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Hermann Kolbe

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952:"Im Gegensatz zu den bis jetzt bekannten gepaarten organischen Säuren, welche durch Zersetzung organischer Materien von meist complicierter Zusammensetzung unter Einwirkung kräftiger Agentien und unter Verhältnissen entstanden sind, welche eine mehrfache Auslegung der Zersetzungserscheinungen gestatten, werden diejenigen, welche den Gegenstand der nachstehenden Betrachtungen ausmachen, durch Synthese aus Körpern von möglichst einfacher Zusammensetzung gebildet, so daß sie uns über ihre Constitution kaum im Zweifel lassen, und können deshalb gewissermaßen als Prototypen jener Körperreihe angesehen werden." 954:(In contrast to the paired organic acids known until now, which have been formed by the decomposition of organic matter of the most complicated composition during the reaction of strong agencies and under conditions that admit multiple interpretations of decomposition phenomena, those that constitute the object of the following observations are formed by synthesis from substances of the simplest possible composition, so that they leave us hardly in doubt about their constitution, and thus can be viewed in a way as prototypes of those series of substances.) 44: 710:, from 1870 to 1884), Kolbe was sometimes so severely critical of the work of others, especially after about 1874, that some wondered whether he might have been suffering a mental illness. He was intolerant of what he regarded as loose speculation parading as theory, and sought through his writings to save his beloved science of chemistry from what he regarded as the scourge of modern structural theory. 595:
can be hydrolyzed to the corresponding acids. In addition to his own bench research and scholarly and editorial work, Kolbe oversaw student research at Leipzig and especially at Marburg; students spending time under his tutelage included
739:...Baeyer is an excellent experimentor, but he is only an empiricist, lacking sense and capability, and his interpretations of his experiments show particular deficiency in his familiarity with the principles of true science...» 504:
could be derived from substances clearly sourced from outside this "organic" context, directly or indirectly, by substitution processes. (Hence, while by modern definitions, he was converting one
312:. This was done via modifications to the idea of "radicals" and accurate prediction of the existence of secondary and tertiary alcohols, and to the emerging array of organic reactions through his 1110: 500:, according to which a special life-force was necessary to create "organic" (i.e., in its original meaning, biologically derived) compounds. Kolbe promoted the idea that 1300: 484:
In 1853, he married Charlotte, the daughter of General-Major Wilhelm von Bardeleben. His wife died in 1876 after 23 years of happy marriage. They had four children.
733:. Some translated quotes illustrate his manner of articulating the deep conflict between his interpretation of chemistry and that of the structural chemists: 1320: 1114: 344:'s Davy Medal in the year of his death. Despite these accomplishments and his training important members of the next generation of chemists (including 410:
pastor. At the age of 13, he entered the Göttingen Gymnasium, residing at the home of one of the professors. He obtained the leaving certificate (the
469:, and he also wrote an important textbook. In 1851, Kolbe succeeded Bunsen as professor of chemistry at Marburg and, in 1865, he was called to the 888: 1305: 1295: 153: 17: 1330: 1310: 1220: 700:
he wrote numerous books Kolbe served for more than a decade as what, in modern terms, would be understood the senior editor of the
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was confirmed by the synthesis of the first of these classes of organic molecules. Kolbe was the first person to use the word
1315: 1280: 872: 784: 1325: 1188: 437:. He took his doctoral degree in 1843 at the same university. A new opportunity arose in 1845, when he became assistant to 1238: 701: 512:—substances into "organic" ones only thought accessible through vital processes.) He validated his theory by converting 365: 1256: 1077: 474: 438: 1030: 970: 902: 722: 375: 1089: 386:'s reforms of nomenclature were personally critical and linguistically violent. Kolbe died of a heart attack in 1057: 776: 601: 478: 345: 217: 929: 926:
Kolbe wrote the word "synthesis" describing his project to transform carbon disulfide into acetic acid. See:
685: 265: 466: 1243:, the article on the original German journal and its descendants, German Knowledge, accessed 2 July 2014. 1225: 132: 1267:. English title: "On the syntheses of salicylic acid"; German title "Ueber Synthese der Salicylsäure". 419: 540:. A dramatic success came when his theoretical prediction of the existence of secondary and tertiary 336:, Kolbe was involved with the early internationalization of chemistry through work in London (with 754: 584: 341: 325: 136: 718: 629: 580: 317: 713:
His rejection of structural chemistry, especially the theories of the structure of benzene by
1136: 665: 621: 434: 285: 187: 183: 117: 1290: 1285: 677: 653: 361: 257: 245: 8: 645: 625: 541: 353: 237: 225: 493: 423: 329: 203: 882: 649: 564: 545: 470: 403: 313: 293: 289: 241: 127: 76: 280:(27 September 1818 – 25 November 1884) was a major contributor to the birth of modern 868: 842: 780: 605: 537: 458: 309: 281: 1216: 1170: 1039: 1006: 979: 941: 807: 726: 588: 513: 505: 501: 446: 383: 337: 305: 301: 194: 714: 532:) in several steps (1843–45). Kolbe also introduced a modified idea of structural 371: 1260: 681: 609: 576: 560: 349: 261: 221: 548:
in its present-day meaning, and contributed a number of new chemical reactions.
