17:
151:
Sharpless, K. Barry; Young, Michael W. (1975). "Olefin synthesis. Rate enhancement of the elimination of alkyl aryl selenoxides by electron-withdrawing substituents".
123:
Grieco, Paul A.; Gilman, Sydney; Nishizawa, Mugio (1976). "Organoselenium chemistry. A facile one-step synthesis of alkyl aryl selenides from alcohols".
100:
479:
464:
225:
188:
509:
106:
The elimination step is common with the Clive-Reich-Sharpless olefination that uses PhSeX as the selenium source.
661:
656:
439:
444:
635:
68:
16:
615:
666:
575:
570:
449:
494:
218:
504:
484:
421:
33:
8:
474:
454:
425:
412:
181:
Organic
Syntheses Based on Name Reactions: A Practical Guide to Over 800 Transformations
565:
539:
605:
529:
519:
489:
430:
184:
76:
60:
585:
514:
499:
211:
161:
133:
96:
29:
625:
595:
524:
45:
37:
620:
610:
650:
580:
555:
459:
153:
125:
630:
560:
534:
84:
590:
49:
165:
137:
600:
416:
80:
248:
72:
64:
41:
333:
299:
265:
92:
434:
384:
367:
350:
316:
282:
234:
99:. This reaction takes part in the synthesis of ring C of the
203:
122:
83:. This structure decomposes to form an alkene by an
75:. In the second step, the selenide is oxidized with
178:
648:
150:
219:
226:
212:
649:
207:
179:Hassner, A.; Namboothiri, I. (2011).
95:in a fashion similar to that of the
13:
15:
14:
678:
480:Horner–Wadsworth–Emmons reaction
172:
144:
116:
59:-nitrophenylselenocyanate and
55:The alcohol first reacts with
1:
465:Corey–Winter olefin synthesis
109:
183:(3rd ed.). p. 91.
7:
233:
101:Danishefsky Taxol synthesis
10:
683:
71:on the electron-deficient
636:Friedel-Crafts Alkylation
548:
510:Ramberg–Bäcklund reaction
405:
241:
69:nucleophilic substitution
440:Bamford–Stevens reaction
576:Oxymercuration reaction
445:Barton–Kellogg reaction
571:Electrophilic addition
450:Boord olefin synthesis
21:
20:The Grieco elimination
662:Olefination reactions
657:Elimination reactions
495:Kauffmann olefination
89:elimination mechanism
19:
616:Diels–Alder reaction
505:Peterson olefination
485:Hydrazone iodination
422:Dehydration reaction
91:with expulsion of a
34:elimination reaction
475:Hofmann elimination
455:Chugaev elimination
413:Dehydrohalogenation
166:10.1021/jo00895a030
138:10.1021/jo00870a052
540:Cope rearrangement
470:Grieco elimination
48:. It is named for
26:Grieco elimination
22:
644:
643:
606:Hydrohalogenation
530:Olefin metathesis
520:Takai olefination
490:Julia olefination
431:Semihydrogenation
77:hydrogen peroxide
61:tributylphosphine
674:
586:Cyclopropanation
515:Shapiro reaction
500:McMurry reaction
397:
380:
363:
346:
329:
312:
295:
278:
261:
228:
221:
214:
205:
204:
195:
194:
176:
170:
169:
148:
142:
141:
132:(8): 1485–1486.
