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Nickel–hydrogen battery

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599: 590: 581: 572: 349:. During discharge, hydrogen contained in the pressure vessel is oxidized into water while the nickel oxyhydroxide electrode is reduced to nickel hydroxide. Water is consumed at the nickel electrode and produced at the hydrogen electrode, so the concentration of the potassium hydroxide electrolyte does not change. As the battery discharges, the hydrogen pressure drops, providing a reliable state of charge indicator. In one communication satellite battery, the pressure at full charge was over 500 pounds/square inch (3.4 MPa), dropping to only about 15 PSI (0.1 MPa) at full discharge. 335: 45: 624: 1291: 638: 608: 484:
of 55-60 watt-hours/kg, and very long cycle life (40,000 cycles at 40% DOD) and operating life (> 15 years) in satellite applications. The cells can tolerate overcharging and accidental polarity reversal, and the hydrogen pressure in the cell provides a good indication of the state of charge.
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If the cell is over-charged, the oxygen produced at the nickel electrode reacts with the hydrogen present in the cell and forms water; as a consequence the cells can withstand overcharging as long as the heat generated can be dissipated.
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However, the gaseous nature of hydrogen means that the volume efficiency is relatively low (60-100 Wh/L for an IPV (individual pressure vessel) cell), and the high pressure required makes for high-cost pressure vessels.
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which is proportional to the pressure of hydrogen in the cell; in some designs, 50% of the capacity can be lost after only a few days' storage. Self-discharge is less at lower temperature.
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The nickel-hydrogen battery combines the positive nickel electrode of a nickel-cadmium battery and the negative electrode, including the catalyst and gas diffusion elements, of a
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Common/dependent pressure vessel (C/DPV) is a hybrid of the common pressure vessel (CPV) and the dependent pressure vessel (DPV) with a high volumetric efficiency.
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The cells have the disadvantage of relatively high self-discharge rate, i.e. chemical reduction of Ni(III) into Ni(II) in the cathode:
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The Hubble replacement batteries are produced with a wet slurry process where a binder agent and powdered metallic materials are
17: 362: 1053: 813: 935: 1007: 1491: 1378: 285:, when its original batteries were changed in May 2009 more than 19 years after launch, led with the highest number of 1160: 719: 681: 1051: 1531: 1173: 1069: 1036: 1025: 950: 877: 666: 150: 31: 1706: 1541: 1701: 1469: 1551: 892: 790: 235:, the distinctive virtue of the nickel–hydrogen battery is its long life: the cells handle more than 20,000 1213: 240: 1383: 661: 266: 1091: 1556: 1526: 1511: 1479: 1571: 1318: 598: 589: 580: 571: 1586: 1484: 910: 750: 548:
Single pressure vessel (SPV) design combines up to 22 cells in series in a single pressure vessel.
169:) pressure. The nickel–hydrogen battery was patented in the United States on February 25, 1971 by 1591: 1536: 1521: 1474: 1454: 1413: 1388: 1368: 1348: 1206: 629: 1680: 1581: 339: 282: 162: 1546: 1442: 1363: 893:
Validation of International Space Station electrical performance model via on-orbit telemetry
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Dependent pressure vessel (DPV) cell design offers higher specific energy and reduced cost.
