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Gyrolite

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by synchrotron X-rays diffraction in hydrothermal synthesis of cement. Synthetic gyrolite has also a large specific surface and could enter industrial applications as oil absorber. Gyrolite globular rosettes resemble that of shlykovite, a new natural crystalline C-S-H mineral characterized in 2010
946:"Patent application number: 15/034,912. Inventors: Yuuta Tsumura (Naruto-shi), Kazuki Kamai (Naruto-shi), Yukinori Konishi (Naruto-shi), Kazuhiko Tamagawa (Naruto-shi). Powdered gyrolite-type calcium silicate having high oil absorbency and large particle diameter, and production method therefor" 1210:
Geng, Guoqing; Shi, Zhenguo; Leemann, Andreas; Borca, Camelia; Huthwelker, Thomas; Glazyrin, Konstantin; Pekov, Igor V.; Churakov, Sergey; Lothenbach, Barbara; Dähn, Rainer; Wieland, Erich (2020-03-01).
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Shawa, S.; Henderson, C. M. B.; Clark, S. M. (2001). "Hydrothermal synthesis of cement phases: An in situ synchrotron, energy dispersive diffraction study of reaction kinetics and mechanisms".
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Gyrolite can be synthesized in the laboratory, or industrially, by hydrothermal reaction in the temperature range 150 – 250 °C by reacting CaO and amorphous SiO
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Pekov, I. V.; Zubkova, N. V.; Filinchuk, Ya. E.; Chukanov, N. V.; Zadov, A. E.; Pushcharovsky, D. Yu.; Gobechiya, E. R. (2010-12-01). "Shlykovite KCa ¡ 3 H
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salts or not. At temperature lower than 150 °C, the reaction rate is very slow. At temperature above 250 °C, gyrolite recrystallizes into 1.13 nm
1385: 960: 1120:"Application of micro X-ray diffraction to investigate the reaction products formed by the alkali–silica reaction in concrete structures" 961:"Crystal structures of shlykovite and cryptophyllite: comparative crystal chemistry of phyllosilicate minerals of the mountainite family" 667: 449:. Gyrolite is found in Scotland, Ireland; Italy, Faroe Islands, Greenland, India, Japan, USA, Canada and various other localities. 820:
Siauciunas, R.; Baltakys, K. (2004). "Formation of gyrolite during hydrothermal synthesis in the mixtures of CaO and amorphous SiO
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Zubkova, Natalia V.; Filinchuk, Yaroslav E.; Pekov, Igor V.; Pushcharovsky, Dmitry Yu; Gobechiya, Elena R. (2010-08-01).
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Dähn, R.; Arakcheeva, A.; Schaub, Ph.; Pattison, P.; Chapuis, G.; Grolimund, D.; Wieland, E.; Leemann, A. (2016-01-01).
1444: 1213:"Atomistic structure of alkali-silica reaction products refined from X-ray diffraction and micro X-ray absorption data" 801: 776: 1075:
De Ceukelaire, L. (1991-05-01). "The determination of the most common crystalline alkali-silica reaction product".
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Baltakys, K.; Siauciunas, R. (2010). "Influence of gypsum additive on the gyrolite formation process".
108: 28: 1404: 1212: 1161:"Synthesis of alkali-silica reaction product structurally identical to that formed in field concrete" 1434: 1409: 458: 1276: 377: 365: 88: 489:
O, which is consistent with the general formulation given here above, but does not consider the
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and also to mountainite and rhodesite, other crystalline ASR products of the same family.
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Shi, Zhenguo; Leemann, Andreas; Rentsch, Daniel; Lothenbach, Barbara (2020-05-01).
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O, new mineral species from the Khibiny alkaline pluton, Kola Peninsula, Russia".
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The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science
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Lea's chemistry of cement and concrete. See chapter 14.2 Oilwell cement, p. 807
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Gyrolite is also one of the rare phases detected in situ along with
522: 498: 452: 446: 427: 410: 373: 958: 387:. These formations can be glassy, dull or fibrous in appearance. 494: 442: 376:. It is most commonly found as spherical or radial formations in 279: 583: â€“ Rock-forming minerals with predominantly silicate anions 434:(γῦρος), based on the round form in which it is commonly found. 1285:
Mineralogical Magazine and Journal of the Mineralogical Society
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Spherical colorless gyrolite crystals from Malad quarry, India
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Spherical brown gyrolite crystals from Lonavala quarry, India
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Description and analysis of gyrolite, a new mineral species
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Mackay, A. L.; Taylor, H. F. W. (March 1953). "Gyrolite".