568: 533: 1159:"Begründung meiner Urtheile über Ad. Baeyer's wissenschaftliche Qualification" 1274: 1174: 1043: 983: 945: 811: 669: 430: 333: 249: 199: 98: 597: 552: 213: 1253: 399: 72: 673: 661: 633: 521: 357: 253: 229: 1189:"Today In Science History – September 27 – Adolph Wilhelm Hermann Kolbe" 1010: 865:
The Quiet Revolution: Hermann Kolbe and the Science of Organic Chemistry
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The Quiet Revolution: Hermann Kolbe and the Science of Organic Chemistry
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The violence of his language worked to limit his posthumous reputation.
340:). He was elected to the Royal Swedish Academy of Sciences, and won the 697: 657: 641: 556: 407: 233: 146: 508:
to another, by the parlance of his era, he was converting "inorganic"—
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in a chemical context, and contributed to the philosophical demise of
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Lindsey, Alan; Jeskey, Harold (1957). "The Kolbe Schmitt Reaction".
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in the spring of 1838 in order to study with the famous chemist
414:) six years later. He had become passionate about the study of 411: 1263:
English Translation of Kolbe's seminal 1860 German article in
966:"Untersuchungen ĂĽber die Elektrolyse organischer Verbindungen" 608:
predicting the product composition of elimination reactions),
1111:"Adolph Wilhelm Hermann Kolbe – developer of Kolbe synthesis" 613: 390:
at age 66, six years after the death of his wife, Charlotte.
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Untersuchungen ĂĽber die Elektrolyse organischer Verbindungen
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for more than a decade, in which his vituperative essays on
932:[Contributions to knowledge of paired compounds]. 583:. His method for the synthesis of nitriles is called the 496:
in 1828, some chemists still believed in the doctrine of
1181: 364:, and others), Kolbe is best remembered for editing the 1082: 1050: 1103: 729:, was expressed in his vituperative articles in the 1213:Kurzes Lehrbuch der Chemie . 1.Anorganische Chemie 930:"Beiträge zur KenntniĂź der gepaarten Verbindungen" 551:In particular, Kolbe developed procedures for the 473:. In 1864, he was elected a foreign member of the 680:(first to describe the double bond of ethylene), 1301:Members of the Royal Swedish Academy of Sciences 1272: 836: 834: 832: 830: 828: 451:Handwörterbuch der reinen und angewandten Chemie 770: 1156: 1023: 996: 963: 825: 793: 725:, and the reform of chemical nomenclature by 308:, and also contributed to the development of 487: 1321:Academic staff of the University of Marburg 1215:. Vieweg, Braunschweig 2. verb. Aufl. 1884 668:describing addition reactions to alkenes), 449:. From 1847, he was engaged in editing the 887:: CS1 maint: location missing publisher ( 42: 1129: 840: 691: 536:, so contributing to the