58:
89:
1285:
410:
266:
80:
46:
744:
749:
1660:
888:
2889:
1197:
2703:
891:
893:
1683:
of unspecified stereochemistry. Detailed speciation of aqueous solutions of ferric chloride is challenging because the individual components do not have distinctive spectroscopic signatures. Iron(III) complexes, with a high spin d configuration, is kinetically labile, which means that ligands rapidly
1849:
A number of variables apply to these processes, including the oxidation of iron by ferric chloride and the hydration of intermediates. Hydrates of iron(III) chloride do not readily yield anhydrous ferric chloride. Attempted thermal dehydration yields hydrochloric acid and
1760:
The reaction is conducted at several hundred degrees such that the product is gaseous. Using excess chlorine guarantees that the intermediate ferrous chloride is converted to the ferric state. A similar but laboratory-scale process also has been described.
1703:
of 10, which exhibit the property of "aging", i.e., the structure change or evolve over the course of days. The polymeric species formed by the hydrolysis of ferric chlorides are key to the use of ferric chloride for water treatment.
1946:
O ligands exchange rapidly with free chloride and water. In contrast to their kinetic lability, iron(III) chlorides are thermodynamically robust, as reflected by the vigorous methods applied to their synthesis, as described above.
1296:, owing to the presence of unpaired electrons residing in 3d orbitals. Although Fe(III) chloride can be octahedral or tetrahedral (or both, see structure section), all of these forms have five unpaired electrons, one per
2814:
because they are inexpensive, earth abundant, and relatively nontoxic. Many experiments probe both its redox activity and its Lewis acidity. For example, iron(III) chloride oxidizes naphthols to naphthoquinones:
2015:. These products have more complicated structures than anhydrous iron(III) chloride. In the solid phase a variety of multinuclear complexes have been described for the nominal stoichiometric reaction between
757:
2515:
as ether-soluble sources of ferric ion. These diketonate complexes have the advantages that they do not form hydrates, unlike iron(III) chloride, and they are more soluble in relevant solvents.
724:
1352:
compound is a hygroscopic crystalline solid with a melting point of 307.6 °C. The colour depends on the viewing angle: by reflected light, the crystals appear dark green, but by
892:
4485:
Riddell WA, Noller CR (1932). "Mixed
Catalysis in the Friedel and Crafts Reaction. The Yields in Typical Reactions using Ferric Chloride–Aluminum Chloride Mixtures as Catalysts".
6450:
6200:
2286:
Unlike the anhydrous material, hydrated ferric chloride is not a particularly strong Lewis acid since water ligands have quenched the Lewis acidity by binding to Fe(III).
4249:
Dueñas Díez M, Fjeld M, Andersen E, et al. (2006). "Validation of a compartmental population balance model of an industrial leaching process: The
Silgrain process".
2594:. By forming highly dispersed networks of Fe-O-Fe containing materials, ferric chlorides serve as coagulant and flocculants. In this application, an aqueous solution of
839:
894:
7127:
1332:, are nearly colorless, whereas the chloride solutions are yellow. Thus, the chloride ligands significantly influence the optical properties of the iron center.
902:
6729:
4122:
1312:. This double forbidden-ness results in its solutions being only pale colored. Or, stated more technically, the optical transitions are non-intense. Aqueous
1256:, these compounds are some of the most important and commonplace compounds of iron. They are available both in anhydrous and in hydrated forms which are both
831:
3127:
938:
4022:
1210:
3022:
An alternative GHS classification from the
Japanese GHS Inter-ministerial Committee (2006) notes the possibility of respiratory tract irritation from
1531:. These species differ with respect to the stereochemistry of the octahedral iron cation, the identity of the anions, and the presence or absence of
2329:. The affinity of iron(III) for oxygen ligands was the basis of qualitative tests for phenols. Although superseded by spectroscopic methods, the
916:
3897:
James A. King, Alan B. Storrow, Jeff A. Finkelstein (1995). "Urine
Trinder Spot Test: A Rapid Salicylate Screen for the Emergency Department".
1958:
Aside from lability, which applies to anhydrous and hydrated forms, the reactivity of anhydrous ferric chloride reveals two trends: It is a
466:
3596:
Boudjouk P, So JH, Ackermann MN, et al. (1992). "Solvated and
Unsolvated Anhydrous Metal Chlorides from Metal Chloride Hydrates".
5789:
5043:
835:
2990:, so they pose few problems as poisons, at low concentrations. Nonetheless, anhydrous iron(III) chloride, as well as concentrated
1205:
5596:
3863:
5579:
2275:
To suppress this reaction, the preparation of iron(III) chloride requires an excess of chlorinating agent, as discussed above.
5190:
4937:
4404:
4222:
Park KH, Mohapatra D, Reddy BR (2006). "A study on the acidified ferric chloride leaching of a complex (Cu–Ni–Co–Fe) matte".
3374:
3255:
3093:
3062:
2408:. The isolation of organoiron(III) intermediates requires low-temperature reactions, lest the intermediates degrade. Using
57:
5133:
3935:
Mako TL, Byers JA (2016). "Recent
Advances in Iron-Catalysed Cross Coupling Reactions and Their Mechanistic Underpinning".
2635:
and thus precipitates as a solid. One potential advantage to its use in water treatment, ferric ion oxidizes (deodorizes)
6135:
4099:
2787:
1767:
solutions of iron(III) chloride are also produced industrially from a number of iron precursors, including iron oxides:
537:
Green-black by reflected light; purple-red by transmitted light; yellow solid as hexahydrate; brown as aqueous solution
4167:
3212:
2516:
971:
4539:
So RC, Carreon-Asok AC (2019). "Molecular Design, Synthetic
Strategies, and Applications of Cationic Polythiophenes".
1340:
Iron(III) chloride can exist as an anhydrous material and a series of hydrates, which results in distinct structures.
5012:
4993:
4974:
4946:
4445:
3881:
3846:
3778:
3722:
3645:
3613:
3580:
3527:
3106:
3075:
743:
424:
4135:
3141:
1217:
7845:
7840:
4745:
1684:
dissociate and reassociate. A further complication is that these solutions are strongly acidic, as expected for
1438:, meaning that they become liquid by absorbing moisture from the air. Hydration invariably gives derivatives of
1376:
Iron(III) chloride has a relatively low melting point and boils at around 315 °C. The vapor consists of the
17:
5776:
5624:
4714:
4681:
4648:
3749:
3687:
3349:
4428:
Dreher EL, Beutel KK, Myers JD, Lübbe T, Krieger S, Pottenger LH (2014). "Chloroethanes and
Chloroethylenes".
3703:
Kikkawa S, Kanamaru F, Koizumi M, et al. (1984). "Layered
Intercalation Compounds". In Holt SL Jr (ed.).
5962:
5078:
1476:
823:
7830:
5066:
5036:
4251:
3332:
Wildermuth E, Stark H, Friedrich G, Ebenhöch FL, Kühborth B, Silver J, Rituper R (2000). "Iron
Compounds".
1854:. In the laboratory, hydrated iron(III) chloride can be converted to the anhydrous form by treatment with
793:
332:
261:
3964:"Synthesis and Characterization of a Sterically Encumbered Homoleptic Tetraalkyliron(III) Ferrate Complex"
2176:
In terms of its being an oxidant, iron(III) chloride oxidizes iron powder to form iron(II) chloride via a
7850:
5640:
5540:
4897:
2957:
2123:
1739:
Several hundred tons of anhydrous iron(III) chloride are produced annually. The principal method, called
388:
863:
819:
7493:
6480:
5930:
5408:
5252:
4895:
Krasnopolsky VA (2006). "Chemical composition of Venus atmosphere and clouds: Some unsolved problems".
1288:
Anhydrous iron(III) chloride evaporates at relatively low temperatures to give the bitetrahedral dimer.
949:
203:
3802:
Cook CM Jr, Dunn WE Jr (1961). "The Reaction of Ferric Chloride with Sodium and Potassium Chlorides".
2651:
agent in chloride hydrometallurgy, for example in the production of Si from FeSi (Silgrain process by
7774:
7750:
7659:
6113:
5793:
5334:
2508:
1935:
1707:
In contrast to the complicated behavior of its aqueous solutions, solutions of iron(III) chloride in
1301:
273:
7395:
4362:
7767:
7666:
7577:
7554:
7516:
6892:
6885:
6498:
4312:
2570:
2386:
2069:
1532:
1088:
748:
405:
4730:
Mallory, Sheehan, Hrapchak (1990). "Verhoeff's Elastic Stain". In Carson F, Cappellano CH (eds.).
4160:
1977:. Myriad manifestations of the oxophiliicty of iron(III) chloride are available. When heated with
7855:
7742:
7726:
7711:
7703:
7623:
7570:
7508:
7477:
7047:
7029:
6943:
6936:
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6878:
6841:
6748:
6663:
6128:
5982:
5806:
5029:
4286:
3167:
2409:
2405:
2373:
This fundamental reaction is relevant to the use of ferric chloride solutions in etching copper.
1859:
1040:
689:
4335:
2956:
and is thought to have a range of cooling effects; thus, it has been proposed as a catalyst for
88:
7835:
7757:
7719:
7636:
7616:
7546:
7531:
7501:
7353:
7149:
7120:
7104:
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6914:
6899:
6848:
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6793:
6656:
6641:
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6612:
6597:
6590:
6491:
6438:
6412:
6189:
5121:
2688:
1030:
7411:
2952:
from sea salt. This iron salt aerosol causes about 1-5% of naturally-occurring oxidization of
7688:
7681:
7674:
7644:
7608:
7585:
7562:
7524:
7361:
7265:
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7250:
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7170:
7156:
7142:
7112:
6951:
6856:
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6763:
6648:
6634:
6605:
6583:
6472:
6401:
6218:
4813:"Climate engineering by mimicking natural dust climate control: the iron salt aerosol method"
3766:
3637:
2843:
2791:
2344:
Aqueous iron(III) chloride serves as a one-electron oxidant illustrated by its reaction with
1667:
Like the solid hydrates, aqueous solutions of ferric chloride also consist of the octahedral
1480:
1173:
771:
736:
107:
4910:
4731:
4582:
Albright H, Davis AJ, Gomez-Lopez JL, Vonesh HL, Quach PK, Lambert TH, Schindler CS (2021).
3463:"Alkoxo-Verbindungen des dreiwertigen Eisen: Synthese und Charakterisierung von [Fe2(Ot
3180:
7734:
7695:
7651:
7601:
7593:
7485:
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7311:
7303:
7277:
7236:
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7199:
7185:
7163:
7134:
7040:
7014:
6991:
6863:
6801:
6741:
6693:
6626:
6528:
6405:
6378:
6356:
6289:
6270:
5704:
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5182:
4906:
4861:
4824:
4259:
4060:
3873:
3403:
3220:
2905:
2901:
2839:
2648:
2330:
356:
348:
341:
243:
178:
170:
162:
2658:
In another commercial application, a solution of iron(III) chloride is useful for etching
827:
155:
8:
7539:
7346:
7292:
7221:
7207:
7078:
7055:
6984:
6870:
6786:
6756:
6733:
6713:
6701:
6686:
6561:
6510:
6367:
6326:
6248:
5798:
5109:
4020:
bei der Umsetzung von Eisen(III)-chlorid mit Lithiummethyl (1:1) in ätherischer Lösung".
3705:
3163:
3003:
2909:
2882:
2761:
2684:
2628:
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2349:
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1357:
1035:
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145:
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4865:
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4263:
4064:
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3224:
409:
265:
223:
7825:
7284:
7228:
7067:
7059:
6980:
6816:
6709:
6556:
6505:
6461:
6442:
6430:
6389:
6281:
6181:
6121:
6050:
5874:
5826:
5751:
5692:
5524:
5448:
5432:
5384:
5313:
5101:
4877:
4852:
Krasnopolsky VA, Parshev VA (1981). "Chemical composition of the atmosphere of Venus".