577: â€“ Igneous rock with more than 50% carbonate minerals 585:
Pages displaying short descriptions of redirect targets
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Rare phyllosilicate mineral crystallizing in spherules
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and is named from the ancient Greek word for circle,
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It was first described in 1851 for an occurrence at
364:(basic sodium calcium silicate hydrate: N-C-S-H, in 1209: 893: 405: 887: 858: 819: 592: â€“ Calcium aluminium silicate hydrate mineral 1068: 815: 813: 794:Cement chemistry. See gyrolite at pp. 344 and 348 1396: 743:"Gyrolite (Hydrated Calcium Silicate Hydroxide)" 453:Occurrence in hardened cement paste and concrete 810: 1379: 1074: 521:. It could also form in CEM III cement-based 1282: 952: 852: 545:, in saturated steam in the presence of CaSO 938: 737: 735: 1386: 1372: 1005: 723: 437:Minerals associated with gyrolite include 1203: 1186: 1176: 1135: 1111: 640: 532: 372:. Gyrolite is also often associated with 1152: 732: 719: 717: 702: 700: 698: 696: 694: 668:"Gyrolite in the Handbook of Mineralogy" 409: 189:White, colorless, green, yellow or brown 176:β = 91.51°, Îł = 120.01°; Z = 4 766: 1397: 791: 714: 691: 662: 660: 511:ground granulated blast furnace slags 457:Gyrolite is also mentioned as a rare 1338: 617:"IMA–CNMNC approved mineral symbols" 614: 13: 1331:; p. 7: Centrallasite = Gyrolite). 1261: 657: 14: 1461: 1342: 985:10.1127/0935-1221/2010/0022-2041 406:Discovery and natural occurrence 274:Transparent, translucent, opaque 27: 1229:10.1016/j.cemconres.2019.105958 1137:10.1016/j.cemconres.2015.07.012 873:10.1016/j.cemconres.2009.11.004 838:10.1016/j.cemconres.2004.03.009 745:. Galleries.com. Archived from 529:(ASR) at elevated temperature. 1350:This article about a specific 1305:10.1180/minmag.1953.030.220.10 965:European Journal of Mineralogy 785: 760: 608: 1: 601: 1358:. You can help Knowledge by 1217:Cement and Concrete Research 1178:10.1016/j.matdes.2020.108562 1124:Cement and Concrete Research 861:Cement and Concrete Research 826:Cement and Concrete Research 368:) belonging to the class of 7: 792:Taylor, Harry F.W. (1997). 568: 174:c = 22.4 ; Îą = 95.71° 10: 1466: 1337: 390:Gyrolite is also known as 1445:Minerals in space group 2 1046:10.1134/S1075701510080088 916:10.1080/08957950108206179 328: 318: 296: 288: 278: 268: 258: 233: 223: 213: 203: 193: 185: 180: 166: 151: 129: 117: 107: 97: 87: 53: 43: 38: 26: 21: 1077:Materials and Structures 459:calcium silicate hydrate 199:Compact, lamellar, platy 1267:Anderson Thomas (1851) 1026:Geology of Ore Deposits 767:Hewlett, Peter (2003). 726:"Gyrolite Mineral Data" 491:isomorphic substitution 366:cement chemist notation 1450:Silicate mineral stubs 1165:Materials & Design 1016:O and cryptophyllite K 896:High Pressure Research 621:Mineralogical Magazine 533:Hydrothermal synthesis 527:alkali-silica reaction 445:and many of the other 415: 378:hydrothermally altered 1325:American Mineralogist 413: 99:Strunz classification 1327:, Vol. 44, 464–470 ( 1319:Fleischer M. (1959) 1275:, Vol. 1, 111–113. ( 1297:1953MinM...30...80M 1038:2010GeoOD..52..767P 977:2010EJMin..22..547Z 908:2001HPR....20..311S 642:10.1180/mgm.2021.43 633:2021MinM...85..291W 615:Warr, L.N. (2021). 