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Ferroelectricity

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1290: 554: 90: 441:, another key ferroelectric material, although the structure is rather similar to barium titanate the driving force for ferroelectricity is more complex with interactions between the lead and oxygen ions also playing an important role. In an order-disorder ferroelectric, there is a dipole moment in each unit cell, but at high temperatures they are pointing in random directions. Upon lowering the temperature and going through the phase transition, the dipoles order, all pointing in the same direction within a domain. 82: 239:. Sabatier principle states that the surface-adsorbates interaction has to be an optimal amount: not too weak to be inert toward the reactants and not too strong to poison the surface and avoid desorption of the products: a compromise situation. This set of optimum interactions is usually referred to as "top of the volcano" in activity volcano plots. On the other hand, ferroelectric polarization-dependent chemistry can offer the possibility of switching the surface—adsorbates interaction from strong 1285:{\displaystyle {\begin{array}{ll}\Delta E=&{\frac {1}{2}}\alpha _{0}\left(T-T_{0}\right)\left(P_{x}^{2}+P_{y}^{2}+P_{z}^{2}\right)+{\frac {1}{4}}\alpha _{11}\left(P_{x}^{4}+P_{y}^{4}+P_{z}^{4}\right)\\&+{\frac {1}{2}}\alpha _{12}\left(P_{x}^{2}P_{y}^{2}+P_{y}^{2}P_{z}^{2}+P_{z}^{2}P_{x}^{2}\right)\\&+{\frac {1}{6}}\alpha _{111}\left(P_{x}^{6}+P_{y}^{6}+P_{z}^{6}\right)\\&+{\frac {1}{2}}\alpha _{112}\left\\&+{\frac {1}{2}}\alpha _{123}P_{x}^{2}P_{y}^{2}P_{z}^{2}\end{array}}} 74: 483:, and the prediction could immediately be verified by several observations of behavior connected to ferroelectricity in smectic liquid-crystal phases that are chiral and tilted. The technology allows the building of flat-screen monitors. Mass production between 1994 and 1999 was carried out by Canon. Ferroelectric liquid crystals are used in production of reflective 282:
surface charge. This can cause current flow in the case of a ferroelectric capacitor even without the presence of an external voltage across the capacitor. Two stimuli that will change the lattice dimensions of a material are force and temperature. The generation of a surface charge in response to the application of an external stress to a material is called
217:) in which a contact is made up by nanometer-thick ferroelectric film placed between metal electrodes. The thickness of the ferroelectric layer is small enough to allow tunneling of electrons. The piezoelectric and interface effects as well as the depolarization field may lead to a giant electroresistance (GER) switching effect. 2933: 452:
lead zirconate. Different compositions are used for different applications; for memory applications, PZT closer in composition to lead titanate is preferred, whereas piezoelectric applications make use of the diverging piezoelectric coefficients associated with the morphotropic phase boundary that is
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The internal electric dipoles of a ferroelectric material are coupled to the material lattice so anything that changes the lattice will change the strength of the dipoles (in other words, a change in the spontaneous polarization). The change in the spontaneous polarization results in a change in the
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make ferroelectric capacitors very useful, e.g. for sensor applications. Ferroelectric capacitors are used in medical ultrasound machines (the capacitors generate and then listen for the ultrasound ping used to image the internal organs of a body), high quality infrared cameras (the infrared image is
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simply consists of a pair of electrodes sandwiching a layer of ferroelectric material. The permittivity of ferroelectrics is not only adjustable but commonly also very high, especially when close to the phase transition temperature. Because of this, ferroelectric capacitors are small in physical size
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cards. In these applications thin films of ferroelectric materials are typically used, as this allows the field required to switch the polarization to be achieved with a moderate voltage. However, when using thin films a great deal of attention needs to be paid to the interfaces, electrodes and
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Wanlin Zhu, John Hayden, Fan He, Jung-In Yang, Pannawit Tipsawat, Mohammad D. Hossain, Jon-Paul Maria, and Susan Trolier-McKinstry, "Strongly temperature dependent ferroelectric switching in AlN, Al1-xScxN, and Al1-xBxN thin films", Appl. Phys. Lett. 119, 062901 (2021)
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of these materials. Surface-perpendicular component of the ferroelectric polarization can dope polarization-dependent charges on surfaces of ferroelectric materials, changing their chemistry. This opens the possibility of performing catalysis beyond the limits of the
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Cao, Yanwei; Wang, Zhen; Park, Se Young; Yuan, Yakun; Liu, Xiaoran; Nikitin, Sergey M.; Akamatsu, Hirofumi; Kareev, M.; Middey, S.; Meyers, D.; Thompson, P.; Ryan, P. J.; Shafer, Padraic; N’Diaye, A.; Arenholz, E.; Gopalan, Venkatraman; Zhu, Yimei;
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Benke, Annegret; Mehner, Erik; Rosenkranz, Marco; Dmitrieva, Evgenia; Leisegang, Tilmann; Stöcker, Hartmut; Pompe, Wolfgang; Meyer, Dirk C. (30 July 2015). "Pyroelectrically Driven •OH Generation by Barium Titanate and Palladium Nanoparticles".
437:. This leads to an asymmetrical shift in the equilibrium ion positions and hence to a permanent dipole moment. The ionic displacement in barium titanate concerns the relative position of the titanium ion within the oxygen octahedral cage. In 206:
projected onto a two dimensional array of ferroelectric capacitors capable of detecting temperature differences as small as millionths of a degree Celsius), fire sensors, sonar, vibration sensors, and even fuel injectors on diesel engines.
2259: 2752: 2714: 3356:). Elimination of this region, and connection of the top and bottom portions of the 'S' curve by vertical lines at the discontinuities gives the hysteresis loop of internal polarization due to an external electric field. 1565: 2959: 158:) and are paraelectric above this temperature: the spontaneous polarization vanishes, and the ferroelectric crystal transforms into the paraelectric state. Many ferroelectrics lose their pyroelectric properties above 3354: 2119: 2583: 1801: 429:, a typical ferroelectric of the displacive type, the transition can be understood in terms of a polarization catastrophe, in which, if an ion is displaced from equilibrium slightly, the force from the local 2420: 1388: 132:
by a suitably strong applied electric field in the opposite direction; the polarization is therefore dependent not only on the current electric field but also on its history, yielding a
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Sliding ferroelectricity is widely found but only in two-dimensional (2D) van der Waals stacked layers. The vertical electric polarization is switched by in-plane interlayer sliding.
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It should be possible to produce materials which combine both ferroelectric and metallic properties simultaneously, at room temperature. According to research published in 2018 in
1477: 1543: 1510: 1444: 3133: 2619: 224:, where researchers are looking for ways to couple magnetic and ferroelectric ordering within a material or heterostructure; there are several recent reviews on this topic. 1394:. Typically, this involves adding a gradient term, an electrostatic term and an elastic term to the free energy. The equations are then discretized onto a grid using the 230:
properties of ferroelectrics have been studied since 1952 when Parravano observed anomalies in CO oxidation rates over ferroelectric sodium and potassium niobates near the
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must be consistent with the crystal symmetry. To investigate domain formation and other phenomena in ferroelectrics, these equations are often used in the context of a
2149: 1793: 528:, scientists were able to produce a two-dimensional sheet of material which was both ferroelectric (had a polar crystal structure) and which conducted electricity. 2928:{\displaystyle \Delta E={\frac {1}{2}}\alpha _{0}\left(T-T_{0}\right)P_{x}^{2}+{\frac {1}{4}}\alpha _{11}P_{x}^{4}+{\frac {1}{6}}\alpha _{111}P_{x}^{6}-E_{x}P_{x}} 4103:
Kolpak, Alexie M.; Grinberg, Ilya; Rappe, Andrew M. (2007-04-16). "Polarization Effects on the Surface Chemistry of $ {\mathrm{PbTiO}}_{3}$ -Supported Pt Films".
502:" properties, and may have wide-ranging applications in device and nano-technology and also influence the electrical nature of dust in the interstellar medium. 57:, meaning iron, was used to describe the property despite the fact that most ferroelectric materials do not contain iron. Materials that are both ferroelectric 4217:
Laursen, Anders B.; Man, Isabela Costinela; Trinhammer, Ole L.; Rossmeisl, Jan; Dahl, Søren (December 2011). "The Sabatier Principle Illustrated by Catalytic H
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effects under varying temperature (heating/cooling cycles) or varying strain (vibrations) conditions extra charges can appear on the surface and drive various
1718:{\displaystyle \Delta E={\frac {1}{2}}\alpha _{0}\left(T-T_{0}\right)P_{x}^{2}+{\frac {1}{4}}\alpha _{11}P_{x}^{4}+{\frac {1}{6}}\alpha _{111}P_{x}^{6}} 4986: 4981: 3120:{\displaystyle {\frac {\partial \Delta E}{\partial P_{x}}}=\alpha _{0}\left(T-T_{0}\right)P_{x}+\alpha _{11}P_{x}^{3}+\alpha _{111}P_{x}^{5}-E_{x}=0} 117:, corresponding to the slope of the polarization curve, is not constant as in linear dielectrics but is a function of the external electric field. 5007: 3294: 1956: 197:
Ferroelectric materials are required by symmetry considerations to be also piezoelectric and pyroelectric. The combined properties of memory,
4941: 1943:{\displaystyle {\frac {\partial \Delta E}{\partial P_{x}}}=\alpha _{0}\left(T-T_{0}\right)P_{x}+\alpha _{11}P_{x}^{3}+\alpha _{111}P_{x}^{5}} 1479:. These coefficients may be obtained experimentally or from ab-initio simulations. For ferroelectrics with a first order phase transition, 1559:
of a ferroelectric for a cubic to tetragonal phase transition may be obtained by considering the 1D expression of the free energy which is:
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and eliminating solutions which take the square root of a negative number (for either the first or second order phase transitions) gives:
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is a technique to record optical information on pieces of ferroelectric material. The images are nonvolatile and selectively erasable.
