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Pauli exclusion principle

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of Li is 1s2s. Similarly, successively larger elements must have shells of successively higher energy. The chemical properties of an element largely depend on the number of electrons in the outermost shell; atoms with different numbers of occupied electron shells but the same number of electrons in
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In one dimension, bosons, as well as fermions, can obey the exclusion principle. A one-dimensional Bose gas with delta-function repulsive interactions of infinite strength is equivalent to a gas of free fermions. The reason for this is that, in one dimension, the exchange of particles requires that
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So, if hypothetically two fermions were in the same state—for example, in the same atom in the same orbital with the same spin—then interchanging them would change nothing and the total wave function would be unchanged. However, the only way a total wave function can both change sign (required for
2808:), who considered the balance of attractive (electron–nuclear) and repulsive (electron–electron and nuclear–nuclear) forces and showed that ordinary matter would collapse and occupy a much smaller volume without the Pauli principle. A much simpler proof was found later by 2071: 2615:, particles with integer spin occupy symmetric quantum states, and particles with half-integer spin occupy antisymmetric states; furthermore, only integer or half-integer values of spin are allowed by the principles of quantum mechanics. In relativistic 1786: 1250:, for example, the third of his six postulates of chemical behavior states that the atom tends to hold an even number of electrons in any given shell, and especially to hold eight electrons, which he assumed to be typically arranged symmetrically 1902: 2429: 2691:) states by acquiring opposite spin; as spin is part of the quantum state of the electron, the two electrons are in different quantum states and do not violate the Pauli principle. However, the spin can take only two different values ( 2781:
The stability of each electron state in an atom is described by the quantum theory of the atom, which shows that close approach of an electron to the nucleus necessarily increases the electron's kinetic energy, an application of the
2797:, who pointed out that the electrons of each atom cannot all fall into the lowest-energy orbital and must occupy successively larger shells. Atoms, therefore, occupy a volume and cannot be squeezed too closely together. 128: 2152: 2680:. Electrons, being fermions, cannot occupy the same quantum state as other electrons, so electrons have to "stack" within an atom, i.e. have different spins while at the same electron orbital as described below. 1577: 2597: 1485: 1078:
fermions), and also remain unchanged is that such a function must be zero everywhere, which means such a state cannot exist. This reasoning does not apply to bosons because the sign does not change.
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To test the Pauli exclusion principle for the helium atom, Gordon Drake carried out very precise calculations for hypothetical states of the He atom that violate it, which are called
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It has been shown that the Pauli exclusion principle is responsible for the fact that ordinary bulk matter is stable and occupies volume. This suggestion was first made in 1931 by
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In the case of electrons in atoms, the exclusion principle can be stated as follows: in a poly-electron atom it is impossible for any two electrons to have the same two values of
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atom (Li), with three bound electrons, the third electron cannot reside in a 1s state and must occupy a higher-energy state instead. The lowest available state is 2s, so that the
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electron per state if the electron states are defined using four quantum numbers. For this purpose he introduced a new two-valued quantum number, identified by
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The Pauli exclusion principle helps explain a wide variety of physical phenomena. One particularly important consequence of the principle is the elaborate
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spin coordinates of two identical particles are interchanged, then the total wave function changes sign for fermions, but does not change sign for bosons.
3951: 1357:, in which for such a permutation the wave function changes its sign... the correct and general wave mechanical formulation of the exclusion principle. 1051:) are not subject to the Pauli exclusion principle. Any number of identical bosons can occupy the same quantum state, such as photons produced by a 58: 3060: 2635:. In momentum space, the exclusion principle is valid also for finite repulsion in a Bose gas with delta-function interactions, as well as for 1262:
could be explained if the electrons in an atom were connected or clustered in some manner. Groups of electrons were thought to occupy a set of
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has spin 0 and is a boson. The Pauli exclusion principle underpins many properties of everyday matter, from its large-scale stability to the
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of a metal. Many mechanical, electrical, magnetic, optical and chemical properties of solids are the direct consequence of Pauli exclusion.
2082: 1210:. In contrast, particles with integer spin (bosons) have symmetric wave functions and may share the same quantum states. Bosons include the 2076:
The first and last terms are diagonal elements and are zero, and the whole sum is equal to zero. So the wavefunction matrix elements obey:
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one-particle states. The condition of antisymmetry states that the coefficients must flip sign whenever any two states are exchanged:
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calculated by Drake. The search was unsuccessful and showed that the statistical weight of this paronic state has an upper limit of
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Deilamian, K.; et al. (1995). "Search for small violations of the symmetrization postulate in an excited state of Helium".
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The Pauli exclusion principle with a single-valued many-particle wavefunction is equivalent to requiring the wavefunction to be
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Pauli, W. (1925). "Über den Zusammenhang des Abschlusses der Elektronengruppen im Atom mit der Komplexstruktur der Spektren".
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Among the different classes of symmetry, the most important ones (which moreover for two particles are the only ones) are the
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of atoms and the way atoms share electrons, explaining the variety of chemical elements and their chemical combinations. An
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they pass through each other; for infinitely strong repulsion this cannot happen. This model is described by a quantum
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in the star's core. In white dwarfs, which do not undergo nuclear fusion, an opposing force to gravity is provided by
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by assuming that certain numbers of electrons (for example 2, 8 and 18) corresponded to stable "closed shells".
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of the Hilbert space describing a system of two such particles. Any two-particle state can be represented as a
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and coworkers showed that the Pauli principle still leads to stability in intense magnetic fields such as in
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The consequence of the Pauli principle here is that electrons of the same spin are kept apart by a repulsive
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In the early 20th century it became evident that atoms and molecules with even numbers of electrons are more
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Straumann, Norbert (2004). "The Role of the Exclusion Principle for Atoms to Stars: A Historical Account".