172:a = 9.74, b = 9.74 109:Dana classification 1440:Triclinic minerals 1415:Aluminium minerals 1089:10.1007/BF02472981 796:. Thomas Telford. 416: 289:Optical properties 1367: 1366: 1321:New mineral names 832:(11): 2029–2036. 335: 334: 147: 1457: 1405:Calcium minerals 1388: 1381: 1374: 1352:silicate mineral 1346: 1339: 1316: 1255: 1254: 1252: 1251: 1207: 1201: 1200: 1190: 1180: 1156: 1150: 1149: 1139: 1115: 1109: 1108: 1072: 1066: 1065: 1009: 1003: 1002: 1000: 999: 956: 950: 949: 942: 936: 935: 902:(1–6): 311–324. 891: 885: 884: 856: 850: 849: 817: 808: 807: 789: 783: 782: 764: 758: 757: 755: 754: 739: 730: 729: 724:Dave Barthelmy. 721: 712: 711: 704: 689: 688: 686: 685: 679: 673:. Archived from 672: 664: 655: 654: 644: 612: 596:List of minerals 586: 362:silicate mineral 298:Refractive index 264:Vitreous, pearly 254: 253: 249: 246: 239: 219:Perfect on {001} 162: 141: 138: 60: 59:(repeating unit) 31: 19: 18: 1465: 1464: 1460: 1459: 1458: 1456: 1455: 1454: 1435:Phyllosilicates 1410:Sodium minerals 1395: 1394: 1393: 1392: 1335: 1264: 1262:Further reading 1259: 1258: 1249: 1247: 1208: 1204: 1157: 1153: 1116: 1112: 1073: 1069: 1023: 1019: 1015: 1010: 1006: 997: 995: 957: 953: 944: 943: 939: 892: 888: 857: 853: 823: 818: 811: 804: 790: 786: 779: 765: 761: 752: 750: 741: 740: 733: 722: 715: 706: 705: 692: 683: 681: 677: 670: 666: 665: 658: 613: 609: 604: 584: 581:Phyllosilicates 571: 548: 540: 535: 517:) activated by 507:crystal lattice 488: 484: 480: 476: 472: 468: 455: 408: 396:glimmer zeolite 370:phyllosilicates 359: 355: 351: 347: 343: 313: 309: 305: 251: 247: 244: 242: 237: 175: 173: 160: 140: 136: 82: 78: 74: 70: 66: 58: 57: 34: 17: 12: 11: 5: 1463: 1453: 1452: 1447: 1442: 1437: 1432: 1427: 1422: 1417: 1412: 1407: 1391: 1390: 1383: 1376: 1368: 1365: 1364: 1347: 1333: 1332: 1317: 1291:(220): 80–92. 1280: 1263: 1260: 1257: 1256: 1202: 1151: 1110: 1083:(3): 169–171. 1067: 1032:(8): 767–777. 1021: 1017: 1013: 1004: 971:(4): 547–555. 951: 948:. Nov 7, 2014. 937: 886: 867:(3): 376–383. 851: 821: 809: 802: 784: 777: 759: 731: 713: 690: 656: 627:(3): 291–320. 606: 605: 603: 600: 599: 598: 593: 587: 578: 570: 567: 546: 538: 534: 531: 486: 482: 478: 474: 470: 466: 454: 451: 407: 404: 385:basaltic tuffs 357: 353: 349: 345: 341: 333: 332: 330: 326: 325: 322: 316: 315: 311: 307: 303: 300: 294: 293: 290: 286: 285: 282: 276: 275: 272: 266: 265: 262: 256: 255: 240: 231: 230: 227: 221: 220: 217: 211: 210: 207: 201: 200: 197: 191: 190: 187: 183: 182: 181:Identification 178: 177: 170: 164: 163: 155: 149: 148: 133: 127: 126: 121: 119:Crystal system 115: 114: 111: 105: 104: 101: 95: 94: 91: 85: 84: 80: 76: 72: 68: 64: 61: 51: 50: 48:Phyllosilicate 45: 41: 40: 36: 35: 32: 24: 23: 15: 9: 6: 4: 3: 2: 1462: 1451: 1448: 1446: 1443: 1441: 1438: 1436: 1433: 1431: 1428: 1426: 1423: 1421: 1418: 1416: 1413: 1411: 1408: 1406: 1403: 1402: 1400: 1389: 1384: 1382: 1377: 1375: 1370: 1369: 1363: 1361: 1357: 1353: 1348: 1345: 1341: 1340: 1336: 1330: 1326: 1322: 1318: 1314: 1310: 1306: 1302: 1298: 1294: 1290: 1286: 1281: 1278: 1274: 1270: 1266: 1265: 1246: 1242: 1238: 1234: 1230: 1226: 1222: 1218: 1214: 1206: 1198: 1194: 1189: 1188:11250/3015094 1184: 1179: 1174: 1170: 1166: 1162: 1155: 1147: 1143: 1138: 1133: 1129: 1125: 1121: 1114: 1106: 1102: 1098: 1094: 1090: 1086: 1082: 1078: 1071: 1063: 1059: 1055: 1051: 1047: 1043: 1039: 