148: 109:; so the polarization is a linear function. This is called linear dielectric polarization (see figure). Some materials, known as 3810:
M.Ye. Zhuravlev; R.F. Sabirianov; S.S. Jaswal; E.Y. Tsymbal (2005). "Giant Electroresistance in Ferroelectric Tunnel Junctions".
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Seh, Zhi Wei; Kibsgaard, Jakob; Dickens, Colin F.; Chorkendorff, Ib; Nørskov, Jens K.; Jaramillo, Thomas F. (13 January 2017).
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Kakekhani, Arvin; Ismail-Beigi, Sohrab (2016). "Ferroelectric oxide surface chemistry: water splitting via pyroelectricity".
3737: 3582: 3557: 1768:, the spontaneous polarization. We find the derivative of the free energy, and set it equal to zero in order to solve for 1331: 305:. Among the piezoelectric classes, 10 have a spontaneous electric polarization which varies with temperature; thus they are 4667: 540:, the free energy of a ferroelectric material, in the absence of an electric field and applied stress may be written as a 247:, thus a compromise between desorption and adsorption is no longer needed. Ferroelectric polarization can also act as an 173:
The nonlinear nature of ferroelectric materials can be used to make capacitors with adjustable capacitance. Typically, a
4261: 37:, with the additional property that their natural electrical polarization is reversible. The term is used in analogy to 3712: 4558:
Clark, Noel A.; Lagerwall, Sven T. (June 1980). "Submicrosecond bistable electro‐optic switching in liquid crystals".
4934: 4368: 309:. Ferroelectricity is a subset of pyroelectricity, which brings spontaneous electronic polarization to the material. 5012: 4645: 4612: 3545: 3378: 4138:
Yun, Yang; Altman, Eric I. (December 2007). "Using Ferroelectric Poling to Change Adsorption on Oxide Surfaces".
548:. If a sixth order expansion is used (i.e. 8th order and higher terms truncated), the free energy is given by: 147:
Typically, materials demonstrate ferroelectricity only below a certain phase transition temperature, called the
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In addition to being nonlinear, ferroelectric materials demonstrate a spontaneous nonzero polarization (after
5017: 3517: 4927: 491: 316: 286:. A change in the spontaneous polarization of a material in response to a change in temperature is called 1449: 3410: 3255:{\displaystyle E_{x}=\alpha _{0}\left(T-T_{0}\right)P_{e}+\alpha _{11}P_{e}^{3}+\alpha _{111}P_{e}^{5}} 1515: 1482: 537: 409: 270: 1416: 5022: 2591: 185:
effect which can be used as a memory function, and ferroelectric capacitors are indeed used to make
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that can be reversed by the application of an external electric field. All ferroelectrics are also
4776:"Sliding ferroelectricity in 2D van der Waals materials: Related physics and future opportunities" 4613:"Pyroelectric Materials for Uncooled Infrared Detectors: Processing, Properties, and Applications" 498:
or propane exhibited ferroelectric properties. This new class of ferroelectric materials exhibit "
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is zero. The distinguishing feature of ferroelectrics is that the spontaneous polarization can be
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Aggarwal, M.D.; A.K. Batra; P. Guggilla; M.E. Edwards; B.G. Penn; J.R. Currie Jr. (March 2010).
3288: 461: 298: 2254:{\displaystyle \alpha _{0}\left(T-T_{0}\right)+\alpha _{11}P_{s}^{2}+\alpha _{111}P_{s}^{4}=0} 3902:
W. Eerenstein; N.D. Mathur; J.F. Scott (2006). "Multiferroic and magnetoelectric materials".
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Ferroelectric phase transitions are often characterized as either displacive (such as BaTiO
98: 26: 448:(PZT), which is part of the solid solution formed between ferroelectric lead titanate and 8: 2709:{\displaystyle P_{s}=\pm {\sqrt{\frac {\alpha _{0}\left(T_{0}-T\right)}{\alpha _{111}}}}} 1728:
This free energy has the shape of a double well potential with two free energy minima at
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can be found in crystals. There are 21 non-centrosymmetric classes, within which 20 are
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Parravano, G. (February 1952). "Ferroelectric Transitions and Heterogenous Catalysis".
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Zhang, Yan; Xie, Mengying; Adamaki, Vana; Khanbareh, Hamideh; Bowen, Chris R. (2017).
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completely, because their paraelectric phase has a centrosymmetric crystal structure.
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Effective Field Approach to Phase Transitions and Some Applications to Ferroelectrics
4871: 4849: 4827: 4815: 4735: 4520: 4470: 4378: 4364: 4333: 4312:"Control of electro-chemical processes using energy harvesting materials and devices" 4296: 4284: 4262:"Combining theory and experiment in electrocatalysis: Insights into materials design" 4155: 4120: 4013: 4005: 3978: 3966: 3927: 3892: 3809: 3733: 3708: 3578: 3553: 3392: 1407: 514: 388: 264: 248: 231: 186: 3849: 3487: – materials that exhibit more than one of the primary ferroic order parameters 4805: 4795: 4725: 4717: 4595:"Novel ferroelectric behaviour of N2O films: spontaneous potentials of up to 40 V." 4575: 4512: 4460: 4429: 4402: 4356: 4323: 4276: 4242: 4197: 4147: 4112: 4083: 4044: 4001: 3958: 3939: 3919: 3884: 3837: 3796: 3784: 3660: 3652: 3620: 3460: 3434: 473: 335: 302: 283: 260: 198: 45:. Ferromagnetism was already known when ferroelectricity was discovered in 1920 in 30: 4116: 3841: 425:), though often phase transitions will demonstrate elements of both behaviors. In 113:
materials, show a more enhanced nonlinear polarization (see figure). The electric
4966: 4516: 4449:"Piezopotential-Driven Redox Reactions at the Surface of Piezoelectric Materials" 3451: 3440: 3425: 480: 434: 426: 374: 348: 306: 287: 256: 202: 110: 42: 34: 4351:
Fang, Liang; You, Lu; Liu, Jun-Ming (2018). "Ferroelectrics in Photocatalysis".
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due to the ions in the crystal increases faster than the elastic-restoring
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P. Chandra; P.B. Littlewood (2006). "A Landau Primer for Ferroelectrics".
73: 4950: 4759: 4610: 4064:"Ferroelectrics: A pathway to switchable surface chemistry and catalysis" 3949:; Fiebig, M. (2005). "The renaissance of magnetoelectric multiferroics". 3824: 3771: 3472: 294: 3923: 3665: 3349:{\displaystyle {\frac {\partial ^{2}\Delta E}{\partial P_{x}^{2}}}<0} 2114:{\displaystyle 0={\frac {\partial \Delta E}{\partial P_{x}}}=P_{s}\left} 517:. A single atom thick ferroelectric monolayer can be created using pure 178:
compared to dielectric (non-tunable) capacitors of similar capacitance.
105:, is almost exactly proportional to the applied external electric field 4961: 4433: 4328: 4311: 4062:
Kakekhani, Arvin; Ismail-Beigi, Sohrab; Altman, Eric I. (August 2016).
3481: – An inorganic, nonmetallic solid prepared by the action of heats 3454: – phenomenon in which a material may exhibit a spontaneous strain 3401: – Group of crystalline polar polymers that are also ferroelectric 3279:(but on the Y axis) gives an S-shaped curve which is multi-valued in P 2727:) may be obtained from the free energy expansion by including the term 398: 394: 244: 240: 182: 133: 4919: 4246: 4151: 4048: 3888: 227: 4579: 4546: 3632: 3600: 3548:. In Frederick Seitz; T. P. Das; David Turnbull; E. L. Hahn (eds.). 2578:{\displaystyle P_{s}=\pm {\sqrt {{\frac {1}{2\alpha _{111}}}\left}}} 479:
In 1974 R.B. Meyer used symmetry arguments to predict ferroelectric
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Principles and applications of ferroelectrics and related materials
457: 3901: 3757:; J.F. Scott (2005). "Physics of thin-film ferroelectric oxides". 181:
The spontaneous polarization of ferroelectric materials implies a
4505:"Piezoelectric and Pyroelectric Materials and Their Applications" 3478: 2949:, again by setting the derivative of the energy with respect to P 518: 4668:"Rutgers Physicists Create New Class of 2D Artificial Materials" 3697:
Piezoelectric and acoustic materials for transducer applications
4259: 3867:(2007). "Multiferroics: Progress and prospects in thin films". 2738:
corresponding to the energy due to an external electric field E
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solution of this equation rather corresponds to a free energy
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Whatmore, R. W. (1991), Miller, L. S.; Mullin, J. B. (eds.),
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An introduction to Landau theory can be found here. Based on
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in some ferroelectric crystals is still not well understood.
