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Flash point

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parameters, the procedure for the operator or automated apparatus to follow, and the precision of the test method. Standard test methods are written and controlled by a number of national and international committees and organizations. The three main bodies are the CEN / ISO Joint Working Group on Flash Point (JWG-FP), ASTM D02.8B Flammability Section and the Energy Institute's TMS SC-B-4 Flammability Panel.
1911: 992: 360: 153:. In addition to the Penskey-Martens flash point testers, other non-equilibrial testers include TAG and Abel, both of which are capable of cooling the sample below ambient for low flash point materials. The TAG flash point tester adheres to ASTM D56 and has no stirrer, while the Abel flash point testers adheres to IP 170 and ISO 13736 and has a stirring motor so the sample is stirred during testing. 117:. As temperature increases, vapor pressure increases. As vapor pressure increases, the concentration of vapor of a flammable or combustible liquid in the air increases. Hence, temperature determines the concentration of vapor of the flammable liquid in the air. A certain concentration of a flammable or combustible vapor is necessary to sustain combustion in air, the 149:
with the liquid. In both these types, the cups are sealed with a lid through which the ignition source can be introduced. Closed cup testers normally give lower values for the flash point than open cup (typically 5–10 °C or 9–18 °F lower) and are a better approximation to the temperature at which the vapour pressure reaches the
137:. In open cup devices, the sample is contained in an open cup which is heated and, at intervals, a flame brought over the surface. The measured flash point will actually vary with the height of the flame above the liquid surface and, at sufficient height, the measured flash point temperature will coincide with the 156:
The flash point is an empirical measurement rather than a fundamental physical parameter. The measured value will vary with equipment and test protocol variations, including temperature ramp rate (in automated testers), time allowed for the sample to equilibrate, sample volume and whether the sample
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There are two types of closed cup testers: non-equilibrial, such as Pensky-Martens, where the vapours above the liquid are not in temperature equilibrium with the liquid, and equilibrial, such as Small Scale (commonly known as Setaflash), where the vapours are deemed to be in temperature equilibrium
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Flash points of substances are measured according to standard test methods described and defined in a 1938 publication by T.L. Ainsley of South Shields entitled "Sea Transport of Petroleum" (Capt. P. Jansen). The test methodology defines the apparatus required to carry out the measurement, key test
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of the fuel, which is then injected as a high-pressure spray, keeping the fuel-air mix within flammable limits. A diesel-fueled engine has no ignition source (such as the spark plugs in a gasoline engine), so diesel fuel can have a high flash point, but must have a low autoignition temperature.
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is the lowest temperature at which the vapors keep burning after the ignition source is removed. It is higher than the flash point, because at the flash point vapor may not be produced fast enough to sustain combustion. Neither flash point nor fire point depends directly on the ignition source
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flash points also vary with the composition of the fuel. Both Jet A and Jet A-1 have flash points between 38 and 66 °C (100 and 151 °F), close to that of off-the-shelf kerosene. Yet both Jet B and JP-4 have flash points between −23 and −1 °C (−9 and 30 °F).
121:, and that concentration is specific to each flammable or combustible liquid. The flash point is the lowest temperature at which there will be enough flammable vapor to support combustion when an ignition source is applied. 41:
of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1)
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D93, IP34, ISO 2719, DIN 51758, JIS K2265 and AFNOR M07-019. Determination of flash point by the Small Scale closed cup method is detailed in ASTM D3828 and D3278, EN ISO 3679 and 3680, and IP 523 and 524.
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temperature, but ignition source temperature is far higher than either the flash or fire point, and can increase the temperature of fuel above the usual ambient temperature to facilitate ignition.
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of fuels. Fuels which have a flash point less than 37.8 °C (100.0 °F) are called flammable, whereas fuels having a flash point above that temperature are called combustible.
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CEN/TR 15138 Guide to Flash Point Testing and ISO TR 29662 Guidance for Flash Point Testing cover the key aspects of flash point testing.
