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Wohl degradation

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is added, leading to removal of all the acetate groups and ejection of the nitrile group and collapse of the second carbon from a tetrahedral structure to an aldehyde.
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Let's say we have a kiliani-fischer synthesis, it basically removes the row of the C2 carbon, it shortens the carbon chain by one carbon. In one modification,
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1893) converts the aldose first to the alpha-hydroxy-carboxylic acid with
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as shown below. The reaction is named after the German chemist
25: 56: 79:. In this reaction step the oxime is converted into the 3455:
Erlenmeyer–Plöchl azlactone and amino-acid synthesis
130:and then to the shortened aldose by reaction with 2516:Divinylcyclopropane-cycloheptadiene rearrangement 3590: 309: 2776:Thermal rearrangement of aromatic hydrocarbons 1410:Thermal rearrangement of aromatic hydrocarbons 3505:Lectka enantioselective beta-lactam synthesis 765: 295: 3284:Inverse electron-demand Diels–Alder reaction 1105:Heterogeneous metal catalyzed cross-coupling 2626:Lobry de Bruyn–Van Ekenstein transformation 28:. The classic example is the conversion of 302: 288: 233: 105: 3116:Petrenko-Kritschenko piperidone synthesis 2571:Fritsch–Buttenberg–Wiechell rearrangement 271:Organic syntheses based on name reactions 3279:Intramolecular Diels–Alder cycloaddition 83:with simultaneous conversion of all the 3591: 3299:Metal-centered cycloaddition reactions 2951:Debus–Radziszewski imidazole synthesis 895:Bodroux–Chichibabin aldehyde synthesis 3445:Diazoalkane 1,3-dipolar cycloaddition 3349:Vinylcyclopropane (5+2) cycloaddition 3254:Diazoalkane 1,3-dipolar cycloaddition 3026:Hurd–Mori 1,2,3-thiadiazole synthesis 2521:Dowd–Beckwith ring-expansion reaction 1688:Hurd–Mori 1,2,3-thiadiazole synthesis 764: 601:LFER solvent coefficients (data page) 283: 200: 2256:Sharpless asymmetric dihydroxylation 1493:Methoxymethylenetriphenylphosphorane 273:, Volume 22 Alfred Hassner,C. Stumer 166: 2381:Allen–Millar–Trippett rearrangement 234:Clarke, H. T.; Nagy, S. M. (1940). 13: 3520:Nitrone-olefin (3+2) cycloaddition 3515:Niementowski quinazoline synthesis 3304:Nitrone-olefin (3+2) cycloaddition 3229:Azide-alkyne Huisgen cycloaddition 3091:Niementowski quinazoline synthesis 2846:Azide-alkyne Huisgen cycloaddition 2151:Meerwein–Ponndorf–Verley reduction 1703:Leimgruber–Batcho indole synthesis 42: 24:is a chain contraction method for 14: 3625: 3344:Trimethylenemethane cycloaddition 3046:Johnson–Corey–Chaykovsky reaction 2911:Cadogan–Sundberg indole synthesis 2891:Bohlmann–Rahtz pyridine synthesis 2851:Baeyer–Emmerling indole synthesis 1658:Cadogan–Sundberg indole synthesis 1150:Johnson–Corey–Chaykovsky reaction 3440:Cook–Heilbron thiazole synthesis 3269:Hexadehydro Diels–Alder reaction 3096:Niementowski quinoline synthesis 2926:Cook–Heilbron thiazole synthesis 2871:Bischler–Möhlau indole synthesis 2781:Tiffeneau–Demjanov rearrangement 2411:Baker–Venkataraman rearrangement 1569:Horner–Wadsworth–Emmons reaction 1240:Mizoroki-Heck vs. Reductive Heck 1125:Horner–Wadsworth–Emmons reaction 636:Neighbouring group participation 2976:Fiesselmann thiophene synthesis 2806:Westphalen–LettrĂ© rearrangement 2786:Vinylcyclopropane rearrangement 2616:Kornblum–DeLaMare rearrangement 2261:Epoxidation of allylic alcohols 2171:Noyori asymmetric hydrogenation 2106:Kornblum–DeLaMare rearrangement 1781:Gallagher–Hollander degradation 3435:Chichibabin pyridine synthesis 2921:Chichibabin pyridine synthesis 2881:Blum–Ittah aziridine synthesis 2716:Ring expansion and contraction 985:Cross dehydrogenative coupling 264: 227: 194: 160: 1: 3405:Bischler–Napieralski reaction 3363:Heterocycle forming reactions 3016:Hemetsberger indole synthesis 2876:Bischler–Napieralski reaction 2791:Wagner–Meerwein rearrangement 2761:Sommelet–Hauser rearrangement 2741:Seyferth–Gilbert homologation 2606:Ireland–Claisen rearrangement 2601:Hofmann–Martius rearrangement 2361:2,3-sigmatropic rearrangement 