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Iron(III) chloride

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of unspecified stereochemistry. Detailed speciation of aqueous solutions of ferric chloride is challenging because the individual components do not have distinctive spectroscopic signatures. Iron(III) complexes, with a high spin d configuration, is kinetically labile, which means that ligands rapidly
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A number of variables apply to these processes, including the oxidation of iron by ferric chloride and the hydration of intermediates. Hydrates of iron(III) chloride do not readily yield anhydrous ferric chloride. Attempted thermal dehydration yields hydrochloric acid and
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The reaction is conducted at several hundred degrees such that the product is gaseous. Using excess chlorine guarantees that the intermediate ferrous chloride is converted to the ferric state. A similar but laboratory-scale process also has been described.
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of 10, which exhibit the property of "aging", i.e., the structure change or evolve over the course of days. The polymeric species formed by the hydrolysis of ferric chlorides are key to the use of ferric chloride for water treatment.
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O ligands exchange rapidly with free chloride and water. In contrast to their kinetic lability, iron(III) chlorides are thermodynamically robust, as reflected by the vigorous methods applied to their synthesis, as described above.
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because they are inexpensive, earth abundant, and relatively nontoxic. Many experiments probe both its redox activity and its Lewis acidity. For example, iron(III) chloride oxidizes naphthols to naphthoquinones:
2015:. These products have more complicated structures than anhydrous iron(III) chloride. In the solid phase a variety of multinuclear complexes have been described for the nominal stoichiometric reaction between 757: 2515:
as ether-soluble sources of ferric ion. These diketonate complexes have the advantages that they do not form hydrates, unlike iron(III) chloride, and they are more soluble in relevant solvents.
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compound is a hygroscopic crystalline solid with a melting point of 307.6 °C. The colour depends on the viewing angle: by reflected light, the crystals appear dark green, but by
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Riddell WA, Noller CR (1932). "Mixed Catalysis in the Friedel and Crafts Reaction. The Yields in Typical Reactions using Ferric Chloride–Aluminum Chloride Mixtures as Catalysts".
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Unlike the anhydrous material, hydrated ferric chloride is not a particularly strong Lewis acid since water ligands have quenched the Lewis acidity by binding to Fe(III).
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Dueñas Díez M, Fjeld M, Andersen E, et al. (2006). "Validation of a compartmental population balance model of an industrial leaching process: The Silgrain process".
2594:. By forming highly dispersed networks of Fe-O-Fe containing materials, ferric chlorides serve as coagulant and flocculants. In this application, an aqueous solution of 839: 894: 7127: 1332:, are nearly colorless, whereas the chloride solutions are yellow. Thus, the chloride ligands significantly influence the optical properties of the iron center. 902: 6729: 4122: 1312:. This double forbidden-ness results in its solutions being only pale colored. Or, stated more technically, the optical transitions are non-intense. Aqueous 1256:, these compounds are some of the most important and commonplace compounds of iron. They are available both in anhydrous and in hydrated forms which are both 831: 3127: 938: 4022: 1210: 3022:
An alternative GHS classification from the Japanese GHS Inter-ministerial Committee (2006) notes the possibility of respiratory tract irritation from
1531:. These species differ with respect to the stereochemistry of the octahedral iron cation, the identity of the anions, and the presence or absence of 2329:. The affinity of iron(III) for oxygen ligands was the basis of qualitative tests for phenols. Although superseded by spectroscopic methods, the 916: 3897:
James A. King, Alan B. Storrow, Jeff A. Finkelstein (1995). "Urine Trinder Spot Test: A Rapid Salicylate Screen for the Emergency Department".
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Aside from lability, which applies to anhydrous and hydrated forms, the reactivity of anhydrous ferric chloride reveals two trends: It is a
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Boudjouk P, So JH, Ackermann MN, et al. (1992). "Solvated and Unsolvated Anhydrous Metal Chlorides from Metal Chloride Hydrates".
5789: 5043: 835: 2990:, so they pose few problems as poisons, at low concentrations. Nonetheless, anhydrous iron(III) chloride, as well as concentrated 1205: 5596: 3863: 5579: 2275:
To suppress this reaction, the preparation of iron(III) chloride requires an excess of chlorinating agent, as discussed above.
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Park KH, Mohapatra D, Reddy BR (2006). "A study on the acidified ferric chloride leaching of a complex (Cu–Ni–Co–Fe) matte".
3374: 3255: 3093: 3062: 2408:. The isolation of organoiron(III) intermediates requires low-temperature reactions, lest the intermediates degrade. Using 57: 5133: 3935:
Mako TL, Byers JA (2016). "Recent Advances in Iron-Catalysed Cross Coupling Reactions and Their Mechanistic Underpinning".
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and thus precipitates as a solid. One potential advantage to its use in water treatment, ferric ion oxidizes (deodorizes)
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solutions of iron(III) chloride are also produced industrially from a number of iron precursors, including iron oxides:
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Green-black by reflected light; purple-red by transmitted light; yellow solid as hexahydrate; brown as aqueous solution
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So RC, Carreon-Asok AC (2019). "Molecular Design, Synthetic Strategies, and Applications of Cationic Polythiophenes".
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Iron(III) chloride can exist as an anhydrous material and a series of hydrates, which results in distinct structures.
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dissociate and reassociate. A further complication is that these solutions are strongly acidic, as expected for
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Iron(III) chloride has a relatively low melting point and boils at around 315 °C. The vapor consists of the
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Dreher EL, Beutel KK, Myers JD, Lübbe T, Krieger S, Pottenger LH (2014). "Chloroethanes and Chloroethylenes".
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Kikkawa S, Kanamaru F, Koizumi M, et al. (1984). "Layered Intercalation Compounds". In Holt SL Jr (ed.).
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Wildermuth E, Stark H, Friedrich G, Ebenhöch FL, Kühborth B, Silver J, Rituper R (2000). "Iron Compounds".
1854:. In the laboratory, hydrated iron(III) chloride can be converted to the anhydrous form by treatment with 793: 332: 261: 3964:"Synthesis and Characterization of a Sterically Encumbered Homoleptic Tetraalkyliron(III) Ferrate Complex" 2176:
In terms of its being an oxidant, iron(III) chloride oxidizes iron powder to form iron(II) chloride via a
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Several hundred tons of anhydrous iron(III) chloride are produced annually. The principal method, called
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Krasnopolsky VA (2006). "Chemical composition of Venus atmosphere and clouds: Some unsolved problems".
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Anhydrous iron(III) chloride evaporates at relatively low temperatures to give the bitetrahedral dimer.
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Cook CM Jr, Dunn WE Jr (1961). "The Reaction of Ferric Chloride with Sodium and Potassium Chlorides".
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agent in chloride hydrometallurgy, for example in the production of Si from FeSi (Silgrain process by
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In contrast to the complicated behavior of its aqueous solutions, solutions of iron(III) chloride in
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Mallory, Sheehan, Hrapchak (1990). "Verhoeff's Elastic Stain". In Carson F, Cappellano CH (eds.).
4160: 1977:. Myriad manifestations of the oxophiliicty of iron(III) chloride are available. When heated with 7855: 7742: 7726: 7711: 7703: 7623: 7570: 7508: 7477: 7047: 7029: 6943: 6936: 6921: 6906: 6878: 6841: 6748: 6663: 6128: 5982: 5806: 5029: 4286: 3167: 2409: 2405: 2373:
This fundamental reaction is relevant to the use of ferric chloride solutions in etching copper.
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and is thought to have a range of cooling effects; thus, it has been proposed as a catalyst for
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from sea salt. This iron salt aerosol causes about 1-5% of naturally-occurring oxidization of
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Aqueous iron(III) chloride serves as a one-electron oxidant illustrated by its reaction with
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Like the solid hydrates, aqueous solutions of ferric chloride also consist of the octahedral
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Albright H, Davis AJ, Gomez-Lopez JL, Vonesh HL, Quach PK, Lambert TH, Schindler CS (2021).
3463:"Alkoxo-Verbindungen des dreiwertigen Eisen: Synthese und Charakterisierung von [Fe2(Ot 3180: 7734: 7695: 7651: 7601: 7593: 7485: 7315: 7311: 7303: 7277: 7236: 7214: 7199: 7185: 7163: 7134: 7040: 7014: 6991: 6863: 6801: 6741: 6693: 6626: 6528: 6405: 6378: 6356: 6289: 6270: 5704: 5280: 5182: 4906: 4861: 4824: 4259: 4060: 3873: 3403: 3220: 2905: 2901: 2839: 2648: 2330: 356: 348: 341: 243: 178: 170: 162: 2658:
In another commercial application, a solution of iron(III) chloride is useful for etching
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bei der Umsetzung von Eisen(III)-chlorid mit Lithiummethyl (1:1) in ätherischer Lösung".
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Krasnopolsky VA, Parshev VA (1981). "Chemical composition of the atmosphere of Venus".
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Tarr BR, Booth HS, Dolance A (1950). "Anhydrous Iron(III) Chloride (Ferric Chloride)".
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upon treatment with ferric chloride. Iron(III) chloride has been shown to promote C-C
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is rinsed away, leaving a copper pattern. This chemistry is used in the production of
2620:). This floc facilitates the separation of suspended materials, clarifying the water. 79: 7371: 7330: 7323: 6811: 6770: 6671: 6575: 6521: 6345: 6334: 6307: 6237: 6211: 6160: 6071: 5902: 5890: 5764: 5735: 5671: 5440: 5420: 5364: 5359: 5272: 5264: 5008: 4989: 4970: 4942: 4710: 4677: 4644: 4613: 4568: 4556: 4441: 4414: 4400: 4208: 3993: 3914: 3877: 3842: 3784: 3774: 3745: 3738:
Turova NY, Turevskaya EP, Kessler VG, et al., eds. (2002). "12.22.1 Synthesis".
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Pray AR, Heitmiller RF, Strycker S, et al. (1990). "Anhydrous Metal Chlorides".
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reactions, the Lewis acidity of ferric chloride enables its use in a variety of acid-
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derivatives. Dilute solutions of ferric chloride produce soluble nanoparticles with
1415: 1377: 1353: 1082: 1025: 1004: 965: 548: 5007:. Handbook of Reagents for Organic Synthesis. New York: John Wiley & Sons, Inc. 4012:
Berthold HJ, Spiegl HJ (1972). "Über die Bildung von Lithiumtetrachloroferrat(II) Li
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has been examined often. These studies are enabled because of the solubility of FeCl
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iron(III) chloride releases chlorine gas when heated above 160 °C, generating
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This conversion, although not of practical value, was important in the history of
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Like the anhydrous material, hydrated ferric chloride is oxophilic. For example,
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Simon A. Cotton (2018). "Iron(III) Chloride and Its Coordination Chemistry".
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Iron(III) chloride is used in many other hobbies involving metallic objects.
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upon exposure to water, reflecting its Lewis acidity. All hydrates exhibit
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Complexes and First-Row Transition Elements, Macmillan Press, London, 1973
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In industry, iron(III) chloride is used as a catalyst for the reaction of
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Reactions of anhydrous iron(III) chloride reflect its description as both
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and differs slightly in other respects from the classification used here.
