense into a crystalline form since the water flux rate is so low. This is expected to be the
3044:
and David F. Blake demonstrated in 1994 that a form of high-density amorphous ice is also created during vapor deposition of water on low-temperature (< 30 K) surfaces such as interstellar grains. The water molecules do not fully align to create the open cage structure of low-density
2130:
F II, whose hydrogen-bonded network is similar to ice IV. As the compression of ice Ih results in the formation of high-density amorphous ice (HDA), not ice IV, they claimed that the compression-induced conversion of ice I into ice IV is important, naming it "Engelhardt–Kamb collapse" (EKC). They
2830:
floats on water, which is highly unusual when compared to other materials. The solid phase of materials is usually more closely and neatly packed and has a higher density than the liquid phase. When lakes freeze, they do so only at the surface, while the bottom of the lake remains near 4 °C
2647:
In 2019, Alexander Rosu-Finsen and
Christoph Salzman argued that there was no need to consider this to be a new phase of ice, and proposed a "deep-glassy" state scenario. According to their DSC data, the size of the endothermic feature depends not only on quench-recovery pressure but also on the
955:
The same answer can be found in another way. First orient each water molecule randomly in each of the 6 possible configurations, then check that each lattice edge contains exactly one hydrogen atom. Assuming that the lattice edges are independent, then the probability that a single edge contains
489:
inherent to the lattice and determined by the number of possible configurations of hydrogen positions that can be formed while still maintaining the requirement for each oxygen atom to have only two hydrogens in closest proximity, and each H-bond joining two oxygen atoms having only one hydrogen
3029:
An additional factor in determining the structure of water ice is deposition rate. Even if it is cold enough to form amorphous ice, crystalline ice will form if the flux of water vapor onto the substrate is less than a temperature-dependent critical flux. This effect is important to consider in
2332:
Based on powder neutron diffraction, the crystal structure of ice XV has been investigated in detail. Some researchers suggested that, in combination with density functional theory calculations, none of the possible perfectly ordered orientational configurations are energetically favoured. This
2079:
In later experiments by
Bridgman in 1912, it was shown that the difference in volume between ice II and ice III was in the range of 0.0001 m/kg (2.8 cu in/lb). This difference hadn't been discovered by Tammann due to the small change and was why he had been unable to determine an
1056:
This estimate is 'naive', as it assumes the six out of 16 hydrogen configurations for oxygen atoms in the second set can be independently chosen, which is false. More complex methods can be employed to better approximate the exact number of possible configurations, and achieve results closer to
484:
atoms in the crystal lattice lie very nearly along the hydrogen bonds, and in such a way that each water molecule is preserved. This means that each oxygen atom in the lattice has two hydrogens adjacent to it: at about 101 pm along the 275 pm length of the bond for ice Ih. The crystal
3037:
At temperatures less than 77 K, irradiation from ultraviolet photons as well as high-energy electrons and ions can damage the structure of crystalline ice, transforming it into amorphous ice. Amorphous ice does not appear to be significantly affected by radiation at temperatures less than
2927:
and release hydrogen molecules without degrading its structure. The total amount of hydrogen that ice XVII can adsorb depends on the amount of pressure applied, but hydrogen molecules can be adsorbed by ice XVII even at pressures as low as a few millibars if the temperature is under
2555:, and from optical measurements of water shocked by extremely powerful lasers. The first definitive evidence for the crystal structure of the oxygen lattice in superionic water came from x-ray measurements on laser-shocked water which were reported in 2019. In 2005 Laurence Fried led a team at
2377:
In 2016, the discovery of a new form of ice was announced. Characterized as a "porous water ice metastable at atmospheric temperatures", this new form was discovered by taking a filled ice and removing the non-water components, leaving the crystal structure behind, similar to how ice XVI,
3140:
Because ice XI can theoretically form at low pressures at temperatures between 50–70 K – temperatures present in astrophysical environments of the outer solar system and within permanently shaded polar craters on the Moon and
Mercury. Ice XI forms most easily around 70 K –
2865:
of water vapor in cold or vacuum conditions. Ice clouds form at and below the Earth's high latitude mesopause (~90 km) where temperatures have been observed to fall as to below 100 K. It has been suggested that homogeneous nucleation of ice particles results in low density amorphous ice.
119:
phase. Less common phases may be found in the atmosphere and underground due to more extreme pressures and temperatures. Some phases are manufactured by humans for nano scale uses due to their properties. In space, amorphous ice is the most common form as confirmed by observation. Thus, it is
2643:
patterns. In the DSC signals, there was an endothermic feature at about 110 K in addition to the endotherm corresponding to the ice XV-VI transition. Additionally, the Raman spectra, dielectric properties, and the ratio of the lattice parameters differed from those of ice XV. Based on these
2668:
In 2021, further crystallographic evidence for a new phase (ice XIX) was individually reported by three groups: Yamane et al. (Hiroyuki Kagi and Kazuki
Komatsu's group from Japan), Gasser et al. (Loerting's group), and Salzmann's group. Yamane et al. collected neutron diffraction profiles
2221:
bonds. Such arrangements should change to the more ordered arrangement of hydrogen bonds found in ice XI at low temperatures, so long as localized proton hopping is sufficiently enabled; a process that becomes easier with increasing pressure. Correspondingly, ice XI is believed to have a
3020:
In general, amorphous ice can form below ~130 K. At this temperature, water molecules are unable to form the crystalline structure commonly found on Earth. Amorphous ice may also form in the coldest region of the Earth's atmosphere, the summer polar mesosphere, where
1161:
configurations. However, by explicit enumeration, there are actually 730 configurations. Now in the lattice, each oxygen atom participates in 12 hexagonal rings, so there are 2N rings in total for N oxygen atoms, or 2 rings for each oxygen atom, giving a refined result of
137:
0 °C. Subjected to higher pressures and varying temperatures, ice can form in nineteen separate known crystalline phases. With care, at least fifteen of these phases (one of the known exceptions being ice X) can be recovered at ambient pressure and low temperature in
3141:
paradoxically, it takes longer to form at lower temperatures. Extrapolating from experimental measurements, it is estimated to take ~50 years to form at 70 K and ~300 million years at 50 K. It is theorized to be present in places like the upper atmospheres of
2656:
O ice VI/XV prepared at different pressures of 1.0, 1.4 and 1.8 GPa, to show that there were no significant differences among them. They concluded that the low-temperature endotherm originated from kinetic features related to glass transitions of deep glassy states of
2112:
F resulted in the disappearance of ice II instead of the formation of a disordered ice II. According to the DFC calculation by
Nakamura et al., the phase boundary between ice II and its disordered counterpart is estimated to be in the stability region of liquid water.
2134:
The disordered nature of Ice IV was confirmed by neutron powder diffraction studies by Lobban (1998) and Klotz et al. (2003). In addition, the entropy difference between ice VI (disordered phase) and ice IV is very small, according to Bridgman's measurement.
2324:
more ordered ice XV is obtained at ambient pressure. Being consistent with this, the ice VI-XV transition is reversible at ambient pressure. It was also shown that HCl-doping is selectively effective in producing ice XV while other acids and bases (HF, LiOH,
3056:
have extremely low temperatures (~10 K), falling well within the amorphous ice regime. The presence of amorphous ice in molecular clouds has been observationally confirmed. When molecular clouds collapse to form stars, the temperature of the resulting
2304:
On 14 June 2009, Christoph Salzmann and colleagues at the University of Oxford reported having experimentally reported an ordered phase of ice VI, named ice XV, and say that its properties differ significantly from those predicted. In particular, ice XV is
10635:
Omont, Alain; Forveille, Thierry; Moseley, S. Harvey; Glaccum, William J.; Harvey, Paul M.; Likkel, Lauren Jones; Loewenstein, Robert F.; Lisse, Casey M. (May 20, 1990), "Observations of 40–70 micron bands of ice in IRAS 09371 + 1212 and other stars",
2131:
suggested that the reason why we cannot obtain ice IV directly from ice Ih is that ice Ih is hydrogen-disordered; if oxygen atoms are arranged in the ice IV structure, hydrogen bonding may not be formed due to the donor-acceptor mismatch. and Raman
2757:
and argued that new Bragg reflections can be explained by distortions of ice VI, so ice XIX may still be regarded as a deep-glassy state of ice VI. The crystal structure of ice XIX including hydrogen order/disorder is still under debate as of 2022.
8395:
Salzmann, Christoph G.; Slater, Ben; Radaelli, Paolo G.; Finney, John L.; Shephard, Jacob J.; Rosillo-Lopez, Martin; Hindley, James (2016-11-22). "Detailed crystallographic analysis of the ice VI to ice XV hydrogen ordering phase transition".
3007:
water absorption lines are dependent on the ice temperature and crystal order. The peak strength of the 1.65 μm band as well as the structure of the 3.1 μm band are particularly useful in identifying the crystallinity of water ice.
2147:
is heated at a rate of 0.4 K/min and a pressure of 0.81 GPa, ice IV is crystallized at about 165 K. What governs the crystallization products is the heating rate; fast heating (over 10 K/min) results in the formation of single-phase ice XII.
2580:
lattice structure that would emerge at higher pressures. Additional experimental evidence was found by Marius Millot and colleagues in 2018 by inducing high pressure on water between diamonds and then shocking the water using a laser pulse.
476:, the oxygen atoms are arranged on the lattice points, and the hydrogen atoms are on the bonds between lattice points. Each oxygen atom has 4 neighboring ones. Note that the lattice bipartites into two subsets, here colored black and white.
285:
temperature, 77 K, in a vacuum. Cooling rates above 10 K/s are required to prevent crystallization of the droplets. At liquid nitrogen temperature, 77 K, HGW is kinetically stable and can be stored for many years.
950:
3217:
superionic phase to be kinetically favoured, but stable over a small window of parameters. On the other hand, there are also studies that suggest that other elements present inside the interiors of these planets, particularly
132:
temperatures because the pressure helps to hold the molecules together. However, the strong hydrogen bonds in water make it different: for some pressures higher than 1 atm (0.10 MPa), water freezes at a temperature
2966:
One significant advantage of using ice XVII as a hydrogen storage medium is the low cost of the only two chemicals involved: hydrogen and water. In addition, ice XVII has shown the ability to store hydrogen at an
11426:"Newly Discovered Form of Water Ice Is 'Really Strange' – Long theorized to be found in the mantles of Uranus and Neptune, the confirmation of the existence of superionic ice could lead to the development of new materials"
2276:
Although the parent phase ice VI was discovered in 1935, corresponding proton-ordered forms (ice XV) had not been observed until 2009. Theoretically, the proton ordering in ice VI was predicted several times; for example,
2234:, on raising the temperature, retains some hydrogen-ordered domains and more easily transforms back to ice XI again. A neutron powder diffraction study found that small hydrogen-ordered domains can exist up to 111 K.
2983:
clathrate hydrates, another potential storage medium. However, if ice XVII is used as a storage medium, it must be kept under a temperature of 130 K (−143 °C; −226 °F) or risk being destabilized.
5416:
Salzmann, Christoph G.; Rosu-Finsen, Alexander; Sharif, Zainab; Radaelli, Paolo G.; Finney, John L. (1 April 2021). "Detailed crystallographic analysis of the ice V to ice XIII hydrogen-ordering phase transition".
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astrophysical environments where the water flux can be low. Conversely, amorphous ice can be formed at temperatures higher than expected if the water flux is high, such as flash-freezing events associated with
2599:
In 2018, the existence of superionic ice was confirmed in a laboratory setting. To create the required pressure, LLNL researchers compressed small amounts of water between pieces of diamond. At 2,500
447:
When medium-density amorphous ice is compressed, released and then heated, it releases a large amount of heat energy, unlike other water ices which return to their normal form after getting similar treatment.
218:-like lattices form in liquid water, with greater frequency closer to 0 °C. This effect decreases the density of the water, causing it to be densest at 4 °C when the structures form infrequently.
202:. The planes alternate in an ABAB pattern, with B planes being reflections of the A planes along the same axes as the planes themselves. The distance between oxygen atoms along each bond is about 275
3119:
was mapped by the Visual and Infrared Mapping Spectrometer (VIMS) on the NASA/ESA/ASI Cassini space probe. The probe found both crystalline and amorphous ice, with a higher degree of crystallinity at the
2575:
which indicated that they had indeed created superionic water. In 2013 Hugh F. Wilson, Michael L. Wong, and Burkhard Militzer at the University of California, Berkeley published a paper predicting the
10689:
Meech, K. J.; Pittichová, J.; Bar-Nun, A.; Notesco, G.; Laufer, D.; Hainaut, O. R.; Lowry, S. C.; Yeomans, D. K.; Pitts, M. (2009). "Activity of comets at large heliocentric distances pre-perihelion".
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del Rosso, Leonardo; Celli, Milva; Grazzi, Francesco; Catti, Michele; Hansen, Thomas C.; Fortes, A. Dominic; Ulivi, Lorenzo (June 2020). "Cubic ice Ic without stacking defects obtained from ice XVII".
2725:
and determined phase boundaries of ices VI/XV/XIX. They found that the sign of the slope of the boundary turns negative from positive at 1.6 GPa indicating the existence of two different phases by the
1243:
112:
ices have been observed. In modern history, phases have been discovered through scientific research with various techniques including pressurization, force application, nucleation agents, and others.
108:
as a solid. Variations in pressure and temperature give rise to different phases, which have varying properties and molecular geometries. Currently, twenty one phases, including both crystalline and
2719:
8269:
Rosu-Finsen, Alexander; Salzmann, Christoph G. (2018-06-28). "Benchmarking acid and base dopants with respect to enabling the ice V to XIII and ice VI to XV hydrogen-ordering phase transitions".
2627:
The first report regarding ice XIX was published in 2018 by Thomas Loerting's group from Austria. They quenched HCl-doped ice VI to 77 K at different pressures between 1.0 and 1.8 GPa to collect
5494:
Drost-Hansen, W. (1969-11-14). "The Structure and Properties of Water. D. Eisenberg and W. Kauzmann. Oxford University Press, New York, 1969. xiv + 300 pp., illus. Cloth, $ 10; paper, $ 4.50".
485:
lattice allows a substantial amount of disorder in the positions of the hydrogen atoms frozen into the structure as it cools to absolute zero. As a result, the crystal structure contains some
1038:
2361:-1 and showed that experimental diffraction data should be analysed using space groups that permit full hydrogen order while the Pmmn model only accepts partially ordered structures. -->
1101:
As an illustrative example of refinement, consider the following way to refine the second estimation method given above. According to it, six water molecules in a hexagonal ring would allow
845:
741:
444:
The transition entropy from ice XIV to ice XII is estimated to be 60% of Pauling entropy based on DSC measurements. The formation of ice XIV from ice XII is more favoured at high pressure.
233:
bonding angles. This structure is stable down to −268 °C (5 K; −450 °F), as evidenced by x-ray diffraction and extremely high resolution thermal expansion measurements. Ice I
261:), or by compressing ordinary ice at low temperatures. The most common form on Earth, low-density ice, is usually formed in the laboratory by a slow accumulation of water vapor molecules (
2397:
O), using temperatures from 100 to 270 K (−173 to −3 °C; −280 to 26 °F) and pressures from 360 to 700 MPa (52,000 to 102,000 psi; 3,600 to 6,900 atm), and C
1159:
1096:
6079:
Salzmann, Christoph G.; Radaelli, Paolo G.; Hallbrucker, Andreas; Mayer, Erwin; Finney, John L. (24 March 2006). "The Preparation and Structures of Hydrogen Ordered Phases of Ice".
1804:
11019:
Spencer, John R.; Tamppari, Leslie K.; Martin, Terry Z.; Travis, Larry D. (1999). "Temperatures on Europa from Galileo Photopolarimeter-Radiometer: Nighttime Thermal Anomalies".
2831:(277 K; 39 °F) because water is densest at this temperature. This anomalous behavior of water and ice is what allows fish to survive harsh winters. The density of ice I
566:
The oxygen atoms can be divided into two sets in a checkerboard pattern, shown in the picture as black and white balls. Focus attention on the oxygen atoms in one set: there are
541:
2893:
due to the strength and rigidity of the diamond lattice, but cooled down to surface temperatures, producing the required environment of high pressure without high temperature.
2992:
In outer space, hexagonal crystalline ice (the predominant form found on Earth) is extremely rare. Known examples are typically associated with volcanic action. Water in the
618:
3890:
Wagner, Wolfgang; Saul, A.; Pruss, A. (May 1994). "International Equations for the Pressure Along the Melting and Along the Sublimation Curve of Ordinary Water Substance".
2316:
In detail, ice XV has a smaller density (larger unit-cell volume) than ice VI. This makes the VI-to-XV disorder-to-order transition much favoured at low pressures. Indeed,
1650:
The hydrogen atoms' positions are disordered. Exhibits Debye relaxation. The hydrogen bonds form two interpenetrating lattices. Tetragonal form (contested) known as Ice VII
2100:
As ice II is completely hydrogen ordered, the presence of its disordered counterpart is a great matter of interest. Shephard et al. investigated the phase boundaries of NH
6377:
Algara-Siller, G.; Lehtinen, O.; Wang, F. C.; Nair, R. R.; Kaiser, U.; Wu, H. A.; Geim, A. K.; Grigorieva, I. V. (2015-03-26). "Square ice in graphene nanocapillaries".
2241:
and XI, with ice XI showing much stronger peaks in the translational (~230 cm), librational (~630 cm) and in-phase asymmetric stretch (~3200 cm) regions.
1985:
A porous crystalline phase with helical channels. Formed by placing hydrogen-filled ice in a vacuum and increasing the temperature until the hydrogen molecules escape.
5250:; Salzmann, Christoph; Kohl, Ingrid; Mayer, Erwin; Hallbrucker, Andreas (2001). "A second distinct structural "state" of high-density amorphous ice at 77 K and 1 bar".
9795:
3026:
temperature of this conversion is dependent on the environment and ice growth conditions. The reaction is irreversible and exothermic, releasing 1.26–1.6 kJ/mol.
9764:
9265:
3045:
amorphous ice. Many water molecules end up at interstitial positions. When warmed above 30 K, the structure re-aligns and transforms into the low-density form.
646:
possible placements of the hydrogen atoms along their hydrogen bonds, of which 6 are allowed. So, naively, we would expect the total number of configurations to be
2320:
by Shephard and Salzmann revealed that reheating quench-recovered HCl-doped ice XV at ambient pressure even produces exotherms originating from transient ordering,
8560:
Komatsu, Kazuki; Machida, Shinichi; Noritake, Fumiya; Hattori, Takanori; Sano-Furukawa, Asami; Yamane, Ryo; Yamashita, Keishiro; Kagi, Hiroyuki (3 February 2020).
2721:
supercell of ice XV and proposed some leading candidates for the space group of ice XIX: P-4, Pca21, Pcc2, P21/a, and P21/c. They also measured dielectric spectra
9587:
Lübken, F.-J.; Lautenbach, J.; Höffner, J.; Rapp, M.; Zecha, M. (March 2009). "First continuous temperature measurements within polar mesosphere summer echoes".
10522:
7943:
Iedema, M. J.; Dresser, M. J.; Doering, D. L.; Rowland, J. B.; Hess, W. P.; Tsekouras, A. A.; Cowin, J. P. (1 November 1998). "Ferroelectricity in Water Ice".
57:
6244:
11065:
Hansen, Gary B.; McCord, Thomas B. (2004). "Amorphous and crystalline ice on the Galilean satellites: A balance between thermal and radiolytic processes".
8543:
7704:
Arakawa, Masashi; Kagi, Hiroyuki; Fukazawa, Hiroshi (2010). "Annealing effects on hydrogen ordering in KOD-doped ice observed using neutron diffraction".
3294:
Klotz, S.; Besson, J. M.; Hamel, G.; Nelmes, R. J.; Loveday, J. S.; Marshall, W. G. (1999). "Metastable ice VII at low temperature and ambient pressure".
862:
9817:
Fukazawa, Hiroshi; Mae, Shinji; Ikeda, Susumu; Watanabe, Okitsugu (1998). "Proton ordering in Antarctic ice observed by Raman and neutron scattering".
7314:
Pruzan, Ph.; Chervin, J. C. & Canny, B. (1993). "Stability domain of the ice VIII proton-ordered phase at very high pressure and low temperature".
2592:
structure. However, at pressures in excess of 100 GPa, and temperatures above 2000 K, it is predicted that the structure would shift to a more stable
2357:, are good indicators of the ice XV formation. Combining density functional theory calculations, they successfully constructed fully ordered model in
2006:
A form of water also known as superionic water or superionic ice in which oxygen ions develop a crystalline structure while hydrogen ions move freely.
2733:
suggested a partially hydrogen-ordered structure. Gasser et al. also found an isotope effect using DSC; the low-temperature endotherm for DCl-doped D
11327:
Iedema, M. J.; Dresser, M. J.; Doering, D. L.; Rowland, J. B.; Hess, W. P.; Tsekouras, A. A.; Cowin, J. P. (1998). "Ferroelectricity in Water Ice".
7573:
Tajima, Yoshimitsu; Matsuo, Takasuke; Suga, Hiroshi (1984). "Calorimetric study of phase transition in hexagonal ice doped with alkali hydroxides".
1913:
when above 145–147 K at positive pressures. Theoretical studies predict ice XVI to be thermodynamically stable at negative pressures (that is under
9250:
9179:
9108:
6790:
6221:
4140:
3517:
1799:
Metastable. Observed in the phase space of ice V and ice VI. A topological mix of seven- and eight-membered rings, a 4-connected net (4-coordinate
11772:
11475:
Cheng, Bingqing; Bethkenhagen, Mandy; Pickard, Chris J.; Hamel, Sebastien (2021). "Phase behaviours of superionic water at planetary conditions".
4220:
Rosu-Finsen, Alexander; Davies, Michael B.; Amon, Alfred; Wu, Han; Sella, Andrea; Michaelides, Angelos; Salzmann, Christoph G. (3 February 2023).
3566:
Velikov, V.; Borick, S; Angell, C. A. (2001). "Estimation of water-glass transition temperature based on hyperquenched glassy water experiments".
