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Equation of state

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terms. Typical multiparameter equations of state use upwards of 50 fluid specific parameters, but are able to represent the fluid's properties with high accuracy. Multiparameter equations of state are available currently for about 50 of the most common industrial fluids including refrigerants. The IAPWS95 reference equation of state for water is also a multiparameter equations of state. Mixture models for multiparameter equations of state exist, as well. Yet, multiparameter equations of state applied to mixtures are known to exhibit artifacts at times.
6038: 10726: 89: 1659: 5551: 4606: 10233: 5217:. Hence, physically based equations of state model the effect of molecular size, attraction and shape as well as hydrogen bonding and polar interactions of fluids. In general, physically based equations of state give more accurate results than traditional cubic equations of state, especially for systems containing liquids or solids. Most physically based equations of state are built on monomer term describing the 4062:. Cubic equations of state originated from the van der Waals equation of state. Hence, all cubic equations of state can be considered 'modified van der Waals equation of state'. There is a very large number of such cubic equations of state. For process engineering, cubic equations of state are today still highly relevant, e.g. the Peng Robinson equation of state or the Soave Redlich Kwong equation of state. 4260: 5199: 4942: 6033:{\displaystyle a^{\mathrm {residual} }=\sum _{i=1}^{8}\sum _{j=-8}^{12}n_{i,j}\delta ^{i}\tau ^{j/8}+\sum _{i=1}^{5}\sum _{j=-8}^{24}n_{i,j}\delta ^{i}\tau ^{j/8}\exp \left(-\delta \right)+\sum _{i=1}^{5}\sum _{j=16}^{56}n_{i,j}\delta ^{i}\tau ^{j/8}\exp \left(-\delta ^{2}\right)+\sum _{i=2}^{4}\sum _{j=24}^{38}n_{i,j}\delta ^{i}\tau ^{j/2}\exp \left(-\delta ^{3}\right)} 4955: 3682: 4669: 3385: 4601:{\displaystyle p=\rho RT+\left(B_{0}RT-A_{0}-{\frac {C_{0}}{T^{2}}}+{\frac {D_{0}}{T^{3}}}-{\frac {E_{0}}{T^{4}}}\right)\rho ^{2}+\left(bRT-a-{\frac {d}{T}}\right)\rho ^{3}+\alpha \left(a+{\frac {d}{T}}\right)\rho ^{6}+{\frac {c\rho ^{3}}{T^{2}}}\left(1+\gamma \rho ^{2}\right)\exp \left(-\gamma \rho ^{2}\right)} 6957: 5542:
are in most cases the critical values for the pure fluid. Because integration of the multiparameter equations of state is not required and thermodynamic properties can be determined using classical thermodynamic relations, there are few restrictions as to the functional form of the ideal or residual
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was added to the tube, trapping a fixed quantity of air in the short, sealed end of the tube. Then the volume of gas was measured as additional mercury was added to the tube. The pressure of the gas could be determined by the difference between the mercury level in the short end of the tube and that
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of Wertheim) to describe the interactions between molecules in a system. The idea of a SAFT equation of state was first proposed by Chapman et al. in 1988 and 1989. Many different versions of the SAFT models have been proposed, but all use the same chain and association terms derived by Chapman et
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is frequently used for modelling dispersive interactions in an equation of state. There is a large number of perturbation theory based equations of state available today, e.g. for the classical Lennard-Jones fluid. The two most important theories used for these types of equations of state are the
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An equation used to model this relationship is called an equation of state. In most cases this model will comprise some empirical parameters that are usually adjusted to measurement data. Equations of state can also describe solids, including the transition of solids from one crystalline state to
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under about 20,000 atmospheres (2 GPa) pressure, and explains why water is commonly assumed to be incompressible: when the external pressure changes from 1 atmosphere to 2 atmospheres (100 kPa to 200 kPa), the water behaves as an ideal gas would when changing from 20,001 to 20,002
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models is in most parts not physically motivated. They can be usually applied in both liquid and gaseous states. Empirical multiparameter equations of state represent the Helmholtz energy of the fluid as the sum of ideal gas and residual terms. Both terms are explicit in temperature and density:
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Multiparameter equations of state are empirical equations of state that can be used to represent pure fluids with high accuracy. Multiparameter equations of state are empirical correlations of experimental data and are usually formulated in the Helmholtz free energy. The functional form of these
4006:, an increase in the value for pressure from its classical value implying an effective repulsion between particles (this is an apparent repulsion due to quantum exchange effects not because of actual interactions between particles since in ideal gas, interactional forces are neglected) and in 5418: 6703: 3468: 3180: 5212:
as a function of temperature, density (and for mixtures additionally the composition). The Helmholtz energy is formulated as a sum of multiple terms modelling different types of molecular interaction or molecular structures, e.g. the formation of chains or
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At present, there is no single equation of state that accurately predicts the properties of all substances under all conditions. An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the
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Note that in this virial equation, the fourth and fifth virial terms are zero. The second virial coefficient is monotonically decreasing as temperature is lowered. The third virial coefficient is monotonically increasing as temperature is lowered.
5194:{\displaystyle p={\frac {RT}{V}}\left(1+{\frac {B}{V_{r}}}+{\frac {C}{V_{r}^{2}}}+{\frac {D}{V_{r}^{5}}}+{\frac {c_{4}}{T_{r}^{3}V_{r}^{2}}}\left(\beta +{\frac {\gamma }{V_{r}^{2}}}\right)\exp \left({\frac {-\gamma }{V_{r}^{2}}}\right)\right)} 1711:, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures. This equation becomes increasingly inaccurate at higher pressures and lower temperatures, and fails to predict condensation from a gas to a liquid. 4937:{\displaystyle p=\rho RT+\left(B_{0}RT-A_{0}-{\frac {C_{0}}{T^{2}}}+{\frac {D_{0}}{T^{3}}}-{\frac {E_{0}}{T^{4}}}\right)\rho ^{2}+\left(bRT-a-{\frac {d}{T}}+{\frac {c}{T^{2}}}\right)\rho ^{3}+\alpha \left(a+{\frac {d}{T}}\right)\rho ^{6}} 8714:
Gil-Villegas, Alejandro; Galindo, Amparo; Whitehead, Paul J.; Mills, Stuart J.; Jackson, George; Burgess, Andrew N. (1997). "Statistical associating fluid theory for chain molecules with attractive potentials of variable range".
2371: 5278: 5484: 2538: 6586: 2653: 2236: 2456: 6267: 4083: 1378: 6352: 6128: 66:. Most modern equations of state are formulated in the Helmholtz free energy. Equations of state are useful in describing the properties of pure substances and mixtures in liquids, gases, and 3798: 3741: 6042:
This is a somewhat simpler form that is intended to be used more in technical applications. Equations of state that require a higher accuracy use a more complicated form with more terms.
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Saajanlehto, Meri; Uusi-Kyyny, Petri; Alopaeus, Ville (2014). "A modified continuous flow apparatus for gas solubility measurements at high pressure and temperature with camera system".
8138:"Molecular thermodynamics for fluids at low and high densities. Part II: Phase equilibria for mixtures containing components with large differences in molecular size or potential energy" 3677:{\displaystyle {\frac {N}{V}}={\frac {(2s+1)(mk_{\text{B}}T)^{3/2}}{{\sqrt {2}}\pi ^{2}\hbar ^{3}}}\int _{0}^{\infty }{\frac {z^{1/2}\,\mathrm {d} z}{e^{z-\mu /(k_{\text{B}}T)}\pm 1}}.} 4224:
is the first virial coefficient, which has a constant value of 1 and makes the statement that when volume is large, all fluids behave like ideal gases. The second virial coefficient
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are given in such references. These parameters are obtained by fitting the JWL-EOS to experimental results. Typical parameters for some explosives are listed in the table below.
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derived by the assumption of a finite volume occupied by the constituent molecules. His new formula revolutionized the study of equations of state, and was the starting point of
2943: 2871: 2821: 7000: 3380:{\displaystyle p={\frac {(2s+1){\sqrt {2m^{3}k_{\text{B}}^{5}T^{5}}}}{3\pi ^{2}\hbar ^{3}}}\int _{0}^{\infty }{\frac {z^{3/2}\,\mathrm {d} z}{e^{z-\mu /(k_{\text{B}}T)}\pm 1}}} 1949: 3412: 7308: 6409: 6382: 3459: 1213: 1158: 1103: 3047:
Since for atomic and molecular gases, the classical ideal gas law is well suited in most cases, let us describe the equation of state for elementary particles with mass
1759: 910: 863: 778: 731: 643: 596: 7188: 7027: 6536: 5513: 7371: 2983: 814: 682: 7524: 7495: 7338: 7161: 6170: 2751: 2267: 7245: 6952:{\displaystyle p=A\left(1-{\frac {\omega }{R_{1}V}}\right)\exp(-R_{1}V)+B\left(1-{\frac {\omega }{R_{2}V}}\right)\exp \left(-R_{2}V\right)+{\frac {\omega e_{0}}{V}}} 5257:) in fluids, which can also be applied for modelling chain formation (in the limit of infinite association strength). The SAFT equation of state was developed using 1048: 7474: 7446: 7272: 7215: 7141: 7114: 7047: 6563: 6197: 5540: 4653: 4060: 3037: 3010: 2891: 2070: 2041: 2012: 1922: 6429: 7417: 7394: 4000: 2093:
in the long, open end. Through these experiments, Boyle noted that the gas volume varied inversely with the pressure. In mathematical form, this can be stated as:
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is another constant, representing the molecular attraction between water molecules. The magnitude of the correction is about 2 gigapascals (20,000 atmospheres).
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equation. If appropriate assumptions are made about the mathematical form of intermolecular forces, theoretical expressions can be developed for each of the
9221:"Equations of states and scaling rules for molecular solids under strong compression" in "Molecular systems under high pressure" ed. R. Pucci and G. Piccino 2159:
found that oxygen, nitrogen, hydrogen, carbon dioxide, and air expand to roughly the same extent over the same 80-kelvin interval. This is known today as
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is the second order virial parameter of Morse oscillator and it depends on the parameters of Morse oscillator in addition to the absolute temperature.
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Values of the various parameters can be found in reference materials. The BWR equation of state has also frequently been used for the modelling of the
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Chapman, Walter G.; Jackson, G.; Gubbins, K.E. (11 July 1988). "Phase equilibria of associating fluids: Chain molecules with multiple bonding sites".
2241:(1801) of partial pressure states that the pressure of a mixture of gases is equal to the sum of the pressures of all of the constituent gases alone. 4010:, a decrease in pressure from its classical value implying an effective attraction. The quantum nature of this equation is in it dependence on s and 2170: 1688: 8282:
Chapman, Walter G.; Gubbins, K.E.; Jackson, G.; Radosz, M. (1 December 1989). "SAFT: Equation-of-state solution model for associating fluids".
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Redlich, Otto.; Kwong, J. N. S. (1949-02-01). "On the Thermodynamics of Solutions. V. An Equation of State. Fugacities of Gaseous Solutions".
8799:"A Reference Equation of State for the Thermodynamic Properties of Nitrogen for Temperatures from 63.151 to 1000 K and Pressures to 2200 MPa" 1277: 10742: 9433: 8054:
Kontogeorgis, Georgios M.; Michelsen, Michael L.; Folas, Georgios K.; Derawi, Samer; von Solms, Nicolas; Stenby, Erling H. (2006-07-01).
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Chapman, Walter G.; Gubbins, K.E.; Jackson, G.; Radosz, M. (1 August 1990). "New Reference Equation of State for Associating Liquids".
3743:, this equation of state will reduce to that of the classical ideal gas. It can be shown that the above equation of state in the limit 5413:{\displaystyle {\frac {a(T,\rho )}{RT}}={\frac {a^{\mathrm {ideal\,gas} }(\tau ,\delta )+a^{\textrm {residual}}(\tau ,\delta )}{RT}}} 4950:
The Lee–Kesler equation of state is based on the corresponding states principle, and is a modification of the BWR equation of state.
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Although usually not the most convenient equation of state, the virial equation is important because it can be derived directly from
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Lee, Byung Ik; Kesler, Michael G. (1975). "A generalized thermodynamic correlation based on three-parameter corresponding states".
2412: 1400: 6698:{\displaystyle pV_{m}=RT~{\frac {\operatorname {Li} _{\alpha +1}(z)}{\zeta (\alpha )}}\left({\frac {T}{T_{c}}}\right)^{\alpha }} 9426: 8325:
Gross, Joachim; Sadowski, Gabriele (2002). "Application of the Perturbed-Chain SAFT Equation of State to Associating Systems".
2409:. However, later work revealed that the number should actually be closer to 273.2, and then the Celsius scale was defined with 7673: 10673: 9379: 7744: 7654: 6205: 6060: 2096: 970: 3805: 8757:"Equations of State for Technical Applications. I. Simultaneously Optimized Functional Forms for Nonpolar and Polar Fluids" 6298: 5246: 4253: 1681: 1268: 937: 504: 382: 6446: 11042: 2832: 2553: 320: 8849:"The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use" 8056:"Ten Years with the CPA (Cubic-Plus-Association) Equation of State. Part 1. Pure Compounds and Self-Associating Systems" 2758: 9730: 9041:"Morse oscillator equation of state: An integral equation theory based with virial expansion and compressibility terms" 7668: 1452: 1426: 947: 401: 1831:
another. Equations of state are also used for the modeling of the state of matter in the interior of stars, including
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There is a large number of physically based equations of state available today. Most of those are formulated in the
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to triplets, and so on. Accuracy can be increased indefinitely by considering higher order terms. The coefficients
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of water but few simple alternatives are available for severely nonisentropic processes such as strong shocks.
4199:{\displaystyle {\frac {pV_{m}}{RT}}=A+{\frac {B}{V_{m}}}+{\frac {C}{V_{m}^{2}}}+{\frac {D}{V_{m}^{3}}}+\cdots } 1605: 137: 8093:
Kontogeorgis, Georgios M.; Voutsas, Epaminondas C.; Yakoumis, Iakovos V.; Tassios, Dimitrios P. (1996-01-01).
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The Benedict–Webb–Rubin–Starling equation of state is a modified BWR equation of state and can be written as
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the temperature of the system. Yet also other variables may be used in that form. It is directly related to
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Span, Roland; Lemmon, Eric W.; Jacobsen, Richard T; Wagner, Wolfgang; Yokozeki, Akimichi (November 2000).
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published results of similar experiments, indicating a linear relationship between volume and temperature:
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The equation of state from Jones–Wilkins–Lee is used to describe the detonation products of explosives.
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Weingerl, Ulrike; Wendland, Martin; Fischer, Johann; MĂŒller, Andreas; Winkelmann, Jochen (March 2001).
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and is sometimes referred to as Mariotte's law. However, Mariotte's work was not published until 1676.
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was one of the earliest formulation of an equation of state. In 1662, the Irish physicist and chemist
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that takes into account quantum effects. In the following, the upper sign will always correspond to
1927: 11052: 10994: 10977: 10654: 10553: 10183: 10029: 10024: 9907: 9875: 9790: 9530: 9520: 7599: 4663:. There are several extensions and modifications of the classical BWR equation of state available. 4028: 4023: 2549: 3390: 10841: 10831: 10757: 10548: 10089: 9770: 9686: 9576: 9366:. NATO Science Series. Vol. 140. Dordrecht, Netherlands: Kluver Academic. pp. 217–236. 8458: 8380: 7950: 7911: 7867: 7285: 6440: 6387: 6360: 5218: 3421: 2164: 1662: 1490: 1287: 1168: 1113: 1058: 990: 929: 465: 454: 120: 55: 43: 8953:"Applications of the IAPWS-95 formulation in fluid inclusion and mineral-fluid phase equilibria" 7818:
Soave, Giorgio (1972). "Equilibrium constants from a modified Redlich-Kwong equation of state".
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performed a series of experiments employing a J-shaped glass tube, which was sealed on one end.
892: 845: 760: 713: 625: 578: 24: 10888: 10573: 10563: 10313: 10308: 9669: 9542: 9401:
S. Benjelloun, "Thermodynamic identities and thermodynamic consistency of Equation of States",
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is an exponent specific to the system (e.g. in the absence of a potential field, α = 3/2),
6541: 6175: 6056: 5518: 4638: 4038: 3015: 2988: 2876: 2048: 2019: 1990: 1900: 1610: 1535: 1525: 325: 187: 8490:"Perturbation Theory and Equation of State for Fluids. II. A Successful Theory of Liquids" 8459:"A child of prediction. On the History, Ontology, and Computation of the Lennard-Jonesium" 7852:
Landau, L. D., Lifshitz, E. M. (1980). Statistical physics: Part I (Vol. 5). page 162-166.
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An equation of state of Morse oscillator has been derived, and it has the following form:
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Barker-Henderson perturbation theory and the Weeks–Chandler–Andersen perturbation theory.
8: 10982: 10961: 10467: 10359: 10349: 10262: 10217: 10109: 9961: 9900: 9880: 9696: 9642: 9525: 9484: 9450: 7401: 7378: 5262: 5233: 4660: 3977: 2946: 2541: 1850: 1555: 1317: 339: 305: 300: 213: 9325: 9274: 9182: 9056: 8968: 8903: 8814: 8728: 8599: 8552: 8505: 8427: 8247: 8208: 8153: 8024: 7966: 7831: 1550: 529: 11009: 10921: 10898: 10879: 10859: 10823: 10614: 10543: 10377: 9780: 9775: 9559: 9294: 9194: 9083: 9040: 9017: 8928: 8887: 8776: 8619: 8307: 8173: 7931: 7700: 7072: 7052: 6734: 6494: 6135: 4616: 4217: 3462: 3415: 3158: 3138: 3118: 3098: 3070: 3050: 2681: 2661: 2247: 1960: 1874: 1806: 1786: 1766: 1644: 1307: 1302: 1255: 871: 824: 739: 692: 604: 557: 487: 471: 358: 310: 295: 285: 94: 88: 50:, which describe the state of matter under a given set of physical conditions, such as 9674: 2374: 11014: 10911: 10884: 10795: 10785: 10778: 10644: 10639: 10568: 10457: 10409: 10394: 10287: 10257: 9828: 9765: 9744: 9739: 9632: 9375: 9337: 9298: 9286: 9282: 9198: 9139: 9108:"LLNL Explosives Handbook: Properties of Chemical Explosives and Explosive Simulants" 9088: 9070: 9021: 8982: 8933: 8915: 8868: 8826: 8780: 8623: 8611: 8564: 8537:"Role of Repulsive Forces in Determining the Equilibrium Structure of Simple Liquids" 8517: 8439: 8299: 8295: 8259: 8165: 8114: 8075: 8036: 7978: 7935: 7889: 7881: 7871: 7839: 7800: 7792: 7740: 7715: 2089: 1639: 1600: 1590: 1162: 960: 788: 290: 280: 8311: 8177: 6761: 6202:
The equation is stated in this form because the speed of sound in water is given by
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Holzapfel, W.B. (1991) . "Equations of state for solids under strong compression".