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Hashimoto S, Forster K, Moss SC (1989). "Structure refinement of an FeCl
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in ethereal solvents, which avoids the possibility of hydrolysis of the
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d electronic configuration requires that d-d electronic transitions are
901: 799: 6102: 4759: 4131: 3948: 2835: 2780: 2420:] have been isolated. Illustrating the sensitivity of these reactions, 2065: 1959: 1659: 1366: 1265: 1179: 908: 633: 506: 274: 234: 6143: 4072: 3416: 3391: 851: 5563: 4873: 3098: 3067: 2948:-based aerosol are produced by a reaction between iron-rich dust and 2816: 2632: 2624: 2520: 2170: 1970: 1693: 1395: 1349: 1297: 785: 705: 368: 2511:
and related beta-diketonate complexes are more widely used than FeCl
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Except where otherwise noted, data are given for materials in their
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undergoes a complex reaction with iron(III) chloride, resulting in
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Kealy TJ, Pauson PL (1951). "A New Type of Organo-Iron Compound".
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reactions as described below in the section on organic chemistry.
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reactions. A similar reagent but moistened induces hydrolysis or
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Sears JD, Muñoz SB, Cuenca MC, Brennessel WW, Neidig ML (2019).
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test. The affinity of iron(III) for phenols is exploited in the
2878: 2874: 2870: 2659: 2061: 1939: 1720: 1639:. The first three members of this series have the tetrahedral 1472: 1370: 1356:, they appear purple-red. Anhydrous iron(III) chloride has the 815: 605:
280 °C (536 °F; 553 K) (hexahydrate, decomposes)
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Oeste FD, de Richter R, Ming T, Caillol S (January 13, 2017).
4581: 3861: 2964: 2652: 1963: 1716: 1268:, while all forms are mild oxidizing agents. It is used as a 602:
316 °C (601 °F; 589 K) (anhydrous, decomposes)
316: 214: 192: 3764: 3709:. Vol. 22. John Wiley & Sons, Inc. pp. 86–89. 3431:
Flynn CM (1984). "Hydrolysis of Inorganic Iron(III) Salts".
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Iron(III) chloride is a component of useful stains, such as
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salts react rapidly with aqueous iron(III) chloride to give
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H. Lux (1963). "Iron (III) Chloride". In G. Brauer (ed.).
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Although iron(III) chlorides are seldom used in practical
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of a tricationic metal. Iron aquo complexes are prone to
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Fe(III) centres interconnected by two-coordinate chloride
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Bradley DC, Mehrotra RC, Rothwell I, et al. (2001).
3595: 3006:, and must be handled using proper protective equipment. 2702: 1016: 990: 5955: 3862:
Furniss BS, Hannaford AJ, Smith PW, et al. (1989).
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P. Kovacic and N. O. Brace (1960). "Iron(II) Chloride".
2764:, which is mainly used for the industrial production of 1149:α = 90°, β = 90°, γ = 120° 777: 5556: 4969:. A Macmillan chemistry text. London: Macmillan Press. 4960:(7th ed.). Rahway, New Jersey, US: Merck & Co. 2400:. Such studies may be relevant to the mechanism of FeCl 587:
307.6 °C (585.7 °F; 580.8 K) (anhydrous)
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White AD (2001). "Iron(III) Chloride-Sodium Hydride".
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naturally occurs as a trace mineral. The rare mineral
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In complementary route, iron metal can be oxidized by
4955: 4941:(71st ed.). Ann Arbor, Michigan, US: CRC Press. 4333: 3460: 3146:, New Zealand Environmental Risk Management Authority 3128:
National Institute for Occupational Safety and Health
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The interaction of anhydrous iron(III) chloride with
4310: 3552:. Vol. 2. NY, NY: Academic Press. p. 1492. 3205: 2908:
with many applications. Also, it is used to prepare
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In the largest application iron(III) chloride is in
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Fe center. Four hydrates have been characterized by
1279: 4851: 4311:Harris P, Hartman R, Hartman J (November 1, 2002). 3550:
Handbook of Preparative Inorganic Chemistry, 2nd Ed
2794:. In this role, its function is similar to that of 1938:d electronic configuration iron(III) chlorides are 1731:. In these complexes, the iron is pentacoordinate. 1471:, reflecting the relative location of the chloride 1232:describes the inorganic compounds with the formula 4631:White AD (2001). "Iron(III) Chloride-Silica Gel". 4221: 3483:Zeitschrift für anorganische und allgemeine Chemie 3392:"Crystal Structure of Ferric Chloride Hexahydrate" 2623:Iron(III) chloride is also used to remove soluble 781: 589:37 °C (99 °F; 310 K) (hexahydrate) 4956:Stecher PG, Finkel MJ, Siegmund OH, eds. (1960). 4180: 3670:White AD, Gallou F (2006). "Iron(III) Chloride". 3631: 3143:HSNO Chemical Classification Information Database 2838:, the anhydrous salt has been applied to certain 7817: 3509: 3245: 3185:, Japanese GHS Inter-ministerial Committee, 2006 304: 4664:White AD (2001). "Iron(III) Chloride-Alumina". 4511: 4360: 4161:"Phosphorus Treatment and Removal Technologies" 3865:Vogel's Textbook of Practical Organic Chemistry 3277: 3166:, collated by the Baylor College of Dentistry, 2854:, ferric chloride has been shown to accelerate 2810:, they have received considerable attention as 2798:. In some cases, mixtures of the two are used. 2430:reacts with iron(III) chloride to give lithium 1663:A brown, acidic solution of iron(III) chloride. 890: 177: 169: 161: 154: 4699:Encyclopedia of Reagents for Organic Synthesis 4666:Encyclopedia of Reagents for Organic Synthesis 4633:Encyclopedia of Reagents for Organic Synthesis 4538: 4512:Louis F. Fieser (1937). "1,2-Naphthoquinone". 4430:Ullmann's Encyclopedia of Industrial Chemistry 4336:"A message about mirror coating and recoating" 4011: 3672:Encyclopedia of Reagents for Organic Synthesis 3365:Holleman AF, Wiberg E (2001). Wiberg N (ed.). 3364: 3334:Ullmann's Encyclopedia of Industrial Chemistry 2830:Several reagents have been developed based on 859: 6129: 5037: 4484: 4284: 2967:are hypothesized to contain approximately 1% 2801: 2642: 2119:, has been crystallized from ether solution. 4894: 4387:Scott D, Schwab R (2019). "3.1.4. Etching". 3627: 3625: 3327: 3325: 3323: 3321: 3319: 3317: 3315: 3313: 3311: 3309: 3250:(4th ed.). Prentice Hall. p. 747. 2573:where ferrocene is emblematic of the field. 4733:Histotechnology – A Self-Instructional Text 4386: 4115: 4048: 3669: 2986:Iron(III) chlorides are widely used in the 2376: 6136: 6122: 5044: 5030: 5002: 4087: 2714:. Color code: Cl=green,Fe = blue, O = red. 408: 264: 242: 4836: 4607: 4198: 3987: 3934: 3773:. San Diego: Academic Press. p. 69. 3622: 3543: 3541: 3539: 3494: 3415: 3306: 3273: 3271: 3269: 3267: 355: 347: 340: 4964: 3930: 3928: 3801: 3771:Alkoxo and aryloxo derivatives of metals 3461:Spandl J, Kusserow M, Brüdgam I (2003). 3122:NIOSH Pocket Guide to Chemical Hazards. 2701: 1658: 1283: 4845: 4790:International Mineralogical Association 4744:– via The Visible Mouse Project, 4723: 4462:"Toxic Substances – 1,2-Dichloroethane" 4391:. Cultural Heritage Science. Springer. 