development of 455:Dictionary of Pure and Applied Chemistry 292:. Kolbe was the first to apply the term 1221:University and State Library DĂĽsseldorf 819: 14: 1273: 927: 862: 1306:Academic staff of Leipzig University 1296:Foreign members of the Royal Society 494:Friedrich Wöhler's synthesis of urea 477:. He was elected as a member of the 398:Kolbe was born in Elliehausen, near 429:In 1842, he became an assistant to 24: 1331:People from the Kingdom of Hanover 1228:Advanced Synthesis & Catalysis 1206: 492:As late as the 1840s, and despite 25: 1342: 1247: 1026:"Ueber Synthese der Salicylsäure" 796:"Zur Erinnerung an Hermann Kolbe" 475:Royal Swedish Academy of Sciences 406:(Germany) as the eldest son of a 1265:Annalen der Chemie und Pharmacie 1031:Annalen der Chemie und Pharmacie 971:Annalen der Chemie und Pharmacie 934:Annalen der Chemie und Pharmacie 843:"Hermann Kolbe – German chemist" 445:in London and a close friend of 1150: 759:. Edinburgh: Livingstone. 1947. 747: 1311:University of Göttingen alumni 1113:. 11 June 2015. Archived from 1071: 1017: 990: 957: 920: 895: 856: 777:University of California Press 708:Journal of practical chemistry 602:Aleksandr Mikhailovich Zaitsev 479:American Philosophical Society 218:Aleksandr Mikhailovich Zaitsev 13: 1: 1240:Journal fĂĽr Praktische Chemie 1232:Journal fĂĽr Praktische Chemie 1230:, ultimate descendant of the 1163:Journal fĂĽr Praktische Chemie 800:Journal fĂĽr Praktische Chemie 731:Journal fĂĽr Praktische Chemie 703:Journal fĂĽr Praktische Chemie 367:Journal fĂĽr Praktische Chemie 1316:University of Marburg alumni 1281:19th-century German chemists 467:Johann Christian Poggendorff 435:Philipps-Universität Marburg 278:Adolph Wilhelm Hermann Kolbe 58:Adolph Wilhelm Hermann Kolbe 18:Adolph Wilhelm Hermann Kolbe 7: 378:'s theory on the origin of 10: 1347: 1078:Electrochemical Dictionary 764: 443:Museum of Economic Geology 316:of carboxylate salts, the 27:German chemist (1818–1884) 1326:Scientists from Göttingen 1090:"Kolbe Nitrile Synthesis" 488:Work in chemical research 374:'s structure of benzene, 300:through synthesis of the 271: 209: 193: 179: 169: 162: 142: 123: 113: 105: 83: 53: 41: 34: 1175:10.1002/prac.18820260121 1137:"Books by Hermann Kolbe" 1058:"Kolbe-Schmitt Reaction" 1044:10.1002/jlac.18601130120 984:10.1002/jlac.18490690302 946:10.1002/jlac.18450540202 812:10.1002/prac.18850300143 660:smaller and larger than 284:. He was a professor at 1259:18 October 2020 at the 1235:, accessed 2 July 2014. 863:Rocke, Alan J. (1993). 771:Rocke, Alan J. (1993). 585:Kolbe nitrile synthesis 420:University of Göttingen 418:, matriculating at the 393: 342:Royal Society of London 326:Kolbe nitrile synthesis 137:Kolbe nitrile synthesis 1226:Wiley online library: 1157:Hermann Kolbe (1882). 1024:Hermann Kolbe (1860). 964:Hermann Kolbe (1849). 794:von Meyer, E. (1884). 