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Grieco elimination

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Sharpless, K. Barry; Young, Michael W. (1975). "Olefin synthesis. Rate enhancement of the elimination of alkyl aryl selenoxides by electron-withdrawing substituents".
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Grieco, Paul A.; Gilman, Sydney; Nishizawa, Mugio (1976). "Organoselenium chemistry. A facile one-step synthesis of alkyl aryl selenides from alcohols".
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The elimination step is common with the Clive-Reich-Sharpless olefination that uses PhSeX as the selenium source.
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Organic Syntheses Based on Name Reactions: A Practical Guide to Over 800 Transformations
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Index

The Grieco elimination
organic reaction
elimination reaction
primary alcohol
selenide
terminal alkene
Paul Grieco
tributylphosphine
selenide
nucleophilic substitution
selenium
hydrogen peroxide
selenoxide
Ei elimination mechanism
selenol
Cope elimination
Danishefsky Taxol synthesis
J. Org. Chem.
doi
10.1021/jo00870a052
J. Org. Chem.
doi
10.1021/jo00895a030
ISBN
9780080966311
v
t
e
Alkenes
Ethene

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