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In his Nobel lecture, Pauli clarified the importance of quantum state symmetry to the exclusion principle:
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A more rigorous statement is: under the exchange of two identical particles, the total (many-particle)
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Astronomy provides a spectacular demonstration of the effect of the Pauli principle, in the form of
2715:. Later, K. Deilamian et al. used an atomic beam spectrometer to search for the paronic state 1s2s S 1907:
This is zero, because the two particles have zero probability to both be in the superposition state
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Dyson and Lenard did not consider the extreme magnetic or gravitational forces that occur in some
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The Life of Stars: The Controversial Inception and Emergence of the Theory of Stellar Structure
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during a lecture in Copenhagen (1929). Wolfgang Pauli formulated the Pauli exclusion principle.
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Quantum mechanics rule: identical fermions cannot occupy the same quantum state simultaneously
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than those with odd numbers of electrons. In the 1916 article "The Atom and the Molecule" by
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Lieb, E. H.; Loss, M.; Solovej, J. P. (1995). "Stability of Matter in Magnetic Fields".
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Dyson, Freeman (1967). "Ground-State Energy of a Finite System of Charged Particles".
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describing a one-particle system, then the tensor product produces the basis vectors
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Dill, Dan (2006). "Chapter 3.5, Many-electron atoms: Fermi holes and Fermi heaps".
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Lieb, Elliott H. (2002). "The Stability of Matter and Quantum Electrodynamics".
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Lieb, Elliott H. (2002). "The Stability of Matter and Quantum Electrodynamics".
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of Heisenberg. However, stability of large systems with many electrons and many
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that, in sufficiently intense gravitational fields, matter collapses to form a
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are separated, is equal to the number of electrons in the closed shell of the
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than a white dwarf. Neutron stars are the most "rigid" objects known; their
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in 1975. They provided a lower bound on the quantum energy in terms of the
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Pauli looked for an explanation for these numbers, which were at first only
3651: 3407: 3237:"Pauli principle for one-dimensional bosons and the algebraic Bethe ansatz" 2980: 2921: 2905: 2875: 2856: 2852: 2848: 2752: 2700: 2652: 2644: 1306: 1286: 1251: 1215: 1199: 851: 846: 781: 766: 731: 225: 3356: 3046:"Linus Pauling and The Nature of the Chemical Bond: A Documentary History" 1597:
is a (complex) scalar coefficient. Antisymmetry under exchange means that
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is necessarily antisymmetric. To prove it, consider the matrix element
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is a different question, and requires the Pauli exclusion principle.
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the outermost shell have similar properties, which gives rise to the
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atom contains bound electrons equal in number to the protons in the
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for fermions and symmetric for bosons. This means that if the space
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Pauli's account of the development of the Exclusion Principle.
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The Pauli exclusion principle describes the behavior of all
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are +1/2 and −1/2, it follows that one electron must have
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Invited Talk at the 12th Workshop on Nuclear Astrophysics