742: 719:asymmetric carbon atom 692:Work as journal editor 630:Beckmann rearrangement 581:Kolbe-Schmitt reaction 571:, a building block of 320:in the preparation of 318:Kolbe-Schmitt reaction 133:Kolbe–Schmitt reaction 735: 696:Besides his work for 622:Curtius rearrangement 328:. After studies with 188:University of Leipzig 184:University of Marburg 118:University of Marburg 907:search.amphilsoc.org 903:"APS Member History" 820:Notes and references 717:, the theory of the 678:Alexander Crum Brown 654:Vladimir Markovnikov 575:in a process called 514:carbon disulfide (CS 258:Alexander Crum Brown 246:Vladimir Markovnikov 1191:. 27 September 2014 1011:10.1021/cr50016a001 656:(first to describe 646:Constantin Fahlberg 628:(discoverer of the 626:Ernst Otto Beckmann 471:Universität Leipzig 238:Constantin Fahlberg 226:Ernst Otto Beckmann 950:From pp. 145–146: 928:Kolbe, H. (1845). 666:Markovnikov's rule 650:Nikolai Menshutkin 565:Kolbe electrolysis 404:Kingdom of Hanover 314:Kolbe electrolysis 242:Nikolai Menshutkin 128:Kolbe electrolysis 77:Kingdom of Hanover 71:Elliehausen, near 1117:on 19 August 2016 874:978-0-520-08110-9 786:978-0-520-08110-9 686:Frederick Guthrie 538:structural theory 502:organic compounds 459:Justus von Liebig 310:structural theory 304:acetic acid from 302:organic substance 282:organic chemistry 275: 274: 266:Frederick Guthrie 210:Doctoral students 164:Scientific career 68:27 September 1818 16:(Redirected from 1338: 1201: 1200: 1198: 1196: 1185: 1179: 1178: 1154: 1148: 1147: 1145: 1143: 1133: 1127: 1126: 1124: 1122: 1107: 1101: 1100: 1098: 1096: 1086: 1080: 1075: 1069: 1068: 1066: 1064: 1054: 1048: 1047: 1021: 1015: 1014: 994: 988: 987: 961: 955: 949: 924: 918: 917: 915: 913: 899: 893: 892: 886: 878: 860: 854: 853: 851: 849: 838: 815: 790: 760: 727:Adolf von Baeyer 664:, and known for 589:Edward Frankland 561:carboxylic acids 555:of the salts of 531: 506:organic molecule 447:Edward Frankland 424:Friedrich Wöhler 306:carbon disulfide 204:Friedrich Wöhler 195:Doctoral advisor 158: 151: 90: 87:25 November 1884 67: 65: 46: 32: 31: 21: 1346: 1345: 1341: 1340: 1339: 1337: 1336: 1335: 1271: 1270: 1261:Wayback Machine 1250: 1217:Digital edition 1209: 1207:Further reading 1204: 1194: 1192: 1187: 1186: 1182: 1155: 1151: 1141: 1139: 1135: 1134: 1130: 1120: 1118: 1109: 1108: 1104: 1094: 1092: 1088: 1087: 1083: 1076: 1072: 1062: 1060: 1056: 1055: 1051: 1022: 1018: 995: 991: 962: 958: 925: 921: 911: 909: 901: 900: 896: 880: 879: 875: 861: 857: 847: 845: 841:Alan J. Rocke. 839: 826: 822: 787: 767: 753: 750: 723:J.H. van't Hoff 694: 682:Maxwell Simpson 636:(discoverer of 612:(discoverer of 610:Theodor Curtius 577:Kolbe synthesis 567:) and prepared 529: 525: 517: 490: 396: 264: 262:Maxwell Simpson 260: 256: 252: 248: 244: 240: 236: 232: 228: 224: 222:Theodor Curtius 220: 216: 202: 186: 156: 152: 149: 135: 131: 114:Alma mater 101: 92: 88: 79: 69: 63: 61: 60: 59: 49: 37: 28: 23: 22: 15: 12: 11: 5: 1344: 1334: 1333: 1328: 1323: 1318: 1313: 1308: 1303: 1298: 1293: 1288: 1283: 1269: 1268: 1249: 1248:External links 1246: 1245: 1244: 1236: 1223: 1208: 1205: 1203: 1202: 1180: 1169:(1): 308–323. 