11206:
University of Liège (2007, May 16). Astronomers Detect Shadow Of Water World In Front Of Nearby Star. ScienceDaily. Retrieved Jan. 3, 2010, from
3062:
case in the circumstellar disk of IRAS 09371+1212, where signatures of crystallized ice were observed despite a low temperature of 30–70 K.
642:
oxygen atoms: in general they won't be satisfied (i.e., they will not have precisely two hydrogen atoms near them). For each of those, there are
8462:
Liu, Yuan; Huang, Yingying; Zhu, Chongqin; Li, Hui; Zhao, Jijun; Wang, Lu; Ojamäe, Lars; Francisco, Joseph S.; Zeng, Xiao Cheng (25 June 2019).
4283:
Bernal, J. D.; Fowler, R. H. (1 January 1933). "A Theory of Water and Ionic Solution, with Particular Reference to Hydrogen and Hydroxyl Ions".
2611:
to be blasted with a laser. For less than a billionth of a second, the ice was subjected to conditions similar to those within the mantle of an
9853:
9316:
Murray, Benjamin J.; Knopf, Daniel A.; Bertram, Allan K. (2005). "The formation of cubic ice under conditions relevant to Earth's atmosphere".
5161:
Mishima, O.; Calvert, L. D.; Whalley, E. (1985). "An apparently 1st-order transition between two amorphous phases of ice induced by pressure".
2281:
calculations predicted the phase transition temperature is 108 K and the most stable ordered structure is antiferroelectric in the space group
321:
Ice from a theorized superionic water may possess two crystalline structures. At pressures in excess of 50 GPa (7,300,000 psi) such
3100:
The Near-Infrared Mapping Spectrometer (NIMS) on NASA's Galileo spacecraft spectroscopically mapped the surface ice of the Jovian satellites
2528:
In 1988, predictions of the so-called superionic water state were made. In superionic water, water molecules break apart and the oxygen ions
2122:
Ic by cutting and forming some hydrogen bondings and adding subtle structural distortions. Shephard et al. compressed the ambient phase of NH
11212:
9698:
O. Tschauner; S Huang; E. Greenberg; V.B. Prakapenka; C. Ma; G.R. Rossman; A.H. Shen; D. Zhang; M. Newville; A. Lanzirotti; K. Tait (2018).
6589:
Millot, Marius; Coppari, Federica; Rygg, J. Ryan; Correa Barrios, Antonio; Hamel, Sebastien; Swift, Damian C.; Eggert, Jon H. (8 May 2019).
2866:
Amorphous ice is likely confined to the coldest parts of the clouds and stacking disordered ice I is thought to dominate elsewhere in these
2349:), whereas Rietveld refinement using the Pmmn space group only works well for poorly ordered samples. The lattice parameters, in particular
1421:
Experimental procedure generates shear force by crushing ice into powder with centimeter-wide stainless-steel balls added to its container.
7451:
2421:(ordinary ice) when brought above 130 K (−143 °C; −226 °F). The crystal structure is hexagonal in nature, and the pores are
9622:
Murray, Benjamin J.; Jensen, Eric J. (January 2010). "Homogeneous nucleation of amorphous solid water particles in the upper mesosphere".
8155:
Salzmann, Christoph G.; Radaelli, Paolo G.; Mayer, Erwin; Finney, John L. (2009). "Ice XV: A New Thermodynamically Stable Phase of Ice".
6269:
Falenty, A.; Hansen, T. C.; Kuhs, W. F. (2014). "Formation and properties of ice XVI obtained by emptying a type sII clathrate hydrate".
10321:
Moore, Marla H.; Hudson, Reggie L. (1992). "Far-infrared spectral studies of phase changes in water ice induced by proton irradiation".
206:
and is the same between any two bonded oxygen atoms in the lattice. The angle between bonds in the crystal lattice is very close to the
4406:
8216:
Shephard, Jacob J.; Salzmann, Christoph G. (2015). "The complex kinetics of the ice VI to ice XV hydrogen ordering phase transition".
5904:
La Placa, Sam J.; Hamilton, Walter C.; Kamb, Barclay; Prakash, Anand (1973-01-15). "On a nearly proton-ordered structure for ice IX".
3338:
44:
3038:
110 K, though some experiments suggest that radiation might lower the temperature at which amorphous ice begins to crystallize.
752:
333:
lattice. Some estimates suggest that at an extremely high pressure of around 1.55 TPa (225,000,000 psi), ice would develop
11261:
10281:
Hagen, W.; ielens, A.G.G.M.; Greenberg, J. M. (1981). "The Infrared Spectra of Amorphous Solid Water and Ice Between 10 and 140 K".
8676:
4441:
4000:
649:
277:(HGW) is formed by spraying a fine mist of water droplets into a liquid such as propane around 80 K, or by hyperquenching fine
237:
is also stable under applied pressures of up to about 210 megapascals (2,100 atm) where it transitions into ice III or ice II.
10582:
Jenniskens, P.; Blake, D. F.; Wilson, M. A.; Pohorille, A. (1995). "High-Density Amorphous Ice, the Frost on Interstellar Grains".
5831:
Whalley, E.; Davidson, D. W.; Heath, J. B. R. (1 December 1966). "Dielectric Properties of Ice VII. Ice VIII: A New Phase of Ice".
10114:
9483:
Malkin, Tamsin L.; Murray, Benjamin J.; Salzmann, Christoph G.; Molinero, Valeria; Pickering, Steven J.; Whale, Thomas F. (2015).
1593:
Most complicated structure of all the phases. Includes 4-membered, 5-membered, 6-membered, and 8-membered rings and a total of 28
210:
of 109.5°, which is also quite close to the angle between hydrogen atoms in the water molecule (in the gas phase), which is 105°.
8924:
5663:
Yao, Shu-Kai; Zhang, Peng; Zhang, Ying; Lu, Ying-Bo; Yang, Tian-Lin; Suna, Bai-Gong; Yuan, Zhen-Yu; Luo, Hui-Wen (21 June 2017).
5028:
4966:
Jenniskens P.; Banham S. F.; Blake D. F.; McCoustra M. R. (July 1997). "Liquid water in the domain of cubic crystalline ice Ic".
2882:
2537:
11238:
9414:
Murray, Benjamin J.; Salzmann, Christoph G.; Heymsfield, Andrew J.; Dobbie, Steven; Neely, Ryan R.; Cox, Christopher J. (2015).
7800:
Abe, K.; Shigenari, T. (2011). "Raman spectra of proton ordered phase XI of ICE I. Translational vibrations below 350 cm-1, J".
5108:
Jenniskens P.; Blake D. F.; Wilson M. A.; Pohorille A. (1995). "High-density amorphous ice, the frost on insterstellar grains".
4032:
Iglev, H.; Schmeisser, M.; Simeonidis, K.; Thaller, A.; Laubereau, A. (2006). "Ultrafast superheating and melting of bulk ice".
2556:
2064:
in this state ice II was denser than he had observed ice III to be. He also found that both types of ice can be kept at normal
2060:
1165:
11385:"Laboratory Measurements of Infrared Absorption Spectra of Hydrogen-Ordered Ice: a Step to the Exploration of Ice XI in Space"
8080:
Knight, Chris; Singer, Sherwin J. (2005-10-19). "Prediction of a Phase Transition to a Hydrogen Bond Ordered Form of Ice VI".
5062:
Mishima O.; Calvert L. D.; Whalley E. (1984). "'Melting ice' I at 77 K and 10 kbar: a new method of making amorphous solids".
2559:(LLNL) to recreate the formative conditions of superionic water. Using a technique involving smashing water molecules between
2337:
space group as a plausible space group to describe the time-space averaged structure of ice XV. Other researchers argued that
120:
theorized to be the most common phase in the universe. Various other phases could be found naturally in astronomical objects.
4424:
9787:
3758:
Conde, M.M.; Vega, C.; Tribello, G.A.; Slater, B. (2009). "The phase diagram of water at negative pressures: Virtual ices".
2850:
may occasionally present in the upper atmosphere clouds. It is believed to be responsible for the observation of Scheiner's
2835:
increases when cooled, down to about −211 °C (62 K; −348 °F); below that temperature, the ice expands again (
9756:
2684:
2584:
As of 2013, it is theorized that superionic ice can possess two crystalline structures. At pressures in excess of 50
11796:
11786:
11631:
10440:
Murray, B. J.; Jensen, E. J. (2010). "Homogeneous nucleation of amorphous solid water particles in the upper mesosphere".
9272:
7843:
Raza, Zamaan; Alfè, Dario (28 Nov 2011). "Proton ordering in cubic ice and hexagonal ice; a potential new ice phase—XIc".
5029:"Scientists Have Created a New Type of Ice – It looks like a white powder and has nearly the same density as liquid water"
2920:
of biomolecules. The individual molecules can be preserved for imaging in a state close to what they are in liquid water.
2333:
implies that there are several energetically close configurations that coexist in ice XV. They proposed 'the orthorhombic
329:
structure. However, at pressures in excess of 100 GPa (15,000,000 psi) the structure may shift to a more stable
10192:"Photometric and spectral analysis of the distribution of crystalline and amorphous ices on Enceladus as seen by Cassini"
9852:
Fortes, A. D.; Wood, I. G.; Grigoriev, D.; Alfredsson, M.; Kipfstuhl, S.; Knight, K. S.; Smith, R. I. (1 January 2004).
8951:"Origin of the low-temperature endotherm of acid-doped ice VI: new hydrogen-ordered phase of ice or deep glassy states?"
8788:
4378:(1 December 1935). "The Structure and Entropy of Ice and of Other Crystals with Some Randomness of Atomic Arrangement".
2461:. This discovery was reported around the same time another research group announced that they were able to obtain pure D
9300:
8755:
8021:
Zhao, H.-X.; Kong, X.-J.; Li, H.; Jin, Y.-C.; Long, L.-S.; Zeng, X. C.; Huang, R.-B.; Zheng, L.-S. (14 February 2011).
7746:
Arakawa, Masashi; Kagi, Hiroyuki; Fernandez-Baca, Jaime A.; Chakoumakos, Bryan C.; Fukazawa, Hiroshi (17 August 2011).
5869:
Whalley, E.; Heath, J. B. R.; Davidson, D. W. (1 March 1968). "Ice IX: An Antiferroelectric Phase Related to Ice III".
4085:"Author Correction: Dynamics enhanced by HCl doping triggers 60% Pauling entropy release at the ice XII-XIV transition"
2932:, through the application of heat. This was an unexpected property of ice XVII, and could allow it to be used for
959:
273:
it is expected to be formed in a similar manner on a variety of cold substrates, such as dust particles. By contrast,
11791:
11670:
11649:
10724:
Tancredi, G.; Rickman, H.; Greenberg, J. M. (1994). "Thermochemistry of cometary nuclei 1: The Jupiter family case".
10499:
5321:
2628:
2317:
298:
3410:
Rottger, K.; Endriss, A.; Ihringer, J.; Doyle, S.; Kuhs, W. F. (1994). "Lattice Constants and Thermal Expansion of H
142:
form. The types are differentiated by their crystalline structure, proton ordering, and density. There are also two
10493:
10491:
10489:
3978:
3259:
La Placa, S. J.; Hamilton, W. C.; Kamb, B.; Prakash, A. (1972). "On a nearly proton ordered structure for ice IX".
2677:
under high pressure) and found new Bragg features completely different from both ice VI and ice XV. They performed
2457:
O ice XVII powder. The result was free of structural deformities compared to standard cubic ice, or ice I
245:
While most forms of ice are crystalline, several amorphous (or "vitreous") forms of ice also exist. Such ice is an
11425:
8891:
2889:. The ice VII was presumably formed when water trapped inside the diamonds retained the high pressure of the deep
2648:
heating rate and annealing duration at 93 K. They also collected neutron diffraction profiles of quench-recovered
11739:
8522:
6236:
4535:
3810:
Militzer, Burkhard; Wilson, Hugh F. (2 November 2010). "New Phases of Water Ice Predicted at Megabar Pressures".
2726:
2603:(360,000 psi), the water became ice VII, a form that is solid at room temperature. This ice, trapped within
563:
edge for the hydrogen to bond to, in a way that still makes sure each oxygen atom is bond to two hydrogen atoms.
10486:
10358:"Molecular ices as temperature indicators for interstellar dust: the 44- and 62-μm lattice features of H2O ice"
4780:
Dowell, L. G.; Rinfret, A. P. (December 1960). "Low-Temperature Forms of Ice as Studied by X-Ray Diffraction".
2644:
observations, they proposed the existence of a second hydrogen-ordered phase of ice VI, naming it ice beta-XV.
2536:
float around freely within the oxygen lattice. The freely mobile hydrogen ions make superionic water almost as
1104:
956:
exactly one hydrogen atom is 1/2, and since there are 2N edges in total, we obtain a total configuration count
746:
10242:
Grundy, W. M.; Schmitt, B. (1998). "The temperature-dependent near-infrared absorption spectrum of hexagonal H
1060:
249:
form of water, which lacks long-range order in its molecular arrangement. Amorphous ice is produced either by
11823:
1257:
nomenclature. The majority have only been created in the laboratory at different temperatures and pressures.
573:
of them. Each has four hydrogen bonds, with two hydrogens close to it and two far away. This means there are
8869:
551:
There are various ways of approximating this number from first principles. The following is the one used by
11756:
11689:
9469:
8330:
Komatsu, K.; Noritake, F.; Machida, S.; Sano-Furukawa, A.; Hattori, T.; Yamane, R.; Kagi, H. (2016-07-04).
7978:
Su, Xingcai; Lianos, L.; Shen, Y.; Somorjai, Gabor (1998). "Surface-Induced Ferroelectric Ice on Pt(111)".
6568:
6329:"Thermodynamic Stability and Growth of Guest-Free Clathrate Hydrates: A Low-Density Crystal Phase of Water"
6152:
6053:
5971:
5649:
5538:
5480:
5402:
5379:
5356:
3076:
2081:
461:
289:
Amorphous ices have the property of suppressing long-range density fluctuations and are, therefore, nearly
254:
187:
9889:
7608:
Matsuo, Takasuke; Tajima, Yoshimitsu; Suga, Hiroshi (1986). "Calorimetric study of a phase transition in D
6441:
11109:
10791:
6804:
Shephard, J. J., Slater, B., Harvey, P., Hart, M., Bull, C. L., Bramwell, S. T., Salzmann, C. G. (2018),
1840:<118 K (−155 °C) (formation from ice XII); <140 K (−133 °C) (stability point)
502:
11762:
1996:<118 K (−155 °C) (formation from ice III);<140 K (−133 °C) (stability point)
10500:"Conditions for condensation and preservation of amorphous ice and crystallinity of astrophysical ices"
10012:
10011:
Dubochet, J.; Adrian, M.; Chang, J. .J; Homo, J. C.; Lepault, J-; McDowall, A. W.; Schultz, P. (1988).
9415:
8464:"An ultralow-density porous ice with the largest internal cavity identified in the water phase diagram"
7790:, in Physics and Chemistry of Ice, ed. W. Kuhs (Royal Society of Chemistry, Cambridge, 2007) pp 101–108
3000:
2996:
is instead dominated by amorphous ice, making it likely the most common form of water in the universe.
2836:
2548:, which is a hypothetical liquid state characterized by a disordered soup of hydrogen and oxygen ions.
2144:
294:
257:(about 136 K or −137 °C) in milliseconds (so the molecules do not have enough time to form a
11286:
Fukazawa, H.; Hoshikawa, A.; Ishii, Y.; Chakoumakos, B. C.; Fernandez-Baca, J. A. (20 November 2006).
10968:
Jewitt, David C.; Luu, Jane (2004). "Crystalline water ice on the Kuiper belt object (50000) Quaoar".
10191:
8134:
6852:"Thermodynamic Stability of Ice II and Its Hydrogen-Disordered Counterpart: Role of Zero-Point Energy"
6732:
12477:
12220:
4082:
3459:
3121:
2928:
40 K (−233.2 °C; −387.7 °F). The adsorbed hydrogen molecules can then be released, or
2851:
2278:
262:
6485:"New porous water ice metastable at atmospheric pressure obtained by emptying a hydrogen-filled ice"
6363:
6313:
6066:
C. Lobban, J.L. Finney and W.F. Kuhs, The structure of a new phase of ice, Nature 391, 268–270, 1998
3796:
576:
313:
11018:
9058:
4683:
3003:
and infrared spectrum. At near-IR wavelengths, the characteristics of the 1.65, 3.1, and 4.53
2937:
2917:
2867:
2545:
2417:
at room pressure while under 120 K (−153 °C; −244 °F), but collapses into ice I
1463:
1 and 2 GPa (formation at 160 K (−113 °C)); ambient (at 77 K (−196.2 °C))
1438:
At 77 K (−196.2 °C): 1.6 GPa (formation from Ih); 0.5 GPa (formation from LDA)
226:
9911:
Furić, K.; Volovšek, V. (2010). "Water ice at low temperatures and pressures; new Raman results".
7745:
4416:
4160:"Thermodynamic and kinetic isotope effects on the order-disorder transition of ice XIV to ice XII"
1901:
The least dense crystalline form of water, topologically equivalent to the empty structure of sII
11975:
11726:
11208:
8628:
8023:"Transition from one-dimensional water to ferroelectric ice within a supramolecular architecture"
5780:
Grande, Zachary M.; et al. (2022). "Pressure-driven symmetry transitions in dense H2O ice".
5553:
5313:
2632:
2608:
1876:
A proton-ordered form of ice VI formed by cooling water to around 80–108 K at 1.1 GPa.
1254:
437:
structure changes to that of ice I. Also, ice XI, an orthorhombic, hydrogen-ordered form of ice I
390:
49:
17:
7478:
1434:<30 K (−243.2 °C) (vapor deposition); 77 K (−196.2 °C) (stability point)
12029:
11721:
11453:
10539:
Kouchi, Akira; Kuroda, Toshio (1990). "Amorphization of cubic ice by ultraviolet irradiation".
7114:"The Pressure-Volume-Temperature Relations of the Liquid, and the Phase Diagram of Heavy Water"
5033:
4837:
2980:
2814:
exhibits many peculiar properties that are relevant to the existence of life and regulation of
2165:
Ice VII is the only disordered phase of ice that can be ordered by simple cooling. (While ice I
345:
9854:"No evidence for large-scale proton ordering in Antarctic ice from powder neutron diffraction"
9290:
6926:
Shephard, J. J., Ling, S., Sosso, G. C., Michaelides, A., Slater, B., Salzmann, C. G. (2017),
11534:
9244:
9173:
9102:
7748:"The existence of memory effect on hydrogen ordering in ice: The effect makes ice attractive"
7503:
Dengel, O.; Eckener, U.; Plitz, H.; Riehl, N. (1 May 1964). "Ferroelectric behavior of ice".
7049:
6784:
6215:
5307:
4134:
3511:
1727:
Has symmetrized hydrogen bonds – a hydrogen atom is found at the center of two oxygen atoms.
10944:
10737:
10518:
10410:
10397:
Seki, J.; Hasegawa, H. (1983). "The heterogeneous condensation of interstellar ice grains".
7651:
Castro Neto, A.; Pujol, P.; Fradkin, E. (2006). "Ice: A strongly correlated proton system".
6928:"Is High-Density Amorphous Ice Simply a "Derailed" State along the Ice I to Ice IV Pathway?"
6733:
Yamane R, Komatsu K, Gouchi J, Uwatoko Y, Machida S, Hattori T, Kagi H; et al. (2021).
6712:
3342:
2951:, it can also be stored within a solid substance, either via a reversible chemical process (
2385:
To create ice XVII, the researchers first produced filled ice in a stable phase named C
146:
phases of ice under pressure, both fully hydrogen-disordered; these are Ice IV and Ice XII.
12430:
12311:
11592:
11543:
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11396:
11299:
11189:
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10548:
10514:
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10369:
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10190:
Newman, Sarah F.; Buratti, B. J.; Brown, R. H.; Jaumann, R.; Bauer, J.; Momary, T. (2008).
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7907:
7852:
7809:
7759:
7713:
7670:
7625:
7582:
7547:
7538:
Kawada, Shuji (1 May 1972). "Dielectric Dispersion and Phase Transition of KOH Doped Ice".
7512:
7408:
7369:
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7235:
7163:
7125:
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5717:
5676:
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5213:
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4640:
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Köster KW, Fuentes-Landete V, Raidt A, Seidl M, Gainaru C, Loerting T; et al. (2018).
4041:
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3640:
3617:
Martelli, Fausto; Torquato, Salvatore; Giovambattista, Nicolas; Car, Roberto (2017-09-29).
3575:
3481:
3431:
3373:
3303:
3268:
2519:
2306:
2065:
621:
12437:
3927:"Review of the vapour pressures of ice and supercooled water for atmospheric applications"
3618:
349:
An alternative formulation of the phase diagram for certain ices and other phases of water
8:
12472:
12467:
12316:
4007:
3048:
2993:
2956:
2944:
2874:
2819:
2678:
2593:
2589:
2577:
1944:
421:
330:
326:
105:
11596:
11547:
11498:
11400:
11303:
11193:
11128:
11078:
11032:
10981:
10903:
10856:
10809:
10792:
Hosek, Matthew W. Jr.; Blaauw, Rhiannon C.; Cooke, William J.; Suggs, Robert M. (2013).
10768:
10702:
10649:
10595:
10552:
10453:
10373:
10334:
10294:
10259:
10210:
10156:
10106:
9973:
9924:
9869:
9830:
9715:
9674:
9635:
9600:
9545:
9434:
9384:
9329:
9210:
9139:
9061:"Deep-Glassy Ice VI Revealed with a Combination of Neutron Spectroscopy and Diffraction"
9019:
8807:
8713:
8647:
8587:
8479:
8419:
8347:
8292:
8239:
8178:
8038:
7991:
7911:
7856:
7813:
7763:
7717:
7674:
7629:
7586:
7551:
7516:
7450:
Fan, Xiaofeng; Bing, Dan; Zhang, Jingyun; Shen, Zexiang; Kuo, Jer-Lai (1 October 2010).
7412:
7373:
7327:
7285:
7239:
7167:
7129:
7083:
6905:
6821:
6750:
6657:
Gasser, TM; Thoeny, AV; Plaga, LJ; Köster, KW; Etter, M; Böhmer, R; et al. (2018).
