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Alloy steel

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fracturing, making it useful for auto parts such as bumpers and pillars. Three generations of advanced, high-strength steel are available. The first was created in the 1990s, increasing strength and ductility. A second generation used new alloys to further increase ductility, but were expensive and difficult to manufacture. The third generation is beginning to be adopted. Refined heating and cooling patterns increase both strength at some cost in ductility (vs 2nd generation). These steels are claimed to approach nearly ten times the strength of earlier steels; and are much cheaper to manufacture.
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Alloying elements are added to achieve specific properties in the result. The alloying elements can affect multiple properties—flexibility, strength, formability, and hardenability. As a guideline, alloying elements are added in lower percentages (less than 5%) to increase strength or hardenability,
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TRIP steels transform under deformation from relatively ductile to relatively hard under deformation such as a car crash. Such deformation transforms austenitic microstructure to martensitic microstructure. TRIP steels use relatively high carbon content to create the austenitic microstructure.
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In one approach steel is heated to a high temperature, cooled somewhat, held stable for an interval and then quenched. This produces islands of austenite surrounded by a matrix of softer ferrite, with regions of harder bainite and martensite. The resulting product can absorb energy without
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precipitation in the bainite region and helps accelerate ferrite/bainite formation. This helps retain carbon to support austenite at room temperature. A specific cooling process reduces the austenite/martensite transformation during forming. TRIP steels typically require an
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hold at an intermediate temperature during cooling, which produces some bainite. The additional silicon/carbon requirements requires weld cycle modification, such as the use of pulsating welding or dilution welding.
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Manganese and nickel lower the eutectoid temperature and are known as austenite stabilizing elements. With enough of these elements the austenitic structure may be obtained at room temperature.
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revealed their compositions. Alloy steels from earlier times were expensive luxuries made on the model of "secret recipes" and forged into tools such as knives and swords.
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Alloy steels divide into two groups: low and high alloy. The boundary between the two is disputed. Smith and Hashemi define the difference at 4.0%, while Degarmo,
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properties, some alloys find important applications where their responses to magnetism are very important, including in electric motors and in transformers.
1042:; inhibits grain growth. Increases the toughness of steel, thus making molybdenum a very valuable alloy metal for making the cutting parts of 1173:
Stable carbides; increases strength while retaining ductility; promotes fine grain structure. Increases the toughness at high temperatures
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or in larger percentages (over 5%) to achieve properties such as corrosion resistance or extreme temperature stability.
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Tungsten and molybdenum form carbides given enough carbon and an absence of stronger carbide forming elements (i.e.,
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Carbide-forming elements raise the eutectoid temperature; these elements are known as ferrite stabilizing elements.
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Nickel and copper improve corrosion resistance in small quantities. Molybdenum helps to resist embrittlement.
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Increases hardenability by lowering transformation points and causing transformations to be sluggish
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with a variety of elements in amounts between 1.0% and 50% by weight, typically to improve its
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Chromium forms partitions between the ferrite and carbide phases in steel, forming (Fe,Cr
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Zirconium, cerium, and calcium increase toughness by controlling the shape of inclusions.
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Chromium, vanadium, molybdenum, and tungsten increase strength by forming second-phase
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The alloying elements tend to form either solid solutions or compounds or carbides.
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Ni 5%, Cr 2%, Si 1.25%, W 1%, Mn 0.85%, Mo 0.55%, Cu 0.5%, Cr 0.40%, C 0.2%, V 0.1%
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The properties of steel depend on its microstructure: the arrangement of different
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Fixes carbon in inert particles; reduces martensitic hardness in chromium steels
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Vanadium, titanium, and niobium are strong carbide-forming elements, forming
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Manganese mostly dissolves in ferrite forming the compounds MnS, MnO•SiO
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FUNDAMENTALS OF MODERN MANUFACTURING: Materials, Processes, and Systems
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Nickel is soluble in ferrite; therefore, it forms compounds, usually Ni
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and AlN. Silicon is also soluble and usually forms the compound SiO
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Si 1.40% or 2.00%, Mn 0.65% or 0.82% or 0.85%, Cr 0.00% or 0.65%
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Cr 0.50% or 0.80% or 0.95%, Mo 0.12% or 0.20% or 0.25% or 0.30%
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to reduce brittleness. Also helps to remove excess oxygen.