4608:
4583:
4564:
4410:
4204:
4076:
3988:
3963:
3510:
Tarr BR, Booth HS, Dolance A (1950). "Anhydrous Iron(III) Chloride (Ferric Chloride)".
3295:
2823:
upon treatment with ferric chloride. Iron(III) chloride has been shown to promote C-C
2795:
2773:
2727:
2431:
2345:
2177:
2127:
1640:
1411:
1391:
1284:
1066:
999:
4183:"Ferric chloride for odour control: studies from wastewater treatment plants in India"
4108:
3910:
2687:
is rinsed away, leaving a copper pattern. This chemistry is used in the production of
2620:). This floc facilitates the separation of suspended materials, clarifying the water.
79:
7371:
7330:
7323:
6811:
6770:
6671:
6575:
6521:
6345:
6334:
6307:
6237:
6211:
6160:
6071:
5902:
5890:
5764:
5735:
5671:
5440:
5420:
5364:
5359:
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5008:
4989:
4970:
4942:
4710:
4677:
4644:
4613:
4568:
4556:
4441:
4414:
4400:
4208:
3993:
3914:
3877:
3842:
3784:
3774:
3745:
3738:
Turova NY, Turevskaya EP, Kessler VG, et al., eds. (2002). "12.22.1 Synthesis".
3718:
3683:
3641:
3609:
3576:
3563:
Pray AR, Heitmiller RF, Strycker S, et al. (1990). "Anhydrous Metal Chlorides".
3523:
3370:
3345:
3299:
3251:
3102:
3071:
2949:
2824:
2807:
2338:
2169:
reactions, the Lewis acidity of ferric chloride enables its use in a variety of acid-
1801:
1699:
derivatives. Dilute solutions of ferric chloride produce soluble nanoparticles with
1415:
1377:
1353:
1082:
1025:
1004:
965:
548:
5007:. Handbook of Reagents for Organic Synthesis. New York: John Wiley & Sons, Inc.
4012:
Berthold HJ, Spiegl HJ (1972). "Über die Bildung von Lithiumtetrachloroferrat(II) Li
2389:
has been examined often. These studies are enabled because of the solubility of FeCl
7338:
7273:
7088:
7071:
7006:
6999:
6972:
6565:
6535:
6349:
6303:
6277:
6259:
6176:
5784:
5727:
5508:
5488:
5468:
5456:
5372:
5326:
5321:
5292:
5244:
4988:. Oxford science publications (5th ed.). Oxford, UK: Oxford University Press.
4914:
4881:
4869:
4832:
4702:
4669:
4636:
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4548:
4521:
4494:
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4267:
4231:
4194:
4104:
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4051:
4031:
3983:
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3944:
3906:
3834:
3811:
3710:
3675:
3601:
3568:
3515:
3490:
3440:
3411:
3337:
3287:
3228:
2831:
2636:
2587:
2397:
2251:
2250:
iron(III) chloride releases chlorine gas when heated above 160 °C, generating
2198:
1982:
1855:
1851:
1700:
1459:
1414:) at higher temperatures, in competition with its reversible decomposition to give
1273:
1116:
1061:
843:
614:
489:
7790:
4437:
3679:
3291:
2569:
This conversion, although not of practical value, was important in the history of
2289:
Like the anhydrous material, hydrated ferric chloride is oxophilic. For example,
305:
7376:
7093:
6967:
6425:
6229:
6002:
5918:
5862:
5400:
5300:
5172:
4235:
3739:
2987:
2591:
2202:
2023:
1978:
1712:
1468:
1269:
1261:
811:
7387:
4812:
4599:
4552:
4461:
6315:
6296:
6083:
5842:
5759:
5676:
5308:
5052:
3979:
3896:
3838:
3714:
3605:
3572:
3519:
2866:
2862:
2765:
2421:
2166:
2012:
1408:
1317:
1313:
1305:
1188:
1092:
45:
4918:
4396:
4271:
3232:
3123:
803:
7819:
6721:
4706:
4673:
4640:
4525:
4035:
3788:
3341:
3278:
Simon A. Cotton (2018). "Iron(III) Chloride and Its Coordination Chemistry".
2975:
2847:
2820:
2694:
Iron(III) chloride is used in many other hobbies involving metallic objects.
2382:
2322:
2209:
1708:
1435:
655:
594:
582:
254:
7798:
7782:
5224:
4617:
4560:
4094:
3997:
3495:
3462:
2855:
2617:
2602:
2394:
2334:
2310:
1685:
1439:
1434:
upon exposure to water, reflecting its Lewis acidity. All hydrates exhibit
1309:
1293:
1156:
1052:
711:
4967:
Complexes and First-Row Transition Elements, Macmillan Press, London, 1973
3918:
2718:
In industry, iron(III) chloride is used as a catalyst for the reaction of
1969:
Reactions of anhydrous iron(III) chloride reflect its description as both
915:
6396:
4837:
4785:
4199:
4182:
3029:
and differs slightly in other respects from the classification used here.
2318:
2314:
2290:
1974:
1696:
1257:
1100:
928:
855:
847:
4498:
3815:
3444:
3206:
Hashimoto S, Forster K, Moss SC (1989). "Structure refinement of an FeCl
2393:
in ethereal solvents, which avoids the possibility of hydrolysis of the
1304:
d electronic configuration requires that d-d electronic transitions are
901:
799:
6102:
4759:
4131:
3948:
2835:
2780:
2420:] have been isolated. Illustrating the sensitivity of these reactions,
2065:
1959:
1659:
1366:
1265:
1179:
908:
633:
506:
274:
234:
6143:
4072:
3416:
3391:
851:
5563:
4873:
3098:
3067:
2948:-based aerosol are produced by a reaction between iron-rich dust and
2816:
2632:
2624:
2520:
2170:
1970:
1693:
1395:
1349:
1297:
785:
705:
368:
2511:
and related beta-diketonate complexes are more widely used than FeCl
1187:
Except where otherwise noted, data are given for materials in their
6543:
6145:
2995:
2936:
2784:
2723:
2719:
2519:
undergoes a complex reaction with iron(III) chloride, resulting in
2008:
1419:
1237:
874:
645:
4049:
Kealy TJ, Pauson PL (1951). "A New Type of Organo-Iron Compound".
3121:
2173:
reactions as described below in the section on organic chemistry.
867:
202:
5021:
3869:
3737:
3562:
2953:
2932:
2888:
2851:
2846:
reactions. A similar reagent but moistened induces hydrolysis or
2811:
2769:
1689:
1431:
909:
807:
650:
640:
555:
292:
3962:
Sears JD, Muñoz SB, Cuenca MC, Brennessel WW, Neidig ML (2019).
3331:
2337:
test. The affinity of iron(III) for phenols is exploited in the
2878:
2874:
2870:
2659:
2061:
1939:
1720:
1639:. The first three members of this series have the tetrahedral
1472:
1370:
1356:, they appear purple-red. Anhydrous iron(III) chloride has the
815:
605:
280 °C (536 °F; 553 K) (hexahydrate, decomposes)
4811:
Oeste FD, de Richter R, Ming T, Caillol S (January 13, 2017).
4581:
3861:
2964:
2652:
1963:
1716:
1268:, while all forms are mild oxidizing agents. It is used as a
602:
316 °C (601 °F; 589 K) (anhydrous, decomposes)
316:
214:
192:
3764:
3709:. Vol. 22. John Wiley & Sons, Inc. pp. 86–89.
3431:
Flynn CM (1984). "Hydrolysis of Inorganic Iron(III) Salts".
2900:
Iron(III) chloride is a component of useful stains, such as
2293:
salts react rapidly with aqueous iron(III) chloride to give
393:
4363:"Buffalo Nickel No Date Value: How Much Is It Worth Today?"
4248:
2992:
1234:
542:
4810:
3961:
3828:
3702:
3548:
H. Lux (1963). "Iron (III) Chloride". In G. Brauer (ed.).
2806:
Although iron(III) chlorides are seldom used in practical
1688:
of a tricationic metal. Iron aquo complexes are prone to
1369:
Fe(III) centres interconnected by two-coordinate chloride
3765:
Bradley DC, Mehrotra RC, Rothwell I, et al. (2001).
3595:
3006:, and must be handled using proper protective equipment.
2702:
1016:
990:
5955:
3862:
Furniss BS, Hannaford AJ, Smith PW, et al. (1989).
3829:
P. Kovacic and N. O. Brace (1960). "Iron(II) Chloride".
2764:, which is mainly used for the industrial production of
1149:α = 90°, β = 90°, γ = 120°
777:
5556:
4969:. A Macmillan chemistry text. London: Macmillan Press.
4960:(7th ed.). Rahway, New Jersey, US: Merck & Co.
2400:. Such studies may be relevant to the mechanism of FeCl
587:
307.6 °C (585.7 °F; 580.8 K) (anhydrous)
5181:
4729:
4697:
White AD (2001). "Iron(III) Chloride-Sodium Hydride".
4427:
2927:
naturally occurs as a trace mineral. The rare mineral
1800:
In complementary route, iron metal can be oxidized by
4955:
4941:(71st ed.). Ann Arbor, Michigan, US: CRC Press.
4333:
3460:
3146:, New Zealand Environmental Risk Management Authority
3128:
National Institute for Occupational Safety and Health
2381:
The interaction of anhydrous iron(III) chloride with
4310:
3552:. Vol. 2. NY, NY: Academic Press. p. 1492.
3205:
2908:
with many applications. Also, it is used to prepare
2586:
In the largest application iron(III) chloride is in
1479:
Fe center. Four hydrates have been characterized by
1279:
4851:
4311:Harris P, Hartman R, Hartman J (November 1, 2002).
3550:
Handbook of Preparative Inorganic Chemistry, 2nd Ed
2794:. In this role, its function is similar to that of
1938:d electronic configuration iron(III) chlorides are
1731:. In these complexes, the iron is pentacoordinate.
1471:, reflecting the relative location of the chloride
1232:describes the inorganic compounds with the formula
4631:White AD (2001). "Iron(III) Chloride-Silica Gel".
4221:
3483:Zeitschrift für anorganische und allgemeine Chemie
3392:"Crystal Structure of Ferric Chloride Hexahydrate"
2623:Iron(III) chloride is also used to remove soluble
781:
589:37 °C (99 °F; 310 K) (hexahydrate)
4956:Stecher PG, Finkel MJ, Siegmund OH, eds. (1960).
4180:
3670:White AD, Gallou F (2006). "Iron(III) Chloride".
3631:
3143:HSNO Chemical Classification Information Database
2838:, the anhydrous salt has been applied to certain
7817:
3509:
3245:
3185:, Japanese GHS Inter-ministerial Committee, 2006
304:
4664:White AD (2001). "Iron(III) Chloride-Alumina".
4511:
4360:
4161:"Phosphorus Treatment and Removal Technologies"
3865:Vogel's Textbook of Practical Organic Chemistry
3277:
3166:, collated by the Baylor College of Dentistry,
2854:, ferric chloride has been shown to accelerate
2810:, they have received considerable attention as
2798:. In some cases, mixtures of the two are used.
2430:reacts with iron(III) chloride to give lithium
1663:A brown, acidic solution of iron(III) chloride.
890:
177:
169:
161:
154:
4699:Encyclopedia of Reagents for Organic Synthesis
4666:Encyclopedia of Reagents for Organic Synthesis
4633:Encyclopedia of Reagents for Organic Synthesis
4538:
4512:Louis F. Fieser (1937). "1,2-Naphthoquinone".
4430:Ullmann's Encyclopedia of Industrial Chemistry
4336:"A message about mirror coating and recoating"
4011:
3672:Encyclopedia of Reagents for Organic Synthesis
3365:Holleman AF, Wiberg E (2001). Wiberg N (ed.).
3364:
3334:Ullmann's Encyclopedia of Industrial Chemistry
2830:Several reagents have been developed based on
859:
6129:
5037:
4484:
4284:
2967:are hypothesized to contain approximately 1%
2801:
2642:
2119:, has been crystallized from ether solution.