6606:
6510:
6400:
6282:
6183:
6092:
6002:
5917:
5882:
5844:
5793:
5721:
5680:
5569:
5430:
5263:
5217:
5174:
5121:
5075:
4979:
4926:
4879:
4793:
4756:
4699:
4644:
4590:
4504:
4457:
4345:
4296:
4237:
4175:
4100:
4045:
3942:
3903:
3833:
3773:
3699:
3644:
3579:
3485:
3435:
3377:
3307:
3272:
2857:
Low-density ASW (LDA), also known as hyperquenched glassy water, may be responsible for
2108:
F has been reported to be a hydrogen disordering reagent. However, adding 2.5 mol% of NH
397:. In an experiment, ice at −3 °C was superheated to about 17 °C for about 250
12462:
12419:
11954:
11510:
11484:
11430:
11363:
11090:
11001:
10868:
10842:
10617:
10564:
10422:
10043:
9993:
9959:
9737:
9564:
9525:
9349:
9227:
9194:
9156:
9123:
9085:
9060:
9041:
8975:
8950:
8733:
8604:
8573:
8561:
8498:
8463:
8405:
8372:
8331:
8278:
8225:
8198:
8164:
8124:
8057:
8022:
8003:
7960:
7925:
7876:
7686:
7660:
7432:
7385:
7297:
7095:
7068:"Recrystallisation of HDA ice under pressure by in-situ neutron diffraction to 3.9 GPa"
6965:
6939:
6833:
6767:
6735:"Experimental evidence for the existence of a second partially-ordered phase of ice VI"
6734:
6683:
6658:
6634:
6527:
6496:
6484:
6420:
6386:
6302:
6203:
6112:
6021:
5986:
5813:
5608:
5275:
5229:
5186:
5143:
5087:
4948:
4813:
4765:
4740:
4664:
4610:
4576:
4331:
4265:
4197:
4117:
4084:
4065:
3956:
3853:
3819:
3737:
3664:
3630:
3599:
3548:
3319:
3214:
3058:
3022:
2858:
2636:
2604:
2552:
2541:
1902:
856:
852:
432:. The high latent heat of sublimation is principally indicative of the strength of the
11409:
11384:
11188:(49.02). Division for Planetary Sciences Meeting, American Astronomical Society: 732.
10818:
10793:
9838:
5740:
5705:
4319:
11816:
11776:
11666:
11645:
11610:
11561:
11514:
11454:"Public Affairs Office: Recreating the Bizarre State of Water Found on Giant Planets"
11344:
11234:
11150:
11094:
11044:
10993:
10663:
10621:
10426:
10355:
10302:
10035:
9985:
9881:
9741:
9729:
9569:
9506:
9396:
9341:
9296:
9232:
9161:
9090:
9045:
9033:
8980:
8899:
8819:
8763:
8737:
8725:
8659:
8609:
8537:
8503:
8439:
8431:
8377:
8359:
8312:
8304:
8251:
8190:
8105:
8097:
8062:
8007:
7929:
7868:
7825:
7690:
7637:
7594:
7524:
7424:
7301:
7251:
6957:
6871:
6772:
6688:
6638:
6626:
6618:
6532:
6412:
6352:
6294:
6195:
6104:
6026:
5929:
5817:
5805:
5745:
5591:
Bridgman, P. W. (1912). "Water, in the Liquid and Five Solid Forms, under Pressure".
5511:
5450:
5442:
5317:
5147:
5009:
4991:
4940:
4891:
4838:"Scientists created a weird new type of ice that is almost exactly as dense as water"
4805:
4721:
4668:
4656:
4614:
4602:
4516:
4512:
4469:
4420:
4357:
4269:
4257:
4249:
4189:
4122:
4057:
3960:
3845:
3785:
3741:
3729:
3721:
3656:
3591:
3499:
3389:
2640:
2453:
O) can be formed from ice XVII. This was done by heating specifically prepared D
2410:
2379:
1914:
1866:
80 K (−193.2 °C) – 108 K (−165 °C) (formation from liquid water)
278:
258:
207:
175:
10885:
10872:
10833:
Jewitt, David C.; Luu, Jane X. (2001). "Colors and Spectra of Kuiper Belt Objects".
10581:
8202:
7964:
7880:
7474:
7436:
7099:
6969:
6837:
6207:
6116:
5279:
4952:
4201:
3857:
3668:
3603:
3531:
P. W. Bridgman (1912). "Water, in the Liquid and Five Solid Forms, under Pressure".
945:{\displaystyle R\ln(3/2)=3.37\mathrm {J} \cdot \mathrm {mol} ^{-1}\mathrm {K} ^{-1}}
317:
Water phase diagram extended to negative pressures calculated with TIP4P/2005 model.
12195:
11766:
11701:
11600:
11551:
11502:
11404:
11336:
11307:
11132:
11082:
11036:
11005:
10985:
10948:
10907:
10860:
10813:
10772:
10706:
10653:
10607:
10599:
10568:
10556:
10457:
10414:
10377:
10338:
10298:
10263:
10222:
10214:
10160:
10085:
10047:
10027:
9997:
9977:
9932:
9928:
9873:
9834:
9719:
9700:"Ice-VII inclusions in diamonds: Evidence for aqueous fluid in Earth's deep mantle"
9678:
9639:
9604:
9559:
9549:
9496:
9438:
9388:
9353:
9333:
9222:
9214:
9151:
9143:
9080:
9072:
9023:
8970:
8962:
8845:
8811:
8717:
8651:
8599:
8591:
8493:
8483:
8423:
8367:
8351:
8296:
8243:
8186:
8182:
8129:
8089:
8052:
8042:
7995:
7952:
7915:
7860:
7817:
7767:
7725:
7721:
7678:
7633:
7590:
7555:
7520:
7470:
7416:
7389:
7377:
7360:
7331:
7289:
7243:
7205:
7171:
7133:
7087:
7025:
6995:
6949:
6909:
6863:
6825:
6762:
6754:
6678:
6670:
6610:
6522:
6514:
6424:
6404:
6342:
6333:
6306:
6286:
6187:
6096:
6016:
6006:
5921:
5886:
5848:
5797:
5735:
5725:
5684:
5600:
5573:
5503:
5434:
5267:
5233:
5221:
5190:
5178:
5133:
5125:
5091:
5079:
4983:
4965:
4930:
4883:
4817:
4797:
4760:
4711:
4703:
4648:
4594:
4508:
4461:
4412:
4387:
4349:
4300:
4241:
4179:
4112:
4104:
4069:
4049:
3946:
3907:
3841:
3837:
3777:
3711:
3703:
3652:
3648:
3583:
3540:
3494:
3489:
3461:
3439:
3381:
3323:
3311:
3276:
3206:
3041:
2933:
2890:
2862:
2568:
2493:
2310:
1624:
1540:
1328:
486:
101:
11040:
9124:"Structural characterization of ice XIX as the second polymorph related to ice VI"
8815:
7269:
7067:
6925:
6442:"Sandwiching water between graphene makes square ice crystals at room temperature"
5948:
4221:
3683:
11845:
11744:
11660:
11639:
10953:
10928:
10753:"The search for a cometary outbursts mechanism: a comparison of various theories"
10710:
10218:
9392:
8999:
8247:
7293:
7189:
7091:
7053:
6927:
5507:
5247:
4631:
Salzmann, Christoph G.; Murray, Benjamin J. (June 2020). "Ice goes fully cubic".
4155:
3385:
3213:
superionic phases to be stable over a wide temperature and pressure range, and a
3186:
3109:
3105:
3053:
2948:
2529:
2195:
413:
290:
282:
246:
109:
11180:
McKinnon, W. B.; Hofmeister, A.M. (August 2005). "Ice XI on Pluto and Charon?".
10926:
10688:
10461:
9683:
9658:
9643:
9608:
9076:
8655:
7999:
7942:
6953:
5801:
5107:
4488:
4442:"Lattice Statistics of Hydrogen Bonded Crystals. I. The Residual Entropy of Ice"
3682:
Martelli, Fausto; Leoni, Fabio; Sciortino, Francesco; Russo, John (2020-09-14).
12400:
12390:
12200:
11506:
10316:
10314:
10312:
9534:
Proceedings of the National Academy of Sciences of the United States of America
9218:
9192:
9147:
8700:
8595:
8562:"Ice Ic without stacking disorder by evacuating hydrogen from hydrogen hydrate"
7682:
6849:
6805:
6758:
6560:
6011:
4353:
3760:
2826:
which causes atoms to become closer in the liquid phase. Because of this, ice I
2823:
2572:
2551:
The initial evidence came from optical measurements of laser-heated water in a
2489:
1952:
11716:
10382:
10357:
10137:
10031:
9788:"What scientists found trapped in a diamond: a type of ice not known on Earth"
9697:
9457:
9442:
8721:
7043:
6851:
6829:
6614:
6144:
5967:
5763:
5577:
5371:
4864:"Structural transitions in amorphous water ice and astrophysical implications"
4652:
4598:
3872:
3460:
David T. W. Buckingham, J. J. Neumeier, S. H. Masunaga, and Yi-Kuo Yu (2018).
3443:
2908:
occurred at 72 K while under hydrostatic pressure conditions of up to 70 MPa.
361:, which is exactly 273.16 K (0.01 °C) at a pressure of 611.657
12456:
12215:
12167:
12152:
12020:
11780:
11752:
11348:
11265:
10667:
8903:
8767:
8435:
8363:
8308:
8255:
8101:
7403:
Katoh, E. (15 February 2002). "Protonic Diffusion in High-Pressure Ice VII".
7065:
6867:
6045:
5933:
5515:
5446:
5394:
5348:
4887:
4809:
4520:
4473:
4375:
4361:
4253:
3725:
3238:
One millibar is equivalent to 100 Pa (0.015 psi; 0.00099 atm).
3173:
3161:
3154:
3101:
3031:
2960:
2952:
2600:
2585:
2533:
2426:
2265:
1786:(5,400 atm) (formation from liquid water); 0.81–1.00 GPa/min (from ice I
1783:
1754:
1365:
552:
433:
386:
362:
199:
179:
89:
85:
81:
11696:
11681:
10612:
10309:
9851:
9724:
9699:
9554:
9059:
Rosu-Finsen A, Amon A, Armstrong J, Fernandez-Alonso F, Salzmann CG (2020).
8488:
8047:
7420:
7187:
7012:
Salzmann, C. G., Kohl, I., Loerting, T., Mayer, E., Hallbrucker, A. (2003),
7011:
6191:
6100:
5530:
5472:
5138:
4245:
4153:
3587:
2502:
12225:
12137:
12132:
12127:
12025:
11995:
11809:
11614:
11565:
11136:
11048:
10997:
10777:
10752:
10498:
Kouchi, A.; Yamamoto, T.; Kozasa, T.; Kuroda, T.; Greenberg, J. M. (1994).
9989:
9885:
9733:
9657:
Murray, Benjamin J.; Malkin, Tamsin L.; Salzmann, Christoph G. (May 2015).
9573:
9510:
9400:
9345:
9236:
9165:
9121:
9094:
9037:
8984:
8823:
8663:
8613:
8507:
8443:
8381:
8316:
8194:
8109:
8066:
7872:
7829:
7428:
7255:
7223:
6961:
6875:
6803:
6776:
6692:
6630:
6536:
6416:
6356:
6298:
6199:
6167:
6108:
6030:
5965:
5749:
5730:
5454:
5204:
O.Mishima (1996). "Relationship between melting and amorphization of ice".
4995:
4944:
4895:
4725:
4660:
4606:
4261:
4193:
4126:
4061:
3849:
3789:
3733:
3660:
3595:
3503:
3393:
3210:
3169:
3125:
3089:
2223:
2194:
Ice XI is the hydrogen-ordered form of the ordinary form of ice. The total
2178:
1749:
1536:
1500:
394:
358:
354:
250:
191:
10090:
10073:
10039:
3258:
1554:
190 K (−83 °C) – 210 K (−63 °C) (formation from HDA);
12395:
12301:
12185:
12157:
12147:
12142:
12080:
12065:
12050:
12035:
11959:
11923:
11086:
10847:
10227:
8849:
8840:
Marris, Emma (22 March 2005). "Giant planets may host superionic water".
7772:
7747:
7665:
7559:
7066:
Klotz, S., Hamel, G., Loveday, J. S., Nelmes, R. J., Guthrie, M. (2003),
4336:
3974:
3716:
2976:
2815:
2588:(7,300,000 psi) it is predicted that superionic ice would take on a
2518:
A remarkable characteristic of superionic ice is its ability to act as a
2446:
2409:
O molecules, formed at high pressures. Although sometimes referred to as
1948:
1482:
190 K (−83 °C) - 210 K (−63 °C) (formation from ice I
1409:
404:
270:
230:
77:
12331:
10989:
9337:
8696:"Experimental evidence for superionic water ice using shock compression"
6518:
6408:
6290:
5641:
5612:
4391:
4108:
4053:
3552:
3293:
2782:
2046:
12385:
12265:
12250:
12210:
12205:
12085:
12060:
12010:
11985:
11889:
11605:
11580:
11556:
11529:
10723:
10418:
9981:
9501:
9484:
9315:
9028:
9003:
8966:
8870:"New phase of water could dominate the interiors of Uranus and Neptune"
7864:
7247:
7193:
7151:
7113:
7013:
6674:
6591:"Nanosecond X-ray diffraction of shock-compressed superionic water ice"
5689:
5664:
4184:
4159:
2414:
2226:
with hexagonal ice and gaseous water at (~72 K, ~0 Pa). Ice I
2069:
1588:
1530:
398:
143:
139:
11340:
11235:"Astronomers Find Super-Earth Using Amateur, Off-the-Shelf Technology"
10267:
10164:
9877:
8729:
8695:
8427:
8355:
8300:
8093:
7956:
7821:
7209:
7175:
7137:
7029:
6983:
6889:
6622:
6590:
6347:
6328:
5925:
5890:
5852:
5809:
5438:
4801:
4741:"The Enhanced formation of cubic ice in aqueous organic acid droplets"
4716:
4465:
4304:
3781:
3707:
3280:
3092:, perhaps due to resurfacing events such as impacts or cryovolcanism.
3049:
Molecular clouds, circumstellar disks, and the primordial solar nebula
3015:
2955:) or by having the hydrogen molecules attach to the substance via the
2482:
1610:
130 K (−143 °C) - 355 K (82 °C) (stability range)
1048:
468:
12357:
12347:
12326:
12255:
12100:
12075:
12055:
11990:
11980:
11949:
11944:
11909:
10679:
Patashnick, et.al., Nature Vol.250, No. 5464, July 1974, pp. 313–314.
10560:
9004:"Distinguishing ice β-XV from deep glassy ice VI: Raman spectroscopy"
7381:
7335:
6999:
6913:
6483:
del Rosso, Leonardo; Celli, Milva; Ulivi, Lorenzo (7 November 2016).
5604:
5271:
5225:
5182:
5083:
5010:"Scientists made a new kind of ice that might exist on distant moons"
4987:
4707:
4405:
Petrenko, Victor F.; Whitworth, Robert W. (2002-01-17). "2. Ice Ih".
3951:
3911:
3684:"Connection between liquid and non-crystalline solid phases in water"
3544:
3194:
3165:
3116:
2795:
2774:
Photograph showing details of an ice cube under magnification. Ice I
2649:
2612:
1316:
457:
225:, the crystal structure is characterized by the oxygen atoms forming
203:
10356:
Smith, R. G.; Robinson, G.; Hyland, A. R.; Carpenter, G. L. (1994).
9946:
Yen, Fei; Chi, Zhenhua (16 Apr 2015). "Proton ordering dynamics of H
8262:
7351:
6166:
Salzmann CG, Radaelli PG, Hallbrucker A, Mayer E, Finney JL (2006).
4863:
3926:
2916:
Amorphous ice is used in some scientific experiments, especially in
2068:
in a stable condition so long as the temperature is kept at that of
12367:
12362:
12352:
12321:
12285:
12280:
12270:
12122:
12070:
12045:
11904:
11899:
11489:
11362:
Iitaka, Toshiaki (13 July 2010). "Stability of ferroelectric ice".
11312:
11287:
10912:
10887:
10864:
10658:
10603:
10342:
9964:
8578:
8410:
8329:
8283:
8230:
8073:
7977:
7014:"Raman Spectroscopic Study on Hydrogen Bonding in Recovered Ice IV"
6944:
6806:"Doping-induced disappearance of ice II from water's phase diagram"
6501:
5129:
4935:
4910:
4581:
3635:
3181:
2929:
2878:
2248:
also has a proton-ordered form. The total internal energy of ice XI
2237:
There are distinct differences in the Raman spectra between ices I
2218:
2186:
2050:
Phase diagram of water, showing the region where ice III is stable.
1929:
1594:
481:
154:
12441:
11368:
11209:"Astronomers Detect Shadow of Water World in Front of Nearby Star"
8169:
7920:
7895:
6659:"Experiments indicating a second hydrogen ordered phase of ice VI"
6391:
6168:"The preparation and structures of hydrogen ordered phases of ice"
4320:"Residual entropy of ordinary ice from multicanonical simulations"
3824:
3315:
12377:
12275:
12245:
12190:
12180:
12005:
11939:
11934:
11919:
11914:
11894:
11730:
11285:
10886:
Brown, Robert H.; Cruikshank, Dale P.; Pendleton, Yvonne (1999).
8209:
5415:
5061:
3616:
3202:
3146:
2999:
Amorphous ice can be separated from crystalline ice based on its
2886:
2770:
2752:
Several months later, Salzmann et al. published a paper based on
2560:
1391:
1300:
11064:
10320:
7456:, II, III, VI and ice VII: DFT methods with localized based set"
7350:
Hemley, R. J.; Jephcoat, A. P.; Mao, H. K.; et al. (1987),
6078:
4031:
2881:. Due to this demonstration that ice VII exists in nature, the
1057:
measured values. Nagle (1966) used a series summation to obtain
35:
12306:
11929:
11717:"A New State of Water Reveals a Hidden Ocean in Earth's Mantle"
10927:
Fornasier, S.; Dotto, E.; Barucci, M. A.; Barbieri, C. (2004).
10072:
Del Rosso, Leonardo; Celli, Milva; Ulivi, Lorenzo (June 2017).
8892:"New Form of Water, Both Liquid and Solid, Is 'Really Strange'"
8020:
6588:
4489:"Configurational statistics and the dielectric constant of ice"
4318:
Berg, Bernd A.; Muguruma, Chizuru; Okamoto, Yuko (2007-03-21).
3364:
Bjerrum, N (11 April 1952). "Structure and Properties of Ice".
3219:
3198:
3142:
2924:
2369:
2207:
2095:
1956:
1800:
1296:
366:
195:
10794:"Outburst Dust Production of Comet 29P/Schwassmann-Wachmann 1"
9413:
8786:
7788:
Raman scattering study of proton ordered ice XI single crystal
7267:
6850:
Nakamura, T., Matsumoto, M., Yagasaki, T., Tanaka, H. (2015),
2508:
When an electric field is applied, H ions migrate towards the
2341:-1 model is still the best (with the second best candidate of
2301:
structure were found 4 K per water molecule higher in energy.
2190:
Crystal structure of ice XI (c-axis in the vertical direction)
2059:
The properties of ice II were first described and recorded by
1466:
1.26 g/cm (77 K (−196.2 °C); ambient pressure)
620:
allowed configurations of hydrogens for this oxygen atom (see
12260:
12175:
12090:
12015:
11849:
11842:
11474:
9295:(9th ed.). New York: W. H. Freeman and Co. p. 144.
8925:"Scientists create a new form of matter—superionic water ice"
8559:
6376:
6327:
Jacobson, Liam C.; Hujo, Waldemar; Molinero, Valeria (2009).
4001:"Information for users about the proposed revision of the SI"
3619:"Large-Scale Structure and Hyperuniformity of Amorphous Ices"
3150:
2896:
Ice XI is thought to be a more stable conformation than ice I
2564:
2509:
2422:
334:
302:
266:
10832:
10634:
9524:
Kuhs, W. F.; Sippel, C.; Falenty, A.; Hansen, T. C. (2012).
9482:
8997:
8394:
7221:
6984:"The infrared spectrum of ice IV in the range 4000–400 cm−1"
4911:"Crystallization of amorphous water ice in the solar system"
3004:
2737:
O ice XIX was significantly smaller than that of HCl-doped H
2151:
166:
12095:
12040:
12000:
11382:
11326:
10538:
9659:"The crystal structure of ice under mesospheric conditions"
9586:
8154:
5903:
4006:. Bureau International des Poids et Mesures. Archived from
3681:
3409:
393:
in May 2019. Unlike most other solids, ice is difficult to
11528:
Chau, Ricky; Hamel, Sebastien; Nellis, William J. (2011).
10497:
9271:(Physics 511 paper). Iowa State University. Archived from
7222:
Salzmann, CG; Radaelli, PG; Slater, B; Finney, JL (2011),
4534:
Flatz, Christian; Hohenwarter, Stefan (18 February 2021).
2230:
that has been transformed to ice XI and then back to ice I
441:, is considered the most stable form at low temperatures.
198:
atom on each vertex, and the edges of the rings formed by
11832:
10967:
10482:. Dordrecht Kluwer Academic Publishers. pp. 139–155.
10189:
8756:"A Bizarre Form of Water May Exist All Over the Universe"
7452:"Predicting the hydrogen bond ordered structures of ice I
6981:
5246:
4566:
2979:
above 40%, higher than the theoretical maximum ratio for
1970:<118 K (−155 °C) (formation from ice III);
1887:<118 K (−155 °C) (formation from ice III);
1852:
1702:
Proton-ordered equivalent to Ice III. Antiferroelectric.
1493:
1238:{\displaystyle R\ln(1.5\times (730/729)^{2})=R\ln(1.504)}
11797:
Computerized illustrations of molecular structure of HDA
11659:
Petrenko, Victor F.; Whitworth, Robert W. (1999-08-19).
10241:
9816:
9367:
Whalley, E. (1981). "Scheiner's Halo: Evidence for Ice I
9193:
Salzmann CG, Loveday JS, Rosu-Finsen A, Bull CL (2021).