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Methods for determining the flash point of a liquid are specified in many standards. For example, testing by the
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flash points vary between 52 and 96 °C (126 and 205 °F). Diesel is suitable for use in a
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The flash point is a descriptive characteristic that is used to distinguish between
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Lowest temperature at which a volatile material's vapors ignite if given a source
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caused by residual heat in a hot combustion chamber, the fuel must have a high
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Sea Transport of Petroleum, Jansen and Hayes, Ainsley, South Shields 1938
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National Council of Examiners for Engineering and Surveying
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There are two basic types of flash point measurement:
1542:Penetrant (mechanical, electrical, or structural) 568:"Fuels and Chemicals — Autoignition Temperatures" 1929: 45:The flash point is sometimes confused with the 33:with a flash point lower than room temperature. 1033: 647: 367:tester with an integrated fire extinguisher 313:above its flash point, then ignited by the 1350:Hypoxic air technology for fire prevention 1040: 1026: 654: 640: 1735:Fire Equipment Manufacturers' Association 689:Native American use of fire in ecosystems 503: 501: 1068:Boiling liquid expanding vapor explosion 358: 25: 1714:Listing and approval use and compliance 898:International Flame Research Foundation 612: 562: 560: 534: 532: 1930: 590: 588: 498: 1759:Society of Fire Protection Engineers 1021: 635: 464: 462: 70:fuels, such as petrol (also known as 1910: 1753:National Fire Protection Association 991: 557: 529: 85:It is also used to characterize the 1047: 585: 13: 1255:Condensed aerosol fire suppression 459: 354: 14: 1954: 1630:Fire alarm notification appliance 1909: 1898: 1897: 1228: 1001: 990: 980: 979: 141:. The best-known example is the 1391:Vehicle fire suppression system 1079:Combustibility and flammability 679:Control of fire by early humans 615:"Auto-Ignition of Cooking Oils" 606: 447: 438: 414: 405: 296:>130 °C (266 °F) 124: 49:, the temperature that causes 1: 1741:Institution of Fire Engineers 1698:Fire Safety Evaluation System 1370:Personal protective equipment 398: 305:(petrol) is a fuel used in a 269:>38 °C (100 °F) 256:>38 °C (100 °F) 243:>52 °C (126 °F) 1812:GHS precautionary statements 1650:Manual fire alarm activation 202:16.6 °C (61.9 °F) 92: 7: 1683:Fire protection engineering 1615:Explosive gas leak detector 1432:Electromagnetic door holder 1265:External water spray system 375: 333:compression-ignition engine 175: 10: 1959: 1859:Harry C. Bigglestone Award 1250:Automatic fire suppression 1190:K-factor (fire protection) 286:424 °C (795 °F) 283:327 °C (621 °F) 272:210 °C (410 °F) 259:210 °C (410 °F) 246:210 °C (410 °F) 233:280 °C (536 °F) 230:−43 °C (−45 °F) 219:215 °C (419 °F) 205:363 °C (685 °F) 18: 1893: 1867: 1846: 1774: 1765:Underwriters Laboratories 1727: 1663: 1600:Aspirating smoke detector 1590: 1399: 1260:Detonation flame arrester 1237: 1226: 1055: 974: 911: 890: 