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Although alloy steels have been made for centuries, their
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Degarmo, E. Paul; Black, J T.; Kohser, Ronald A. (2007),
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Aluminum dissolves in ferrite and forms the compounds Al
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the advancing chemical science of the nineteenth century
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Principal effects of major alloying elements for steel
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Relatively high silicon/aluminum content suppresses
1211: 46:. Unsourced material may be challenged and removed. 1448: 1377: 1341: 1292: 725:Manganese, silicon, or aluminum are added during 659:Cr 0.60% or 0.80% or 0.95%, V 0.10% or 0.15% min 1498: 1481:Foundations of Material Science and Engineering 1392:"New forms of steel for stronger, lighter cars" 699:Ni 0.45%, Cr 0.40%, Mo 0.12%, and added boron 875:Alloying elements also have an effect on the 627:Cr 0.80% or 0.87% or 0.92% or 1.00% or 1.05% 545:Mo 0.20% or 0.25% or 0.25% Mo & 0.042% S 1478: 1365: 1353: 1304: 1277: 1389: 1483:(4th ed.), McGraw-Hill, p. 394, 1479:Smith, William F.; Hashemi, Javad (2001), 1424:"Transformation Induced Plasticity (TRIP)" 471:, combined with strict cooling protocols. 1403: 106:Learn how and when to remove this message 1468:Groover, Mikell P. (February 26, 2009). 1451:Materials and Processes in Manufacturing 486:alloy steels were developed as improved 118:Steel alloyed with a variety of elements 1467: 1499: 1421: 587:Ni 1.05%, Cr 0.45%, Mo 0.20% or 0.35% 563:Ni 1.82%, Cr 0.50% to 0.80%, Mo 0.25% 1417: 1415: 579:Ni 0.85% or 1.82%, Mo 0.20% or 0.25% 603:Cr 0.27% or 0.40% or 0.50% or 0.65% 44:adding citations to reliable sources 15: 715: 619:Cr 0.28% or 0.50%, and added boron 504: 387:(B). Less common alloyants include 13: 1412: 1160:Also increases the melting point. 810:, but also forms carbides: (Fe,Mn) 14: 1518: 1212:Transformation-induced plasticity 1188:, some harder, some with greater 1179: 949:) A powerful hardenability agent 1390:Johnson, Jr, John (2024-08-05). 1378:Degarmo, Black & Kohser 2007 1342:Degarmo, Black & Kohser 2007 1293:Degarmo, Black & Kohser 2007 1196:(the hardest yet most brittle), 129: 20: 1442: 1079:Increases corrosion resistance 970:Increases corrosion resistance 439:Alloy steels variously improve 351:(Fe) alloyed with (0.1% to 1%) 31:needs additional citations for 1383: 1310: 478:was not well understood until 1: 1474:. John Wiley & Sons, Inc. 1266: 1121:Improves magnetic properties 683:Ni 0.55%, Cr 0.50%, Mo 0.35% 675:Ni 0.55%, Cr 0.50%, Mo 0.25% 667:Ni 0.55%, Cr 0.50%, Mo 0.20% 511:High-strength low-alloy steel 434: 7: 1422:Hickey, Kate (2021-06-23). 1234: 889: 848:), they form the carbides W 703: 695: 687: 679: 671: 663: 655: 647: 639: 631: 623: 615: 607: 599: 591: 583: 575: 567: 559: 549: 541: 533: 10: 1523: 1134:Free-machining properties 1092:Stabilizes microstructure 879:temperature of the steel. 