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Nobel Lecture: Exclusion Principle and Quantum Mechanics
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The Universe: A View from Classical and Quantum Gravity
1340: 2727:. (The exclusion principle implies a weight of zero.) 2457:. The exclusion principle is the consequence that, if 936:. This principle was formulated by Austrian physicist 3061:"The Arrangement of Electrons in Atoms and Molecules" 2532: 2503: 2463: 2437: 2314: 2242: 2166: 2085: 1958: 1913: 1800: 1680: 1500: 1431: 1399: 1371: 1163: 61: 3952:
Electron configurations of the elements (data page)
3298: 3219:"Wolfgang Pauli, Nobel lecture (December 13, 1946)" 2643:in one dimension, and for other models solvable by 1297:, which pointed out that, for a given value of the 1230:, which they obey, and bosons take theirs from the 997:. For example, if two electrons reside in the same 3790:The periodic table: Its story and its significance 3787: 3722: 3427:(8th ed.), USA: John Wiley & Sons, Inc., 2591: 2518: 2489: 2449: 2423: 2296: 2232:particles, the multi-particle basis states become 2214: 2146: 2065: 1941: 1896: 1780: 1571: 1479: 1413: 1385: 1186: 122: 2800:The first rigorous proof was provided in 1967 by 1886: 1814: 1773: 1741: 1309:spectra in an external magnetic field, where all 1142:has spin 1/2 and is therefore a fermion, whereas 4056: 3744: 3019: 2924:) is 20 orders of magnitude larger than that of 1293:. He found an essential clue in a 1924 paper by 3672: 3609: 3485:Quantum Mechanics and Its Emergent Macrophysics 3001:"Wolfgang Pauli during a lecture in Copenhagen" 3325:"Predicted energy shifts for "paronic" Helium" 2619:, the Pauli principle follows from applying a 944:, and later extended to all fermions with his 3838: 3292: 2763:that they cannot even contribute much to the 889: 3785: 3666: 3482: 2297:{\displaystyle A(x_{1},x_{2},\ldots ,x_{n})} 2132: 2112: 2106: 2086: 2057: 2037: 2031: 2011: 2005: 1985: 1979: 1959: 1936: 1922: 1878: 1864: 1844: 1830: 1801: 1768: 1754: 1728: 1722: 1702: 1563: 1509: 1474: 1460: 1446: 1408: 1380: 117: 91: 3301:Introduction to Quantum Mechanics (2nd ed.) 1153:Half-integer spin means that the intrinsic 1016:are equal. In that case, the two values of 3852: 3845: 3831: 3568: 3528:As described by F. J. Dyson (J.Math.Phys. 3414: 3235:A. G. Izergin; V. E. Korepin (July 1982). 2606: 896: 882: 3703: 3625: 3474: 3452: 3377: 3159: 3141: 3131: 2730: 3947:Periodic table (electron configurations) 3125: 3068:Journal of the American Chemical Society 3058: 3013: 2651:in models solvable by Bethe ansatz is a 1202:(1/2, 3/2, 5/2, etc.). In the theory of 928:) cannot simultaneously occupy the same 29: 3767:Tipler, Paul; Llewellyn, Ralph (2002). 1652:Conversely, if the diagonal quantities 932:within a system that obeys the laws of 14: 4057: 3420: 3106: 2770: 1363:antisymmetric with respect to exchange 3826: 3794:. New York: Oxford University Press. 3574: 3461: 3322: 3174: 3100: 2932:of a neutron star mass exceeding the 1942:{\displaystyle |x\rangle +|y\rangle } 1130:composed from three quarks) and some 3706:Notes on General Chemistry (2nd ed.) 3468: 3446: 3440: 3020:Kenneth S. Krane (5 November 1987). 2747:which effectively form a continuous 2603:particles may be in the same state. 1421:range over the basis vectors of the 1341:Connection to quantum state symmetry 1228:Fermi–Dirac statistical distribution 1226:. Fermions take their name from the 3673:Martin Bojowald (5 November 2012). 3547:Stability of Matter, Parts I and II 3501:Stability of Matter, Parts I and II 3424:Introduction to Solid State Physics 2627:to particles of half-integer spin. 1491:(i.e. sum) of these basis vectors: 24: 3467:This realization is attributed by 2743:, there are very large numbers of 1671:, then the wavefunction component 428:Sum-over-histories (path integral) 114: 88: 44:Part of a series of articles about 25: 4096: 3880:Introduction to quantum mechanics 3810: 65: 2936:, leading to the formation of a 2934:Tolman–Oppenheimer–Volkoff limit 1047:Particles with an integer spin ( 3771:(4th ed.). W. H. Freeman. 3603: 3539: 3522: 3371: 3316: 3244:Letters in Mathematical Physics 2842: 2658: 2215:{\displaystyle A(x,y)=-A(y,x).} 3752:. Cambridge University Press. 3728:Introductory Quantum Mechanics 3499:to F. J. Dyson and A. Lenard: 3487:. Princeton University Press. 