864: 836: 815: 789: 753: 697: 669: 365:Pensky-Martens closed cup 339:until it heats above the 162:Pensky-Martens closed cup 1709:Kitchen exhaust cleaning 1625:Fire alarm control panel 1605:Carbon monoxide detector 1582:Standpipe (firefighting) 1345:Gaseous fire suppression 1110:Enthalpy of vaporization 903:The Combustion Institute 661: 382:Autoignition temperature 341:autoignition temperature 323:autoignition temperature 216:−4 °C (25 °F) 61: 47:autoignition temperature 1552:Pressurisation ductwork 1517:Firewall (construction) 1365:Passive fire protection 1315:Fire suppression system 613:Buda-Ortins, Krystyna. 1943:Threshold temperatures 1728:Industry organizations 1693:Fire-resistance rating 1572:Smoke exhaust ductwork 1547:Penetration (firestop) 1537:Packing (firestopping) 1245:Active fire protection 1205:Spontaneous combustion 745:Spontaneous combustion 572:Engineeringtoolbox.com 544:Engineeringtoolbox.com 368: 164:method is detailed in 34: 1880:Template:Firefighting 1854:Arthur B. Guise Medal 1807:GHS hazard statements 1310:Fire sprinkler system 1290:Fire-retardant fabric 600:www.sciencedirect.com 540:"Flash Point — Fuels" 444:Jansen and Hyams.pp62 362: 307:spark-ignition engine 151:lower flammable limit 119:lower flammable limit 29: 1664:Professions, trades, 1577:Smokeproof enclosure 1437:Electromagnetic lock 1145:Flammability diagram 1056:Fundamental concepts 51:spontaneous ignition 19:For other uses, see 1620:Fire alarm call box 1527:Heat and smoke vent 509:"Coleman Fuel MSDS" 426:www.ehs.iastate.edu 1592:Fire alarm systems 1407:Annulus (firestop) 1335:Flashback arrestor 1300:Fire-safe polymers 1295:Fire retardant gel 1150:Flammability limit 369: 143:Cleveland open cup 113:and is subject to 35: 1925: 1924: 1833:Safety data sheet 1828:List of S-phrases 1823:List of R-phrases 1719:Sprinkler fitting 1610:Circuit integrity 1482:Fire extinguisher 1320:Firefighting foam 1215:Thermal radiation 1015: 1014: 924:List of wildfires 392:Safety data sheet 300: 299: 109:of that liquid's 31:Flaming cocktails 1950: 1913: 1912: 1901: 1900: 1817:Life Safety Code 1422:Compartmentation 1232: 1155:Flammable liquid 1042: 1035: 1028: 1019: 1018: 1005: 994: 993: 983: 982: 828:Death by burning 790:Individual fires 656: 649: 642: 633: 632: 626: 625: 622:Drum.lib.umd.edu 619: 610: 604: 603: 592: 583: 582: 580: 578: 564: 555: 554: 552: 550: 536: 527: 526: 524: 522: 513: 505: 496: 495: 493: 491: 486:on June 17, 2019 485: 479:. Archived from 474: 466: 457: 451: 445: 442: 436: 435: 433: 432: 418: 412: 409: 252:Jet fuel (A/A-1) 180: 179: 101:have a specific 1958: 1957: 1953: 1952: 1951: 1949: 1948: 1947: 1928: 1927: 1926: 1921: 1889: 1863: 1842: 1770: 1723: 1665: 1659: 1586: 1512:Firestop pillow 1447:Emergency light 1400:Building design 1395: 1386:Tank blanketing 1355:Inerting system 1330:Flame retardant 1280:Fire protection 1275:Fire prevention 1233: 1224: 1089:Dangerous goods 1051: 1049:Fire protection 1046: 1016: 1011: 970: 907: 886: 860: 832: 811: 785: 749: 735:Fire protection 693: 665: 660: 630: 629: 617: 611: 607: 594: 593: 586: 576: 574: 566: 565: 558: 548: 546: 538: 537: 530: 520: 518: 511: 507: 506: 499: 489: 487: 483: 472: 468: 467: 460: 452: 448: 443: 439: 430: 428: 420: 419: 415: 410: 406: 401: 378: 357: 355:Standardization 190: 178: 127: 95: 78:fuels, such as 64: 24: 17: 12: 11: 5: 1956: 1946: 1945: 1940: 1923: 1922: 1920: 1919: 1907: 1894: 1891: 1890: 1888: 1887: 1882: 1877: 1871: 1869: 1865: 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glass 1492:Fire hydrant 1457:Fire curtain 1417:Booster pump 1376:Relief valve 1340:Fusible link 1164: 1130:Fire loading 1125:Fire control 1095:Deflagration 936:Firefighting 877:Fire worship 729: 720:Fire ecology 621: 608: 599: 575:. 