4894:
4387:Scott D, Schwab R (2019). "3.1.4. Etching".
3627:
3625:
3327:
3325:
3323:
3321:
3319:
3317:
3315:
3313:
3311:
3309:
3250:(4th ed.). Prentice Hall. p. 747.
2573:where ferrocene is emblematic of the field.
4733:Histotechnology – A Self-Instructional Text
4386:
4115:
4048:
3669:
2986:Iron(III) chlorides are widely used in the
2376:
6136:
6122:
5044:
5030:
5002:
4087:
2714:. Color code: Cl=green,Fe = blue, O = red.
408:
264:
242:
4836:
4607:
4198:
3987:
3934:
3773:. San Diego: Academic Press. p. 69.
3622:
3543:
3541:
3539:
3494:
3415:
3306:
3273:
3271:
3269:
3267:
355:
347:
340:
4964:
3930:
3928:
3801:
3771:Alkoxo and aryloxo derivatives of metals
3461:Spandl J, Kusserow M, Brüdgam I (2003).
3122:NIOSH Pocket Guide to Chemical Hazards.
2701:
1658:
1283:
4845:
4790:International Mineralogical Association
4744:– via The Visible Mouse Project,
4723:
4462:"Toxic Substances – 1,2-Dichloroethane"
4391:. Cultural Heritage Science. Springer.
3665:
3663:
3661:
3659:
3657:
3456:
3454:
2412:as the alkylation agent, salts of Fe(CH
404:
14:
7818:
6166:
6144:Salts and covalent derivatives of the
4958:The Merck Index of Chemicals and Drugs
4224:Separation and Purification Technology
4097:(2001). "Ferrocene—how it all began".
4093:
3767:"3.2.10. Alkoxides of later 3d metals"
3547:
3536:
3264:
3090:
3059:
255:
7466:
6117:
5025:
4983:
4938:CRC Handbook of Chemistry and Physics
4696:
4663:
4630:
3925:
3430:
3201:
3199:
3094:CRC Handbook of Chemistry and Physics
3063:CRC Handbook of Chemistry and Physics
3055:
3053:
3051:
3049:
3047:
3045:
2915:
2865:, iron(III) chloride gives a hydride
2662:according to the following equation:
2197:A traditional synthesis of anhydrous
453:Key: RBTARNINKXHZNM-UHFFFAOYSA-K
436:Key: RBTARNINKXHZNM-UHFFFAOYSA-K
222:
4934:
4389:Metallography in Archaeology and Art
4361:CoinValueLookup (13 December 2023).
3654:
3451:
3389:
3210:crystal using a thin plate sample".
2697:
2122:Iron(III) chloride also reacts with
4778:
4100:Journal of Organometallic Chemistry
2788:electrophilic aromatic substitution
1394:. This dimer dissociates into the
446:Key: RBTARNINKXHZNM-DFZHHIFOAF
295:
24:
5051:
4928:
4168:Minnesota Pollution Control Agency
3600:. Vol. 29. pp. 108–111.
3567:. Vol. 28. pp. 321–323.
3196:
3042:
2887:
2581:
2517:Cyclopentadienyl magnesium bromide
1950:
1743:, uses scrap iron as a precursor:
886:
443:InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
433:InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
87:
78:
56:
44:
25:
7867:
5003:Reich HJ, Rigby HJ, eds. (1999).
4181:Prathna TC, Srivastava A (2021).
3833:. Vol. 6. pp. 172–173.
3744:. Springer Science. p. 481.
3632:Greenwood NN, Earnshaw A (1997).
3514:. Vol. 3. pp. 191–194.
3479:)4]2[Fe6OCl6(OMe)12]"
3280:Journal of Coordination Chemistry
3246:Housecroft CE, Sharpe AG (2012).
3097:(92nd ed.). Boca Raton, FL:
3066:(92nd ed.). Boca Raton, FL:
2278:
1981:at 350 °C it reacts to give
1292:All forms of ferric chloride are
1280:Electronic and optical properties
624:g/L (anhydrous or hexahydrate, 25
3741:The Chemistry of Metal Alkoxides
3182:GHS classification – ID 831
1264:. The anhydrous derivative is a
1195:
747:
742:
4888:
4841:– via esd.copernicus.org.
4804:
4752:
4690:
4657:
4624:
4575:
4532:
4505:
4478:
4454:
4421:
4380:
4354:
4327:
4304:
4278:
4242:
4215:
4174:
4153:
4042:
4005:
3955:
3890:
3855:
3822:
3795:
3758:
3731:
3696:
3589:
3556:
3503:
3424:
3396:The Journal of Chemical Physics
3383:
3358:
2726:, forming ethylene dichloride (
2616:), also formulated as FeO(OH) (
2601:is treated with base to form a
2126:to give the yellow salt of the
2060:Iron(III) chloride forms a 1:2
1458:. This cation can adopt either
1308:, in addition to violating the
1191:(at 25 °C , 100 kPa).
4986:Structural Inorganic Chemistry
3239:
3173:
3157:
3134:
3115:
3084:
3016:
1734:
1535:. The structural formulas are
1519:, and finally the hexahydrate
1260:. They feature iron in its +3
52:Iron(III) chloride (anhydrous)
13:
1:
4438:10.1002/14356007.o06_o01.pub2
4334:Mike Lockwood, Carl Zambuto.
4187:Water Practice and Technology
4109:10.1016/S0022-328X(01)01126-3
3937:Inorganic Chemistry Frontiers
3911:10.1016/S0196-0644(95)70082-X
3680:10.1002/047084289X.ri054.pub2
3369:. San Diego: Academic Press.
3292:10.1080/00958972.2018.1519188
3036:
943:(US health exposure limits):
4584:"Carbonyl–Olefin Metathesis"
4287:"Safer Printmaking—Intaglio"
4236:10.1016/j.seppur.2006.02.013
3899:Annals of Emergency Medicine
3002:aqueous solution, is highly
2895:
2165:In addition to these simple
2142:). Similarly, combining FeCl
2011:react to give the iron(III)
1942:, meaning that its Cl- and H
1929:
1343:
1335:
64:Iron(III) chloride (hydrate)
7:
4898:Planetary and Space Science
4600:10.1021/acs.chemrev.0c01096
4553:10.1021/acs.chemrev.8b00773
4340:Lockwood Custom Optics, Inc
2988:treatment of drinking water
2958:Atmospheric Methane Removal
2931:is usually associated with
2124:tetraethylammonium chloride
1804:followed by chlorination:
1723:of the general formula FeCl
1654:
1425:
74:
40:
10:
7872:
7468:
4291:University of Saskatchewan
3980:10.1016/j.poly.2018.10.041
3868:(5th ed.). New York:
3839:10.1002/9780470132371.ch54
3715:10.1002/9780470132531.ch17
3606:10.1002/9780470132609.ch26
3573:10.1002/9780470132593.ch80
3520:10.1002/9780470132340.ch51
2844:pinacol-type rearrangement
2802:Organic synthesis research
2643:Etching and metal cleaning
2095:. The related 1:2 complex
6168:
6153:
6095:
6064:
6043:
5956:Organoiron(III) compounds
5720:
5685:
5664:
5237:
5217:
5165:
5094:
5059:
5005:Acidic and Basic Reagents
4919:10.1016/j.pss.2006.04.019
4397:10.1007/978-3-030-11265-3
4313:"Etching Iron Meteorites"
4272:10.1016/j.ces.2005.01.047
4132:Akzo Nobel Base Chemicals
4124:Water Treatment Chemicals
3634:Chemistry of the Elements
3233:10.1107/S0021889888013913
2981:
2920:Like many metal halides,
2779:Illustrating it use as a
2760:Ethylene dichloride is a
2592:drinking water production
2509:iron(III) acetylacetonate
2507:To a significant extent,
2387:organomagnesium compounds
1185:
1075:
982:
937:
723:
718:
671:630 g/L (18 °C)
482:
462:
420:
138:
118:
106:
101:
73:
39:
5557:Organoiron(II) compounds
4707:10.1002/047084289X.ri060
4674:10.1002/047084289X.ri057
4641:10.1002/047084289X.ri059
4526:10.15227/orgsyn.017.0068
4342:. Lockwood Custom Optics
4036:10.1002/zaac.19723910302
3636:(2nd ed.). Oxford:
3471:)4], [Fe2Cl4(Ot
3467:)6], [Fe2Cl2(Ot
3342:10.1002/14356007.a14_591
3168:Texas A&M University
3009:
2834:iron(III) chloride. On
2571:organometallic chemistry
2406:cross-coupling reactions
2377:Organometallic chemistry
2146:with NaCl and KCl gives
2070:triphenylphosphine oxide
1533:water of crystallization
794:Precautionary statements
4911:2006P&SS...54.1352K
4002:and references therein.
3170:. (accessed 2010-09-19)
3091:Haynes WM, ed. (2011).
3060:Haynes WM, ed. (2011).
2576:
2410:methylmagnesium bromide
2352:and iron(II) chloride.
2325:, bind as well to give
1860:trimethylsilyl chloride
1715:are well-behaved. Both
1507:, the trisesquihydrate
1495:, the disesquihydrate
1041:Ruthenium(III) chloride
690:Magnetic susceptibility
379:2582 (aqueous solution)
7846:Deliquescent materials
7841:Coordination complexes
4786:"IMA list of Minerals"
4134:. 2007. Archived from
3496:10.1002/zaac.200300008
2892:
2715:
2689:printed circuit boards
1664:
1289:
1067:Polyaluminium chloride
1031:Manganese(II) chloride
897:
92:
83:
61:
49:
4935:Lide DR, ed. (1990).
4817:Earth System Dynamics
4736:. Chicago: ASCP Press
4023:Z. Anorg. Allg. Chem.
3638:Butterworth-Heinemann
3475:)2] und [N(n
3213:J. Appl. Crystallogr.
2906:histological fixative
2891:
2861:When pretreated with
2783:, iron(III) chloride
2705:
2647:It is also used as a
2327:carboxylate complexes
1662:
1481:X-ray crystallography
1430:Ferric chloride form
1287:
1174:Coordination geometry
896:
91:
82:
60:
48:
6103:Hemolithin (protein)
4905:(13–14): 1352–1359.
4838:10.5194/esd-8-1-2017
4200:10.2166/wpt.2020.111
2331:ferric chloride test
2201:is the reduction of
1809:Fe + 2 HCl → FeCl
879:(fire diamond)
714:(40% solution)
7831:Iron(III) compounds
4965:Nicholls D (1974).
4866:1981Natur.292..610K
4829:2017ESD.....8....1O
4547:(21): 11442–11509.
4499:10.1021/ja01340a043
4285:John David Graham.
4264:2006ChEnS..61..229D
4065:1951Natur.168.1039K
3831:Inorganic Syntheses
3816:10.1021/j100905a008
3706:Inorganic Syntheses
3598:Inorganic Syntheses
3565:Inorganic Syntheses
3512:Inorganic Syntheses
3445:10.1021/cr00059a003
3408:1967JChPh..47..990L
3367:Inorganic Chemistry
3248:Inorganic Chemistry
3225:1989JApCr..22..173H
2819:are polymerized to
2685:copper(II) chloride
2629:Iron(III) phosphate
2607:iron(III) hydroxide
2350:copper(II) chloride
1741:direct chlorination
1692:, the formation of
1134: = 0.6065
1126: = 0.6065
1036:Cobalt(II) chloride
615:Solubility in water
525:g/mol (hexahydrate)
352: (hexahydrate)
166: (hexahydrate)
36:
35:Iron(III) chloride
7851:Dehydrating agents
3949:10.1039/C5QI00295H
2916:Natural occurrence
2893:
2796:aluminium chloride
2762:commodity chemical
2728:1,2-dichloroethane
2716:
2671:+ Cu → 2 FeCl
2432:tetrachloroferrate
2346:copper(I) chloride
2178:comproportionation
2128:tetrachloroferrate
2013:alkoxide complexes
1665:
1641:tetrachloroferrate
1412:molecular symmetry
1392:aluminium chloride
1290:
1230:Iron(III) chloride
1218:Infobox references
1142: = 1.742
1000:Iron(III) fluoride
983:Related compounds
898:
574:g/cm (hexahydrate)
182: (3.5hydrate)
111:Iron(III) chloride
93:
84:
62:
50:
34:
29:Inorganic compound
7813:
7812:
7807:
7806:
6111:
6110:
6039:
6038:
5660:
5659:
5213:
5212:
4984:Wells AF (1984).