3228: 3211: 3168: 3052: 3038: 2993: 2706:periodic table of the elements 2633:nonlinear Schrödinger equation 2580: 2536: 2418: 2374: 2362: 2318: 2291: 2246: 2206: 2194: 2182: 2170: 2119: 2093: 2044: 2018: 1992: 1966: 1929: 1915: 1881: 1871: 1857: 1853: 1847: 1837: 1823: 1819: 1808: 1761: 1747: 1735: 1709: 1696: 1684: 1550: 1546: 1534: 1502: 1467: 1453: 1433: 1401: 1373: 1252:at the eight corners of a cube 1187:{\displaystyle \hbar =h/2\pi } 578:Relativistic quantum mechanics 110: 103: 84: 13: 1: 2987: 1266:around the nucleus. In 1922, 1090:(particles with half-integer 618:Quantum statistical mechanics 3299:Griffiths, David J. (2004), 3022:Introductory Nuclear Physics 2902:electron degeneracy pressure 2599:This shows that none of the 1206:, fermions are described by 7: 3940:Ground-state configurations 3750:Pauli's Exclusion Principle 3545:F. J. Dyson and A. Lenard: 3400:10.1103/PhysRevLett.74.4787 2943: 2910:neutron degeneracy pressure 2896:caused by heat produced in 2820:, which is stable due to a 2490:{\displaystyle x_{i}=x_{j}} 1081: 588:Quantum information science 10: 4101: 3909:Azimuthal quantum number ( 3900:Principal quantum number ( 3644:10.1103/PhysRevLett.75.985 2774: 2683:An example is the neutral 1414:{\displaystyle |y\rangle } 1386:{\displaystyle |x\rangle } 1237: 1232:Bose–Einstein distribution 1218:which are responsible for 1148:chemical behavior of atoms 4065:Pauli exclusion principle 4028: 4007: 3986: 3968:Pauli exclusion principle 3960: 3939: 3918:Magnetic quantum number ( 3890: 3860: 3677:. John Wiley & Sons. 3059:Langmuir, Irving (1919). 914:Pauli exclusion principle 3421:Kittel, Charles (2005), 2826:Lieb–Thirring inequality 2755:. In strong conductors ( 2670:electron shell structure 2663: 2519:{\displaystyle i\neq j,} 1311:degenerate energy levels 1299:principal quantum number 1057:Bose–Einstein condensate 973:azimuthal quantum number 965:principal quantum number 916:states that two or more 623:Quantum machine learning 376:Wheeler's delayed-choice 3613:Physical Review Letters 3349:10.1103/PhysRevA.39.897 2951:Spin-statistics theorem 2880:hydrostatic equilibrium 2613:spin–statistics theorem 2607:Advanced quantum theory 2450:{\displaystyle i\neq j} 1949:. But this is equal to 1196:reduced Planck constant 1001:, then their values of 984:magnetic quantum number 946:spin–statistics theorem 333:Leggett–Garg inequality 3854:Electron configuration 3323:Drake, G.W.F. (1989). 3177:Zeitschrift fĂŒr Physik 3107:Shaviv, Glora (2010). 2966:Fermi–Dirac statistics 2731:Solid state properties 2593: 2520: 2491: 2451: 2425: 2298: 2216: 2148: 2067: 1943: 1898: 1782: 1573: 1481: 1415: 1387: 1359: 1317:for the same value of 1188: 1055:, or atoms found in a 124: 38: 4085:Lorentz Medal winners 4008:Bonding participation 3927:Spin quantum number ( 3786:Scerri, Eric (2007). 3483:G. L. Sewell (2002). 2920:(or more accurately, 2784:uncertainty principle 2775:Further information: 2594: 2521: 2492: 2452: 2426: 2299: 2217: 2149: 2068: 1944: 1899: 1783: 1574: 1482: 1416: 1388: 1355:antisymmetrical class 1347: 1272:his model of the atom 1189: 1157:value of fermions is 318:Elitzur–Vaidman 308:Davisson–Germer 125: 33: 2956:Exchange interaction 2898:thermonuclear fusion 2833:exchange interaction 2674:electrically neutral 2617:quantum field theory 2530: 2501: 2461: 2435: 2312: 2240: 2164: 2083: 1956: 1911: 1798: 1678: 1498: 1429: 1397: 1369: 1208:antisymmetric states 1161: 1100:elementary particles 583:Quantum field theory 495:Consistent histories 132:Schrödinger equation 59: 4070:Concepts in physics 3636:1995PhRvL..75..985L 3589:1967JMP.....8.1538D 3519:, 698–711 (1968) ). 3392:1995PhRvL..74.4787D 3341:1989PhRvA..39..897D 3256:1982LMaPh...6..283I 3189:1925ZPhy...31..765P 3152:2004quant.ph..3199S 3080:10.1021/ja02227a002 2930:gravitational field 2885:degeneracy pressure 2804:and Andrew Lenard ( 2777:Stability of matter 2771:Stability of matter 2759:) electrons are so 1258:suggested that the 1128:subatomic particles 995:spin quantum number 918:identical particles 371:Stern–Gerlach 168:Classical mechanics 3730:. Addison-Wesley. 3724:Liboff, Richard L. 3565:, 698–711 (1968) ) 3557:, 423–434 (1967); 3511:, 423–434 (1967); 3264:10.1007/BF00400323 3197:10.1007/BF02980631 2861:general relativity 2818:Thomas-Fermi model 2745:molecular orbitals 2589: 2516: 2487: 2447: 2421: 2304:are identified by 2294: 2225:For a system with 2212: 2144: 2063: 1939: 1894: 1778: 1569: 1530: 1477: 1411: 1383: 1254:. In 1919 chemist 1184: 922:half-integer spins 559:Von Neumann–Wigner 539:Objective-collapse 338:Mach–Zehnder 328:Leggett inequality 323:Franck–Hertz 173:Old quantum theory 120: 39: 4052: 4051: 4030:Electron counting 3999:Unpaired electron 3875:Quantum mechanics 3801:978-0-19-530573-9 3708:. W. H. Freeman. 