4688:"Artificial two-dimensional polar metal at room temperature" 3752: 3287:. The central part of the 'S' corresponds to a free energy 2621:, the solution for the spontaneous polarization reduces to: 4619: 4447:
Starr, Matthew B.; Shi, Jian; Wang, Xudong (11 June 2012).
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M. Fiebig (2005). "Revival of the magnetoelectric effect".
484: 190: 4642:"Discovery of ferroelectricity in an elementary substance" 4490:
McGraw-Hill Concise Encyclopedia of Science and Technology
2415:{\displaystyle P_{s}^{2}={\frac {1}{2\alpha _{111}}}\left} 251:. Polarization can help the separation of photo-generated 4752: 4598:
Poster Session Presented at ECAMP 2010, Salamanca, Spain.
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Domain Structure in Ferroelectrics and Related Materials
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An important ferroelectric material for applications is
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Kakekhani, Arvin; Ismail-Beigi, Sohrab (29 June 2015).
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3413: – Imaging technique using ferroelectric materials 3633:"Piezo-Electric and Allied Phenomena in Rochelle Salt" 3475: – Solid-state electronics based on electron spin 2136:
in the ferroelectric phase, the desired solutions for
1383:{\displaystyle \alpha _{i},\alpha _{ij},\alpha _{ijk}} 4419: 4175: 3699:. Springer Science & Business Media. p. 21. 3601:"Piezoelectric and allied phenomena in Rochelle salt" 3297: 3136: 2962: 2755: 2630: 2594: 2434: 2273: 2152: 1959: 1804: 1774: 1734: 1568: 1518: 1485: 1452: 1419: 1334: 1316:
are the components of the polarization vector in the
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is a characteristic of certain materials that have a
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Pages displaying wikidata descriptions as a fallback
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Pages displaying wikidata descriptions as a fallback
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Pages displaying wikidata descriptions as a fallback
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correspond to setting the remaining factor to zero:
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loop. They are called ferroelectrics by analogy to
4102: 3386: – capacitor based on a ferroelectric material 255:, leading to enhanced photocatalysis. Also, due to 4488:Land, Cecil (2004). "Photoferroelectric imaging". 3505: – Phenomena involving electrical occurrences 3348: 3254: 3119: 2927: 2708: 2613: 2577: 2414: 2253: 2113: 1942: 1787: 1760: 1717: 1537: 1504: 1471: 1438: 1382: 1284: 4999: 4884: 3572: 3514: – Overview of and topical guide to physics 3443: – Voltage created when a crystal is heated 4868:Physics of Ferroelectrics: A modern perspective 4780:Proceedings of the National Academy of Sciences 4680: 4353:Ferroelectric Materials for Energy Applications 1328:directions respectively, and the coefficients, 16:Characteristic of certain crystalline materials 4843: 4557: 4509:Electronic Materials: From Silicon to Organics 494:found that prosaic films of chemicals such as 4935: 4511:, Boston, MA: Springer US, pp. 283–290, 3945: 3862: 3543: 3463: – Polarization due to a strain gradient 194:sample quality for devices to work reliably. 4866:; Jean-Marc Triscone; Charles H Ahn (2007). 4446: 3359: 2938:We find the stable polarization values of P 505:Other ferroelectric materials used include 41:, in which a material exhibits a permanent 4942: 4928: 4746: 4350: 3727: 3630: 3598: 3552:. Vol. 4. Academic Press. p. 5. 2567: 2406: 124:, see figure) even when the applied field 4809: 4799: 4758: 4729: 4703: 4464: 4327: 4201: 4137: 4087: 4026: 3983: 3823: 3770: 3664: 2943:under the influence of the external field 1402:and solved subject to the constraints of 4774:Wu, Menghao; Li, Ju (14 December 2021). 4604: 4502: 4140:Journal of the American Chemical Society 357: 352: 341: 339: 88: 80: 72: 4949: 4453:Angewandte Chemie International Edition 3856: 3546:"Ferroelectrics and Antiferroelectrics" 209:Another idea of recent interest is the 5008:Electric and magnetic fields in matter 5000: 4592: 3694: 3679:Chiang, Y. et al.: Physical Ceramics, 3591: 453:found close to the 50/50 composition. 220:Yet another burgeoning application is 144:and exhibit similar hysteresis loops. 4923: 4551: 4171: 4169: 3986:Journal of Physics D: Applied Physics 3746: 3395: – Novel type of computer memory 1545:for a second order phase transition. 4773: 4492:(5 ed.). New York: McGraw-Hill. 4487: 4481: 3721: 3566: 3537: 3372: 4395:The Journal of Physical Chemistry C 2742:interacting with the polarization P 13: 4837: 4686:; Chakhalian, J. (18 April 2018). 4225:Decomposition on Metal Surfaces". 4166: 3803: 3319: 3311: 3302: 2977: 2969: 2966: 2756: 1980: 1972: 1969: 1819: 1811: 1808: 1569: 1472:{\displaystyle \alpha _{111}>0} 562: 140:materials, which have spontaneous 14: 5034: 4904: 4547:https://doi.org/10.1063/5.0057869 3272:(on the X axis) as a function of 1538:{\displaystyle \alpha _{11}>0} 1505:{\displaystyle \alpha _{11}<0} 544:in terms of the order parameter, 421:) or order-disorder (such as NaNO 4646:National University of Singapore 4422:Journal of Materials Chemistry A 3379:Category:Ferroelectric materials 1439:{\displaystyle \alpha _{0}>0} 4767: 4674: 4660: 4634: 4586: 4538: 4496: 4440: 4413: 4385: 4344: 4303: 4253: 4210: 4131: 4096: 4055: 4029:The Journal of Chemical Physics 4020: 168: 68: 4848:. Cambridge University Press. 4600:– via Aarhus University. 3688: 3673: 3405:Piezoresponse force microscopy 2614:{\displaystyle \alpha _{11}=0} 77:Linear dielectric polarization 1: 4227:Journal of Chemical Education 4117:10.1103/PhysRevLett.98.166101 3842:10.1103/PhysRevLett.94.246802 3531: 3518:Index of electronics articles 1413:In all known ferroelectrics, 211:ferroelectric tunnel junction 4517:10.1007/978-1-4615-3818-9_19 472:crystals. The nature of the 360: 311: 276: 101:, the polarization induced, 7: 3577:. Clarendon Press, Oxford. 3573:M. Lines; A. Glass (1979). 