9186: 9078: 9060: 9013: 8972: 8923: 8907: 8860: 8818: 8768: 8756: 8732: 8696: 8669: 8642:
Chapman, Walter G. (1988). "Theory and Simulation of Associating Liquid Mixtures".
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gas approximation is used, then the ideal gas law may also be expressed as follows
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An equation describing the state of matter under a given set of physical conditions
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One example of such an equation of state is the form proposed by Span and Wagner.
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Holzapfel, W.B. (1998). "Equation of state for solids under strong compression".
8848: 8798: 8584:"Fluids with highly directional attractive forces. I. Statistical thermodynamics" 8536: 8489: 7531: 2238: 2156: 1510: 1358: 1012: 653: 476: 237: 204: 63: 9418: 8474: 8396: 8381:"Equation of state for the Lennard–Jones fluid based on the perturbation theory" 8365: 7927: 2366:{\displaystyle p_{\text{total}}=p_{1}+p_{2}+\cdots +p_{n}=\sum _{i=1}^{n}p_{i}.} 10999: 10715: 10387: 10382: 10339: 10272: 10267: 10084: 9951: 9865: 9823: 9637: 8911: 8133: 7163:
are given by several references. In addition, the initial density (solid part)
6566: 4032: 2894: 2081: 1565: 1335: 435: 315: 252: 242: 110: 80: 47: 9333: 9247: 8977: 8952: 8772: 8673: 7974: 11031: 10987: 10624: 10604: 10527: 10487: 10422: 10354: 10277: 10132: 10099: 9996: 9860: 9725: 9341: 9290: 9074: 9025: 8986: 8919: 8872: 8830: 8615: 8568: 8521: 8443: 8303: 8263: 8169: 8118: 8094: 8079: 8055: 8040: 7982: 7796: 7639: 7565: 6738: 5254: 5222: 5214: 2712: 2379: 2149: 1840: 1708: 1634: 952: 521: 482: 194: 8435: 8193:"Backone family of equations of state: 2. Nonpolar and polar fluid mixtures" 11004: 10649: 10522: 10517: 10512: 10477: 10427: 10344: 10104: 10094: 10069: 9357:"Equations of State and Thermophysical Properties of Solids Under Pressure" 9092: 8937: 8379:
Betancourt-CĂĄrdenas, F.F.; Galicia-Luna, L.A.; Sandler, S.I. (March 2008).
7804: 6172:
is an empirically determined constant typically taken to be about 6.1, and
5479:{\displaystyle \tau ={\frac {T_{r}}{T}},\delta ={\frac {\rho }{\rho _{r}}}} 2406: 2085: 1978: 1952: 1832: 1585: 1570: 1520: 1003: 10148: 8888:"Unphysical Critical Curves of Binary Mixtures Predicted with GERG Models" 8255: 8216: 8161: 8032: 7893: 7762:
On the Continuity of the Gaseous and Liquid States (doctoral dissertation)
10813: 10808: 10558: 10452: 10364: 10019: 9107: 8232:"Backone family of equations of state: 1. Nonpolar and polar pure fluids" 7949:
Nicolas, J.J.; Gubbins, K.E.; Streett, W.B.; Tildesley, D.J. (May 1979).
7912:"Review and comparison of equations of state for the Lennard-Jones fluid" 5245:
An important contribution for physically based equations of state is the
2826: 2533:{\displaystyle pV_{m}=R\left(T_{C}+273.15\ {}^{\circ }{\text{C}}\right).} 1892: 1540: 348: 59: 10665: 8700: 8583: 7788: 6055:
When considering water under very high pressures, in situations such as
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Holzapfel, Wi.B. (1996). "Physics of solids under strong compression".
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for water and other liquids. Several equations are referred to as the
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is the first order virial parameter and it depends on the temperature,
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is the internal energy per unit mass (the "specific internal energy"),
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is a parameter describing the attractive energy between particles and
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combined Boyle's law and Charles' law into the first statement of the
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MĂŒller, Andreas; Winkelmann, Jochen; Fischer, Johann (April 1996).
7710: 7695: 6578: 4007: 1343: 1260: 1052: 460: 232: 51: 8092: 7811: 7049:, which is the density of the detonation products. The parameters 2648:{\displaystyle \left(P+a{\frac {1}{V_{m}^{2}}}\right)(V_{m}-b)=RT} 10933: 10594: 10482: 10417: 10334: 10329: 9818: 9758: 8713: 8535:
Weeks, John D.; Chandler, David; Andersen, Hans C. (1971-06-15).
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Jones–Wilkins–Lee equation of state for explosives (JWL equation)
449: 31: 9167:"Finite strain theories and comparisons with seismological data" 8457:
Lenhard, Johannes; Stephan, Simon; Hasse, Hans (February 2024).
8053: 7885: 10203: 9922: 1865: 7948: 5240: 2401:+ 267) (with temperature expressed in degrees Celsius), where 2231:{\displaystyle {\frac {V_{1}}{T_{1}}}={\frac {V_{2}}{T_{2}}}.} 10212: 10198: 10124: 9853: 9620: 8351: 8190: 7910:
Stephan, Simon; Staubach, Jens; Hasse, Hans (November 2020).
67: 23:. For the use of this concept in optimal control theory, see 9105: 8686: 8281: 2451:{\displaystyle 0~^{\circ }\mathrm {C} =273.15~\mathrm {K} } 1853:
and petroleum industry as well as pharmaceutical industry.
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The general form of an equation of state may be written as
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and the chemical energy per unit volume of the explosive
7029:, which is the density of the explosive (solid part) and 70:
states as well as the state of matter in the interior of
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Thus water behaves as though it is an ideal gas that is
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corresponds to interactions between pairs of molecules,
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of the gas (number of atoms/molecules per unit volume),
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is a parameter describing the volume of the particles.
2557: 8999: 8229: 6262:{\displaystyle c^{2}=\gamma \left(p+p^{0}\right)/\rho } 2755:
In the form shown above, the equation of state is thus
8412:"Perturbation Theory and Equation of State for Fluids" 6434: 5203: 3012:
is the specific heat capacity at constant volume, and
2563:
The van der Waals equation of state can be written as
1849:
Equations of state are applied in many fields such as
8659: 8655: 8653: 8534: 8277: 8275: 8273: 7504: 7483: 7455: 7427: 7404: 7381: 7348: 7318: 7288: 7253: 7223: 7196: 7169: 7149: 7122: 7095: 7075: 7055: 7035: 7008: 6967: 6772: 6589: 6544: 6517: 6497: 6449: 6417: 6390: 6363: 6347:{\displaystyle p=\Gamma _{1}\nu +\Gamma _{2}\nu ^{2}} 6301: 6287: 6208: 6178: 6158: 6138: 6075: 6045: 5554: 5521: 5494: 5426: 5281: 4958: 4672: 4641: 4619: 4263: 4086: 4041: 3980: 3808: 3749: 3692: 3471: 3424: 3393: 3183: 3161: 3141: 3121: 3101: 3073: 3053: 3018: 2991: 2955: 2903: 2879: 2835: 2761: 2721: 2684: 2664: 2572: 2464: 2415: 2270: 2250: 2173: 2099: 2051: 2022: 1993: 1963: 1930: 1903: 1877: 1809: 1789: 1769: 1720: 1171: 1116: 1061: 1021: 895: 874: 848: 827: 799: 763: 742: 716: 695: 664: 628: 607: 581: 560: 532: 7909: 5269: 3039:
is the specific heat capacity at constant pressure.
9165:Stacey, F.D.; Brennan, B. J.; Irvine, R.D. (1981). 9164: 9000:Le MĂ©tayer, O; Massoni, J; Saurel, R (2004-03-01). 8456: 5228: 4031:are called such because they can be rewritten as a 2148:The above relationship has also been attributed to 8886:Deiters, Ulrich K.; Bell, Ian H. (December 2020). 8680: 8650: 8270: 8131: 7759: 7518: 7489: 7468: 7440: 7411: 7388: 7365: 7332: 7302: 7266: 7239: 7209: 7182: 7155: 7135: 7108: 7081: 7061: 7041: 7021: 6994: 6951: 6697: 6557: 6530: 6503: 6483: 6423: 6403: 6376: 6346: 6277:atmospheres (2000.1 MPa to 2000.2 MPa). 6261: 6191: 6164: 6144: 6123:{\displaystyle p=\rho (\gamma -1)e-\gamma p^{0}\,} 6122: 6032: 5534: 5507: 5478: 5412: 5193: 4936: 4647: 4625: 4600: 4198: 4054: 3994: 3964: 3792: 3735: 3676: 3453: 3406: 3379: 3167: 3147: 3127: 3107: 3079: 3059: 3031: 3004: 2977: 2937: 2885: 2865: 2815: 2745: 2690: 2670: 2647: 2532: 2450: 2365: 2256: 2230: 2140: 2064: 2035: 2006: 1969: 1943: 1916: 1883: 1856:Any consistent set of units may be used, although 1815: 1795: 1775: 1753: 1207: 1152: 1097: 1042: 904: 880: 857: 833: 808: 772: 748: 725: 701: 676: 637: 613: 590: 566: 541: 9448: 9158: 6067:, the stiffened equation of state is often used: 1839:) and radiation fields. A related concept is the 11029: 8410:Levesque, Dominique; Verlet, Loup (1969-06-05). 7905: 7903: 8853:Journal of Physical and Chemical Reference Data 8803:Journal of Physical and Chemical Reference Data 8487: 8327:Industrial & Engineering Chemistry Research 8099:Industrial & Engineering Chemistry Research 8060:Industrial & Engineering Chemistry Research 7951:"Equation of state for the Lennard-Jones fluid" 6572: 8637: 8635: 8633: 8488:Barker, J. A.; Henderson, D. (December 1967). 8409: 7734: 6050: 10681: 10164: 9434: 9305: 9254: 8324: 8095:"An Equation of State for Associating Fluids" 7900: 7861: 3793:{\displaystyle e^{\mu /(k_{\text{B}}T)}\ll 1} 3736:{\displaystyle e^{\mu /(k_{\text{B}}T)}\ll 1} 1682: 8463:Studies in History and Philosophy of Science 7998:Fluid Properties for Light Petroleum Systems 7864:Fluid Properties for Light Petroleum Systems 7774: 7753: 4247: 4065: 3465:is given by the following implicit function 2244:Mathematically, this can be represented for 2072:, absolute temperature at the critical point 10178: 8885: 8630: 5241:Statistical associating fluid theory (SAFT) 4070: 4017: 3095:. The equation of state of such gases with 10688: 10674: 10171: 10157: 9441: 9427: 9395: 9223:. North-Holland: Elsevier. pp. 61–68. 8846: 8754: 4244:, etc. are functions of temperature only. 2706: 1689: 1675: 87: 10695: 9362:. In Katrusiak, A.; McMillan, P. (eds.). 9354: 9311: 9260: 9233: 9218: 9082: 9064: 9006:International Journal of Thermal Sciences 8976: 8927: 8644:Doctoral Dissertation, Cornell University 8010: 7515: 7408: 7385: 7362: 7329: 7299: 6119: 5341: 3611: 3317: 9135:Computer Simulation of Dynamic Phenomena 9038: 8581: 7995: 6431:is the fractional volume of the system. 3042: 2552:, which most famously continued via the 2076: 9131: 9125: 9099: 8641: 8000:. Gulf Publishing Company. p. 270. 7659:Stacey–Brennan–Irvine equation of state 6754:is the critical temperature at which a 5253:that describes the association (a.k.a. 4002:, decreasing the temperature causes in 2383:. Initially, the law was formulated as 2141:{\displaystyle pV=\mathrm {constant} .} 1955:, the volume of 1 mole of gas or liquid 11030: 9106:B. M. Dobratz; P. C. Crawford (1985). 8951:Shi, Lanlan; Mao, Shide (2012-01-01). 8950: 8892:International Journal of Thermophysics 8761:International Journal of Thermophysics 6152:is the internal energy per unit mass, 3965:{\displaystyle pV=Nk_{\text{B}}T\left} 19:For the use of this in cosmology, see 10669: 10152: 9422: 8842: 8840: 8792: 8790: 8750: 8748: 8746: 7817: 7728: 25:Optimal control § General method 7665:Adapted polynomial equation of state 6484:{\displaystyle p=\rho _{m}c_{s}^{2}} 5247:statistical associating fluid theory 2043:, molar volume at the critical point 1868:(K), with zero being absolute zero. 7669:Johnson–Holmquist equation of state 6577:The equation of state for an ideal 6435:Ultrarelativistic equation of state 5204:Physically based equations of state 4212:. This equation is also called the 2945:is the (constant) adiabatic index ( 2938:{\displaystyle \gamma =C_{p}/C_{v}} 2866:{\displaystyle p=\rho (\gamma -1)e} 2558:Soave modification of Redlich-Kwong 1844:equation of state used in cosmology 13: 9018:10.1016/j.ijthermalsci.2003.09.002 8847:Wagner, W.; Pruß, A. (June 2002). 8837: 8787: 8743: 7662:Modified Rydberg equation of state 6392: 6365: 6325: 6309: 6288:Morse oscillator equation of state 6046:List of further equations of state 5582: 5579: 5576: 5573: 5570: 5567: 5564: 5561: 5348: 5345: 5342: 5338: 5335: 5332: 5329: 5326: 3613: 3585: 3319: 3291: 2816:{\displaystyle f(p,V,T)=pV-nRT=0.} 2444: 2430: 2131: 2128: 2125: 2122: 2119: 2116: 2113: 2110: 896: 849: 764: 717: 629: 582: 402:Intensive and extensive properties 14: 11074: 9414: 7768: 7655:Birch–Murnaghan equation of state 6995:{\displaystyle V=\rho _{e}/\rho } 5270:Multiparameter equations of state 10724: 10231: 7706:Table of thermodynamic equations 5229:Perturbation theory-based models 2701: 2014:, pressure at the critical point 1658: 1657: 977:Table of thermodynamic equations 9355:Holzapfel, Wilfried B. (2004). 