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Flexoelectricity

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25: 144:. Flexoelectricity plays a critical role in explaining many interesting electromechanical behaviors in hard crystalline materials and core mechanoelectric transduction phenomena in soft biomaterials. Most excitingly, flexoelectricity is a size-dependent effect that becomes more significant in nanoscale systems, such as crack tips. 147:
In common useage flexoelectricity is the generation of polarization due to a strain gradient; inverse flexoectricity is when polarization, often due to an applied electric field, generates a strain gradient. Converse flexoelectricity is where a polarization gradient induces strain in a material.
331: 136:, but while piezoelectricity refers to polarization due to uniform strain, flexoelectricity refers specifically to polarization due to strain that changes from point to point in the material. This nonuniform strain breaks 567:
Hongguang Wang, Xijie Jiang, Yi Wang, Robert W. Stark, Peter A. van Aken, Jochen Mannhart, Hans Boschker (2020). "Direct observation of huge flexoelectric polarization around crack tips".
218: 210: 377: 410: 140:, meaning that unlike in piezoelectricity, flexoelectric effects occur in both centrosymmetric and asymmetric crystal structures. Flexoelectricity is not the same as 176: 603: 553: 503: 701: 566: 89: 682: 61: 436: 458: 517:
Thanh D. Nguyen, Sheng Mao, Yao-Wen Yeh, Prashant K. Purohit, Michael C. McAlpine (2013). "Nanoscale Flexoelectricity".
68: 706: 108: 42: 75: 516: 46: 619:"Converse flexoelectricity yields large piezoresponse force microscopy signals in non-piezoelectric materials" 57: 340:
effect and the second term corresponds to the flexoelectric polarization induced by the strain gradient.
326:{\displaystyle P_{i}=e_{ijk}\epsilon _{jk}+\mu _{ijkl}{\frac {\partial \epsilon _{jk}}{\partial x_{l}}}} 129: 185: 456:
Pavlo Zubko, Gustau Catalan, and Alexander K. Tagantsev (2013). "Flexoelectric Effect in Solids".
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material where there is coupling between electrical polarization and a
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is the coefficient corresponding to the direct piezoelectric effect.
24: 616: 385: 349: 221: 188: 157: 617:Abdollahi A, Domingo N, Arias I, Catalan G (2019). 49:. Unsourced material may be challenged and removed. 404: 371: 325: 204: 170: 132:gradient. Flexoelectricity is closely related to 693: 336:where the first term corresponds to the direct 602:: CS1 maint: multiple names: authors list ( 552:: CS1 maint: multiple names: authors list ( 502:: CS1 maint: multiple names: authors list ( 652: 642: 487: 109:Learn how and when to remove this message 702:Electric and magnetic fields in matter 694: 343:Here, the flexoelectric coefficient, 16:Polarization due to a strain gradient 480:10.1146/annurev-matsci-071312-121634 379:, is a fourth-rank polar tensor and 47:adding citations to reliable sources 18: 459:Annual Review of Materials Research 13: 307: 289: 14: 718: 680:Introduction to Flexoelectricity 673: 23: 34:needs additional citations for 610: 560: 510: 449: 205:{\displaystyle \epsilon _{ij}} 1: 442: 582:10.1021/acs.nanolett.9b03176 212:in a dielectric is given by 7: 415: 372:{\displaystyle \mu _{ijkl}} 10: 723: 644:10.1038/s41467-019-09266-y 151:The electric polarization 707:Condensed matter physics 405:{\displaystyle e_{ijk}} 532:10.1002/adma.201203852 406: 373: 327: 206: 172: 623:Nature Communications 407: 374: 328: 207: 173: 171:{\displaystyle P_{i}} 437:Triboelectric effect 383: 347: 219: 186: 155: 43:improve this article 635:2019NatCo..10.1266A 472:2013AnRMS..43..387Z 124:is a property of a 685:2009-03-06 at the 402: 369: 323: 202: 178:due to mechanical 168: 