362:
354:. He developed the paradigm of Lewis base activation of Lewis acids and successfully applied it to the asymmetric addition of a broad range of nucleophiles to silyl ketene acetals, iodo- and bromo-functionalization of alkenes, and enantioselective thio- and seleno-functionalization of alkenes. His work has yielded several Lewis base catalysts that are chiral phosphoramide derivatives. Unlike other organocatalysts, the Lewis base catalysts operate without the assistance of
44:
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since 1994 and the editor-in-chief and president from 2008 to 2019. Denmark is known for his intensity and enthusiasm as an advisor and for his strict adherence to the 'Swiss method' of organic synthesis, compound characterization, and reporting of experimental methods. Students who worked with him
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An additional area of research for the
Denmark group is the observation and characterization of the pre-transmetalation species of the boron-palladium adduct in
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Significant interests of
Denmark's also include asymmetric catalysis with main group elements, also known as Lewis base catalysis, which is a subclass of
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early in his research career later recalled their self-description as "Denmark's
Disciples" in a retrospective recognizing his contributions.
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Synthetic, Mechanistic and
Computational Studies on AE Inspired Chemistry: From Polyene Cyclizations to Origin of Biomolecular Homochirality
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425:
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207:
296:. Denmark was the third Eschenmoser lecturer at the ETH ZĂĽrich in 2018, the first former Eschenmoser graduate student thus honored.
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343:. His work on the palladium-catalyzed cross-coupling reaction with vinylsilanol and arylrsilanol has been recognized as the
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in 1987, and was named the Fuson
Professor of Chemistry in 1991. He served as the president and editor-in-chief of the
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Denmark has published over 400 peer-reviewed articles and 27 book chapters and edited several book volumes including:
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743:"Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates"
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Denmark, S. E.; Harmata, M. A. (September 1, 1982). "Carbanion-accelerated
Claisen rearrangements".
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880:"Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link"
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689:"Frederic Stanley Kipping Award In Silicon Chemistry | Chemical & Engineering News"
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Select chiral Lewis base catalysts developed by Scott
Denmark for asymmetric catalysis
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Denmark, S. E.; Jones, T. K. (May 1, 1982). "Silicon-directed
Nazarov cyclization".
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chemistry, asymmetric allylmetal chemistry, silicon-based cross-coupling reactions,
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849:. Topics in Organometallic Chemistry. Springer Berlin Heidelberg. pp. 55–89.
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as an undergraduate and during his studies he was involved in research with both
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using rapid-injection NMR techniques. Denmark also has research interests in
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and chemoinformatics, organic chemistry, and catalysis with nanoparticles.
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1097:"Scott E. Denmark Elected to the American Academy of Arts and Sciences"
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Beutner, Gregory L.; Denmark, Scott E. (2012). GooĂźen, Lukas J. (ed.).
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book series between 2008 and 2018. In 2017, Denmark was elected to the
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Denmark began his independent academic research career in 1980 at the
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degree from MIT in 1975. His graduate studies were conducted at the
1039:"Special Issue Dedicated to Professor Scott E. Denmark - Laudation"
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Fellows of the
American Association for the Advancement of Science
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University of
Illinois at Urbana-Champaign Department of Chemistry
292:. Denmark received the D.Tech. Sc. degree in 1980 for his thesis
43:
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related cycloaddition reactions, phosphorus-stabilized anions,
800:
Lewis base catalysis in organic synthesis. Volume 1, 2 and 3
226:. He joined the faculty at UIUC the same year and became an
1199:
Members of the United States National Academy of Sciences
261:
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Vedejs, Edwin; E., Denmark, Scott (October 10, 2016).
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Denmark, Scott E.; Ambrosi, Andrea (August 21, 2015).
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Thomas, Andy A.; Denmark, Scott E. (April 15, 2016).
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Fellows of the American Academy of Arts and Sciences
567:"Past Eschenmoser Lecturers and Their Laudations"
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1164:University of Illinois Urbana-Champaign faculty
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571:Department of Chemistry and Applied Biosciences
539:(PhD). ETH ZĂĽrich (Promotionsarbeit Nr. 6665).
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830:: CS1 maint: multiple names: authors list (
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222:in 1980, under the supervision of Professor
323:Other interests in Denmark's group include
294:On the Stereochemistry of the S N’ Reaction
251:
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747:Organic Process Research & Development
537:On the stereochemistry of the S-N'Reaction
426:United States National Academy of Sciences
306:University of Illinois at Urbana-Champaign
208:University of Illinois at Urbana-Champaign
156:University of Illinois at Urbana–Champaign
42:
1184:Fellows of the Royal Society of Chemistry
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392:Lewis Base Catalysis in Organic Synthesis
1189:Fellows of the American Chemical Society
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654:Journal of the American Chemical Society
619:Journal of the American Chemical Society
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316:. This work was later recognized by the
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592:Denmark, Scott E. (November 27, 1972).
