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can occur where the radical at the end of the growing chain can be transferred from the chain to an individual monomer unit causing a new chain to start growing and the previous chain to stop growing. With
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637:"Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)"
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Termination by recombination increases the chain length and therefore the molecular weight of the final polymer.
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since it involves breaking of one bond, and therefore is more important at higher energy.
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step, one radical transfers a hydrogen atom to the other to form two stable molecules:
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The termination steps of free radical polymerization steps are of two types:
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Chemical reaction in which a chain carrier is converted irreversibly into
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a non-propagating species without the formation of a new chain carrier.
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73:Mechanisms of termination
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153:step, two growing chain
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61:definition
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724:Category
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155:radicals
149:. In a
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108:alcohol
91:radical
87:monomer
83:polymer
38:is any
709:IUPAC
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119:polyol
117:and a
661:S2CID
385:In a
111:R'−OH
59:IUPAC
46:in a
691:ISBN
145:and
23:and
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553:CHX
496:CHX
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30:In
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