4860:(5824): 610–613.
4594:(15): 9359–9406.
4514:Organic Syntheses
4432:. pp. 1–81.
4406:978-3-030-11265-3
4315:. Meteorite Times
4141:on 13 August 2010
4073:10.1038/1681039b0
3417:10.1063/1.1712067
3376:978-0-12-352651-9
3286:(21): 3415–3443.
3257:978-0-273-74275-3
3164:Various suppliers
3101:. p. 4.133.
2950:hydrochloric acid
2902:Carnoy's solution
2825:coupling reaction
2808:organic synthesis
2706:Structure of FeCl
2698:Organic chemistry
2627:from wastewater.
2398:alkylating agents
2339:Trinder spot test
2333:is a traditional
1802:hydrochloric acid
1442:with the formula
1416:iron(II) chloride
1354:transmitted light
1226:Chemical compound
1224:
1223:
1083:Crystal structure
1026:Iron(II) chloride
1005:Iron(III) bromide
966:Safety data sheet
772:Hazard statements
518:g/mol (anhydrous)
389:CompTox Dashboard
360: (dihydrate)
204:Interactive image
174: (dihydrate)
97:
96:
69:
68:
16:(Redirected from
7863:
7763:
6157:
6156:
6138:
6131:
6124:
6115:
6114:
6056:
6031:
6030:
6029:
6021:
6020:
6012:
6011:
5953:
5952:
5554:
5553:
5179:
5178:
5046:
5039:
5032:
5023:
5022:
5018:
4999:
4980:
4961:
4952:
4923:
4922:
4892:
4886:
4885:
4874:10.1038/292610a0
4849:
4843:
4842:
4840:
4808:
4802:
4801:
4799:
4797:
4782:
4776:
4775:
4773:
4771:
4756:
4750:
4749:
4743:
4741:
4727:
4721:
4720:
4694:
4688:
4687:
4661:
4655:
4654:
4628:
4622:
4621:
4611:
4588:Chemical Reviews
4579:
4573:
4572:
4541:Chemical Reviews
4536:
4530:
4529:
4509:
4503:
4502:
4487:J. Am. Chem. Soc
4482:
4476:
4475:
4473:
4472:
4458:
4452:
4451:
4425:
4419:
4418:
4384:
4378:
4377:
4375:
4373:
4358:
4352:
4351:
4349:
4347:
4331:
4325:
4324:
4322:
4320:
4308:
4302:
4301:
4299:
4297:
4282:
4276:
4275:
4246:
4240:
4239:
4219:
4213:
4212:
4202:
4178:
4172:
4171:
4165:
4157:
4151:
4150:
4148:
4146:
4140:
4129:
4119:
4113:
4112:
4103:. 637–639: 3–6.
4091:
4085:
4084:
4046:
4040:
4039:
4009:
4003:
4001:
3991:
3959:
3953:
3952:
3932:
3923:
3922:
3894:
3888:
3887:
3859:
3853:
3852:
3826:
3820:
3819:
3810:(9): 1505–1511.
3799:
3793:
3792:
3762:
3756:
3755:
3735:
3729:
3728:
3700:
3694:
3693:
3667:
3652:
3651:
3640:. p. 1084.
3629:
3620:
3619:
3593:
3587:
3586:
3560:
3554:
3553:
3545:
3534:
3533:
3507:
3501:
3500:
3498:
3458:
3449:
3448:
3433:Chemical Reviews
3428:
3422:
3421:
3419:
3390:Lind MD (1967).
3387:
3381:
3380:
3362:
3356:
3355:
3329:
3304:
3303:
3275:
3262:
3261:
3243:
3237:
3236:
3203:
3194:
3193:
3192:
3190:
3177:
3171:
3161:
3155:
3154:
3153:
3151:
3138:
3132:
3131:
3119:
3113:
3112:
3088:
3082:
3081:
3070:. p. 4.69.
3057:
3030:
3028:
3020:
3001:
2973:
2947:
2926:
2910:Verhoeff's stain
2885:, respectively.
2756:
2679:
2637:hydrogen sulfide
2615:
2600:
2588:sewage treatment
2565:
2503:
2475:
2445:
2429:
2369:
2308:
2271:
2252:ferrous chloride
2246:
2199:ferrous chloride
2193:
2162:, respectively.
2161:
2153:
2141:
2118:
2094:
2056:
2021:
2003:
1983:iron oxychloride
1925:
1900:
1856:thionyl chloride
1852:iron oxychloride
1845:
1817:
1796:
1756:
1701:molecular weight
1682:
1650:
1638:
1614:
1586:
1558:
1530:
1518:
1506:
1494:
1483:: the dihydrate
1457:
1403:
1389:
1365:structure, with
1363:
1331:
1320:, which contain
1243:
1208:
1202:
1199:
1198:
1145:
1137:
1129:
1117:Lattice constant
1109:
1062:Iron(II) sulfate
978:
959:
918:
911:
904:
889:
869:
865:
861:
857:
853:
849:
845:
841:
837:
833:
829:
825:
821:
817:
813:
809:
805:
801:
787:
783:
779:
751:
746:
699:
668:
627:
623:
573:
567:g/cm (anhydrous)
566:
524:
517:
500:
490:Chemical formula
413:
412:
397:
395:
376:1773 (anhydrous)
359:
351:
344:
308:
297:
276:
268:
257:
246:
226:
206:
181:
173:
165:
158:
113:Iron trichloride
75:
41:
37:
33:
21:
7871:
7870:
7866:
7865:
7864:
7862:
7861:
7860:
7816:
7815:
7814:
7809:
7808:
7802:
7794:
7786:
7778:
7773:
7771:
7762:
7758:
7756:
7754:
7746:
7738:
7730:
7725:
7723:
7715:
7707:
7699:
7694:
7692:
7687:
7685:
7680:
7678:
7670:
7665:
7663:
7655:
7650:
7648:
7640:
7627:
7622:
7620:
7612:
7607:
7605:
7597:
7589:
7581:
7576:
7574:
7566:
7558:
7550:
7545:
7543:
7535:
7530:
7528:
7520:
7512:
7507:
7505:
7497:
7489:
7481:
7427:
7419:
7415:
7407:
7399:
7391:
7380:
7357:
7352:
7350:
7342:
7334:
7329:
7327:
7319:
7314:
7307:
7302:
7300:
7296:
7288:
7283:
7281:
7276:
7269:
7264:
7262:
7254:
7249:
7247:
7242:
7240:
7232:
7227:
7225:
7220:
7218:
7213:
7211:
7203:
7198:
7196:
7191:
7189:
7184:
7182:
7174:
7169:
7167:
7162:
7160:
7155:
7153:
7148:
7146:
7138:
7133:
7131:
7126:
7124:
7116:
7108:
7097:
7082:
7077:
7075:
7070:
7063:
7058:
7051:
7046:
7044:
7039:
7037:
7033:
7025:
7020:
7018:
7010:
7005:
7003:
6995:
6990:
6988:
6983:
6976:
6963:
6955:
6947:
6942:
6940:
6935:
6933:
6925:
6920:
6918:
6910:
6905:
6903:
6898:
6896:
6891:
6889:
6884:
6882:
6874:
6869:
6867:
6862:
6860:
6852:
6847:
6845:
6840:
6838:
6830:
6820:
6797:
6792:
6790:
6785:
6783:
6779:
6769:
6767:
6762:
6760:
6752:
6747:
6745:
6737:
6732:
6725:
6717:
6712:
6705:
6697:
6692:
6690:
6682:
6677:
6675:
6667:
6662:
6660:
6652:
6647:
6645:
6640:
6638:
6630:
6625:
6623:
6618:
6616:
6611:
6609:
6601:
6596:
6594:
6589:
6587:
6579:
6569:
6564:
6547:
6539:
6534:
6532:
6527:
6525:
6520:
6518:
6514:
6504:
6502:
6497:
6495:
6490:
6488:
6484:
6476:
6471:
6469:
6465:
6460:
6458:
6454:
6446:
6441:
6434:
6416:
6411:
6409:
6404:
6395:
6393:
6388:
6386:
6382:
6377:
6375:
6371:
6366:
6364:
6360:
6355:
6353:
6348:
6344:
6342:
6338:
6333:
6330:
6325:
6323:
6319:
6311:
6306:
6302:
6300:
6295:
6293:
6285:
6280:
6276:
6274:
6269:
6267:
6263:
6258:
6256:
6252:
6247:
6245:
6241:
6233:
6228:
6226:
6222:
6217:
6215:
6210:
6208:
6204:
6199:
6197:
6193:
6185:
6149:
6142:
6112:
6107:
6091:
6087:
6079:
6075:
6060:
6055:
6051:
6035:
6028:
6025:
6024:
6023:
6019:
6016:
6015:
6014:
6010:
6007:
6006:
6005:
6003:
5998:
5994:
5990:
5986:
5978:
5974:
5970:
5966:
5951:
5946:
5942:
5938:
5934:
5926:
5922:
5914:
5910:
5906:
5898:
5894:
5886:
5882:
5878:
5870:
5866:
5858:
5854:
5850:
5846:
5838:
5834:
5830:
5822:
5818:
5814:
5810:
5802:
5780:
5772:
5768:
5755:
5747:
5739:
5731:
5716:
5712:
5708:
5700:
5696:
5681:
5656:
5652:
5648:
5644:
5636:
5632:
5628:
5620:
5616:
5612:
5608:
5604:
5600:
5591:
5587:
5583:
5575:
5571:
5567:
5552:
5548:
5544:
5536:
5532:
5528:
5520:
5516:
5512:
5504:
5500:
5496:
5492:
5484:
5480:
5476:
5472:
5464:
5460:
5452:
5444:
5436:
5428:
5424:
5416:
5412:
5404:
5396:
5392:
5388:
5380:
5376:
5368:
5354:
5350:
5346:
5342:
5338:
5330:
5317:
5304:
5296:
5288:
5284:
5276:
5268:
5260:
5256:
5248:
5233:
5228:
5209:
5206:
5202:
5198:
5194:
5177:
5161:
5157:
5153:
5149:
5145:
5141:
5137:
5129:
5125:
5117:
5113:
5105:
5090:
5086:
5082:
5074:
5070:
5055:
5050:
5015:
4996:
4977:
4949:
4931:
4929:Further reading
4926:
4893:
4889:
4850:
4846:
4809:
4805:
4795:
4793:
4792:. 21 March 2011
4784:
4783:
4779:
4769:
4767:
4758:
4757:
4753:
4739:
4737:
4728:
4724:
4717:
4695:
4691:
4684:
4662:
4658:
4651:
4629:
4625:
4580:
4576:
4537:
4533:
4510:
4506:
4483:
4479:
4470:
4468:
4460:
4459:
4455:
4448:
4426:
4422:
4407:
4385:
4381:
4371:
4369:
4367:CoinValueLookup
4359:
4355:
4345:
4343:
4332:
4328:
4318:
4316:
4309:
4305:
4295:
4293:
4283:
4279:
4252:Chem. Eng. Sci.