7072:
Zeitschrift für Kristallographie – Crystalline Materials
5593:
Proceedings of the American Academy of Arts and Sciences
4908:
4684:"Formation and stability of cubic ice in water droplets"
3533:
Proceedings of the American Academy of Arts and Sciences
1818:
130 K (−143 °C) (formation from liquid water)
1772:
260 K (−13 °C) (formation from liquid water);
1579:
253 K (−20 °C) (formation from liquid water);
1515:
250 K (−23 °C) (formation from liquid water);
10010:
9523:
8863:
8861:
8859:
8679:, New Scientist,01 September 2010, Magazine issue 2776.
7650:
7502:
6890:"Structure of ice IV, a metastable high-pressure phase"
6816:(6), Springer Science and Business Media LLC: 569–572,
6656:
5057:
5055:
5053:
5051:
4219:
3757:
3180:
space and converting regular ice, much like the fabled
2329:, HBr) do not significantly enhance ice XV formations.
1851:
The proton-ordered form of ice XII. Formation requires
1608:
270 K (−3 °C) (formation from liquid water);
1345:
130 and 220 K (−143 and −53 °C) (formation);
11801:
11383:
Arakawa, M.; Kagi, H.; Fukazawa, H. (1 October 2009).
8789:"Dynamic Ionization of Water under Extreme Conditions"
6887:
5665:"Computing analysis of lattice vibrations of ice VIII"
2567:
they observed frequency shifts which indicated that a
2544:. The ice appears black in color. It is distinct from
2072:, which slows the change in conformation back to ice I
1778:); 183 K (−90 °C) (formation from HDA ice)
581:
579:
10477:
10185:
10183:
10181:
10107:"Astronomers Contemplate Icy Volcanoes in Far Places"
9757:"Pockets of water may lay deep below Earth's surface"
8342:(1). Springer Science and Business Media LLC: 28920.
7224:"The polymorphism of ice: five unresolved questions."
5160:
4857:
4855:
4853:
4851:
3931:
Quarterly Journal of the Royal Meteorological Society
2714:{\displaystyle {\sqrt {2}}\times {\sqrt {2}}\times 1}
2687:
2465:
O cubic ice by first synthesizing filled ice in the C
2202:, so in principle it should naturally form when ice I
2017:<100 K (−173 °C) (formation from ice VI
1951:
and liquid water to pass through laminated sheets of
1713:
165 K (−108 °C) (formation from ice III);
1687:
165 K (−108 °C) (formation from ice III);
1168:
1107:
1063:
962:
865:
755:
652:
505:
10396:
10280:
9663:
Journal of Atmospheric and Solar-Terrestrial Physics
9656:
9624:
Journal of Atmospheric and Solar-Terrestrial Physics
9589:
Journal of Atmospheric and Solar-Terrestrial Physics
9526:"Extent and relevance of stacking disorder in "ice I
9122:
Gasser TM, Thoeny AV, Fortes AD, Loerting T (2021).
8856:
8125:"Super-Dense Frozen Water Breaks Final Ice Frontier"
8088:(44). American Chemical Society (ACS): 21040–21046.
6326:
5868:
5830:
5048:
1665:<278 K (5 °C) (formation from ice VII)
1323:, with the exception only of a small amount of ice I
11530:"Chemical processes in the deep interior of Uranus"
11445:
11110:"Coupled Orbital and Thermal Evolution of Ganymede"
10929:"Water ice on the surface of the large TNO 2004 DW"
10473:
10471:
10439:
10074:"Ice XVII as a Novel Material for Hydrogen Storage"
10071:
8948:
8268:
7703:
6482:
5704:Kamb, Barclay; Davis, Briant L. (1 December 1964).
4317:
3565:
3341:. University of Wisconsin Green Bay. Archived from
3016:
Properties of the amorphous ice in the Solar System
2378:another porous form of ice, was synthesized from a
2182:
Crystal structure of Ice XI viewed along the c-axis
1390:Likely the most common phase in the universe. More
11581:"High pressure partially ionic phase of water ice"
11335:(46). American Chemical Society (ACS): 9203–9214.
11179:
10178:
8626:
7741:
7739:
7737:
7735:
7313:
7270:"Is pressure the key to hydrogen ordering ice IV?"
7204:(22), American Chemical Society (ACS): 5587–5590,
7024:(12), American Chemical Society (ACS): 2802–2807,
5551:
4848:
2818:. For instance, its density is lower than that of
2713:
1803:packing)—the densest possible arrangement without
1432:<140 K (−133 °C) (normal formation);
1237:
1153:
1090:
1032:
944:
839:
735:
612:
535:
115:On Earth, most ice is found in the hexagonal Ice I
11873:
11658:
10362:Monthly Notices of the Royal Astronomical Society
10136:Debennetti, Pablo G.; Stanley, H. Eugene (2003).
10135:
10013:"Cryo-electron microscopy of vitrified specimens"
8670:
7349:
6938:(7), American Chemical Society (ACS): 1645–1650,
6862:(8), American Chemical Society (ACS): 1843–1848,
6370:
6268:
5966:Chaplin, Martinwork=Water Structure and Science.
4773:
4404:
3222:, may prevent the formation of superionic water.
2126:F, an isostructural material of ice, to obtain NH
1738:72 K (−201.2 °C) (formation from ice I
12454:
11288:"Existence of Ferroelectric Ice in the Universe"
11232:
10468:
10067:
10065:
10063:
10061:
10059:
10057:
8542:: CS1 maint: bot: original URL status unknown (
8215:
7607:
7572:
7449:
7152:"Selective Nucleation of the High-Pressure Ices"
6706:
6704:
6702:
5949:"Inside the hotly contested creation of 'ice X'"
5630:science.sciencemag.org, B. Kamb, 8 October 1965.
4533:
2445:It was reported in 2020 that cubic ice based on
1972:<140 K (−133 °C) (stability point)
1889:<140 K (−133 °C) (stability point)
1774:77 K (−196.2 °C) (formation from ice I
1715:<140 K (−133 °C) (stability point)
1689:<140 K (−133 °C) (stability point)
1638:355 K (82 °C) (formation from ice VI)
1457:160 K (−113 °C) (formation from HDA);
1033:{\displaystyle 6^{N}\times (1/2)^{2N}=(3/2)^{N}}
385:of the difference between this triple point and
128:Most liquids under increased pressure freeze at
11527:
11237:. Harvard-Smithsonian Center for Astrophysics.
9423:Bulletin of the American Meteorological Society
8694:Millot, Marius; et al. (5 February 2018).
8689:
8687:
8685:
8555:
8553:
8468:Proceedings of the National Academy of Sciences
8027:Proceedings of the National Academy of Sciences
7732:
7192:, Kohl, I., Mayer, E., Hallbrucker, A. (2002),
7111:
6728:
6726:
6652:
6650:
6648:
6478:
6476:
6474:
6472:
6470:
6468:
6466:
6464:
6462:
6074:
6072:
5710:Proceedings of the National Academy of Sciences
5662:
5552:Kamb, B.; Prakash, A.; Knobler, C. (May 1967).
4861:
4831:
4829:
4827:
4626:
4624:
4562:
4560:
4558:
4556:
3892:Journal of Physical and Chemical Reference Data
3889:
2472:
1568:Typically requires a nucleating agent to form.
840:{\displaystyle S_{0}=k\ln(3/2)^{N}=nR\ln(3/2),}
11060:
11058:
10750:
10104:
9288:
8835:
8833:
8693:
6264:
6262:
6234:
5864:
5862:
4630:
3809:
3530:
2765:
2217:are surrounded by four semi-randomly directed
736:{\displaystyle 6^{N/2}(6/16)^{N/2}=(3/2)^{N}.}
11817:
11417:
11182:Bulletin of the American Astronomical Society
10054:
9910:
9416:"Trigonal Ice Crystals in Earth's Atmosphere"
9186:
9115:
9052:
8991:
8942:
8787:Goncharov, Alexander F.; et al. (2005).
8461:
8388:
7194:"Pure Ice IV from High-Density Amorphous Ice"
6699:
6584:
6582:
6580:
6578:
4779:
4681:
4215:
4213:
4211:
3977:. Bureau International des Poids et Mesures.
3873:"Verwiebe's '3-D' Ice phase diagram reworked"
2749:O is sufficient for the ordering transition.
2401:are all stable solid phases of a mixture of H
2198:of ice XI is about one sixth lower than ice I
1556:77 K (−196.2 °C) (stability point)
1517:77 K (−196.2 °C) (stability point)
1488:77 K (−196.2 °C) (stability point)
1459:77 K (−196.2 °C) (stability point)
1347:240 K (−33 °C) (conversion to Ice I
597:
584:
190:, roughly one of crinkled planes composed of
11729:from the original on 2021-12-21 – via
11175:
11173:
11171:
11101:
10888:"Water Ice on Kuiper Belt Object 1996 TO_66"
9621:
9249:: CS1 maint: multiple names: authors list (
9178:: CS1 maint: multiple names: authors list (
9107:: CS1 maint: multiple names: authors list (
8682:
8550:
8323:
8079:
7799:
7215:
7149:
7041:
6789:: CS1 maint: multiple names: authors list (
6723:
6645:
6554:
6552:
6550:
6548:
6546:
6459:
6320:
6220:: CS1 maint: multiple names: authors list (
6159:
6069:
5493:
5409:
4824:
4621:
4553:
4282:
4147:
4139:: CS1 maint: multiple names: authors list (
4076:
3753:
3751:
3516:: CS1 maint: multiple names: authors list (
3455:
3453:
2425:channels with a diameter of about 6.10
2096:Search for a hydrogen-disordered counterpart
1693:200 MPa-400 MPa (stability range)
1521:300 MPa (formation from liquid water)
308:
11679:
11389:The Astrophysical Journal Supplement Series
11055:
9754:
9455:
9263:
8830:
8457:
8455:
8453:
6558:
6436:
6434:
6259:
6142:
6043:
5859:
5639:
5528:
5470:
5392:
5369:
5346:
5020:
4862:Jenniskens, Peter; Blake, David F. (1994).
2259:
1905:. Transforms into the stacking-faulty ice I
1821:500 MPa (formation from liquid water)
1614:1.1 GPa (formation from liquid water)
1582:500 MPa (formation from liquid water)
499:is equal to 3.4±0.1 J mol K
281:-sized droplets on a sample-holder kept at
92:correspond to some ice phases listed below.
11824:
11810:
11714:
11451:
11355:
11262:"Electric ice a shock to the solar system"
8780:
8525:. Archived from the original on 2022-09-11
7618:Journal of Physics and Chemistry of Solids
7575:Journal of Physics and Chemistry of Solids
7343:
7307:
6575:
6138:
6136:
6134:
6132:
6130:
6128:
6126:
4208:
2778:is the form of ice commonly seen on Earth.
11740:"The Hunt for Earth's Deep Hidden Oceans"
11604:
11555:
11488:
11408:
11367:
11311:
11168:
10952:
10911:
10846:
10817:
10776:
10657:
10611:
10381:
10226:
10089:
9963:
9723:
9682:
9563:
9553:
9500:
9226:
9155:
9084:
9027:
8974:
8749:
8747:
8620:
8603:
8577:
8497:
8487:
8409:
8371:
8282:
8229:
8168:
8056:
8046:
7919:
7771:
7664:
7268:Rosu-Finsen, A., Salzmann, C. G. (2022),
6943:
6932:The Journal of Physical Chemistry Letters
6766:
6682:
6543:
6526:
6500:
6390:
6346:
6020:
6010:
5987:"The everlasting hunt for new ice phases"
5739:
5729:
5703:
5688:
5203:
5137:
4934:
4764:
4715:
4580:
4417:10.1093/acprof:oso/9780198518945.003.0002
4335:
4183:
4116:
3950:
3823:
3748:
3715:
3634:
3493:
3450:
3405:
3403:
2760:
2152:Search for a hydrogen-ordered counterpart
1790:); 810 MPa (formation from HDA ice)
1154:{\displaystyle 6^{6}\times (1/2)^{6}=729}
11715:Hunsberger, Maren (September 21, 2018).
11637:
11259:
10129:
8677:Weird water lurking inside giant planets
8450:
8014:
7893:
7842:
7540:Journal of the Physical Society of Japan
6713:"Exotic crystals of 'ice 19' discovered"
6710:
6431:
5697:
5590:
5545:
5466:
5464:
5301:
5299:
5297:
5295:
5293:
5291:
5289:
5103:
5101:
5026:
4536:"Neue kristalline Eisform aus Innsbruck"
4380:Journal of the American Chemical Society
4154:Fuentes-Landete V; Köster KW; Böhmer R;
3160:Ice VII may comprise the ocean floor of
2822:. This is attributed to the presence of
2781:
2769:
2571:had taken place. The team also created
2532:into an evenly spaced lattice while the
2368:
2185:
2177:
2045:
1793:1.3 g·cm (at 127 K (−146 °C))
1757:. The most stable configuration of ice I
1253:These phases are named according to the
1091:{\displaystyle R\ln(1.50685\pm 0.00015)}
1047:
467:
462:Geometrical frustration § Water ice
403:
344:
312:
165:
162:. Dashed lines represent hydrogen bonds
153:
76:
60:of all important aspects of the article.
11763:Glass transition in hyperquenched water
11107:
9366:
9289:Atkins, Peter; de Paula, Julio (2010).
8122:
7894:Bramwell, Steven T. (21 January 1999).
6123:
5775:
5773:
5656:
5522:
5342:
5340:
4486:
4374:
3363:
2883:International Mineralogical Association
2741:O ice XIX, and that doping of 0.5% of H
1451:Very high-density amorphous ice (VHDA)
1405:73.15 K (−200 °C) (freezing)
635:atoms. But now, consider the remaining
14:
12455:
11361:
9945:
8885:
8883:
8839:
8744:
8116:
7537:
7078:(2), Walter de Gruyter GmbH: 117–122,
6247:from the original on 14 September 2009
5984:
5779:
4835:
4738:
4276:
3924:
3462:"Thermal Expansion of Single-Crystal H
3400:
3357:
3088:crystalline water ice was observed on
3082:
2885:duly classified ice VII as a distinct
2873:In 2018, ice VII was identified among
2557:Lawrence Livermore National Laboratory
2092: m/kg (1.51 cu in/lb).
2061:Gustav Heinrich Johann Apollon Tammann
2041:
1676:Proton-ordered equivalent to Ice VII.
1668:2.1 GPa (formation from ice VII)
178:of ordinary ice was first proposed by
56:Please consider expanding the lead to
11805:
11423:
8949:Rosu-Finsen, A; Salzmann, CG (2019).
8889:
8753:
7402:
5959:
5461:
5305:
5286:
5098:
4836:Pappas, Stephanie (2 February 2023).
4682:Murray, B.J.; Bertram, A. K. (2006).
4439:
3870:
3132:quakes' within the thick ice layers.
1928:Room temperature (in the presence of
1869:1.1GPa (formation from liquid water)
1641:2.2 GPa (formation from ice VI)
269:crystal surface under 120 K. In
27:States of matter for water as a solid
12426:
11578:
8867:
8514:
8123:Sanders, Laura (11 September 2009).
7786:K. Abe, Y. Ootake and T. Shigenari,
6982:Engelhardt, H., Whalley, E. (1979),
6235:Sanders, Laura (11 September 2009).
5770:
5337:
859:. So, the molar residual entropy is
451:
221:In the best-known form of ice, ice I
149:
29:
11737:
11704:(PDF in German, iktp.tu-dresden.de)
11697:London South Bank University Report
11329:The Journal of Physical Chemistry B
10528:from the original on 22 March 2020.
9952:Physical Chemistry Chemical Physics
9785:
9489:Physical Chemistry Chemical Physics
8880:
8520:
8332:"Partially ordered state of ice XV"
8082:The Journal of Physical Chemistry B
7945:The Journal of Physical Chemistry B
7845:Physical Chemistry Chemical Physics
7198:The Journal of Physical Chemistry B
7045:Neutron diffraction studies of ices
7018:The Journal of Physical Chemistry B
6856:The Journal of Physical Chemistry B
5946:
5669:Royal Society of Chemistry Advances
5252:Physical Chemistry Chemical Physics
4909:Jenniskens P.; Blake D. F. (1996).
4493:Proceedings of the Physical Society
1955:, unlike smaller molecules such as
1399:Medium-density amorphous ice (MDA)
536:{\displaystyle =R\ln(1.50\pm 0.02)}
340:
24:
11863:
11625:
11579:Wang, Yanchao (29 November 2011).
11424:Chang, Kenneth (5 February 2018).
11241:from the original on April 7, 2012
10478:Jenniskens; Blake; Kouchi (1998).
10105:Chang, Kenneth (9 December 2004).
9798:from the original on 12 March 2018
9767:from the original on March 8, 2018
8922:
8627:Demontis, P.; et al. (1988).
5706:"Ice Vii, the Densest Form of Ice"
5027:Sullivan, Will (3 February 2023).
3205:hold a layer of superionic water.
3176:) that are largely made of water.
2861:on Earth and is usually formed by
2469:phase, and then decompressing it.
2252:was predicted as similar as ice XI
1829:The proton-ordered form of ice V.
1560:810 MPa (formation from HDA)
1441:1.17 g/cm (ambient pressure)
929:
914:
911:
908:
899:
628:configurations that satisfy these
588:
408:Pressure dependence of ice melting
301:has shown that amorphous ices are
25:
12489:
11868:
11708:
11260:Grossman, Lisa (25 August 2011).
9195:"Structure and nature of ice XIX"
8629:"New high-pressure phases of ice"
7162:(12), AIP Publishing: 4930–4932,
6994:(10), AIP Publishing: 4050–4051,
6900:(12), AIP Publishing: 5887–5899,
6888:Engelhardt, H., Kamb, B. (1981),
5985:Hansen, Thomas C. (26 May 2021).
3981:from the original on 16 July 2012
3336:
3115:The surface ice of Saturn's moon
2911:
2790:with respect to other ice phases.
2629:differential scanning calorimetry
2318:differential scanning calorimetry
1426:High-density amorphous ice (HDA)
1052:The crystal structure of ice VIII
558:Suppose there are a given number
12436:
12425:
12415:
12414:
11787:AIP accounting discovery of VHDA
11783:of water (requires registration)
11572:
11521:
11468:
11376:
11320:
11279:
11253:
11226:
11200:
11143:
11012:
10961:
10920:
10879:
10826:
10785:
10744:
10717:
10682:
10673:
10628:
10575:
10532:
10433:
10390:
10349:
10274:
10235:
10098:
10004:
9939:
9904:
9845:
9810:
9779:
9748:
9691:
9650:
9615:
9580:
9517:
9476:
9449:
9407:
9360:
9309:
9282:
9257:
8916:
8148:
7971:
7936:
7887:
7836:
7793:
7780:
7697:
7644:
7601:
7566:
7531:
7496:
6362:
6312:
4487:Hollins, G. T. (December 1964).
3795:
3232:
3209:and free-energy methods predict
2943:Aside from storing hydrogen via
2501:
2481:
2145:high-density amorphous ice (HDA)
1843:1.2GPa (formation from ice XII)
1373:Low-density amorphous ice (LDA)
472:The Wurtzite structure. In Ice I
240:
170:The crystal structure of ice XII
34:
11233:David A. Aguilar (2009-12-16).
11215:from the original on 2017-08-21
11067:Journal of Geophysical Research
10248:Journal of Geophysical Research
10117:from the original on 9 May 2015
10020:Quarterly Reviews of Biophysics
9858:The Journal of Chemical Physics
9458:"Stacking disordered ice; Ice I
8398:The Journal of Chemical Physics
8271:The Journal of Chemical Physics
7802:The Journal of Chemical Physics
7475:10.1016/j.commatsci.2010.04.004
7463:Computational Materials Science
7443:
7396:
7261:
7181:
7143:
7124:(10), AIP Publishing: 597–605,
7118:The Journal of Chemical Physics
7105:
7059:
7035:
7005:
6988:The Journal of Chemical Physics
6975:
6919:
6894:The Journal of Chemical Physics
6881:
6843:
6797:
6334:Journal of Physical Chemistry B
6228:
6060:
6037:
5978:
5940:
5906:The Journal of Chemical Physics
5897:
5871:The Journal of Chemical Physics
5833:The Journal of Chemical Physics
5824:
5756:
5633:
5619:
5584:
5487:
5419:The Journal of Chemical Physics
5386:
5363:
5306:Hobbs, Peter V. (May 6, 2010).
5240:
5197:
5154:
5002:
4959:
4902:
4732:
4675:
4527:
4480:
4446:Journal of Mathematical Physics
4433:
4398:
4368:
4311:
4285:The Journal of Chemical Physics
4025:
3993:
3967:
3918:
3883:
3864:
3803:
3761:The Journal of Chemical Physics
3688:The Journal of Chemical Physics
3675:
3128:is believed to contain ice VI.
2540:as typical metals, making it a
2035:Formation requires HCl doping.
1943:Formation likely driven by the
1909:and further into ordinary ice I
1543:of 1.16 with respect to water.
1248:
613:{\textstyle {\tbinom {4}{2}}=6}
546:
182:in 1935. The structure of ice I
48:may be too short to adequately
11644:. Cambridge University Press.
11638:Fletcher, N. H. (2009-06-04).
10399:Astrophysics and Space Science
10138:"Supercooled and Glassy Water"
9933:10.1016/j.molstruc.2010.03.024
8277:(24). AIP Publishing: 244507.
8187:10.1103/PhysRevLett.103.105701
7726:10.1016/j.molstruc.2010.02.016
7706:Journal of Molecular Structure
6711:Metcalfe, Tom (9 March 2021).
4222:"Medium-density amorphous ice"
3842:10.1103/PhysRevLett.105.195701
3653:10.1103/PhysRevLett.119.136002
3610:
3559:
3524:
3495:10.1103/PhysRevLett.121.185505
3330:
3287:
3252:
2987:
2936:, an issue often mentioned in
1805:hydrogen bond interpenetration
1719:30-70 GPa (from ice VII)
1232:
1226:
1211:
1202:
1187:
1178:
1136:
1121:
1085:
1073:
1043:
1021:
1006:
991:
976:
889:
875:
831:
817:
793:
778:
721:
706:
686:
671:
530:
518:
293:. Despite the epithet "ice",
58:provide an accessible overview
13:
1:
11738:Woo, Marcus (July 11, 2018).