3684:978-3-527-66769-7 3597:10.1063/1.1705389 3434:978-0-471-41526-8 3386:(24): 4787–4790. 3303:, Prentice Hall, 3118:978-3-642-02087-2 3031:978-0-471-80553-3 2961:Exchange symmetry 2890:degenerate matter 2851:objects. In 1995 2822:theorem of Teller 2637:interacting spins 2621:rotation operator 2611:According to the 1515: 1351:symmetrical class 1244:chemically stable 1220:superconductivity 1204:quantum mechanics 934:quantum mechanics 910:quantum mechanics 906: 905: 613:Scattering theory 593:Quantum computing 366:Schrödinger's cat 298:Bell's inequality 106: 81: 50:Quantum mechanics 16:(Redirected from 4092: 4080:Chemical bonding 4044:18-electron rule 4015:Valence electron 3987:Electron pairing 3978:Aufbau principle 3961:Electron filling 3930: 3921: 3912: 3903: 3847: 3840: 3833: 3824: 3823: 3805: 3793: 3782: 3763: 3746:Massimi, Michela 3741: 3719: 3689: 3688: 3670: 3664: 3663: 3629: 3627:cond-mat/9506047 3607: 3601: 3600: 3583:(8): 1538–1545. 3572: 3566: 3543: 3537: 3526: 3520: 3498: 3480: 3478: 3465: 3459: 3458: 3456: 3444: 3438: 3437: 3418: 3412: 3411: 3375: 3369: 3368: 3320: 3314: 3313: 3296: 3290: 3289: 3287: 3286: 3280: 3274:. Archived from 3241: 3232: 3226: 3225: 3223: 3215: 3209: 3208: 3172: 3166: 3165: 3163: 3145: 3143:quant-ph/0403199 3129: 3123: 3122: 3104: 3098: 3097: 3095: 3094: 3088: 3082:. Archived from 3065: 3056: 3050: 3049: 3042: 3036: 3035: 3017: 3011: 3010: 3008: 3007: 2997: 2894:thermal pressure 2765:thermal capacity 2726: 2724: 2598: 2596: 2595: 2590: 2573: 2572: 2554: 2553: 2525: 2523: 2522: 2517: 2496: 2494: 2493: 2488: 2486: 2485: 2473: 2472: 2456: 2454: 2453: 2448: 2430: 2428: 2427: 2422: 2411: 2410: 2392: 2391: 2355: 2354: 2336: 2335: 2303: 2301: 2300: 2295: 2290: 2289: 2271: 2270: 2258: 2257: 2231: 2221: 2219: 2218: 2213: 2153: 2151: 2150: 2145: 2122: 2096: 2072: 2070: 2069: 2064: 2047: 2021: 1995: 1969: 1948: 1946: 1945: 1940: 1932: 1918: 1903: 1901: 1900: 1895: 1890: 1889: 1874: 1860: 1840: 1826: 1818: 1817: 1811: 1787: 1785: 1784: 1779: 1777: 1776: 1764: 1750: 1745: 1744: 1738: 1712: 1666: 1648: 1638: 1623: 1596: 1578: 1576: 1575: 1570: 1553: 1529: 1505: 1486: 1484: 1483: 1478: 1470: 1456: 1436: 1420: 1418: 1417: 1412: 1404: 1392: 1390: 1389: 1384: 1376: 1331:George Uhlenbeck 1295:Edmund C. Stoner 1248:Gilbert N. Lewis 1193: 1191: 1190: 1185: 1177: 1155:angular momentum 1114:. Additionally, 898: 891: 884: 525:Superdeterminism 178:Bra–ket notation 129: 127: 126: 121: 113: 108: 107: 99: 87: 82: 80: 69: 41: 40: 21: 4100: 4099: 4095: 4094: 4093: 4091: 4090: 4089: 4055: 4054: 4053: 4048: 4024: 4003: 3982: 3956: 3935: 3928: 3919: 3910: 3901: 3892:Quantum numbers 3886: 3856: 3851: 3813: 3808: 3802: 3779: 3760: 3738: 3716: 3692: 3685: 3671: 3667: 3608: 3604: 3573: 3569: 3544: 3540: 3527: 3523: 3495: 3476:math-ph/0209034 3466: 3462: 3454:math-ph/0209034 3445: 3441: 3435: 3419: 3415: 3380:Phys. Rev. Lett 3376: 3372: 3321: 3317: 3311: 3297: 3293: 3284: 3282: 3278: 3239: 3233: 3229: 3221: 3217: 3216: 3212: 3173: 3169: 3161:10.1.1.251.9585 3130: 3126: 3119: 3105: 3101: 3092: 3090: 3086: 3063: 3057: 3053: 3044: 3043: 3039: 3032: 3018: 3014: 3005: 3003: 2999: 2998: 2994: 2990: 2985: 2946: 2845: 2837:Coulombic force 2814:Walter Thirring 2810:Elliott H. Lieb 2779: 2773: 2733: 2722: 2720: 2718: 2666: 2661: 2609: 2568: 2564: 2549: 2545: 2531: 2528: 2527: 2502: 2499: 2498: 2481: 2477: 2468: 2464: 2462: 2459: 2458: 2436: 2433: 2432: 2406: 2402: 2387: 2383: 2350: 2346: 2331: 2327: 2313: 2310: 2309: 2285: 2281: 2266: 2262: 2253: 2249: 2241: 2238: 2237: 2226: 2165: 2162: 2161: 2118: 2092: 2084: 2081: 2080: 2043: 2017: 1991: 1965: 1957: 1954: 1953: 1928: 1914: 1912: 1909: 1908: 1885: 1884: 1870: 1856: 1836: 1822: 1813: 1812: 1807: 1799: 1796: 1795: 1772: 1771: 1760: 1746: 1740: 1739: 1734: 1708: 1679: 1676: 1675: 1653: 1640: 1625: 1624:. This implies 1598: 1583: 1549: 1519: 1501: 1499: 1496: 1495: 1466: 1452: 1432: 1430: 1427: 1426: 1400: 1398: 1395: 1394: 1372: 1370: 1367: 1366: 1343: 1327:Samuel Goudsmit 1264:electron shells 1256:Irving Langmuir 1240: 1173: 1162: 1159: 1158: 1084: 1043: 1037:= +1/2 and one 1036: 1029: 1022: 1014: 991: 980: 957:quantum numbers 902: 873: 872: 871: 636: 628: 627: 573: 572:Advanced topics 565: 564: 563: 515:Hidden-variable 505:de Broglie–Bohm 484: 482:Interpretations 474: 473: 472: 442: 434: 433: 432: 390: 382: 381: 380: 347: 303:CHSH inequality 292: 