3665: 3663: 3661: 3659: 3657: 3456: 3454: 2412:as the alkylation agent, salts of Fe(CH 404: 14: 7818: 6166: 6144:Salts and covalent derivatives of the 4958:The Merck Index of Chemicals and Drugs 4224:Separation and Purification Technology 4097:(2001). "Ferrocene—how it all began". 4093: 3767:"3.2.10. Alkoxides of later 3d metals" 3547: 3536: 3264: 3090: 3059: 255: 7466: 6117: 5025: 4983: 4938:CRC Handbook of Chemistry and Physics 4696: 4663: 4630: 3925: 3430: 3201: 3199: 3094:CRC Handbook of Chemistry and Physics 3063:CRC Handbook of Chemistry and Physics 3055: 3053: 3051: 3049: 3047: 3045: 2915: 2865:, iron(III) chloride gives a hydride 2662:according to the following equation: 2197:A traditional synthesis of anhydrous 453:Key: RBTARNINKXHZNM-UHFFFAOYSA-K 436:Key: RBTARNINKXHZNM-UHFFFAOYSA-K 222: 4934: 4389:Metallography in Archaeology and Art 4361:CoinValueLookup (13 December 2023). 3654: 3451: 3389: 3210:crystal using a thin plate sample". 2697: 2122:Iron(III) chloride also reacts with 4778: 4100:Journal of Organometallic Chemistry 2788:electrophilic aromatic substitution 1394:. This dimer dissociates into the 446:Key: RBTARNINKXHZNM-DFZHHIFOAF 295: 24: 5051: 4928: 4168:Minnesota Pollution Control Agency 3600:. Vol. 29. pp. 108–111. 3567:. Vol. 28. pp. 321–323. 3196: 3042: 2887: 2581: 2517:Cyclopentadienyl magnesium bromide 1950: 1743:, uses scrap iron as a precursor: 886: 443:InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3 433:InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3 87: 78: 56: 44: 25: 7867: 5003:Reich HJ, Rigby HJ, eds. (1999). 4181:Prathna TC, Srivastava A (2021). 3833:. Vol. 6. pp. 172–173. 3744:. Springer Science. p. 481. 3632:Greenwood NN, Earnshaw A (1997). 3514:. Vol. 3. pp. 191–194. 3479:)4]2[Fe6OCl6(OMe)12]" 3280:Journal of Coordination Chemistry 3246:Housecroft CE, Sharpe AG (2012). 3097:(92nd ed.). Boca Raton, FL: 3066:(92nd ed.). Boca Raton, FL: 2278: 1981:at 350 °C it reacts to give 1292:All forms of ferric chloride are 1280:Electronic and optical properties 624:g/L (anhydrous or hexahydrate, 25 3741:The Chemistry of Metal Alkoxides 3182:GHS classification – ID 831 1264:. The anhydrous derivative is a 1195: 747: 742: 4888: 4841:– via esd.copernicus.org. 4804: 4752: 4690: 4657: 4624: 4575: 4532: 4505: 4478: 4454: 4421: 4380: 4354: 4327: 4304: 4278: 4242: 4215: 4174: 4153: 4042: 4005: 3955: 3890: 3855: 3822: 3795: 3758: 3731: 3696: 3589: 3556: 3503: 3424: 3396:The Journal of Chemical Physics 3383: 3358: 2726:, forming ethylene dichloride ( 2616:), also formulated as FeO(OH) ( 2601:is treated with base to form a 2126:to give the yellow salt of the 2060:Iron(III) chloride forms a 1:2 1458:. This cation can adopt either 1308:, in addition to violating the 1191:(at 25 °C , 100 kPa). 4986:Structural Inorganic Chemistry 3239: 3173: 3157: 3134: 3115: 3084: 3016: 1734: 1535:. The structural formulas are 1519:, and finally the hexahydrate 1260:. They feature iron in its +3 52:Iron(III) chloride (anhydrous) 13: 1: 4438:10.1002/14356007.o06_o01.pub2 4334:Mike Lockwood, Carl Zambuto. 4187:Water Practice and Technology 4109:10.1016/S0022-328X(01)01126-3 3937:Inorganic Chemistry Frontiers 3911:10.1016/S0196-0644(95)70082-X 3680:10.1002/047084289X.ri054.pub2 3369:. San Diego: Academic Press. 3292:10.1080/00958972.2018.1519188 3036: 943:(US health exposure limits): 4584:"Carbonyl–Olefin Metathesis" 4287:"Safer Printmaking—Intaglio" 4236:10.1016/j.seppur.2006.02.013 3899:Annals of Emergency Medicine 3002:aqueous solution, is highly 2895: 2165:In addition to these simple 2142:). Similarly, combining FeCl 2011:react to give the iron(III) 1942:, meaning that its Cl- and H 1929: 1343: 1335: 64:Iron(III) chloride (hydrate) 7: 4898:Planetary and Space Science 4600:10.1021/acs.chemrev.0c01096 4553:10.1021/acs.chemrev.8b00773 4340:Lockwood Custom Optics, Inc 2988:treatment of drinking water 2958:Atmospheric Methane Removal 2931:is usually associated with 2124:tetraethylammonium chloride 1804:followed by chlorination: 1723:of the general formula FeCl 1654: 1425: 74: 40: 10: 7872: 7468: 4291:University of Saskatchewan 3980:10.1016/j.poly.2018.10.041 3868:(5th ed.). New York: 3839:10.1002/9780470132371.ch54 3715:10.1002/9780470132531.ch17 3606:10.1002/9780470132609.ch26 3573:10.1002/9780470132593.ch80 3520:10.1002/9780470132340.ch51 2844:pinacol-type rearrangement 2802:Organic synthesis research 2643:Etching and metal cleaning 2095:. The related 1:2 complex 6168: 6153: 6095: 6064: 6043: 5956:Organoiron(III) compounds 5720: 5685: 5664: 5237: 5217: 5165: 5094: 5059: 5005:Acidic and Basic Reagents 4919:10.1016/j.pss.2006.04.019 4397:10.1007/978-3-030-11265-3 4313:"Etching Iron Meteorites" 4272:10.1016/j.ces.2005.01.047 4132:Akzo Nobel Base Chemicals 4124:Water Treatment Chemicals 3634:Chemistry of the Elements 3233:10.1107/S0021889888013913 2981: 2920:Like many metal halides, 2779:Illustrating it use as a 2760:Ethylene dichloride is a 2592:drinking water production 2509:iron(III) acetylacetonate 2507:To a significant extent, 2387:organomagnesium compounds 1185: 1075: 982: 937: 723: 718: 671:630 g/L (18 °C) 482: 462: 420: 138: 118: 106: 101: 73: 39: 5557:Organoiron(II) compounds 4707:10.1002/047084289X.ri060 4674:10.1002/047084289X.ri057 4641:10.1002/047084289X.ri059 4526:10.15227/orgsyn.017.0068 4342:. Lockwood Custom Optics 4036:10.1002/zaac.19723910302 3636:(2nd ed.). Oxford: 3471:)4], [Fe2Cl4(Ot 3467:)6], [Fe2Cl2(Ot 3342:10.1002/14356007.a14_591 3168:Texas A&M University 3009: 2834:iron(III) chloride. On 2571:organometallic chemistry 2406:cross-coupling reactions 2377:Organometallic chemistry 2146:with NaCl and KCl gives 2070:triphenylphosphine oxide 1533:water of crystallization 794:Precautionary statements 4911:2006P&SS...54.1352K 4002:and references therein. 3170:. (accessed 2010-09-19) 3091:Haynes WM, ed. (2011). 3060:Haynes WM, ed. (2011). 2576: 2410:methylmagnesium bromide 2352:and iron(II) chloride. 2325:, bind as well to give 1860:trimethylsilyl chloride 1715:are well-behaved. Both 1507:, the trisesquihydrate 1495:, the disesquihydrate 1041:Ruthenium(III) chloride 690:Magnetic susceptibility 379:2582 (aqueous solution) 7846:Deliquescent materials 7841:Coordination complexes 4786:"IMA list of Minerals" 4134:. 2007. Archived from 3496:10.1002/zaac.200300008 2892: 2715: 2689:printed circuit boards 1664: 1289: 1067:Polyaluminium chloride 1031:Manganese(II) chloride 897: 92: 83: 61: 49: 4935:Lide DR, ed. (1990). 4817:Earth System Dynamics 4736:. Chicago: ASCP Press 4023:Z. Anorg. Allg. Chem. 3638:Butterworth-Heinemann 3475:)2] und [N(n 3213:J. Appl. Crystallogr. 2906:histological fixative 2891: 2861:When pretreated with 2783:, iron(III) chloride 2705: 2647:It is also used as a 2327:carboxylate complexes 1662: 1481:X-ray crystallography 1430:Ferric chloride form 1287: 1174:Coordination geometry 896: 91: 82: 60: 48: 6103:Hemolithin (protein) 4905:(13–14): 1352–1359. 4838:10.5194/esd-8-1-2017 4200:10.2166/wpt.2020.111 2331:ferric chloride test 2201:is the reduction of 1809:Fe + 2 HCl → FeCl 879:(fire diamond) 714:(40% solution) 7831:Iron(III) compounds 4965:Nicholls D (1974). 4866:1981Natur.292..610K 4829:2017ESD.....8....1O 4547:(21): 11442–11509. 4499:10.1021/ja01340a043 4285:John David Graham. 