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32:. Simply put, the ideal polarizable electrode is characterized by charge separation at the electrode-electrolyte boundary and is electrically equivalent to a capacitor, while the ideal non-polarizable electrode is characterized by no charge separation and is electrically equivalent to a short.
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The classical examples of the two nearly ideal types of electrodes, polarizable and non-polarizable, are the
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Vladimir
Sergeevich Bagot'skiĭ, "Fundamentals Of Electrochemistry",John Wiley & Sons, 2006, p. 178.
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The concept of the ideal polarizability has been first introduced by
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184:(3rd ed.). Hoboken, NJ: John Wiley & Sons, Inc.
159:(2nd ed.). Hoboken, NJ: John Wiley & Sons, Inc.
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Electrochemical
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in contact with an oxygen-free KCl solution and the
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