284: 283: 282: 211:Complementarity 205: 197: 196: 195: 163: 134: 109: 98: 97: 83: 73: 68: 60: 57: 56: 28: 23: 22: 18:Pauli exclusion 15: 12: 11: 5: 4098: 4088: 4087: 4082: 4077: 4072: 4067: 4050: 4049: 4047: 4046: 4041: 4035: 4033: 4026: 4025: 4023: 4022: 4017: 4011: 4009: 4005: 4004: 4002: 4001: 3996: 3990: 3988: 3984: 3983: 3981: 3980: 3975: 3970: 3964: 3962: 3958: 3957: 3955: 3954: 3949: 3943: 3941: 3937: 3936: 3934: 3933: 3924: 3915: 3906: 3896: 3894: 3888: 3887: 3885: 3884: 3883: 3882: 3872: 3870:Atomic orbital 3867: 3865:Electron shell 3861: 3858: 3857: 3850: 3849: 3842: 3835: 3827: 3821: 3820: 3812: 3811:External links 3809: 3807: 3806: 3800: 3783: 3777: 3769:Modern Physics 3764: 3758: 3742: 3736: 3720: 3714: 3700: 3699: 3698: 3696: 3691: 3690: 3683: 3665: 3602: 3567: 3559:J. Math. Phys. 3551:J. Math. Phys. 3538: 3521: 3513:J. Math. Phys. 3505:J. Math. Phys. 3493: 3460: 3439: 3433: 3413: 3370: 3335:(2): 897–899. 3315: 3309: 3291: 3250:(4): 283–288. 3227: 3210: 3183:(1): 765–783. 3167: 3124: 3117: 3099: 3074:(6): 868–934. 3051: 3037: 3030: 3012: 2991: 2989: 2986: 2984: 2983: 2978: 2973: 2968: 2963: 2958: 2953: 2947: 2945: 2942: 2844: 2841: 2795:Paul Ehrenfest 2772: 2769: 2749:band structure 2741:semiconductors 2732: 2729: 2716: 2713:paronic states 2665: 2662: 2660: 2657: 2625:imaginary time 2608: 2605: 2588: 2585: 2582: 2579: 2576: 2571: 2567: 2563: 2560: 2557: 2552: 2548: 2544: 2541: 2538: 2535: 2515: 2512: 2509: 2506: 2484: 2480: 2476: 2471: 2467: 2446: 2443: 2440: 2420: 2417: 2414: 2409: 2405: 2401: 2398: 2395: 2390: 2386: 2382: 2379: 2376: 2373: 2370: 2367: 2364: 2361: 2358: 2353: 2349: 2345: 2342: 2339: 2334: 2330: 2326: 2323: 2320: 2317: 2293: 2288: 2284: 2280: 2277: 2274: 2269: 2265: 2261: 2256: 2252: 2248: 2245: 2223: 2222: 2211: 2208: 2205: 2202: 2199: 2196: 2193: 2190: 2187: 2184: 2181: 2178: 2175: 2172: 2169: 2155: 2154: 2143: 2140: 2137: 2134: 2131: 2128: 2125: 2121: 2117: 2114: 2111: 2108: 2105: 2102: 2099: 2095: 2091: 2088: 2074: 2073: 2062: 2059: 2056: 2053: 2050: 2046: 2042: 2039: 2036: 2033: 2030: 2027: 2024: 2020: 2016: 2013: 2010: 2007: 2004: 2001: 1998: 1994: 1990: 1987: 1984: 1981: 1978: 1975: 1972: 1968: 1964: 1961: 1938: 1935: 1931: 1927: 1924: 1921: 1917: 1905: 1904: 1893: 1888: 1883: 1880: 1877: 1873: 1869: 1866: 1863: 1859: 1855: 1852: 1849: 1846: 1843: 1839: 1835: 1832: 1829: 1825: 1821: 1816: 1810: 1806: 1803: 1789: 1788: 1775: 1770: 1767: 1763: 1759: 1756: 1753: 1749: 1743: 1737: 1733: 1730: 1727: 1724: 1721: 1718: 1715: 1711: 1707: 1704: 1701: 1698: 1695: 1692: 1689: 1686: 1683: 1669:in every basis 1580: 1579: 1568: 1565: 1562: 1559: 1556: 1552: 1548: 1545: 1542: 1539: 1536: 1533: 1528: 1525: 1522: 1518: 1514: 1511: 1508: 1504: 1476: 1473: 1469: 1465: 1462: 1459: 1455: 1451: 1448: 1445: 1442: 1439: 1435: 1410: 1407: 1403: 1382: 1379: 1375: 1342: 1339: 1291:ferromagnetism 1260:periodic table 1239: 1236: 1224:W and Z bosons 1183: 1180: 1176: 1172: 1169: 1166: 1083: 1080: 1041: 1034: 1027: 1020: 1012: 989: 978: 955:four of their 938:Wolfgang Pauli 904: 903: 901: 900: 893: 886: 878: 875: 874: 870: 869: 864: 859: 854: 849: 844: 839: 834: 829: 824: 819: 814: 809: 804: 799: 794: 789: 784: 779: 774: 769: 764: 759: 754: 749: 744: 739: 734: 729: 724: 719: 714: 709: 704: 699: 694: 689: 684: 679: 674: 669: 664: 659: 654: 649: 644: 638: 637: 634: 633: 630: 629: 626: 625: 620: 615: 610: 608:Density matrix 605: 600: 595: 590: 585: 580: 574: 571: 570: 567: 566: 562: 561: 556: 551: 546: 541: 536: 531: 530: 529: 528: 527: 512: 507: 502: 497: 492: 486: 485: 480: 479: 476: 475: 471: 470: 465: 460: 455: 450: 444: 443: 440: 439: 436: 435: 431: 430: 425: 420: 415: 410: 405: 399: 398: 397: 391: 388: 387: 384: 383: 379: 378: 373: 368: 362: 361: 360: 359: 358: 356:Delayed-choice 351:Quantum eraser 346: 345: 340: 335: 330: 325: 320: 315: 310: 305: 300: 294: 293: 290: 289: 286: 285: 281: 280: 279: 278: 268: 263: 258: 253: 248: 243: 241:Quantum number 238: 233: 228: 223: 218: 213: 207: 206: 203: 202: 199: 198: 194: 193: 188: 182: 181: 180: 175: 170: 164: 161: 160: 157: 156: 155: 154: 149: 144: 136: 135: 130: 119: 116: 112: 105: 102: 96: 93: 90: 86: 79: 76: 72: 67: 64: 53: 52: 46: 45: 35:Wolfgang Pauli 26: 9: 6: 4: 3: 2: 4097: 4086: 4083: 4081: 4078: 4076: 4073: 4071: 4068: 4066: 4063: 4062: 4060: 4045: 4042: 4040: 4037: 4036: 4034: 4031: 4027: 4021: 4020:Core electron 4018: 4016: 4013: 4012: 4010: 4006: 4000: 3997: 3995: 3994:Electron pair 3992: 3991: 3989: 3985: 3979: 3976: 3974: 3971: 3969: 3966: 