4247:
4243:
4220:
4216:
4179:
4175:
4163:
4159:
4158:
4154:
4144:
4142:
4138:
4127:
4121:
4120:
4116:
4092:
4088:
4047:
4043:
4019:
4015:
4010:
4006:
3960:
3956:
3933:
3926:
3895:
3891:
3884:
3860:
3856:
3849:
3827:
3823:
3800:
3796:
3781:
3763:
3759:
3752:
3736:
3732:
3725:
3701:
3697:
3690:
3668:
3655:
3648:
3630:
3623:
3616:
3594:
3590:
3583:
3561:
3557:
3546:
3537:
3530:
3508:
3504:
3459:
3452:
3429:
3425:
3388:
3384:
3377:
3363:
3359:
3352:
3330:
3307:
3276:
3265:
3258:
3244:
3240:
3209:
3204:
3197:
3188:
3186:
3179:
3178:
3174:
3162:
3158:
3149:
3147:
3140:
3139:
3135:
3120:
3116:
3109:
3089:
3085:
3078:
3058:
3043:
3039:
3034:
3033:
3027:
3023:
3021:
3017:
3012:
3000:
2991:
2984:
2972:
2968:
2946:
2942:
2925:
2921:
2918:
2898:
2804:
2754:
2750:
2746:
2742:
2738:
2734:
2713:
2709:
2700:
2678:
2674:
2670:
2666:
2645:
2614:
2610:
2599:
2595:
2584:
2582:Water treatment
2579:
2563:
2559:
2555:
2551:
2547:
2543:
2539:
2535:
2531:
2527:
2514:
2502:
2498:
2494:
2490:
2486:
2482:
2478:
2474:
2470:
2466:
2462:
2458:
2454:
2450:
2443:
2439:
2435:
2428:
2424:
2419:
2415:
2403:
2392:
2379:
2368:
2364:
2360:
2356:
2317:sources, e.g.,
2306:
2302:
2298:
2294:
2284:
2282:
2270:
2266:
2262:
2258:
2244:
2240:
2236:
2232:
2228:
2224:
2220:
2216:
2206:
2192:
2188:
2184:
2159:
2155:
2151:
2147:
2145:
2139:
2135:
2131:
2116:
2112:
2108:
2104:
2100:
2096:
2093:
2089:
2085:
2081:
2077:
2073:
2054:
2050:
2046:
2042:
2038:
2034:
2030:
2024:sodium ethoxide
2020:
2016:
2001:
1997:
1993:
1989:
1979:iron(III) oxide
1975:hard Lewis acid
1964:oxidizing agent
1956:
1954:
1945:
1932:
1923:
1919:
1915:
1911:
1907:
1903:
1898:
1894:
1890:
1886:
1882:
1878:
1874:
1870:
1866:
1844:
1840:
1836:
1832:
1828:
1824:
1820:
1816:
1812:
1808:
1795:
1791:
1787:
1783:
1779:
1775:
1771:
1755:
1751:
1747:
1737:
1730:
1726:
1713:tetrahydrofuran
1680:
1676:
1672:
1668:
1657:
1648:
1644:
1636:
1632:
1628:
1624:
1616:
1612:
1608:
1604:
1600:
1596:
1588:
1584:
1580:
1576:
1572:
1568:
1560:
1556:
1552:
1548:
1544:
1536:
1528:
1524:
1520:
1516:
1512:
1508:
1504:
1500:
1496:
1492:
1488:
1484:
1469:stereochemistry
1455:
1451:
1447:
1443:
1428:
1407:
1402:
1398:
1388:
1384:
1380:
1362:
1358:
1346:
1338:
1329:
1325:
1321:
1282:
1262:oxidation state
1254:ferric chloride
1251:
1247:
1242:
1233:
1227:
1220:
1215:
1214:
1213: ?)
1204:
1200:
1196:
1192:
1176:
1164:
1150:
1147:
1143:
1135:
1127:
1119:
1107:
1103:
1085:
1071:
1055:
1045:
1019:
1009:
993:
974:
957:
953:
923:
922:
921:
920:
913:
906:
899:
895:
887:
796:
774:
760:
739:
697:
693:
683:
666:
660:
625:
621:
617:
608:
588:
577:
571:
564:
528:
522:
515:
499:
495:
492:
478:
475:
470:
469:
458:
455:
454:
448:
447:
444:
438:
437:
434:
428:
427:
416:
398:
391:
382:
363:
327:
311:
298:
286:
249:
229:
209:
196:
185:
148:
134:
133:
124:Ferric chloride
114:
112:
65:
53:
30:
23:
22:
18:Ferric chloride
15:
12:
11:
5:
7869:
7859:
7858:
7856:Acid catalysts
7853:
7848:
7843:
7838:
7833:
7828:
7811:
7810:
7805:
7804:
7800:
7796:
7792:
7788:
7784:
7780:
7776:
7769:
7765:
7760:
7752:
7748:
7744:
7740:
7736:
7732:
7728:
7721:
7717:
7713:
7709:
7705:
7701:
7697:
7690:
7683:
7676:
7672:
7668:
7661:
7657:
7653:
7646:
7642:
7638:
7634:
7630:
7629:
7625:
7618:
7614:
7610:
7603:
7599:
7595:
7591:
7587:
7583:
7579:
7572:
7568:
7564:
7560:
7556:
7552:
7548:
7541:
7537:
7533:
7526:
7522:
7518:
7514:
7510:
7503:
7499:
7495:
7491:
7487:
7483:
7479:
7475:
7471:
7470:
7467:
7464:
7463:
7460:
7457:
7454:
7451:
7448:
7445:
7442:
7439:
7436:
7433:
7430:
7425:
7421:
7417:
7413:
7409:
7405:
7401:
7397:
7393:
7389:
7385:
7382:
7378:
7374:
7368:
7367:
7364:
7359:
7355:
7348:
7344:
7340:
7336:
7332:
7325:
7321:
7317:
7309:
7305:
7298:
7294:
7290:
7286:
7279:
7271:
7267:
7260:
7256:
7252:
7245:
7238:
7234:
7230:
7223:
7216:
7209:
7205:
7201:
7194:
7187:
7180:
7176:
7172:
7165:
7158:
7151:
7144:
7140:
7136:
7129:
7122:
7118:
7114:
7110:
7106:
7102:
7099:
7095:
7091:
7085:
7084:
7080:
7073:
7065:
7061:
7053:
7049:
7042:
7035:
7031:
7027:
7023:
7016:
7012:
7008:
7001:
6997:
6993:
6986:
6978:
6974:
6970:
6965:
6961:
6957:
6953:
6949:
6945:
6938:
6931:
6927:
6923:
6916:
6912:
6908:
6901:
6894:
6887:
6880:
6876:
6872:
6865:
6858:
6854:
6850:
6843:
6836:
6832:
6828:
6824:
6822:
6818:
6814:
6808:
6807:
6804:
6799:
6795:
6788:
6781:
6777:
6773:
6765:
6758:
6754:
6750:
6743:
6739:
6735:
6727:
6723:
6719:
6715:
6707:
6703:
6699:
6695:
6688:
6684:
6680:
6673:
6669:
6665:
6658:
6654:
6650:
6643:
6636:
6632:
6628:
6621:
6614:
6607:
6603:
6599:
6592:
6585:
6581:
6577:
6573:
6571:
6567:
6559:
6553:
6552:
6549:
6545:
6541:
6537:
6530:
6523:
6516:
6512:
6508:
6500:
6493:
6486:
6482:
6478:
6474:
6467:
6463:
6456:
6452:
6448:
6444:
6436:
6432:
6428:
6422:
6421:
6418:
6414:
6407:
6399:
6391:
6384:
6380:
6373:
6369:
6362:
6358:
6351:
6340:
6336:
6328:
6321:
6317:
6313:
6309:
6298:
6291:
6287:
6283:
6272:
6265:
6261:
6254:
6250:
6243:
6239:
6235:
6231:
6224:
6220:
6213:
6206:
6202:
6195:
6191:
6187:
6183:
6179:
6173:
6172:
6169:
6167:
6165:
6163:
6155:
6154:
6151:
6150:
6141:
6140:
6133:
6126:
6118:
6109:
6108:
6106:
6105:
6099:
6097:
6093:
6092:
6090:
6089:
6085:
6081:
6077:
6073:
6068:
6066:
6062:
6061:
6059:
6058:
6053:
6047:
6045:
6041:
6040:
6037:
6036:
6034:
6033:
6026:
6017:
6008:
6000:
5996:
5992:
5988:
5984:
5980:
5976:
5972:
5968:
5964:
5959:
5957:
5950:
5949:
5944:
5940:
5936:
5932:
5928:
5924:
5920:
5916:
5912:
5908:
5904:
5900:
5896:
5892:
5888:
5884:
5880:
5876:
5872:
5868:
5864:
5860:
5856:
5852:
5848:
5844:
5840:
5836:
5832:
5828:
5824:
5820:
5816:
5812:
5808:
5804:
5800:
5796:
5791:
5787:
5782:
5778:
5774:
5770:
5766:
5762:
5757:
5753:
5749:
5745:
5741:
5737:
5733:
5729:
5724:
5722:
5718:
5717:
5715:
5714:
5710:
5706:
5702:
5698:
5694:
5689:
5687:
5683:
5682:
5680:
5679:
5674:
5668:
5666:
5662:
5661:
5658:
5657:
5655:
5654:
5650:
5646:
5642:
5638:
5634:
5630:
5626:
5622:
5618:
5614:
5610:
5606:
5602:
5598:
5594:
5589:
5585:
5581:
5577:
5573:
5569:
5565:
5560:
5558:
5551:
5550:
5546:
5542:
5538:
5534:
5530:
5526:
5522:
5518:
5514:
5510:
5506:
5502:
5498:
5494:
5490:
5486:
5482:
5478:
5474:
5470:
5466:
5462:
5458:
5454:
5450:
5446:
5442:
5438:
5434:
5430:
5426:
5422:
5418:
5414:
5410:
5406:
5402:
5398:
5394:
5390:
5386:
5382:
5378:
5374:
5370:
5366:
5362:
5357:
5352:
5348:
5344:
5340:
5336:
5332:
5328:
5324:
5319:
5315:
5311:
5306:
5302:
5298:
5294:
5290:
5286:
5282:
5278:
5274:
5270:
5266:
5262:
5258:
5254:
5250:
5246:
5241:
5239:
5235:
5234:
5232:
5231:
5226:
5221:
5219:
5215:
5214:
5211:
5210:
5208:
5204:
5200:
5196:
5192:
5188:
5186:
5176:
5175:
5169:
5167:
5163:
5162:
5160:
5159:
5155:
5151:
5147:
5143:
5139:
5135:
5131:
5127:
5123:
5119:
5115:
5111:
5107:
5103:
5098:
5096:
5092:
5091:
5089:
5088:
5084:
5080:
5076:
5072:
5068:
5063:
5061:
5057:
5056:
5053:Iron compounds
5049:
5048:
5041:
5034:
5026:
5020:
5019:
5013:
5000:
4994:
4981:
4975:
4962:
4953:
4947:
4930:
4927:
4925:
4924:
4887:
4844:
4803:
4777:
4751:
4722:
4715:
4689:
4682:
4656:
4649:
4623:
4574:
4531:
4504:
4493:(1): 290–294.
4477:
4453:
4446:
4420:
4405:
4379:
4353:
4326:
4303:
4277:
4258:(1): 229–245.
4241:
4230:(3): 332–337.
4214:
4173:
4152:
4114:
4086:
4059:(4285): 1040.
4041:
4030:(3): 193–202.
4017:
4013:
4004:
3954:
3943:(6): 766–790.
3924:
3905:(3): 330–333.
3889:
3882:
3854:
3847:
3821:
3794:
3779:
3757:
3750:
3730:
3723:
3695:
3688:
3653:
3646:
3621:
3614:
3588:
3581:
3555:
3535:
3528:
3502:
3489:(6): 968–974.
3450:
3423:
3402:(3): 990–993.
3382:
3375:
3357:
3350:
3305:
3263:
3256:
3238:
3219:(2): 173–180.