11151:"Titan: Facts – NASA Science"
11041:10.1126/science.284.5419.1514
10638:Astrophysical Journal Letters
9839:10.1016/S0009-2614(98)00908-7
8890:Chang, Kenneth (2018-02-05).
8816:10.1103/PhysRevLett.94.125508
7407:. 29=5558 (5558): 1264–1266.
7356:O-ice to 128 GPa (1.28 Mbar)"
7048:, University College London,
5947:Kim, Shi En (24 March 2022).
3877:Chemistry Education Materials
3871:David, Carl (8 August 2016).
3245:
2923:Ice XVII can repeatedly
2681:of the profiles based on the
2488:In the absence of an applied
2389:from a mixture of hydrogen (H
2373:Crystal structure of ice XVII
2285:, while an antiferroelectric
11690:London South Bank University
10711:10.1016/j.icarus.2008.12.045
10303:10.1016/0301-0104(81)80158-9
10219:10.1016/j.icarus.2007.04.019
9485:"Stacking disorder in ice I"
9470:London South Bank University
9393:10.1126/science.211.4480.389
8868:Zyga, Lisa (25 April 2013).
8754:Sokol, Joshua (2019-05-12).
8248:10.1016/j.cplett.2015.07.064
7752:Geophysical Research Letters
7638:10.1016/0022-3697(86)90126-5
7595:10.1016/0022-3697(84)90008-8
7525:10.1016/0031-9163(64)90366-X
7294:10.1016/j.cplett.2021.139325
7092:10.1524/zkri.218.2.117.20669
6569:London South Bank University
6153:London South Bank University
6054:London South Bank University
5972:London South Bank University
5650:London South Bank University
5642:"Ice-six (Ice VI) structure"
5627:Reports: Structure of Ice VI
5539:London South Bank University
5508:10.1126/science.166.3907.861
5481:London South Bank University
5403:London South Bank University
5380:London South Bank University
5357:London South Bank University
4766:10.1088/1748-9326/3/2/025008
3386:10.1126/science.115.2989.385
3095:
2473:Ice XVIII (superionic water)
2440:
1368:crystalline variant of ice.
490:atom. This residual entropy
255:glass transition temperature
7:
11753:Discussion of amorphous ice
11686:Water Structure and Science
11641:The Chemical Physics of Ice
11410:10.1088/0067-0049/184/2/361
10819:10.1088/0004-6256/145/5/122
10462:10.1016/j.jastp.2009.10.007
9684:10.1016/j.jastp.2014.12.005
9644:10.1016/j.jastp.2009.10.007
9609:10.1016/j.jastp.2008.06.001
9466:Water Structure and Science
9077:10.1021/acs.jpclett.0c00125
8656:10.1103/PhysRevLett.60.2284
8000:10.1103/PhysRevLett.80.1533
7316:Journal of Chemical Physics
6954:10.1021/acs.jpclett.7b00492
6565:Water Structure and Science
6149:Water Structure and Science
6050:Water Structure and Science
5802:10.1103/PhysRevB.105.104109
5646:Water Structure and Science
5535:Water Structure and Science
5477:Water Structure and Science
5399:Water Structure and Science
5376:Water Structure and Science
5353:Water Structure and Science
4968:Journal of Chemical Physics
4440:Nagle, J. F. (1966-08-01).
4411:. Oxford University Press.
3261:Journal of Chemical Physics
2766:Earth's natural environment
2727:Clausius–Clapeyron relation
2364:
2206:is cooled to below 72
2024:2GPa (formation from ice VI
747:Boltzmann's entropy formula
10:
12494:
11507:10.1038/s41567-021-01334-9
10954:10.1051/0004-6361:20048004
10933:Astronomy and Astrophysics
10726:Astronomy and Astrophysics
10507:Astronomy and Astrophysics
9755:Sid Perkins (2018-03-08).
9219:10.1038/s41467-021-23399-z
9148:10.1038/s41467-021-21161-z
8596:10.1038/s41467-020-14346-5
8523:"Ice-seventeen (Ice XVII)"
7683:10.1103/PhysRevB.74.024302
7156:Journal of Applied Physics
6759:10.1038/s41467-021-21351-9
6561:"Ice-seventeen (Ice XVII)"
6012:10.1038/s41467-021-23403-6
4513:10.1088/0370-1328/84/6/318
4354:10.1103/PhysRevB.75.092202
3135:
2837:negative thermal expansion
2622:
2563:and super heating it with
2160:
1381:NA (atmospheric or lower)
455:
275:hyperquenched glassy water
158:Crystal structure of ice I
12409:
12376:
12340:
12294:
12238:
12221:Short-track speed skating
12166:
12118:
12109:
11968:
11882:
11856:
11839:
11682:"Hexagonal ice structure"
11292:The Astrophysical Journal
10892:The Astrophysical Journal
10757:Astronomische Nachrichten
10442:J. Atmos. Sol.-Terr. Phys
10032:10.1017/S0033583500004297
9443:10.1175/BAMS-D-13-00128.1
8722:10.1038/s41567-017-0017-4
7616:doped with KOD: Ice XI".
6830:10.1038/s41567-018-0094-z
6615:10.1038/s41586-019-1114-6
6237:"A Very Special Snowball"
5578:10.1107/S0365110X67001409
4653:10.1038/s41563-020-0696-6
4599:10.1038/s41563-020-0606-y
3444:10.1107/S0108768194004933
3193:It is theorized that the
3069:
2846:, a small amount of ice I
2794:Virtually all ice in the
2279:density functional theory
2271:
2173:
2116:
2054:
1315:Virtually all ice in the
389:, though this definition
309:Pressure-dependent states
263:physical vapor deposition
194:hexagonal rings, with an
123:
10835:The Astronomical Journal
10798:The Astronomical Journal
9819:Chemical Physics Letters
9266:"The Many Phases of Ice"
8218:Chemical Physics Letters
7352:"Static compression of H
7274:Chemical Physics Letters
7112:Bridgman, P. W. (1935),
6868:10.1021/acs.jpcb.5b09544
4888:10.1126/science.11539186
3225:
3184:mentioned in Vonnegut's
3077:29P/Schwassmann–Wachmann
2938:environmental technology
2918:cryo-electron microscopy
2868:polar mesospheric clouds
2260:Ferroelectric properties
2213:Water molecules in ice I
1585:1.24 g cm (at 350 MPa).
11831:
11769:(requires registration)
11542:. Article number: 203.
10945:2004A&A...422L..43F
10751:Gronkowski, P. (2007).
10738:1994A&A...286..659T
10519:1994A&A...290.1009K
10411:1983Ap&SS..94..177S
10383:10.1093/mnras/271.2.481
9725:10.1126/science.aao3030
9555:10.1073/pnas.1210331110
8489:10.1073/pnas.1900739116
8157:Physical Review Letters
8048:10.1073/pnas.1010310108
7980:Physical Review Letters
7421:10.1126/science.1067746
7280:, Elsevier BV: 139325,
6192:10.1126/science.1123896
6101:10.1126/science.1123896
5314:Oxford University Press
4246:10.1126/science.abq2105
3812:Physical Review Letters
3623:Physical Review Letters
3588:10.1126/science.1061757
3474:Physical Review Letters
3422:Between 10 and 265 K".
2609:University of Rochester
2313:as had been predicted.
2104:F-doped ices because NH
1269:Temperature thresholds
253:of liquid water to its
11137:10.1006/icar.1997.5778
10778:10.1002/asna.200510657
8998:Thoeny AV; Gasser TM;
8404:(20). AIP Publishing.
8224:. Elsevier BV: 63–66.
6145:"Ice-twelve (Ice XII)"
5731:10.1073/pnas.52.6.1433
5558:Acta Crystallographica
5425:(13). AIP Publishing.
4688:Phys. Chem. Chem. Phys
3925:Murphy, D. M. (2005).
2791:
2779:
2761:Practical implications
2715:
2374:
2191:
2183:
2051:
1999:1.2GPa (from ice VII)
1979:Near that of ice XVI.
1976:1.2GPa (from ice III)
1893:1.2GPa (from ice VII)
1281:Other characteristics
1239:
1155:
1092:
1053:
1034:
946:
841:
737:
614:
537:
477:
409:
350:
318:
171:
163:
93:
11585:Nature Communications
11535:Nature Communications
10584:Astrophysical Journal
10323:Astrophysical Journal
10091:10.3390/challe8010003
8566:Nature Communications
7150:Evans, L. F. (1967),
7042:Colin Lobban (1998),
6489:Nature Communications
6046:"Ice-eleven (ice XI)"
5991:Nature Communications
5968:"Ice-seven (Ice VII)"
5764:"Ice VII (ice-seven)"
5554:"Structure of ice. V"
5372:"Ice-three (Ice III)"
5110:Astrophysical Journal
4915:Astrophysical Journal
4739:Murray, B.J. (2008).
4540:Universität Innsbruck
3066:orbit (~12 AU).
2785:
2773:
2716:
2372:
2189:
2181:
2049:
1240:
1156:
1093:
1051:
1035:
947:
842:
738:
615:
538:
471:
407:
348:
316:
265:) onto a very smooth
169:
157:
84:pressure-temperature
80:
11634:(www.idc-online.com)
11108:Showman, A. (1997).
11087:10.1029/2003JE002149
9371:in the Atmosphere".
8850:10.1038/news050321-4
7773:10.1029/2011GL048217
7581:(11–12): 1135–1144.
7560:10.1143/JPSJ.32.1442
5034:Smithsonian Magazine
2786:Phase space of ice I
2685:
2542:superionic conductor
2066:atmospheric pressure
1272:Pressure thresholds
1166:
1105:
1061:
960:
863:
753:
650:
622:Binomial coefficient
577:
503:
12317:Iceman (occupation)
11597:2011NatCo...2..563W
11548:2011NatCo...2..203C
11499:2021NatPh..17.1228C
11401:2009ApJS..184..361A
11304:2006ApJ...652L..57F
11194:2005DPS....37.4902M
11129:1997Icar..129..367S
11079:2004JGRE..109.1012H
11033:1999Sci...284.1514S
11027:(5419): 1514–1516.
10990:10.1038/nature03111
10982:2004Natur.432..731J
10904:1999ApJ...519L.101B
10857:2001AJ....122.2099J
10810:2013AJ....145..122H
10769:2007AN....328..126G
10703:2009Icar..201..719M
10650:1990ApJ...355L..27O
10596:1995ApJ...455..389J
10553:1990Natur.344..134K
10454:2010JASTP..72...51M
10374:1994MNRAS.271..481S
10335:1992ApJ...401..353M
10295:1981CP.....56..367H
10260:1998JGR...10325809G
10211:2008Icar..193..397N
10157:2003PhT....56f..40D
9974:2015PCCP...1712458Y
9958:(19): 12458–12461.
9925:2010JMoSt.976..174F
9870:2004JChPh.12011376F
9831:1998CPL...294..554F
9716:2018Sci...359.1136T
9710:(6380): 1136–1139.
9675:2015JASTP.127...78M
9636:2010JASTP..72...51M
9601:2009JASTP..71..453L
9546:2012PNAS..10921259K
9540:(52): 21259–21264.
9435:2015BAMS...96.1519M
9385:1981Sci...211..389W
9338:10.1038/nature03403
9330:2005Natur.434..202M
9211:2021NatCo..12.3162S
9140:2021NatCo..12.1128G
9020:2019PCCP...2115452T
9014:(28): 15452–15462.
9008:Phys Chem Chem Phys
8808:2005PhRvL..94l5508G
8714:2018NatPh..14..297M
8648:1988PhRvL..60.2284D
8588:2020NatCo..11..464K
8480:2019PNAS..11612684L
8474:(26): 12684–12691.
8420:2016JChPh.145t4501S
8348:2016NatSR...628920K
8293:2018JChPh.148x4507R
8240:2015CPL...637...63S
8179:2009PhRvL.103j5701S
8039:2011PNAS..108.3481Z
7992:1998PhRvL..80.1533S
7912:1999Natur.397..212B
7896:"Ferroelectric ice"
7857:2011PCCP...1319788R
7814:2011JChPh.134j4506A
7764:2011GeoRL..3816101A
7718:2010JMoSt.972..111A
7675:2006PhRvB..74b4302C
7630:1986JPCS...47..165M
7587:1984JPCS...45.1135T
7552:1972JPSJ...32.1442K
7517:1964PhL.....9..291D
7413:2002Sci...295.1264K
7374:1987Natur.330..737H
7328:1993JChPh..99.9842P
7286:2022CPL...78939325R
7240:2011PCCP...1318468S
7228:Phys Chem Chem Phys
7168:1967JAP....38.4930E
7130:1935JChPh...3..597B
7084:2003ZK....218..117K
6906:1981JChPh..75.5887E
6822:2018NatPh..14..569S
6751:2021NatCo..12.1129Y
6607:2019Natur.569..251M
6519:10.1038/ncomms13394
6511:2016NatCo...713394D
6409:10.1038/nature14295
6401:2015Natur.519..443A
6341:(30): 10298–10307.
6291:10.1038/nature14014
6283:2014Natur.516..231F
6184:2006Sci...311.1758S
6093:2006Sci...311.1758S
6087:(5768): 1758–1761.
6003:2021NatCo..12.3161H
5918:1973JChPh..58..567L
5883:1968JChPh..48.2362W
5845:1966JChPh..45.3976W
5794:2022PhRvB.105j4109G
5722:1964PNAS...52.1433K
5681:2017RSCAd...731789Y
5675:(51): 31789–31794.
5570:1967AcCry..22..706K
5431:2021JChPh.154m4504S
5395:"Ice-four (Ice IV)"
5264:2001PCCP....3.5355L
5218:1996Natur.384..546M
5175:1985Natur.314...76M
5122:1995ApJ...455..389J
5076:1984Natur.310..393M
4980:1997JChPh.107.1232J
4927:1996ApJ...473.1104J
4880:1994Sci...265..753J
4794:1960Natur.188.1144D
4788:(4757): 1144–1148.
4757:2008ERL.....3b5008M
4700:2006PCCP....8..186M
4645:2020NatMa..19..586S
4591:2020NatMa..19..663D
4505:1964PPS....84.1001H
4458:1966JMP.....7.1484N
4392:10.1021/ja01315a102
4346:2007PhRvB..75i2202B
4297:1933JChPh...1..515B
4238:2023Sci...379..474R
4176:2018PCCP...2021607F
4170:(33): 21607–21616.
4164:Phys Chem Chem Phys
4109:10.1038/ncomms16189
4101:2018NatCo...916189K
4054:10.1038/nature04415
4046:2006Natur.439..183I
3943:2005QJRMS.131.1539M
3904:1994JPCRD..23..515W
3834:2010PhRvL.105s5701M
3774:2009JChPh.131c4510C
3700:2020JChPh.153j4503M
3645:2017PhRvL.119m6002M
3580:2001Sci...294.2335V
3486:2018PhRvL.121r5505B
3436:1994AcCrB..50..644R
3378:1952Sci...115..385B
3308:1999Natur.398..681K
3273:1973JChPh..58..567L
3083:Kuiper Belt objects
2994:interstellar medium
2957:van der Waals force
2679:Rietveld refinement
2633:dielectric spectrum
2631:(DSC) thermograms,
2607:, was taken to the
2605:diamond anvil cells
2594:face-centered cubic
2590:body-centered cubic
2578:face-centered cubic
2042:History of research
1945:van der Waals force
1535:Very high relative
1394:than normal water.
749:, we conclude that
624:). Thus, there are
422:heat of sublimation
357:can coexist at the
331:face-centered cubic
327:body-centered cubic
297:analysis utilizing
11869:Crystalline phases
11606:10.1038/ncomms1566
11557:10.1038/ncomms1198
11431:The New York Times
10419:10.1007/BF00651770
10111:The New York Times
9982:10.1039/C5CP01529D
9786:Netburn, Deborah.
9502:10.1039/c4cp02893g
9292:Physical chemistry
9278:on 7 October 2009.
9029:10.1039/c9cp02147g
8967:10.1039/c8sc03647k
8896:The New York Times
8336:Scientific Reports
7865:10.1039/c1cp22506e
7248:10.1039/c1cp21712g
6675:10.1039/c8sc00135a
5690:10.1039/C7RA05563C
5531:"Ice-five (Ice V)"
5473:"Ice-five (Ice V)"
5349:"Ice-two (Ice II)"
5316:. pp. 61–70.
5016:. 4 February 2023.
4185:10.1039/c8cp03786h
4013:on 21 January 2018
3937:(608): 1539–1565.
3345:on 16 October 2016
3215:body-centred cubic
3166:extrasolar planets
3059:circumstellar disk
3023:noctilucent clouds
2859:noctilucent clouds
2792:
2780:
2711:
2553:diamond anvil cell
2411:clathrate hydrates
2375:
2192:
2184:
2139:to prepare ice IV
2052:
1903:clathrate hydrates
1597:in the unit cell.
1358:Similar to Ice Ih
1292:12,976 - 8,476 BC
1266:Year of discovery
1235:
1151:
1088:
1054:
1030:
942:
857:molar gas constant
853:Boltzmann constant
837:
733:
610:
602:
533:
478:
410:
351:
319:
227:hexagonal symmetry
172:
164:
94:
12450:
12449:
12431:Wikimedia Commons
12234:
12233:
11680:Chaplin, Martin.
11483:(11): 1228–1232.
11341:10.1021/jp982549e
10547:(6262): 134–135.
10480:Solar System Ices
10268:10.1029/98je00738
10165:10.1063/1.1595053
9913:J. Mol. Structure
9878:10.1063/1.1765099
9792:Los Angeles Times
9456:Chaplin, Martin.
9379:(4480): 389–390.
9324:(7030): 202–205.
9264:Norman Anderson.
8642:(22): 2284–2287.
8521:Chaplin, Martin.
8428:10.1063/1.4967167
8356:10.1038/srep28920
8301:10.1063/1.5022159
8094:10.1021/jp0540609
7957:10.1021/jp982549e
7951:(46): 9203–9214.
7906:(6716): 212–213.
7822:10.1063/1.3551620
7653:Physical Review B
7368:(6150): 737–740,
7322:(12): 9842–9846.
7210:10.1021/jp014391v
7188:Salzmann, C. G.,
7176:10.1063/1.1709255
7138:10.1063/1.1749561
7030:10.1021/jp021534k
6669:(18): 4224–4234.
6601:(7755): 251–255.
6559:Chaplin, Martin.
6385:(7544): 443–445.
6348:10.1021/jp903439a
6277:(7530): 231–233.
6178:(5768): 1758–61.
6143:Chaplin, Martin.
6044:Chaplin, Martin.
5926:10.1063/1.1679238
5891:10.1063/1.1669438
5853:10.1063/1.1727447
5839:(11): 3976–3982.
5640:Chaplin, Martin.
5529:Chaplin, Martin.
5471:Chaplin, Martin.
5439:10.1063/5.0045443
5393:Chaplin, Martin.
5370:Chaplin, Martin.
5347:Chaplin, Martin.
5258:(24): 5355–5357.
5212:(6609): 546–549.
5070:(5976): 393–395.
4802:10.1038/1881144a0
4466:10.1063/1.1705058
4426:978-0-19-851894-5
4386:(12): 2680–2684.
4324:Physical Review B
4305:10.1063/1.1749327
4232:(6631): 474–478.
4040:(7073): 183–186.
3782:10.1063/1.3182727
3768:(34510): 034510.
3708:10.1063/5.0018923
3372:(2989): 385–390.
3302:(6729): 681–684.
3281:10.1063/1.1679238
2877:found in natural
2703:
2693:
2652:chloride-doped, D
2641:X-ray diffraction
2496:in the O lattice.
2380:clathrate hydrate
2307:antiferroelectric
2082:equilibrium curve
2039:
2038:
1710:2022 (contested)
1355:NA (atmospheric)
1306:NA (atmospheric)
595:
452:Hydrogen disorder
420:, and its latent
208:tetrahedral angle
176:crystal structure
150:Crystal structure
100:are all possible
75:
74:
16:(Redirected from
12485:
12478:Hydrogen storage
12440:
12429:
12428:
12418:
12417:
12116:
12115:
11826:
11819:
11812:
11803:
11802:
11749:
11734:
11702:Physik des Eises
11693:
11676:
11655:
11619:
11618:
11608:
11576:
11570:
11569:
11559:
11525:
11519:
11518:
11492:
11472:
11466:
11465:
11463:
11461:
11452:Charlie Osolin.
11449:
11443:
11442:
11440:
11438:
11421:
11415:
11414:
11412:
11380:
11374:
11373:
11371:
11359:
11353:
11352:
11324:
11318:
11317:
11315:
11283:
11277:
11276:
11274:
11272:
11257:
11251:
11250:
11248:
11246:
11230:
11224:
11223:
11221:
11220:
11204:
11198:
11197:
11177:
11166:
11165:
11163:
11161:
11155:science.nasa.gov
11147:
11141:
11140:
11114:
11105:
11099:
11098:
11062:
11053:
11052:
11016:
11010:
11009:
10965:
10959:
10958:
10956:
10924:
10918:
10917:
10915:
10883:
10877:
10876:
10850:
10848:astro-ph/0107277
10841:(4): 2099–2114.
10830:
10824:
10823:
10821:
10789:
10783:
10782:
10780:
10748:
10742:
10741:
10721:
10715:
10714:
10686:
10680:
10677:
10671:
10670:
10661:
10632:
10626:
10625:
10615:
10613:2060/19980018148
10579:
10573:
10572:
10561:10.1038/344134a0
10536:
10530:
10529:
10527:
10504:
10495:
10484:
10483:
10475:
10466:
10465:
10437:
10431:
10430:
10394:
10388:
10387:
10385:
10353:
10347:
10346:
10318:
10307:
10306:
10283:Chemical Physics
10278:
10272:
10271:
10239:
10233:
10232:
10230:
10196:
10187:
10176:
10175:
10173:
10171:
10142:
10133:
10127:
10126:
10124:
10122:
10102:
10096:
10095:
10093:
10069:
10052:
10051:
10017:
10008:
10002:
10001:
9967:
9943:
9937:
9936:
9919:(1–3): 174–180.