643:Cr 0.80%, and added boron 517:Principal low-alloy steels 508: 275:Other iron-based materials 1405:10.1146/knowable-080524-1 1096: 1062: 1000: 953: 522: 1453:(10th ed.), Wiley, 1366:Smith & Hashemi 2001 1354:Smith & Hashemi 2001 1305:Smith & Hashemi 2001 1278:Smith & Hashemi 2001 962:Increases hardenability 363:(Mn) (the most common), 347:The simplest steels are 335: 211:Widmanstätten structures 996:Improved machinability 932:Improves machinability 764:Sulfur (in the form of 490:and as newly available 651:Cr 1.45%, C 1.00% min 635:Cr 1.02%, C 1.00% min 611:Cr 0.50%, C 1.00% min 983:Corrosion resistance 330:mechanical properties 1204:(more ductile), and 915:Alloying element in 744:Manganese, silicon, 729:to remove dissolved 457:corrosion resistance 40:improve this article 1368:, pp. 395–396. 1356:, pp. 394–395. 1118:Higher percentages 1105:Increases strength 892: 595:Ni 3.50%, Mo 0.25% 519: 206:Tempered martensite 1251:Microalloyed steel 890: 571:Mo 0.40% or 0.52% 515: 497:Because of iron's 1460:978-0-470-05512-0 1396:Knowable Magazine 1177: 1176: 902:Primary function 766:manganese sulfide 713: 712: 315: 314: 116: 115: 108: 90: 1514: 1493: 1475: 1463: 1438: 1437: 1435: 1434: 1419: 1410: 1409: 1407: 1387: 1381: 1375: 1369: 1363: 1357: 1351: 1345: 1339: 1333: 1332: 1330: 1329: 1314: 1308: 1302: 1296: 1290: 1281: 1275: 1256:SAE steel grades 1241:Dual-phase steel 1052:turbojet engines 893: 865:titanium carbide 861:vanadium carbide 856:C, respectively. 716:Material science 520: 514: 505:Low-alloy steels 492:stainless steels 262:Weathering steel 257:High-speed steel 133: 121: 120: 111: 104: 100: 97: 91: 89: 48: 24: 16: 1522: 1521: 1517: 1516: 1515: 1513: 1512: 1511: 1497: 1496: 1491: 1461: 1445: 1432: 1430: 1428:AHSS Guidelines 1420: 1413: 1388: 1384: 1376: 1372: 1364: 1360: 1352: 1348: 1340: 1336: 1327: 1325: 1322:Metal Exponents 1316: 1315: 1311: 1303: 1299: 1291: 1284: 1276: 1272: 1269: 1237: 1214: 1182: 1054:. Also used in 871:, respectively. 869:niobium carbide 855: 851: 836: 832: 828: 824: 820: 813: 809: 802: 798: 794: 790: 786: 779: 718: 513: 507: 453:wear resistance 437: 338: 252:Stainless steel 177:Microstructures 119: 112: 101: 95: 92: 49: 47: 37: 25: 12: 11: 5: 1520: 1510: 1509: 1495: 1494: 1489: 1476: 1465: 1459: 1444: 1441: 1440: 1439: 1411: 1382: 1380:, p. 144. 1370: 1358: 1346: 1344:, p. 113. 1334: 1309: 1307:, p. 394. 1297: 1295:, p. 112. 1282: 1280:, p. 393. 1268: 1265: 1264: 1263: 1258: 1253: 1248: 1243: 1236: 1233: 1213: 1210: 1181: 1180:Microstructure 1178: 1175: 1174: 1171: 1168: 1162: 1161: 1158: 1155: 1149: 1148: 1145: 1142: 1136: 1135: 1132: 1129: 1123: 1122: 1119: 1115: 1114: 1113:Spring steels 1111: 1107: 1106: 1103: 1100: 1094: 1093: 1090: 1087: 1081: 1080: 1077: 1073: 1072: 1069: 1066: 1060: 1059: 1036: 1033: 1027: 1026: 1023: 1019: 1018: 1009:Combines with 1007: 1004: 998: 997: 994: 991: 985: 984: 981: 978: 972: 971: 968: 964: 963: 960: 957: 951: 950: 943: 940: 934: 933: 930: 927: 921: 920: 913: 910: 904: 903: 900: 897: 888: 887: 884: 873: 872: 857: 853: 849: 838: 834: 830: 826: 822: 818: 815: 811: 807: 804: 800: 796: 792: 788: 784: 781: 777: 770: 769: 762: 759: 756: 749: 742: 717: 714: 711: 710: 707: 701: 700: 697: 693: 692: 689: 