3207:
3195:
3172:
3156:
3133:
3114:
3107:
3083:
3076:
3040:
3038:
3035:
3032:
3031:
3025:
3014:
3013:
3011:
3008:
2998:
2983:
2980:
2970:
2963:The clouds of
2944:
2923:
2917:
2914:
2897:
2894:
2867:reducing agent
2863:sodium hydride
2850:reactions. On
2821:polythiophenes
2803:
2800:
2766:vinyl chloride
2758:
2757:
2752:
2748:
2744:
2740:
2736:
2711:
2710:(diethylether)
2707:
2699:
2696:
2681:
2680:
2676:
2672:
2668:
2644:
2641:
2612:
2597:
2583:
2580:
2578:
2575:
2567:
2566:
2561:
2557:
2553:
2549:
2545:
2541:
2537:
2533:
2529:
2512:
2505:
2504:
2500:
2496:
2492:
2488:
2484:
2480:
2476:
2472:
2468:
2464:
2460:
2456:
2452:
2441:
2437:
2426:
2422:methyl lithium
2417:
2413:
2401:
2390:
2378:
2375:
2371:
2370:
2366:
2362:
2358:
2304:
2300:
2296:
2283:
2280:
2277:
2273:
2272:
2268:
2264:
2260:
2248:
2247:
2242:
2238:
2234:
2230:
2226:
2222:
2218:
2204:
2195:
2194:
2190:
2186:
2167:stoichiometric
2157:
2149:
2143:
2137:
2133:
2114:
2110:
2109:, where Et = C
2106:
2102:
2098:
2091:
2087:
2083:
2079:
2075:
2058:
2057:
2052:
2048:
2044:
2040:
2036:
2032:
2018:
2005:
2004:
1999:
1995:
1991:
1955:
1952:
1951:Anhydrous FeCl
1949:
1943:
1931:
1928:
1927:
1926:
1921:
1917:
1913:
1909:
1905:
1901:
1896:
1892:
1888:
1884:
1880:
1876:
1872:
1868:
1847:
1846:
1842:
1838:
1834:
1830:
1826:
1822:
1818:
1814:
1810:
1798:
1797:
1793:
1789:
1785:
1781:
1780:+ 6 HCl + 9 H
1777:
1773:
1758:
1757:
1753:
1749:
1736:
1733:
1728:
1724:
1686:aquo complexes
1678:
1674:
1670:
1656:
1653:
1646:
1634:
1630:
1626:
1622:
1610:
1606:
1602:
1598:
1594:
1582:
1578:
1574:
1570:
1566:
1554:
1550:
1546:
1542:
1526:
1522:
1514:
1510:
1502:
1498:
1490:
1486:
1453:
1449:
1445:
1440:aquo complexes
1427:
1424:
1405:
1400:
1386:
1382:
1360:
1345:
1342:
1337:
1334:
1327:
1323:
1318:ferric nitrate
1314:ferric sulfate
1306:spin forbidden
1281:
1278:
1252:. Also called
1249:
1245:
1240:
1225:
1222:
1221:
1216:
1194:
1193:
1189:standard state
1186:
1183:
1182:
1177:
1172:
1169:
1168:
1165:
1155:
1152:
1151:
1148:
1122:
1120:
1115:
1112:
1111:
1104:
1099:
1096:
1095:
1086:
1081:
1078:
1077:
1073:
1072:
1070:
1069:
1064:
1058:
1056:
1050:
1047:
1046:
1044:
1043:
1038:
1033:
1028:
1022:
1020:
1014:
1011:
1010:
1008:
1007:
1002:
996:
994:
988:
985:
984:
980:
979:
969:
962:
961:
954:
948:
945:
944:
935:
934:
933:Non-flammable
931:
925:
924:
914:
907:
900:
885:
884:
883:
882:
880:
871:
870:
840:P305+P351+P338
832:P303+P361+P353
828:P301+P330+P331
797:
792:
789:
788:
775:
770:
767:
766:
761:
756:
753:
752:
740:
735:
732:
731:
721:
720:
716:
715:
708:
702:
701:
694:
688:
685:
684:
682:
681:
680:Highly soluble
678:
675:
674:Highly soluble
672:
669:
663:
661:
659:
658:
653:
648:
643:
637:
630:
629:
618:
613:
610:
609:
607:
606:
603:
599:
597:
591:
590:
585:
579:
578:
576:
575:
568:
560:
558:
552:
551:
545:
539:
538:
535:
531:
530:
529:
527:
526:
519:
511:
509:
503:
502:
497:
493:
488:
485:
484:
480:
479:
477:
476:
473:
465:
464:
463:
460:
459:
457:
456:
452:
451:
449:
445:
442:
441:
439:
435:
432:
431:
423:
422:
421:
418:
417:
415:
414:
401:
399:
387:
384:
383:
381:
380:
377:
373:
371:
365:
364:
362:
361:
353:
345:
337:
335:
329:
328:
326:
325:
321:
319:
313:
312:
310:
309:
301:
299:
291:
288:
287:
285:
284:
280:
278:
270:
269:
259:
251:
250:
248:
247:
239:
237:
231:
230:
228:
227:
219:
217:
211:
210:
208:
207:
199:
197:
190:
187:
186:
184:
183:
175:
167:
159:
151:
149:
144:
141:
140:
136:
135:
132:
131:
128:
125:
121:
120:
116:
115:
110:
104:
103:
99:
98:
95:
94:
85:
71:
70:
67:
66:
63:
54:
51:
28:
9:
6:
4:
3:
2:
7868:
7857:
7854:
7852:
7849:
7847:
7844:
7842:
7839:
7837:
7836:Metal halides
7834:
7832:
7829:
7827:
7824:
7823:
7821:
7803:
7797:
7795:
7789:
7787:
7781:
7779:
7772:
7766:
7764:
7755:
7749:
7747:
7741:
7739:
7733:
7731:
7724:
7718:
7716:
7710:
7708:
7702:
7700:
7693:
7686:
7679:
7673:
7671:
7664:
7658:
7656:
7649:
7643:
7641:
7635:
7632:
7631:
7628:
7621:
7615:
7613:
7606:
7600:
7598:
7592:
7590:
7584:
7582:
7575:
7569:
7567:
7561:
7559:
7553:
7551:
7544:
7538:
7536:
7529:
7523:
7521:
7515:
7513:
7506:
7500:
7498:
7492:
7490:
7484:
7482:
7476:
7473:
7472:
7465:
7461:
7458:
7455:
7452:
7449:
7446:
7443:
7440:
7437:
7434:
7431:
7429:
7422:
7420:
7410:
7408:
7402:
7400:
7394:
7392:
7386:
7383:
7381:
7375:
7373:
7370:
7369:
7365:
7363:
7360:
7358:
7351:
7345:
7343:
7337:
7335:
7328:
7322:
7320:
7313:
7310:
7308:
7301:
7291:
7289:
7282:
7275:
7272:
7270:
7263:
7257:
7255:
7248:
7241:
7235:
7233:
7226:
7219:
7212:
7206:
7204:
7197:
7190:
7183:
7177:
7175:
7168:
7161:
7154:
7147:
7141:
7139:
7132:
7125:
7119:
7117:
7111:
7109:
7103:
7100:
7098:
7092:
7090:
7087:
7086:
7083:
7076:
7069:
7066:
7064:
7057:
7054:
7052:
7045:
7038:
7028:
7026:
7019:
7013:
7011:
7004:
6998:
6996:
6989:
6982:
6979:
6977:
6971:
6969:
6966:
6964:
6958:
6956:
6950:
6948:
6941:
6934:
6928:
6926:
6919:
6913:
6911:
6904:
6897:
6890:
6883:
6877:
6875:
6868:
6861:
6855:
6853:
6846:
6839:
6833:
6831:
6825:
6823:
6821:
6815:
6813:
6810:
6809:
6805:
6803:
6800:
6798:
6791:
6784:
6774:
6772:
6768:
6761:
6755:
6753:
6746:
6740:
6738:
6731:
6728:
6726:
6720:
6718:
6711:
6708:
6706:
6700:
6698:
6691:
6685:
6683:
6676:
6670:
6668:
6661:
6655:
6653:
6646:
6639:
6633:
6631:
6624:
6617:
6610:
6604:
6602:
6595:
6588:
6582:
6580:
6574:
6572:
6570:
6563:
6560:
6558:
6555:
6554:
6550:
6548:
6542:
6540:
6533:
6526:
6519:
6509:
6507:
6503:
6496:
6489:
6479:
6477:
6470:
6459:
6449:
6447:
6440:
6437:
6435:
6429:
6427:
6424:
6423:
6419:
6417:
6410:
6403:
6400:
6398:
6394:
6387:
6376:
6365:
6354:
6347:
6343:
6332:
6324:
6314:
6312:
6305:
6301:
6294:
6288:
6286:
6279:
6275:
6268:
6257:
6246:
6236:
6234:
6227:
6216:
6209:
6198:
6188:
6186:
6180:
6178:
6175:
6174:
6170:
6164:
6162:
6159:
6158:
6152:
6147:
6139:
6134:
6132:
6127:
6125:
6120:
6119:
6116:
6104:
6101:
6100:
6098:
6094:
6088:
6082:
6080:
6070:
6069:
6067:
6063:
6057:
6049:
6048:
6046:
6042:
6032:
6001:
5999:
5981:
5979:
5961:
5960:
5958:
5954:
5948:
5929:
5927:
5917:
5915:
5901:
5899:
5889:
5887:
5873:
5871:
5861:
5859:
5841:
5839:
5825:
5823:
5805:
5803:
5797:
5795:
5792:
5790:
5788:
5786:
5783:
5781:
5775:
5773:
5763:
5761:
5758:
5756:
5750:
5748:
5742:
5740:
5734:
5732:
5726:
5725:
5723:
5719:
5713:
5703:
5701:
5691:
5690:
5688:
5684:
5678:
5675:
5673:
5670:
5669:
5667:
5663:
5653:
5639:
5637:
5623:
5621:
5595:
5593:
5578:
5576:
5562:
5561:
5559:
5555:
5549:
5539:
5537:
5523:
5521:
5507:
5505:
5487:
5485:
5467:
5465:
5455:
5453:
5447:
5445:
5439:
5437:
5431:
5429:
5419:
5417:
5407:
5405:
5399:
5397:
5383:
5381:
5371:
5369:
5363:
5361:
5358:
5356:
5333:
5331:
5325:
5323:
5320:
5318:
5312:
5310:
5307:
5305:
5299:
5297:
5291:
5289:
5279:
5277:
5271:
5269:
5263:
5261:
5251:
5249:
5243:
5242:
5240:
5236:
5230:
5223:
5222:
5220:
5216:
5207:
5189:
5187:
5185:(I) compounds
5184:
5180:
5174:
5171:
5170:
5168:
5164:
5158:
5132:
5130:
5120:
5118:
5108:
5106:
5100:
5099:
5097:
5093:
5087:
5077:
5075:
5065:
5064:
5062:
5058:
5054:
5047:
5042:
5040:
5035:
5033:
5028:
5027:
5024:
5016:
5014:9780471979258
5010:
5006:
5001:
4997:
4995:9780198553700
4991:
4987:
4982:
4978:
4976:9780333170885
4972:
4968:
4963:
4959:
4954:
4950:
4948:9780849304712
4944:
4940:
4939:
4933:
4932:
4920:
4916:
4912:
4908:
4904:
4900:
4899:
4891:
4883:
4879:
4875:
4871:
4867:
4863:
4859:
4855:
4848:
4839:
4834:
4830:
4826:
4822:
4818:
4814:
4807:
4791:
4787:
4781:
4765:
4761:
4755:
4747:
4735:
4734:
4726:
4718:
4712:
4708:
4704:
4700:
4693:
4685:
4679:
4675:
4671:
4667:
4660:
4652:
4646:
4642:
4638:
4634:
4627:
4619:
4615:
4610:
4605:
4601:
4597:
4593:
4589:
4585:
4578:
4570:
4566:
4562:
4558:
4554:
4550:
4546:
4542:
4535:
4527:
4523:
4519:
4515:
4508:
4500:
4496:
4492:
4488:
4481:
4467:
4463:
4457:
4449:
4447:9783527306732
4443:
4439:
4435:
4431:
4424:
4416:
4412:
4408:
4402:
4398:
4394:
4390:
4383:
4368:
4364:
4357:
4341:
4337:
4330:
4314:
4307:
4292:
4288:
4281:
4273:
4269:
4265:
4261:
4257:
4254:
4253:
4245:
4237:
4233:
4229:
4225:
4218:
4210:
4206:
4201:
4196:
4192:
4188:
4184:
4177:
4169:
4162:
4156:
4137:
4133:
4126:
4125:
4118:
4110:
4106:
4102:
4101:
4096:
4090:
4082:
4078:
4074:
4070:
4066:
4062:
4058:
4054:
4053:
4045:
4037:
4033:
4029:
4026:(in German).