9908:
9902:
9901:
9899:
9897:
9888:. Archived from
9849:
9843:
9842:
9814:
9808:
9807:
9805:
9803:
9783:
9777:
9776:
9774:
9772:
9752:
9746:
9745:
9727:
9695:
9689:
9688:
9686:
9654:
9648:
9647:
9619:
9613:
9612:
9595:(3–4): 453–463.
9584:
9578:
9577:
9567:
9557:
9521:
9515:
9514:
9504:
9480:
9474:
9473:
9453:
9447:
9446:
9429:(9): 1519–1531.
9420:
9411:
9405:
9404:
9364:
9358:
9357:
9313:
9307:
9306:
9286:
9280:
9279:
9277:
9270:
9261:
9255:
9254:
9248:
9240:
9230:
9190:
9184:
9183:
9177:
9169:
9159:
9119:
9113:
9112:
9106:
9098:
9088:
9071:(3): 1106–1111.
9065:J Phys Chem Lett
9056:
9050:
9049:
9031:
8995:
8989:
8988:
8978:
8946:
8940:
8939:
8937:
8935:
8920:
8914:
8913:
8911:
8910:
8887:
8878:
8877:
8865:
8854:
8853:
8837:
8828:
8827:
8793:
8784:
8778:
8777:
8775:
8774:
8751:
8742:
8741:
8691:
8680:
8674:
8668:
8667:
8633:
8624:
8618:
8617:
8607:
8581:
8557:
8548:
8547:
8541:
8533:
8531:
8530:
8518:
8512:
8511:
8501:
8491:
8459:
8448:
8447:
8413:
8392:
8386:
8385:
8375:
8327:
8321:
8320:
8286:
8266:
8260:
8259:
8233:
8213:
8207:
8206:
8172:
8152:
8146:
8145:
8143:
8141:
8120:
8114:
8113:
8077:
8071:
8070:
8060:
8050:
8033:(9): 3481–3486.
8018:
8012:
8011:
7986:(7): 1533–1536.
7975:
7969:
7968:
7940:
7934:
7933:
7923:
7891:
7885:
7884:
7851:(44): 19788–95.
7840:
7834:
7833:
7797:
7791:
7784:
7778:
7777:
7775:
7743:
7730:
7729:
7712:(1–3): 111–114.
7701:
7695:
7694:
7668:
7666:cond-mat/0511092
7648:
7642:
7641:
7605:
7599:
7598:
7570:
7564:
7563:
7535:
7529:
7528:
7500:
7494:
7493:
7491:
7489:
7483:
7477:. Archived from
7469:(4): S170–S175.
7460:
7447:
7441:
7440:
7400:
7394:
7392:
7382:10.1038/330737a0
7347:
7341:
7339:
7336:10.1063/1.465467
7311:
7305:
7304:
7265:
7259:
7258:
7234:(41): 18468–80,
7219:
7213:
7212:
7185:
7179:
7178:
7147:
7141:
7140:
7109:
7103:
7102:
7063:
7057:
7056:
7039:
7033:
7032:
7009:
7003:
7002:
7000:10.1063/1.438173
6979:
6973:
6972:
6947:
6923:
6917:
6916:
6914:10.1063/1.442040
6885:
6879:
6878:
6847:
6841:
6840:
6801:
6795:
6794:
6788:
6780:
6770:
6730:
6721:
6720:
6708:
6697:
6696:
6686:
6654:
6643:
6642:
6586:
6573:
6572:
6556:
6541:
6540:
6530:
6504:
6480:
6457:
6456:
6454:
6453:
6438:
6429:
6428:
6394:
6374:
6368:
6367:
6366:
6360:
6350:
6324:
6318:
6317:
6316:
6310:
6266:
6257:
6256:
6254:
6252:
6232:
6226:
6225:
6219:
6211:
6163:
6157:
6156:
6140:
6121:
6120:
6076:
6067:
6064:
6058:
6057:
6041:
6035:
6034:
6024:
6014:
5982:
5976:
5975:
5963:
5957:
5956:
5944:
5938:
5937:
5901:
5895:
5894:
5877:(5): 2362–2370.
5866:
5857:
5856:
5828:
5822:
5821:
5777:
5768:
5767:
5760:
5754:
5753:
5743:
5733:
5716:(6): 1433–1439.
5701:
5695:
5694:
5692:
5660:
5654:
5653:
5637:
5631:
5623:
5617:
5616:
5605:10.2307/20022754
5588:
5582:
5581:
5549:
5543:
5542:
5526:
5520:
5519:
5491:
5485:
5484:
5468:
5459:
5458:
5413:
5407:
5406:
5390:
5384:
5383:
5367:
5361:
5360:
5344:
5335:
5334:
5332:
5330:
5303:
5284:
5283:
5272:10.1039/b108676f
5248:Loerting, Thomas
5244:
5238:
5237:
5226:10.1038/384546a0
5201:
5195:
5194:
5183:10.1038/314076a0
5158:
5152:
5151:
5141:
5139:2060/19980018148
5105:
5096:
5095:
5084:10.1038/310393a0
5059:
5046:
5045:
5043:
5041:
5024:
5018:
5017:
5006:
5000:
4999:
4988:10.1063/1.474468
4963:
4957:
4956:
4938:
4906:
4900:
4899:
4859:
4846:
4845:
4833:
4822:
4821:
4777:
4771:
4770:
4768:
4736:
4730:
4729:
4719:
4708:10.1039/b513480c
4679:
4673:
4672:
4633:Nature Materials
4628:
4619:
4618:
4584:
4569:Nature Materials
4564:
4551:
4550:
4548:
4547:
4531:
4525:
4524:
4499:(6): 1001–1016.
4484:
4478:
4477:
4452:(8): 1484–1491.
4437:
4431:
4430:
4402:
4396:
4395:
4372:
4366:
4365:
4339:
4337:cond-mat/0609211
4315:
4309:
4308:
4280:
4274:
4273:
4217:
4206:
4205:
4187:
4151:
4145:
4144:
4138:
4130:
4120:
4080:
4074:
4073:
4029:
4023:
4022:
4020:
4018:
4012:
4005:
3997:
3991:
3990:
3988:
3986:
3971:
3965:
3964:
3954:
3952:10.1256/qj.04.94
3922:
3916:
3915:
3912:10.1063/1.555947
3887:
3881:
3880:
3868:
3862:
3861:
3827:
3807:
3801:
3800:
3799:
3793:
3755:
3746:
3745:
3719:
3679:
3673:
3672:
3638:
3614:
3608:
3607:
3574:(5550): 2335–8.
3563:
3557:
3556:
3545:10.2307/20022754
3528:
3522:
3521:
3515:
3507:
3497:
3457:
3448:
3447:
3424:Acta Crystallogr
3407:
3398:
3397:
3361:
3355:
3354:
3352:
3350:
3337:Dutch, Stephen.
3334:
3328:
3327:
3291:
3285:
3284:
3256:
3239:
3236:
3207:Machine learning
3054:Molecular clouds
3042:Peter Jenniskens
2934:hydrogen storage
2806:, also known as
2720:
2718:
2717:
2712:
2704:
2699:
2694:
2689:
2569:phase transition
2505:
2485:
2436:
2432:
2091:
2090:
1625:Debye relaxation
1541:specific gravity
1526:
1329:refractive index
1260:
1259:
1244:
1242:
1241:
1236:
1210:
1209:
1197:
1160:
1158:
1157:
1152:
1144:
1143:
1131:
1117:
1116:
1097:
1095:
1094:
1089:
1039:
1037:
1036:
1031:
1029:
1028:
1016:
1002:
1001:
986:
972:
971:
951:
949:
948:
943:
941:
940:
932:
926:
925:
917:
902:
885:
850:
846:
844:
843:
838:
827:
801:
800:
788:
765:
764:
742:
740:
739:
734:
729:
728:
716:
702:
701:
697:
681:
670:
669:
665:
645:
641:
634:
627:
619:
617:
616:
611:
603:
601:
600:
587:
572:
561:
542:
540:
539:
534:
498:
487:residual entropy
431:
429:
419:
384:
382:
381:
378:
375:
353:Ice, water, and
341:Heat and entropy
325:would take on a
188:wurtzite lattice
102:states of matter
70:
67:
61:
38:
30:
21:
12493:
12492:
12488:
12487:
12486:
12484:
12483:
12482:
12453:
12452:
12451:
12446:
12405:
12372:
12336:
12290:
12230:
12162:
12111:
12105:
11976:Albedo feedback
11964:
11878:
11864:Amorphous solid
11852:
11835:
11830:
11745:Quanta Magazine
11711:
11673:
11652:
11628:
11626:Further reading
11623:
11622:
11577:
11573:
11526:
11522:
11473:
11469:
11459:
11457:
11450:
11446:
11436:
11434:
11422:
11418:
11381:
11377:
11360:
11356:
11325:
11321:
11284:
11280:
11270:
11268:
11258:
11254:
11244:
11242:
11231:
11227:
11218:
11216:
11207:
11205:
11201:
11178:
11169:
11159:
11157:
11149:
11148:
11144:
11112:
11106:
11102:
11063:
11056:
11017:
11013:
10976:(7018): 731–3.
10966:
10962:
10925:
10921:
10884:
10880:
10831:
10827:
10790:
10786:
10749:
10745:
10722:
10718:
10687:
10683:
10678:
10674:
10633:
10629:
10580:
10576:
10537:
10533:
10525:
10502:
10496:
10487:
10476:
10469:
10438:
10434:
10395:
10391:
10354:
10350:
10319:
10310:
10279:
10275:
10245:
10240:
10236:
10194:
10188:
10179:
10169:
10167:
10140:
10134:
10130:
10120:
10118:
10103:
10099:
10070:
10055:
10015:
10009:
10005:
9949:
9944:
9940:
9909:
9905:
9895:
9893:
9892:on 29 July 2012
9864:(24): 11376–9.
9850:
9846:
9815:
9811:
9801:
9799:
9784:
9780:
9770:
9768:
9753:
9749:
9696:
9692:
9655:
9651:
9620:
9616:
9585:
9581:
9529:
9522:
9518:
9481:
9477:
9461:
9454:
9450:
9418:
9412:
9408:
9370:
9365:
9361:
9314:
9310:
9303:
9287:
9283:
9275:
9268:
9262:
9258:
9242:
9241:
9191:
9187:
9171:
9170:
9120:
9116:
9100:
9099:
9057:
9053:
8996:
8992:
8947:
8943:
8933:
8931:
8923:Langin, Katie.
8921:
8917:
8908:
8906:
8888:
8881:
8866:
8857:
8838:
8831:
8796:Phys. Rev. Lett
8791:
8785:
8781:
8772:
8770:
8752:
8745:
8692:
8683:
8675:
8671:
8636:Phys. Rev. Lett
8631:
8625:
8621:
8558:
8551:
8535:
8534:
8528:
8526:
8519:
8515:
8460:
8451:
8393:
8389:
8328:
8324:
8267:
8263:
8214:
8210:
8153:
8149:
8139:
8137:
8121:
8117:
8078:
8074:
8019:
8015:
7976:
7972:
7941:
7937:
7892:
7888:
7841:
7837:
7798:
7794:
7785:
7781:
7744:
7733:
7702:
7698:
7649:
7645:
7615:
7611:
7606:
7602:
7571:
7567:
7536:
7532:
7505:Physics Letters
7501:
7497:
7487:
7485:
7484:on 14 July 2014
7481:
7458:
7455:
7448:
7444:
7401:
7397:
7355:
7348:
7344:
7312:
7308:
7266:
7262:
7220:
7216:
7186:
7182:
7148:
7144:
7110:
7106:
7064:
7060:
7040:
7036:
7010:
7006:
6980:
6976:
6924:
6920:
6886:
6882:
6848:
6844:
6802:
6798:
6782:
6781:
6731:
6724:
6709:
6700:
6655:
6646:
6587:
6576:
6557:
6544:
6481:
6460:
6451:
6449:
6440:
6439:
6432:
6375:
6371:
6361:
6325:
6321:
6311:
6267:
6260:
6250:
6248:
6233:
6229:
6213:
6212:
6164:
6160:
6141:
6124:
6077:
6070:
6065:
6061:
6042:
6038:
5983:
5979:
5964:
5960:
5953:Popular Science
5945:
5941:
5902:
5898:
5867:
5860:
5829:
5825:
5778:
5771:
5762:
5761:
5757:
5702:
5698:
5661:
5657:
5638:
5634:
5624:
5620:
5599:(13): 441–558.
5589:
5585:
5550:
5546:
5527:
5523:
5492:
5488:
5469:
5462:
5414:
5410:
5391:
5387:
5368:
5364:
5345:
5338:
5328:
5326:
5324:
5304:
5287:
5245:
5241:
5202:
5198:
5169:(6006): 76–78.
5159:
5155:
5106:
5099:
5060:
5049:
5039:
5037:
5025:
5021:
5008:
5007:
5003:
4964:
4960:
4907:
4903:
4874:(5173): 753–6.
4860:
4849:
4834:
4825:
4778:
4774:
4737:
4733:
4680:
4676:
4629:
4622:
4565:
4554:
4545:
4543:
4532:
4528:
4485:
4481:
4438:
4434:
4427:
4403:
4399:
4373:
4369:
4316:
4312:
4281:
4277:
4218:
4209:
4152:
4148:
4132:
4131:
4081:
4077:
4030:
4026:
4016:
4014:
4010:
4003:
3999:
3998:
3994:
3984:
3982:
3975:"SI base units"
3973:
3972:
3968:
3923:
3919:
3888:
3884:
3869:
3865:
3808:
3804:
3794:
3756:
3749:
3680:
3676:
3615:
3611:
3564:
3560:
3539:(13): 441–558.
3529:
3525:
3509:
3508:
3469:
3465:
3458:
3451:
3421:
3417:
3413:
3408:
3401:
3362:
3358:
3348:
3346:
3339:"Ice Structure"
3335:
3331:
3292:
3288:
3257:
3253:
3248:
3243:
3242:
3237:
3233:
3228:
3138:
3098:
3085:
3072:
3051:
3018:
2990:
2974:
2970:
2914:
2907:
2903:
2899:
2849:
2845:
2834:
2829:
2813:
2801:
2789:
2777:
2768:
2763:
2748:
2744:
2740:
2736:
2698:
2688:
2686:
2683:
2682:
2655:
2625:
2573:computer models
2526:
2525:
2524:
2523:
2515:
2514:
2513:
2506:
2498:
2497:
2486:
2475:
2468:
2464:
2460:
2456:
2452:
2443:
2434:
2433:10 m; 2.40
2430:
2420:
2408:
2404:
2400:
2396:
2392:
2388:
2367:
2348:
2328:
2300:
2296:
2292:
2274:
2262:
2255:
2251:
2247:
2240:
2233:
2229:
2216:
2205:
2201:
2196:internal energy
2176:
2168:
2163:
2154:
2129:
2125:
2119:
2111:
2107:
2103:
2098:
2088:
2086:
2075:
2057:
2044:
2027:
2020:
1947:, which allows
1912:
1908:
1789:
1777:
1760:
1741:
1696:1.16 g/cm
1653:
1524:
1485:
1469:NA (amorphous)
1444:NA (amorphous)
1418:NA (amorphous)
1415:1.06±0.06 g cm
1387:NA (amorphous)
1384:0.94 g/cm
1350:
1339:
1326:
1322:
1289:
1251:
1205:
1201:
1193:
1167:
1164:
1163:
1139:
1135:
1127:
1112:
1108:
1106:
1103:
1102:
1062:
1059:
1058:
1046:
1024:
1020:
1012:
994:
990:
982:
967:
963:
961:
958:
957:
933:
928:
927:
918:
907:
906:
898:
881:
864:
861:
860:
848:
823:
796:
792:
784:
760:
756:
754:
751:
750:
724:
720:
712:
693:
689:
685:
677:
661:
657:
653:
651:
648:
647:
643:
639:
636:
632:
629:
625:
596:
583:
582:
580:
578:
575:
574:
570:
567:
559:
549:
504:
501:
500:
497:
494:
491:
475:
464:
454:
440:
427:
425:
418:5987 J/mol
417:
414:heat of melting
379:
376:
373:
372:
370:
369:was defined as
343:
311:
299:neural networks
283:liquid nitrogen
259:crystal lattice
247:amorphous solid
243:
236:
224:
217:
185:
161:
152:
126:
118:
71:
65:
62:
55:
43:This article's
39:
28:
23:
22:
15:
12:
11:
5:
12491:
12481:
12480:
12475:
12470:
12465:
12448:
12447:
12445:
12444:
12433:
12422:
12410:
12407:
12406:
12404:
12403:
12401:Snowball Earth
12398:
12393:
12391:Little Ice Age
12388:
12382:
12380:
12374:
12373:
12371:
12370:
12365:
12360:
12355:
12350:
12344:
12342:
12338:
12337:
12335:
12334:
12329:
12324:
12319:
12314:
12309:
12304:
12298:
12296:
12292:
12291:
12289:
12288:
12283:
12278:
12273:
12268:
12263:
12258:
12253:
12248:
12242:
12240:
12236:
12235:
12232:
12231:
12229:
12228:
12223:
12218:
12213:
12208:
12203:
12201:Figure skating
12198:
12193:
12188:
12183:
12178:
12172:
12170:
12164:
12163:
12161:
12160:
12155:
12150:
12145:
12140:
12135:
12130:
12125:
12119:
12113:
12107:
12106:
12104:
12103:
12098:
12093:
12088:
12083:
12078:
12073:
12068:
12063:
12058:
12053:
12048:
12043:
12038:
12033:
12023:
12018:
12013:
12008:
12003:
11998:
11993:
11988:
11986:Circle or disc
11983:
11978:
11972:
11970:
11966:
11965:
11963:
11962:
11957:
11952:
11947:
11942:
11937:
11932:
11927:
11917:
11912:
11907:
11902:
11897:
11892:
11886:
11884:
11880:
11879:
11877:
11876:
11871:
11866:
11860:
11858:
11854:
11853:
11840:
11837:
11836:
11829:
11828:
11821:
11814:
11806:
11800:
11799:
11794:
11789:
11784:
11781:phase diagrams
11770:
11760:
11750:
11735:
11710:
11709:External links
11707:
11706:
11705:
11699:
11694:
11677:
11671:
11665:. OUP Oxford.
11662:Physics of Ice
11656:
11650:
11635:
11627:
11624:
11621:
11620:
11571:
11520:
11477:Nature Physics
11467:
11444:
11416:
11395:(2): 361–365.
11375:
11354:
11319:
11313:10.1086/510017
11298:(1): L57–L60.
11278:
11252:
11225:
11199:
11167:
11142:
11123:(2): 367–383.
11100:
11073:(E1): E01012.
11054:
11011:
10960:
10919:
10913:10.1086/312098
10878:
10865:10.1086/323304
10825:
10784:
10763:(2): 126–136.
10743:
10716:
10697:(2): 719–739.
10681:
10672:
10659:10.1086/185730
10627:
10604:10.1086/176585
10574:
10531:
10485:
10467:
10432:
10405:(1): 177–189.
10389:
10368:(2): 481–489.
10348:
10343:10.1086/172065
10308:
10289:(3): 367–379.
10273:
10254:(E11): 25809.
10243:
10234:
10205:(2): 397–406.
10177:
10128:
10097:
10053:
10026:(2): 129–228.
10003:
9947:
9938:
9903:
9844:
9825:(6): 554–558.
9809:
9778:
9747:
9690:
9649:
9614:
9579:
9527:
9516:
9475:
9459:
9448:
9406:
9368:
9359:
9308:
9302:978-1429218122
9301:
9281:
9256:
9185:
9114:
9051:
8990:
8961:(2): 515–523.
8941:
8915:
8879:
8855:
8829:
8802:(12): 125508.
8779:
8743:
8708:(3): 297–302.
8701:Nature Physics
8681:
8669:
8619:
8549:
8513:
8449:
8387:
8322:
8261:
8208:
8163:(10): 105701.
8147:
8115:
8072:
8013:
7970:
7935:
7886:
7835:
7808:(10): 104506.
7792:
7779:
7731:
7696:
7643:
7624:(2): 165–173.
7613:
7609:
7600:
7565:
7530:
7511:(4): 291–292.
7495:
7453:
7442:
7395:
7353:
7342:
7306:
7260:
7214:
7180:
7142:
7104:
7058:
7034:
7004:
6974:
6918:
6880:
6842:
6810:Nature Physics
6796:
6722:
6698:
6644:
6574:
6542:
6458:
6430:
6369:
6319:
6258:
6227:
6158:
6122:
6068:
6059:
6036:
5977:
5958:
5939:
5912:(2): 567–580.
5896:
5858:
5823:
5788:(10): 104109.
5769:
5755:
5696:
5655:
5632:
5618:
5583:
5564:(5): 706–715.
5544:
5521:
5486:
5460:
5408:
5385:
5362:
5336:
5322:
5285:
5239:
5196:
5153:
5130:10.1086/176585
5097:
5047:
5019:
5001:
4974:(4): 1232–41.
4958:
4936:10.1086/178220
4921:(2): 1104–13.
4901:
4847:
4823:
4772:
4745:Env. Res. Lett
4731:
4694:(1): 186–192.
4674:
4639:(6): 586–587.
4620:
4575:(6): 663–668.
4552:
4526:
4479:
4432:
4425:
4408:Physics of Ice
4397:
4376:Pauling, Linus
4367:
4310:
4275:
4207:
4146:
4075:
4024:
3992:
3966:
3917:
3898:(3): 515–527.
3882:
3863:
3818:(19): 195701.
3802:
3747:
3694:(10): 104503.
3674:
3629:(13): 136002.
3609:
3558:
3523:
3480:(18): 185505.
3467:
3463:
3449:
3430:(6): 644–648.
3419:
3415:
3411:
3399:
3356:
3329:
3286:
3267:(2): 567–580.