3367: 1761:{\displaystyle P_{x}=P_{s}} 466:domain structure hysteresis 265:(electro)chemical reactions 61:ferromagnetic are known as 10: 5039: 4722:10.1038/s41467-018-03964-9 4089:10.1016/j.susc.2015.10.055 4006:10.1088/0022-3727/38/8/R01 3789:10.1103/RevModPhys.77.1083 3411:Photoferroelectric imaging 271:Photoferroelectric imaging 93:Ferroelectric polarization 4957: 4885:Julio A. Gonzalo (2006). 4361:10.1002/9783527807505.ch9 3759:Reviews of Modern Physics 3469: – Branch of physics 531: 322: 314: 293:Generally, there are 230 85:Paraelectric polarization 4407:10.1021/acs.jpcc.5b04589 4316:Chemical Society Reviews 4203:10.1021/acscatal.5b00507 3467:Condensed matter physics 3360:Sliding ferroelectricity 1550:spontaneous polarization 1396:finite difference method 97:When most materials are 5013:Ferroelectric materials 4915:University of Cambridge 4911:Ferroelectric Materials 4844:A. S. Sidorkin (2006). 4801:10.1073/pnas.2115703118 4593:Plekan, Oksana (2010). 4560:Applied Physics Letters 4281:10.1126/science.aad4998 4105:Physical Review Letters 3963:10.1126/science.1113357 3812:Physical Review Letters 3384:Ferroelectric capacitor 511:polyvinylidene fluoride 462:transition temperatures 446:lead zirconate titanate 175:ferroelectric capacitor 4466:10.1002/anie.201201424 3730:Ferroelectric Memories 3695:Safari, Ahmad (2008). 3657:10.1103/PhysRev.17.475 3625:10.1103/PhysRev.15.505 3544:Werner Känzig (1957). 3350: 3256: 3121: 2929: 2719:The hysteresis loop (P 2710: 2615: 2579: 2416: 2255: 2115: 1944: 1789: 1762: 1719: 1539: 1506: 1473: 1440: 1384: 1286: 538:Ginzburg–Landau theory 323:21 noncentrosymmetric 99:electrically polarized 94: 86: 78: 4692:Nature Communications 3682:John Wiley & Sons 3399:Ferroelectric polymer 3351: 3257: 3122: 2930: 2711: 2616: 2580: 2417: 2256: 2116: 1945: 1790: 1788:{\displaystyle P_{s}} 1763: 1720: 1540: 1507: 1474: 1441: 1400:finite element method 1385: 1287: 526:Nature Communications 92: 84: 76: 27:electric polarization 5018:Electrical phenomena 4977:antiferroelectricity 4889:. World Scientific. 4355:. pp. 265–309. 3503:Electrical phenomena 3447:Antiferroelectricity 3295: 3283:for some values of E 3134: 2960: 2753: 2628: 2592: 2432: 2271: 2150: 1957: 1802: 1772: 1732: 1566: 1516: 1483: 1450: 1417: 1332: 555: 4951:Polarization states 4792:2021PNAS..11815703W 4786:(50): e2115703118. 4714:2018NatCo...9.1547C 4572:1980ApPhL..36..899C 4401:(32): 18278–18286. 4239:2011JChEd..88.1711L 4194:2015APS..MARY26011K 4146:(50): 15684–15689. 4080:2016SurSc.650..302K 4041:1952JChPh..20..342P 3998:2005JPhD...38R.123F 3924:10.1038/nature05023 3916:2006Natur.442..759E 3881:2007NatMa...6...21R 3834:2005PhRvL..94x6802Z 3781:2005RvMP...77.1083D 3728:J.F. Scott (2000). 3705:2008pamt.book.....S 3649:1921PhRv...17..475V 3631:J. Valasek (1921). 3617:1920PhRv...15..505. 3599:J. Valasek (1920). 3550:Solid State Physics 3336: 3251: 3223: 3097: 3069: 2901: 2863: 2825: 2512: 2351: 2288: 2264:whose solution is: 2244: 2216: 2105: 2077: 1939: 1911: 1714: 1676: 1638: 1277: 1262: 1247: 1194: 1176: 1156: 1133: 1115: 1095: 1072: 1054: 1034: 981: 963: 945: 892: 877: 859: 844: 826: 811: 758: 740: 722: 674: 656: 638: 460:often show several 317:Crystalline classes 299:crystalline classes 253:electron-hole pairs 53:. Thus, the prefix 4434:10.1039/C6TA00513F 4329:10.1039/c7cs00387k 4275:(6321): eaad4998. 3512:Outline of physics 3346: 3322: 3252: 3237: 3209: 3117: 3083: 3055: 2945:, now denoted as P 2925: 2887: 2849: 2811: 2706: 2611: 2575: 2498: 2412: 2337: 2274: 2251: 2230: 2202: 2111: 2091: 2063: 1940: 1925: 1897: 1785: 1758: 1715: 1700: 1662: 1624: 1535: 1502: 1469: 1436: 1380: 1282: 1280: 1263: 1248: 1233: 1180: 1162: 1142: 1119: 1101: 1081: 1058: 1040: 1020: 967: 949: 931: 878: 863: 845: 830: 812: 797: 744: 726: 708: 660: 642: 624: 507:triglycine sulfate 450:anti-ferroelectric 361:non ferroelectric 342:non piezoelectric 237:Sabatier principle 189:for computers and 95: 87: 79: 4995: 4994: 4896:978-981-256-875-5 4877:978-3-540-34591-6 4855:978-1-904602-14-9 4526:978-1-4615-3818-9 4459:(24): 5962–5966. 4428:(14): 5235–5246. 4322:(24): 7757–7786. 4247:10.1021/ed101010x 4233:(12): 1711–1715. 4152:10.1021/ja0762644 4049:10.1063/1.1700412 3739:978-3-540-66387-4 3584:978-0-19-851286-8 3559:978-0-12-607704-9 3528: 3527: 3393:Ferroelectric RAM 3338: 2991: 2875: 2837: 2773: 2704: 2698: 2573: 2565: 2473: 2404: 2312: 1994: 1833: 1688: 1650: 1586: 1408:Linear elasticity 1392:phase field model 1221: 1003: 914: 780: 691: 581: 515:lithium tantalate 415: 414: 353:non pyroelectric 232:Curie temperature 187:ferroelectric RAM 149:Curie temperature 5030: 5023:Phases of matter 4987:ferrielectricity 4972:ferroelectricity 4944: 4937: 4930: 4921: 4920: 4900: 4881: 4859: 4832: 4831: 4813: 4803: 4771: 4765: 4764: 4762: 4760:cond-mat/0609347 4750: 4744: 4743: 4733: 4707: 4678: 4672: 4671: 4664: 4658: 4657: 4655: 4653: 4638: 4632: 4631: 4629: 4627: 4617: 4608: 4602: 4601: 4590: 4584: 4583: 4555: 4549: 4542: 4536: 4535: 4534: 4533: 4500: 4494: 4493: 4485: 4479: 4478: 4468: 4444: 4438: 4437: 4417: 4411: 4410: 4389: 4383: 4382: 4348: 4342: 4341: 4331: 4307: 4301: 4300: 4266: 4257: 4251: 4250: 4214: 4208: 4207: 4205: 4188:(8): 4537–4545. 4173: 4164: 4163: 4135: 4129: 4128: 4100: 4094: 4093: 4091: 4059: 4053: 4052: 4024: 4018: 4017: 3982: 3943: 3910:(7104): 759–65. 3900: 3889:10.1038/nmat1805 3869:Nature Materials 3860: 3854: 3853: 3827: 3825:cond-mat/0502109 3818:(24): 246802–4. 