4025:
4024:
4008:
3999:
3995:
3990:
3985:
3981:
3977:
3973:
3969:
3965:
3958:
3950:
3946:
3942:
3938:
3931:
3929:
3920:
3916:
3912:
3908:
3904:
3900:
3893:
3885:
3883:9780582462366
3879:
3875:
3871:
3867:
3866:
3858:
3850:
3848:9780470132371
3844:
3840:
3836:
3832:
3825:
3817:
3813:
3809:
3805:
3804:J. Phys. Chem
3798:
3790:
3786:
3782:
3780:9780121241407
3776:
3772:
3768:
3761:
3753:
3747:
3743:
3742:
3734:
3726:
3724:9780470132531
3720:
3716:
3712:
3708:
3707:
3699:
3691:
3685:
3681:
3677:
3673:
3666:
3664:
3662:
3660:
3658:
3649:
3647:9780750633659
3643:
3639:
3635:
3628:
3626:
3617:
3615:9780470132609
3611:
3607:
3603:
3599:
3592:
3584:
3582:9780470132593
3578:
3574:
3570:
3566:
3559:
3551:
3544:
3542:
3540:
3531:
3529:9780470131626
3525:
3521:
3517:
3513:
3506:
3497:
3492:
3488:
3484:
3480:
3478:
3474:
3470:
3466:
3457:
3455:
3446:
3442:
3438:
3434:
3427:
3418:
3413:
3409:
3405:
3401:
3397:
3393:
3386:
3378:
3372:
3368:
3361:
3353:
3347:
3343:
3339:
3335:
3328:
3326:
3324:
3322:
3320:
3318:
3316:
3314:
3312:
3310:
3301:
3297:
3293:
3289:
3285:
3281:
3274:
3272:
3270:
3268:
3259:
3253:
3249:
3242:
3234:
3230:
3226:
3222:
3218:
3215:
3214:
3202:
3200:
3184:
3183:
3176:
3169:
3165:
3160:
3145:
3144:
3137:
3129:
3125:
3118:
3110:
3108:1-4398-5511-0
3104:
3100:
3096:
3095:
3087:
3079:
3077:1-4398-5511-0
3073:
3069:
3065:
3064:
3056:
3054:
3052:
3050:
3048:
3046:
3041:
3019:
3015:
3007:
3005:
2997:
2994:
2989:
2979:
2977:
2976:sulfuric acid
2974:dissolved in
2966:
2961:
2959:
2955:
2951:
2940:
2938:
2934:
2930:
2913:
2911:
2907:
2903:
2890:
2886:
2884:
2880:
2876:
2872:
2869:that convert
2868:
2864:
2859:
2857:
2856:ene reactions
2853:
2849:
2848:epimerization
2845:
2841:
2837:
2833:
2828:
2826:
2822:
2818:
2813:
2809:
2799:
2797:
2793:
2792:chlorinations
2789:
2786:
2782:
2777:
2775:
2771:
2767:
2763:
2733:
2732:
2731:
2729:
2725:
2721:
2704:
2695:
2692:
2690:
2686:
2665:
2664:
2663:
2661:
2656:
2654:
2650:
2640:
2638:
2634:
2630:
2626:
2621:
2619:
2608:
2604:
2593:
2589:
2574:
2572:
2536:MgBr + FeCl
2526:
2525:
2524:
2522:
2518:
2510:
2477:
2463:+ Li[FeCl
2449:
2448:
2447:
2433:
2423:
2411:
2407:
2399:
2396:
2388:
2384:
2383:organolithium
2374:
2361:+ CuCl → FeCl
2355:
2354:
2353:
2351:
2347:
2342:
2340:
2336:
2332:
2328:
2324:
2320:
2316:
2312:
2292:
2287:
2279:Hydrated FeCl
2276:
2257:
2256:
2255:
2253:
2215:
2214:
2213:
2211:
2210:chlorobenzene
2207:
2200:
2189:+ Fe → 3 FeCl
2183:
2182:
2181:
2179:
2174:
2172:
2168:
2163:
2129:
2125:
2120:
2071:
2067:
2063:
2043:ONa → "Fe(OCH
2029:
2028:
2027:
2025:
2014:
2010:
2007:Alkali metal
1988:
1987:
1986:
1984:
1980:
1976:
1972:
1967:
1965:
1961:
1948:
1941:
1937:
1902:
1865:
1864:
1863:
1861:
1857:
1853:
1819:
1807:
1806:
1805:
1803:
1770:
1769:
1768:
1766:
1762:
1746:
1745:
1744:
1742:
1732:
1722:
1718:
1714:
1710:
1709:diethyl ether
1705:
1702:
1698:
1695:
1691:
1687:
1661:
1652:
1642:
1620:
1592:
1564:
1540:
1534:
1482:
1478:
1474:
1470:
1467:
1466:
1462:
1441:
1437:
1436:deliquescence
1433:
1423:
1421:
1417:
1413:
1410:
1397:
1393:
1379:
1374:
1372:
1368:
1364:
1355:
1351:
1341:
1333:
1319:
1315:
1311:
1307:
1303:
1299:
1295:
1286:
1277:
1275:
1271:
1270:water cleaner
1267:
1263:
1259:
1255:
1239:
1236:
1231:
1219:
1212:
1207:
1190:
1184:
1181:
1178:
1175:
1171:
1170:
1166:
1162:
1158:
1157:Formula units
1154:
1153:
1141:
1133:
1125:
1121:
1118:
1114:
1113:
1105:
1102:
1098:
1097:
1094:
1090:
1087:
1084:
1080:
1079:
1074:
1068:
1065:
1063:
1060:
1059:
1057:
1054:
1049:
1048:
1042:
1039:
1037:
1034:
1032:
1029:
1027:
1024:
1023:
1021:
1018:
1013:
1012:
1006:
1003:
1001:
998:
997:
995:
992:
987:
986:
981:
977:
973:
970:
967:
964:
963:
955:
952:(Recommended)
951:
947:
946:
942:
941:
936:
932:
930:
927:
926:
919:
912:
905:
881:
878:
877:
873:
872:
798:
795:
791:
790:
776:
773:
769:
768:
765:
762:
759:
755:
754:
750:
745:
741:
738:
734:
733:
729:
727:
722:
717:
713:
709:
707:
704:
703:
695:
691:
687:
686:
679:
676:
673:
670:
665:
664:
662:
657:
656:Diethyl ether
654:
652:
649:
647:
644:
642:
639:
638:
635:
632:
631:
619:
616:
612:
611:
604:
601:
600:
598:
596:
595:Boiling point
593:
592:
586:
584:
583:Melting point
581:
580:
569:
562:
561:
559:
557:
554:
553:
550:
546:
544:
541:
540:
536:
533:
532:
520:
513:
512:
510:
508:
505:
504:
494:
491:
487:
486:
481:
472:
471:
468:
461:
450:
440:
430:
429:
426:
419:
411:
407:
406:DTXSID8020622
403:
402:
400:
390:
386:
385:
378:
375:
374:
372:
370:
367:
366:
358:
354:
350:
346:
343:
339:
338:
336:
334:
331:
330:
323:
322:
320:
318:
315:
314:
307:
303:
302:
300:
294:
290:
289:
282:
281:
279:
277:
272:
271:
267:
263:
260:
258:
256:ECHA InfoCard
253:
252:
245:
241:
240:
238:
236:
233:
232:
225:
221:
220:
218:
216:
213:
212:
205:
201:
200:
198:
194:
189:
188:
180:
176:
172:
168:
164:
160:
157:
153:
152:
150:
147:
143:
142:
137:
130:Flores martis
129:
126:
123:
122:
117:
109:
105:
100:
90:
86:
81:
77:
76:
72:
59:
55:
47:
43:
42:
38:
32:
27:
19:
6678:
5743:
5004:
4985:
4966:
4957:
4936:
4902:
4896:
4890:
4857:
4853:
4847:
4820:
4816:
4806:
4794:. Retrieved
4789:
4780:
4768:. Retrieved
4763:
4754:
4738:. Retrieved
4732:
4725:
4698:
4692:
4665:
4659:
4632:
4626:
4591:
4587:
4577:
4544:
4540:
4534:
4517:
4513:
4507:
4490:
4486:
4480:
4469:. Retrieved
4465:
4456:
4429:
4423:
4388:
4382:
4370:. Retrieved
4366:
4356:
4344:. Retrieved
4339:
4329:
4317:. Retrieved
4306:
4294:. Retrieved
4290:
4280:
4255:
4250:
4244:
4227:
4223:
4217:
4193:(1): 35–41.
4190:
4186:
4176:
4170:. June 2006.
4155:
4143:. Retrieved
4136:the original
4123:
4117:
4098:
4089:
4056:
4050:
4044:
4027:
4021:
4007:
3971:
3967:
3957:
3940:
3936:
3902:
3898:
3892:
3864:
3857:
3830:
3824:
3807:
3803:
3797:
3770:
3760:
3740:
3733:
3704:
3698:
3671:
3633:
3597:
3591:
3564:
3558:
3549:
3511:
3505:
3486:
3482:
3476:
3472:
3468:
3464:
3436:
3432:
3426:
3399:
3395:
3385:
3366:
3360:
3333:
3283:
3279:
3247:
3241:
3216:
3211:
3187:, retrieved
3181:
3175:
3159:
3148:, retrieved
3142:
3136:
3117:
3092:
3086:
3061:
3018:
2985:
2962:
2941:
2928:
2919:
2899:
2860:
2829:
2805:
2778:
2759:
2717:
2693:
2683:The soluble
2682:
2657:
2646:
2622:
2618:ferrihydrite
2585:
2568:
2506:
2495:] + 0.5 CH
2467:] + 0.5 CH
2395:nucleophilic
2380:
2372:
2343:
2335:colorimetric
2311:ferrioxalate
2288:
2285:
2274:
2249:
2196:
2175:
2164:
2121:
2059:
2006:
1968:
1957:
1933:
1848:
1799:
1764:
1763:
1759:
1740:
1738:
1706:
1666:
1618:
1590:
1562:
1538:
1464:
1460:
1429:
1390:, much like
1375:
1347:
1339:
1310:Laporte rule
1294:paramagnetic
1291:
1276:for metals.
1253:
1229:
1228:
1160:
1139:
1131:
1123:
939:
875:
763:
725:
677:830 g/L
317:RTECS number
139:Identifiers
119:Other names
31:
26:
4823:(1): 1–54.