3250:
3249:
3247:
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3240:
3230:
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3227:
3224:
3137:
3134:
3097:
3094:
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3081:
3071:
3068:
3050:
3047:
3017:
3014:
2989:
2986:
2972:
2968:
2913:
2912:Human industry
2910:
2905:
2901:
2897:
2847:
2843:
2832:
2827:
2824:hydrogen bonds
2816:global climate
2811:
2799:
2787:
2775:
2767:
2764:
2762:
2759:
2746:
2742:
2738:
2734:
2710:
2707:
2702:
2697:
2692:
2653:
2637:Raman spectrum
2624:
2621:
2517:
2516:
2507:
2500:
2499:
2490:electric field
2487:
2480:
2479:
2478:
2477:
2476:
2474:
2471:
2466:
2462:
2458:
2454:
2450:
2442:
2439:
2418:
2406:
2402:
2398:
2394:
2393:) and water (H
2390:
2386:
2366:
2363:
2346:
2326:
2298:
2294:
2290:
2273:
2270:
2261:
2258:
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2249:
2245:
2238:
2231:
2227:
2214:
2203:
2199:
2175:
2172:
2166:
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2159:
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2127:
2123:
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2109:
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2036:
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2025:
2022:
2018:
2015:
2012:
2008:
2007:
2004:
2002:
2000:
1997:
1994:
1991:
1987:
1986:
1983:
1980:
1977:
1974:
1968:
1965:
1961:
1960:
1953:graphene oxide
1941:
1938:
1936:
1933:
1926:
1923:
1919:
1918:
1910:
1906:
1899:
1897:
1894:
1891:
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1503:
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1496:
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1461:
1455:
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1419:
1416:
1413:
1406:
1403:
1400:
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1382:
1379:
1377:
1374:
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1332:
1324:
1320:
1313:
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1283:
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1234:
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989:
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830:
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804:
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708:
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517:
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511:
508:
495:
492:
473:
453:
450:
438:
434:hydrogen bonds
342:
339:
323:superionic ice
310:
307:
295:classification
242:
239:
234:
222:
215:
200:hydrogen bonds
183:
159:
151:
148:
125:
122:
116:
90:Roman numerals
88:of water. The
73:
72:
52:the key points
42:
40:
33:
26:
9:
6:
4:
3:
2:
12490:
12479:
12476:
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12387:
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12379:
12375:
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12364:
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12345:
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12241:
12239:Constructions
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12227:
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12219:
12217:
12216:Speed skating
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12212:
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12077:
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12072:
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12067:
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12054:
12052:
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12047:
12044:
12042:
12039:
12037:
12034:
12031:
12027:
12024:
12022:
12019:
12017:
12014:
12012:
12009:
12007:
12004:
12002:
11999:
11997:
11994:
11992:
11989:
11987:
11984:
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11979:
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11901:
11898:
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11870:
11867:
11865:
11862:
11861:
11859:
11855:
11851:
11847:
11844:
11838:
11834:
11827:
11822:
11820:
11815:
11813:
11808:
11807:
11804:
11798:
11795:
11793:
11790:
11788:
11785:
11782:
11778:
11774:
11771:
11768:
11764:
11761:
11758:
11754:
11751:
11747:
11746:
11741:
11736:
11732:
11728:
11724:
11723:
11718:
11713:
11712:
11703:
11700:
11698:
11695:
11691:
11687:
11683:
11678:
11674:
11672:9780191581342
11668:
11664:
11663:
11657:
11653:
11651:9780521112307
11647:
11643:
11642:
11636:
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11607:
11602:
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11594:
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11567:
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11558:
11553:
11549:
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11541:
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11516:
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10145:Physics Today
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8326:
8318:
8314:
8310:
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8302:
8298:
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8280:
8276:
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8232:
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8017:
8009:
8005:
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7993:
7989:
7985:
7981:
7974:
7966:
7962:
7958:
7954:
7950:
7946:
7939:
7931:
7927:
7922:
7921:10.1038/16594
7917:
7913:
7909:
7905:
7901:
7897:
7890:
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7874:
7870:
7866:
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7711:
7707:
7700:
7692:
7688:
7684:
7680:
7676:
7672:
7667:
7662:
7659:(2): 024302.
7658:
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7592:
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6018:
6013:
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6000:
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5992:
5988:
5981:
5973:
5969:
5962:
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5950:
5943:
5935:
5931:
5927:
5923:
5919:
5915:
5911:
5907:
5900:
5892:
5888:
5884:
5880:
5876:
5872:
5865:
5863:
5854:
5850:
5846:
5842:
5838:
5834:
5827:
5819:
5815:
5811:
5807:
5803:
5799:
5795:
5791:
5787:
5783:
5776:
5774:
5765:
5759:
5751:
5747:
5742:
5737:
5732:
5727:
5723:
5719:
5715:
5711:
5707:
5700:
5691:
5686:
5682:
5678:
5674:
5670:
5666:
5659:
5651:
5647:
5643:
5636:
5629:
5628:
5622:
5614:
5610:
5606:
5602:
5598:
5594:
5587:
5579:
5575:
5571:
5567:
5563:
5559:
5555:
5548:
5540:
5536:
5532:
5525:
5517:
5513:
5509:
5505:
5502:(3907): 861.
5501:
5497:
5490:
5482:
5478:
5474:
5467:
5465:
5456:
5452:
5448:
5444:
5440:
5436:
5432:
5428:
5424:
5420:
5412:
5404:
5400:
5396:
5389:
5381:
5377:
5373:
5366:
5358:
5354:
5350:
5343:
5341:
5325:
5323:9780199587711
5319:
5315:
5311:
5310:
5302:
5300:
5298:
5296:
5294:
5292:
5290:
5281:
5277:
5273:
5269:
5265:
5261:
5257:
5253:
5249:
5243:
5235:
5231:
5227:
5223:
5219:
5215:
5211:
5207:
5200:
5192:
5188:
5184:
5180:
5176:
5172:
5168:
5164:
5157:
5149:
5145:
5140:
5135:
5131:
5127:
5123:
5119:
5115:
5111:
5104:
5102:
5093:
5089:
5085:
5081:
5077:
5073:
5069:
5065:
5058:
5056:
5054:
5052:
5036:
5035:
5030:
5023:
5015:
5011:
5005:
4997:
4993:
4989:
4985:
4981:
4977:
4973:
4969:
4962:
4954:
4950:
4946:
4942:
4937:
4932:
4928:
4924:
4920:
4916:
4912:
4905:
4897:
4893:
4889:
4885:
4881:
4877:
4873:
4869:
4865:
4858:
4856:
4854:
4852:
4843:
4839:
4832:
4830:
4828:
4819:
4815:
4811:
4807:
4803:
4799:
4795:
4791:
4787:
4783:
4776:
4767:
4762:
4758:
4754:
4751:(2): 025008.
4750:
4746:
4742:
4735:
4727:
4723:
4718:
4713:
4709:
4705:
4701:
4697:
4693:
4689:
4685:
4678:
4670:
4666:
4662:
4658:
4654:
4650:
4646:
4642:
4638:
4634:
4627:
4625:
4616:
4612:
4608:
4604:
4600:
4596:
4592:
4588:
4583:
4578:
4574:
4570:
4563:
4561:
4559:
4557:
4541:
4537:
4530:
4522:
4518:
4514:
4510:
4506:
4502:
4498:
4494:
4490:
4483:
4475:
4471:
4467:
4463:
4459:
4455:
4451:
4447:
4443:
4436:
4428:
4422:
4418:
4414:
4410:
4409:
4401:
4393:
4389:
4385:
4381:
4377:
4371:
4363:
4359:
4355:
4351:
4347:
4343:
4338:
4333:
4330:(9): 092202.
4329:
4325:
4321:
4314:
4306:
4302:
4298:
4294:
4290:
4286:
4279:
4271:
4267:
4263:
4259:
4255:
4251:
4247:
4243:
4239:
4235:
4231:
4227:
4223:
4216:
4214:
4212:
4203:
4199:
4195:
4191:
4186:
4181:
4177:
4173:
4169:
4165:
4161:
4157:
4150:
4142:
4136:
4128:
4124:
4119:
4114:
4110:
4106:
4102:
4098:
4094:
4090:
4086:
4079:
4071:
4067:
4063:
4059:
4055:
4051:
4047:
4043:
4039:
4035:
4028:
4009:
4002:
3996:
3980:
3976:
3970:
3962:
3958:
3953:
3948:
3944:
3940:
3936:
3932:
3928:
3921:
3913:
3909:
3905:
3901:
3897:
3893:
3886:
3878:
3874:
3867:
3859:
3855:
3851:
3847:
3843:
3839:
3835:
3831:
3826:
3821:
3817:
3813:
3806:
3798:
3791:
3787:
3783:
3779:
3775:
3771:
3767:
3763:
3762:
3754:
3752:
3743:
3739:
3735:
3731:
3727:
3723:
3718:
3717:11573/1440448
3713:
3709:
3705:
3701:
3697:
3693:
3689:
3685:
3678:
3670:
3666:
3662:
3658:
3654:
3650:
3646:
3642:
3637:
3632:
3628:
3624:
3620:
3613:
3605:
3601:
3597:
3593:
3589:
3585:
3581:
3577:
3573:
3569:
3562:
3554:
3550:
3546:
3542:
3538:
3534:
3527:
3519:
3513:
3505:
3501:
3496:
3491:
3487:
3483:
3479:
3475:
3471:
3456:
3454:
3445:
3441:
3437:
3433:
3429:
3425:
3406:
3404:
3395:
3391:
3387:
3383:
3379:
3375:
3371:
3367:
3360:
3344:
3340:
3333:
3325:
3321:
3317:
3316:10.1038/19480
3313:
3309:
3305:
3301:
3297:
3290:
3282:
3278:
3274:
3270:
3266:
3262:
3255:
3251:
3235:
3231:
3223:
3221:
3216:
3212:
3208:
3204:
3200:
3196:
3191:
3189:
3188:
3183:
3177:
3175:
3171:
3167:
3163:
3158:
3156:
3152:
3148:
3144:
3133:
3129:
3127:
3123:
3118:
3113:
3111:
3107:
3103:
3093:
3091:
3080:
3078:
3067:
3063:
3060:
3055:
3046:
3043:
3039:
3035:
3033:
3032:cryovolcanism
3027:
3024:
3013:
3009:
3006:
3002:
3001:near-infrared
2997:
2995:
2985:
2982:
2978:
2964:
2962:
2961:physisorption
2958:
2954:
2953:chemisorption
2950:
2949:liquification
2946:
2941:
2939:
2935:
2931:
2926:
2921:
2919:
2909:
2894:
2892:
2888:
2884:
2880:
2876:
2871:
2869:
2864:
2860:
2855:
2853:
2842:Besides ice I
2840:
2838:
2825:
2821:
2817:
2809:
2808:ice-phase-one
2805:
2802:(pronounced:
2797:
2784:
2772:
2758:
2755:
2750:
2730:
2728:
2724:
2708:
2705:
2700:
2695:
2690:
2680:
2676:
2672:
2666:
2662:
2660:
2651:
2645:
2642:
2638:
2634:
2630:
2620:
2619:in May 2019.
2618:
2614:
2610:
2606:
2602:
2597:
2595:
2591:
2587:
2582:
2579:
2574:
2570:
2566:
2562:
2558:
2554:
2549:
2547:
2543:
2539:
2535:
2534:hydrogen ions
2531:
2521:
2511:
2504:
2495:
2491:
2484:
2470:
2448:
2438:
2437:10 in).
2428:
2424:
2416:
2412:
2383:
2381:
2371:
2362:
2360:
2356:
2352:
2344:
2340:
2336:
2330:
2323:
2319:
2314:
2312:
2311:ferroelectric
2308:
2302:
2288:
2284:
2280:
2269:
2267:
2266:ferroelectric
2257:
2242:
2235:
2225:
2220:
2211:
2209:
2197:
2188:
2180:
2171:
2158:
2149:
2146:
2142:
2136:
2132:
2114:
2093:
2083:
2077:
2071:
2067:
2062:
2048:
2034:
2032:
2030:
2023:
2016:
2013:
2010:
2009:
2005:
2003:
2001:
1998:
1995:
1992:
1989:
1988:
1984:
1981:
1978:
1975:
1973:
1969:
1966:
1963:
1962:
1958:
1954:
1950:
1946:
1942:
1939:
1937:
1934:
1931:
1927:
1924:
1921:
1920:
1916:
1904:
1900:
1898:
1895:
1892:
1890:
1886:
1883:
1880:
1879:
1875:
1873:
1871:
1868:
1865:
1862:
1859:
1858:
1854:
1850:
1848:Orthorhombic
1847:
1845:
1842:
1839:
1836:
1833:
1832:
1828:
1825:
1823:
1820:
1817:
1814:
1811:
1810:
1806:
1802:
1798:
1795:
1792:
1785:
1781:
1779:
1771:
1768:
1765:
1764:
1756:
1755:Ferroelectric
1753:
1751:
1748:
1746:
1744:
1737:
1734:
1731:
1730:
1726:
1723:
1721:
1718:
1716:
1712:
1709:
1706:
1705:
1701:
1698:
1695:
1692:
1690:
1686:
1683:
1680:
1679:
1675:
1672:
1670:
1667:
1664:
1661:
1658:
1657:
1649:
1646:
1643:
1640:
1637:
1634:
1631:
1630:
1626:
1622:
1619:
1616:
1613:
1611:
1607:
1604:
1601:
1600:
1596:
1592:
1590:
1587:
1584:
1581:
1578:
1575:
1572:
1571:
1567:
1565:Rhombohedral
1564:
1562:
1559:
1557:
1553:
1550:
1547:
1546:
1542:
1538:
1534:
1532:
1529:
1527:(at 350 MPa)
1523:
1520:
1518:
1514:
1511:
1508:
1507:
1504:
1502:
1499:
1497:
1495:
1491:
1489:
1481:
1478:
1475:
1474:
1471:
1468:
1465:
1462:
1460:
1456:
1453:
1450:
1449:
1446:
1443:
1440:
1437:
1435:
1431:
1428:
1425:
1424:
1420:
1417:
1414:
1411:
1408:NA (requires
1407:
1404:
1401:
1398:
1397:
1393:
1389:
1386:
1383:
1380:
1378:
1375:
1372:
1371:
1367:
1364:A metastable
1363:
1360:
1357:
1354:
1352:
1344:
1341:
1335:
1334:
1330:
1318:
1314:
1311:
1308:
1305:
1303:) (freezing)
1302:
1298:
1294:
1291:
1285:
1284:
1280:
1278:Crystal form
1277:
1274:
1271:
1268:
1265:
1262:
1261:
1258:
1256:
1246:
1229:
1223:
1220:
1217:
1214:
1206:
1198:
1194:
1190:
1184:
1181:
1175:
1172:
1169:
1148:
1145:
1140:
1132:
1128:
1124:
1118:
1113:
1109:
1099:
1082:
1079:
1076:
1070:
1067:
1064:
1050:
1041:
1040:, as before.
1025:
1017:
1013:
1009:
1003:
998:
995:
987:
983:
979:
973:
968:
964:
953:
937:
934:
922:
919:
903:
895:
892:
886:
882:
878:
872:
869:
866:
858:
855:and R is the
854:
834:
828:
824:
820:
814:
811:
808:
805:
802:
797:
789:
785:
781:
775:
772:
769:
766:
761:
757:
748:
743:
730:
725:
717:
713:
709:
703:
698:
694:
690:
682:
678:
674:
666:
662:
658:
654:
623:
607:
604:
592:
589:
564:
556:
554:
553:Linus Pauling
544:
527:
524:
521:
515:
512:
509:
506:
488:
483:
470:
466:
463:
459:
449:
445:
442:
435:
423:
415:
406:
402:
400:
396:
392:
388:
387:absolute zero
368:
364:
360:
356:
347:
338:
336:
332:
328:
324:
315:
306:
304:
300:
296:
292:
287:
284:
280:
276:
272:
268:
264:
260:
256:
252:
251:rapid cooling
248:
241:Amorphous ice
238:
232:
228:
219:
211:
209:
205:
201:
197:
193:
189:
181:
180:Linus Pauling
177:
174:The accepted
168:
156:
147:
145:
141:
136:
131:
121:
113:
111:
107:
103:
99:
98:phases of ice
91:
87:
86:phase diagram
83:
79:
69:
59:
53:
51:
46:
41:
37:
32:
31:
19:
12226:Tour skating
12026:Frost flower
11857:Major phases
11792:HDA in space
11773:Glassy Water
11743:
11720:
11685:
11661:
11640:
11588:
11584:
11574:
11539:
11533:
11523:
11480:
11476:
11470:
11458:. Retrieved
11447:
11435:. Retrieved
11429:
11419:
11392:
11388:
11378:
11357:
11332:
11328:
11322:
11295:
11291:
11281:
11269:. Retrieved
11255:
11243:. Retrieved
11228:
11217:. Retrieved
11202:
11185:
11181:
11158:. Retrieved
11154:
11145:
11120:
11116:
11103:
11070:
11066:
11024:
11020:
11014:
10973:
10969:
10963:
10936:
10932:
10922:
10895:
10891:
10881:
10838:
10834:
10828:
10801:
10797:
10787:
10760:
10756:
10746:
10729:
10725:
10719:
10694:
10690:
10684:
10675:
10641:
10637:
10630:
10587:
10583:
10577:
10544:
10540:
10534:
10510:
10506:
10479:
10448:(1): 51–61.
10445:
10441:
10435:
10402:
10398:
10392:
10365:
10361:
10351:
10326:
10322:
10286:
10282:
10276:
10251:
10247:
10237:
10202:
10198:
10170:19 September
10168:. Retrieved
10151:(6): 40–46.
10148:
10144:
10131:
10119:. Retrieved
10110:
10100:
10081:
10077:
10023:
10019:
10006:
9955:
9951:
9941:
9916:
9912:
9906:
9894:. Retrieved
9890:the original
9861:
9857:
9847:
9822:
9818:
9812:
9800:. Retrieved
9791:
9781:
9769:. Retrieved
9760:
9750:
9707:
9703:
9693:
9666:
9662:
9652:
9630:(1): 51–61.
9627:
9623:
9617:
9592:
9588:
9582:
9537:
9533:
9519:
9495:(1): 60–76.
9492:
9488:
9478:
9465:
9451:
9426:
9422:
9409:
9376:
9372:
9362:
9321:
9317:
9311:
9291:
9284:
9273:the original
9259:
9245:cite journal
9202:
9198:
9188:
9174:cite journal
9131:
9127:
9117:
9103:cite journal
9068:
9064:
9054:
9011:
9007:
8993:
8958:
8954:
8944:
8932:. Retrieved
8928:
8918:
8907:. Retrieved
8895:
8873:
8841:
8799:
8795:
8782:
8771:. Retrieved
8759:
8705:
8699:
8672:
8639:
8635:
8622:
8569:
8565:
8527:. Retrieved
8516:
8471:
8467:
8401:
8397:
8390:
8339:
8335:
8325:
8274:
8270:
8264:
8221:
8217:
8211:
8160:
8156:
8150:
8140:13 September
8138:. Retrieved
8128:
8118:
8085:
8081:
8075:
8030:
8026:
8016:
7983:
7979:
7973:
7948:
7944:
7938:
7903:
7899:
7889:
7848:
7844:
7838:
7805:
7801:
7795:
7787:
7782:
7755:
7751:
7709:
7705:
7699:
7656:
7652:
7646:
7621:
7617:
7603:
7578:
7574:
7568:
7543:
7539:
7533:
7508:
7504:
7498:
7486:. Retrieved
7479:the original
7466:
7462:
7445:
7404:
7398:
7365:
7359:
7345:
7319:
7315:
7309:
7277:
7273:
7263:
7231:
7227:
7217:
7201:
7197:
7190:Loerting, T.
7183:
7159:
7155:
7145:
7121:
7117:
7107:
7075:
7071:
7061:
7044:
7037:
7021:
7017:
7007:
6991:
6987:
6977:
6935:
6931:
6921:
6897:
6893:
6883:
6859:
6855:
6845:
6813:
6809:
6799:
6785:cite journal
6742:
6738:
6717:Live Science
6716:
6666:
6662:
6598:
6594:
6564:
6495:(1): 13394.
6492:
6488:
6450:. Retrieved
6448:. 2015-03-27
6445:
6382:
6378:
6372:
6338:
6332:
6322:
6274:
6270:
6251:11 September
6249:. Retrieved
6241:Science News
6240:
6230:
6216:cite journal
6175:
6171:
6161:
6148:
6084:
6080:
6062:
6049:
6039:
5994:
5990:
5980:
5961:
5952:
5942:
5909:
5905:
5899:
5874:
5870:
5836:
5832:
5826:
5785:
5781:
5758:
5713:
5709:
5699:
5672:
5668:
5658:
5645:
5635:
5626:
5621:
5596:
5592:
5586:
5561:
5557:
5547:
5534:
5524:
5499:
5495:
5489:
5476:
5422:
5418:
5411:
5398:
5388:
5375:
5365:
5352:
5327:. Retrieved
5308:
5255:
5251:
5242:
5209:
5205:
5199:
5166:
5162:
5156:
5113:
5109:
5067:
5063:
5038:. Retrieved
5032:
5022:
5013:
5004:
4971:
4967:
4961:
4918:
4914:
4904:
4871:
4867:
4842:Live Science
4841:
4785:
4781:
4775:
4748:
4744:
4734:
4691:
4687:
4677:
4636:
4632:
4572:
4568:
4544:. Retrieved
4539:
4529:
4496:
4492:
4482:
4449:
4445:
4435:
4407:
4400:
4383:
4379:
4370:
4327:
4323:
4313:
4288:
4284:
4278:
4229:
4225:
4167:
4163:
4149:
4135:cite journal
4092:
4088:
4078:
4037:
4033:
4027:
4015:. Retrieved
4008:the original
3995:
3983:. Retrieved
3969:
3934:
3930:
3920:
3895:
3891:
3885:
3876:
3866:
3815:
3811:
3805:
3765:
3759:
3691:
3687:
3677:
3626:
3622:
3612:
3571:
3567:
3561:
3536:
3532:
3526:
3512:cite journal
3477:
3473:
3427:
3423:
3369:
3365:
3359:
3347:. Retrieved
3343:the original
3332:
3299:
3295:
3289:
3264:
3260:
3254:
3234:
3211:close-packed
3192:
3187:Cat's Cradle
3185:
3178:
3159:
3139:
3130:
3122:tiger stripe
3114:
3099:
3090:50000 Quaoar
3086:
3073:
3064:
3052:
3040:
3036:
3028:
3019:
3010:
2998:
2991:
2965:
2942:
2922:
2915:
2895:
2872:
2856:
2841:
2820:liquid water
2807:
2803:
2793:
2753:
2751:
2731:
2722:
2674:
2670:
2667:
2663:
2658:
2646:
2626:
2616:
2598:
2583:
2550:
2527:
2444:
2384:
2376:
2358:
2354:
2350:
2342:
2338:
2334:
2331:
2321:
2315:
2309:rather than
2303:
2286:
2282:
2275:
2263:
2243:
2236:
2224:triple point
2212:
2193:
2164:
2155:
2141:reproducibly
2140:
2137:
2133:
2120:
2099:
2078:
2058:
1971:
1888:
1773:
1750:Orthorhombic
1714:
1688:
1609:
1555:
1537:permittivity
1516:
1501:Rhombohedral
1487:
1458:
1433:
1346:
1295:273.15
1252:
1249:Known phases
1100:
1055:
954:
744:
565:
557:
550:
547:Calculations
479:
465:
446:
443:
411:
359:triple point
355:water vapour
352:
337:properties.