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A lightweight high reliability single battery power system for interplanetary spacecraft
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cell stacks in series in a common pressure vessel. The CPV provides a slightly higher
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Compared with other rechargeable batteries, a nickel-hydrogen battery provides good
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Overview of the design, development, and application of nickel-hydrogen batteries
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A microfabricated nickel-hydrogen battery using thick film printing techniques
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Individual pressure vessel (IPV) design consists of a single unit of NiH
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History of the battery § Nickel-hydrogen and nickel metal-hydride
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reliability impact upon Hubble Space Telescope battery replacement
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Hermetically sealed nickel-hydrogen storage cell US Patent 3669744
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The development of the nickel hydrogen battery started in 1970 at
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Implantable nickel hydrogen batteries for bio-power applications
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Nickel-hydrogen spacecraft battery handling and storage practice
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and was used for the first time in 1977 aboard the U.S. Navy's
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While the energy density is only around one third as that of a
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Optimization of spacecraft electrical power subsystems -Pag.40
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Common/dependent-pressure-vessel nickel-hydrogen Batteries
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at a loading of 7 mg/cm2 and the separator is knit
467:{\displaystyle {\ce {NiOOH + 1/2H2 <=> Ni(OH)2.}}} 228:, the average voltage during discharge is 1.25 V. 213: 66: 555:, positive-to-negative back-to-back stacked in a SPV. 537:
Common pressure vessel (CPV) design consist of two NiH
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possess properties which make them attractive for the
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A nickel/hydrogen battery for terrestrial PV systems
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Hubble space telescope servicing mission 4 batteries
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Hubble Space Telescope Servicing Mission 4 Batteries
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Hubble space telescope servicing mission 4 batteries
619: 762: 466: 1153:Nickel-Hydrogen Batteries Principles and Practice 772:Five-year update: nickel hydrogen industry survey 425: 424: 407: 406: 281:are equipped with nickel–hydrogen batteries. The 1693: 1155:, The Aerospace Press, El Segundo, California. 1214: 1008:NTS-2 Nickel-Hydrogen Battery Performance 31 1184:NASA handbook for nickel-hydrogen batteries 882:Cell Characterization for INTELSAT Programs 488:The positive electrode is made up of a dry 1221: 1207: 706: 704: 702: 1228: 157:in gaseous form, stored in a pressurized 1110:Development of a large scale bipolar NiH 732: 730: 728: 333: 722:Chapter 32, "Nickel Hydrogen Batteries" 699: 400: 261:of electrical energy in satellites and 49:Schematics of a nickel-hydrogen battery 14: 1694: 1202: 1092:Nickel hydrogen batteries-an overview 1041:dry sinter and slurry electrode cells 725: 492:porous nickel plaque, which contains 1126:1995–dependent pressure vessel (DPV) 712:Handbook of Batteries Third Edition 521:and heated to boil off the liquid. 