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Retrieved 425: 416: 407: 370: 346: 327: 301: 239:Diesel (2-D) 213:(White Gas) 211:Coleman fuel 191:temperature 189:Autoignition 186:Flash point 171: 159: 157:is stirred. 155: 147: 134: 130: 128: 96: 87:fire hazards 84: 65: 44: 38: 36: 1522:Grease duct 1477:Fire escape 1467:Fire damper 1360:Intumescent 1305:Fire safety 1270:Fire bucket 1165:Flash point 966:Fire making 882:Terra preta 856:Firefighter 730:Flash point 725:Fire piston 521:November 3, 329:Diesel fuel 319:preignition 311:Boyle's Law 227:(gasoline) 125:Measurement 115:Boyle's Law 111:temperature 76:combustible 39:flash point 1938:Combustion 1932:Categories 1819:(NFPA 101) 1782:CE marking 1635:Fire drill 1238:Technology 1135:Fire point 1120:Fire class 1100:Detonation 1007:Wiktionary 946:Fire whirl 844:Pyromanias 802:By country 754:Components 710:Combustion 577:January 4, 549:January 4, 490:January 4, 456:, ASTM.org 431:2021-11-10 399:References 387:Fire point 363:Automatic 337:compressed 315:spark plug 139:fire point 135:closed cup 55:fire point 21:Flashpoint 1775:Standards 1704:Fire test 1532:Occupancy 1497:Fire pump 1487:Fire hose 1472:Fire door 1452:Exit sign 1427:Crash bar 1200:Pyrolysis 1195:Pool fire 1160:Flashover 1115:Explosive 1063:Backdraft 951:Blue lava 941:Firestorm 931:Backdraft 919:Wildfires 872:Cremation 740:Pyrolysis 477:Nafaa.org 335:. Air is 292:Biodiesel 280:(canola) 93:Mechanism 68:flammable 1904:Category 1868:See also 1797:EN 16034 1507:Firestop 1462:Fire cut 1185:Jet fire 1175:Gas leak 1091:(HAZMAT) 1074:Boilover 985:Category 376:See also 348:Jet fuel 303:Gasoline 265:Kerosene 176:Examples 131:open cup 107:function 72:gasoline 1916:Commons 1749:(NCEES) 1070:(BLEVE) 996:Commons 865:Culture 807:By year 797:By type 698:Science 671:History 197:Ethanol 145:(COC). 99:liquids 74:), and 1847:Awards 1761:(SFPE) 1755:(NFPA) 1737:(FEMA) 1700:(FSES) 1000:  989:  978:  837:People 766:Oxygen 225:Petrol 199:(70%) 80:diesel 53:. The 1838:UL 94 1792:EN 54 1743:(IFE) 1372:(PPE) 912:Other 849:Child 823:Arson 816:Crime 781:Smoke 776:Flame 618:(PDF) 512:(PDF) 484:(PDF) 473:(PDF) 394:(SDS) 183:Fuel 62:Fuels 1787:EN 3 1767:(UL) 771:Heat 761:Fuel 663:Fire 579:2014 551:2014 523:2019 492:2014 166:ASTM 133:and 97:All 37:The 956:Ash 1934:: 620:. 598:. 587:^ 570:. 559:^ 542:. 531:^ 514:. 500:^ 475:. 461:^ 424:. 325:. 82:. 1041:e 1034:t 1027:v 655:e 648:t 641:v 624:. 602:. 581:. 553:. 525:. 494:. 434:. 23:.

Index

Flashpoint

Flaming cocktails
autoignition temperature
spontaneous ignition
fire point
flammable
gasoline
combustible
diesel
fire hazards
liquids
vapor pressure
function
temperature
Boyle's Law
lower flammable limit
fire point
Cleveland open cup
lower flammable limit
Pensky-Martens closed cup
ASTM
Ethanol
Coleman fuel
Petrol
Diesel (2-D)
Jet fuel (A/A-1)
Kerosene
Vegetable oil
Biodiesel

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