3807: 3801: 3800: 3774: 3772:cond-mat/0503372 3750: 3744: 3743: 3725: 3719: 3718: 3692: 3686: 3677: 3671: 3670: 3668: 3628: 3595: 3589: 3588: 3570: 3564: 3563: 3541: 3508: 3490: 3461:Flexoelectricity 3457: 3435:Piezoelectricity 3431: 3389: 3373: 3355: 3353: 3352: 3347: 3339: 3337: 3335: 3330: 3317: 3310: 3309: 3299: 3261: 3259: 3258: 3253: 3250: 3245: 3236: 3235: 3222: 3217: 3208: 3207: 3195: 3194: 3185: 3181: 3180: 3179: 3159: 3158: 3146: 3145: 3126: 3124: 3123: 3118: 3110: 3109: 3096: 3091: 3082: 3081: 3068: 3063: 3054: 3053: 3041: 3040: 3031: 3027: 3026: 3025: 3005: 3004: 2992: 2990: 2989: 2988: 2975: 2964: 2934: 2932: 2931: 2926: 2924: 2923: 2914: 2913: 2900: 2895: 2886: 2885: 2876: 2868: 2862: 2857: 2848: 2847: 2838: 2830: 2824: 2819: 2810: 2806: 2805: 2804: 2784: 2783: 2774: 2766: 2715: 2713: 2712: 2707: 2705: 2703: 2697: 2696: 2687: 2686: 2682: 2675: 2674: 2660: 2659: 2649: 2648: 2640: 2639: 2620: 2618: 2617: 2612: 2604: 2603: 2584: 2582: 2581: 2576: 2574: 2572: 2568: 2566: 2564: 2560: 2553: 2552: 2538: 2537: 2528: 2527: 2511: 2506: 2497: 2492: 2491: 2474: 2472: 2471: 2470: 2454: 2452: 2444: 2443: 2421: 2419: 2418: 2413: 2411: 2407: 2405: 2403: 2399: 2392: 2391: 2377: 2376: 2367: 2366: 2350: 2345: 2336: 2331: 2330: 2313: 2311: 2310: 2309: 2293: 2287: 2282: 2260: 2258: 2257: 2252: 2243: 2238: 2229: 2228: 2215: 2210: 2201: 2200: 2188: 2184: 2183: 2182: 2162: 2161: 2120: 2118: 2117: 2112: 2110: 2106: 2104: 2099: 2090: 2089: 2076: 2071: 2062: 2061: 2049: 2045: 2044: 2043: 2023: 2022: 2008: 2007: 1995: 1993: 1992: 1991: 1978: 1967: 1949: 1947: 1946: 1941: 1938: 1933: 1924: 1923: 1910: 1905: 1896: 1895: 1883: 1882: 1873: 1869: 1868: 1867: 1847: 1846: 1834: 1832: 1831: 1830: 1817: 1806: 1794: 1792: 1791: 1786: 1784: 1783: 1767: 1765: 1764: 1759: 1757: 1756: 1744: 1743: 1724: 1722: 1721: 1716: 1713: 1708: 1699: 1698: 1689: 1681: 1675: 1670: 1661: 1660: 1651: 1643: 1637: 1632: 1623: 1619: 1618: 1617: 1597: 1596: 1587: 1579: 1544: 1542: 1541: 1536: 1528: 1527: 1511: 1509: 1508: 1503: 1495: 1494: 1478: 1476: 1475: 1470: 1462: 1461: 1445: 1443: 1442: 1437: 1429: 1428: 1389: 1387: 1386: 1381: 1379: 1378: 1360: 1359: 1344: 1343: 1291: 1289: 1288: 1283: 1281: 1276: 1271: 1261: 1256: 1246: 1241: 1232: 1231: 1222: 1214: 1208: 1204: 1200: 1199: 1195: 1193: 1188: 1175: 1170: 1155: 1150: 1138: 1134: 1132: 1127: 1114: 1109: 1094: 1089: 1077: 1073: 1071: 1066: 1053: 1048: 1033: 1028: 1014: 1013: 1004: 996: 990: 986: 982: 980: 975: 962: 957: 944: 939: 925: 924: 915: 907: 901: 897: 893: 891: 886: 876: 871: 858: 853: 843: 838: 825: 820: 810: 805: 791: 790: 781: 773: 767: 763: 759: 757: 752: 739: 734: 721: 716: 702: 701: 692: 684: 679: 675: 673: 668: 655: 650: 637: 632: 618: 614: 613: 612: 592: 591: 582: 574: 542:Taylor expansion 474:phase transition 312: 284:piezoelectricity 249:energy harvester 199:piezoelectricity 20:Ferroelectricity 5038: 5037: 5033: 5032: 5031: 5029: 5028: 5027: 4998: 4997: 4996: 4991: 4982:helielectricity 4967:paraelectricity 4953: 4948: 4907: 4897: 4878: 4856: 4840: 4838:Further reading 4835: 4772: 4768: 4751: 4747: 4679: 4675: 4666: 4665: 4661: 4651: 4649: 4640: 4639: 4635: 4625: 4623: 4615: 4609: 4605: 4591: 4587: 4580:10.1063/1.91359 4566:(11): 899–901. 4556: 4552: 4543: 4539: 4531: 4529: 4527: 4501: 4497: 4486: 4482: 4445: 4441: 4418: 4414: 4390: 4386: 4371: 4349: 4345: 4308: 4304: 4264: 4258: 4254: 4224: 4220: 4215: 4211: 4174: 4167: 4136: 4132: 4101: 4097: 4068:Surface Science 4060: 4056: 4025: 4021: 3957:(5733): 391–2. 3861: 3857: 3808: 3804: 3751: 3747: 3740: 3726: 3722: 3715: 3693: 3689: 3678: 3674: 3637:Physical Review 3605:Physical Review 3596: 3592: 3585: 3571: 3567: 3560: 3542: 3538: 3534: 3529: 3506: 3488: 3455: 3452:Ferroelasticity 3441:Pyroelectricity 3429: 3426:Paraelectricity 3387: 3370: 3362: 3331: 3326: 3318: 3305: 3301: 3300: 3298: 3296: 3293: 3292: 3286: 3282: 3277: 3270: 3246: 3241: 3231: 3227: 3218: 3213: 3203: 3199: 3190: 3186: 3175: 3171: 3164: 3160: 3154: 3150: 3141: 3137: 3135: 3132: 3131: 3105: 3101: 3092: 3087: 3077: 3073: 3064: 3059: 3049: 3045: 3036: 3032: 3021: 3017: 3010: 3006: 3000: 2996: 2984: 2980: 2976: 2965: 2963: 2961: 2958: 2957: 2952: 2948: 2941: 2919: 2915: 2909: 2905: 2896: 2891: 2881: 2877: 2867: 2858: 2853: 2843: 2839: 2829: 2820: 2815: 2800: 2796: 2789: 2785: 2779: 2775: 2765: 2754: 2751: 2750: 2745: 2741: 2736: 2732: 2726: 2722: 2699: 2692: 2688: 2670: 2666: 2665: 2661: 2655: 2651: 2650: 2647: 2635: 2631: 2629: 2626: 2625: 2599: 2595: 2593: 2590: 2589: 2548: 2544: 2543: 2539: 2533: 2529: 2523: 2519: 2507: 2502: 2496: 2487: 2483: 2479: 2475: 2466: 2462: 2458: 2453: 2451: 2439: 2435: 2433: 2430: 2429: 2387: 2383: 2382: 2378: 2372: 2368: 2362: 2358: 2346: 2341: 2335: 2326: 2322: 2318: 2314: 2305: 2301: 2297: 2292: 2283: 2278: 2272: 2269: 2268: 2239: 2234: 2224: 2220: 2211: 2206: 2196: 2192: 2178: 2174: 2167: 2163: 2157: 2153: 2151: 2148: 2147: 2141: 2129: 2100: 2095: 2085: 2081: 2072: 2067: 2057: 2053: 2039: 2035: 2028: 2024: 2018: 2014: 2013: 2009: 2003: 1999: 1987: 1983: 1979: 1968: 1966: 1958: 1955: 1954: 1934: 1929: 1919: 1915: 1906: 1901: 1891: 1887: 1878: 1874: 1863: 1859: 1852: 1848: 1842: 1838: 1826: 1822: 1818: 1807: 1805: 1803: 1800: 1799: 1779: 1775: 1773: 1770: 1769: 1752: 1748: 1739: 1735: 1733: 1730: 1729: 1709: 1704: 1694: 1690: 1680: 1671: 1666: 1656: 1652: 1642: 1633: 1628: 1613: 1609: 1602: 1598: 1592: 1588: 1578: 1567: 1564: 1563: 1557: 1523: 1519: 1517: 1514: 1513: 1490: 1486: 1484: 1481: 1480: 1457: 1453: 1451: 1448: 1447: 1424: 1420: 1418: 1415: 1414: 1368: 1364: 1352: 1348: 1339: 1335: 1333: 1330: 1329: 1314: 1307: 1300: 1279: 1278: 1272: 1267: 1257: 1252: 1242: 1237: 1227: 1223: 1213: 1206: 1205: 1189: 1184: 1171: 1166: 1161: 1157: 1151: 1146: 1128: 1123: 1110: 1105: 1100: 1096: 1090: 1085: 1067: 1062: 1049: 1044: 1039: 1035: 1029: 1024: 1019: 1015: 1009: 1005: 995: 988: 987: 976: 971: 958: 953: 940: 935: 930: 926: 920: 916: 906: 899: 898: 887: 882: 872: 867: 854: 849: 839: 834: 821: 816: 806: 801: 796: 792: 786: 782: 772: 765: 764: 753: 748: 735: 730: 717: 712: 707: 703: 697: 693: 683: 669: 664: 651: 646: 633: 628: 623: 619: 608: 604: 597: 593: 587: 583: 573: 571: 558: 556: 553: 552: 534: 481:liquid crystals 431:electric fields 427:barium titanate 424: 420: 386: 379: 371: 328:centrosymmetric 297:among which 32 288:pyroelectricity 279: 203:pyroelectricity 171: 164: 157: 71: 43:magnetic moment 17: 12: 11: 5: 5036: 5026: 5025: 5020: 5015: 5010: 4993: 4992: 4990: 4989: 4984: 4979: 4974: 4969: 4964: 4958: 4955: 4954: 4947: 4946: 4939: 4932: 4924: 4918: 4917: 4906: 4905:External links 4903: 4902: 4901: 4895: 4882: 4876: 4860: 4854: 4839: 4836: 4834: 4833: 4766: 4745: 4684:Rabe, Karin M. 4673: 4659: 4633: 4603: 4585: 4550: 4537: 4525: 4495: 4480: 4439: 4412: 4384: 4369: 4343: 4302: 4252: 4222: 4218: 4209: 4165: 4130: 4111:(16): 166101. 