3965: 3963: 3959: 3953: 3950: 3948: 3945: 3944: 3942: 3938: 3932: 3925: 3923: 3916: 3914: 3907: 3905: 3898: 3897: 3895: 3893: 3889: 3881: 3878: 3877: 3876: 3873: 3871: 3868: 3866: 3863: 3862: 3859: 3855: 3848: 3843: 3841: 3836: 3834: 3829: 3828: 3825: 3818: 3815: 3814: 3803: 3797: 3792: 3791: 3784: 3780: 3778:0-7167-4345-0 3774: 3770: 3765: 3761: 3759:0-521-83911-4 3755: 3751: 3747: 3743: 3739: 3737:0-8053-8714-5 3733: 3729: 3725: 3721: 3717: 3715:1-4292-0068-5 3711: 3707: 3702: 3701: 3697: 3694: 3693: 3686: 3680: 3676: 3669: 3661: 3657: 3653: 3649: 3645: 3641: 3637: 3633: 3628: 3623: 3619: 3615: 3614: 3606: 3598: 3594: 3590: 3586: 3582: 3578: 3577:J. Math. Phys 3571: 3564: 3560: 3556: 3552: 3548: 3542: 3535: 3534:Lorentz Medal 3531: 3525: 3518: 3514: 3510: 3506: 3502: 3496: 3494:0-691-05832-6 3490: 3486: 3477: 3472: 3464: 3455: 3450: 3443: 3436: 3430: 3426: 3425: 3417: 3409: 3405: 3401: 3397: 3393: 3389: 3385: 3381: 3374: 3366: 3362: 3358: 3354: 3350: 3346: 3342: 3338: 3334: 3330: 3326: 3319: 3312: 3310:0-13-111892-7 3306: 3302: 3295: 3281:on 2018-11-25 3277: 3273: 3269: 3265: 3261: 3257: 3253: 3249: 3245: 3238: 3231: 3220: 3214: 3206: 3202: 3198: 3194: 3190: 3186: 3182: 3178: 3171: 3162: 3157: 3153: 3149: 3144: 3139: 3135: 3128: 3120: 3114: 3110: 3103: 3089:on 2012-03-30 3085: 3081: 3077: 3073: 3069: 3062: 3055: 3047: 3041: 3033: 3027: 3023: 3016: 3002: 2996: 2992: 2982: 2979: 2977: 2974: 2972: 2969: 2967: 2964: 2962: 2959: 2957: 2954: 2952: 2949: 2948: 2941: 2939: 2935: 2931: 2927: 2923: 2919: 2918:Young modulus 2915: 2911: 2907: 2906:neutron stars 2903: 2899: 2895: 2891: 2887: 2886: 2881: 2877: 2876:neutron stars 2873: 2868: 2866: 2862: 2858: 2857:neutron stars 2854: 2850: 2840: 2838: 2834: 2829: 2827: 2823: 2819: 2815: 2811: 2807: 2803: 2802:Freeman Dyson 2798: 2796: 2791: 2789: 2785: 2778: 2768: 2766: 2762: 2758: 2754: 2753:energy levels 2750: 2746: 2742: 2738: 2728: 2714: 2709: 2707: 2702: 2698: 2694: 2690: 2686: 2681: 2679: 2675: 2671: 2656: 2654: 2650: 2646: 2642: 2641:Hubbard model 2638: 2634: 2628: 2626: 2622: 2618: 2614: 2604: 2602: 2586: 2583: 2577: 2574: 2569: 2565: 2561: 2558: 2555: 2550: 2546: 2542: 2539: 2533: 2513: 2510: 2507: 2504: 2482: 2478: 2474: 2469: 2465: 2444: 2441: 2438: 2415: 2412: 2407: 2403: 2399: 2396: 2393: 2388: 2384: 2380: 2377: 2371: 2368: 2365: 2359: 2356: 2351: 2347: 2343: 2340: 2337: 2332: 2328: 2324: 2321: 2315: 2307: 2286: 2282: 2278: 2275: 2272: 2267: 2263: 2259: 2254: 2250: 2243: 2235: 2229: 2209: 2203: 2200: 2197: 2191: 2188: 2185: 2179: 2176: 2173: 2167: 2160: 2159: 2158: 2141: 2138: 2135: 2129: 2126: 2123: 2115: 2109: 2103: 2100: 2097: 2089: 2079: 2078: 2077: 2060: 2054: 2051: 2048: 2040: 2034: 2028: 2025: 2022: 2014: 2008: 2002: 1999: 1996: 1988: 1982: 1976: 1973: 1970: 1962: 1952: 1951: 1950: 1933: 1925: 1919: 1891: 1875: 1867: 1861: 1850: 1841: 1833: 1827: 1804: 1794: 1793: 1792: 1765: 1757: 1751: 1731: 1725: 1719: 1716: 1713: 1705: 1699: 1693: 1690: 1687: 1681: 1674: 1673: 1672: 1670: 1664: 1660: 1656: 1650: 1647: 1643: 1636: 1632: 1628: 1621: 1617: 1613: 1609: 1605: 1601: 1594: 1590: 1586: 1566: 1560: 1557: 1554: 1543: 1540: 1537: 1531: 1526: 1523: 1520: 1516: 1512: 1506: 1494: 1493: 1492: 1490: 1489:superposition 1471: 1463: 1457: 1449: 1443: 1440: 1437: 1424: 1423:Hilbert space 1405: 1377: 1364: 1358: 1356: 1352: 1346: 1338: 1336: 1335:electron spin 1332: 1328: 1324: 1320: 1316: 1312: 1308: 1304: 1300: 1296: 1292: 1288: 1284: 1283:Zeeman effect 1280: 1275: 1273: 1269: 1265: 1261: 1257: 1253: 1249: 1245: 1235: 1233: 1229: 1225: 1221: 1217: 1213: 1209: 1205: 1201: 1197: 1181: 1178: 1174: 1170: 1167: 1164: 1156: 1151: 1149: 1145: 1141: 1137: 1133: 1129: 1125: 1121: 1117: 1113: 1109: 1105: 1101: 1097: 1093: 1089: 1079: 1075: 1073: 1069: 1068:antisymmetric 1065: 1064:wave function 1060: 1058: 1054: 1050: 1045: 1040: 1033: 1026: 1019: 1015: 1008: 1004: 1000: 996: 992: 985: 981: 974: 970: 966: 962: 959:, which are: 958: 954: 949: 947: 943: 939: 935: 931: 930:quantum state 927: 923: 919: 915: 911: 899: 894: 892: 887: 885: 880: 879: 877: 876: 868: 865: 863: 860: 858: 855: 853: 850: 848: 845: 843: 840: 838: 835: 833: 830: 828: 825: 823: 820: 818: 815: 813: 810: 808: 805: 803: 800: 798: 795: 793: 790: 788: 785: 783: 780: 778: 775: 773: 770: 768: 765: 763: 760: 758: 755: 753: 750: 748: 745: 743: 740: 738: 735: 733: 730: 728: 725: 723: 720: 718: 715: 713: 710: 708: 705: 703: 700: 698: 695: 693: 690: 688: 685: 683: 680: 678: 675: 673: 670: 668: 665: 663: 660: 658: 