151:nickel–metal hydride (NiMH) battery 24: 1145: 1037:Performance comparison between NiH 329: 25: 1718: 1167: 751:NASA/CR—2001-210563/PART2 -Pag.10 710:David Linden, Thomas Reddy (ed.) 682:Timeline of hydrogen technologies 551:Bipolar design is based on thick 317:Navigation technology satellite-2 1289: 636: 622: 606: 597: 588: 579: 570: 43: 1130: 1119: 1103: 1085: 1074: 1063: 1045: 1030: 1019: 1001: 970: 955: 944: 926: 915: 904: 886: 871: 860: 829: 818: 807: 776: 737:Spacecraft Power Systems Pag.9 447: 441: 427: 402: 338:Nickel-hydrogen batteries for 175:Vyacheslav Mikhailovic Sergeev 13: 1: 692: 667:Nickel–metal hydride battery 32:Nickel–metal hydride battery 27:Type of rechargeable battery 7: 662:Comparison of battery types 615: 534:cells in a pressure vessel. 287:charge and discharge cycles 200:of 15 years or more at 80% 107:Charge/discharge efficiency 10: 1723: 1151:Albert H. Zimmerman (ed), 524: 304: 300: 29: 1628: 1600: 1422: 1379:Metal–air electrochemical 1298: 1287: 1236: 1070:Nickel-Hydrogen Batteries 503:utilises a teflon-bonded 321:Eagle-Picher Technologies 114: 106: 93: 73: 54: 42: 179:Boris Ioselevich Tsenter 30:Not to be confused with 630:Renewable energy portal 514:cloth (ZYK-15 Zircar). 181:from the Soviet Union. 131:nickel–hydrogen battery 38:Nickel–hydrogen battery 18:Nickel hydrogen battery 1707:Rechargeable batteries 1681:Semipermeable membrane 1470:Lithium–iron–phosphate 468: 342: 325:Johnson Controls, Inc. 283:Hubble Space Telescope 255:rechargeable batteries 1702:Hydrogen technologies 1552:Rechargeable alkaline 1230:Electrochemical cells 672:Power-to-weight ratio 657:List of battery sizes 652:List of battery types 469: 337: 1532:Nickel–metal hydride 933:Mars Global Surveyor 714:, McGraw-Hill, 2002 363: 279:Mars Global Surveyor 222:open-circuit voltage 171:Alexandr Ilich Kloss 149:. It differs from a 1542:Polysulfide–bromide 1384:Nickel oxyhydroxide 1276:Thermogalvanic cell 459: 413: 395: 265:. For example, the 245:faradaic efficiency 220:220 W/kg. The 190:potassium hydroxide 161:at up to 1200  39: 1305:(non-rechargeable) 1249:Concentration cell 1097:2009-04-12 at the 1056:2008-08-17 at the 1013:2009-08-10 at the 938:2009-08-10 at the 898:2009-02-18 at the 756:2008-12-19 at the 687:Batteries in space 464: 439: 432: 383: 382: 343: 202:depth of discharge 37: 1689: 1688: 446: 438: 434: 386: 381: 369: 271:Mercury Messenger 241:energy efficiency 127: 126: 16:(Redirected from 1714: 1485:Lithium–titanate 1430: 1306: 1293: 1254:Electric battery 1223: 1216: 1209: 1200: 1199: 1139: 1134: 1128: 1123: 1117: 1107: 1101: 1089: 1083: 1078: 1072: 1067: 1061: 1049: 1043: 1034: 1028: 1023: 1017: 1005: 999: 998: 996: 995: 989: 983:. Archived from 982: 974: 968: 959: 953: 948: 942: 930: 924: 919: 913: 908: 902: 890: 884: 875: 869: 864: 858: 857: 855: 854: 848: 842:. Archived from 841: 833: 827: 822: 816: 811: 805: 804: 802: 801: 795: 789:. Archived from 788: 780: 774: 769: 760: 748: 739: 734: 723: 708: 646: 641: 640: 632: 627: 626: 610: 601: 592: 583: 574: 494:nickel hydroxide 473: 471: 470: 465: 463: 458: 455: 450: 444: 436: 435: 433: 431: 430: 423: 415: 414: 412: 405: 397: 394: 391: 384: 374: 367: 216:, 60 Wh/dm 188:cells using 26% 123: 115:Cycle durability 102: 89: 69: 47: 40: 36: 21: 1722: 1721: 1717: 1716: 1715: 1713: 1712: 1711: 1692: 1691: 1690: 1685: 1624: 1603: 1596: 1517:Nickel–hydrogen 1475:Lithium–polymer 1431: 1428: 1427: 1418: 1307: 1304: 1303: 1294: 1285: 1232: 1227: 1170: 1148: 1146:Further reading 1143: 1142: 1135: 1131: 1124: 1120: 1113: 1108: 1104: 1099:Wayback Machine 1090: 1086: 1079: 1075: 1068: 1064: 1058:Wayback Machine 1050: 1046: 1040: 1035: 1031: 1024: 1020: 1015:Wayback Machine 1006: 1002: 993: 991: 987: 980: 976: 975: 971: 965: 960: 956: 949: 945: 940:Wayback