9348: 9227: 9212: 9039:Al-Raeei, Marwan (2022-04-01). 9032: 8993: 8944: 8879: 8717:The Journal of Chemical Physics 8707: 8575: 8541:The Journal of Chemical Physics 8528: 8494:The Journal of Chemical Physics 8481: 8450: 8403: 8372: 8345: 8318: 8223: 8184: 8125: 8086: 8047: 8004: 7679:Anton-Schmidt equation of state 7674:Mie–GrĂŒneisen equation of state 2554:Redlich–Kwong equation of state 1453:Maxwell's thermodynamic surface 8588:Journal of Statistical Physics 8582:Wertheim, M. S. (April 1984). 7989: 7942: 7855: 7846: 6845: 6826: 6657: 6651: 6643: 6637: 6280:This equation mispredicts the 6097: 6085: 5396: 5384: 5366: 5354: 5300: 5288: 3931: 3911: 3884: 3869: 3779: 3763: 3722: 3706: 3657: 3641: 3526: 3506: 3503: 3488: 3448: 3428: 3363: 3347: 3208: 3193: 2857: 2845: 2783: 2765: 2633: 2614: 1944:{\displaystyle {\frac {V}{n}}} 1742: 1724: 1187: 1175: 1132: 1120: 1077: 1065: 1037: 1025: 1: 10620:Macroscopic quantum phenomena 9364:High-Pressure Crystallography 9066:10.1016/j.heliyon.2022.e09328 8755:Span, R.; Wagner, W. (2003). 7996:Starling, Kenneth E. (1973). 7760:van der Waals; J. D. (1873). 7721: 6057:underwater nuclear explosions 3115:particles occupying a volume 2155:In 1787 the French physicist 1354:Mechanical equivalent of heat 21:Equation of state (cosmology) 10711:Principle of maximum entropy 10630:Order and disorder (physics) 9372:10.1007/978-1-4020-2102-2_14 8296:10.1016/0378-3812(89)80308-5 7840:10.1016/0009-2509(72)80096-4 7820:Chemical Engineering Science 6573:Ideal Bose equation of state 5249:(SAFT) that contributes the 4254:Benedict–Webb–Rubin equation 3974:With a fixed number density 3407:{\displaystyle k_{\text{B}}} 966:Onsager reciprocal relations 7: 8475:10.1016/j.shpsa.2023.11.007 8397:10.1016/j.fluid.2007.11.015 8366:10.1016/j.fluid.2014.08.035 7928:10.1016/j.fluid.2020.112772 7739:. Oxford University Press. 7689: 7650:Murnaghan equation of state 7303:{\displaystyle \rho _{e}\,} 7217:, Chapman–Jouguet pressure 6404:{\displaystyle \Gamma _{2}} 6377:{\displaystyle \Gamma _{1}} 6051:Stiffened equation of state 5261:methods (in particular the 3686:In the limiting case where 3454:{\displaystyle \mu (T,N/V)} 1701: 1458:Entropy as energy dispersal 1269:"Perpetual motion" machines 1208:{\displaystyle G(T,p)=H-TS} 1153:{\displaystyle A(T,V)=U-TS} 1098:{\displaystyle H(S,p)=U+pV} 10: 11079: 11043:Engineering thermodynamics 10735:Statistical thermodynamics 9283:10.1088/0034-4885/59/1/002 8912:10.1007/s10765-020-02743-3 4251: 4074: 4021: 1754:{\displaystyle f(p,V,T)=0} 905:{\displaystyle \partial T} 858:{\displaystyle \partial V} 773:{\displaystyle \partial p} 726:{\displaystyle \partial V} 638:{\displaystyle \partial T} 591:{\displaystyle \partial S} 18: 10970: 10932: 10897: 10852: 10794: 10733: 10722: 10703: 10582: 10536: 10408: 10322: 10296: 10240: 10229: 10191: 10123: 10055: 10005: 9982: 9844: 9607: 9493: 9457: 9334:10.1080/08957959808200283 9248:10.1080/08957959108245571 9132:Wilkins, Mark L. (1999), 8978:10.1016/j.gsf.2011.08.002 8674:10.1080/00268978800101601 7975:10.1080/00268977900101051 7684:State-transition equation 7633: 7183:{\displaystyle \rho _{0}} 7022:{\displaystyle \rho _{e}} 6538:is the mass density, and 6531:{\displaystyle \rho _{m}} 5508:{\displaystyle \rho _{r}} 4248:The BWR equation of state 4066:Virial equations of state 1864:refers to the use of the 1379:An Inquiry Concerning the 10995:Condensed matter physics 10978:Statistical field theory 10655:Thermo-dielectric effect 10554:Enthalpy of vaporization 10248:Bose–Einstein condensate 9791:Compact tension specimen 9511:Conservation of momentum 9219:Holzapfel, W.B. (1991). 9138:, Springer, p. 80, 7737:A to Z of Thermodynamics 7366:{\displaystyle p_{CJ}\,} 6756:Bose–Einstein condensate 5515:and reduced temperature 4071:Virial equation of state 4029:Cubic equations of state 4024:Cubic equations of state 4018:Cubic equations of state 3093:Bose–Einstein statistics 2978:{\displaystyle e=C_{v}T} 2550:cubic equations of state 1392:Heterogeneous Substances 809:{\displaystyle \alpha =} 677:{\displaystyle \beta =-} 10853:Mathematical approaches 10842:Lennard-Jones potential 10758:thermodynamic potential 10549:Enthalpy of sublimation 9871:Navier–Stokes equations 9771:Material failure theory 9759:Material failure theory 8773:10.1023/A:1022390430888 8436:10.1103/PhysRev.182.307 7868:Gulf Publishing Company 7735:Perrot, Pierre (1998). 7519:{\displaystyle e_{0}\,} 7490:{\displaystyle \omega } 7333:{\displaystyle v_{D}\,} 7156:{\displaystyle \omega } 6441:ultrarelativistic fluid 6165:{\displaystyle \gamma } 6061:sonic shock lithotripsy 2947:ratio of specific heats 2746:{\displaystyle pV=nRT.} 2707:Classical ideal gas law 2165:Joseph Louis Gay-Lussac 11048:Mechanical engineering 10889:conformal field theory 10564:Latent internal energy 10314:Color-glass condensate 9543:Conservation of energy 9403:Link to Archiv e-print 8385:Fluid Phase Equilibria 8354:Fluid Phase Equilibria 8284:Fluid Phase Equilibria 7916:Fluid Phase Equilibria 7862:K.E. Starling (1973). 7764:. Universiteit Leiden. 7520: 7491: 7470: 7442: 7413: 7390: 7367: 7334: 7304: 7268: 7241: 7240:{\displaystyle P_{CJ}} 7211: 7190:, speed of detonation 7184: 7157: 7137: 7110: 7083: 7063: 7043: 7023: 6996: 6953: 6699: 6559: 6532: 6505: 6485: 6443:has equation of state 6425: 6405: 6378: 6348: 6282:specific heat capacity 6263: 6193: 6166: 6146: 6124: 6034: 5956: 5935: 5838: 5817: 5727: 5703: 5635: 5611: 5536: 5509: 5480: 5414: 5259:statistical mechanical 5195: 4938: 4649: 4627: 4602: 4200: 4056: 3996: 3966: 3794: 3737: 3678: 3455: 3408: 3381: 3169: 3149: 3129: 3109: 3091:and the lower sign to 3089:Fermi–Dirac statistics 3081: 3061: 3033: 3006: 2979: 2939: 2887: 2867: 2817: 2747: 2692: 2672: 2649: 2534: 2452: 2367: 2349: 2258: 2232: 2142: 2066: 2037: 2008: 1971: 1945: 1918: 1885: 1817: 1797: 1777: 1755: 1209: 1154: 1099: 1044: 1043:{\displaystyle U(S,V)} 906: 882: 859: 835: 810: 774: 750: 727: 703: 678: 639: 615: 592: 568: 543: 522:Specific heat capacity 126:Quantum thermodynamics 44:thermodynamic equation 10804:Ferromagnetism models 10697:Statistical mechanics 10374:Magnetically ordered 9908:Archimedes' principle 9876:Bernoulli's principle 9171:Surveys in Geophysics 8256:10.1002/aic.690420423 8217:10.1002/aic.690470317 8162:10.1002/aic.690321105 8033:10.1002/aic.690210313 7521: 7492: 7471: 7469:{\displaystyle R_{2}} 7443: 7441:{\displaystyle R_{1}} 7414: 7391: 7368: 7335: 7305: 7269: 7267:{\displaystyle e_{0}} 7242: 7212: 7210:{\displaystyle V_{D}} 7185: 7158: 7138: 7136:{\displaystyle R_{2}} 7111: 7109:{\displaystyle R_{1}} 7084: 7064: 7044: 7042:{\displaystyle \rho } 7024: 6997: 6954: 6743:Riemann zeta function 6700: 6560: 6558:{\displaystyle c_{s}} 6533: 6506: 6486: 6426: 6406: 6379: 6349: 6264: 6194: 6192:{\displaystyle p^{0}} 6167: 6147: 6125: 6035: 5936: 5915: 5818: 5797: 5704: 5683: 5612: 5591: 5537: 5535:{\displaystyle T_{r}} 5510: 5481: 5415: 5210:Helmholtz free energy 5196: 4939: 4650: 4648:{\displaystyle \rho } 4628: 4603: 4210:statistical mechanics 4201: 4057: 4055:{\displaystyle V_{m}} 3997: 3967: 3795: 3738: 3679: 3456: 3409: 3382: 3170: 3150: 3130: 3110: 3082: 3062: 3043:Quantum ideal gas law 3034: 3032:{\displaystyle C_{p}} 3007: 3005:{\displaystyle C_{v}} 2980: 2940: 2888: 2886:{\displaystyle \rho } 2868: 2818: 2748: 2693: 2673: 2650: 2544:introduced the first 2535: 2453: 2368: 2329: 2259: 2233: 2143: 2077:Historical background 2067: 2065:{\displaystyle T_{c}} 2038: 2036:{\displaystyle V_{c}} 2009: 2007:{\displaystyle p_{c}} 1972: 1946: 1919: 1917:{\displaystyle V_{m}} 1886: 1860:units are preferred. 1818: 1798: 1778: 1756: 1390:On the Equilibrium of 1210: 1155: 1108:Helmholtz free energy 1100: 1045: 907: 883: 860: 836: 811: 775: 751: 728: 704: 679: 640: 616: 593: 569: 544: 11063:Thermodynamic models 11038:Equations of physics 10253:Fermionic condensate 10138:William Prager Medal 9716:Rock mass plasticity 9613:Structural mechanics 9506:Conservation of mass 9494:Laws and Definitions 8957:Geoscience Frontiers 7502: 7481: 7453: 7425: 7402: 7379: 7346: 7316: 7286: 7251: 7221: 7194: 7167: 7147: 7120: 7093: 7073: 7053: 7033: 7006: 7002:is defined by using 6965: 6770: 6587: 6542: 6515: 6495: 6447: 6424:{\displaystyle \nu } 6415: 6388: 6361: 6299: 6206: 6176: 6156: 6136: 6073: 5552: 5519: 5492: 5488:The reduced density 5424: 5279: 5215:dipolar interactions 4956: 4670: 4639: 4617: 4261: 4084: 4039: 3978: 3806: 3747: 3690: 3469: 3422: 3391: 3181: 3159: 3139: 3119: 3099: 3071: 3051: 3016: 2989: 2953: 2901: 2877: 2833: 2759: 2719: 2682: 2662: 2570: 2462: 2413: 2268: 2248: 2171: 2097: 2049: 2020: 1991: 1961: 1928: 1901: 1875: 1862:Absolute temperature 1807: 1787: 1767: 1718: 1403:Motive Power of Fire 1169: 1114: 1059: 1019: 971:Bridgman's equations 948:Fundamental relation 893: 872: 846: 825: 797: 761: 740: 714: 693: 662: 626: 605: 579: 558: 530: 10983:elementary particle 10748:partition functions 10468:Chemical ionization 10360:Programmable matter 10350:Quantum spin liquid 10218:Supercritical fluid 9881:Poiseuille equation 9658:Membrane elasticity 9643:Transverse isotropy 9485:Rigid body dynamics 9451:continuum mechanics 9406:Link to Hal e-print 9326:1998HPR....16...81H 9275:1996RPPh...59...29H 9183:1981GeoSu...4..189S 9057:2022Heliy...809328A 8969:2012GeoFr...3...51S 8904:2020IJT....41..169D 8815:2000JPCRD..29.1361S 8729:1997JChPh.106.4168G 8701:10.1021/ie00104a021 8689:Ind. Eng. Chem. Res 8600:1984JSP....35...19W 8553:1971JChPh..54.5237W 8506:1967JChPh..47.4714B 8428:1969PhRv..182..307L 8248:1996AIChE..42.1116M 8209:2001AIChE..47..705W 8154:1986AIChE..32.1799C 8025:1975AIChE..21..510L 7967:1979MolPh..37.1429N 7832:1972ChEnS..27.1197S 7789:10.1021/cr60137a013 7412:{\displaystyle B\,} 7389:{\displaystyle A\,} 6480: 5263:perturbation theory 5234:Perturbation theory 5219:Lennard-Jones fluid 5179: 5137: 5103: 5088: 5055: 5030: 4661:Lennard-Jones fluid 4187: 4162: 3995:{\displaystyle N/V} 3589: 3295: 3240: 2827:calorically perfect 2606: 2542:J. D. van der Waals 1851:process engineering 1837:quark–gluon plasmas 1381:Source ... Friction 1313:Loschmidt's paradox 505:Material properties 383:Conjugate variables 11058:Equations of state 11010:information theory 10917:correlation length 10912:Critical exponents 10899:Critical phenomena 10880:stochastic process 10860:Boltzmann equation 10753:equations of state 10615:Leidenfrost effect 10544:Enthalpy of fusion 10309:Quark–gluon plasma 10030:Electrorheological 10025:Magnetorheological 9781:Fracture mechanics 9548:Entropy inequality 9191:10.1007/BF01449185 8608:10.1007/bf01017362 8132:Cotterman, R. L.; 7701:Departure function 7516: 7487: 7466: 7438: 7409: 7386: 7363: 7330: 7300: 7264: 7237: 7207: 7180: 7153: 7133: 7106: 7079: 7059: 7039: 7019: 6992: 6949: 6735:chemical potential 6695: 6555: 6528: 6501: 6481: 6466: 6421: 6401: 6374: 6344: 6259: 6189: 6162: 6142: 6120: 6030: 5532: 5505: 5476: 5410: 5191: 5165: 5123: 5089: 5074: 5041: 5016: 4934: 4645: 4623: 4598: 4196: 4173: 4148: 4052: 3992: 3962: 3790: 3733: 3674: 3575: 3463:chemical potential 3451: 3416:Boltzmann constant 3404: 3377: 3281: 3226: 3165: 3145: 3125: 3105: 3077: 3057: 3029: 3002: 2975: 2935: 2883: 2863: 2813: 2743: 2688: 2668: 2645: 2592: 2530: 2448: 2363: 2254: 2228: 2163:. Later, in 1802, 2138: 2062: 2033: 2004: 1979:ideal gas constant 1967: 1941: 1914: 1881: 1813: 1793: 1773: 1751: 1645:Order and disorder 1401:Reflections on the 1308:Heat death paradox 1205: 1150: 1095: 1040: 902: 878: 855: 831: 806: 770: 746: 723: 699: 674: 635: 611: 588: 564: 542:{\displaystyle c=} 539: 512:Property databases 488:Reduced properties 472:Chemical potential 436:Functions of state 359:Thermal efficiency 95:Carnot heat engine 11025: 11024: 11015:Boltzmann machine 10885:mean-field theory 10786:Maxwell relations 10663: 10662: 10645:Superheated vapor 10640:Superconductivity 10610:Equation of state 10458:Flash evaporation 10410:Phase transitions 10395:String-net liquid 10288:Photonic molecule 10258:Degenerate matter 10146: 10145: 9829:Bending of plates 9803:Johnson-Holmquist 9766:Drucker stability 9740:Contact mechanics 9687:Cauchy elasticity 9665:Equation of state 9381:978-1-4020-1954-8 8865:10.1063/1.1461829 8823:10.1063/1.1349047 8723:(10): 4168–4186. 