322:
320:
291:hyperuniform
288:
274:
244:
220:
212:
192:tessellating
173:
134:
129:
127:
114:
97:
95:
63:
47:
45:lead section
12396:Pleistocene
12110:Ice-related
12021:Frost heave
11955:Stalactites
11759:'s website.
11460:24 December
11245:January 23,
10898:(1): L101.
10644:: L27–L30,
9205:(1): 3162.
9134:(1): 1128.
7758:(16): n/a.
7546:(5): 1442.
6745:(1): 1129.
6446:ZME Science
5997:(1): 3161.
5782:APS Physics
5329:December 6,
5309:Ice Physics
4542:(in German)
3164:as well as
2988:Outer space
2977:molar ratio
2945:compression
2546:ionic water
2530:crystallize
2447:heavy water
1949:water vapor
1922:Square ice
1826:Monoclinic
1796:Tetragonal
1784:gigapascals
1699:Tetragonal
1673:Tetragonal
1620:Tetragonal
1410:shear force
1309:0.917 g/cm
1044:Refinements
430: J/mol
412:The latent
399:picoseconds
271:outer space
231:tetrahedral
12473:Cryosphere
12468:Glaciology
12457:Categories
12442:Wiktionary
12386:Glaciology
12341:Other uses
12211:Ice racing
12206:Ice hockey
12181:Iceboating
12112:activities
11883:Formations
11874:Superionic
11632:Ice phases
11490:2103.09035
11456:. Llnl.gov
11437:5 February
11219:2018-04-22
10939:(2): L43.
10804:(5): 122.
10078:Challenges
9965:1503.01830
9199:Nat Commun
9128:Nat Commun
9000:Loerting T
8909:2018-02-13
8773:2019-05-13
8579:1909.03400
8572:(1): 464.
8529:2022-09-11
8411:1607.04794
8284:1801.03812
8231:1507.02665
8135:Condé Nast
7054:1752797359
6945:1701.05398
6739:Nat Commun
6502:1607.07617
6452:2018-05-02
5040:4 February
4717:2429/33770
4582:1907.02915
4546:2021-02-18
4291:(8): 515.
4156:Loerting T
4089:Nat Commun
3636:1705.09961
3246:References
2875:inclusions
2863:deposition
2659:disordered
2538:conductive
2415:metastable
2264:Ice XI is
2070:liquid air
1990:Ice XVIII
1982:Hexagonal
1896:0.81 g/cm
1644:1.65 g/cm
1617:1.31 g/cm
1589:Monoclinic
1539:at 117. A
1531:Tetragonal
1342:1943/2020
1312:Hexagonal
456:See also:
279:micrometer
229:with near
144:metastable
140:metastable
12463:Water ice
12153:Sculpture
11969:Phenomena
11515:232240463
11369:1007.1792
11349:1520-6106
11095:140162310
10668:0004-637X
10622:122950585
10427:121008219
9742:206662912
9669:: 78–82.
9046:195764029
8904:0362-4331
8768:1059-1028
8738:256703104
8436:0021-9606
8364:2045-2322
8309:0021-9606
8256:0009-2614
8170:0906.2489
8102:1520-6106
8008:121266617
7930:204990667
7691:102581583
7302:245597764
6639:256768272
6392:1412.7498
5934:0021-9606
5818:247530544
5516:0036-8075
5447:0021-9606
5148:122950585
4810:0028-0836
4669:218913209
4615:195820566
4521:0370-1328
4474:0022-2488
4362:1098-0121
4270:256504172
4254:0036-8075
4095:: 16189.
4017:6 January
3985:31 August
3961:122365938
3825:1009.4722
3742:221746507
3726:0021-9606
3470:O Ice Ih"
3195:ice giant
3174:Enaiposha
3168:(such as
3117:Enceladus
3096:Icy moons
2804:ice one h
2796:biosphere
2706:×
2696:×
2650:deuterium
2613:ice giant
2596:lattice.
2520:conductor
2492:, H ions
2441:Cubic ice
1964:Ice XVII
1812:Ice XIII
1659:Ice VIII
1623:Exhibits
1595:molecules
1525:1.16 g/cm
1331:of 1.31.
1317:biosphere
1224:
1185:×
1176:
1119:×
1080:±
1071:
974:×
935:−
920:−
904:⋅
873:
815:
776:
525:±
516:
458:Ice rules
395:superheat
110:amorphous
50:summarize
12420:Category
12378:Ice ages
12332:Yakhchāl
12312:Icehouse
12138:Climbing
12133:Blocking
12128:Blasting
12046:Hair ice
11996:Crystals
11727:Archived
11615:22127059
11566:21343921
11239:Archived
11213:Archived
11160:25 April
11049:10348736
10998:15592406
10873:35561353
10523:Archived
10513:: 1009.
10246:O ice".
10115:Archived
10084:(1): 3.
9990:25912948
9950:O ice".
9896:22 April
9886:15268170
9802:12 March
9796:Archived
9771:March 8,
9765:Archived
9734:29590042
9574:23236184
9511:25380218
9401:17748273
9346:15758996
9237:34039987
9166:33602946
9095:31972078
9038:31257365
9002:(2019).
8985:30713649
8955:Chem Sci
8874:Phys.org
8824:15903935
8664:10038311
8614:32015342
8538:cite web
8508:31182582
8444:27908115
8382:27375120
8317:29960300
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8195:19792330
8110:16853726
8067:21321232
7965:97894870
7881:31673433
7873:22009223
7830:21405174
7488:24 April
7437:38999963
7429:11847334
7256:21946782
7100:96109290
7050:ProQuest
6970:13662778
6962:28323429
6876:26595233
6838:54544973
6777:33602936
6693:29780552
6663:Chem Sci
6631:31068720
6537:27819265
6417:25810206
6357:19585976
6299:25503235
6245:Archived
6208:44522271
6200:16556840
6117:44522271
6109:16556840
6031:34039991
5750:16591242
5613:20022754
5455:33832256
5280:59485355
4996:11542399
4953:33622340
4945:11539415
4896:11539186
4726:16482260
4661:32461682
4607:32015533
4262:36730416
4202:51969440
4194:30101255
4158:(2018).
4127:29923547
4062:16407948
3979:Archived
3858:15761164
3850:21231184
3790:19624212
3734:32933306
3669:44864111
3661:29341697
3604:43859537
3596:11743196
3553:20022754
3504:30444387
3394:17741864
3197:planets
3182:ice-nine
3110:Callisto
3106:Ganymede
2930:desorbed
2879:diamonds
2810:). Ice I
2798:is ice I
2745:O into D
2661:ice VI.
2561:diamonds
2365:Ice XVII
2219:hydrogen
2011:Ice XIX
1930:graphene
1881:Ice XVI
1855:doping.
1834:Ice XIV
1766:Ice XII
1632:Ice VII
1509:Ice III
1361:Diamond
1327:. Has a
1319:is ice I
1299:(0
1275:Density
1255:Bridgman
482:hydrogen
335:metallic
66:May 2024
12302:Cutting
12276:Pykrete
12196:Cycling
12191:Curling
12186:Cricket
12158:Skating
12148:Rafting
12143:Fishing
12123:Bathing
12066:Nucleus
12051:Jacking
12030:sea ice
12028: (
11960:Volcano
11924:calving
11922: (
11920:Iceberg
11915:Glacier
11777:Science
11731:YouTube
11593:Bibcode
11591:: 563.
11544:Bibcode
11495:Bibcode
11397:Bibcode
11300:Bibcode
11271:7 April
11190:Bibcode
11125:Bibcode
11075:Bibcode
11029:Bibcode
11021:Science
11006:4334385
10978:Bibcode
10941:Bibcode
10900:Bibcode
10853:Bibcode
10806:Bibcode
10765:Bibcode
10734:Bibcode
10732:: 659.
10699:Bibcode
10646:Bibcode
10592:Bibcode
10590:: 389.
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10549:Bibcode
10515:Bibcode
10450:Bibcode
10407:Bibcode
10370:Bibcode
10331:Bibcode
10329:: 353.
10291:Bibcode
10256:Bibcode
10207:Bibcode
10153:Bibcode
10121:30 July
10048:2741633
10040:3043536
9998:7736338
9970:Bibcode
9921:Bibcode
9866:Bibcode
9827:Bibcode
9761:Science
9712:Bibcode
9704:Science
9671:Bibcode
9632:Bibcode
9597:Bibcode
9565:3535660
9542:Bibcode
9431:Bibcode
9381:Bibcode
9373:Science
9354:4427815
9326:Bibcode
9228:8155070
9207:Bibcode
9157:7892819
9136:Bibcode
9086:7008458
9016:Bibcode
8976:6334492
8929:Science
8804:Bibcode
8730:1542614
8710:Bibcode
8644:Bibcode
8605:6997176
8584:Bibcode
8499:6600908
8476:Bibcode
8416:Bibcode
8373:4931510
8344:Bibcode
8289:Bibcode
8236:Bibcode
8175:Bibcode
8058:3048133
8035:Bibcode
7988:Bibcode
7908:Bibcode
7853:Bibcode
7810:Bibcode
7760:Bibcode
7714:Bibcode
7671:Bibcode
7626:Bibcode
7612:O ice I
7583:Bibcode
7548:Bibcode
7513:Bibcode
7409:Bibcode
7405:Science
7390:4265919
7370:Bibcode
7324:Bibcode
7282:Bibcode
7236:Bibcode
7164:Bibcode
7126:Bibcode
7080:Bibcode
6902:Bibcode
6818:Bibcode
6768:7893076
6747:Bibcode
6684:5942039
6623:1568026
6603:Bibcode
6528:5103070
6507:Bibcode
6425:4462633
6397:Bibcode
6307:4464711
6279:Bibcode
6180:Bibcode
6172:Science
6089:Bibcode
6081:Science
6022:8154907
5999:Bibcode
5914:Bibcode
5879:Bibcode
5841:Bibcode
5810:1989084
5790:Bibcode
5718:Bibcode
5677:Bibcode
5566:Bibcode
5496:Science
5427:Bibcode
5260:Bibcode
5234:4274283
5214:Bibcode
5191:4241205
5171:Bibcode
5118:Bibcode
5116:: 389.
5092:4265281
5072:Bibcode
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4876:Bibcode
4868:Science
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4753:Bibcode
4696:Bibcode
4641:Bibcode
4587:Bibcode
4501:Bibcode
4454:Bibcode
4342:Bibcode
4293:Bibcode
4234:Bibcode
4226:Science
4172:Bibcode
4118:6026910
4097:Bibcode
4070:4404036
4042:Bibcode
3939:Bibcode
3900:Bibcode
3830:Bibcode
3770:Bibcode
3696:Bibcode
3641:Bibcode
3576:Bibcode
3568:Science
3482:Bibcode
3466:O and D
3432:Bibcode
3418:O Ice I
3414:O and D
3374:Bibcode
3366:Science
3349:12 July
3324:4382067
3304:Bibcode
3269:Bibcode
3203:Neptune
3170:Awohali
3149:and on
3147:Neptune
3136:Planets
2887:mineral
2754:in-situ
2723:in situ
2671:in situ
2623:Ice XIX
2494:diffuse
2423:helical
2161:Ice VII
2143:; when
1940:Square
1915:tension
1860:Ice XV
1732:Ice XI
1681:Ice IX
1602:Ice VI
1548:Ice IV
1476:Ice II
1392:viscous
1083:0.00015
1077:1.50685
851:is the
391:changed
383:
371:
303:glasses
186:is the
82:Log-lin
18:Ice one
12435:
12424:
12413:
12307:Icebox
12266:Palace
12251:Bridge
12168:Sports
12086:Slurry
12061:Needle
12011:Frazil
11930:Icicle
11890:Anchor
11767:Nature
11722:Seeker
11669:
11648:
11613:
11564:
11513:
11347:
11117:Icarus
11093:
11047:
11004:
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10970:Nature
10871:
10691:Icarus
10666:
10620:
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10541:Nature
10425:
10199:Icarus
10046:
10038:
9996:
9988:
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9318:Nature
9299:
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9225:
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8973:
8934:17 May
8902:
8842:Nature
8822:
8766:
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7900:Nature
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7828:
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7361:Nature
7300:
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7098:
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6629:
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6595:Nature
6535:
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6379:Nature
6355:
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6271:Nature
6206:
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6029:
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5932:
5816:
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5748:
5741:300465
5738:
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5232:
5206:Nature
5189:
5163:Nature
5146:
5090:
5064:Nature
5014:Nature
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4951:
4943:
4894:
4816:
4808:
4782:Nature
4724:
4667:
4659:
4613:
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4472:
4423:
4360:
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4260:
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4034:Nature
3959:
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3848:
3788:
3740:
3732:
3724:
3667:
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3602:
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3551:
3502:
3392:
3322:
3296:Nature
3220:carbon
3199:Uranus
3172:, and
3162:Europa
3155:Charon
3143:Uranus
3108:, and
3102:Europa
3070:Comets
2925:adsorb
2891:mantle
2639:, and
2617:Nature
2565:lasers
2272:Ice XV
2174:Ice XI
2117:Ice IV
2055:Ice II
1957:helium
1935:10GPa
1801:sphere
1724:Cubic
1707:Ice X
1647:Cubic
1576:1900s
1573:Ice V
1376:1930s
1263:Phase
847:where
745:Using
644:2 = 16
380:273.16
367:kelvin
365:. The
196:oxygen
130:higher
124:Theory
12358:Cream
12348:Chips
12327:Trade
12261:Igloo
12256:Hotel
12176:Bandy
12101:Storm
12091:Slush
12081:Shuga
12076:Shove
12036:Glaze
12016:Frost
11991:Clear
11981:Black
11950:Spike
11945:Sheet
11910:Field
11850:water
11846:state
11843:solid
11779:, on
11775:from
11765:from
11511:S2CID
11485:arXiv
11364:arXiv
11113:(PDF)
11091:S2CID
11002:S2CID
10869:S2CID
10843:arXiv
10618:S2CID
10565:S2CID
10526:(PDF)
10503:(PDF)
10423:S2CID
10195:(PDF)
10141:(PDF)
10044:S2CID
10016:(PDF)
9994:S2CID
9960:arXiv
9738:S2CID
9419:(PDF)
9350:S2CID
9276:(PDF)
9269:(PDF)
9042:S2CID
8792:(PDF)
8760:Wired
8734:S2CID
8632:(PDF)
8574:arXiv
8406:arXiv
8279:arXiv
8226:arXiv
8199:S2CID
8165:arXiv
8130:Wired
8004:S2CID
7961:S2CID
7926:S2CID
7877:S2CID
7687:S2CID
7661:arXiv
7482:(PDF)
7459:(PDF)
7433:S2CID
7386:S2CID
7298:S2CID
7096:S2CID
6966:S2CID
6940:arXiv
6834:S2CID
6635:S2CID
6497:arXiv
6421:S2CID
6387:arXiv
6303:S2CID
6204:S2CID
6113:S2CID
5814:S2CID
5609:JSTOR
5276:S2CID
5230:S2CID
5187:S2CID
5144:S2CID
5088:S2CID
4949:S2CID
4814:S2CID
4665:S2CID
4611:S2CID
4577:arXiv
4332:arXiv
4266:S2CID
4198:S2CID
4066:S2CID
4011:(PDF)
4004:(PDF)
3957:S2CID
3854:S2CID
3820:arXiv
3738:S2CID
3665:S2CID
3631:arXiv
3600:S2CID
3549:JSTOR
3320:S2CID
3226:Notes
3151:Pluto
3126:Titan
2510:anode
2429:(6.10
2405:and H
2244:Ice I
2087:0.000
2014:2018
1993:2019
1967:2016
1925:2014
1884:2014
1863:2009
1837:2006
1815:2006
1782:0.55
1769:1996
1735:1972
1684:1968
1662:1966
1635:1937
1605:1912
1551:1900
1512:1900
1479:1900
1454:1996
1429:1984
1402:2023
1366:cubic
1336:Ice I
1286:Ice I
1230:1.504
267:metal
135:below
106:water
12368:Pack
12363:Cube
12353:Core
12322:Pick
12295:Work
12286:Road
12281:Rink
12271:Pier
12096:Snow
12071:Rime
12056:Névé
12041:Hail
12001:Firn
11905:Dune
11900:Cave
11841:The
11757:LSBU
11667:ISBN
11646:ISBN
11611:PMID
11562:PMID
11462:2010
11439:2018
11345:ISSN
11273:2012
11247:2010
11162:2024
11045:PMID
10994:PMID
10664:ISSN
10172:2012
10123:2012
10036:PMID
9986:PMID
9898:2012
9882:PMID
9804:2018
9773:2018
9730:PMID
9570:PMID
9507:PMID
9397:PMID
9342:PMID
9297:ISBN
9251:link
9233:PMID
9180:link
9162:PMID
9109:link
9091:PMID
9034:PMID
8981:PMID
8936:2024
8900:ISSN
8820:PMID
8764:ISSN
8726:OSTI
8660:PMID
8610:PMID
8544:link
8504:PMID
8440:PMID
8432:ISSN
8378:PMID
8360:ISSN
8313:PMID
8305:ISSN
8252:ISSN
8191:PMID
8142:2009
8106:PMID
8098:ISSN
8063:PMID
7869:PMID
7826:PMID
7490:2012
7425:PMID
7252:PMID
6958:PMID
6872:PMID
6791:link
6773:PMID
6689:PMID
6627:PMID
6619:OSTI
6533:PMID
6413:PMID
6353:PMID
6295:PMID
6253:2009
6222:link
6196:PMID
6105:PMID
6027:PMID
5930:ISSN
5806:OSTI
5746:PMID
5512:ISSN
5451:PMID
5443:ISSN
5331:2014
5318:ISBN
5042:2023
4992:PMID
4941:PMID
4892:PMID
4806:ISSN
4722:PMID
4657:PMID
4603:PMID
4517:ISSN
4470:ISSN
4421:ISBN
4358:ISSN
4258:PMID
4250:ISSN
4190:PMID
4141:link
4123:PMID
4058:PMID
4019:2019
3987:2012
3846:PMID
3786:PMID
3730:PMID
3722:ISSN
3657:PMID
3592:PMID
3518:link
3500:PMID
3390:PMID
3351:2017
3201:and
3153:and
3145:and
2971:to H
2852:halo
2675:i.e.
2353:and
2335:Pmmn
2325:HClO
2322:i.e.
2089:0545
1492:300
896:3.37
528:0.02
522:1.50
480:The
460:and
104:for
96:The
12246:Bar
12006:Fog
11940:Sea
11935:Jam
11895:Cap
11848:of
11833:Ice
11755:at
11601:doi
11552:doi
11503:doi
11405:doi
11393:184
11337:doi
11333:102
11308:doi
11296:652
11133:doi
11121:129
11083:doi
11071:109
11037:doi
11025:284
10986:doi
10974:432
10949:doi
10937:422
10908:doi
10896:519
10861:doi
10839:122
10814:doi
10802:145
10773:doi
10761:328
10730:286
10707:doi
10695:201
10654:doi
10642:355
10608:hdl
10600:doi
10588:401
10557:doi
10545:344
10511:290
10458:doi
10415:doi
10378:doi
10366:271
10339:doi
10327:401
10299:doi
10264:doi
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10223:hdl
10215:doi
10203:193
10161:doi
10086:doi
10028:doi
9978:doi
9929:doi
9917:976
9874:doi
9862:120
9835:doi
9823:294
9720:doi
9708:359
9679:doi
9667:127
9640:doi
9605:doi
9560:PMC
9550:doi
9538:109
9497:doi
9439:doi
9389:doi
9377:211
9334:doi
9322:434
9223:PMC
9215:doi
9152:PMC
9144:doi
9081:PMC
9073:doi
9024:doi
8971:PMC
8963:doi
8846:doi
8812:doi
8718:doi
8652:doi
8600:PMC
8592:doi
8494:PMC
8484:doi
8472:116
8424:doi
8402:145
8368:PMC
8352:doi
8297:doi
8275:148
8244:doi
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8053:PMC
8043:doi
8031:108
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7949:102
7916:doi
7904:397
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7818:doi
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7768:doi
7722:doi
7710:972
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7634:doi
7591:doi
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7417:doi
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7088:doi
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7026:doi
7022:107
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6950:doi
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6864:doi
6860:120
6826:doi
6763:PMC
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6671:doi
6611:doi
6599:569
6523:PMC
6515:doi
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5726:doi
5685:doi
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5574:doi
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5500:166
5435:doi
5423:154
5268:doi
5222:doi
5210:384
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4919:473
4884:doi
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4712:hdl
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4509:doi
4462:doi
4413:doi
4388:doi
4350:doi
4301:doi
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4230:379
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4105:doi
4050:doi
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3838:doi
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3649:doi
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