Machine 931: 927: 920: 916: 909: 905: 900:Wayback Machine 891: 887: 881: 876: 872: 865: 861: 852: 850: 846: 839: 835: 834: 830: 823: 819: 812: 808: 799: 797: 793: 786: 782: 781: 777: 770: 763: 758:Wayback Machine 749: 742: 735: 726: 709: 700: 695: 677:Pressure vessel 642: 635: 628: 621: 618: 611: 602: 593: 584: 575: 543:specific energy 540: 533: 527: 496:. The negative 482:specific energy 456: 451: 440: 426: 419: 418: 416: 408: 401: 399: 398: 396: 392: 387: 366: 364: 361: 360: 332: 330:Characteristics 309: 303: 295:low Earth orbit 292: 253: 233:lithium battery 187: 140: 136: 118: 100: 80: 60: 56:Specific energy 50: 35: 28: 23: 22: 15: 12: 11: 5: 1720: 1710: 1709: 1704: 1687: 1686: 1684: 1683: 1678: 1673: 1668: 1663: 1658: 1653: 1648: 1643: 1638: 1632: 1630: 1626: 1625: 1623: 1622: 1617: 1612: 1610:Atomic battery 1606: 1604: 1601: 1598: 1597: 1595: 1594: 1589: 1584: 1582:Vanadium redox 1579: 1574: 1569: 1564: 1559: 1557:Silver–cadmium 1554: 1549: 1544: 1539: 1534: 1529: 1527:Nickel–lithium 1524: 1519: 1514: 1512:Nickel–cadmium 1509: 1504: 1499: 1494: 1489: 1488: 1487: 1482: 1480:Lithium–sulfur 1477: 1472: 1467: 1457: 1452: 1451: 1450: 1440: 1434: 1432: 1429:(rechargeable) 1425:Secondary cell 1423: 1420: 1419: 1417: 1416: 1411: 1406: 1401: 1396: 1391: 1386: 1381: 1376: 1371: 1366: 1361: 1356: 1351: 1349:Edison–Lalande 1346: 1341: 1336: 1331: 1326: 1321: 1316: 1310: 1308: 1299: 1296: 1295: 1288: 1286: 1284: 1283: 1278: 1273: 1268: 1267: 1266: 1264:Trough battery 1261: 1251: 1246: 1240: 1238: 1234: 1233: 1226: 1225: 1218: 1211: 1203: 1197: 1196: 1191: 1186: 1181: 1176: 1169: 1168:External links 1166: 1165: 1164: 1147: 1144: 1141: 1140: 1129: 1118: 1111: 1102: 1084: 1073: 1062: 1044: 1038: 1029: 1018: 1000: 969: 963: 954: 943: 925: 914: 903: 885: 879: 870: 859: 828: 817: 806: 775: 761: 740: 724: 697: 696: 694: 691: 690: 689: 684: 679: 674: 669: 664: 659: 654: 648: 647: 633: 617: 614: 613: 612: 605: 603: 596: 594: 587: 585: 578: 576: 569: 567: 563: 562: 559: 556: 549: 546: 538: 535: 531: 526: 523: 505:platinum black 475: 474: 462: 454: 449: 443: 429: 422: 411: 404: 390: 380: 377: 372: 331: 328: 305:Main article: 302: 299: 290: 259:energy storage 251: 218:specific power 206:energy density 185: 153:by the use of 138: 134: 125: 124: 116: 112: 111: 108: 104: 103: 97: 95:Specific power 91: 90: 77: 75:Energy density 71: 70: 58: 52: 51: 48: 26: 9: 6: 4: 3: 2: 1719: 1708: 1705: 1703: 1700: 1699: 1697: 1682: 1679: 1677: 1674: 1672: 1669: 1667: 1664: 1662: 1659: 1657: 1654: 1652: 1649: 1647: 1644: 1642: 1639: 1637: 1634: 1633: 1631: 1627: 1621: 1618: 1616: 1613: 1611: 1608: 1607: 1605: 1599: 1593: 1590: 1588: 1585: 1583: 1580: 1578: 1575: 1573: 1572:Sodium–sulfur 1570: 1568: 1565: 1563: 1560: 1558: 1555: 1553: 1550: 1548: 1547:Potassium ion 1545: 1543: 1540: 1538: 1535: 1533: 1530: 1528: 1525: 1523: 1520: 1518: 1515: 1513: 1510: 1508: 1505: 1503: 1500: 1498: 1495: 1493: 1490: 1486: 1483: 1481: 1478: 1476: 1473: 1471: 1468: 1466: 1463: 1462: 1461: 1458: 1456: 1453: 1449: 1446: 1445: 1444: 1441: 1439: 1436: 1435: 1433: 1426: 1421: 1415: 1412: 1410: 1407: 1405: 1402: 1400: 1397: 1395: 1392: 1390: 1387: 1385: 1382: 1380: 1377: 1375: 1372: 1370: 1367: 1365: 1364:Lithium metal 1362: 1360: 1357: 1355: 1352: 1350: 1347: 1345: 1342: 1340: 1337: 1335: 1332: 1330: 1327: 1325: 1322: 1320: 1319:Aluminium–air 1317: 1315: 1312: 1311: 1309: 1302: 1297: 1292: 1282: 1279: 1277: 1274: 1272: 1269: 1265: 1262: 1260: 1257: 1256: 1255: 1252: 1250: 1247: 1245: 1244:Galvanic cell 1242: 1241: 1239: 1235: 1231: 1224: 1219: 1217: 1212: 1210: 1205: 1204: 1201: 1195: 1192: 1190: 1187: 1185: 1182: 1180: 1177: 1175: 1172: 1171: 1162: 1161:1-884989-20-9 1158: 1154: 1150: 1149: 1138: 1133: 1127: 1122: 1115: 1106: 1100: 1096: 1093: 1088: 1082: 1077: 1071: 1066: 1059: 1055: 1052: 1048: 1042: 1033: 