1149: 1128: 1102: 1081: 1070: 1049: 1038:(1): 125–127. 1016: 1005:(4): 583–620. 989: 978:(3): 257–372. 956: 940:(2): 145–188. 919: 894: 873: 855: 823: 821: 818: 817: 816: 806:(1): 417–467. 791: 785: 766: 763: 762: 761: 749: 746: 693: 690: 606:Zaitsev's rule 591:he found that 569:salicylic acid 527: 515: 489: 486: 395: 392: 273: 272: 269: 268: 211: 207: 206: 197: 191: 190: 181: 177: 176: 171: 167: 166: 160: 159: 144: 140: 139: 125: 124:Known for 121: 120: 115: 111: 110: 107: 103: 102: 93: 91:(aged 66) 85: 81: 80: 70: 57: 55: 51: 50: 48:Kolbe, c. 1860 47: 39: 38: 35: 26: 9: 6: 4: 3: 2: 1343: 1332: 1329: 1327: 1324: 1322: 1319: 1317: 1314: 1312: 1309: 1307: 1304: 1302: 1299: 1297: 1294: 1292: 1289: 1287: 1284: 1282: 1279: 1278: 1276: 1266: 1262: 1258: 1255: 1252: 1251: 1242: 1241: 1237: 1234: 1233: 1229: 1224: 1222: 1218: 1214: 1211: 1210: 1190: 1184: 1176: 1172: 1168: 1164: 1160: 1153: 1138: 1132: 1116: 1112: 1106: 1091: 1085: 1079: 1074: 1059: 1053: 1045: 1041: 1037: 1033: 1032: 1027: 1020: 1012: 1008: 1004: 1000: 993: 985: 981: 977: 973: 972: 967: 960: 953: 947: 943: 939: 936:(in German). 935: 931: 923: 908: 904: 898: 890: 884: 876: 870: 866: 859: 844: 837: 835: 833: 831: 829: 824: 813: 809: 805: 801: 797: 792: 788: 782: 778: 774: 769: 768: 758: 757: 752: 751: 745: 741: 740: 734: 732: 728: 724: 720: 716: 715:August KekulĂ© 711: 709: 705: 704: 699: 689: 687: 683: 679: 675: 671: 670:Jacob Volhard 667: 663: 659: 655: 651: 647: 643: 639: 635: 631: 627: 623: 619: 615: 611: 607: 603: 599: 594: 590: 586: 582: 578: 574: 570: 566: 562: 558: 554: 549: 547: 543: 539: 535: 523: 519: 511: 507: 503: 499: 495: 485: 482: 480: 476: 472: 468: 464: 460: 456: 452: 448: 444: 440: 439:Lyon Playfair 436: 432: 431:Robert Bunsen 427: 425: 421: 417: 413: 409: 405: 401: 391: 389: 385: 381: 377: 373: 369: 368: 363: 359: 355: 351: 347: 343: 339: 335: 331: 327: 323: 319: 315: 311: 307: 303: 299: 295: 291: 287: 283: 279: 270: 267: 263: 259: 255: 251: 250:Jacob Volhard 247: 243: 239: 235: 231: 227: 223: 219: 215: 212: 208: 205: 201: 200:Robert Bunsen 198: 196: 192: 189: 185: 182: 178: 175: 172: 168: 165: 161: 155: 148: 145: 141: 138: 134: 129: 126: 122: 119: 116: 112: 108: 104: 100: 99:German Empire 96: 86: 82: 78: 74: 56: 52: 45: 40: 36:Hermann Kolbe 33: 30: 19: 1264: 1254:Translations 1239: 1231: 1227: 1212: 1193:. 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Index

Adolph Wilhelm Hermann Kolbe

Göttingen
Kingdom of Hanover
Leipzig
German Empire
University of Marburg
Kolbe electrolysis
Kolbe–Schmitt reaction
Kolbe nitrile synthesis
Davy Medal
ForMemRS
Chemist
University of Marburg
University of Leipzig
Doctoral advisor
Robert Bunsen
Friedrich Wöhler
Peter Griess
Aleksandr Mikhailovich Zaitsev
Theodor Curtius
Ernst Otto Beckmann
Carl Graebe
Oscar Loew
Constantin Fahlberg
Nikolai Menshutkin
Vladimir Markovnikov
Jacob Volhard
Ludwig Mond
Alexander Crum Brown

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