655: 653: 650: 648: 645: 643: 640: 639: 632: 631: 624: 621: 619: 616: 614: 611: 609: 606: 604: 601: 599: 598:Quantum chaos 596: 594: 591: 589: 586: 584: 581: 579: 576: 575: 569: 568: 560: 557: 555: 554:Transactional 552: 550: 547: 545: 544:Quantum logic 542: 540: 537: 535: 532: 526: 523: 522: 521: 518: 517: 516: 513: 511: 508: 506: 503: 501: 498: 496: 493: 491: 488: 487: 483: 478: 477: 469: 466: 464: 461: 459: 456: 454: 451: 449: 446: 445: 438: 437: 429: 426: 424: 421: 419: 416: 414: 411: 409: 406: 404: 401: 400: 396: 393: 392: 386: 385: 377: 374: 372: 369: 367: 364: 363: 357: 354: 353: 352: 349: 348: 344: 341: 339: 336: 334: 331: 329: 326: 324: 321: 319: 316: 314: 311: 309: 306: 304: 301: 299: 296: 295: 288: 287: 277: 274: 273: 272: 271:Wave function 269: 267: 264: 262: 259: 257: 254: 252: 251:Superposition 249: 247: 244: 242: 239: 237: 234: 232: 229: 227: 224: 222: 219: 217: 214: 212: 209: 208: 201: 200: 192: 189: 187: 184: 183: 179: 176: 174: 171: 169: 166: 165: 159: 158: 153: 150: 148: 145: 143: 140: 139: 138: 137: 133: 100: 94: 77: 74: 70: 62: 55: 54: 51: 48: 47: 43: 42: 36: 32: 19: 3967: 3789: 3768: 3749: 3727: 3705: 3674: 3668: 3620:(6): 985–9. 3617: 3611: 3605: 3580: 3576: 3570: 3562: 3558: 3554: 3550: 3546: 3541: 3529: 3524: 3516: 3512: 3508: 3504: 3500: 3484: 3463: 3442: 3422: 3416: 3383: 3379: 3373: 3332: 3329:Phys. Rev. A 3328: 3318: 3300: 3294: 3283:. Retrieved 3276:the original 3247: 3243: 3230: 3213: 3180: 3176: 3170: 3133: 3127: 3111:. Springer. 3108: 3102: 3091:. Retrieved 3084:the original 3071: 3067: 3054: 3040: 3021: 3015: 3004:. Retrieved 2995: 2981:Pauli effect 2922:bulk modulus 2883: 2869: 2853:Elliott Lieb 2849:astronomical 2846: 2843:Astrophysics 2830: 2799: 2792: 2780: 2734: 2712: 2710: 2701:ground state 2682: 2667: 2659:Applications 2653:Fermi sphere 2649:ground state 2645:Bethe ansatz 2629: 2610: 2600: 2305: 2233: 2227: 2224: 2156: 2075: 1906: 1790: 1668: 1662: 1658: 1654: 1651: 1645: 1641: 1634: 1630: 1626: 1619: 1615: 1611: 1607: 1603: 1599: 1592: 1588: 1584: 1581: 1360: 1348: 1344: 1322: 1318: 1307:alkali metal 1302: 1287:spectroscopy 1276: 1241: 1216:Cooper pairs 1200:half-integer 1152: 1085: 1076: 1071: 1061: 1046: 1038: 1031: 1024: 1017: 1010: 1006: 1002: 987: 976: 968: 960: 952: 950: 940:in 1925 for 913: 907: 453:Klein–Gordon 389:Formulations 226:Energy level 221:Entanglement 204:Fundamentals 191:Interference 142:Introduction 4075:Spintronics 3973:Hund's rule 3136:: 184–196. 2976:Hund's rule 2872:white dwarf 2693:eigenvalues 2685:helium atom 1582:where each 1315:noble gases 842:von Neumann 827:Schrödinger 603:EPR paradox 534:Many-worlds 468:Schrödinger 423:Schrödinger 418:Phase-space 408:Interaction 313:Double-slit 291:Experiments 266:Uncertainty 236:Nonlocality 231:Measurement 216:Decoherence 186:Hamiltonian 4059:Categories 4039:Octet rule 3285:2009-12-02 3093:2008-09-01 3006:2023-09-11 2988:References 2971:Fermi hole 2938:black hole 2865:black hole 2761:degenerate 2737:conductors 1285:in atomic 1268:Niels Bohr 1222:, and the 1198:) times a 837:Sommerfeld 752:Heisenberg 747:Gutzwiller 687:de Broglie 635:Scientists 549:Relational 500:Copenhagen 403:Heisenberg 261:Tunnelling 162:Background 3536:to Pauli. 3272:121829553 3205:122941900 3156:CiteSeerX 3024:. Wiley. 2578:… 2559:… 2540:… 2508:≠ 2442:≠ 2416:… 2397:… 2378:… 2369:− 2360:… 2341:… 2322:… 2276:… 2189:− 2133:⟩ 2116:ψ 2113:⟨ 2107:⟩ 2090:ψ 2087:⟨ 2058:⟩ 2041:ψ 2038:⟨ 2032:⟩ 2015:ψ 2012:⟨ 2006:⟩ 1989:ψ 1986:⟨ 1980:⟩ 1963:ψ 1960:⟨ 1937:⟩ 1923:⟩ 1879:⟩ 1865:⟩ 1851:⊗ 1845:⟩ 1831:⟩ 1805:ψ 1802:⟨ 1769:⟩ 1758:⊗ 1755:⟩ 1732:ψ 1729:⟨ 1723:⟩ 1706:ψ 1703:⟨ 1667:are zero 1564:⟩ 1517:∑ 1510:⟩ 1507:ψ 1475:⟩ 1464:⊗ 1461:⟩ 1447:⟩ 1409:⟩ 1381:⟩ 1279:empirical 1182:π 1165:ℏ 1134:(such as 1112:neutrinos 1108:electrons 1094:), while 948:of 1940. 942:electrons 867:Zeilinger 712:Ehrenfest 441:Equations 118:⟩ 115:Ψ 104:^ 92:⟩ 89:Ψ 66:ℏ 3748:(2005). 3726:(2002). 3652:10060179 3408:10058599 3365:35775478 2944:See also 2788:nucleons 2695:). 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Index

Pauli exclusion

Wolfgang Pauli
Quantum mechanics
Schrödinger equation
Introduction
Glossary
History
Classical mechanics
Old quantum theory
Bra–ket notation
Hamiltonian
Interference
Complementarity
Decoherence
Entanglement
Energy level
Measurement
Nonlocality
Quantum number
State
Superposition
Symmetry
Tunnelling
Uncertainty
Wave function
Collapse
Bell's inequality
CHSH inequality
Davisson–Germer

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