685: 684: 681: 677: 676: 673: 669: 668: 665: 661: 660: 657: 653: 652: 649: 645: 644: 641: 637: 636: 633: 629: 628: 625: 621: 620: 617: 613: 612: 609: 605: 604: 601: 597: 596: 593: 589: 588: 585: 581: 580: 577: 573: 572: 569: 565: 564: 561: 557: 556: 553: 547: 546: 543: 539: 538: 535: 531: 530: 527: 509:Main article: 506: 503: 436: 433: 337: 334: 313: 312: 311: 310: 305: 303:Malleable iron 300: 295: 290: 285: 277: 276: 272: 271: 270: 269: 264: 259: 254: 249: 247:Maraging steel 244: 239: 234: 229: 227:Crucible steel 221: 220: 216: 215: 214: 213: 208: 203: 198: 193: 188: 180: 179: 173: 172: 171: 170: 165: 160: 155: 150: 142: 141: 135: 134: 126: 125: 117: 114: 113: 28: 26: 19: 9: 6: 4: 3: 2: 1519: 1508: 1505: 1504: 1502: 1492: 1490:0-07-295358-6 1486: 1482: 1477: 1473: 1472: 1466: 1462: 1456: 1452: 1447: 1446: 1429: 1425: 1418: 1416: 1406: 1401: 1397: 1393: 1386: 1379: 1374: 1367: 1362: 1355: 1350: 1343: 1338: 1323: 1319: 1313: 1306: 1301: 1294: 1289: 1287: 1279: 1274: 1270: 1262: 1259: 1257: 1254: 1252: 1249: 1247: 1244: 1242: 1239: 1238: 1232: 1228: 1225: 1220: 1209: 1207: 1203: 1200:(less hard), 1199: 1195: 1191: 1187: 1172: 1169: 1167: 1164: 1163: 1159: 1156: 1154: 1151: 1150: 1146: 1143: 1141: 1138: 1137: 1133: 1130: 1128: 1125: 1124: 1120: 1117: 1116: 1112: 1109: 1108: 1104: 1101: 1099: 1095: 1091: 1088: 1086: 1083: 1082: 1078: 1075: 1074: 1070: 1067: 1065: 1061: 1057: 1056:rocket motors 1053: 1049: 1046:and also the 1045: 1044:machine tools 1041: 1037: 1034: 1032: 1029: 1028: 1024: 1021: 1020: 1016: 1012: 1008: 1005: 1003: 999: 995: 992: 990: 987: 986: 982: 979: 977: 974: 973: 969: 966: 965: 961: 958: 956: 952: 948: 944: 941: 939: 936: 935: 931: 928: 926: 923: 922: 918: 914: 911: 909: 906: 905: 901: 898: 895: 894: 885: 882: 881: 880: 878: 870: 866: 862: 858: 847: 843: 839: 816: 805: 782: 775: 774: 773: 767: 763: 760: 757: 754: 750: 747: 743: 740: 736: 732: 728: 724: 723: 722: 708: 706: 702: 698: 694: 690: 686: 682: 678: 674: 670: 666: 662: 658: 654: 650: 646: 642: 638: 634: 630: 626: 622: 618: 614: 610: 606: 602: 598: 594: 590: 586: 582: 578: 574: 570: 566: 562: 558: 554: 552: 548: 544: 540: 536: 532: 528: 525: 521: 518: 512: 502: 500: 499:ferromagnetic 495: 493: 489: 485: 481: 477: 472: 470: 469:heat treating 466: 462: 461:hardenability 458: 454: 450: 446: 442: 432: 430: 426: 422: 418: 414: 410: 406: 402: 398: 394: 390: 386: 382: 378: 374: 370: 366: 362: 358: 357:carbon steels 354: 350: 345: 343: 333: 331: 327: 323: 319: 309: 306: 304: 301: 299: 296: 294: 291: 289: 286: 284: 281: 280: 279: 278: 274: 273: 268: 265: 263: 260: 258: 255: 253: 250: 248: 245: 243: 240: 238: 235: 233: 230: 228: 225: 224: 223: 222: 218: 217: 212: 209: 207: 204: 202: 199: 197: 194: 192: 189: 187: 184: 183: 182: 181: 178: 175: 174: 169: 166: 164: 161: 159: 156: 154: 151: 149: 146: 145: 144: 143: 140: 137: 136: 132: 128: 127: 123: 122: 110: 107: 99: 88: 85: 81: 78: 74: 71: 67: 64: 60: 57: â€“  56: 55:"Alloy steel" 52: 51:Find sources: 45: 41: 35: 34: 29:This article 27: 23: 18: 17: 1480: 1470: 1450: 1443:Bibliography 1431:. Retrieved 1427: 1395: 1385: 1373: 1361: 1349: 1337: 1326:. Retrieved 1324:. 