4095: 4054: 4035:(2): 342–343. 4019: 3855: 3802: 3745: 3738: 3720: 3714:978-0387765402 3713: 3687: 3685:1997, New York 3672: 3590: 3583: 3565: 3558: 3535: 3533: 3530: 3526: 3525: 3521: 3520: 3515: 3509: 3493: 3492: 3491: 3482: 3476: 3470: 3464: 3458: 3449: 3444: 3438: 3432: 3416: 3415: 3414: 3408: 3402: 3396: 3390: 3381: 3371: 3369: 3366: 3361: 3358: 3345: 3342: 3334: 3329: 3325: 3321: 3316: 3313: 3308: 3304: 3284: 3280: 3275: 3268: 3263: 3262: 3249: 3244: 3240: 3234: 3230: 3226: 3221: 3216: 3212: 3206: 3202: 3198: 3193: 3189: 3184: 3178: 3174: 3170: 3167: 3163: 3157: 3153: 3149: 3144: 3140: 3128: 3127: 3116: 3113: 3108: 3104: 3100: 3095: 3090: 3086: 3080: 3076: 3072: 3067: 3062: 3058: 3052: 3048: 3044: 3039: 3035: 3030: 3024: 3020: 3016: 3013: 3009: 3003: 2999: 2995: 2987: 2983: 2979: 2974: 2971: 2968: 2950: 2946: 2939: 2936: 2935: 2922: 2918: 2912: 2908: 2904: 2899: 2894: 2890: 2884: 2880: 2874: 2871: 2866: 2861: 2856: 2852: 2846: 2842: 2836: 2833: 2828: 2823: 2818: 2814: 2809: 2803: 2799: 2795: 2792: 2788: 2782: 2778: 2772: 2769: 2764: 2761: 2758: 2746:, as follows: 2743: 2739: 2734: 2730: 2724: 2720: 2717: 2716: 2702: 2695: 2691: 2685: 2681: 2678: 2673: 2669: 2664: 2658: 2654: 2646: 2643: 2638: 2634: 2610: 2607: 2602: 2598: 2586: 2585: 2571: 2563: 2559: 2556: 2551: 2547: 2542: 2536: 2532: 2526: 2522: 2518: 2515: 2510: 2505: 2501: 2495: 2490: 2486: 2482: 2478: 2469: 2465: 2461: 2457: 2450: 2447: 2442: 2438: 2423: 2422: 2410: 2402: 2398: 2395: 2390: 2386: 2381: 2375: 2371: 2365: 2361: 2357: 2354: 2349: 2344: 2340: 2334: 2329: 2325: 2321: 2317: 2308: 2304: 2300: 2296: 2291: 2286: 2281: 2277: 2262: 2261: 2250: 2247: 2242: 2237: 2233: 2227: 2223: 2219: 2214: 2209: 2205: 2199: 2195: 2191: 2187: 2181: 2177: 2173: 2170: 2166: 2160: 2156: 2139: 2127: 2122: 2121: 2109: 2103: 2098: 2094: 2088: 2084: 2080: 2075: 2070: 2066: 2060: 2056: 2052: 2048: 2042: 2038: 2034: 2031: 2027: 2021: 2017: 2012: 2006: 2002: 1998: 1990: 1986: 1982: 1977: 1974: 1971: 1965: 1962: 1951: 1950: 1937: 1932: 1928: 1922: 1918: 1914: 1909: 1904: 1900: 1894: 1890: 1886: 1881: 1877: 1872: 1866: 1862: 1858: 1855: 1851: 1845: 1841: 1837: 1829: 1825: 1821: 1816: 1813: 1810: 1782: 1778: 1755: 1751: 1747: 1742: 1738: 1726: 1725: 1712: 1707: 1703: 1697: 1693: 1687: 1684: 1679: 1674: 1669: 1665: 1659: 1655: 1649: 1646: 1641: 1636: 1631: 1627: 1622: 1616: 1612: 1608: 1605: 1601: 1595: 1591: 1585: 1582: 1577: 1574: 1571: 1555: 1534: 1531: 1526: 1522: 1501: 1498: 1493: 1489: 1468: 1465: 1460: 1456: 1435: 1432: 1427: 1423: 1377: 1374: 1371: 1367: 1363: 1358: 1355: 1351: 1347: 1342: 1338: 1312: 1305: 1298: 1293: 1292: 1275: 1270: 1266: 1260: 1255: 1251: 1245: 1240: 1236: 1230: 1226: 1220: 1217: 1212: 1209: 1207: 1203: 1198: 1192: 1187: 1183: 1179: 1174: 1169: 1165: 1160: 1154: 1149: 1145: 1141: 1137: 1131: 1126: 1122: 1118: 1113: 1108: 1104: 1099: 1093: 1088: 1084: 1080: 1076: 1070: 1065: 1061: 1057: 1052: 1047: 1043: 1038: 1032: 1027: 1023: 1018: 1012: 1008: 1002: 999: 994: 991: 989: 985: 979: 974: 970: 966: 961: 956: 952: 948: 943: 938: 934: 929: 923: 919: 913: 910: 905: 902: 900: 896: 890: 885: 881: 875: 870: 866: 862: 857: 852: 848: 842: 837: 833: 829: 824: 819: 815: 809: 804: 800: 795: 789: 785: 779: 776: 771: 768: 766: 762: 756: 751: 747: 743: 738: 733: 729: 725: 720: 715: 711: 706: 700: 696: 690: 687: 682: 678: 672: 667: 663: 659: 654: 649: 645: 641: 636: 631: 627: 622: 617: 611: 607: 603: 600: 596: 590: 586: 580: 577: 572: 570: 567: 564: 561: 560: 533: 530: 456:Ferroelectric 422: 418: 413: 412: 402: 391: 384: 377: 369: 363: 362: 359: 358:ferroelectric 355: 354: 351: 344: 343: 340: 338: 331: 330: 324: 320: 319: 278: 275: 170: 167: 162: 155: 70: 67: 51:Joseph Valasek 39:ferromagnetism 15: 9: 6: 4: 3: 2: 5035: 5024: 5021: 5019: 5016: 5014: 5011: 5009: 5006: 5005: 5003: 4988: 4985: 4983: 4980: 4978: 4975: 4973: 4970: 4968: 4965: 4963: 4960: 4959: 4956: 4952: 4945: 4940: 4938: 4933: 4931: 4926: 4925: 4922: 4916: 4912: 4909: 4908: 4898: 4892: 4888: 4883: 4879: 4873: 4869: 4865: 4861: 4857: 4851: 4847: 4842: 4841: 4829: 4825: 4821: 4817: 4812: 4807: 4802: 4797: 4793: 4789: 4785: 4781: 4777: 4770: 4761: 4756: 4749: 4741: 4737: 4732: 4727: 4723: 4719: 4715: 4711: 4706: 4701: 4697: 4693: 4689: 4685: 4677: 4669: 4663: 4647: 4643: 4637: 4621: 4614: 4607: 4599: 4596: 4589: 4581: 4577: 4573: 4569: 4565: 4561: 4554: 4548: 4541: 4528: 4522: 4518: 4514: 4510: 4506: 4499: 4491: 4484: 4476: 4472: 4467: 4462: 4458: 4454: 4450: 4443: 4435: 4431: 4427: 4423: 4416: 4408: 4404: 4400: 4396: 4388: 4380: 4376: 4372: 4370:9783527807505 4366: 4362: 4358: 4354: 4347: 4339: 4335: 4330: 4325: 4321: 4317: 4313: 4306: 4298: 4294: 4290: 4286: 4282: 4278: 4274: 4270: 4263: 4256: 4248: 4244: 4240: 4236: 4232: 4228: 4213: 4204: 4199: 4195: 4191: 4187: 4183: 4182:ACS Catalysis 4179: 4172: 4170: 4161: 4157: 4153: 4149: 4145: 4141: 4134: 4126: 4122: 4118: 4114: 4110: 4106: 4099: 4090: 4085: 4081: 4077: 4073: 4069: 4065: 4058: 4050: 4046: 4042: 4038: 4034: 4030: 4023: 4015: 4011: 4007: 4003: 3999: 3995: 3991: 3987: 3980: 3976: 3972: 3968: 3964: 3960: 3956: 3952: 3948: 3947:Spaldin, N.A. 3941: 3937: 3933: 3929: 3925: 3921: 3917: 3913: 3909: 3905: 3898: 3894: 3890: 3886: 3882: 3878: 3874: 3870: 3866: 3859: 3851: 3847: 3843: 3839: 3835: 3831: 3826: 3821: 3817: 3813: 3806: 3798: 3794: 3790: 3786: 3782: 3778: 3773: 3768: 3764: 3760: 3756: 3749: 3741: 3735: 3731: 3724: 3716: 3710: 3706: 3702: 3698: 3691: 3684: 3683: 3676: 3667: 3662: 3658: 3654: 3650: 3646: 3642: 3638: 3634: 3626: 3622: 3618: 3614: 3610: 3606: 3602: 3594: 3586: 3580: 3576: 3569: 3561: 3555: 3551: 3547: 3540: 3536: 3524: 3519: 3516: 3513: 3510: 3504: 3501: 3500: 3499: 3498: 3494: 3486: 3485:Multiferroics 3483: 3480: 3477: 3474: 3471: 3468: 3465: 3462: 3459: 3453: 3450: 3448: 3445: 3442: 3439: 3436: 3433: 3427: 3424: 3423: 3422: 3421: 3417: 3412: 3409: 3406: 3403: 3400: 3397: 3394: 3391: 3385: 3382: 