8662:Molecular Physics 8561:10.1063/1.1674820 8547:(12): 5237–5247. 8514:10.1063/1.1701689 8500:(11): 4714–4721. 8339:10.1021/ie010954d 8333:(22): 5510–5515. 8148:(11): 1799–1812. 8136:(November 1986). 8111:10.1021/ie9600203 8105:(11): 4310–4318. 8072:10.1021/ie051305v 8066:(14): 4855–4868. 7955:Molecular Physics 7746:978-0-19-856552-9 7716:Cluster expansion 7631: 7630: 7082:{\displaystyle B} 7062:{\displaystyle A} 6947: 6885: 6813: 6683: 6661: 6614: 6511:is the pressure, 6504:{\displaystyle p} 6145:{\displaystyle e} 5474: 5448: 5408: 5380: 5312: 5180: 5138: 5105: 5056: 5031: 5006: 4978: 4917: 4875: 4855: 4804: 4777: 4750: 4626:{\displaystyle p} 4535: 4488: 4446: 4395: 4368: 4341: 4188: 4163: 4138: 4112: 3949: 3924: 3888: 3828: 3773: 3716: 3669: 3651: 3573: 3550: 3519: 3480: 3401: 3375: 3357: 3279: 3251: 3233: 3168:{\displaystyle p} 3148:{\displaystyle T} 3135:with temperature 3128:{\displaystyle V} 3108:{\displaystyle N} 3080:{\displaystyle s} 3060:{\displaystyle m} 2691:{\displaystyle b} 2671:{\displaystyle a} 2607: 2546:equation of state 2520: 2507: 2442: 2422: 2278: 2257:{\displaystyle n} 2223: 2196: 1970:{\displaystyle R} 1939: 1884:{\displaystyle n} 1816:{\displaystyle T} 1796:{\displaystyle V} 1783:is the pressure, 1776:{\displaystyle p} 1699: 1698: 1640:Self-organization 1465: 1464: 1163:Gibbs free energy 961:Maxwell relations 919: 918: 915: 914: 881:{\displaystyle V} 834:{\displaystyle 1} 789:Thermal expansion 783: 782: 749:{\displaystyle V} 702:{\displaystyle 1} 648: 647: 614:{\displaystyle N} 567:{\displaystyle T} 495: 494: 411:Process functions 397:Property diagrams 376:System properties 366: 365: 331:Endoreversibility 223:Equation of state 40:equation of state 11070: 10907:Phase transition 10728: 10727: 10690: 10683: 10676: 10667: 10666: 10600:Compressed fluid 10235: 10180:States of matter 10173: 10166: 10159: 10150: 10149: 9967:Combined gas law 9962:Gay-Lussac's law 9933:Capillary action 9798:Damage mechanics 9443: 9436: 9429: 9420: 9419: 9408: 9399: 9393: 9392: 9390: 9388: 9361: 9352: 9346: 9345: 9309: 9303: 9302: 9258: 9252: 9251: 9231: 9225: 9224: 9216: 9210: 9209: 9207: 9205: 9162: 9156: 9155: 9154: 9152: 9129: 9123: 9122: 9120: 9118: 9103: 9097: 9096: 9086: 9068: 9036: 9030: 9029: 8997: 8991: 8990: 8980: 8948: 8942: 8941: 8931: 8883: 8877: 8876: 8844: 8835: 8834: 8809:(6): 1361–1433. 8794: 8785: 8784: 8752: 8741: 8740: 8737:10.1063/1.473101 8711: 8705: 8704: 8695:(8): 1709–1721. 8684: 8678: 8677: 8657: 8648: 8647: 8639: 8628: 8627: 8579: 8573: 8572: 8532: 8526: 8525: 8485: 8479: 8478: 8454: 8448: 8447: 8407: 8401: 8400: 8391:(1–2): 174–183. 8376: 8370: 8369: 8349: 8343: 8342: 8322: 8316: 8315: 8279: 8268: 8267: 8242:(4): 1116–1126. 8227: 8221: 8220: 8188: 8182: 8181: 8134:Prausnitz, J. M. 8129: 8123: 8122: 8090: 8084: 8083: 8051: 8045: 8044: 8008: 8002: 8001: 7993: 7987: 7986: 7961:(5): 1429–1454. 7946: 7940: 7939: 7907: 7898: 7897: 7859: 7853: 7850: 7844: 7843: 7826:(6): 1197–1203. 7815: 7809: 7808: 7777:Chemical Reviews 7772: 7766: 7765: 7757: 7751: 7750: 7732: 7525: 7523: 7522: 7517: 7514: 7513: 7496: 7494: 7493: 7488: 7475: 7473: 7472: 7467: 7465: 7464: 7447: 7445: 7444: 7439: 7437: 7436: 7418: 7416: 7415: 7410: 7395: 7393: 7392: 7387: 7372: 7370: 7369: 7364: 7361: 7360: 7339: 7337: 7336: 7331: 7328: 7327: 7309: 7307: 7306: 7301: 7298: 7297: 7277: 7276: 7273: 7271: 7270: 7265: 7263: 7262: 7246: 7244: 7243: 7238: 7236: 7235: 7216: 7214: 7213: 7208: 7206: 7205: 7189: 7187: 7186: 7181: 7179: 7178: 7162: 7160: 7159: 7154: 7142: 7140: 7139: 7134: 7132: 7131: 7115: 7113: 7112: 7107: 7105: 7104: 7088: 7086: 7085: 7080: 7068: 7066: 7065: 7060: 7048: 7046: 7045: 7040: 7028: 7026: 7025: 7020: 7018: 7017: 7001: 6999: 6998: 6993: 6988: 6983: 6982: 6958: 6956: 6955: 6950: 6948: 6943: 6942: 6941: 6928: 6923: 6919: 6915: 6914: 6891: 6887: 6886: 6884: 6880: 6879: 6866: 6841: 6840: 6819: 6815: 6814: 6812: 6808: 6807: 6794: 6758:begins to form. 6704: 6702: 6701: 6696: 6694: 6693: 6688: 6684: 6682: 6681: 6669: 6662: 6660: 6646: 6633: 6632: 6616: 6612: 6602: 6601: 6564: 6562: 6561: 6556: 6554: 6553: 6537: 6535: 6534: 6529: 6527: 6526: 6510: 6508: 6507: 6502: 6490: 6488: 6487: 6482: 6479: 6474: 6465: 6464: 6430: 6428: 6427: 6422: 6410: 6408: 6407: 6402: 6400: 6399: 6383: 6381: 6380: 6375: 6373: 6372: 6353: 6351: 6350: 6345: 6343: 6342: 6333: 6332: 6317: 6316: 6268: 6266: 6265: 6260: 6255: 6250: 6246: 6245: 6244: 6218: 6217: 6198: 6196: 6195: 6190: 6188: 6187: 6171: 6169: 6168: 6163: 6151: 6149: 6148: 6143: 6129: 6127: 6126: 6121: 6118: 6117: 6065:sonoluminescence 6039: 6037: 6036: 6031: 6029: 6025: 6024: 6023: 6000: 5999: 5995: 5982: 5981: 5972: 5971: 5955: 5950: 5934: 5929: 5911: 5907: 5906: 5905: 5882: 5881: 5877: 5864: 5863: 5854: 5853: 5837: 5832: 5816: 5811: 5793: 5789: 5771: 5770: 5766: 5753: 5752: 5743: 5742: 5726: 5721: 5702: 5697: 5679: 5678: 5674: 5661: 5660: 5651: 5650: 5634: 5629: 5610: 5605: 5587: 5586: 5585: 5541: 5539: 5538: 5533: 5531: 5530: 5514: 5512: 5511: 5506: 5504: 5503: 5485: 5483: 5482: 5477: 5475: 5473: 5472: 5460: 5449: 5444: 5443: 5434: 5419: 5417: 5416: 5411: 5409: 5407: 5399: 5383: 5382: 5381: 5378: 5353: 5352: 5351: 5318: 5313: 5311: 5303: 5283: 5255:hydrogen bonding 5251:Helmholtz energy 5200: 5198: 5197: 5192: 5190: 5186: 5185: 5181: 5178: 5173: 5164: 5156: 5144: 5140: 5139: 5136: 5131: 5119: 5106: 5104: 5102: 5097: 5087: 5082: 5072: 5071: 5062: 5057: 5054: 5049: 5037: 5032: 5029: 5024: 5012: 5007: 5005: 5004: 4992: 4979: 4974: 4966: 4943: 4941: 4940: 4935: 4933: 4932: 4923: 4919: 4918: 4910: 4891: 4890: 4881: 4877: 4876: 4874: 4873: 4861: 4856: 4848: 4820: 4819: 4810: 4806: 4805: 4803: 4802: 4793: 4792: 4783: 4778: 4776: 4775: 4766: 4765: 4756: 4751: 4749: 4748: 4739: 4738: 4729: 4724: 4723: 4705: 4704: 4655:is molar density 4654: 4652: 4651: 4646: 4632: 4630: 4629: 4624: 4607: 4605: 4604: 4599: 4597: 4593: 4592: 4591: 4565: 4561: 4560: 4559: 4536: 4534: 4533: 4524: 4523: 4522: 4509: 4504: 4503: 4494: 4490: 4489: 4481: 4462: 4461: 4452: 4448: 4447: 4439: 4411: 4410: 4401: 4397: 4396: 4394: 4393: 4384: 4383: 4374: 4369: 4367: 4366: 4357: 4356: 4347: 4342: 4340: 4339: 4330: 4329: 4320: 4315: 4314: 4296: 4295: 4214:Kamerlingh Onnes 4205: 4203: 4202: 4197: 4189: 4186: 4181: 4169: 4164: 4161: 4156: 4144: 4139: 4137: 4136: 4124: 4113: 4111: 4103: 4102: 4101: 4088: 4077:Virial expansion 4061: 4059: 4058: 4053: 4051: 4050: 4001: 3999: 3998: 3993: 3988: 3971: 3969: 3968: 3963: 3961: 3957: 3950: 3948: 3947: 3946: 3942: 3926: 3925: 3922: 3906: 3905: 3904: 3891: 3889: 3887: 3864: 3863: 3859: 3846: 3830: 3829: 3826: 3799: 3797: 3796: 3791: 3783: 3782: 3775: 3774: 3771: 3762: 3742: 3740: 3739: 3734: 3726: 3725: 3718: 3717: 3714: 3705: 3683: 3681: 3680: 3675: 3670: 3668: 3661: 3660: 3653: 3652: 3649: 3640: 3620: 3616: 3610: 3609: 3605: 3591: 3588: 3583: 3574: 3572: 3571: 3570: 3561: 3560: 3551: 3546: 3543: 3542: 3541: 3537: 3521: 3520: 3517: 3486: 3481: 3473: 3460: 3458: 3457: 3452: 3444: 3413: 3411: 3410: 3405: 3403: 3402: 3399: 3386: 3384: 3383: 3378: 3376: 3374: 3367: 3366: 3359: 3358: 3355: 3346: 3326: 3322: 3316: 3315: 3311: 3297: 3294: 3289: 3280: 3278: 3277: 3276: 3267: 3266: 3253: 3252: 3250: 3249: 3239: 3234: 3231: 3225: 3224: 3212: 3191: 3174: 3172: 3171: 3166: 3154: 3152: 3151: 3146: 3134: 3132: 3131: 3126: 3114: 3112: 3111: 3106: 3086: 3084: 3083: 3078: 3066: 3064: 3063: 3058: 3038: 3036: 3035: 3030: 3028: 3027: 3011: 3009: 3008: 3003: 3001: 3000: 2984: 2982: 2981: 2976: 2971: 2970: 2944: 2942: 2941: 2936: 2934: 2933: 2924: 2919: 2918: 2892: 2890: 2889: 2884: 2872: 2870: 2869: 2864: 2822: 2820: 2819: 2814: 2752: 2750: 2749: 2744: 2697: 2695: 2694: 2689: 2677: 2675: 2674: 2669: 2654: 2652: 2651: 2646: 2626: 2625: 2613: 2609: 2608: 2605: 2600: 2588: 2539: 2537: 2536: 2531: 2526: 2522: 2521: 2518: 2516: 2515: 2510: 2505: 2498: 2497: 2477: 2476: 2457: 2455: 2454: 2449: 2447: 2440: 2433: 2428: 2427: 2420: 2372: 2370: 2369: 2364: 2359: 2358: 2348: 2343: 2325: 2324: 2306: 2305: 2293: 2292: 2280: 2279: 2276: 2263: 2261: 2260: 2255: 2237: 2235: 2234: 2229: 2224: 2222: 2221: 2212: 2211: 2202: 2197: 2195: 2194: 2185: 2184: 2175: 2147: 2145: 2144: 2139: 2134: 2071: 2069: 2068: 2063: 2061: 2060: 2042: 2040: 2039: 2034: 2032: 2031: 2013: 2011: 2010: 2005: 2003: 2002: 1984: 1976: 1974: 1973: 1968: 1950: 1948: 1947: 1942: 1940: 1932: 1923: 1921: 1920: 1915: 1913: 1912: 1890: 1888: 1887: 1882: 1835:, dense matter ( 1825:Gibbs phase rule 1822: 1820: 1819: 1814: 1803:the volume, and 1802: 1800: 1799: 1794: 1782: 1780: 1779: 1774: 1760: 1758: 1757: 1752: 1691: 1684: 1677: 1661: 1660: 1368:Key publications 1349: 1348:("living force") 1298:Brownian ratchet 1293:Entropy and life 1288:Entropy and time 1239: 1238: 1214: 1212: 1211: 1206: 1159: 1157: 1156: 1151: 1104: 1102: 1101: 1096: 1049: 1047: 1046: 1041: 943:Clausius theorem 938:Carnot's theorem 911: 909: 908: 903: 887: 885: 884: 879: 864: 862: 861: 856: 840: 838: 837: 832: 819: 818: 815: 813: 812: 807: 779: 777: 776: 771: 755: 753: 752: 747: 732: 730: 729: 724: 708: 706: 705: 700: 687: 686: 683: 681: 680: 675: 644: 642: 641: 636: 620: 618: 617: 612: 597: 595: 594: 589: 573: 571: 570: 565: 552: 551: 548: 546: 545: 540: 518: 517: 391: 390: 210: 209: 91: 77: 76: 11078: 11077: 11073: 11072: 11071: 11069: 11068: 11067: 11053:Fluid mechanics 11028: 11027: 11026: 11021: 10966: 10928: 10893: 10875:BBGKY hierarchy 10870:Vlasov equation 10848: 10837:depletion force 10830:Particles with 10790: 10729: 10725: 10720: 10699: 10694: 10664: 10659: 10590:Baryonic matter 10578: 10532: 10503:Saturated fluid 10443:Crystallization 10404: 10378:Antiferromagnet 10318: 10292: 10236: 10227: 10187: 10177: 10147: 10142: 10119: 10051: 10015:Viscoelasticity 10001: 9992:Acoustic theory 9978: 9928:Surface tension 9846:Fluid mechanics 9840: 9834:Sandwich theory 9726:Yield criterion 9721:Viscoplasticity 9692:Viscoelasticity 9653:hyperelasticity 9603: 9587:Antiplane shear 9570:Stress measures 9489: 9470:Fluid mechanics 9465:Solid mechanics 9453: 9447: 9417: 9412: 9411: 9400: 9396: 9386: 9384: 9382: 9359: 9353: 9349: 9314:High Press. Res 9310: 9306: 9263:Rep. Prog. Phys 9259: 9255: 9236:High Press. Res 9232: 9228: 9217: 9213: 9203: 9201: 9163: 9159: 9150: 9148: 9146: 9130: 9126: 9116: 9114: 9104: 9100: 9037: 9033: 8998: 8994: 8949: 8945: 8884: 8880: 8845: 8838: 8795: 8788: 8753: 8744: 8712: 8708: 8685: 8681: 8658: 8651: 8640: 8631: 8580: 8576: 8533: 8529: 8486: 8482: 8455: 8451: 8416:Physical Review 8408: 8404: 8377: 8373: 8350: 8346: 8323: 8319: 8280: 8271: 8228: 8224: 8189: 8185: 8130: 8126: 8091: 8087: 8052: 8048: 8009: 8005: 7994: 7990: 7947: 7943: 7908: 7901: 7878: 7860: 7856: 7851: 7847: 7816: 7812: 7773: 7769: 7758: 7754: 7747: 7733: 7729: 7724: 7692: 7636: 7509: 7505: 7503: 7500: 7499: 7482: 7479: 7478: 7460: 7456: 7454: 7451: 7450: 7432: 7428: 7426: 7423: 7422: 7403: 7400: 7399: 7380: 7377: 7376: 7353: 7349: 7347: 7344: 7343: 7323: 7319: 7317: 7314: 7313: 7293: 7289: 7287: 7284: 7283: 7258: 7254: 7252: 7249: 7248: 7228: 7224: 7222: 7219: 7218: 7201: 7197: 7195: 7192: 7191: 7174: 7170: 7168: 7165: 7164: 7148: 7145: 7144: 7127: 7123: 7121: 7118: 7117: 7100: 7096: 7094: 7091: 7090: 7074: 7071: 7070: 7054: 7051: 7050: 7034: 7031: 7030: 7013: 7009: 7007: 7004: 7003: 6984: 6978: 6974: 6966: 6963: 6962: 6937: 6933: 6929: 6927: 6910: 6906: 6902: 6898: 6875: 6871: 6870: 6865: 6858: 6854: 6836: 6832: 6803: 6799: 6798: 6793: 6786: 6782: 6771: 6768: 6767: 6764: 6753: 6725: 6689: 6677: 6673: 6668: 6664: 6663: 6647: 6622: 6618: 6617: 6615: 6597: 6593: 6588: 6585: 6584: 6575: 6549: 6545: 6543: 6540: 6539: 6522: 6518: 6516: 6513: 6512: 6496: 6493: 6492: 6475: 6470: 6460: 6456: 6448: 6445: 6444: 6437: 6416: 6413: 6412: 6395: 6391: 6389: 6386: 6385: 6368: 6364: 6362: 6359: 