120:
97:Cope elimination
36:of an aliphatic
30:organic reaction
682:
681:
677:
676:
675:
673:
672:
671:
647:
646:
645:
640:
626:Dehydrogenation
596:Dihydroxylation
544:
525:Wittig reaction
401:
396:
392:
388:
379:
375:
371:
362:
358:
354:
345:
341:
337:
328:
324:
320:
311:
307:
303:
294:
290:
286:
277:
273:
269:
260:
256:
252:
237:
232:
201:
199:
198:
191:
177:
173:
149:
145:
121:
117:
112:
88:
46:terminal alkene
38:primary alcohol
32:describing the
12:
11:
5:
680:
670:
669:
667:Name reactions
664:
659:
642:
641:
639:
638:
633:
628:
623:
621:Wacker process
618:
613:
611:Polymerization
608:
603:
598:
593:
588:
583:
578:
573:
568:
563:
558:
552:
550:
546:
545:
543:
542:
537:
532:
527:
522:
517:
512:
507:
502:
497:
492:
487:
482:
477:
472:
467:
462:
457:
452:
447:
442:
437:
428:
419:
409:
407:
403:
402:
400:
399:
394:
390:
382:
377:
373:
365:
360:
356:
348:
343:
339:
331:
326:
322:
314:
309:
305:
297:
292:
288:
280:
275:
271:
263:
258:
254:
245:
243:
239:
238:
231:
230:
223:
216:
208:
197:
196:
189:
171:
160:(7): 947–949.
143:
114:
113:
111:
108:
86:
9:
6:
4:
3:
2:
679:
668:
665:
663:
660:
658:
655:
654:
652:
637:
634:
632:
629:
627:
624:
622:
619:
617:
614:
612:
609:
607:
604:
602:
599:
597:
594:
592:
589:
587:
584:
582:
581:Hydroboration
579:
577:
574:
572:
569:
567:
564:
562:
559:
557:
556:Hydrogenation
554:
553:
551:
547:
541:
538:
536:
533:
531:
528:
526:
523:
521:
518:
516:
513:
511:
508:
506:
503:
501:
498:
496:
493:
491:
488:
486:
483:
481:
478:
476:
473:
471:
468:
466:
463:
461:
460:Cope reaction
458:
456:
453:
451:
448:
446:
443:
441:
438:
436:
432:
429:
427:
423:
420:
418:
414:
411:
410:
408:
404:
386:
383:
369:
366:
352:
349:
335:
332:
318:
315:
301:
298:
284:
281:
267:
264:
250:
247:
246:
244:
240:
236:
229:
224:
222:
217:
215:
210:
209:
206:
202:
192:
190:9780080966311
186:
182:
175:
167:
163:
159:
156:
155:
154:J. Org. Chem.
147:
139:
135:
131:
128:
127:
126:J. Org. Chem.
119:
115:
107:
104:
102:
98:
94:
90:
82:
78:
74:
70:
66:
62:
58:
53:
51:
47:
43:
39:
35:
31:
27:
18:
631:Ene reaction
561:Halogenation
535:Ene reaction
469:
406:Preparations
200:
180:
174:
157:
152:
146:
129:
124:
118:
105:
56:
54:
25:
23:
591:Epoxidation
50:Paul Grieco
651:Categories
601:Ozonolysis
417:haloalkane
110:References
81:selenoxide
79:to give a
63:to form a
40:through a
566:Hydration
549:Reactions
73:selenium
65:selenide
42:selenide
426:alcohol
334:Heptene
300:Pentene
266:Propene
242:Alkenes
235:Alkenes
93:selenol
435:alkyne
385:Decene
368:Nonene
351:Octene
317:Hexene
283:Butene
249:Ethene
187:
67:via a
28:is an
433:from
424:from
415:from
44:to a
185:ISBN
24:The
162:doi
134:doi
653::
395:20
391:10
378:18
361:16
344:14
327:12
310:10
158:40
130:41
103:.
52:.
398:)
393:H
389:C
387:(
381:)
376:H
374:9
372:C
370:(
364:)
359:H
357:8
355:C
353:(
347:)
342:H
340:7
338:C
336:(
330:)
325:H
323:6
321:C
319:(
313:)
308:H
306:5
304:C
302:(
296:)
293:8
291:H
289:4
287:C
285:(
279:)
276:6
274:H
272:3
270:C
268:(
262:)
259:4
257:H
255:2
253:C
251:(
227:e
220:t
213:v
193:.
168:.
164::
140:.
136::
87:i
85:E
57:o
Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.