3380: 3377: 3376: 3375: 3374: 3365: 3357: 3343: 3340: 3332: 3327: 3323: 3314: 3306: 3290: 3289:local maximum 3278: 3271: 3247: 3242: 3238: 3232: 3228: 3224: 3219: 3214: 3210: 3204: 3200: 3196: 3191: 3187: 3182: 3176: 3172: 3168: 3165: 3161: 3155: 3151: 3147: 3142: 3138: 3130: 3129: 3114: 3111: 3106: 3102: 3098: 3093: 3088: 3084: 3078: 3074: 3070: 3065: 3060: 3056: 3050: 3046: 3042: 3037: 3033: 3028: 3022: 3018: 3014: 3011: 3007: 3001: 2997: 2993: 2985: 2981: 2972: 2956: 2955: 2954: 2944: 2920: 2916: 2910: 2906: 2902: 2897: 2892: 2888: 2882: 2878: 2872: 2869: 2864: 2859: 2854: 2850: 2844: 2840: 2834: 2831: 2826: 2821: 2816: 2812: 2807: 2801: 2797: 2793: 2790: 2786: 2780: 2776: 2770: 2767: 2762: 2759: 2749: 2748: 2747: 2737: 2700: 2693: 2689: 2683: 2679: 2676: 2671: 2667: 2662: 2656: 2652: 2644: 2641: 2636: 2632: 2624: 2623: 2622: 2608: 2605: 2600: 2596: 2569: 2561: 2557: 2554: 2549: 2545: 2540: 2534: 2530: 2524: 2520: 2516: 2513: 2508: 2503: 2499: 2493: 2488: 2484: 2480: 2476: 2467: 2463: 2459: 2455: 2448: 2445: 2440: 2436: 2428: 2427: 2426: 2408: 2400: 2396: 2393: 2388: 2384: 2379: 2373: 2369: 2363: 2359: 2355: 2352: 2347: 2342: 2338: 2332: 2327: 2323: 2319: 2315: 2306: 2302: 2298: 2294: 2289: 2284: 2279: 2275: 2267: 2266: 2265: 2248: 2245: 2240: 2235: 2231: 2225: 2221: 2217: 2212: 2207: 2203: 2197: 2193: 2189: 2185: 2179: 2175: 2171: 2168: 2164: 2158: 2154: 2146: 2145: 2144: 2142: 2135: 2131: 2107: 2101: 2096: 2092: 2086: 2082: 2078: 2073: 2068: 2064: 2058: 2054: 2050: 2046: 2040: 2036: 2032: 2029: 2025: 2019: 2015: 2010: 2004: 2000: 1996: 1988: 1984: 1975: 1963: 1960: 1953: 1952: 1935: 1930: 1926: 1920: 1916: 1912: 1907: 1902: 1898: 1892: 1888: 1884: 1879: 1875: 1870: 1864: 1860: 1856: 1853: 1849: 1843: 1839: 1835: 1827: 1823: 1814: 1798: 1797: 1796: 1780: 1776: 1753: 1749: 1745: 1740: 1736: 1710: 1705: 1701: 1695: 1691: 1685: 1682: 1677: 1672: 1667: 1663: 1657: 1653: 1647: 1644: 1639: 1634: 1629: 1625: 1620: 1614: 1610: 1606: 1603: 1599: 1593: 1589: 1583: 1580: 1575: 1572: 1562: 1561: 1560: 1558: 1551: 1546: 1532: 1529: 1524: 1520: 1499: 1496: 1491: 1487: 1466: 1463: 1458: 1454: 1433: 1430: 1425: 1421: 1411: 1409: 1405: 1401: 1397: 1393: 1375: 1372: 1369: 1365: 1361: 1356: 1353: 1349: 1345: 1340: 1336: 1327: 1323: 1319: 1315: 1308: 1301: 1273: 1268: 1264: 1258: 1253: 1249: 1243: 1238: 1234: 1228: 1224: 1218: 1215: 1210: 1201: 1196: 1190: 1185: 1181: 1177: 1172: 1167: 1163: 1158: 1152: 1147: 1143: 1139: 1135: 1129: 1124: 1120: 1116: 1111: 1106: 1102: 1097: 1091: 1086: 1082: 1078: 1074: 1068: 1063: 1059: 1055: 1050: 1045: 1041: 1036: 1030: 1025: 1021: 1016: 1010: 1006: 1000: 997: 992: 983: 977: 972: 968: 964: 959: 954: 950: 946: 941: 936: 932: 927: 921: 917: 911: 908: 903: 894: 888: 883: 879: 873: 868: 864: 860: 855: 850: 846: 840: 835: 831: 827: 822: 817: 813: 807: 802: 798: 793: 787: 783: 777: 774: 769: 760: 754: 749: 745: 741: 736: 731: 727: 723: 718: 713: 709: 704: 698: 694: 688: 685: 680: 676: 670: 665: 661: 657: 652: 647: 643: 639: 634: 629: 625: 620: 615: 609: 605: 601: 598: 594: 588: 584: 578: 575: 568: 565: 551: 550: 549: 547: 543: 539: 529: 527: 522: 520: 516: 512: 508: 503: 501: 500:spontelectric 497: 496:nitrous oxide 493: 488: 486: 482: 477: 475: 471: 470:ferromagnetic 468:, much as do 467: 463: 459: 454: 451: 447: 442: 440: 439:lead titanate 436: 432: 428: 411: 407: 403: 400: 396: 392: 390: 383: 376: 372: 365: 364: 356: 350: 345: 337: 336:piezoelectric 332: 329: 325: 321: 318: 313: 310: 308: 304: 303:piezoelectric 300: 296: 291: 289: 285: 274: 272: 268: 266: 262: 261:piezoelectric 258: 254: 250: 246: 242: 238: 233: 229: 225: 223: 222:multiferroics 218: 216: 212: 207: 204: 200: 195: 192: 188: 184: 179: 176: 166: 161: 154: 150: 145: 143: 142:magnetization 139: 138:ferromagnetic 135: 131: 127: 123: 118: 116: 112: 108: 104: 100: 91: 83: 75: 66: 64: 63:multiferroics 60: 56: 52: 48: 47:Rochelle salt 44: 40: 36: 32: 31:piezoelectric 28: 25: 21: 4971: 4886: 4870:. Springer. 4867: 4864:Karin M Rabe 4845: 4783: 4779: 4769: 4748: 4695: 4691: 4676: 4662: 4650:. Retrieved 4648:. April 2023 4636: 4624:. Retrieved 4606: 4597: 4588: 4563: 4559: 4553: 4540: 4530:, retrieved 4508: 4498: 4489: 4483: 4456: 4452: 4442: 4425: 4421: 4415: 4398: 4394: 4387: 4352: 4346: 4319: 4315: 4305: 4272: 4268: 4255: 4230: 4226: 4212: 4185: 4181: 4143: 4139: 4133: 4108: 4104: 4098: 4071: 4067: 4057: 4032: 4028: 4022: 3989: 3985: 3954: 3950: 3907: 3903: 3872: 3868: 3865:Spaldin, N.A 3863:Ramesh, R.; 3858: 3815: 3811: 3805: 3762: 3758: 3748: 3732:. Springer. 3729: 3723: 3696: 3690: 3680: 3675: 3666:11299/179514 3640: 3636: 3608: 3604: 3593: 3574: 3568: 3549: 3539: 3522: 3496: 3495: 3419: 3418: 3363: 3273: 3266: 3264: 2942: 2937: 2728: 2718: 2587: 2424: 2263: 2137: 2133: 2125: 2123: 1727: 1553: 1549: 1547: 1412: 1325: 1321: 1317: 1310: 1303: 1296: 1294: 545: 535: 525: 523: 504: 489: 478: 455: 443: 416: 404:e.g. : 393:e.g. : 366:e.g. : 349:pyroelectric 307:pyroelectric 295:space groups 292: 280: 269: 257:pyroelectric 226: 219: 214: 210: 208: 196: 180: 172: 169:Applications 159: 152: 146: 129: 125: 119: 115:permittivity 111:paraelectric 106: 102: 96: 69:Polarization 58: 54: 35:pyroelectric 19: 18: 4698:(1): 1547. 4622:. p. 3 4074:: 302–316. 3992:(8): R123. 3875:(1): 21–9. 3765:(4): 1083. 3753:M. Dawber; 3473:Spintronics 1512:, whereas 1404:Gauss's law 513:(PVDF) and 492:David Field 347:10 classes 334:20 classes 122:entrainment 24:spontaneous 5002:Categories 4962:dielectric 4705:1804.05487 4532:2022-09-22 3643:(4): 475. 3611:(6): 537. 3532:References 2124:Since the 395:Tourmaline 245:desorption 243:to strong 241:adsorption 183:hysteresis 134:hysteresis 4828:244872105 4379:104740681 4297:217918130 4014:121588385 3979:118513837 3755:K.M. Rabe 3320:∂ 3312:Δ 3303:∂ 3265:Plotting 3229:α 3201:α 3169:− 3152:α 3099:− 3075:α 3047:α 3015:− 2998:α 2978:∂ 2970:Δ 2967:∂ 2953:to zero: 2903:− 2879:α 2841:α 2794:− 2777:α 2757:Δ 2690:α 2677:− 2653:α 2645:± 2597:α 2555:− 2531:α 2521:α 2500:α 2485:α 2481:− 2464:α 2449:± 2394:− 2370:α 2360:α 2339:α 2333:± 2324:α 2320:− 2303:α 2222:α 2194:α 2172:− 2155:α 2083:α 2055:α 2033:− 2016:α 1981:∂ 1973:Δ 1970:∂ 1917:α 1889:α 1857:− 1840:α 1820:∂ 1812:Δ 1809:∂ 1692:α 1654:α 1607:− 1590:α 1570:Δ 1521:α 1488:α 1455:α 1422:α 1366:α 1350:α 1337:α 1225:α 1007:α 918:α 784:α 695:α 602:− 585:α 563:Δ 410:Langasite 277:Materials 267:forward. 