1384:<ref>{{cite journal | vauthors = Wood JR | title = Chemical Warfare-A Chemical and Toxicological Review | journal = American Journal of Public Health and the Nation's Health | volume = 34 | issue = 5 | pages = 455–60 | date = May 1944 | pmid = 18015982 | pmc = 1625133 | doi = 10.2105/AJPH.34.5.455 }}</ref>
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Besides avoiding situations in which it might be used, an ] filter and a ] can help protect against MD. It should, however, be noted that MD can penetrate ], so some masks and clothing are ineffective.<ref name=ledgard/> Other protective clothing, such as full body protection, are useful as
200:
Updating {{chembox}} (no changed fields - added verified revid - updated 'DrugBank_Ref', 'UNII_Ref', 'ChEMBL_Ref', 'ChEBI_Ref', 'KEGG_Ref', 'StdInChI_Ref', 'StdInChIKey_Ref', 'ChEBI_Ref') per [[Knowledge:WikiProject
2044:
73yFBWU8ckX4vCH8qafExaduwN0&hl=en&sa=X&oi=book_result&resnum=1&ct=result</ref> Other symptoms include: ] with vesicle formation; ] and ]. ]s, ], ], and ] with damage to the ] can be delayed for about three to five days; ] can also occur.<ref
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It should, however, be noted that MD can penetrate ], so some masks and clothing are ineffective.<ref name=ledgard/> Other protective clothing, such as full body protection, are useful as well. Among the agents useful for decontamination of MD are ] and ].<ref
222:
2033:
216 | isbn = 9781420052664 | publisher = CRC Press }}</ref> Other symptoms include: ] with vesicle formation; ] and ]. ]s, ], ], and ] with damage to the ] can be delayed for about three to five days; ] can also occur.<ref name =
78:
35:
1355:'''Methyldichloroarsine''', sometimes abbreviated "MD", is an ] with the formula CH<sub>3</sub>AsCl<sub>2</sub>. This colourless volatile liquid is a highly toxic ] that has been used in ].<ref name=
86:
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MD is not persistent, meaning that it will dissipate after a short time.<ref name=emergency/> It is, however, still quite lethal. The ] for MD is about 3,000 mg/min.<ref name=emergency/>
92:
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11:
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Focusing on the ] center, the molecule is pyramidal with the Cl-As-Cl and C-As-Cl angles approaching 90° (see image). Virtually all related arsenic(III) compounds adopt similar structures.
43:
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MD is not persistent, meaning that it will dissipate after a short time.<ref name=emergency/> It is, however, still quite lethal. The ] for MD is about 3,000 mg/
1770::CH<sub>3</sub>AsO(ONa)<sub>2</sub> + SO<sub>2</sub> → CH<sub>3</sub>AsO + Na<sub>2</sub>SO<sub>4</sub>,
1763::CH<sub>3</sub>AsO(ONa)<sub>2</sub> + SO<sub>2</sub> → CH<sub>3</sub>AsO + Na<sub>2</sub>SO<sub>4</sub>,
57:
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is an ] with the formula CH<sub>3</sub>AsCl<sub>2</sub>. This colourless volatile liquid is a highly toxic ] that has been used in ].<ref name=
1999:
Although some of its symptoms resemble those from ], other symptoms include ] to the eyes and to the nose, although ]ing may be delayed for hours.<ref name=
1957:
Although some of its symptoms resemble those from ], other symptoms include ] to the eyes and to the nose, although ]ing may be delayed for hours.<ref name=
116:
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pyramidal with the Cl-As-Cl and C-As-Cl angles approaching 90° (see image). Virtually all related arsenic(III) compounds adopt similar structures.