58:"Flexoelectricity" 321: 119: 118: 111: 93: 714: 667: 666: 656: 646: 614: 608: 607: 601: 593: 564: 558: 557: 551: 543: 514: 508: 507: 501: 493: 491: 453: 427:Ferroelectricity 422:Piezoelectricity 411: 409: 408: 403: 401: 400: 378: 376: 375: 370: 368: 367: 332: 330: 329: 324: 322: 320: 319: 318: 305: 304: 303: 287: 285: 284: 263: 262: 250: 249: 231: 230: 211: 209: 208: 203: 201: 200: 177: 175: 174: 169: 167: 166: 134:piezoelectricity 122:Flexoelectricity 114: 107: 103: 100: 94: 92: 51: 27: 19: 722: 721: 717: 716: 715: 713: 712: 711: 692: 691: 687:Wayback Machine 676: 671: 670: 615: 611: 595: 594: 565: 561: 545: 544: 515: 511: 495: 494: 454: 450: 445: 432:Ferroelasticity 418: 390: 386: 384: 381: 380: 354: 350: 348: 345: 344: 314: 310: 306: 296: 292: 288: 286: 271: 267: 255: 251: 239: 235: 226: 222: 220: 217: 216: 193: 189: 187: 184: 183: 162: 158: 156: 153: 152: 142:Ferroelasticity 115: 104: 98: 95: 52: 50: 40: 28: 17: 12: 11: 5: 720: 710: 709: 704: 690: 689: 675: 674:External links 672: 669: 668: 609: 559: 526:(7): 946–974. 509: 447: 446: 444: 441: 440: 439: 434: 429: 424: 417: 414: 399: 396: 393: 389: 366: 363: 360: 357: 353: 334: 333: 317: 313: 309: 302: 299: 295: 291: 283: 280: 277: 274: 270: 266: 261: 258: 254: 248: 245: 242: 238: 234: 229: 225: 199: 196: 192: 165: 161: 138:centrosymmetry 117: 116: 31: 29: 22: 15: 9: 6: 4: 3: 2: 719: 708: 705: 703: 700: 699: 697: 688: 684: 681: 678: 677: 664: 660: 655: 650: 645: 640: 636: 632: 628: 624: 620: 613: 605: 599: 591: 587: 583: 579: 575: 572: 571: 563: 555: 549: 541: 537: 533: 529: 525: 522: 521: 513: 505: 499: 490: 485: 481: 477: 473: 469: 465: 461: 460: 452: 448: 438: 435: 433: 430: 428: 425: 423: 420: 419: 413: 397: 394: 391: 387: 364: 361: 358: 355: 351: 341: 339: 338:piezoelectric 315: 311: 300: 297: 293: 281: 278: 275: 272: 268: 264: 259: 256: 252: 246: 243: 240: 236: 232: 227: 223: 215: 214: 213: 197: 194: 190: 181: 163: 159: 149: 145: 143: 139: 135: 131: 127: 123: 113: 110: 102: 91: 88: 84: 81: 77: 74: 70: 67: 63: 60: –  59: 55: 54:Find sources: 48: 44: 38: 37: 32:This article 30: 26: 21: 20: 626: 622: 612: 598:cite journal 576:(1): 88–94. 573: 568: 562: 548:cite journal 523: 518: 512: 498:cite journal 463: 457: 451: 342: 335: 150: 146: 121: 120: 105: 96: 86: 79: 72: 65: 53: 41:Please help 36:verification 33: 629:(1): 1266. 520:Adv. Mater. 489:10261/99362 466:: 387–421. 696:Categories 570:Nano Lett. 443:References 126:dielectric 69:newspapers 352:μ 308:∂ 294:ϵ 290:∂ 269:μ 253:ϵ 191:ϵ 683:Archived 663:30894544 590:31851827 540:23293034 416:See also 99:May 2012 654:6427004 631:Bibcode 468:Bibcode 83:scholar 661:  651:  588:  538:  180:strain 130:strain 85:  78:  71:  64:  56:  90:JSTOR 76:books 659:PMID 604:link 586:PMID 554:link 536:PMID 504:link 62:news 649:PMC 639:doi 578:doi 528:doi 484:hdl 476:doi 182:of 45:by 698:: 657:. 647:. 637:. 627:10 625:. 621:. 600:}} 596:{{ 584:. 574:20 550:}} 546:{{ 534:. 524:25 500:}} 496:{{ 482:. 474:. 464:43 462:. 665:. 641:: 633:: 606:) 592:. 580:: 556:) 542:. 530:: 506:) 492:. 486:: 478:: 470:: 398:k 395:j 392:i 388:e 365:l 362:k 359:j 356:i 316:l 312:x 301:k 298:j 282:l 279:k 276:j 273:i 265:+ 260:k 257:j 247:k 244:j 241:i 237:e 233:= 228:i 224:P 198:j 195:i 164:i 160:P 112:) 106:( 101:) 97:( 87:· 80:· 73:· 66:· 39:.

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"Flexoelectricity"
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scholar
JSTOR
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dielectric
strain
piezoelectricity
centrosymmetry
Ferroelasticity
strain
piezoelectric
Piezoelectricity
Ferroelectricity
Ferroelasticity
Triboelectric effect
Annual Review of Materials Research
Bibcode
2013AnRMS..43..387Z
doi
10.1146/annurev-matsci-071312-121634
hdl
10261/99362
cite journal

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