4319:October 14,
2840:dehydration
2772:for making
2564:+ 3 MgBrCl
2479:Li[FeCl
2404:-catalyzed
2315:carboxylate
2309:, known as
2229:Cl → 2 FeCl
2148:Na[FeCl
2136:N)[FeCl
2066:Lewis bases
1883:SiCl → FeCl
1784:O → 2 FeCl
1748:2 Fe + 3 Cl
1735:Preparation
1633:]Cl·2H
1409:point group
1258:hygroscopic
1101:Space group
929:Flash point
758:Signal word
534:Appearance
483:Properties
262:100.028.846
224:CHEBI:30808
108:IUPAC names
7820:Categories
5686:Fe(II,III)
5183:Organoiron
4796:5 February
4770:5 February
4764:mindat.org
4760:"Molysite"
4746:U.C. Davis
4716:0471936235
4683:0471936235
4650:0471936235
4471:2023-08-30
4372:5 February
4346:5 February
4296:5 February
3968:Polyhedron
3751:0306476576
3689:0471936235
3351:3527306730
3037:References
2836:silica gel
2817:thiophenes
2781:Lewis acid
2483:] + LiCH
2180:reaction:
2156:K[FeCl
2055:" + 3 NaCl
1960:Lewis acid
1912:O + 6 SOCl
1899:O + 12 HCl
1875:O + 12 (CH
1605:][FeCl
1577:][FeCl
1553:][FeCl
1513:·3.5H
1501:·2.5H
1477:octahedral
1367:octahedral
1272:and as an
1266:Lewis acid
1180:Octahedral
1110:, No. 148
1076:Structure
1053:coagulants
737:Pictograms
696:+13,450·10
634:Solubility
507:Molar mass
357:Y048945596
349:0I2XIN602U
342:U38V3ZVV3V
235:ChemSpider
191:3D model (
179:64333-00-2
171:54862-84-9
163:10025-77-1
146:CAS Number
7826:Chlorides
6096:Purported
5665:Fe(0,III)
4740:2 January
4569:206542971
4415:201676001
4209:229396639
4095:Pauson PL
3974:: 91–96.
3789:162129468
3439:: 31–41.
3300:105925459
3099:CRC Press
3068:CRC Press
3004:corrosive
2937:fumaroles
2933:volcanoes
2896:Histology
2832:supported
2785:catalyses
2633:insoluble
2625:phosphate
2521:ferrocene
2491:[FeCl
2440:[FeCl
2295:[Fe(C
2171:catalyzed
2009:alkoxides
1971:oxophilic
1936:high spin
1930:Reactions
1833:O → FeCl
1719:form 1:2
1694:polymeric
1669:[FeCl
1651:) anion.
1645:[FeCl
1444:[FeCl
1396:monomeric
1350:anhydrous
1344:Anhydrous
1336:Structure
1322:[Fe(H
1302:high spin
1298:d-orbital
1089:Hexagonal
836:P304+P340
824:P301+P312
728:labelling
710:12 c
706:Viscosity
369:UN number
324:LJ9100000
283:231-729-4
275:EC Number
156:7705-08-0
6146:chloride
5995:⋅xFe⋅yNH
5777:Fe(acac)
5218:Fe(0,II)
4766:. Mindat
4618:34133136
4561:31580649
3998:31031511
3130:(NIOSH).
2929:molysite
2883:alcohols
2812:reagents
2724:chlorine
2720:ethylene
2649:leaching
2552:+ 1/n (C
2540:→ Fe(C
2348:to give
2323:tartrate
2313:. Other
2072:; e.g.,
2068:such as
2002:→ 3FeOCl
1924:+ 12 HCl
1908:·6H
1887:+ 6 ((CH
1871:·6H
1825:+ 0.5 Cl
1752:→ 2 FeCl
1655:Solution
1609:]·H
1581:]·H
1525:·6H
1489:·2H
1432:hydrates
1426:Hydrates
1420:chlorine
1051:Related
876:NFPA 704
719:Hazards
692:(χ)
646:Methanol
474:Cl(Cl)Cl
127:Molysite
7469:
5794:FeO(OH)
5721:Fe(III)
5060:Fe(-II)
4907:Bibcode
4882:4369293
4862:Bibcode
4825:Bibcode
4609:9008594
4260:Bibcode
4081:4181383
4061:Bibcode
3989:6481957
3919:7661424
3870:Longman
3404:Bibcode
3221:Bibcode
3124:"#0346"
2954:methane
2879:alkanes
2875:ketones
2871:alkenes
2852:alumina
2815:3-Alkyl
2770:monomer
2691:(PCB).
2675:+ CuCl
2455:+ LiCH
2319:citrate
2291:oxalate
2263:→ 2FeCl
1962:and an
1765:Aqueous
1727:(ether)
1721:adducts
1690:olation
1475:on the
1473:ligands
1404:(with D
1371:ligands
1300:. The
1274:etchant
1211:what is
1209: (
1017:cations
700:cm/mol
651:Ethanol
641:Acetone
556:Density
547:Slight
521:270.295
514:162.204
501:
293:PubChem
6065:Fe(VI)
6044:Fe(IV)
5649:Fe(CO)
5633:Fe(CO)
5314:Fe(OH)
5281:Fe(ClO
5238:Fe(II)
5134:Fe(CO)
5102:Fe(CO)
5083:Fe(CO)
5071:Fe(CO)
5011:
4992:
4973:
4945:
4880:
4854:Nature
4713:
4680:
4647:
4616:
4606:
4567:
4559:
4520:: 68.
4444:
4413:
4403:
4207:
4145:26 Oct
4079:
4052:Nature
3996:
3986:
3917:
3880:
3845:
3787:
3777:
3748:
3721:
3686:
3644:
3612:
3579:
3526:
3373:
3348:
3298:
3254:
3189:19 Sep
3150:19 Sep
3105:
3074:
2982:Safety
2768:, the
2747:→ ClCH
2667:2 FeCl
2660:copper
2611:Fe(OH)
2459:→ FeCl
2451:2 FeCl
2365:+ CuCl
2217:2 FeCl
2185:2 FeCl
2062:adduct
2035:+ 3 CH
1973:and a
1940:labile
1934:Being
1920:+ 6 SO
1916:→ FeCl
1829:+ 6 H
1717:ethers
1615:, and
1206:verify
1203:
1144:
1136:
1128:
1015:Other
991:anions
989:Other
968:(SDS)
958:
764:Danger
698:
667:
626:
622:
572:
565:
523:
516:
467:SMILES
102:Names
6084:BaFeO
5935:Fe(SO
5785:FeOCl
5765:Fe(NO
5588:)(CO)
5441:FeTiO
5433:FeMoO
5409:Fe(BF
5373:Fe(NO
5365:FeSeO
5343:Fe(SO
5199:FeCO)
5166:Fe(I)
5095:Fe(0)
4878:S2CID
4565:S2CID
4466:ATSDR
4411:S2CID
4205:S2CID
4164:(PDF)
4139:(PDF)
4128:(PDF)
4077:S2CID
3874:Wiley
3296:S2CID
3010:Notes
2965:Venus
2877:into
2722:with
2653:Elkem
2434:(II)
2259:2FeCl
2245:+ HCl
2208:with
2130:ion (
2078:(OP(C
2064:with
1621:−FeCl
1619:trans
1617:[
1593:−FeCl
1589:[
1565:−FeCl
1561:[
1541:−FeCl
1539:trans
1537:[
1461:trans
1422:gas.
1378:dimer
960:mg/m
956:TWA 1
940:NIOSH
425:InChI
306:24380
244:22792
215:ChEBI
193:JSmol
7799:NoCl
7791:MdCl
7783:FmCl
7775:EsCl
7768:EsCl
7759:CfCl
7751:CfCl
7743:BkCl
7735:CmCl
7727:AmCl
7720:AmCl
7712:PuCl
7704:NpCl
7667:PaCl
7660:PaCl
7652:ThCl
7645:ThCl
7637:AcCl
7624:YbCl
7617:YbCl
7609:TmCl
7602:TmCl
7594:ErCl
7586:HoCl
7578:DyCl
7571:DyCl
7563:TbCl
7555:GdCl
7547:EuCl
7540:EuCl
7532:SmCl
7525:SmCl
7517:PmCl
7509:NdCl
7502:NdCl
7494:PrCl
7486:CeCl
7478:LaCl
7404:DbCl
7396:RfCl
7388:LrCl
7377:RaCl
7372:FrCl
7362:AtCl
7354:PoCl
7347:PoCl
7339:BiCl
7331:PbCl
7324:PbCl
7316:TlCl
7312:TlCl
7304:HgCl
7285:AuCl
7278:(Au)
7274:AuCl
7266:PtCl
7259:PtCl
7251:IrCl
7244:IrCl
7237:IrCl
7229:OsCl
7222:OsCl
7215:OsCl
7208:OsCl
7200:ReCl
7193:ReCl
7186:ReCl
7179:ReCl
7135:TaCl
7128:TaCl
7121:TaCl
7113:HfCl
7105:LuCl
7094:BaCl
7089:CsCl
7079:XeCl
7072:XeCl
7068:XeCl
7048:TeCl
7041:TeCl
7022:SbCl
7015:SbCl
7007:SnCl
7000:SnCl
6992:InCl
6985:InCl
6981:InCl
6973:CdCl
6968:AgCl
6960:PdCl
6952:RhCl
6944:RuCl
6937:RuCl
6930:RuCl
6922:TcCl
6915:TcCl
6907:MoCl
6900:MoCl
6893:MoCl
6886:MoCl
6879:MoCl
6871:NbCl
6864:NbCl
6857:NbCl
6849:ZrCl
6842:ZrCl
6835:ZrCl
6817:SrCl
6812:RbCl
6802:BrCl
6794:SeCl
6787:SeCl
6764:AsCl
6757:AsCl
6749:GeCl
6742:GeCl
6734:GaCl
6730:GaCl
6722:ZnCl
6714:CuCl
6710:CuCl
6702:NiCl
6694:CoCl
6687:CoCl
6679:FeCl
6672:FeCl
6664:MnCl
6657:MnCl
6649:CrCl
6642:CrCl
6635:CrCl
6598:TiCl
6591:TiCl
6584:TiCl
6576:ScCl
6566:CaCl
6562:CaCl
6473:SiCl
6443:AlCl
6439:AlCl
6431:MgCl
6426:NaCl
6182:BeCl
6177:LiCl
5963:Fe(C
5943:·12H
5919:Fe(N
5879:(SeO
5831:(CrO
5799:FePO
5744:FeCl
5736:FeBr
5677:FeGe
5672:FeSi
5597:Fe(C
5580:Fe(C
5564:Fe(C
5545:(CO)
5489:Fe(C
5469:Fe(C
5449:FeCO
5421:FeCr
5401:FeSi
5360:FeSe
5327:FeSO
5293:FeBr
5273:FeCl
5203:(CO)
5126:(CO)
5114:(CO)
5009:ISBN
4990:ISBN
4971:ISBN
4943:ISBN
4798:2024
4772:2024
4742:2013
4711:ISBN
4678:ISBN
4645:ISBN
4614:PMID
4557:PMID
4442:ISBN
4401:ISBN
4374:2024
4348:2024
4321:2016
4298:2024
4147:2007
4016:FeCl
3994:PMID
3915:PMID
3878:ISBN
3843:ISBN
3785:OCLC
3775:ISBN
3746:ISBN
3719:ISBN
3684:ISBN
3642:ISBN
3610:ISBN
3577:ISBN
3524:ISBN
3371:ISBN
3346:ISBN
3252:ISBN
3191:2010
3152:2010
3103:ISBN
3072:ISBN
3024:FeCl
2969:FeCl
2943:FeCl
2935:and
2922:FeCl
2904:, a
2881:and
2873:and
2842:and
2790:and
2743:+ Cl
2739:C=CH
2730:):
2603:floc
2596:FeCl
2590:and
2577:Uses
2487:→ Li
2425:LiCH
2385:and
2357:FeCl
2321:and
2267:+ Cl
2203:FeCl
2154:and
2101:(OEt
2097:FeCl
2074:FeCl
2031:FeCl
2022:and
2017:FeCl
1994:+ Fe
1990:FeCl
1904:FeCl
1867:FeCl
1821:FeCl
1711:and
1521:FeCl
1509:FeCl
1497:FeCl
1485:FeCl
1418:and
1399:FeCl
1348:The
1316:and
1138:nm,
1130:nm,
1093:hR24
976:1499
972:ICSC
868:P501
864:P406
860:P405
856:P390
852:P363
848:P321
844:P310
820:P280
816:P273
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