6358: 6356: 6338: 6334: 6328: 6324: 6312: 6308: 6300: 6297: 6296: 6295: 6290: 6251: 6240: 6236: 6229: 6225: 6213: 6209: 6207: 6204: 6203: 6183: 6179: 6177: 6174: 6173: 6157: 6154: 6153: 6137: 6134: 6133: 6113: 6109: 6074: 6071: 6070: 6053: 6048: 6019: 6015: 6011: 6007: 5991: 5987: 5983: 5977: 5973: 5961: 5957: 5951: 5940: 5930: 5919: 5901: 5897: 5893: 5889: 5873: 5869: 5865: 5859: 5855: 5843: 5839: 5833: 5822: 5812: 5801: 5782: 5778: 5762: 5758: 5754: 5748: 5744: 5732: 5728: 5722: 5708: 5698: 5687: 5670: 5666: 5662: 5656: 5652: 5640: 5636: 5630: 5616: 5606: 5595: 5560: 5559: 5555: 5553: 5550: 5549: 5526: 5522: 5520: 5517: 5516: 5499: 5495: 5493: 5490: 5489: 5468: 5464: 5459: 5439: 5435: 5433: 5425: 5422: 5421: 5400: 5377: 5376: 5372: 5325: 5324: 5320: 5319: 5317: 5304: 5284: 5282: 5280: 5277: 5276: 5272: 5243: 5231: 5206: 5174: 5169: 5157: 5155: 5151: 5132: 5127: 5118: 5111: 5107: 5098: 5093: 5083: 5078: 5073: 5067: 5063: 5061: 5050: 5045: 5036: 5025: 5020: 5011: 5000: 4996: 4991: 4984: 4980: 4967: 4965: 4957: 4954: 4953: 4928: 4924: 4909: 4902: 4898: 4886: 4882: 4869: 4865: 4860: 4847: 4828: 4824: 4815: 4811: 4798: 4794: 4788: 4784: 4782: 4771: 4767: 4761: 4757: 4755: 4744: 4740: 4734: 4730: 4728: 4719: 4715: 4700: 4696: 4695: 4691: 4671: 4668: 4667: 4640: 4637: 4636: 4618: 4615: 4614: 4587: 4583: 4576: 4572: 4555: 4551: 4541: 4537: 4529: 4525: 4518: 4514: 4510: 4508: 4499: 4495: 4480: 4473: 4469: 4457: 4453: 4438: 4419: 4415: 4406: 4402: 4389: 4385: 4379: 4375: 4373: 4362: 4358: 4352: 4348: 4346: 4335: 4331: 4325: 4321: 4319: 4310: 4306: 4291: 4287: 4286: 4282: 4262: 4259: 4258: 4256: 4250: 4182: 4177: 4168: 4157: 4152: 4143: 4132: 4128: 4123: 4104: 4097: 4093: 4089: 4087: 4085: 4082: 4081: 4079: 4073: 4068: 4046: 4042: 4040: 4037: 4036: 4026: 4020: 3984: 3979: 3976: 3975: 3938: 3934: 3930: 3921: 3917: 3907: 3900: 3896: 3892: 3890: 3865: 3855: 3851: 3847: 3845: 3838: 3834: 3825: 3821: 3807: 3804: 3803: 3770: 3766: 3758: 3754: 3750: 3748: 3745: 3744: 3713: 3709: 3701: 3697: 3693: 3691: 3688: 3687: 3648: 3644: 3636: 3626: 3622: 3621: 3612: 3601: 3597: 3593: 3592: 3590: 3584: 3579: 3566: 3562: 3556: 3552: 3545: 3544: 3533: 3529: 3525: 3516: 3512: 3487: 3485: 3472: 3470: 3467: 3466: 3440: 3423: 3420: 3419: 3398: 3394: 3392: 3389: 3388: 3354: 3350: 3342: 3332: 3328: 3327: 3318: 3307: 3303: 3299: 3298: 3296: 3290: 3285: 3272: 3268: 3262: 3258: 3254: 3245: 3241: 3235: 3230: 3220: 3216: 3211: 3192: 3190: 3182: 3179: 3178: 3160: 3157: 3156: 3140: 3137: 3136: 3120: 3117: 3116: 3100: 3097: 3096: 3072: 3069: 3068: 3052: 3049: 3048: 3045: 3023: 3019: 3017: 3014: 3013: 2996: 2992: 2990: 2987: 2986: 2966: 2962: 2954: 2951: 2950: 2929: 2925: 2920: 2914: 2910: 2902: 2899: 2898: 2878: 2875: 2874: 2834: 2831: 2830: 2760: 2757: 2756: 2720: 2717: 2716: 2715:may be written 2709: 2704: 2683: 2680: 2679: 2663: 2660: 2659: 2621: 2617: 2601: 2596: 2587: 2577: 2573: 2571: 2568: 2567: 2517: 2511: 2509: 2508: 2493: 2489: 2488: 2484: 2472: 2468: 2463: 2460: 2459: 2443: 2429: 2423: 2419: 2414: 2411: 2410: 2399: 2388: 2375:Émile Clapeyron 2354: 2350: 2344: 2333: 2320: 2316: 2301: 2297: 2288: 2284: 2275: 2271: 2269: 2266: 2265: 2249: 2246: 2245: 2217: 2213: 2207: 2203: 2201: 2190: 2186: 2180: 2176: 2174: 2172: 2169: 2168: 2157:Jacques Charles 2109: 2098: 2095: 2094: 2079: 2056: 2052: 2050: 2047: 2046: 2027: 2023: 2021: 2018: 2017: 1998: 1994: 1992: 1989: 1988: 1982: 1962: 1959: 1958: 1931: 1929: 1926: 1925: 1908: 1904: 1902: 1899: 1898: 1876: 1873: 1872: 1808: 1805: 1804: 1788: 1785: 1784: 1768: 1765: 1764: 1719: 1716: 1715: 1704: 1695: 1650: 1649: 1625: 1617: 1616: 1615: 1475: 1467: 1466: 1445: 1431: 1406: 1402: 1395: 1391: 1384: 1380: 1347: 1340: 1322: 1303:Maxwell's demon 1265: 1236: 1235: 1219: 1218: 1217: 1170: 1167: 1166: 1165: 1115: 1112: 1111: 1110: 1060: 1057: 1056: 1055: 1020: 1017: 1016: 1015: 1013:Internal energy 1008: 993: 983: 982: 957: 932: 922: 921: 920: 894: 891: 890: 873: 870: 869: 847: 844: 843: 826: 823: 822: 798: 795: 794: 762: 759: 758: 741: 738: 737: 715: 712: 711: 694: 691: 690: 663: 660: 659: 654:Compressibility 627: 624: 623: 606: 603: 602: 580: 577: 576: 559: 556: 555: 531: 528: 527: 507: 497: 496: 477:Particle number 430: 389: 378: 368: 367: 326:Irreversibility 238:State of matter 205:Isolated system 190: 180: 179: 178: 153: 143: 142: 138:Non-equilibrium 130: 105: 97: 64:internal energy 48:state variables 28: 17: 12: 11: 5: 11076: 11066: 11065: 11060: 11055: 11050: 11045: 11040: 11023: 11022: 11020: 11019: 11018: 11017: 11012: 11007: 11000:Complex system 10997: 10992: 10991: 10990: 10985: 10974: 10972: 10968: 10967: 10965: 10964: 10959: 10954: 10949: 10944: 10938: 10936: 10930: 10929: 10927: 10926: 10925: 10924: 10919: 10909: 10903: 10901: 10895: 10894: 10892: 10891: 10882: 10877: 10872: 10867: 10862: 10856: 10854: 10850: 10849: 10847: 10846: 10845: 10844: 10839: 10828: 10827: 10826: 10821: 10816: 10811: 10800: 10798: 10792: 10791: 10789: 10788: 10783: 10782: 10781: 10776: 10771: 10766: 10755: 10750: 10745: 10739: 10737: 10731: 10730: 10723: 10721: 10719: 10718: 10716:ergodic theory 10713: 10707: 10705: 10701: 10700: 10693: 10692: 10685: 10678: 10670: 10661: 10660: 10658: 10657: 10652: 10647: 10642: 10637: 10632: 10627: 10622: 10617: 10612: 10607: 10602: 10597: 10592: 10586: 10584: 10580: 10579: 10577: 10576: 10571: 10569:Trouton's rule 10566: 10561: 10556: 10551: 10546: 10540: 10538: 10534: 10533: 10531: 10530: 10525: 10520: 10515: 10510: 10505: 10500: 10495: 10490: 10485: 10480: 10475: 10470: 10465: 10460: 10455: 10450: 10445: 10440: 10438:Critical point 10435: 10430: 10425: 10420: 10414: 10412: 10406: 10405: 10403: 10402: 10397: 10392: 10391: 10390: 10385: 10380: 10372: 10367: 10362: 10357: 10352: 10347: 10342: 10340:Liquid crystal 10337: 10332: 10326: 10324: 10320: 10319: 10317: 10316: 10311: 10306: 10300: 10298: 10294: 10293: 10291: 10290: 10285: 10280: 10275: 10273:Strange matter 10270: 10268:Rydberg matter 10265: 10260: 10255: 10250: 10244: 10242: 10238: 10237: 10230: 10228: 10226: 10225: 10220: 10215: 10206: 10201: 10195: 10193: 10189: 10188: 10176: 10175: 10168: 10161: 10153: 10144: 10143: 10141: 10140: 10135: 10129: 10127: 10121: 10120: 10118: 10117: 10112: 10107: 10102: 10097: 10092: 10087: 10082: 10077: 10072: 10067: 10061: 10059: 10053: 10052: 10050: 10049: 10044: 10039: 10038: 10037: 10032: 10027: 10017: 10011: 10009: 10003: 10002: 10000: 9999: 9994: 9988: 9986: 9980: 9979: 9977: 9976: 9970: 9969: 9964: 9959: 9954: 9949: 9943: 9942: 9936: 9935: 9930: 9925: 9920: 9915: 9910: 9905: 9904: 9903: 9898: 9888: 9883: 9878: 9873: 9868: 9866:Fluid dynamics 9863: 9857: 9856: 9850: 9848: 9842: 9841: 9839: 9838: 9837: 9836: 9831: 9826: 9824:Bending moment 9815: 9814: 9808: 9807: 9806: 9805: 9795: 9794: 9793: 9788: 9778: 9773: 9768: 9762: 9761: 9755: 9754: 9753: 9752: 9747: 9737: 9736: 9735: 9734: 9733: 9731:Bresler-Pister 9723: 9718: 9708: 9707: 9706: 9705: 9704: 9702:Concrete creep 9699: 9689: 9684: 9682:hypoelasticity 9679: 9678: 9677: 9672: 9662: 9661: 9660: 9650: 9645: 9640: 9635: 9624: 9623: 9617: 9615: 9605: 9604: 9602: 9601: 9596: 9591: 9590: 9589: 9579: 9574: 9573: 9572: 9567: 9556: 9555: 9551: 9550: 9545: 9540: 9539: 9538: 9533: 9528: 9523: 9518: 9508: 9502: 9501: 9497: 9495: 9491: 9490: 9488: 9487: 9482: 9477: 9472: 9467: 9461: 9459: 9455: 9454: 9446: 9445: 9438: 9431: 9423: 9416: 9415:External links 9413: 9410: 9409: 9394: 9380: 9347: 9304: 9253: 9226: 9211: 9177:(3): 189–232. 9157: 9144: 9124: 9098: 9031: 9012:(3): 265–276. 8992: 8943: 8878: 8859:(2): 387–535. 8836: 8786: 8742: 8706: 8679: 8649: 8629: 8594:(1–2): 19–34. 8574: 8527: 8480: 8449: 8422:(1): 307–316. 8402: 8371: 8344: 8317: 8269: 8222: 8203:(3): 705–717. 8183: 8124: 8085: 8046: 8019:(3): 510–527. 8003: 7988: 7941: 7899: 7876: 7854: 7845: 7810: 7783:(1): 233–244. 7767: 7752: 7745: 7726: 7725: 7723: 7720: 7719: 7718: 7713: 7708: 7703: 7698: 7691: 7688: 7687: 7686: 7681: 7676: 7671: 7666: 7663: 7660: 7657: 7652: 7647: 7635: 7632: 7629: 7628: 7625: 7622: 7619: 7616: 7613: 7610: 7607: 7605: 7602: 7596: 7595: 7592: 7589: 7586: 7583: 7580: 7577: 7574: 7571: 7568: 7562: 7561: 7558: 7555: 7552: 7549: 7546: 7543: 7540: 7537: 7534: 7528: 7527: 7512: 7508: 7497: 7486: 7476: 7463: 7459: 7448: 7435: 7431: 7420: 7407: 7397: 7384: 7374: 7359: 7356: 7352: 7341: 7326: 7322: 7311: 7296: 7292: 7281: 7261: 7257: 7234: 7231: 7227: 7204: 7200: 7177: 7173: 7152: 7130: 7126: 7103: 7099: 7078: 7058: 7038: 7016: 7012: 6991: 6987: 6981: 6977: 6973: 6970: 6946: 6940: 6936: 6932: 6926: 6922: 6918: 6913: 6909: 6905: 6901: 6897: 6894: 6890: 6883: 6878: 6874: 6869: 6864: 6861: 6857: 6853: 6850: 6847: 6844: 6839: 6835: 6831: 6828: 6825: 6822: 6818: 6811: 6806: 6802: 6797: 6792: 6789: 6785: 6781: 6778: 6775: 6763: 6760: 6749: 6723: 6692: 6687: 6680: 6676: 6672: 6667: 6659: 6656: 6653: 6650: 6645: 6642: 6639: 6636: 6631: 6628: 6625: 6621: 6611: 6608: 6605: 6600: 6596: 6592: 6574: 6571: 6567:speed of sound 6552: 6548: 6525: 6521: 6500: 6478: 6473: 6469: 6463: 6459: 6455: 6452: 6436: 6433: 6420: 6398: 6394: 6371: 6367: 6341: 6337: 6331: 6327: 6323: 6320: 6315: 6311: 6307: 6304: 6289: 6286: 6258: 6254: 6249: 6243: 6239: 6235: 6232: 6228: 6224: 6221: 6216: 6212: 6186: 6182: 6161: 6141: 6116: 6112: 6108: 6105: 6102: 6099: 6096: 6093: 6090: 6087: 6084: 6081: 6078: 6052: 6049: 6047: 6044: 6028: 6022: 6018: 6014: 6010: 6006: 6003: 5998: 5994: 5990: 5986: 5980: 5976: 5970: 5967: 5964: 5960: 5954: 5949: 5946: 5943: 5939: 5933: 5928: 5925: 5922: 5918: 5914: 5910: 5904: 5900: 5896: 5892: 5888: 5885: 5880: 5876: 5872: 5868: 5862: 5858: 5852: 5849: 5846: 5842: 5836: 5831: 5828: 5825: 5821: 5815: 5810: 5807: 5804: 5800: 5796: 5792: 5788: 5785: 5781: 5777: 5774: 5769: 5765: 5761: 5757: 5751: 5747: 5741: 5738: 5735: 5731: 5725: 5720: 5717: 5714: 5711: 5707: 5701: 5696: 5693: 5690: 5686: 5682: 5677: 5673: 5669: 5665: 5659: 5655: 5649: 5646: 5643: 5639: 5633: 5628: 5625: 5622: 5619: 5615: 5609: 5604: 5601: 5598: 5594: 5590: 5584: 5581: 5578: 5575: 5572: 5569: 5566: 5563: 5558: 5529: 5525: 5502: 5498: 5471: 5467: 5463: 5458: 5455: 5452: 5447: 5442: 5438: 5432: 5429: 5406: 5403: 5398: 5395: 5392: 5389: 5386: 5375: 5371: 5368: 5365: 5362: 5359: 5356: 5350: 5347: 5344: 5340: 5337: 5334: 5331: 5328: 5323: 5316: 5310: 5307: 5302: 5299: 5296: 5293: 5290: 5287: 5271: 5268: 5242: 5239: 5230: 5227: 5205: 5202: 5189: 5184: 5177: 5172: 5168: 5163: 5160: 5154: 5150: 5147: 5143: 5135: 5130: 5126: 5122: 5117: 5114: 5110: 5101: 5096: 5092: 5086: 5081: 5077: 5070: 5066: 5060: 5053: 5048: 5044: 5040: 5035: 5028: 5023: 5019: 5015: 5010: 5003: 4999: 4995: 4990: 4987: 4983: 4977: 4973: 4970: 4964: 4961: 4931: 4927: 4922: 4916: 4913: 4908: 4905: 4901: 4897: 4894: 4889: 4885: 4880: 4872: 4868: 4864: 4859: 4854: 4851: 4846: 4843: 4840: 4837: 4834: 4831: 4827: 4823: 4818: 4814: 4809: 4801: 4797: 4791: 4787: 4781: 4774: 4770: 4764: 4760: 4754: 4747: 4743: 4737: 4733: 4727: 4722: 4718: 4714: 4711: 4708: 4703: 4699: 4694: 4690: 4687: 4684: 4681: 4678: 4675: 4657: 4656: 4644: 4634: 4622: 4596: 4590: 4586: 4582: 4579: 4575: 4571: 4568: 4564: 4558: 4554: 4550: 4547: 4544: 4540: 4532: 4528: 4521: 4517: 4513: 4507: 4502: 4498: 4493: 4487: 4484: 4479: 4476: 4472: 4468: 4465: 4460: 4456: 4451: 4445: 4442: 4437: 4434: 4431: 4428: 4425: 4422: 4418: 4414: 4409: 4405: 4400: 4392: 4388: 4382: 4378: 4372: 4365: 4361: 4355: 4351: 4345: 4338: 4334: 4328: 4324: 4318: 4313: 4309: 4305: 4302: 4299: 4294: 4290: 4285: 4281: 4278: 4275: 4272: 4269: 4266: 4252:Main article: 4249: 4246: 4195: 4192: 4185: 4180: 4176: 4172: 4167: 4160: 4155: 4151: 4147: 4142: 4135: 4131: 4127: 4122: 4119: 4116: 4110: 4107: 4100: 4096: 4092: 4075:Main article: 4072: 4069: 4067: 4064: 4049: 4045: 4033:cubic function 4022:Main article: 4019: 4016: 3991: 3987: 3983: 3960: 3956: 3953: 3945: 3941: 3937: 3933: 3929: 3920: 3916: 3913: 3910: 3903: 3899: 3895: 3886: 3883: 3880: 3877: 3874: 3871: 3868: 3862: 3858: 3854: 3850: 3844: 3841: 3837: 3833: 3824: 3820: 3817: 3814: 3811: 3789: 3786: 3781: 3778: 3769: 3765: 3761: 3757: 3753: 3732: 3729: 3724: 3721: 3712: 3708: 3704: 3700: 3696: 3673: 