4264:2006ChEnS..61..229D 4065:1951Natur.168.1039K 3831:Inorganic Syntheses 3816:10.1021/j100905a008 3706:Inorganic Syntheses 3598:Inorganic Syntheses 3565:Inorganic Syntheses 3512:Inorganic Syntheses 3445:10.1021/cr00059a003 3408:1967JChPh..47..990L 3367:Inorganic Chemistry 3248:Inorganic Chemistry 3225:1989JApCr..22..173H 2819:are polymerized to 2685:copper(II) chloride 2629:Iron(III) phosphate 2607:iron(III) hydroxide 2350:copper(II) chloride 1741:direct chlorination 1692:, the formation of 1134: = 0.6065 1126: = 0.6065 1036:Cobalt(II) chloride 615:Solubility in water 525:g/mol (hexahydrate) 352: (hexahydrate) 166: (hexahydrate) 36: 35:Iron(III) chloride 7851:Dehydrating agents 3949:10.1039/C5QI00295H 2916:Natural occurrence 2893: 2796:aluminium chloride 2762:commodity chemical 2728:1,2-dichloroethane 2716: 2671:+ Cu → 2 FeCl 2432:tetrachloroferrate 2346:copper(I) chloride 2178:comproportionation 2128:tetrachloroferrate 2013:alkoxide complexes 1665: 1641:tetrachloroferrate 1412:molecular symmetry 1392:aluminium chloride 1290: 1230:Iron(III) chloride 1218:Infobox references 1142: = 1.742 1000:Iron(III) fluoride 983:Related compounds 898: 574:g/cm (hexahydrate) 182: (3.5hydrate) 111:Iron(III) chloride 93: 84: 62: 50: 34: 29:Inorganic compound 7813: 7812: 7807: 7806: 6111: 6110: 6039: 6038: 5660: 5659: 5213: 5212: 4984:Wells AF (1984). 4860:(5824): 610–613. 4594:(15): 9359–9406. 4514:Organic Syntheses 4432:. pp. 1–81. 4406:978-3-030-11265-3 4315:. Meteorite Times 4141:on 13 August 2010 4073:10.1038/1681039b0 3417:10.1063/1.1712067 3376:978-0-12-352651-9 3286:(21): 3415–3443. 3257:978-0-273-74275-3 3164:Various suppliers 3101:. p. 4.133. 2950:hydrochloric acid 2902:Carnoy's solution 2825:coupling reaction 2808:organic synthesis 2706:Structure of FeCl 2698:Organic chemistry 2627:from wastewater. 2398:alkylating agents 2339:Trinder spot test 2333:is a traditional 1802:hydrochloric acid 1442:with the formula 1416:iron(II) chloride 1354:transmitted light 1226:Chemical compound 1224: 1223: 1083:Crystal structure 1026:Iron(II) chloride 1005:Iron(III) bromide 966:Safety data sheet 772:Hazard statements 518:g/mol (anhydrous) 389:CompTox Dashboard 360: (dihydrate) 204:Interactive image 174: (dihydrate) 97: 96: 69: 68: 16:(Redirected from 7863: 7763: 6157: 6156: 6138: 6131: 6124: 6115: 6114: 6056: 6031: 6030: 6029: 6021: 6020: 6012: 6011: 5953: 5952: 5554: 5553: 5179: 5178: 5046: 5039: 5032: 5023: 5022: 5018: 4999: 4980: 4961: 4952: 4923: 4922: 4892: 4886: 4885: 4874:10.1038/292610a0 4849: 4843: 4842: 4840: 4808: 4802: 4801: 4799: 4797: 4782: 4776: 4775: 4773: 4771: 4756: 4750: 4749: 4743: 4741: 4727: 4721: 4720: 4694: 4688: 4687: 4661: 4655: 4654: 4628: 4622: 4621: 4611: 4588:Chemical Reviews 4579: 4573: 4572: 4541:Chemical Reviews 4536: 4530: 4529: 4509: 4503: 4502: 4487:J. Am. Chem. Soc 4482: 4476: 4475: 4473: 4472: 4458: 4452: 4451: 4425: 4419: 4418: 4384: 4378: 4377: 4375: 4373: 4358: 4352: 4351: 4349: 4347: 4331: 4325: 4324: 4322: 4320: 4308: 4302: 4301: 4299: 4297: 4282: 4276: 4275: 4246: 4240: 4239: 4219: 4213: 4212: 4202: 4178: 4172: 4171: 4165: 4157: 4151: 4150: 4148: 4146: 4140: 4129: 4119: 4113: 4112: 4103:. 637–639: 3–6. 4091: 4085: 4084: 4046: 4040: 4039: 4009: 4003: 4001: 3991: 3959: 3953: 3952: 3932: 3923: 3922: 3894: 3888: 3887: 3859: 3853: 3852: 3826: 3820: 3819: 3810:(9): 1505–1511. 3799: 3793: 3792: 3762: 3756: 3755: 3735: 3729: 3728: 3700: 3694: 3693: 3667: 3652: 3651: 3640:. p. 1084. 3629: 3620: 3619: 3593: 3587: 3586: 3560: 3554: 3553: 3545: 3534: 3533: 3507: 3501: 3500: 3498: 3458: 3449: 3448: 3433:Chemical Reviews 3428: 3422: 3421: 3419: 3390:Lind MD (1967). 3387: 3381: 3380: 3362: 3356: 3355: 3329: 3304: 3303: 3275: 3262: 3261: 3243: 3237: 3236: 3203: 3194: 3193: 3192: 3190: 3177: 3171: 3161: 3155: 3154: 3153: 3151: 3138: 3132: 3131: 3119: 3113: 3112: 3088: 3082: 3081: 3070:. p. 4.69. 3057: 3030: 3028: 3020: 3001: 2973: 2947: 2926: 2910:Verhoeff's stain 2885:, respectively. 2756: 2679: 2637:hydrogen sulfide 2615: 2600: 2588:sewage treatment 2565: 2503: 2475: 2445: 2429: 2369: 2308: 2271: 2252:ferrous chloride 2246: 2199:ferrous chloride 2193: 2162:, respectively. 2161: 2153: 2141: 2118: 2094: 2056: 2021: 2003: 1983:iron oxychloride 1925: 1900: 1856:thionyl chloride 1852:iron oxychloride 1845: 1817: 1796: 1756: 1701:molecular weight 1682: 1650: 1638: 1614: 1586: 1558: 1530: 1518: 1506: 1494: 1483:: the dihydrate 1457: 1403: 1389: 1365:structure, with 1363: 1331: 1320:, which contain 1243: 1208: 1202: 1199: 1198: 1145: 1137: 1129: 1117:Lattice constant 1109: 1062:Iron(II) sulfate 978: 959: 918: 911: 904: 889: 869: 865: 861: 857: 853: 849: 845: 841: 837: 833: 829: 825: 821: 817: 813: 809: 805: 801: 787: 783: 779: 751: 746: 699: 668: 627: 623: 573: 567:g/cm (anhydrous) 566: 524: 517: 500: 490:Chemical formula 413: 412: 397: 395: 376:1773 (anhydrous) 359: 351: 344: 308: 297: 276: 268: 257: 246: 226: 206: 181: 173: 165: 158: 113:Iron trichloride 75: 41: 37: 33: 21: 7871: 7870: 7866: 7865: 7864: 7862: 7861: 7860: 7816: 7815: 7814: 7809: 7808: 7802: 7794: 7786: 7778: 7773: 7771: 7762: 7758: 7756: 7754: 7746: 7738: 7730: 7725: 7723: 7715: 7707: 7699: 7694: 7692: 7687: 7685: 7680: 7678: 7670: 7665: 7663: 7655: 7650: 7648: 7640: 7627: 7622: 7620: 7612: 7607: 7605: 7597: 7589: 7581: 7576: 7574: 7566: 7558: 7550: 7545: 7543: 7535: 7530: 7528: 7520: 7512: 7507: 7505: 7497: 7489: 7481: 7427: 7419: 7415: 7407: 7399: 7391: 7380: 7357: 7352: 7350: 7342: 7334: 7329: 7327: 7319: 7314: 7307: 7302: 7300: 7296: 7288: 7283: 7281: 7276: 7269: 7264: 7262: 7254: 7249: 7247: 7242: 7240: 7232: 7227: 7225: 7220: 7218: 7213: 7211: 7203: 7198: 7196: 7191: 7189: 7184: 7182: 7174: 7169: 7167: 7162: 7160: 7155: 7153: 7148: 7146: 7138: 7133: 7131: 7126: 7124: 7116: 7108: 7097: 7082: 7077: 7075: 7070: 7063: 7058: 7051: 7046: 7044: 7039: 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5141: 5137: 5129: 5125: 5117: 5113: 5105: 5090: 5086: 5082: 5074: 5070: 5055: 5050: 5015: 4996: 4977: 4949: 4931: 4929:Further reading 4926: 4893: 4889: 4850: 4846: 4809: 4805: 4795: 4793: 4792:. 21 March 2011 4784: 4783: 4779: 4769: 4767: 4758: 4757: 4753: 4739: 4737: 4728: 4724: 4717: 4695: 4691: 4684: 4662: 4658: 4651: 4629: 4625: 4580: 4576: 4537: 4533: 4510: 4506: 4483: 4479: 4470: 4468: 4460: 4459: 4455: 4448: 4426: 4422: 4407: 4385: 4381: 4371: 4369: 4367:CoinValueLookup 4359: 4355: 4345: 4343: 4332: 4328: 4318: 4316: 4309: 4305: 4295: 4293: 4283: 4279: 4252:Chem. Eng. Sci. 4247: 4243: 4220: 4216: 4179: 4175: 4163: 4159: 4158: 4154: 4144: 4142: 4138: 4127: 4121: 4120: 4116: 4092: 4088: 4047: 4043: 4019: 4015: 4010: 4006: 3960: 3956: 3933: 3926: 3895: 3891: 3884: 3860: 3856: 3849: 3827: 3823: 3800: 3796: 3781: 3763: 3759: 3752: 3736: 3732: 3725: 3701: 3697: 3690: 3668: 3655: 3648: 3630: 3623: 3616: 3594: 3590: 3583: 3561: 3557: 3546: 3537: 3530: 3508: 3504: 3459: 3452: 3429: 3425: 3388: 3384: 3377: 3363: 3359: 3352: 3330: 3307: 3276: 3265: 3258: 3244: 3240: 3209: 3204: 3197: 3188: 3186: 3179: 3178: 3174: 3162: 3158: 3149: 3147: 3140: 3139: 3135: 3120: 3116: 3109: 3089: 3085: 3078: 3058: 3043: 3039: 3034: 3033: 3027: 3023: 3021: 3017: 3012: 3000: 2991: 2984: 2972: 2968: 2946: 2942: 2925: 2921: 2918: 2898: 2804: 2754: 2750: 2746: 2742: 2738: 2734: 2713: 2709: 2700: 2678: 2674: 2670: 2666: 2645: 2614: 2610: 2599: 2595: 2584: 2582:Water treatment 2579: 2563: 2559: 2555: 2551: 2547: 2543: 2539: 2535: 2531: 2527: 2514: 2502: 2498: 2494: 2490: 2486: 2482: 2478: 2474: 2470: 2466: 2462: 2458: 2454: 2450: 2443: 2439: 2435: 2428: 2424: 2419: 2415: 2403: 2392: 2379: 2368: 2364: 2360: 2356: 2317:sources, e.g., 2306: 2302: 2298: 2294: 2284: 2282: 2270: 2266: 2262: 2258: 2244: 2240: 2236: 2232: 2228: 2224: 2220: 2216: 2206: 2192: 2188: 2184: 2159: 2155: 2151: 2147: 2145: 2139: 2135: 2131: 2116: 2112: 2108: 2104: 2100: 2096: 2093: 2089: 2085: 2081: 2077: 2073: 2054: 2050: 2046: 2042: 2038: 2034: 2030: 2024:sodium ethoxide 2020: 2016: 2001: 1997: 1993: 1989: 1979:iron(III) oxide 1975:hard Lewis acid 1964:oxidizing agent 1956: 1954: 1945: 1932: 1923: 1919: 1915: 1911: 1907: 1903: 1898: 1894: 1890: 1886: 1882: 1878: 1874: 1870: 1866: 1844: 1840: 1836: 1832: 1828: 1824: 1820: 1816: 1812: 1808: 1795: 1791: 1787: 1783: 1779: 1775: 1771: 1755: 1751: 1747: 1737: 1730: 1726: 1713:tetrahydrofuran 1680: 1676: 1672: 1668: 1657: 1648: 1644: 1636: 1632: 1628: 1624: 1616: 1612: 1608: 1604: 1600: 1596: 1588: 1584: 1580: 1576: 1572: 1568: 1560: 1556: 1552: 1548: 1544: 1536: 1528: 1524: 1520: 1516: 1512: 1508: 1504: 1500: 1496: 1492: 1488: 1484: 1469:stereochemistry 1455: 1451: 1447: 1443: 1428: 1407: 1402: 1398: 1388: 1384: 1380: 1362: 1358: 1346: 1338: 1329: 1325: 1321: 1282: 1262:oxidation state 1254:ferric chloride 1251: 1247: 1242: 1233: 1227: 1220: 1215: 1214: 1213:  ?) 