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218:in 1975 and the D.Sc.Tech. degree from
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1095:Yoksoulian, Lois E. (April 13, 2017).
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419:American Academy of Arts and Sciences
242:American Academy of Arts and Sciences
127:American Academy of Arts and Sciences
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358:, and have a broad substrate scope.
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1139:from the original on June 16, 2023
1121:Notman, Nina (September 9, 2022).
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202:is an American chemist who is the
25:
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244:. In 2018, he was elected to the
192:http://denmark.scs.illinois.edu/
1128:Chemical & Engineering News
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1003:Denmark, Scott E., ed. (2004).
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1169:21st-century American chemists
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206:Professor of Chemistry at the
125:, RSC Pedler Medal, Member of
13:
1:
1123:"2023 National Award winners"
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310:Nazarov cyclization reaction
246:National Academy of Sciences
210:(UIUC). Denmark received an
131:National Academy of Sciences
123:Arthur C. Cope Scholar Award
7:
1049:(13): I–II. June 19, 2013.
979:"Topics in Stereochemistry"
394:. He has been an editor of
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598:. ETH Zurich (Switzerland)
535:Denmark, Scott E. (1980).
320:Award to Denmark in 2014.
101:Enantioselective synthesis
1174:American organic chemists
1075:American Chemical Society
511:"May 1 2018 NAS Election"
412:American Chemical Society
382:Topics in Stereochemistry
318:Frederick Stanley Kipping
288:under the supervision of
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759:10.1021/acs.oprd.5b00201
545:10.3929/ethz-a-000266394
337:water-gas shift reaction
333:phase-transfer catalysis
252:Early life and education
109:Organometallic chemistry
905:10.1126/science.aad6981
375:computational chemistry
345:Hiyama-Denmark coupling
1101:University of Illinois
1056:10.1055/s-0033-1338502
410:Elected fellow of the
366:
487:Denmark Group website
364:
314:Claisen rearrangement
260:in 1953. He attended
983:Wiley Online Library
855:10.1007/3418_2012_43
256:Denmark was born in
896:2016Sci...352..329T
847:Inventing Reactions
666:10.1021/ja00382a051
631:10.1021/ja00373a055
553:20.500.11850/137417
433:Arthur C.Cope Award
228:associate professor
1071:"2009 ACS Fellows"
1015:10.1002/0471264180
483:"Scott E. Denmark"
453:"Scott E. Denmark"
367:
290:Albert Eschenmoser
280:. He received his
276:on functionalized
258:Lynbrook, New York
224:Albert Eschenmoser
200:Scott Eric Denmark
168:Albert Eschenmoser
36:Scott Eric Denmark
1006:Organic Reactions
890:(6283): 329–332.
660:(18): 4972–4974.
515:www.nasonline.org
431:Recipient of the
405:Awards and honors
397:Organic Reactions
387:Organic Syntheses
237:Organic Reactions
197:
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178:Erick M. Carreira
138:Scientific career
113:Organic Reactions
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1141:. Retrieved
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272:analogs and
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152:Institutions
137:
129:, Member of
57:17 June 1953
26:
1209:1953 births
693:cen.acs.org
325:nitroalkene
278:cyclophanes
1158:Categories
954:"Research"
915:2142/97541
440:References
286:ETH ZĂĽrich
270:ferredoxin
220:ETH Zurich
88:(Graduate)
86:ETH ZĂĽrich
68:Lynbrook,
61:1953-06-17
1106:April 22,
1080:April 22,
1043:Synthesis
963:April 22,
924:0036-8075
826:cite book
818:954732847
767:1083-6160
726:April 22,
674:0002-7863
639:0002-7863
492:April 22,
462:April 22,
356:H-bonding
230:in 1986,
147:Chemistry
1143:June 16,
1137:Archived
932:27081068
785:26478695
698:June 20,
300:Research
70:New York
940:1431914
892:Bibcode
884:Science
776:4608042
188:Website
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390:, and
339:, and
144:Fields
119:Awards
936:S2CID
329:aldol
1145:2023
1108:2019
1082:2019
1019:ISBN
990:2019
965:2019
928:PMID
920:ISSN
859:ISBN
832:link
814:OCLC
804:ISBN
781:PMID
763:ISSN
728:2019
700:2017
670:ISSN
635:ISSN
604:2019
579:2019
522:2018
494:2019
464:2019
312:and
282:S.B.
212:S.B.
54:Born
1133:100
1051:doi
1011:doi
910:hdl
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771:PMC
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268:on
262:MIT
216:MIT
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Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.