3667: 3664: 3659: 3656: 3647: 3643: 3639: 3635: 3632: 3629: 3625: 3619: 3615: 3608: 3604: 3600: 3596: 3587: 3582: 3578: 3569: 3565: 3559: 3555: 3549: 3540: 3536: 3532: 3528: 3524: 3515: 3511: 3508: 3505: 3502: 3499: 3496: 3493: 3490: 3484: 3479: 3476: 3450: 3447: 3443: 3439: 3436: 3433: 3430: 3427: 3397: 3373: 3370: 3365: 3362: 3353: 3349: 3345: 3341: 3338: 3335: 3331: 3325: 3321: 3314: 3310: 3306: 3302: 3293: 3288: 3284: 3275: 3271: 3265: 3261: 3257: 3248: 3244: 3238: 3229: 3223: 3219: 3215: 3210: 3207: 3204: 3201: 3198: 3195: 3189: 3186: 3164: 3144: 3124: 3104: 3076: 3056: 3044: 3041: 3026: 3022: 2999: 2995: 2974: 2969: 2965: 2961: 2958: 2932: 2928: 2923: 2917: 2913: 2909: 2906: 2895:number density 2882: 2862: 2859: 2856: 2853: 2850: 2847: 2844: 2841: 2838: 2812: 2809: 2806: 2803: 2800: 2797: 2794: 2791: 2788: 2785: 2782: 2779: 2776: 2773: 2770: 2767: 2764: 2742: 2739: 2736: 2733: 2730: 2727: 2724: 2711:The classical 2708: 2705: 2703: 2700: 2687: 2667: 2656: 2655: 2644: 2641: 2638: 2635: 2632: 2629: 2624: 2620: 2616: 2612: 2604: 2599: 2595: 2591: 2586: 2583: 2580: 2576: 2529: 2525: 2514: 2504: 2501: 2496: 2492: 2487: 2483: 2480: 2475: 2471: 2467: 2446: 2439: 2436: 2432: 2426: 2418: 2397: 2386: 2362: 2357: 2353: 2347: 2342: 2339: 2336: 2332: 2328: 2323: 2319: 2315: 2312: 2309: 2304: 2300: 2296: 2291: 2287: 2283: 2274: 2253: 2227: 2220: 2216: 2210: 2206: 2200: 2193: 2189: 2183: 2179: 2137: 2133: 2130: 2127: 2124: 2121: 2118: 2115: 2112: 2108: 2105: 2102: 2078: 2075: 2074: 2073: 2059: 2055: 2044: 2030: 2026: 2015: 2001: 1997: 1986: 1966: 1956: 1938: 1935: 1911: 1907: 1896: 1895:of a substance 1880: 1812: 1792: 1772: 1750: 1747: 1744: 1741: 1738: 1735: 1732: 1729: 1726: 1723: 1703: 1700: 1697: 1696: 1694: 1693: 1686: 1679: 1671: 1668: 1667: 1666: 1665: 1652: 1651: 1648: 1647: 1642: 1637: 1632: 1626: 1623: 1622: 1619: 1618: 1614: 1613: 1608: 1603: 1598: 1593: 1588: 1583: 1578: 1573: 1568: 1563: 1558: 1553: 1548: 1543: 1538: 1533: 1528: 1523: 1518: 1513: 1508: 1503: 1498: 1493: 1488: 1483: 1477: 1476: 1473: 1472: 1469: 1468: 1463: 1462: 1461: 1460: 1455: 1447: 1446: 1444: 1443: 1440: 1436: 1433: 1432: 1430: 1429: 1424: 1422:Thermodynamics 1418: 1415: 1414: 1410: 1409: 1408: 1407: 1398: 1396: 1387: 1385: 1376: 1371: 1370: 1364: 1363: 1362: 1361: 1356: 1351: 1339: 1338: 1336:Caloric theory 1332: 1329: 1328: 1324: 1323: 1321: 1320: 1315: 1310: 1305: 1300: 1295: 1290: 1284: 1281: 1280: 1274: 1273: 1272: 1271: 1264: 1263: 1258: 1253: 1247: 1244: 1243: 1237: 1234: 1233: 1230: 1226: 1225: 1224: 1221: 1220: 1216: 1215: 1204: 1201: 1198: 1195: 1192: 1189: 1186: 1183: 1180: 1177: 1174: 1160: 1149: 1146: 1143: 1140: 1137: 1134: 1131: 1128: 1125: 1122: 1119: 1105: 1094: 1091: 1088: 1085: 1082: 1079: 1076: 1073: 1070: 1067: 1064: 1050: 1039: 1036: 1033: 1030: 1027: 1024: 1009: 1007: 1006: 1001: 995: 994: 989: 988: 985: 984: 981: 980: 973: 968: 963: 956: 955: 950: 945: 940: 934: 933: 928: 927: 924: 923: 917: 916: 913: 912: 901: 898: 888: 877: 866: 865: 854: 851: 841: 830: 816: 805: 802: 792: 785: 784: 781: 780: 769: 766: 756: 745: 734: 733: 722: 719: 709: 698: 684: 673: 670: 667: 657: 650: 649: 646: 645: 634: 631: 621: 610: 599: 598: 587: 584: 574: 563: 549: 538: 535: 525: 516: 515: 514: 508: 503: 502: 499: 498: 493: 492: 491: 490: 485: 480: 469: 458: 439: 438: 432: 431: 429: 428: 423: 417: 414: 413: 407: 406: 405: 404: 399: 380: 379: 374: 373: 370: 369: 364: 363: 362: 361: 356: 351: 343: 342: 336: 335: 334: 333: 328: 323: 318: 316:Free expansion 313: 308: 303: 298: 293: 288: 283: 278: 270: 269: 263: 262: 261: 260: 255: 253:Control volume 250: 245: 243:Phase (matter) 240: 235: 230: 225: 217: 216: 208: 207: 202: 197: 191: 186: 185: 182: 181: 177: 176: 171: 166: 161: 155: 154: 149: 148: 145: 144: 141: 140: 129: 128: 123: 118: 113: 107: 106: 103: 102: 99: 98: 93:The classical 92: 84: 83: 81:Thermodynamics 15: 9: 6: 4: 3: 2: 11075: 11064: 11061: 11059: 11056: 11054: 11051: 11049: 11046: 11044: 11041: 11039: 11036: 11035: 11033: 11016: 11013: 11011: 11008: 11006: 11003: 11002: 11001: 10998: 10996: 10993: 10989: 10988:superfluidity 10986: 10984: 10981: 10980: 10979: 10976: 10975: 10973: 10969: 10963: 10960: 10958: 10955: 10953: 10950: 10948: 10945: 10943: 10940: 10939: 10937: 10935: 10931: 10923: 10920: 10918: 10915: 10914: 10913: 10910: 10908: 10905: 10904: 10902: 10900: 10896: 10890: 10886: 10883: 10881: 10878: 10876: 10873: 10871: 10868: 10866: 10863: 10861: 10858: 10857: 10855: 10851: 10843: 10840: 10838: 10835: 10834: 10833: 10829: 10825: 10822: 10820: 10817: 10815: 10812: 10810: 10807: 10806: 10805: 10802: 10801: 10799: 10797: 10793: 10787: 10784: 10780: 10777: 10775: 10772: 10770: 10767: 10765: 10762: 10761: 10759: 10756: 10754: 10751: 10749: 10746: 10744: 10741: 10740: 10738: 10736: 10732: 10717: 10714: 10712: 10709: 10708: 10706: 10702: 10698: 10691: 10686: 10684: 10679: 10677: 10672: 10671: 10668: 10656: 10653: 10651: 10648: 10646: 10643: 10641: 10638: 10636: 10633: 10631: 10628: 10626: 10625:Mpemba effect 10623: 10621: 10618: 10616: 10613: 10611: 10608: 10606: 10605:Cooling curve 10603: 10601: 10598: 10596: 10593: 10591: 10588: 10587: 10585: 10581: 10575: 10572: 10570: 10567: 10565: 10562: 10560: 10557: 10555: 10552: 10550: 10547: 10545: 10542: 10541: 10539: 10535: 10529: 10528:Vitrification 10526: 10524: 10521: 10519: 10516: 10514: 10511: 10509: 10506: 10504: 10501: 10499: 10496: 10494: 10493:Recombination 10491: 10489: 10488:Melting point 10486: 10484: 10481: 10479: 10476: 10474: 10471: 10469: 10466: 10464: 10461: 10459: 10456: 10454: 10451: 10449: 10446: 10444: 10441: 10439: 10436: 10434: 10433:Critical line 10431: 10429: 10426: 10424: 10423:Boiling point 10421: 10419: 10416: 10415: 10413: 10411: 10407: 10401: 10398: 10396: 10393: 10389: 10386: 10384: 10381: 10379: 10376: 10375: 10373: 10371: 10368: 10366: 10363: 10361: 10358: 10356: 10355:Exotic matter 10353: 10351: 10348: 10346: 10343: 10341: 10338: 10336: 10333: 10331: 10328: 10327: 10325: 10321: 10315: 10312: 10310: 10307: 10305: 10302: 10301: 10299: 10295: 10289: 10286: 10284: 10281: 10279: 10276: 10274: 10271: 10269: 10266: 10264: 10261: 10259: 10256: 10254: 10251: 10249: 10246: 10245: 10243: 10239: 10234: 10224: 10221: 10219: 10216: 10214: 10210: 10207: 10205: 10202: 10200: 10197: 10196: 10194: 10190: 10185: 10181: 10174: 10169: 10167: 10162: 10160: 10155: 10154: 10151: 10139: 10136: 10134: 10133:Eringen Medal 10131: 10130: 10128: 10126: 10122: 10116: 10113: 10111: 10108: 10106: 10103: 10101: 10098: 10096: 10093: 10091: 10088: 10086: 10083: 10081: 10078: 10076: 10073: 10071: 10068: 10066: 10063: 10062: 10060: 10058: 10054: 10048: 10045: 10043: 10040: 10036: 10033: 10031: 10028: 10026: 10023: 10022: 10021: 10018: 10016: 10013: 10012: 10010: 10008: 10004: 9998: 9997:Aeroacoustics 9995: 9993: 9990: 9989: 9987: 9985: 9981: 9975: 9972: 9971: 9968: 9965: 9963: 9960: 9958: 9957:Charles's law 9955: 9953: 9950: 9948: 9945: 9944: 9941: 9938: 9937: 9934: 9931: 9929: 9926: 9924: 9921: 9919: 9916: 9914: 9911: 9909: 9906: 9902: 9901:Non-Newtonian 9899: 9897: 9894: 9893: 9892: 9889: 9887: 9884: 9882: 9879: 9877: 9874: 9872: 9869: 9867: 9864: 9862: 9861:Fluid statics 9859: 9858: 9855: 9852: 9851: 9849: 9847: 9843: 9835: 9832: 9830: 9827: 9825: 9822: 9821: 9820: 9817: 9816: 9813: 9810: 9809: 9804: 9801: 9800: 9799: 9796: 9792: 9789: 9787: 9784: 9783: 9782: 9779: 9777: 9774: 9772: 9769: 9767: 9764: 9763: 9760: 9757: 9756: 9751: 9748: 9746: 9743: 9742: 9741: 9738: 9732: 9729: 9728: 9727: 9724: 9722: 9719: 9717: 9714: 9713: 9712: 9709: 9703: 9700: 9698: 9695: 9694: 9693: 9690: 9688: 9685: 9683: 9680: 9676: 9673: 9671: 9668: 9667: 9666: 9663: 9659: 9656: 9655: 9654: 9651: 9649: 9646: 9644: 9641: 9639: 9636: 9634: 9631: 9630: 9629: 9626: 9625: 9622: 9619: 9618: 9616: 9614: 9610: 9606: 9600: 9599:Compatibility 9597: 9595: 9592: 9588: 9585: 9584: 9583: 9580: 9578: 9575: 9571: 9568: 9566: 9565:Cauchy stress 9563: 9562: 9561: 9558: 9557: 9553: 9552: 9549: 9546: 9544: 9541: 9537: 9534: 9532: 9529: 9527: 9524: 9522: 9519: 9517: 9516:Navier-Stokes 9514: 9513: 9512: 9509: 9507: 9504: 9503: 9499: 9498: 9496: 9492: 9486: 9483: 9481: 9478: 9476: 9473: 9471: 9468: 9466: 9463: 9462: 9460: 9456: 9452: 9444: 9439: 9437: 9432: 9430: 9425: 9424: 9421: 9407: 9404: 9398: 9383: 9377: 9373: 9369: 9365: 9358: 9351: 9343: 9339: 9335: 9331: 9327: 9323: 9320:(2): 81–126. 9319: 9315: 9308: 9300: 9296: 9292: 9288: 9284: 9280: 9276: 9272: 9268: 9264: 9257: 9249: 9245: 9241: 9237: 9230: 9222: 9215: 9200: 9196: 9192: 9188: 9184: 9180: 9176: 9172: 9168: 9161: 9147: 9145:9783662038857 9141: 9137: 9136: 9128: 9113: 9109: 9102: 9094: 9090: 9085: 9080: 9076: 9072: 9067: 9062: 9058: 9054: 9051:(4): e09328. 9050: 9046: 9042: 9035: 9027: 9023: 9019: 9015: 9011: 9008:(in French). 9007: 9003: 8996: 8988: 8984: 8979: 8974: 8970: 8966: 8962: 8958: 8954: 8947: 8939: 8935: 8930: 8925: 8921: 8917: 8913: 8909: 8905: 8901: 8897: 8893: 8889: 8882: 8874: 8870: 8866: 8862: 8858: 8854: 8850: 8843: 8841: 8832: 8828: 8824: 8820: 8816: 8812: 8808: 8804: 8800: 8793: 8791: 8782: 8778: 8774: 8770: 8766: 8762: 8758: 8751: 8749: 8747: 8738: 8734: 8730: 8726: 8722: 8718: 8710: 8702: 8698: 8694: 8690: 8683: 8675: 8671: 8668:: 1057–1079. 8667: 8663: 8656: 8654: 8645: 8638: 8636: 8634: 8625: 8621: 8617: 8613: 8609: 8605: 8601: 8597: 8593: 8589: 8585: 8578: 8570: 8566: 8562: 8558: 8554: 8550: 8546: 8542: 8538: 8531: 8523: 8519: 8515: 8511: 8507: 8503: 8499: 8495: 8491: 8484: 8476: 8472: 8468: 8464: 8460: 8453: 8445: 8441: 8437: 8433: 8429: 8425: 8421: 8417: 8413: 8406: 8398: 8394: 8390: 8386: 8382: 8375: 8367: 8363: 8359: 8355: 8348: 8340: 8336: 8332: 8328: 8321: 8313: 8309: 8305: 8301: 8297: 8293: 8289: 8285: 8278: 8276: 8274: 8265: 8261: 8257: 8253: 8249: 8245: 8241: 8237: 8236:AIChE Journal 8233: 8226: 8218: 8214: 8210: 8206: 8202: 8198: 8197:AIChE Journal 8194: 8187: 8179: 8175: 8171: 8167: 8163: 8159: 8155: 8151: 8147: 8143: 8142:AIChE Journal 8139: 8135: 8128: 8120: 8116: 8112: 8108: 8104: 8100: 8096: 8089: 8081: 8077: 8073: 8069: 8065: 8061: 8057: 8050: 8042: 8038: 8034: 8030: 8026: 8022: 8018: 8015:(in French). 8014: 8013:AIChE Journal 8007: 7999: 7992: 7984: 7980: 7976: 7972: 7968: 7964: 7960: 7956: 7952: 7945: 7937: 7933: 7929: 7925: 7921: 7917: 7913: 7906: 7904: 7895: 7891: 7887: 7883: 7879: 7873: 7869: 7865: 7858: 7849: 7841: 7837: 7833: 7829: 7825: 7821: 7814: 7806: 7802: 7798: 7794: 7790: 7786: 7782: 7778: 7771: 7763: 7756: 7748: 7742: 7738: 7731: 7727: 7717: 7714: 7712: 7709: 7707: 7704: 7702: 7699: 7697: 7694: 7693: 7685: 7682: 7680: 7677: 7675: 7672: 7670: 7667: 7664: 7661: 7658: 7656: 7653: 7651: 7648: 7645: 7644:Tait equation 7641: 7640:Tait equation 7638: 7637: 7626: 7623: 7620: 7617: 7614: 7611: 7608: 7606: 7603: 7601: 7598: 7597: 7593: 7590: 7587: 7584: 7581: 7578: 7575: 7572: 7569: 7567: 7566:Composition B 7564: 7563: 7559: 7556: 7553: 7550: 7547: 7544: 7541: 7538: 7535: 7533: 7530: 7529: 7510: 7506: 7498: 7484: 7477: 7461: 7457: 7449: 7433: 7429: 7421: 7405: 7398: 7382: 7375: 7357: 7354: 7350: 7342: 7324: 7320: 7312: 7294: 7290: 7282: 7279: 7278: 7275: 7259: 7255: 7232: 7229: 7225: 7202: 7198: 7175: 7171: 7150: 7128: 7124: 7101: 7097: 7076: 7056: 7036: 7014: 7010: 6989: 6985: 6979: 6975: 6971: 6968: 6959: 6944: 6938: 6934: 6930: 6924: 6920: 6916: 6911: 6907: 6903: 6899: 6895: 6892: 6888: 6881: 6876: 6872: 6867: 6862: 6859: 6855: 6851: 6848: 6842: 6837: 6833: 6829: 6823: 6820: 6816: 6809: 6804: 6800: 6795: 6790: 6787: 6783: 6779: 6776: 6773: 6759: 6757: 6752: 6748: 6744: 6740: 6739:polylogarithm 6736: 6732: 6728: 6722: 6718: 6714: 6710: 6705: 6690: 6685: 6678: 6674: 6670: 6665: 6654: 6648: 6640: 6634: 6629: 6626: 6623: 6619: 6609: 6606: 6603: 6598: 6594: 6590: 6582: 6580: 6570: 6568: 6550: 6546: 6523: 6519: 6498: 6476: 6471: 6467: 6461: 6457: 6453: 6450: 6442: 6432: 6418: 6396: 6369: 6354: 6339: 6335: 6329: 6321: 6318: 6313: 6305: 6302: 6293: 6285: 6283: 6278: 6275: 6270: 6256: 6252: 6247: 6241: 6237: 6233: 6230: 6226: 6222: 6219: 6214: 6210: 6200: 6184: 6180: 6159: 6139: 6130: 6114: 6110: 6106: 6103: 6100: 6094: 6091: 6088: 6082: 6079: 6076: 