1204: 1200: 1196: 1192: 1176: 1164: 1150: 1147: 1143: 1135: 1127: 1119: 1107: 1103: 1085: 1071: 1055: 1045: 1019: 1009: 993: 974: 957: 953: 923: 922: 921: 920: 913: 906: 899: 895: 887: 796: 774: 760: 739: 697: 693: 683: 666: 660: 625: 621: 617: 608: 588: 577: 571: 564: 528: 522: 515: 499: 495: 492: 478: 475: 470: 469: 458: 455: 454: 448: 447: 444: 438: 437: 434: 428: 427: 416: 398: 391: 382: 363: 327: 311: 298: 286: 249: 229: 209: 196: 185: 148: 134: 133: 124:Ferric chloride 114: 112: 65: 53: 30: 23: 22: 18:Ferric chloride 15: 12: 11: 5: 7869: 7859: 7858: 7856:Acid catalysts 7853: 7848: 7843: 7838: 7833: 7828: 7811: 7810: 7805: 7804: 7800: 7796: 7792: 7788: 7784: 7780: 7776: 7769: 7765: 7760: 7752: 7748: 7744: 7740: 7736: 7732: 7728: 7721: 7717: 7713: 7709: 7705: 7701: 7697: 7690: 7683: 7676: 7672: 7668: 7661: 7657: 7653: 7646: 7642: 7638: 7634: 7630: 7629: 7625: 7618: 7614: 7610: 7603: 7599: 7595: 7591: 7587: 7583: 7579: 7572: 7568: 7564: 7560: 7556: 7552: 7548: 7541: 7537: 7533: 7526: 7522: 7518: 7514: 7510: 7503: 7499: 7495: 7491: 7487: 7483: 7479: 7475: 7471: 7470: 7467: 7464: 7463: 7460: 7457: 7454: 7451: 7448: 7445: 7442: 7439: 7436: 7433: 7430: 7425: 7421: 7417: 7413: 7409: 7405: 7401: 7397: 7393: 7389: 7385: 7382: 7378: 7374: 7368: 7367: 7364: 7359: 7355: 7348: 7344: 7340: 7336: 7332: 7325: 7321: 7317: 7309: 7305: 7298: 7294: 7290: 7286: 7279: 7271: 7267: 7260: 7256: 7252: 7245: 7238: 7234: 7230: 7223: 7216: 7209: 7205: 7201: 7194: 7187: 7180: 7176: 7172: 7165: 7158: 7151: 7144: 7140: 7136: 7129: 7122: 7118: 7114: 7110: 7106: 7102: 7099: 7095: 7091: 7085: 7084: 7080: 7073: 7065: 7061: 7053: 7049: 7042: 7035: 7031: 7027: 7023: 7016: 7012: 7008: 7001: 6997: 6993: 6986: 6978: 6974: 6970: 6965: 6961: 6957: 6953: 6949: 6945: 6938: 6931: 6927: 6923: 6916: 6912: 6908: 6901: 6894: 6887: 6880: 6876: 6872: 6865: 6858: 6854: 6850: 6843: 6836: 6832: 6828: 6824: 6822: 6818: 6814: 6808: 6807: 6804: 6799: 6795: 6788: 6781: 6777: 6773: 6765: 6758: 6754: 6750: 6743: 6739: 6735: 6727: 6723: 6719: 6715: 6707: 6703: 6699: 6695: 6688: 6684: 6680: 6673: 6669: 6665: 6658: 6654: 6650: 6643: 6636: 6632: 6628: 6621: 6614: 6607: 6603: 6599: 6592: 6585: 6581: 6577: 6573: 6571: 6567: 6559: 6553: 6552: 6549: 6545: 6541: 6537: 6530: 6523: 6516: 6512: 6508: 6500: 6493: 6486: 6482: 6478: 6474: 6467: 6463: 6456: 6452: 6448: 6444: 6436: 6432: 6428: 6422: 6421: 6418: 6414: 6407: 6399: 6391: 6384: 6380: 6373: 6369: 6362: 6358: 6351: 6340: 6336: 6328: 6321: 6317: 6313: 6309: 6298: 6291: 6287: 6283: 6272: 6265: 6261: 6254: 6250: 6243: 6239: 6235: 6231: 6224: 6220: 6213: 6206: 6202: 6195: 6191: 6187: 6183: 6179: 6173: 6172: 6169: 6167: 6165: 6163: 6155: 6154: 6151: 6150: 6141: 6140: 6133: 6126: 6118: 6109: 6108: 6106: 6105: 6099: 6097: 6093: 6092: 6090: 6089: 6085: 6081: 6077: 6073: 6068: 6066: 6062: 6061: 6059: 6058: 6053: 6047: 6045: 6041: 6040: 6037: 6036: 6034: 6033: 6026: 6017: 6008: 6000: 5996: 5992: 5988: 5984: 5980: 5976: 5972: 5968: 5964: 5959: 5957: 5950: 5949: 5944: 5940: 5936: 5932: 5928: 5924: 5920: 5916: 5912: 5908: 5904: 5900: 5896: 5892: 5888: 5884: 5880: 5876: 5872: 5868: 5864: 5860: 5856: 5852: 5848: 5844: 5840: 5836: 5832: 5828: 5824: 5820: 5816: 5812: 5808: 5804: 5800: 5796: 5791: 5787: 5782: 5778: 5774: 5770: 5766: 5762: 5757: 5753: 5749: 5745: 5741: 5737: 5733: 5729: 5724: 5722: 5718: 5717: 5715: 5714: 5710: 5706: 5702: 5698: 5694: 5689: 5687: 5683: 5682: 5680: 5679: 5674: 5668: 5666: 5662: 5661: 5658: 5657: 5655: 5654: 5650: 5646: 5642: 5638: 5634: 5630: 5626: 5622: 5618: 5614: 5610: 5606: 5602: 5598: 5594: 5589: 5585: 5581: 5577: 5573: 5569: 5565: 5560: 5558: 5551: 5550: 5546: 5542: 5538: 5534: 5530: 5526: 5522: 5518: 5514: 5510: 5506: 5502: 5498: 5494: 5490: 5486: 5482: 5478: 5474: 5470: 5466: 5462: 5458: 5454: 5450: 5446: 5442: 5438: 5434: 5430: 5426: 5422: 5418: 5414: 5410: 5406: 5402: 5398: 5394: 5390: 5386: 5382: 5378: 5374: 5370: 5366: 5362: 5357: 5352: 5348: 5344: 5340: 5336: 5332: 5328: 5324: 5319: 5315: 5311: 5306: 5302: 5298: 5294: 5290: 5286: 5282: 5278: 5274: 5270: 5266: 5262: 5258: 5254: 5250: 5246: 5241: 5239: 5235: 5234: 5232: 5231: 5226: 5221: 5219: 5215: 5214: 5211: 5210: 5208: 5204: 5200: 5196: 5192: 5188: 5186: 5176: 5175: 5169: 5167: 5163: 5162: 5160: 5159: 5155: 5151: 5147: 5143: 5139: 5135: 5131: 5127: 5123: 5119: 5115: 5111: 5107: 5103: 5098: 5096: 5092: 5091: 5089: 5088: 5084: 5080: 5076: 5072: 5068: 5063: 5061: 5057: 5056: 5053:Iron compounds 5049: 5048: 5041: 5034: 5026: 5020: 5019: 5013: 5000: 4994: 4981: 4975: 4962: 4953: 4947: 4930: 4927: 4925: 4924: 4887: 4844: 4803: 4777: 4751: 4722: 4715: 4689: 4682: 4656: 4649: 4623: 4574: 4531: 4504: 4493:(1): 290–294. 4477: 4453: 4446: 4420: 4405: 4379: 4353: 4326: 4303: 4277: 4258:(1): 229–245. 4241: 4230:(3): 332–337. 4214: 4173: 4152: 4114: 4086: 4059:(4285): 1040. 4041: 4030:(3): 193–202. 4017: 4013: 4004: 3954: 3943:(6): 766–790. 3924: 3905:(3): 330–333. 3889: 3882: 3854: 3847: 3821: 3794: 3779: 3757: 3750: 3730: 3723: 3695: 3688: 3653: 3646: 3621: 3614: 3588: 3581: 3555: 3535: 3528: 3502: 3489:(6): 968–974. 3450: 3423: 3402:(3): 990–993. 3382: 3375: 3357: 3350: 3305: 3263: 3256: 3238: 3219:(2): 173–180. 3207: 3195: 3172: 3156: 3133: 3114: 3107: 3083: 3076: 3040: 3038: 3035: 3032: 3031: 3025: 3014: 3013: 3011: 3008: 2998: 2983: 2980: 2970: 2963:The clouds of 2944: 2923: 2917: 2914: 2897: 2894: 2867:reducing agent 2863:sodium hydride 2850:reactions. On 2821:polythiophenes 2803: 2800: 2766:vinyl chloride 2758: 2757: 2752: 2748: 2744: 2740: 2736: 2711: 2710:(diethylether) 2707: 2699: 2696: 2681: 2680: 2676: 2672: 2668: 2644: 2641: 2612: 2597: 2583: 2580: 2578: 2575: 2567: 2566: 2561: 2557: 2553: 2549: 2545: 2541: 2537: 2533: 2529: 2512: 2505: 2504: 2500: 2496: 2492: 2488: 2484: 2480: 2476: 2472: 2468: 2464: 2460: 2456: 2452: 2441: 2437: 2426: 2422:methyl lithium 2417: 2413: 2401: 2390: 2378: 2375: 2371: 2370: 2366: 2362: 2358: 2304: 2300: 2296: 2283: 2280: 2277: 2273: 2272: 2268: 2264: 2260: 2248: 2247: 2242: 2238: 2234: 2230: 2226: 2222: 2218: 2204: 2195: 2194: 2190: 2186: 2167:stoichiometric 2157: 2149: 2143: 2137: 2133: 2114: 2110: 2109:, where Et = C 2106: 2102: 2098: 2091: 2087: 2083: 2079: 2075: 2058: 2057: 2052: 2048: 2044: 2040: 2036: 2032: 2018: 2005: 2004: 1999: 1995: 1991: 1955: 1952: 1951:Anhydrous FeCl 1949: 1943: 1931: 1928: 1927: 1926: 1921: 1917: 1913: 1909: 1905: 1901: 1896: 1892: 1888: 1884: 1880: 1876: 1872: 1868: 1847: 1846: 1842: 1838: 1834: 1830: 1826: 1822: 1818: 1814: 1810: 1798: 1797: 1793: 1789: 1785: 1781: 1780:+ 6 HCl + 9 H 1777: 1773: 1758: 1757: 1753: 1749: 1736: 1733: 1728: 1724: 1686:aquo complexes 1678: 1674: 1670: 1656: 1653: 1646: 1634: 1630: 1626: 1622: 1610: 1606: 1602: 1598: 1594: 1582: 1578: 1574: 1570: 1566: 1554: 1550: 1546: 1542: 1526: 1522: 1514: 1510: 1502: 1498: 1490: 1486: 1453: 1449: 1445: 1440:aquo complexes 1427: 1424: 1405: 1400: 1386: 1382: 1360: 1345: 1342: 1337: 1334: 1327: 1323: 1318:ferric nitrate 1314:ferric sulfate 1306:spin forbidden 1281: 1278: 1252:. Also called 1249: 1245: 1240: 1225: 1222: 1221: 1216: 1194: 1193: 1189:standard state 1186: 1183: 1182: 1177: 1172: 1169: 1168: 1165: 1155: 1152: 1151: 1148: 1122: 1120: 1115: 1112: 1111: 1104: 1099: 1096: 1095: 1086: 1081: 1078: 