1035: 1031: 1027: 1008: 994: 990: 986: 982: 978: 974: 970: 966: 962: 955: 947: 941: 933: 929: 925: 921: 917: 913: 909: 905: 901: 897: 890: 882: 878: 874: 870: 866: 862: 855: 847: 843: 839: 835: 831: 827: 816: 814: 805: 803:0-7277-2592-0 799: 795: 788: 780: 778:0-08-053541-0 774: 770: 763: 749:on 2016-02-22 748: 744: 738: 736: 727: 720: 718: 709: 703: 701: 699: 697: 695: 680:on 2022-01-25 676: 669: 663: 661: 652: 648: 643: 638: 634: 630: 626: 622: 618: 611: 607: 597: 594: 591: 588: 582: 579: 576: 573: 572: 566: 563: 558: 556: 552: 544: 530: 528: 524: 520: 516: 512: 508: 505:atoms in its 504: 500: 496: 492: 464: 460: 450: 448: 444: 440: 435: 433: 429: 425: 421: 412: 403: 401: 397: 393: 392:centrallasite 388: 386: 382: 379: 375: 371: 367: 363: 360:O, is a rare 339: 331: 327: 323: 321: 320:Birefringence 317: 301: 299: 295: 291: 287: 283: 281: 277: 273: 271: 267: 263: 261: 257: 241: 236: 232: 228: 226: 222: 218: 216: 212: 208: 206: 202: 198: 196: 195:Crystal habit 192: 188: 184: 179: 171: 169: 165: 159: 156: 154: 150: 145: 134: 132: 131:Crystal class 128: 125: 122: 120: 116: 112: 110: 106: 102: 100: 96: 92: 90: 86: 62: 56: 52: 49: 46: 42: 37: 30: 25: 20: 1360:expanding it 1349: 1334: 1324: 1320: 1288: 1284: 1277:PDF 239,5 kB 1272: 1268: 1248:. Retrieved 1220: 1216: 1205: 1168: 1164: 1154: 1127: 1123: 1113: 1080: 1076: 1070: 1029: 1025: 1007: 996:. Retrieved 968: 964: 954: 940: 899: 895: 889: 864: 860: 854: 829: 825: 824:or quartz". 793: 787: 771:. Elsevier. 768: 762: 751:. Retrieved 747:the original 682:. Retrieved 675:the original 624: 620: 610: 559: 536: 497:atom by one 456: 436: 431: 424:Isle of Skye 417: 399: 395: 391: 389: 337: 336: 157: 135:Pinacoidal ( 590:Tacharanite 575:Carbonatite 551:tobermorite 525:exposed to 439:apophyllite 292:Biaxial (−) 270:Diaphaneity 153:Space group 1399:Categories 1329:PDF 444 kB 1250:2020-04-29 1223:: 105958. 1171:: 108562. 998:2020-04-29 753:2016-02-27 708:"Gyrolite" 684:2016-02-27 602:References 329:References 324:δ = 0.0140 235:Mohs scale 144:H-M symbol 89:IMA symbol 1313:0369-0148 1245:212942959 1237:0008-8846 1197:0264-1275 1146:0008-8846 1130:: 49–56. 1105:137653659 1097:1871-6873 1062:129570863 1054:1555-6476 993:0935-1221 924:0895-7959 881:0008-8846 846:0008-8846 651:235729616 562:pectolite 555:xonotlite 420:The Storr 310:= 1.548 n 306:= 1.535 n 284:2.45–2.51 168:Unit cell 124:Triclinic 113:73.2.2c.1 1430:Hydrates 1425:Concrete 1020:Ca ¡ 5 H 932:98509464 569:See also 523:concrete 501:and one 499:aluminum 447:zeolites 428:Scotland 400:gurolite 374:zeolites 338:Gyrolite 238:hardness 225:Tenacity 215:Cleavage 209:Lamellar 205:Twinning 44:Category 22:Gyrolite 1293:Bibcode 1034:Bibcode 973:Bibcode 904:Bibcode 629:Bibcode 495:silicon 493:of one 443:okenite 422:on the 314:= 1.549 280:Density 250:⁄ 229:Brittle 103:9.EE.30 55:Formula 39:General 1420:Cement 1323:. 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Index


Phyllosilicate
Formula
IMA symbol
Strunz classification
Dana classification
Crystal system
Triclinic
Crystal class
H-M symbol
Space group
Unit cell
Crystal habit
Twinning
Cleavage
Tenacity
Mohs scale
Luster
Diaphaneity
Density
Refractive index
Birefringence
silicate mineral
cement chemist notation
phyllosilicates
zeolites
hydrothermally altered
basalt
basaltic tuffs

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