6068: 6066: 6062: 6058: 6043: 6040: 6026: 6020: 6016: 6012: 6008: 6004: 6001: 5996: 5992: 5988: 5984: 5978: 5974: 5968: 5965: 5962: 5958: 5952: 5947: 5944: 5941: 5937: 5931: 5926: 5923: 5920: 5916: 5912: 5908: 5902: 5898: 5894: 5890: 5886: 5883: 5878: 5874: 5870: 5866: 5860: 5856: 5850: 5847: 5844: 5840: 5834: 5829: 5826: 5823: 5819: 5813: 5808: 5805: 5802: 5798: 5794: 5790: 5786: 5783: 5779: 5775: 5772: 5767: 5763: 5759: 5755: 5749: 5745: 5739: 5736: 5733: 5729: 5723: 5718: 5715: 5712: 5709: 5705: 5699: 5694: 5691: 5688: 5684: 5680: 5675: 5671: 5667: 5663: 5657: 5653: 5647: 5644: 5641: 5637: 5631: 5626: 5623: 5620: 5617: 5613: 5607: 5602: 5599: 5596: 5592: 5588: 5556: 5547: 5544: 5527: 5523: 5500: 5496: 5486: 5469: 5465: 5461: 5456: 5453: 5450: 5445: 5440: 5436: 5430: 5427: 5404: 5401: 5393: 5390: 5387: 5373: 5369: 5363: 5360: 5357: 5321: 5314: 5308: 5305: 5297: 5294: 5291: 5285: 5267: 5264: 5260: 5256: 5252: 5248: 5238: 5235: 5226: 5224: 5220: 5216: 5211: 5201: 5187: 5182: 5175: 5170: 5166: 5161: 5158: 5152: 5148: 5145: 5141: 5133: 5128: 5124: 5120: 5115: 5112: 5108: 5099: 5094: 5090: 5084: 5079: 5075: 5068: 5064: 5058: 5051: 5046: 5042: 5038: 5033: 5026: 5021: 5017: 5013: 5008: 5001: 4997: 4993: 4988: 4985: 4981: 4975: 4971: 4968: 4962: 4959: 4951: 4948: 4944: 4929: 4925: 4920: 4914: 4911: 4906: 4903: 4899: 4895: 4892: 4887: 4883: 4878: 4870: 4866: 4862: 4857: 4852: 4849: 4844: 4841: 4838: 4835: 4832: 4829: 4825: 4821: 4816: 4812: 4807: 4799: 4795: 4789: 4785: 4779: 4772: 4768: 4762: 4758: 4752: 4745: 4741: 4735: 4731: 4725: 4720: 4716: 4712: 4709: 4706: 4701: 4697: 4692: 4688: 4685: 4682: 4679: 4676: 4673: 4664: 4662: 4642: 4635: 4620: 4613: 4612: 4611: 4608: 4594: 4588: 4584: 4580: 4577: 4573: 4569: 4566: 4562: 4556: 4552: 4548: 4545: 4542: 4538: 4530: 4526: 4519: 4515: 4511: 4505: 4500: 4496: 4491: 4485: 4482: 4477: 4474: 4470: 4466: 4463: 4458: 4454: 4449: 4443: 4440: 4435: 4432: 4429: 4426: 4423: 4420: 4416: 4412: 4407: 4403: 4398: 4390: 4386: 4380: 4376: 4370: 4363: 4359: 4353: 4349: 4343: 4336: 4332: 4326: 4322: 4316: 4311: 4307: 4303: 4300: 4297: 4292: 4288: 4283: 4279: 4276: 4273: 4270: 4267: 4264: 4255: 4245: 4243: 4239: 4235: 4231: 4227: 4223: 4219: 4215: 4211: 4206: 4193: 4190: 4183: 4178: 4174: 4170: 4165: 4158: 4153: 4149: 4145: 4140: 4133: 4129: 4125: 4120: 4117: 4114: 4108: 4105: 4098: 4094: 4090: 4078: 4063: 4047: 4043: 4034: 4030: 4025: 4015: 4013: 4009: 4005: 3989: 3985: 3981: 3972: 3958: 3954: 3951: 3943: 3939: 3935: 3927: 3918: 3914: 3908: 3901: 3897: 3893: 3881: 3878: 3875: 3872: 3866: 3860: 3856: 3852: 3848: 3842: 3839: 3835: 3831: 3822: 3818: 3815: 3812: 3809: 3801: 3787: 3784: 3776: 3767: 3759: 3755: 3751: 3730: 3727: 3719: 3710: 3702: 3698: 3694: 3684: 3671: 3665: 3662: 3654: 3645: 3637: 3633: 3630: 3627: 3623: 3617: 3606: 3602: 3598: 3594: 3580: 3576: 3567: 3563: 3557: 3553: 3547: 3538: 3534: 3530: 3522: 3513: 3509: 3500: 3497: 3494: 3491: 3482: 3477: 3474: 3464: 3445: 3441: 3437: 3434: 3431: 3425: 3417: 3395: 3371: 3368: 3360: 3351: 3343: 3339: 3336: 3333: 3329: 3323: 3312: 3308: 3304: 3300: 3286: 3282: 3273: 3269: 3263: 3259: 3255: 3246: 3242: 3236: 3227: 3221: 3217: 3213: 3205: 3202: 3199: 3196: 3187: 3184: 3176: 3162: 3155:and pressure 3142: 3122: 3102: 3094: 3090: 3074: 3054: 3040: 3024: 3020: 2997: 2993: 2972: 2967: 2963: 2959: 2956: 2948: 2930: 2926: 2921: 2915: 2911: 2907: 2904: 2896: 2880: 2860: 2854: 2851: 2848: 2842: 2839: 2836: 2828: 2823: 2810: 2807: 2804: 2801: 2798: 2795: 2792: 2789: 2786: 2780: 2777: 2774: 2771: 2768: 2762: 2753: 2740: 2737: 2734: 2731: 2728: 2725: 2722: 2714: 2713:ideal gas law 2702:Ideal gas law 2699: 2685: 2665: 2642: 2639: 2636: 2630: 2627: 2622: 2618: 2610: 2602: 2597: 2593: 2589: 2584: 2581: 2578: 2574: 2566: 2565: 2564: 2561: 2559: 2555: 2551: 2547: 2543: 2527: 2523: 2512: 2502: 2499: 2494: 2490: 2485: 2481: 2478: 2473: 2469: 2465: 2437: 2434: 2424: 2416: 2408: 2404: 2400: 2393: 2389: 2382: 2381: 2380:ideal gas law 2376: 2360: 2355: 2351: 2345: 2340: 2337: 2334: 2330: 2326: 2321: 2317: 2313: 2310: 2307: 2302: 2298: 2294: 2289: 2285: 2281: 2272: 2251: 2242: 2240: 2225: 2218: 2214: 2208: 2204: 2198: 2191: 2187: 2181: 2177: 2166: 2162: 2161:Charles's law 2158: 2153: 2151: 2150:Edme Mariotte 2135: 2106: 2103: 2100: 2091: 2087: 2083: 2057: 2053: 2045: 2028: 2024: 2016: 1999: 1995: 1987: 1980: 1964: 1957: 1954: 1936: 1933: 1909: 1905: 1897: 1894: 1878: 1871: 1870: 1869: 1867: 1863: 1859: 1854: 1852: 1847: 1845: 1842: 1841:perfect fluid 1838: 1834: 1833:neutron stars 1828: 1826: 1810: 1790: 1770: 1761: 1748: 1745: 1739: 1736: 1733: 1730: 1727: 1721: 1712: 1710: 1709:ideal gas law 1692: 1687: 1685: 1680: 1678: 1673: 1672: 1670: 1669: 1664: 1656: 1655: 1654: 1653: 1646: 1643: 1641: 1638: 1636: 1635:Self-assembly 1633: 1631: 1628: 1627: 1621: 1620: 1612: 1609: 1607: 1606:van der Waals 1604: 1602: 1599: 1597: 1594: 1592: 1589: 1587: 1584: 1582: 1579: 1577: 1574: 1572: 1569: 1567: 1564: 1562: 1559: 1557: 1554: 1552: 1549: 1547: 1544: 1542: 1539: 1537: 1534: 1532: 1531:von Helmholtz 1529: 1527: 1524: 1522: 1519: 1517: 1514: 1512: 1509: 1507: 1504: 1502: 1499: 1497: 1494: 1492: 1489: 1487: 1484: 1482: 1479: 1478: 1471: 1470: 1459: 1456: 1454: 1451: 1450: 1449: 1448: 1441: 1438: 1437: 1435: 1434: 1428: 1425: 1423: 1420: 1419: 1417: 1416: 1412: 1411: 1405: 1404: 1397: 1394: 1393: 1386: 1383: 1382: 1375: 1374: 1373: 1372: 1369: 1366: 1365: 1360: 1357: 1355: 1352: 1350: 1346: 1342: 1341: 1337: 1334: 1333: 1331: 1330: 1326: 1325: 1319: 1316: 1314: 1311: 1309: 1306: 1304: 1301: 1299: 1296: 1294: 1291: 1289: 1286: 1285: 1283: 1282: 1279: 1276: 1275: 1270: 1267: 1266: 1262: 1259: 1257: 1254: 1252: 1249: 1248: 1246: 1245: 1241: 1240: 1231: 1228: 1227: 1223: 1222: 1202: 1199: 1196: 1193: 1190: 1184: 1181: 1178: 1172: 1164: 1161: 1147: 1144: 1141: 1138: 1135: 1129: 1126: 1123: 1117: 1109: 1106: 1092: 1089: 1086: 1083: 1080: 1074: 1071: 1068: 1062: 1054: 1051: 1034: 1031: 1028: 1022: 1014: 1011: 1010: 1005: 1002: 1000: 997: 996: 992: 987: 986: 979: 978: 974: 972: 969: 967: 964: 962: 959: 958: 954: 953:Ideal gas law 951: 949: 946: 944: 941: 939: 936: 935: 931: 926: 925: 899: 889: 875: 868: 867: 852: 842: 828: 821: 820: 817: 803: 800: 793: 790: 787: 786: 767: 757: 743: 736: 735: 720: 710: 696: 689: 688: 685: 671: 668: 665: 658: 655: 652: 651: 632: 622: 608: 601: 600: 585: 575: 561: 554: 553: 550: 536: 533: 526: 523: 520: 519: 513: 510: 509: 506: 501: 500: 489: 486: 484: 483:Vapor quality 481: 479: 478: 473: 470: 468: 467: 462: 459: 456: 452: 451: 446: 443: 442: 441: 440: 437: 434: 433: 427: 424: 422: 419: 418: 416: 415: 412: 409: 408: 403: 400: 398: 395: 394: 393: 392: 388: 384: 377: 372: 371: 360: 357: 355: 352: 350: 347: 346: 345: 344: 341: 338: 337: 332: 329: 327: 324: 322: 321:Reversibility 319: 317: 314: 312: 309: 307: 304: 302: 299: 297: 294: 292: 289: 287: 284: 282: 279: 277: 274: 273: 272: 271: 268: 265: 264: 259: 256: 254: 251: 249: 246: 244: 241: 239: 236: 234: 231: 229: 226: 224: 221: 220: 219: 218: 215: 212: 211: 206: 203: 201: 198: 196: 195:Closed system 193: 192: 189: 184: 183: 175: 172: 170: 167: 165: 162: 160: 157: 156: 152: 147: 146: 139: 135: 132: 131: 127: 124: 122: 119: 117: 114: 112: 109: 108: 101: 100: 96: 90: 86: 85: 82: 79: 78: 75: 73: 69: 65: 61: 57: 53: 49: 45: 41: 37: 33: 26: 22: 10971:Applications 10922:size scaling 10752: 10650:Superheating 10609: 10523:Vaporization 10518:Triple point 10513:Supercooling 10478:Lambda point 10428:Condensation 10345:Time crystal 10323:Other states 10263:Quantum Hall 10020:Smart fluids 9913:Pascal's law 9745:Frictionless 9664: 9594:Large strain 9582:Small strain 9397: 9385:. Retrieved 9363: 9350: 9317: 9313: 9307: 9269:(1): 29–90. 9266: 9262: 9256: 9239: 9235: 9229: 9220: 9214: 9202:. Retrieved 9174: 9170: 9160: 9149:, retrieved 9134: 9127: 9115:. Retrieved 9111: 9101: 9048: 9044: 9034: 9009: 9005: 8995: 8963:(1): 51–58. 8960: 8956: 8946: 8895: 8891: 8881: 8856: 8852: 8806: 8802: 8764: 8760: 8720: 8716: 8709: 8692: 8688: 8682: 8665: 8661: 8643: 8591: 8587: 8577: 8544: 8540: 8530: 8497: 8493: 8483: 8466: 8462: 8452: 8419: 8415: 8405: 8388: 8384: 8374: 8357: 8353: 8347: 8330: 8326: 8320: 8287: 8283: 8239: 8235: 8225: 8200: 8196: 8186: 8145: 8141: 8127: 8102: 8098: 8088: 8063: 8059: 8049: 8016: 8012: 8006: 7997: 7991: 7958: 7954: 7944: 7919: 7915: 7863: 7857: 7848: 7823: 7819: 7813: 7780: 7776: 7770: 7761: 7755: 7736: 7730: 7643: 6960: 6765: 6750: 6746: 6737:, Li is the 6730: 6726: 6720: 6716: 6712: 6708: 6706: 6583: 6576: 6438: 6355: 6294: 6291: 6279: 6273: 6271: 6201: 6131: 6069: 6054: 6041: 5548: 5545: 5487: 5273: 5244: 5232: 5207: 4952: 4949: 4945: 4665: 4658: 4609: 4257: 4241: 4237: 4233: 4229: 4225: 4221: 4218:coefficients 4207: 4080: 4027: 4011: 3973: 3802: 3685: 3177: 3175:is given by 3046: 2824: 2754: 2710: 2657: 2562: 2407:gas constant 2402: 2395: 2391: 2384: 2378: 2243: 2239:Dalton's law 2154: 2086:Robert Boyle 2080: 1953:molar volume 1891:, number of 1855: 1848: 1829: 1762: 1713: 1705: 1496:CarathĂ©odory 1427:Heat engines 1399: 1388: 1377: 1359:Motive power 1344: 1004:Free entropy 975: 475: 474: / 464: 463: / 455:introduction 448: 447: / 386: 349:Heat engines 222: 136: / 39: 29: 10962:von Neumann 10832:force field 10824:percolation 10559:Latent heat 10508:Sublimation 10453:Evaporation 10388:Ferromagnet 10383:Ferrimagnet 10365:Dark matter 10297:High energy 10035:Ferrofluids 9952:Boyle's law 9638:Hooke's law 9577:Deformation 9554:Definitions 9242:: 290–293. 8898:(12): 169. 8767:(1): 1–39. 8469:: 105–113. 8360:: 150–157. 6741:, ζ is the 4633:is pressure 3800:reduces to 2264:species as: 2082:Boyle's law 1981:≈ 8.3144621 1318:Synergetics 999:Free energy 445:Temperature 306:Quasistatic 301:Isenthalpic 258:Instruments 248:Equilibrium 200:Open system 134:Equilibrium 116:Statistical 60:temperature 11032:Categories 10819:Heisenberg 10574:Volatility 10537:Quantities 10498:Regelation 10473:Ionization 10448:Deposition 10400:Superglass 10370:Antimatter 10304:QCD matter 10283:Supersolid 10278:Superfluid 10241:Low energy 10090:Gay-Lussac 10057:Scientists 9947:Atmosphere 9812:Structures 9786:J-integral 9750:Frictional 9711:Plasticity 9648:Orthotropy 9628:Elasticity 9531:Archimedes 9526:Poiseuille 9480:Vibrations 9449:Topics in 9112:Ucrl-52997 7922:: 112772. 7877:087201293X 7722:References 6961:The ratio 1630:Nucleation 1474:Scientists 1278:Philosophy 991:Potentials 354:Heat pumps 311:Polytropic 296:Isentropic 286:Isothermal 10942:Boltzmann 10865:H-theorem 10743:Ensembles 10065:Bernoulli 10047:Rheometer 10042:Rheometry 9984:Acoustics 9896:Newtonian 9891:Viscosity 9521:Bernoulli 9475:Acoustics 9458:Divisions 9387:31 August 9342:0895-7959 9299:250909120 9291:0034-4885 9204:31 August 9199:129899060 9151:31 August 9117:31 August 9075:2405-8440 9026:1290-0729 8987:1674-9871 8920:0195-928X 8873:0047-2689 8831:0047-2689 8781:116961558 8624:121383911 8616:0022-4715 8569:0021-9606 8522:0021-9606 8444:0031-899X 8304:0378-3812 8290:: 31–38. 