1077: 1073: 1072: 1070: 1069: 1064: 1058: 1056: 1050: 1047: 1046: 1044: 1043: 1038: 1033: 1028: 1022: 1020: 1014: 1011: 1010: 1008: 1007: 1002: 996: 994: 988: 985: 984: 980: 979: 969: 962: 961: 954: 948: 945: 944: 935: 934: 933:Non-flammable 931: 925: 924: 914: 907: 900: 885: 884: 883: 882: 880: 871: 870: 840:P305+P351+P338 832:P303+P361+P353 828:P301+P330+P331 797: 792: 789: 788: 775: 770: 767: 766: 761: 756: 753: 752: 740: 735: 732: 731: 721: 720: 716: 715: 708: 702: 701: 694: 688: 685: 684: 682: 681: 680:Highly soluble 678: 675: 674:Highly soluble 672: 669: 663: 661: 659: 658: 653: 648: 643: 637: 630: 629: 618: 613: 610: 609: 607: 606: 603: 599: 597: 591: 590: 585: 579: 578: 576: 575: 568: 560: 558: 552: 551: 545: 539: 538: 535: 531: 530: 529: 527: 526: 519: 511: 509: 503: 502: 497: 493: 488: 485: 484: 480: 479: 477: 476: 473: 465: 464: 463: 460: 459: 457: 456: 452: 451: 449: 445: 442: 441: 439: 435: 432: 431: 423: 422: 421: 418: 417: 415: 414: 401: 399: 387: 384: 383: 381: 380: 377: 373: 371: 365: 364: 362: 361: 353: 345: 337: 335: 329: 328: 326: 325: 321: 319: 313: 312: 310: 309: 301: 299: 291: 288: 287: 285: 284: 280: 278: 270: 269: 259: 251: 250: 248: 247: 239: 237: 231: 230: 228: 227: 219: 217: 211: 210: 208: 207: 199: 197: 190: 187: 186: 184: 183: 175: 167: 159: 151: 149: 144: 141: 140: 136: 135: 132: 131: 128: 125: 121: 120: 116: 115: 110: 104: 103: 99: 98: 95: 94: 85: 71: 70: 67: 66: 63: 54: 51: 28: 9: 6: 4: 3: 2: 7868: 7857: 7854: 7852: 7849: 7847: 7844: 7842: 7839: 7837: 7836:Metal halides 7834: 7832: 7829: 7827: 7824: 7823: 7821: 7803: 7797: 7795: 7789: 7787: 7781: 7779: 7772: 7766: 7764: 7755: 7749: 7747: 7741: 7739: 7733: 7731: 7724: 7718: 7716: 7710: 7708: 7702: 7700: 7693: 7686: 7679: 7673: 7671: 7664: 7658: 7656: 7649: 7643: 7641: 7635: 7632: 7631: 7628: 7621: 7615: 7613: 7606: 7600: 7598: 7592: 7590: 7584: 7582: 7575: 7569: 7567: 7561: 7559: 7553: 7551: 7544: 7538: 7536: 7529: 7523: 7521: 7515: 7513: 7506: 7500: 7498: 7492: 7490: 7484: 7482: 7476: 7473: 7472: 7465: 7461: 7458: 7455: 7452: 7449: 7446: 7443: 7440: 7437: 7434: 7431: 7429: 7422: 7420: 7410: 7408: 7402: 7400: 7394: 7392: 7386: 7383: 7381: 7375: 7373: 7370: 7369: 7365: 7363: 7360: 7358: 7351: 7345: 7343: 7337: 7335: 7328: 7322: 7320: 7313: 7310: 7308: 7301: 7291: 7289: 7282: 7275: 7272: 7270: 7263: 7257: 7255: 7248: 7241: 7235: 7233: 7226: 7219: 7212: 7206: 7204: 7197: 7190: 7183: 7177: 7175: 7168: 7161: 7154: 7147: 7141: 7139: 7132: 7125: 7119: 7117: 7111: 7109: 7103: 7100: 7098: 7092: 7090: 7087: 7086: 7083: 7076: 7069: 7066: 7064: 7057: 7054: 7052: 7045: 7038: 7028: 7026: 7019: 7013: 7011: 7004: 6998: 6996: 6989: 6982: 6979: 6977: 6971: 6969: 6966: 6964: 6958: 6956: 6950: 6948: 6941: 6934: 6928: 6926: 6919: 6913: 6911: 6904: 6897: 6890: 6883: 6877: 6875: 6868: 6861: 6855: 6853: 6846: 6839: 6833: 6831: 6825: 6823: 6821: 6815: 6813: 6810: 6809: 6805: 6803: 6800: 6798: 6791: 6784: 6774: 6772: 6768: 6761: 6755: 6753: 6746: 6740: 6738: 6731: 6728: 6726: 6720: 6718: 6711: 6708: 6706: 6700: 6698: 6691: 6685: 6683: 6676: 6670: 6668: 6661: 6655: 6653: 6646: 6639: 6633: 6631: 6624: 6617: 6610: 6604: 6602: 6595: 6588: 6582: 6580: 6574: 6572: 6570: 6563: 6560: 6558: 6555: 6554: 6550: 6548: 6542: 6540: 6533: 6526: 6519: 6509: 6507: 6503: 6496: 6489: 6479: 6477: 6470: 6459: 6449: 6447: 6440: 6437: 6435: 6429: 6427: 6424: 6423: 6419: 6417: 6410: 6403: 6400: 6398: 6394: 6387: 6376: 6365: 6354: 6347: 6343: 6332: 6324: 6314: 6312: 6305: 6301: 6294: 6288: 6286: 6279: 6275: 6268: 6257: 6246: 6236: 6234: 6227: 6216: 6209: 6198: 6188: 6186: 6180: 6178: 6175: 6174: 6170: 6164: 6162: 6159: 6158: 6152: 6147: 6139: 6134: 6132: 6127: 6125: 6120: 6119: 6116: 6104: 6101: 6100: 6098: 6094: 6088: 6082: 6080: 6070: 6069: 6067: 6063: 6057: 6049: 6048: 6046: 6042: 6032: 6001: 5999: 5981: 5979: 5961: 5960: 5958: 5954: 5948: 5929: 5927: 5917: 5915: 5901: 5899: 5889: 5887: 5873: 5871: 5861: 5859: 5841: 5839: 5825: 5823: 5805: 5803: 5797: 5795: 5792: 5790: 5788: 5786: 5783: 5781: 5775: 5773: 5763: 5761: 5758: 5756: 5750: 5748: 5742: 5740: 5734: 5732: 5726: 5725: 5723: 5719: 5713: 5703: 5701: 5691: 5690: 5688: 5684: 5678: 5675: 5673: 5670: 5669: 5667: 5663: 5653: 5639: 5637: 5623: 5621: 5595: 5593: 5578: 5576: 5562: 5561: 5559: 5555: 5549: 5539: 5537: 5523: 5521: 5507: 5505: 5487: 5485: 5467: 5465: 5455: 5453: 5447: 5445: 5439: 5437: 5431: 5429: 5419: 5417: 5407: 5405: 5399: 5397: 5383: 5381: 5371: 5369: 5363: 5361: 5358: 5356: 5333: 5331: 5325: 5323: 5320: 5318: 5312: 5310: 5307: 5305: 5299: 5297: 5291: 5289: 5279: 5277: 5271: 5269: 5263: 5261: 5251: 5249: 5243: 5242: 5240: 5236: 5230: 5223: 5222: 5220: 5216: 5207: 5189: 5187: 5185:(I) compounds 5184: 5180: 5174: 5171: 5170: 5168: 5164: 5158: 5132: 5130: 5120: 5118: 5108: 5106: 5100: 5099: 5097: 5093: 5087: 5077: 5075: 5065: 5064: 5062: 5058: 5054: 5047: 5042: 5040: 5035: 5033: 5028: 5027: 5024: 5016: 5014:9780471979258 5010: 5006: 5001: 4997: 4995:9780198553700 4991: 4987: 4982: 4978: 4976:9780333170885 4972: 4968: 4963: 4959: 4954: 4950: 4948:9780849304712 4944: 4940: 4939: 4933: 4932: 4920: 4916: 4912: 4908: 4904: 4900: 4899: 4891: 4883: 4879: 4875: 4871: 4867: 4863: 4859: 4855: 4848: 4839: 4834: 4830: 4826: 4822: 4818: 4814: 4807: 4791: 4787: 4781: 4765: 4761: 4755: 4747: 4735: 4734: 4726: 4718: 4712: 4708: 4704: 4700: 4693: 4685: 4679: 4675: 4671: 4667: 4660: 4652: 4646: 4642: 4638: 4634: 4627: 4619: 4615: 4610: 4605: 4601: 4597: 4593: 4589: 4585: 4578: 4570: 4566: 4562: 4558: 4554: 4550: 4546: 4542: 4535: 4527: 4523: 4519: 4515: 4508: 4500: 4496: 4492: 4488: 4481: 4467: 4463: 4457: 4449: 4447:9783527306732 4443: 4439: 4435: 4431: 4424: 4416: 4412: 4408: 4402: 4398: 4394: 4390: 4383: 4368: 4364: 4357: 4341: 4337: 4330: 4314: 4307: 4292: 4288: 4281: 4273: 4269: 4265: 4261: 4257: 4254: 4253: 4245: 4237: 4233: 4229: 4225: 4218: 4210: 4206: 4201: 4196: 4192: 4188: 4184: 4177: 4169: 4162: 4156: 4137: 4133: 4126: 4125: 4118: 4110: 4106: 4102: 4101: 4096: 4090: 4082: 4078: 4074: 4070: 4066: 4062: 4058: 4054: 4053: 4045: 4037: 4033: 4029: 4026:(in German). 4025: 4024: 4008: 3999: 3995: 3990: 3985: 3981: 3977: 3973: 3969: 3965: 3958: 3950: 3946: 3942: 3938: 3931: 3929: 3920: 3916: 3912: 3908: 3904: 3900: 3893: 3885: 3883:9780582462366 3879: 3875: 3871: 3867: 3866: 3858: 3850: 3848:9780470132371 3844: 3840: 3836: 3832: 3825: 3817: 3813: 3809: 3805: 3804:J. Phys. Chem 3798: 3790: 3786: 3782: 3780:9780121241407 3776: 3772: 3768: 3761: 3753: 3747: 3743: 3742: 3734: 3726: 3724:9780470132531 3720: 3716: 3712: 3708: 3707: 3699: 3691: 3685: 3681: 3677: 3673: 3666: 3664: 3662: 3660: 3658: 3649: 3647:9780750633659 3643: 3639: 3635: 3628: 3626: 3617: 3615:9780470132609 3611: 3607: 3603: 3599: 3592: 3584: 3582:9780470132593 3578: 3574: 3570: 3566: 3559: 3551: 3544: 3542: 3540: 3531: 3529:9780470131626 3525: 3521: 3517: 3513: 3506: 3497: 3492: 3488: 3484: 3480: 3478: 3474: 3470: 3466: 3457: 3455: 3446: 3442: 3438: 3434: 3427: 3418: 3413: 3409: 3405: 3401: 3397: 3393: 3386: 3378: 3372: 3368: 3361: 3353: 3347: 3343: 3339: 3335: 3328: 3326: 3324: 3322: 3320: 3318: 3316: 3314: 3312: 3310: 3301: 3297: 3293: 3289: 3285: 3281: 3274: 3272: 3270: 3268: 3259: 3253: 3249: 3242: 3234: 3230: 3226: 3222: 3218: 3215: 3214: 3202: 3200: 3184: 3183: 3176: 3169: 3165: 3160: 3145: 3144: 3137: 3129: 3125: 3118: 3110: 3108:1-4398-5511-0 3104: 3100: 3096: 3095: 3087: 3079: 3077:1-4398-5511-0 3073: 3069: 3065: 3064: 3056: 3054: 3052: 3050: 3048: 3046: 3041: 3019: 3015: 3007: 3005: 2997: 2994: 2989: 2979: 2977: 2976:sulfuric acid 2974:dissolved in 2966: 2961: 2959: 2955: 2951: 2940: 2938: 2934: 2930: 2913: 2911: 2907: 2903: 2890: 2886: 2884: 2880: 2876: 2872: 2869:that convert 2868: 2864: 2859: 2857: 2856:ene reactions 2853: 2849: 2848:epimerization 