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name=northshore/><ref>http://web.gideononline.com/abstract.php?module=toxagents&disease=1636&view=General</ref>
1918:
Methyldichloroarsine's only documented large-scale use is as a ].{{Citation needed|date=December 2008}}{{Clarify|date=December 2008}}
1718::AsCl<sub>3</sub> + CH<sub>3</sub>MgCl → CH<sub>3</sub>AsCl<sub>2</sub> + ]
1711::AsCl<sub>3</sub> + CH<sub>3</sub>MgCl → CH<sub>3</sub>AsCl<sub>2</sub> + ]
213:
157:
1861::CH<sub>3</sub>AsO + 2 HCl → CH<sub>3</sub>AsCl<sub>2</sub> + H<sub>2</sub>O
1854::CH<sub>3</sub>AsO + 2 HCl → CH<sub>3</sub>AsCl<sub>2</sub> + H<sub>2</sub>O
24:
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CA34Kf2r6n&sig=3ZuaZscVDFuliScsWni7QHRFWCo&hl=en&sa=X&oi=book_result&resnum=5&ct=result#PPA118,M1.
87:
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subsequently reacting the monomethylarsine oxide thus formed with ] to yield methyldichloroarsine:<ref>Lohs
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subsequently reacting the monomethylarsine oxide thus formed with ] to yield methyldichloroarsine:<ref>
1680:{{ cite book | vauthors = Ledgard J | title = The Laboratory History of Chemical Warfare Agents | url = https
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Besides avoiding situations in which it might be used, an ] filter and a ] can help protect against MD.
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well. Among the agents useful for decontamination of MD are ] and ].<ref name=emergency/>
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was the first organoarsenic compound to be weaponized.<ref name=emed>Fitzgerald,
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2021:
Emergency
Response Handbook for Chemical and Biological Agents and Weapons | edition
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Methyldichloroarsine is produced by the reaction of ] and ]:<ref name=ledgard>
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Methyldichloroarsine is produced by the reaction of ] and ]:<ref name=ledgard>
1361:/www.northshore.org/healthresources/encyclopedia/bioterrorism/ch018200.aspx</ref
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was the first organoarsenic compound to be weaponized.<ref name=emed>
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367:| ImageName = Stereo structural formula of methyldichloroarsine
1112:| ExactMass = 159.882776927 g mol<sup>-1</sup>
736:| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
1543:
CBRNE - Vesicants, Organic
Arsenicals: L, ED, MD, PD, HL
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followed by ] of the disodium monomethylarsonate with ]:
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followed by ] of the disodium monomethylarsonate with ]:
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German chemists weaponized methyldichloroarsine during ]
783:
ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
872:| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
865:| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
2011:://books.google.com/books?id=S4PW-5qHUU8C&pg=PA216
1972:://books.google.com/books?id=S4PW-5qHUU8C&pg=PA216
1682:://books.google.com/books?id=atU4GuKE8x0C&pg=PA117
1651:://books.google.com/books?id=atU4GuKE8x0C&pg=PA117
139:
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http://emedicine.medscape.com/article/832158-overview
801:| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
1833:
Militärverlag der
Deutschen Demokratischen Republik
1800:
Militärverlag der
Deutschen Demokratischen Republik
1370:'''Methyldichloroarsine''', sometimes abbreviated "
838:StdInChI_Ref = {{stdinchicite|correct|chemspider}}
718:| PubChem_Ref = {{Pubchemcite|correct|PubChem}}