228:Catalytic 4820:34862304 4740:29670098 4652:10 April 4475:22556008 4338:29125613 4289:28082532 4160:18034485 4125:17501432 3971:16020720 3932:16915279 3897:17199122 3850:15093350 3368:See also 2723:versus E 490:In 2010 458:crystals 368:PbZr/TiO 130:reversed 4811:8685923 4788:Bibcode 4731:5906683 4710:Bibcode 4626:26 July 4568:Bibcode 4269:Science 4235:Bibcode 4190:Bibcode 4076:Bibcode 4037:Bibcode 3994:Bibcode 3951:Science 3940:4387694 3912:Bibcode 3877:Bibcode 3830:Bibcode 3797:7517767 3777:Bibcode 3701:Bibcode 3645:Bibcode 3613:Bibcode 3479:Ceramic 3420:Physics 3291:(since 519:bismuth 4893:  4874:  4852:  4826:  4818:  4808:  4738:  4728:  4523:  4473:  4377:  4367:  4336:  4295:  4287:  4158:  4123:  4012:  3977:  3969:  3938:  3930:  3904:Nature 3895:  3848:  3795:  3736:  3711:  3581:  3556:  3523: 2134:maxima 1324:, and 1309:, and 1295:where 532:Theory 435:forces 406:Quartz 201:, and 4824:S2CID 4755:arXiv 4700:arXiv 4616:(PDF) 4375:S2CID 4293:S2CID 4265:(PDF) 4010:S2CID 3975:S2CID 3936:S2CID 3846:S2CID 3820:arXiv 3793:S2CID 3767:arXiv 3497:Lists 382:PbTiO 375:BaTiO 55:ferro 4891:ISBN 4872:ISBN 4850:ISBN 4816:PMID 4736:PMID 4654:2023 4628:2013 4620:NASA 4521:ISBN 4471:PMID 4365:ISBN 4334:PMID 4285:PMID 4156:PMID 4121:PMID 3967:PMID 3928:PMID 3893:PMID 3734:ISBN 3709:ISBN 3629:and 3597:See 3579:ISBN 3554:ISBN 3341:< 1548:The 1530:> 1497:< 1464:> 1446:and 1431:> 1406:and 485:LCoS 464:and 259:and 191:RFID 33:and 4913:at 4806:PMC 4796:doi 4784:118 4726:PMC 4718:doi 4576:doi 4513:doi 4461:doi 4430:doi 4403:doi 4399:119 4357:doi 4324:doi 4277:doi 4273:355 4243:doi 4198:doi 4148:doi 4144:129 4113:doi 4084:doi 4072:650 4045:doi 4002:doi 3959:doi 3955:309 3920:doi 3908:442 3885:doi 3838:doi 3785:doi 3661:hdl 3653:doi 3621:doi 3233:111 3079:111 2883:111 2694:111 2588:If 2535:111 2468:111 2374:111 2307:111 2226:111 2130:= 0 2087:111 1921:111 1696:111 1459:111 1398:or 1229:123 1011:112 922:111 521:. 399:ZnO 389:AlN 326:11 315:32 215:FTJ 59:and 49:by 5004:: 4822:. 4814:. 4804:. 4794:. 4782:. 4778:. 4734:. 4724:. 4716:. 4708:. 4694:. 4690:. 4644:. 4618:. 4574:. 4564:36 4562:. 4519:, 4507:, 4469:. 4457:51 4455:. 4451:. 4424:. 4397:. 4373:. 4363:. 4332:. 4320:46 4318:. 4314:. 4291:. 4283:. 4271:. 4267:. 4241:. 4231:88 4229:. 4196:. 4184:. 4180:. 4168:^ 4154:. 4142:. 4119:. 4109:98 4107:. 4082:. 4070:. 4066:. 4043:. 4033:20 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3787:: 3779:: 3769:: 3742:. 3717:. 3703:: 3669:. 3663:: 3655:: 3647:: 3627:. 3623:: 3615:: 3587:. 3562:. 3344:0 3333:2 3328:x 3324:P 3315:E 3307:2 3285:x 3281:e 3276:e 3274:P 3269:x 3267:E 3248:5 3243:e 3239:P 3225:+ 3220:3 3215:e 3211:P 3197:+ 3192:e 3188:P 3183:) 3177:0 3173:T 3166:T 3162:( 3156:0 3148:= 3143:x 3139:E 3115:0 3112:= 3107:x 3103:E 3094:5 3089:x 3085:P 3071:+ 3066:3 3061:x 3057:P 3043:+ 3038:x 3034:P 3029:) 3023:0 3019:T 3012:T 3008:( 3002:0 2994:= 2986:x 2982:P 2973:E 2951:x 2947:e 2940:x 2921:x 2917:P 2911:x 2907:E 2898:6 2893:x 2889:P 2873:6 2870:1 2865:+ 2860:4 2855:x 2851:P 2835:4 2832:1 2827:+ 2822:2 2817:x 2813:P 2808:) 2802:0 2798:T 2791:T 2787:( 2781:0 2771:2 2768:1 2763:= 2760:E 2744:x 2740:x 2735:x 2733:P 2731:x 2725:x 2721:x 2701:4 2684:) 2680:T 2672:0 2668:T 2663:( 2657:0 2642:= 2637:s 2633:P 2609:0 2606:= 2570:] 2562:) 2558:T 2550:0 2546:T 2541:( 2525:0 2517:4 2514:+ 2509:2 2494:+ 2477:[ 2460:2 2456:1 2446:= 2441:s 2437:P 2409:] 2401:) 2397:T 2389:0 2385:T 2380:( 2364:0 2356:4 2353:+ 2348:2 2316:[ 2299:2 2295:1 2290:= 2285:2 2280:s 2276:P 2249:0 2246:= 2241:4 2236:s 2232:P 2218:+ 2213:2 2208:s 2204:P 2190:+ 2186:) 2180:0 2176:T 2169:T 2165:( 2159:0 2140:s 2138:P 2128:s 2126:P 2108:] 2102:4 2097:s 2093:P 2079:+ 2074:2 2069:s 2065:P 2051:+ 2047:) 2041:0 2037:T 2030:T 2026:( 2020:0 2011:[ 2005:s 2001:P 1997:= 1989:x 1985:P 1976:E 1964:= 1961:0 1936:5 1931:x 1927:P 1913:+ 1908:3 1903:x 1899:P 1885:+ 1880:x 1876:P 1871:) 1865:0 1861:T 1854:T 1850:( 1844:0 1836:= 1828:x 1824:P 1815:E 1781:s 1777:P 1754:s 1750:P 1746:= 1741:x 1737:P 1711:6 1706:x 1702:P 1686:6 1683:1 1678:+ 1673:4 1668:x 1664:P 1648:4 1645:1 1640:+ 1635:2 1630:x 1626:P 1621:) 1615:0 1611:T 1604:T 1600:( 1594:0 1584:2 1581:1 1576:= 1573:E 1556:s 1554:P 1533:0 1500:0 1467:0 1434:0 1426:0 1376:k 1373:j 1370:i 1362:, 1357:j 1354:i 1346:, 1341:i 1326:z 1322:y 1318:x 1313:z 1311:P 1306:y 1304:P 1299:x 1297:P 1274:2 1269:z 1265:P 1259:2 1254:y 1250:P 1244:2 1239:x 1235:P 1219:2 1216:1 1211:+ 1202:] 1197:) 1191:2 1186:y 1182:P 1178:+ 1173:2 1168:x 1164:P 1159:( 1153:4 1148:z 1144:P 1140:+ 1136:) 1130:2 1125:z 1121:P 1117:+ 1112:2 1107:x 1103:P 1098:( 1092:4 1087:y 1083:P 1079:+ 1075:) 1069:2 1064:z 1060:P 1056:+ 1051:2 1046:y 1042:P 1037:( 1031:4 1026:x 1022:P 1017:[ 1001:2 998:1 993:+ 984:) 978:6 973:z 969:P 965:+ 960:6 955:y 951:P 947:+ 942:6 937:x 933:P 928:( 912:6 909:1 904:+ 895:) 889:2 884:x 880:P 874:2 869:z 865:P 861:+ 856:2 851:z 847:P 841:2 836:y 832:P 828:+ 823:2 818:y 814:P 808:2 803:x 799:P 794:( 778:2 775:1 770:+ 761:) 755:4 750:z 746:P 742:+ 737:4 732:y 728:P 724:+ 719:4 714:x 710:P 705:( 689:4 686:1 681:+ 677:) 671:2 666:z 662:P 658:+ 653:2 648:y 644:P 640:+ 635:2 630:x 626:P 621:( 616:) 610:0 606:T 599:T 595:( 589:0 579:2 576:1 569:= 566:E 546:P 423:2 419:3 385:3 378:3 370:3 213:( 163:C 160:T 156:C 153:T 151:( 126:E 107:E 103:P

Index

spontaneous
electric polarization
piezoelectric
pyroelectric
ferromagnetism
magnetic moment
Rochelle salt
Joseph Valasek
multiferroics



electrically polarized
paraelectric
permittivity
entrainment
hysteresis
ferromagnetic
magnetization
Curie temperature
ferroelectric capacitor
hysteresis
ferroelectric RAM
RFID
piezoelectricity
pyroelectricity
multiferroics
Catalytic
Curie temperature
Sabatier principle

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