2845: 2841: 2837: 2833: 2828: 2826: 2822: 2818: 2813: 2809: 2799: 2797: 2793: 2792:chlorinations 2789: 2786: 2782: 2777: 2775: 2771: 2767: 2763: 2733: 2732: 2731: 2729: 2725: 2721: 2704: 2695: 2692: 2690: 2686: 2665: 2664: 2663: 2661: 2656: 2654: 2650: 2640: 2638: 2634: 2630: 2626: 2621: 2619: 2608: 2604: 2593: 2589: 2574: 2572: 2536:MgBr + FeCl 2526: 2525: 2524: 2522: 2518: 2510: 2477: 2463:+ Li[FeCl 2449: 2448: 2447: 2433: 2423: 2411: 2407: 2399: 2396: 2388: 2384: 2383:organolithium 2374: 2361:+ CuCl → FeCl 2355: 2354: 2353: 2351: 2347: 2342: 2340: 2336: 2332: 2328: 2324: 2320: 2316: 2312: 2292: 2287: 2279:Hydrated FeCl 2276: 2257: 2256: 2255: 2253: 2215: 2214: 2213: 2211: 2210:chlorobenzene 2207: 2200: 2189:+ Fe → 3 FeCl 2183: 2182: 2181: 2179: 2174: 2172: 2168: 2163: 2129: 2125: 2120: 2071: 2067: 2063: 2043:ONa → "Fe(OCH 2029: 2028: 2027: 2025: 2014: 2010: 2007:Alkali metal 1988: 1987: 1986: 1984: 1980: 1976: 1972: 1967: 1965: 1961: 1948: 1941: 1937: 1902: 1865: 1864: 1863: 1861: 1857: 1853: 1819: 1807: 1806: 1805: 1803: 1770: 1769: 1768: 1766: 1762: 1746: 1745: 1744: 1742: 1732: 1722: 1718: 1714: 1710: 1709:diethyl ether 1705: 1702: 1698: 1695: 1691: 1687: 1661: 1652: 1642: 1620: 1592: 1564: 1540: 1534: 1482: 1478: 1474: 1470: 1467: 1466: 1462: 1441: 1437: 1436:deliquescence 1433: 1423: 1421: 1417: 1413: 1410: 1397: 1393: 1379: 1374: 1372: 1368: 1364: 1355: 1351: 1341: 1333: 1319: 1315: 1311: 1307: 1303: 1299: 1295: 1286: 1277: 1275: 1271: 1270:water cleaner 1267: 1263: 1259: 1255: 1239: 1236: 1231: 1219: 1212: 1207: 1190: 1184: 1181: 1178: 1175: 1171: 1170: 1166: 1162: 1158: 1157:Formula units 1154: 1153: 1141: 1133: 1125: 1121: 1118: 1114: 1113: 1105: 1102: 1098: 1097: 1094: 1090: 1087: 1084: 1080: 1079: 1074: 1068: 1065: 1063: 1060: 1059: 1057: 1054: 1049: 1048: 1042: 1039: 1037: 1034: 1032: 1029: 1027: 1024: 1023: 1021: 1018: 1013: 1012: 1006: 1003: 1001: 998: 997: 995: 992: 987: 986: 981: 977: 973: 970: 967: 964: 963: 955: 952:(Recommended) 951: 947: 946: 942: 941: 936: 932: 930: 927: 926: 919: 912: 905: 881: 878: 877: 873: 872: 798: 795: 791: 790: 776: 773: 769: 768: 765: 762: 759: 755: 754: 750: 745: 741: 738: 734: 733: 729: 727: 722: 717: 713: 709: 707: 704: 703: 695: 691: 687: 686: 679: 676: 673: 670: 665: 664: 662: 657: 656:Diethyl ether 654: 652: 649: 647: 644: 642: 639: 638: 635: 632: 631: 619: 616: 612: 611: 604: 601: 600: 598: 596: 595:Boiling point 593: 592: 586: 584: 583:Melting point 581: 580: 569: 562: 561: 559: 557: 554: 553: 550: 546: 544: 541: 540: 536: 533: 532: 520: 513: 512: 510: 508: 505: 504: 494: 491: 487: 486: 481: 472: 471: 468: 461: 450: 440: 430: 429: 426: 419: 411: 407: 406:DTXSID8020622 403: 402: 400: 390: 386: 385: 378: 375: 374: 372: 370: 367: 366: 358: 354: 350: 346: 343: 339: 338: 336: 334: 331: 330: 323: 322: 320: 318: 315: 314: 307: 303: 302: 300: 294: 290: 289: 282: 281: 279: 277: 272: 271: 267: 263: 260: 258: 256:ECHA InfoCard 253: 252: 245: 241: 240: 238: 236: 233: 232: 225: 221: 220: 218: 216: 213: 212: 205: 201: 200: 198: 194: 189: 188: 180: 176: 172: 168: 164: 160: 157: 153: 152: 150: 147: 143: 142: 137: 130:Flores martis 129: 126: 123: 122: 117: 109: 105: 100: 90: 86: 81: 77: 76: 72: 59: 55: 47: 43: 42: 38: 32: 27: 19: 6678: 5743: 5004: 4985: 4966: 4957: 4936: 4902: 4896: 4890: 4857: 4853: 4847: 4820: 4816: 4806: 4794:. Retrieved 4789: 4780: 4768:. Retrieved 4763: 4754: 4738:. Retrieved 4732: 4725: 4698: 4692: 4665: 4659: 4632: 4626: 4591: 4587: 4577: 4544: 4540: 4534: 4517: 4513: 4507: 4490: 4486: 4480: 4469:. Retrieved 4465: 4456: 4429: 4423: 4388: 4382: 4370:. Retrieved 4366: 4356: 4344:. Retrieved 4339: 4329: 4317:. Retrieved 4306: 4294:. Retrieved 4290: 4280: 4255: 4250: 4244: 4227: 4223: 4217: 4193:(1): 35–41. 4190: 4186: 4176: 4170:. June 2006. 4155: 4143:. Retrieved 4136:the original 4123: 4117: 4098: 4089: 4056: 4050: 4044: 4027: 4021: 4007: 3971: 3967: 3957: 3940: 3936: 3902: 3898: 3892: 3864: 3857: 3830: 3824: 3807: 3803: 3797: 3770: 3760: 3740: 3733: 3704: 3698: 3671: 3633: 3597: 3591: 3564: 3558: 3549: 3511: 3505: 3486: 3482: 3476: 3472: 3468: 3464: 3436: 3432: 3426: 3399: 3395: 3385: 3366: 3360: 3333: 3283: 3279: 3247: 3241: 3216: 3211: 3187:, retrieved 3181: 3175: 3159: 3148:, retrieved 3142: 3136: 3117: 3092: 3086: 3061: 3018: 2985: 2962: 2941: 2928: 2919: 2899: 2860: 2829: 2805: 2778: 2759: 2717: 2693: 2683:The soluble 2682: 2657: 2646: 2622: 2618:ferrihydrite 2585: 2568: 2506: 2495:] + 0.5 CH 2467:] + 0.5 CH 2395:nucleophilic 2380: 2372: 2343: 2335:colorimetric 2311:ferrioxalate 2288: 2285: 2274: 2249: 2196: 2175: 2164: 2121: 2059: 2006: 1968: 1957: 1933: 1848: 1799: 1764: 1763: 1759: 1740: 1738: 1706: 1666: 1618: 1590: 1562: 1538: 1464: 1460: 1429: 1390:, much like 1375: 1347: 1339: 1310:Laporte rule 1294:paramagnetic 1291: 1276:for metals. 1253: 1229: 1228: 1160: 1139: 1131: 1123: 939: 875: 763: 725: 677:830 g/L 317:RTECS number 139:Identifiers 119:Other names 31: 26: 4823:(1): 1–54. 4319:October 14, 2840:dehydration 2772:for making 2564:+ 3 MgBrCl 2479:Li[FeCl 2404:-catalyzed 2315:carboxylate 2309:, known as 2229:Cl → 2 FeCl 2148:Na[FeCl 2136:N)[FeCl 2066:Lewis bases 1883:SiCl → FeCl 1784:O → 2 FeCl 1748:2 Fe + 3 Cl 1735:Preparation 1633:]Cl·2H 1409:point group 1258:hygroscopic 1101:Space group 929:Flash point 758:Signal word 534:Appearance 483:Properties 262:100.028.846 224:CHEBI:30808 108:IUPAC names 7820:Categories 5686:Fe(II,III) 5183:Organoiron 4796:5 February 4770:5 February 4764:mindat.org 4760:"Molysite" 4746:U.C. Davis 4716:0471936235 4683:0471936235 4650:0471936235 4471:2023-08-30 4372:5 February 4346:5 February 4296:5 February 3968:Polyhedron 3751:0306476576 3689:0471936235 3351:3527306730 3037:References 2836:silica gel 2817:thiophenes 2781:Lewis acid 2483:] + LiCH 2180:reaction: 2156:K[FeCl 2055:" + 3 NaCl 1960:Lewis acid 1912:O + 6 SOCl 1899:O + 12 HCl 1875:O + 12 (CH 1605:][FeCl 1577:][FeCl 1553:][FeCl 1513:·3.5H 1501:·2.5H 1477:octahedral 1367:octahedral 1272:and as an 1266:Lewis acid 1180:Octahedral 1110:, No. 148 1076:Structure 1053:coagulants 737:Pictograms 696:+13,450·10 634:Solubility 507:Molar mass 357:Y048945596 349:0I2XIN602U 342:U38V3ZVV3V 235:ChemSpider 191:3D model ( 179:64333-00-2 171:54862-84-9 163:10025-77-1 146:CAS Number 7826:Chlorides 6096:Purported 5665:Fe(0,III) 4740:2 January 4569:206542971 4415:201676001 4209:229396639 4095:Pauson PL 3974:: 91–96. 3789:162129468 3439:: 31–41. 3300:105925459 3099:CRC Press 3068:CRC Press 3004:corrosive 2937:fumaroles 2933:volcanoes 2896:Histology 2832:supported 2785:catalyses 2633:insoluble 2625:phosphate 2521:ferrocene 2491:[FeCl 2440:[FeCl 2295:[Fe(C 2171:catalyzed 2009:alkoxides 1971:oxophilic 1936:high spin 1930:Reactions 1833:O → FeCl 1719:form 1:2 1694:polymeric 1669:[FeCl 1651:) anion. 1645:[FeCl 1444:[FeCl 1396:monomeric 1350:anhydrous 1344:Anhydrous 1336:Structure 1322:[Fe(H 1302:high spin 1298:d-orbital 1089:Hexagonal 836:P304+P340 824:P301+P312 728:labelling 710:12 c 706:Viscosity 369:UN number 324:LJ9100000 283:231-729-4 275:EC Number 156:7705-08-0 6146:chloride 5995:⋅xFe⋅yNH 5777:Fe(acac) 5218:Fe(0,II) 4766:. Mindat 4618:34133136 4561:31580649 3998:31031511 3130:(NIOSH). 2929:molysite 2883:alcohols 2812:reagents 2724:chlorine 2720:ethylene 2649:leaching 2552:+ 1/n (C 2540:→ Fe(C 2348:to give 2323:tartrate 2313:. Other 2072:; e.g., 2068:such as 2002:→ 3FeOCl 1924:+ 12 HCl 1908:·6H 1887:+ 6 ((CH 1871:·6H 1825:+ 0.5 Cl 1752:→ 2 FeCl 1655:Solution 1609:]·H 1581:]·H 1525:·6H 1489:·2H 1432:hydrates 1426:Hydrates 1420:chlorine 1051:Related 876:NFPA 704 719:Hazards 692:(χ) 646:Methanol 474:Cl(Cl)Cl 127:Molysite 7469:  5794:FeO(OH) 5721:Fe(III) 5060:Fe(-II) 4907:Bibcode 4882:4369293 4862:Bibcode 4825:Bibcode 4609:9008594 4260:Bibcode 4081:4181383 4061:Bibcode 3989:6481957 3919:7661424 3870:Longman 3404:Bibcode 3221:Bibcode 3124:"#0346" 2954:methane 2879:alkanes 2875:ketones 2871:alkenes 2852:alumina 2815:3-Alkyl 2770:monomer 2691:(PCB). 