275:(40 intermediate revisions by 33 users not shown)
344:=Molecular_structure_of_methyldichloroarsine.png
358:Molecular_structure_of_methyldichloroarsine.png
1046:| Density = 1.836 g/cm<sup>3</sup>
214:Latest revision as of 08:56, 2 September 2024
1186:Density = 1.836 g/cm<sup>3</sup>
888:| StdInChIKey = VXRMBBLRHSRVDK-UHFFFAOYSA-N
881:| StdInChIKey = VXRMBBLRHSRVDK-UHFFFAOYSA-N
942:| InChIKey = VXRMBBLRHSRVDK-UHFFFAOYSA-N}}
453:| SystematicName = Dichloro(methyl)arsane
935:InChIKey = VXRMBBLRHSRVDK-UHFFFAOYSA-N}}
631:| InChIKey1 = VXRMBBLRHSRVDK-UHFFFAOYAY
624:| InChIKey1 = VXRMBBLRHSRVDK-UHFFFAOYAY
1618:Focusing on the ] center, the molecule
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856:| StdInChI = 1S/CH3AsCl2/c1-2(3)4/h1H3
849:| StdInChI = 1S/CH3AsCl2/c1-2(3)4/h1H3
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1602:==Structure, synthesis, reactivity==
1595:==Structure, synthesis, reactivity==
158:Revision as of 07:09, 10 August 2011
148:
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1380:and also known as '''methyl Dick'''
923:| InChI = 1S/CH3AsCl2/c1-2(3)4/h1H3
615:| InChI1 = 1/CH3AsCl2/c1-2(3)4/h1H3
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502:| ImageAltR1 = Space-filling model
201:Chemicals/Chembox validation|Chem/
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916:InChI = 1S/CH3AsCl2/c1-2(3)4/h1H3
766:| MeSHName = Methyldichloroarsine
608:InChI1 = 1/CH3AsCl2/c1-2(3)4/h1H3
532:| PIN = Methylarsonous dichloride
410:| ImageAltL1 = Structural formula
95:
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564:| Abbreviations = MD<br />
1982:Methyldichloroarsine&source
1661:Methyldichloroarsine&source
1019:| Appearance = Colorless liquid
548:|Section1={{Chembox Identifiers
1435:during ] between 1917 and 1918
967:|Section2={{Chembox Properties
519:Abbreviations = MD<br />
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14:Browse history interactively
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1948:===Symptoms of poisoning===
1941:===Symptoms of poisoning===
1831:edition = 4th | publisher =
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441:= Methyldichloroarsine
1508:between 1917 and 1918
489:{{Chembox Identifiers
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1431:methyldichloroarsine
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960:{{Chembox Properties
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2017:Cashman JR | title
1909:==Use as a weapon==
1902:==Use as a weapon==
1826:Synthetische Gifte
1804:Berlin (East), 1974
1357:northshore>http:
1197:| MeltingPtC = −55
466:| ImageSizeR1 = 125
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2005:{{ cite book | url
1990:yAI5GDodNn&sig
1843:| language = de }}
1790:Synthetische Gifte
1103:| BoilingPtC = 133
904:| SMILES = Cl(Cl)C
897:| SMILES = Cl(Cl)C
647:| CASNo = 593-89-5
640:| CASNo = 593-89-5
328:| verifiedrevid =
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443:-3D-spacefill.png
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2111:===Protection===
2104:===Protection===
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1471:
1467:
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1428:
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1379:
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1371:
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1360:
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1349:
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1343:
1340:
1337:
1336:
1333:
1331:
1329:
1326:
1324:
1321:
1320:
1316:AutoignitionPt
1315:
1313:
1311:
1309:
1304:
1302:
1300:
1297:
1296:
1293:
1291:
1289:
1286:
1284:
1281:
1280:
1277:
1275:
1273:
1270:
1268:
1265:
1264:
1262:
1258:
1255:
1252:
1248:
1246:
1240:
1239:
1237:
1233:
1229:
1227:
1221:
1220:
1218:
1214:
1210:
1208:
1202:
1201:
1199:
1196:
1194:
1191:
1190:
1188:
1184:
1180:
1178:
1172:
1171:
1166:
1164:
1159:
1156:
1155:
1153:
1149:
1145:
1143:
1137:
1136:
1131:
1127:
1125:
1120:
1117:
1116:
1114:
1111:
1109:
1106:
1105:
1100:
1098:
1093:
1090:
1089:
1085:
1081:
1079:
1077:
1075:
1071:
1067:
1065:
1063:
1060:
1059:
1057:
1054:
1052:
1049:
1048:
1043:
1041:
1036:
1033:
1032:
1030:
1027:
1025:
1022:
1021:
1016:
1014:
1009:
1006:
1005:
1001:
997:
994:
990:
987:
985:
983:
981:
977:
975:
973:
970:
969:
966:
964:
962:
958:
955:
952:
950:
948:
945:
944:
941:
939:
937:
933:
931:
929:
926:
925:
922:
920:
918:
914:
912:
910:
907:
906:
903:
901:
899:
896:
894:
891:
890:
887:
885:
883:
880:
878:
875:
874:
871:
869:
867:
864:
862:
859:
858:
855:
853:
851:
848:
846:
843:
842:
840:
836:
832:
830:
824:
823:
821:
816:
812:
810:
804:
803:
798:
796:
791:
788:
787:
785:
781:
777:
775:
769:
768:
765:
763:
761:
758:
757:
755:
751:
747:
745:
739:
738:
733:
731:
726:
723:
722:
720:
717:
715:
712:
711:
706:
704:
699:
696:
695:
692:
690:
688:
684:
682:
680:
677:
676:
671:
669:
667:
665:
660:
657:
655:
653:
650:
649:
646:
644:
642:
639:
637:
634:
633:
630:
628:
626:
623:
621:
618:
617:
614:
612:
610:
606:
604:
602:
599:
598:
595:
593:
591:
588:
586:
583:
582:
579:
577:
575:
572:
570:
567:
566:
561:
559:
554:
551:
550:
545:
543:
538:
535:
534:
531:
529:
527:
524:
523:
521:
517:
513:
511:
505:
504:
501:
499:
497:
494:
493:
491:
487:
484:
481:
477:
475:
469:
468:
465:
463:
461:
458:
457:
455:
452:
450:
447:
446:
442:
438:
434:
432:
427:
424:
423:
421:
418:
416:
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409:
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402:
401:
397:
393:
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389:
387:
383:
379:
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375:
372:
371:
369:
366:
364:
361:
360:
356:
352:
350:
348:
346:
341:
339:
337:
334:
333:
329:
327:
325:
323:
319:
317:
315:
312:
311:
308:
306:
304:
301:
300:
297:
295:
293:
290:
288:
285:
284:
281:
277:
276:
272:
271:
251:
246:
245:
230:
209:
190:
185:
184:
169:
129:
121:
115:
99:
93:
85:
79:
76:
75:
68:
56:
50:
42:
36:
33:
32:
25:
23:
19:
18:
10:
6:
4:
3:
2:
2435:
2419:
2416:
2408:
2405:
2397:
2394:
2386:
2383:
2377:
2372:
2366:
2363:
2357:
2352:
2346:
2339:
2336:
2330:
2323:
2320:
2314:
2307:
2304:
2300:
2298:
2295:
2293:
2292:
2286:
2284:
2279:
2277:
2276:
2272:
2270:
2267:
2265:
2264:
2258:
2256:
2251:
2249:
2248:
2236:
2229:
2226:
2222:
2220:
2217:
2215:
2214:
2208:
2203:
2197:
2195:
2190:
2188:
2187:
2181:
2179:
2174:
2172:
2171:
2159:
2152:
2149:
2145:
2143:
2140:
2138:
2137:
2130:
2118:
2115:
2109:
2107:
2102:
2100:
2099:
2095:
2093:
2090:
2088:
2087:
2073:
2066:
2063:
2059:
2057:
2054:
2052:
2051:
2042:
2039:
1997:
1955:
1952:
1946:
1944:
1939:
1937:
1936:
1932:
1930:
1927:
1925:
1924:
1916:
1913:
1907:
1905:
1900:
1898:
1897:
1893:
1891:
1888:
1886:
1885:
1877:
1873:
1871:
1868:
1866:
1865:
1859:
1857:
1852:
1850:
1849:
1816:
1777:
1774:
1768:
1766:
1761:
1759:
1758:
1752:
1750:
1745:
1743:
1742:
1734:
1730:
1728:
1725:
1723:
1722:
1716:
1714:
1709:
1707:
1706:
1676:
1645:
1642:
1638:
1636:
1633:
1631:
1630:
1616:
1609:
1606:
1600:
1598:
1593:
1591:
1590:
1586:
1584:
1581:
1579:
1578:
1502:
1462:''emedicine''
1425:
1422:
1416:
1414:
1409:
1407:
1406:
1402:
1400:
1397:
1395:
1394:
1368:
1353:
1350:
1346:
1344:
1341:
1339:
1338:
1332:
1330:
1325:
1323:
1322:
1312:
1301:
1298:
1292:
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1285:
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1250:
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1242:
1241:
1231:
1228:
1226:
1223:
1222:
1212:
1209:
1207:
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1195:
1192:
1182:
1179:
1177:
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1129:
1126:
1124:
1121:
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1107:
1102:
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1091:
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1040:
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1026:
1023:
1018:
1015:
1013:
1010:
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940:
930:
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911:
908:
902:
900:
895:
893:
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879:
877:
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863:
861:
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852:
847:
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825:
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749:
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741:
740:
735:
732:
730:
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724:
716:
713:
708:
705:
703:
700:
697:
691:
681:
678:
668:
654:
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645:
643:
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636:
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629:
627:
622:
620:
619:
613:
603:
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592:
587:
585:
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512:
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506:
500:
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476:
474:
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403:
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296:
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286:
278:
273:
268:
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249:
242:
238:
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219:
215:
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172:
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126:Content added
118:
16:
2154:==See also==
2029:2008 | page
1978:PA216&dq
1845:</ref>
1839:GDR | year =
1835:| location =
1811:</ref>
1702:</ref>
1696:2006 | page
1671:</ref>
1657:PA117&dq
1574:</ref>
1497:</ref>
1305:Autoignition
1294:| FlashPt =
1287:| FlashPt =
2260:{{reflist}}
2253:{{reflist}}
2025:2nd | year
2013:| vauthors
1986:web&ots
1959:northshore/
1665:web&ots
1565:access-date
1548:publisher =
1418:==History==
1411:==History==
439:ImageFileR1
394:ImageSizeL1
353:ImageFileL1
2241:References
1824:| title =
1519:Fitzgerald
1082:MeltingPtC
96:Revision 2
53:Revision 1
2034:emed/>
2001:emergency
1572:-12-23 }}
1541:| title =
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380:ImageSize
342:ImageFile
330:444013566
320:444012581
298:{{Chembox
291:{{Chembox
2164:See also
1974:&lpg
1882:Line 64:
1879:Line 66:
1822:Lohs KH
1809:(german)
1798:Auflage,
1739:Line 58:
1736:Line 60:
1653:&lpg
1624:trigonal
1620:geometry
1488:December
1485:accessed
1456:Timothy.
1453:Vollmer,
1444:Geoffrey
1254:Section3
1244:⚫
1225:⚫
1206:⚫
1176:⚫
1162:⚫
1141:⚫
1123:⚫
1096:⚫
1039:⚫
1028:| H = 3
1012:⚫
954:Section2
828:⚫
817:MeSHName
808:⚫
794:⚫
773:⚫
743:⚫
729:⚫
702:⚫
557:⚫
541:⚫
509:⚫
483:Section1
473:⚫
430:⚫
241:contribs
180:contribs
170:CheMoBot
141:Wikitext
1963:<ref
1684:| isbn
1525:Vollmer
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283:Line 1:
280:Line 1:
192:141,565
1700:117 }}
1559:-06-19
1555:date =
1132:reacts
267:HotCat
265:using
261:added
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231:JWBE
223:undo
218:edit
187:Bots
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2077:(
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Text is available under the Creative Commons Attribution-ShareAlike License. Additional terms may apply.