8264:0001-1541 8170:0001-1541 8119:0888-5885 8080:0888-5885 8041:1547-5905 7983:0026-8976 7936:224844789 7797:0009-2665 7485:ω 7291:ρ 7172:ρ 7151:ω 7037:ρ 7011:ρ 6990:ρ 6976:ρ 6931:ω 6904:− 6896:⁡ 6868:ω 6863:− 6830:− 6824:⁡ 6796:ω 6791:− 6691:α 6655:α 6649:ζ 6635:⁡ 6624:α 6520:ρ 6458:ρ 6419:ν 6393:Γ 6366:Γ 6336:ν 6326:Γ 6319:ν 6310:Γ 6257:ρ 6223:γ 6160:γ 6107:γ 6104:− 6092:− 6089:γ 6083:ρ 6017:δ 6013:− 6005:⁡ 5985:τ 5975:δ 5938:∑ 5917:∑ 5899:δ 5895:− 5887:⁡ 5867:τ 5857:δ 5820:∑ 5799:∑ 5787:δ 5784:− 5776:⁡ 5756:τ 5746:δ 5716:− 5706:∑ 5685:∑ 5664:τ 5654:δ 5624:− 5614:∑ 5593:∑ 5497:ρ 5466:ρ 5462:ρ 5454:δ 5428:τ 5394:δ 5388:τ 5364:δ 5358:τ 5298:ρ 5223:Mie fluid 5162:γ 5159:− 5149:⁡ 5121:γ 5113:β 4926:ρ 4896:α 4884:ρ 4845:− 4839:− 4813:ρ 4780:− 4726:− 4713:− 4680:ρ 4643:ρ 4585:ρ 4581:γ 4578:− 4570:⁡ 4553:ρ 4549:γ 4516:ρ 4497:ρ 4467:α 4455:ρ 4436:− 4430:− 4404:ρ 4371:− 4317:− 4304:− 4271:ρ 4194:⋯ 4004:Fermi gas 3955:⋯ 3898:ℏ 3849:π 3843:± 3785:≪ 3756:μ 3728:≪ 3699:μ 3663:± 3634:μ 3631:− 3586:∞ 3577:∫ 3564:ℏ 3554:π 3426:μ 3369:± 3340:μ 3337:− 3292:∞ 3283:∫ 3270:ℏ 3260:π 3067:and spin 2905:γ 2881:ρ 2852:− 2849:γ 2843:ρ 2796:− 2628:− 2540:In 1873, 2513:∘ 2458:, giving: 2425:∘ 2373:In 1834, 2331:∑ 2311:⋯ 1611:Waterston 1561:von Mayer 1516:de Donder 1506:Clapeyron 1486:Boltzmann 1481:Bernoulli 1442:Education 1413:Timelines 1197:− 1142:− 930:Equations 897:∂ 850:∂ 801:α 765:∂ 718:∂ 672:− 666:β 630:∂ 583:∂ 291:Adiabatic 281:Isochoric 267:Processes 228:Ideal gas 111:Classical 46:relating 36:chemistry 10952:Tsallis 10635:Spinodal 10583:Concepts 10463:Freezing 10007:Rheology 9918:Pressure 9886:Buoyancy 9670:Hugoniot 9093:35520603 8938:34121788 8312:53310898 8178:96417239 7886:70184683 7805:18125401 7711:Real gas 7696:Gas laws 7690:See also 7600:PBX 9501 7280:Material 6729:) where 6579:Bose gas 5379:residual 4008:Bose gas 2556:and the 1702:Overview 1663:Category 1601:Thompson 1511:Clausius 1491:Bridgman 1345:Vis viva 1327:Theories 1261:Gas laws 1053:Enthalpy 461:Pressure 276:Isobaric 233:Real gas 121:Chemical 104:Branches 52:pressure 10947:Shannon 10934:Entropy 10595:Binodal 10483:Melting 10418:Boiling 10335:Crystal 10330:Colloid 10080:Charles 9923:Liquids 9819:Bending 9776:Fatigue 9322:Bibcode 9271:Bibcode 9179:Bibcode 9084:9062208 9053:Bibcode 9045:Heliyon 8965:Bibcode 8929:8191392 8900:Bibcode 8811:Bibcode 8725:Bibcode 8596:Bibcode 8549:Bibcode 8502:Bibcode 8424:Bibcode 8244:Bibcode 8205:Bibcode 8150:Bibcode 8021:Bibcode 7963:Bibcode 7828:Bibcode 6733:is the 6715:is exp( 6565:is the 6274:already 5221:or the 3414:is the 2893:is the 2825:If the 2405:is the 2090:Mercury 1985:J/mol·K 1586:Smeaton 1581:Rankine 1571:Onsager 1556:Maxwell 1551:Massieu 1256:Entropy 1251:General 1242:History 1232:Culture 1229:History 453: ( 450:Entropy 387:italics 188:Systems 32:physics 10796:Models 10704:Theory 10223:Plasma 10204:Liquid 10125:Awards 10115:Stokes 10110:Navier 10105:Newton 10100:Pascal 10075:Cauchy 9974:Plasma 9854:Fluids 9633:linear 9621:Solids 9560:Stress 9536:Pascal 9378:  9340:  9297:  9289:  9197:  9142:  9091:  9081:  9073:  9024:  8985:  8936:  8926:  8918:  8871:  8829:  8779:  8622:  8614:  8567:  8520:  8442:  8310:  8302:  8262:  8176:  8168:  8117:  8078:  8039:  7981:  7934:  7894:947455 7892:  7884:  7874:  7803:  7795:  7743:  7634:Others 7526:(GPa) 7310:(g/cm) 6745:, and 6707:where 6613:  6491:where 6357:Where 6132:where 6063:, and 4610:where 3387:where 2873:where 2658:where 2506:  2503:273.15 2441:  2438:273.15 2421:  1983:  1866:Kelvin 1763:where 1576:Planck 1566:Nernst 1541:Kelvin 1501:Carnot 791:  656:  524:  466:Volume 381:Note: 340:Cycles 169:Second 159:Zeroth 56:volume 11005:chaos 10957:RĂ©nyi 10814:Potts 10809:Ising 10213:Vapor 10199:Solid 10192:State 10095:Hooke 10085:Euler 10070:Boyle 9940:Gases 9697:Creep 9609:Solid 9360:(PDF) 9295:S2CID 9195:S2CID 8777:S2CID 8620:S2CID 8308:S2CID 8174:S2CID 7932:S2CID 7627:10.2 7615:18.02 7612:852.4 7604:1.844 7594:8.50 7582:7.678 7579:524.2 7570:1.717 7560:6.00 7548:3.747 7545:373.8 7536:1.630 7419:(GPa) 7396:(GPa) 7373:(GPa) 7340:(m/s) 5420:with 2277:total 1893:moles 1624:Other 1591:Stahl 1546:Lewis 1536:Joule 1526:Gibbs 1521:Duhem 214:State 174:Third 164:First 72:stars 68:solid 62:, or 42:is a 38:, an 10887:and 10184:list 9611:and 9500:Laws 9389:2018 9376:ISBN 9338:ISSN 9287:ISSN 9206:2018 9153:2018 9140:ISBN 9119:2018 9089:PMID 9071:ISSN 9022:ISSN 8983:ISSN 8934:PMID 8916:ISSN 8869:ISSN 8827:ISSN 8612:ISSN 8565:ISSN 8518:ISSN 8440:ISSN 8300:ISSN 8260:ISSN 8166:ISSN 8115:ISSN 8076:ISSN 8037:ISSN 7979:ISSN 7890:OCLC 7882:LCCN 7872:ISBN 7801:PMID 7793:ISSN 7741:ISBN 7624:0.38 7618:4.55 7609:36.3 7591:0.35 7588:1.10 7585:4.20 7576:29.5 7573:7980 7557:0.35 7554:0.90 7551:4.15 7542:21.0 7539:6930 7143:and 5266:al. 3461:the 3418:and 1596:Tait 426:Heat 421:Work 151:Laws 34:and 10209:Gas 9675:JWL 9368:doi 9330:doi 9279:doi 9244:doi 9187:doi 9079:PMC 9061:doi 9014:doi 8973:doi 8924:PMC 8908:doi 8861:doi 8819:doi 8769:doi 8733:doi 8721:106 8697:doi 8670:doi 8604:doi 8557:doi 8510:doi 8471:doi 8467:103 8432:doi 8420:182 8393:doi 8389:264 8362:doi 8358:382 8335:doi 8292:doi 8252:doi 8213:doi 8158:doi 8107:doi 8068:doi 8029:doi 7971:doi 7924:doi 7920:523 7836:doi 7785:doi 7621:1.3 7532:TNT 6893:exp 6821:exp 6581:is 6439:An 6002:exp 5884:exp 5773:exp 5146:exp 4567:exp 4035:of 2949:), 1439:Art 385:in 74:. 30:In 11034:: 10760:: 10211:/ 9374:. 9336:. 9328:. 9318:16 9316:. 9293:. 9285:. 9277:. 9267:59 9265:. 9238:. 9193:. 9185:. 9173:. 9169:. 9110:. 9087:. 9077:. 9069:. 9059:. 9047:. 9043:. 9020:. 9010:43 9004:. 8981:. 8971:. 8959:. 8955:. 8932:. 8922:. 8914:. 8906:. 8896:41 8894:. 8890:. 8867:. 8857:31 8855:. 8851:. 8839:^ 8825:. 8817:. 8807:29 8805:. 8801:. 8789:^ 8775:. 8765:24 8763:. 8759:. 8745:^ 8731:. 8719:. 8693:29 8691:. 8666:65 8664:. 8652:^ 8632:^ 8618:. 8610:. 8602:. 8592:35 8590:. 8586:. 8563:. 8555:. 8545:54 8543:. 8539:. 8516:. 8508:. 8498:47 8496:. 8492:. 8465:. 8461:. 8438:. 8430:. 8418:. 8414:. 8387:. 8383:. 8356:. 8331:41 8329:. 8306:. 8298:. 8288:52 8286:. 8272:^ 8258:. 8250:. 8240:42 8238:. 8234:. 8211:. 8201:47 8199:. 8195:. 8172:. 8164:. 8156:. 8146:32 8144:. 8140:. 8113:. 8103:35 8101:. 8097:. 8074:. 8064:45 8062:. 8058:. 8035:. 8027:. 8017:21 7977:. 7969:. 7959:37 7957:. 7953:. 7930:. 7918:. 7914:. 7902:^ 7888:. 7880:. 7870:. 7866:. 7834:. 7824:27 7822:. 7799:. 7791:. 7781:44 7779:. 7116:, 7089:, 7069:, 6620:Li 6569:. 6269:. 6059:, 5953:38 5948:24 5835:56 5830:16 5724:24 5632:12 5225:. 4240:, 4236:, 4220:. 4014:. 2811:0. 2560:. 2390:= 2385:pV 1977:, 1951:, 1924:, 1858:SI 1846:. 58:, 54:, 10779:G 10774:F 10769:H 10764:U 10689:e 10682:t 10675:v 10186:) 10182:( 10172:e 10165:t 10158:v 9442:e 9435:t 9428:v 9391:. 9370:: 9344:. 9332:: 9324:: 9301:. 9281:: 9273:: 9250:. 9246:: 9240:7 9208:. 9189:: 9181:: 9175:4 9121:. 9095:. 9063:: 9055:: 9049:8 9028:. 9016:: 8989:. 8975:: 8967:: 8961:3 8940:. 8910:: 8902:: 8875:. 8863:: 8833:. 8821:: 8813:: 8783:. 8771:: 8739:. 8735:: 8727:: 8703:. 8699:: 8676:. 8672:: 8646:. 8626:. 8606:: 8598:: 8571:. 8559:: 8551:: 8524:. 8512:: 8504:: 8477:. 8473:: 8446:. 8434:: 8426:: 8399:. 8395:: 8368:. 8364:: 8341:. 8337:: 8314:. 8294:: 8266:. 8254:: 8246:: 8219:. 8215:: 8207:: 8180:. 8160:: 8152:: 8121:. 8109:: 8082:. 8070:: 8043:. 8031:: 8023:: 7985:. 7973:: 7965:: 7938:. 7926:: 7896:. 7842:. 7838:: 7830:: 7807:. 7787:: 7749:. 7646:. 7511:0 7507:e 7462:2 7458:R 7434:1 7430:R 7406:B 7383:A 7358:J 7355:C 7351:p 7325:D 7321:v 7295:e 7260:0 7256:e 7233:J 7230:C 7226:P 7203:D 7199:V 7176:0 7129:2 7125:R 7102:1 7098:R 7077:B 7057:A 7015:e 6986:/ 6980:e 6972:= 6969:V 6945:V 6939:0 6935:e 6925:+ 6921:) 6917:V 6912:2 6908:R 6900:( 6889:) 6882:V 6877:2 6873:R 6860:1 6856:( 6852:B 6849:+ 6846:) 6843:V 6838:1 6834:R 6827:( 6817:) 6810:V 6805:1 6801:R 6788:1 6784:( 6780:A 6777:= 6774:p 6751:c 6747:T 6731:ÎŒ 6727:T 6724:B 6721:k 6719:/ 6717:ÎŒ 6713:z 6709:α 6686:) 6679:c 6675:T 6671:T 6666:( 6658:) 6652:( 6644:) 6641:z 6638:( 6630:1 6627:+ 6610:T 6607:R 6604:= 6599:m 6595:V 6591:p 6551:s 6547:c 6524:m 6499:p 6477:2 6472:s 6468:c 6462:m 6454:= 6451:p 6397:2 6370:1 6340:2 6330:2 6322:+ 6314:1 6306:= 6303:p 6253:/ 6248:) 6242:0 6238:p 6234:+ 6231:p 6227:( 6220:= 6215:2 6211:c 6185:0 6181:p 6140:e 6115:0 6111:p 6101:e 6098:) 6095:1 6086:( 6080:= 6077:p 6027:) 6021:3 6009:( 5997:2 5993:/ 5989:j 5979:i 5969:j 5966:, 5963:i 5959:n 5945:= 5942:j 5932:4 5927:2 5924:= 5921:i 5913:+ 5909:) 5903:2 5891:( 5879:8 5875:/ 5871:j 5861:i 5851:j 5848:, 5845:i 5841:n 5827:= 5824:j 5814:5 5809:1 5806:= 5803:i 5795:+ 5791:) 5780:( 5768:8 5764:/ 5760:j 5750:i 5740:j 5737:, 5734:i 5730:n 5719:8 5713:= 5710:j 5700:5 5695:1 5692:= 5689:i 5681:+ 5676:8 5672:/ 5668:j 5658:i 5648:j 5645:, 5642:i 5638:n 5627:8 5621:= 5618:j 5608:8 5603:1 5600:= 5597:i 5589:= 5583:l 5580:a 5577:u 5574:d 5571:i 5568:s 5565:e 5562:r 5557:a 5528:r 5524:T 5501:r 5470:r 5457:= 5451:, 5446:T 5441:r 5437:T 5431:= 5405:T 5402:R 5397:) 5391:, 5385:( 5374:a 5370:+ 5367:) 5361:, 5355:( 5349:s 5346:a 5343:g 5339:l 5336:a 5333:e 5330:d 5327:i 5322:a 5315:= 5309:T 5306:R 5301:) 5295:, 5292:T 5289:( 5286:a 5188:) 5183:) 5176:2 5171:r 5167:V 5153:( 5142:) 5134:2 5129:r 5125:V 5116:+ 5109:( 5100:2 5095:r 5091:V 5085:3 5080:r 5076:T 5069:4 5065:c 5059:+ 5052:5 5047:r 5043:V 5039:D 5034:+ 5027:2 5022:r 5018:V 5014:C 5009:+ 5002:r 4998:V 4994:B 4989:+ 4986:1 4982:( 4976:V 4972:T 4969:R 4963:= 4960:p 4930:6 4921:) 4915:T 4912:d 4907:+ 4904:a 4900:( 4893:+ 4888:3 4879:) 4871:2 4867:T 4863:c 4858:+ 4853:T 4850:d 4842:a 4836:T 4833:R 4830:b 4826:( 4822:+ 4817:2 4808:) 4800:4 4796:T 4790:0 4786:E 4773:3 4769:T 4763:0 4759:D 4753:+ 4746:2 4742:T 4736:0 4732:C 4721:0 4717:A 4710:T 4707:R 4702:0 4698:B 4693:( 4689:+ 4686:T 4683:R 4677:= 4674:p 4621:p 4595:) 4589:2 4574:( 4563:) 4557:2 4546:+ 4543:1 4539:( 4531:2 4527:T 4520:3 4512:c 4506:+ 4501:6 4492:) 4486:T 4483:d 4478:+ 4475:a 4471:( 4464:+ 4459:3 4450:) 4444:T 4441:d 4433:a 4427:T 4424:R 4421:b 4417:( 4413:+ 4408:2 4399:) 4391:4 4387:T 4381:0 4377:E 4364:3 4360:T 4354:0 4350:D 4344:+ 4337:2 4333:T 4327:0 4323:C 4312:0 4308:A 4301:T 4298:R 4293:0 4289:B 4284:( 4280:+ 4277:T 4274:R 4268:= 4265:p 4242:D 4238:C 4234:B 4230:C 4226:B 4222:A 4191:+ 4184:3 4179:m 4175:V 4171:D 4166:+ 4159:2 4154:m 4150:V 4146:C 4141:+ 4134:m 4130:V 4126:B 4121:+ 4118:A 4115:= 4109:T 4106:R 4099:m 4095:V 4091:p 4048:m 4044:V 4012:ħ 3990:V 3986:/ 3982:N 3959:] 3952:+ 3944:2 3940:/ 3936:3 3932:) 3928:T 3923:B 3919:k 3915:m 3912:( 3909:V 3902:3 3894:N 3885:) 3882:1 3879:+ 3876:s 3873:2 3870:( 3867:2 3861:2 3857:/ 3853:3 3840:1 3836:[ 3832:T 3827:B 3823:k 3819:N 3816:= 3813:V 3810:p 3788:1 3780:) 3777:T 3772:B 3768:k 3764:( 3760:/ 3752:e 3731:1 3723:) 3720:T 3715:B 3711:k 3707:( 3703:/ 3695:e 3672:. 3666:1 3658:) 3655:T 3650:B 3646:k 3642:( 3638:/ 3628:z 3624:e 3618:z 3614:d 3607:2 3603:/ 3599:1 3595:z 3581:0 3568:3 3558:2 3548:2 3539:2 3535:/ 3531:3 3527:) 3523:T 3518:B 3514:k 3510:m 3507:( 3504:) 3501:1 3498:+ 3495:s 3492:2 3489:( 3483:= 3478:V 3475:N 3449:) 3446:V 3442:/ 3438:N 3435:, 3432:T 3429:( 3400:B 3396:k 3372:1 3364:) 3361:T 3356:B 3352:k 3348:( 3344:/ 3334:z 3330:e 3324:z 3320:d 3313:2 3309:/ 3305:3 3301:z 3287:0 3274:3 3264:2 3256:3 3247:5 3243:T 3237:5 3232:B 3228:k 3222:3 3218:m 3214:2 3209:) 3206:1 3203:+ 3200:s 3197:2 3194:( 3188:= 3185:p 3163:p 3143:T 3123:V 3103:N 3075:s 3055:m 3025:p 3021:C 2998:v 2994:C 2973:T 2968:v 2964:C 2960:= 2957:e 2931:v 2927:C 2922:/ 2916:p 2912:C 2908:= 2861:e 2858:) 2855:1 2846:( 2840:= 2837:p 2808:= 2805:T 2802:R 2799:n 2793:V 2790:p 2787:= 2784:) 2781:T 2778:, 2775:V 2772:, 2769:p 2766:( 2763:f 2741:. 2738:T 2735:R 2732:n 2729:= 2726:V 2723:p 2686:b 2666:a 2643:T 2640:R 2637:= 2634:) 2631:b 2623:m 2619:V 2615:( 2611:) 2603:2 2598:m 2594:V 2590:1 2585:a 2582:+ 2579:P 2575:( 2528:. 2524:) 2519:C 2500:+ 2495:C 2491:T 2486:( 2482:R 2479:= 2474:m 2470:V 2466:p 2445:K 2435:= 2431:C 2417:0 2403:R 2398:C 2396:T 2394:( 2392:R 2387:m 2361:. 2356:i 2352:p 2346:n 2341:1 2338:= 2335:i 2327:= 2322:n 2318:p 2314:+ 2308:+ 2303:2 2299:p 2295:+ 2290:1 2286:p 2282:= 2273:p 2252:n 2226:. 2219:2 2215:T 2209:2 2205:V 2199:= 2192:1 2188:T 2182:1 2178:V 2136:. 2132:t 2129:n 2126:a 2123:t 2120:s 2117:n 2114:o 2111:c 2107:= 2104:V 2101:p 2058:c 2054:T 2029:c 2025:V 2000:c 1996:p 1965:R 1937:n 1934:V 1910:m 1906:V 1879:n 1811:T 1791:V 1771:p 1749:0 1746:= 1743:) 1740:T 1737:, 1734:V 1731:, 1728:p 1725:( 1722:f 1690:e 1683:t 1676:v 1203:S 1200:T 1194:H 1191:= 1188:) 1185:p 1182:, 1179:T 1176:( 1173:G 1148:S 1145:T 1139:U 1136:= 1133:) 1130:V 1127:, 1124:T 1121:( 1118:A 1093:V 1090:p 1087:+ 1084:U 1081:= 1078:) 1075:p 1072:, 1069:S 1066:( 1063:H 1038:) 1035:V 1032:, 1029:S 1026:( 1023:U 900:T 876:V 853:V 829:1 804:= 768:p 744:V 721:V 697:1 669:= 633:T 609:N 586:S 562:T 537:= 534:c 457:) 27:.

Index

Equation of state (cosmology)
Optimal control § General method
physics
chemistry
thermodynamic equation
state variables
pressure
volume
temperature
internal energy
solid
stars
Thermodynamics

Carnot heat engine
Classical
Statistical
Chemical
Quantum thermodynamics
Equilibrium
Non-equilibrium
Laws
Zeroth
First
Second
Third
Systems
Closed system
Open system
Isolated system

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