2675:+ CuCl 2455:+ LiCH 2319:citrate 2291:oxalate 2263:→ 2FeCl 1962:and an 1765:Aqueous 1727:(ether) 1721:adducts 1690:olation 1475:on the 1473:ligands 1404:(with D 1371:ligands 1300:. The 1274:etchant 1211:what is 1209: ( 1017:cations 700:cm/mol 651:Ethanol 641:Acetone 556:Density 547:Slight 521:270.295 514:162.204 501: 293:PubChem 6065:Fe(VI) 6044:Fe(IV) 5649:Fe(CO) 5633:Fe(CO) 5314:Fe(OH) 5281:Fe(ClO 5238:Fe(II) 5134:Fe(CO) 5102:Fe(CO) 5083:Fe(CO) 5071:Fe(CO) 5011:  4992:  4973:  4945:  4880:  4854:Nature 4713:  4680:  4647:  4616:  4606:  4567:  4559:  4520:: 68. 4444:  4413:  4403:  4207:  4145:26 Oct 4079:  4052:Nature 3996:  3986:  3917:  3880:  3845:  3787:  3777:  3748:  3721:  3686:  3644:  3612:  3579:  3526:  3373:  3348:  3298:  3254:  3189:19 Sep 3150:19 Sep 3105:  3074:  2982:Safety 2768:, the 2747:→ ClCH 2667:2 FeCl 2660:copper 2611:Fe(OH) 2459:→ FeCl 2451:2 FeCl 2365:+ CuCl 2217:2 FeCl 2185:2 FeCl 2062:adduct 2035:+ 3 CH 1973:and a 1940:labile 1934:Being 1920:+ 6 SO 1916:→ FeCl 1829:+ 6 H 1717:ethers 1615:, and 1206:verify 1203:  1144:  1136:  1128:  1015:Other 991:anions 989:Other 968:(SDS) 958:  764:Danger 698:  667:  626:  622:  572:  565:  523:  516:  467:SMILES 102:Names 6084:BaFeO 5935:Fe(SO 5785:FeOCl 5765:Fe(NO 5588:)(CO) 5441:FeTiO 5433:FeMoO 5409:Fe(BF 5373:Fe(NO 5365:FeSeO 5343:Fe(SO 5199:FeCO) 5166:Fe(I) 5095:Fe(0) 4878:S2CID 4565:S2CID 4466:ATSDR 4411:S2CID 4205:S2CID 4164:(PDF) 4139:(PDF) 4128:(PDF) 4077:S2CID 3874:Wiley 3296:S2CID 3010:Notes 2965:Venus 2877:into 2722:with 2653:Elkem 2434:(II) 2259:2FeCl 2245:+ HCl 2208:with 2130:ion ( 2078:(OP(C 2064:with 1621:−FeCl 1619:trans 1617:[ 1593:−FeCl 1589:[ 1565:−FeCl 1561:[ 1541:−FeCl 1539:trans 1537:[ 1461:trans 1422:gas. 1378:dimer 960:mg/m 956:TWA 1 940:NIOSH 425:InChI 306:24380 244:22792 215:ChEBI 193:JSmol 7799:NoCl 7791:MdCl 7783:FmCl 7775:EsCl 7768:EsCl 7759:CfCl 7751:CfCl 7743:BkCl 7735:CmCl 7727:AmCl 7720:AmCl 7712:PuCl 7704:NpCl 7667:PaCl 7660:PaCl 7652:ThCl 7645:ThCl 7637:AcCl 7624:YbCl 7617:YbCl 7609:TmCl 7602:TmCl 7594:ErCl 7586:HoCl 7578:DyCl 7571:DyCl 7563:TbCl 7555:GdCl 7547:EuCl 7540:EuCl 7532:SmCl 7525:SmCl 7517:PmCl 7509:NdCl 7502:NdCl 7494:PrCl 7486:CeCl 7478:LaCl 7404:DbCl 7396:RfCl 7388:LrCl 7377:RaCl 7372:FrCl 7362:AtCl 7354:PoCl 7347:PoCl 7339:BiCl 7331:PbCl 7324:PbCl 7316:TlCl 7312:TlCl 7304:HgCl 7285:AuCl 7278:(Au) 7274:AuCl 7266:PtCl 7259:PtCl 7251:IrCl 7244:IrCl 7237:IrCl 7229:OsCl 7222:OsCl 7215:OsCl 7208:OsCl 7200:ReCl 7193:ReCl 7186:ReCl 7179:ReCl 7135:TaCl 7128:TaCl 7121:TaCl 7113:HfCl 7105:LuCl 7094:BaCl 7089:CsCl 7079:XeCl 7072:XeCl 7068:XeCl 7048:TeCl 7041:TeCl 7022:SbCl 7015:SbCl 7007:SnCl 7000:SnCl 6992:InCl 6985:InCl 6981:InCl 6973:CdCl 6968:AgCl 6960:PdCl 6952:RhCl 6944:RuCl 6937:RuCl 6930:RuCl 6922:TcCl 6915:TcCl 6907:MoCl 6900:MoCl 6893:MoCl 6886:MoCl 6879:MoCl 6871:NbCl 6864:NbCl 6857:NbCl 6849:ZrCl 6842:ZrCl 6835:ZrCl 6817:SrCl 6812:RbCl 6802:BrCl 6794:SeCl 6787:SeCl 6764:AsCl 6757:AsCl 6749:GeCl 6742:GeCl 6734:GaCl 6730:GaCl 6722:ZnCl 6714:CuCl 6710:CuCl 6702:NiCl 6694:CoCl 6687:CoCl 6679:FeCl 6672:FeCl 6664:MnCl 6657:MnCl 6649:CrCl 6642:CrCl 6635:CrCl 6598:TiCl 6591:TiCl 6584:TiCl 6576:ScCl 6566:CaCl 6562:CaCl 6473:SiCl 6443:AlCl 6439:AlCl 6431:MgCl 6426:NaCl 6182:BeCl 6177:LiCl 5963:Fe(C 5943:·12H 5919:Fe(N 5879:(SeO 5831:(CrO 5799:FePO 5744:FeCl 5736:FeBr 5677:FeGe 5672:FeSi 5597:Fe(C 5580:Fe(C 5564:Fe(C 5545:(CO) 5489:Fe(C 5469:Fe(C 5449:FeCO 5421:FeCr 5401:FeSi 5360:FeSe 5327:FeSO 5293:FeBr 5273:FeCl 5203:(CO) 5126:(CO) 5114:(CO) 5009:ISBN 4990:ISBN 4971:ISBN 4943:ISBN 4798:2024 4772:2024 4742:2013 4711:ISBN 4678:ISBN 4645:ISBN 4614:PMID 4557:PMID 4442:ISBN 4401:ISBN 4374:2024 4348:2024 4321:2016 4298:2024 4147:2007 4016:FeCl 3994:PMID 3915:PMID 3878:ISBN 3843:ISBN 3785:OCLC 3775:ISBN 3746:ISBN 3719:ISBN 3684:ISBN 3642:ISBN 3610:ISBN 3577:ISBN 3524:ISBN 3371:ISBN 3346:ISBN 3252:ISBN 3191:2010 3152:2010 3103:ISBN 3072:ISBN 3024:FeCl 2969:FeCl 2943:FeCl 2935:and 2922:FeCl 2904:, a 2881:and 2873:and 2842:and 2790:and 2743:+ Cl 2739:C=CH 2730:): 2603:floc 2596:FeCl 2590:and 2577:Uses 2487:→ Li 2425:LiCH 2385:and 2357:FeCl 2321:and 2267:+ Cl 2203:FeCl 2154:and 2101:(OEt 2097:FeCl 2074:FeCl 2031:FeCl 2022:and 2017:FeCl 1994:+ Fe 1990:FeCl 1904:FeCl 1867:FeCl 1821:FeCl 1711:and 1521:FeCl 1509:FeCl 1497:FeCl 1485:FeCl 1418:and 1399:FeCl 1348:The 1316:and 1138:nm, 1130:nm, 1093:hR24 976:1499 972:ICSC 868:P501 864:P406 860:P405 856:P390 852:P363 848:P321 844:P310 820:P280 816:P273 812:P270 808:P264 804:P260 800:P234 786:H314 782:H302 778:H290 628:°C) 570:1.82 563:2.90 543:Odor 496:FeCl 333:UNII 7696:UCl 7689:UCl 7682:UCl 7675:UCl 7633:** 7462:Og 7459:Ts 7456:Lv 7453:Mc 7450:Fl 7447:Nh 7444:Cn 7441:Rg 7438:Ds 7435:Mt 7432:Hs 7424:BhO 7412:SgO 7384:** 7366:Rn 7171:WCl 7164:WCl 7157:WCl 7150:WCl 7143:WCl 7060:ICl 7056:ICl 6827:YCl 6806:Kr 6771:+As 6627:VCl 6620:VCl 6613:VCl 6606:VCl 6557:KCl 6551:Ar 6536:+SO 6529:SCl 6522:SCl 6499:PCl 6492:PCl 6420:Ne 6413:ClF 6406:ClF 6402:ClF 6390:ClO 6350:ClO 6346:ClO 6308:+NO 6297:ClN 6290:NCl 6282:+CO 6271:CCl 6230:+BO 6212:BCl 6171:He 6161:HCl 6148:ion 6076:FeO 6052:FeF 6022:FeO 6018:105 5907:(SO 5760:FeP 5752:FeF 5728:FeI 5605:P(C 5541:FeI 5525:FeC 5509:FeC 5457:FeC 5389:(PO 5351:·6H 5335:(NH 5322:FeS 5309:FeO 5301:FeI 5265:FeF 5257:FeH 5245:FeH 5173:FeH 5142:COC 4915:doi 4870:doi 4858:292 4833:doi 4703:doi 4670:doi 4637:doi 4604:PMC 4596:doi 4592:121 4549:doi 4545:119 4522:doi 4495:doi 4434:doi 4393:doi 4268:doi 4232:doi 4195:doi 4105:doi 4069:doi 4057:168 4032:doi 4028:391 3984:PMC 3976:doi 3972:158 3945:doi 3907:doi 3835:doi 3812:doi 3711:doi 3676:doi 3602:doi 3569:doi 3516:doi 3491:doi 3487:629 3441:doi 3412:doi 3338:doi 3288:doi 3229:doi 2960:. 2774:PVC 2655:). 2631:is 2605:of 2528:3 C 2233:+ C 2221:+ C 2132:(Et 1895:Si) 1858:or 1813:+ H 1697:oxo 1591:cis 1563:cis 1465:cis 1463:or 1359:BiI 950:REL 726:GHS 636:in 620:912 549:HCl 394:EPA 296:CID 7822:: 7474:* 7428:Cl 7416:Cl 7297:Cl 7293:Hg 7101:* 7034:Cl 7030:Te 6780:Cl 6776:Se 6544:Cl 6515:Cl 6506:+P 6485:Cl 6466:Cl 6462:Si 6457:12 6455:Cl 6451:Si 6397:+O 6379:Cl 6368:Cl 6357:Cl 6335:Cl 6327:Cl 6316:Cl 6304:+N 6278:+C 6264:Cl 6253:Cl 6242:Cl 6223:Cl 6207:12 6205:Cl 6203:12 6194:Cl 6009:54 5975:BF 5931:NH 5903:Fe 5891:Fe 5875:Fe 5863:Fe 5847:(C 5843:Fe 5827:Fe 5811:(P 5807:Fe 5705:Fe 5693:Fe 5535:14 5531:22 5527:12 5385:Fe 5253:Mg 5225:Fe 5191:(C 5138:CH 5128:12 5122:Fe 5110:Fe 5079:Na 4913:. 4903:54 4901:. 4876:. 4868:. 4856:. 4831:. 4819:. 4815:. 4788:. 4762:. 4709:. 4701:. 4676:. 4668:. 4643:. 4635:. 4612:. 4602:. 4590:. 4586:. 4563:. 4555:. 4543:. 4518:17 4516:. 4491:54 4489:. 4464:. 4440:. 4409:. 4399:. 4365:. 4338:. 4289:. 4266:. 4256:61 4228:51 4226:. 4203:. 4191:16 4189:. 4185:. 4166:. 4130:. 4075:. 4067:. 4055:. 3992:. 3982:. 3970:. 3966:. 3939:. 3927:^ 3913:. 3903:26 3901:. 3876:. 3841:. 3808:65 3806:. 3783:. 3769:. 3717:. 3682:. 3674:. 3656:^ 3624:^ 3608:. 3575:. 3538:^ 3522:. 3485:. 3481:. 3477:Bu 3473:Bu 3469:Bu 3465:Bu 3453:^ 3437:84 3435:. 3410:. 3400:47 3398:. 3394:. 3344:. 3336:. 3308:^ 3294:. 3284:71 3282:. 3266:^ 3227:. 3217:22 3198:^ 3126:. 3044:^ 2996:Cl 2993:Fe 2978:. 2939:. 2912:. 2858:. 2827:. 2776:. 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Index

Ferric chloride




IUPAC names
CAS Number
7705-08-0
10025-77-1
54862-84-9
64333-00-2
JSmol
Interactive image
ChEBI
CHEBI:30808
ChemSpider
22792
ECHA InfoCard
100.028.846
Edit this at Wikidata
EC Number
PubChem
24380
RTECS number
UNII
U38V3ZVV3V
0I2XIN602U
Y048945596
UN number
CompTox Dashboard

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