1027: 1022: 1016: 1012: 1009: 1004: 990:on 2009-03-18 986: 979: 973: 967: 958: 952: 947: 941: 937: 934: 929: 923: 918: 912: 907: 901: 897: 894: 889: 883: 874: 868: 863: 849:on 2009-03-18 845: 838: 832: 826: 821: 815: 810: 796:on 2016-03-03 792: 785: 779: 773: 768: 766: 759: 755: 752: 747: 745: 738: 733: 731: 729: 721: 720:0-07-135978-8 717: 713: 707: 705: 703: 698: 688: 685: 683: 680: 678: 675: 673: 670: 668: 665: 663: 660: 658: 655: 653: 650: 649: 645: 644:Energy portal 639: 634: 631: 625: 620: 609: 604: 600: 595: 591: 586: 582: 577: 573: 568: 565: 564: 560: 557: 554: 550: 547: 545:than the IPV. 544: 536: 529: 528: 522: 520: 515: 513: 509: 506: 502: 499: 495: 491: 486: 483: 478: 460: 452: 420: 409: 388: 378: 375: 370: 359: 358: 357: 354: 350: 348: 341: 336: 327: 326: 322: 318: 314: 308: 298: 296: 288: 284: 280: 276: 272: 268: 264: 260: 256: 248: 246: 242: 238: 237:charge cycles 234: 229: 227: 224:is 1.55  223: 219: 215: 211: 207: 203: 199: 196:have shown a 195: 191: 182: 180: 176: 172: 168: 164: 160: 156: 152: 148: 144: 132: 122: 117: 113: 109: 105: 98: 96: 92: 88: 84: 78: 76: 72: 68: 64: 59: 57: 53: 46: 41: 33: 19: 1587:Zinc–bromine 1516: 1394:Silver oxide 1329:Chromic acid 1301:Primary cell 1281:Voltaic pile 1259:Flow battery 1152: 1132: 1121: 1105: 1087: 1076: 1065: 1047: 1032: 1021: 1003: 992:. 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Retrieved 791:the original 778: 711: 516: 487: 479: 476: 355: 351: 344: 310: 275:Mars Odyssey 263:space probes 249: 230: 198:service life 192:(KOH) as an 183: 130: 128: 1676:Salt bridge 1661:Electrolyte 1592:Zinc–cerium 1577:Solid state 1562:Silver–zinc 1537:Nickel–zinc 1522:Nickel–iron 1497:Molten salt 1465:Dual carbon 1460:Lithium ion 1455:Lithium–air 1414:Zinc–carbon 1389:Silicon–air 1369:Lithium–air 293:battery in 208:is 75  194:electrolyte 165:(82.7  119:>20,000 1696:Categories 1629:Cell parts 1620:Solar cell 1602:Other cell 1567:Sodium ion 1438:Automotive 994:2012-08-29 853:2008-10-25 800:2008-10-25 693:References 566:Schematics 553:electrodes 289:of any NiH 204:(DOD) The 1666:Half-cell 1656:Electrode 1615:Fuel cell 1492:Metal–air 1443:Lead–acid 1359:Leclanché 1271:Fuel cell 501:electrode 461:⋅ 428:⇀ 421:− 410:− 403:↽ 347:fuel cell 243:and 100% 239:with 85% 1646:Catalyst 1507:Nanowire 1502:Nanopore 1448:gel–VRLA 1409:Zinc–air 1314:Alkaline 1095:Archived 1054:Archived 1011:Archived 936:Archived 911:NASA.gov 896:Archived 754:Archived 616:See also 512:zirconia 508:catalyst 498:hydrogen 490:sintered 277:and the 155:hydrogen 147:hydrogen 101:220 W/kg 1651:Cathode 1404:Zamboni 1374:Mercury 1339:Daniell 1114:battery 525:Designs 301:History 137:or Ni–H 1641:Binder 1399:Weston 1324:Bunsen 1159:  718:  519:molded 340:Hubble 313:Comsat 143:nickel 121:cycles 61:55-75 1636:Anode 1354:Grove 1334:Clark 1237:Types 988:(PDF) 981:(PDF) 847:(PDF) 840:(PDF) 794:(PDF) 787:(PDF) 368:NiOOH 1671:Ions 1157:ISBN 878:Ni-H 716:ISBN 323:and 177:and 159:cell 145:and 133:(NiH 1344:Dry 962:NiH 267:ISS 250:NiH 184:NiH 167:bar 163:psi 110:85% 83:W·h 81:60 63:W·h 1698:: 764:^ 743:^ 727:^ 701:^ 445:OH 437:Ni 297:. 273:, 269:, 247:. 214:kg 210:Wh 173:, 129:A 67:kg 1222:e 1215:t 1208:v 1163:. 1116:. 1112:2 1060:. 1039:2 997:. 964:2 880:2 856:. 803:. 539:2 532:2 453:2 448:) 442:( 389:2 385:H 379:2 376:1 371:+ 291:2 252:2 226:V 212:/ 186:2 139:2 135:2 99:~ 87:L 85:/ 79:~ 65:/ 34:. 20:)

Index

Nickel hydrogen battery
Nickel–metal hydride battery

Specific energy
W·h
kg
Energy density
W·h
L
Specific power
cycles
nickel
hydrogen
nickel–metal hydride (NiMH) battery
hydrogen
cell
psi
bar
Alexandr Ilich Kloss
Vyacheslav Mikhailovic Sergeev
Boris Ioselevich Tsenter
potassium hydroxide
electrolyte
service life
depth of discharge
energy density
Wh
kg
specific power
open-circuit voltage

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