2020-08-18 1321: 1312: 1300: 1273: 1261:Reynolds 531 1229: 1215: 1183: 942:0.001–0.003 874: 771: 719: 529:Composition 526:designation 516: 496: 473: 465:hot hardness 438: 346: 341: 339: 317: 316: 308:Wrought iron 298:Ductile iron 241: 237:Spring steel 232:Carbon steel 102: 93: 83: 76: 69: 62: 50: 38:Please help 33:verification 30: 947:Boron steel 899:Percentage 727:steelmaking 488:tool steels 484:Machine age 318:Alloy steel 242:Alloy steel 186:Spheroidite 96:August 2024 1433:2024-08-21 1328:2021-01-29 1267:References 1246:HSLA steel 1224:isothermal 1194:martensite 1131:0.08–0.15 1071:Toughener 1050:blades of 1031:Molybdenum 1015:phosphorus 1006:0.25–0.40 912:0.95–1.30 739:phosphorus 476:metallurgy 435:Properties 427:(Pb), and 383:(Si), and 373:molybdenum 293:White iron 267:Tool steel 201:Ledeburite 163:Martensite 66:newspapers 1206:austenite 1190:ductility 1013:and with 1002:Manganese 917:nitriding 877:eutectoid 537:Mn 1.75% 449:toughness 429:zirconium 361:manganese 288:Gray iron 283:Cast iron 158:Cementite 153:Austenite 1501:Category 1235:See also 1166:Vanadium 1153:Tungsten 1140:Titanium 1102:0.2–0.7 1040:carbides 980:0.1–0.4 955:Chromium 908:Aluminum 896:Element 852:C and Mo 842:titanium 829:, and Cr 753:carbides 445:hardness 441:strength 413:tungsten 409:titanium 389:aluminum 377:vanadium 369:chromium 324:that is 191:Pearlite 168:Graphite 1219:carbide 1202:ferrite 1198:bainite 1098:Silicon 1085:Niobium 1048:turbine 1038:Stable 925:Bismuth 919:steels 846:niobium 405:niobium 381:silicon 326:alloyed 219:Classes 196:Bainite 148:Ferrite 80:scholar 1507:Steels 1487:  1457:  1186:phases 1127:Sulfur 1076:12–20 1064:Nickel 1035:0.2–5 1022:>1 1011:sulfur 976:Copper 959:0.5–2 867:, and 844:& 821:)C, Cr 746:nickel 735:sulfur 731:oxygen 696:94Bxx 648:52xxx 640:51Bxx 632:51xxx 616:50Bxx 608:50xxx 463:, and 431:(Zr). 423:(Zn), 419:(Sn), 411:(Ti), 407:(Nb), 403:(Ce), 401:cerium 399:(Cu), 397:copper 395:(Co), 393:cobalt 391:(Al), 375:(Mo), 371:(Cr), 367:(Ni), 365:nickel 353:carbon 342:et al. 139:Phases 124:Steels 82:  75:  68:  61:  53:  1170:0.15 967:4–18 938:Boron 688:92xx 680:88xx 672:87xx 664:86xx 656:61xx 624:51xx 600:50xx 592:48xx 584:47xx 576:46xx 568:44xx 560:43xx 542:40xx 534:13xx 415:(W), 385:boron 379:(V), 336:Types 322:steel 87:JSTOR 73:books 1485:ISBN 1455:ISBN 1110:2.0 1068:2–5 989:Lead 737:and 705:ES-1 551:41xx 425:lead 421:zinc 349:iron 59:news 1400:doi 780:Al. 524:SAE 417:tin 320:is 42:by 1503:: 1426:. 1414:^ 1398:. 1394:. 1320:. 1285:^ 1157:— 1144:— 1089:— 1058:. 993:— 929:— 863:, 831:23 814:C. 795:•M 733:, 459:, 455:, 451:, 447:, 443:, 332:. 1464:. 1436:. 1408:. 1402:: 1331:. 945:( 854:2 850:2 835:6 833:C 827:3 825:C 823:7 819:3 812:3 808:2 803:. 801:y 799:O 797:x 793:2 789:3 787:O 785:2 778:3 755:. 741:. 109:) 103:( 98:) 94:( 84:· 77:· 70:· 63:· 36:.

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Phases
Ferrite
Austenite
Cementite
Martensite
Graphite
Microstructures
Spheroidite
Pearlite
Bainite
Ledeburite
Tempered martensite
Widmanstätten structures
Crucible steel
Carbon steel
Spring steel
Alloy steel
Maraging steel

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