1976:Corey–Winter olefin synthesis 1901:Barton–McCombie deoxygenation 1544:Corey–Winter olefin synthesis 1498:Seyferth–Gilbert homologation 1365:Seyferth–Gilbert homologation 153: 3510:Lehmstedt–Tanasescu reaction 3470:Gabriel–Colman rearrangement 3425:Bucherer carbazole synthesis 3420:Borsche–Drechsel cyclization 3400:Bernthsen acridine synthesis 3385:Bamberger triazine synthesis 3370:Algar–Flynn–Oyamada reaction 3081:Nazarov cyclization reaction 2946:De Kimpe aziridine synthesis 2901:Bucherer carbazole synthesis 2896:Borsche–Drechsel cyclization 2666:Nazarov cyclization reaction 2646:Meyer–Schuster rearrangement 2576:Gabriel–Colman rearrangement 2326:Wolffenstein–Böters reaction 2211:Reduction of nitro compounds 2061:Grundmann aldehyde synthesis 1866:Algar–Flynn–Oyamada reaction 1275:Olefin conversion technology 1270:Nozaki–Hiyama–Kishi reaction 1065:Gabriel–Colman rearrangement 955:Claisen-Schmidt condensation 900:Bouveault aldehyde synthesis 55:is converted to the glucose 7: 3485:Hantzsch pyridine synthesis 3264:Enone–alkene cycloadditions 3086:Nenitzescu indole synthesis 3006:Hantzsch pyridine synthesis 2971:Ferrario–Ackermann reaction 2621:Kowalski ester homologation 2586:Halogen dance rearrangement 2431:Benzilic acid rearrangement 1856:Akabori amino-acid reaction 1816:Von Braun amide degradation 1761:Barbier–Wieland degradation 1713:Nenitzescu indole synthesis 1693:Kharasch–Sosnovsky reaction 1584:Julia–Kocienski olefination 1488:Kowalski ester homologation 1185:Kowalski ester homologation 1160:Julia–Kocienski olefination 915:Cadiot–Chodkiewicz coupling 840:Aza-Baylis–Hillman reaction 785:Acetoacetic ester synthesis 496:Dynamic binding (chemistry) 486:Conrotatory and disrotatory 461:Charge remote fragmentation 141: 10: 3630: 3550:Robinson–Gabriel synthesis 3500:Kröhnke pyridine synthesis 3334:Retro-Diels–Alder reaction 3274:Imine Diels–Alder reaction 3061:Kröhnke pyridine synthesis 2676:Newman–Kwart rearrangement 2651:Mislow–Evans rearrangement 2561:Fischer–Hepp rearrangement 2506:Di-Ď€-methane rearrangement 2286:Stephen aldehyde synthesis 2021:Eschweiler–Clarke reaction 1738:Williamson ether synthesis 1055:Fujiwara–Moritani reaction 960:Combes quinoline synthesis 925:Carbonyl olefin metathesis 626:More O'Ferrall–Jencks plot 551:Grunwald–Winstein equation 521:Electron-withdrawing group 456:Catalytic resonance theory 259:, vol. 3, p. 690 222:, vol. 3, p. 101 172:"Abbau des Traubenzuckers" 3560:Urech hydantoin synthesis 3540:Pomeranz–Fritsch reaction 3465:Fischer oxazole synthesis 3362: 3199:1,3-Dipolar cycloaddition 3189: 3171:Urech hydantoin synthesis 3141:Reissert indole synthesis 3126:Pomeranz–Fritsch reaction 3056:Knorr quinoline synthesis 2986:Fischer oxazole synthesis 2916:Camps quinoline synthesis 2836:1,3-Dipolar cycloaddition 2824: 2736:Semipinacol rearrangement 2711:Ramberg–Bäcklund reaction 2696:Piancatelli rearrangement 2636:McFadyen–Stevens reaction 2391:Alpha-ketol rearrangement 2339: 2146:McFadyen–Stevens reaction 2091:Kiliani–Fischer synthesis 2011:Elbs persulfate oxidation 1936:Bouveault–Blanc reduction 1896:Baeyer–Villiger oxidation 1834: 1751: 1728:Schotten–Baumann reaction 1631: 1604:Ramberg–Bäcklund reaction 1511: 1483:Kiliani–Fischer synthesis 1463: 1325:Ramberg–Bäcklund reaction 1310:Pinacol coupling reaction 1305:Piancatelli rearrangement 1200:Liebeskind–Srogl coupling 1050:Fujimoto–Belleau reaction 773: 767:List of organic reactions 631:Negative hyperconjugation 376: 318: 188:10.1002/cber.189302601150 3535:Pictet–Spengler reaction 3450:Einhorn–Brunner reaction 3415:Boger pyridine synthesis 3309:Oxo-Diels–Alder reaction 3224:Aza-Diels–Alder reaction 3121:Pictet–Spengler reaction 3021:Hofmann–Löffler reaction 3011:Hegedus indole synthesis 2981:Fischer indole synthesis 2856:Bartoli indole synthesis 2811:Willgerodt rearrangement 2641:McLafferty rearrangement 2551:Ferrier carbocyclization 2366:2,3-Wittig rearrangement 2356:1,2-Wittig rearrangement 2196:Parikh–Doering oxidation 2186:Oxygen rebound mechanism 1851:Adkins–Peterson reaction 1743:Yamaguchi esterification 1683:Hegedus indole synthesis 1648:Bartoli indole synthesis 1519:Bamford–Stevens reaction 1435:Weinreb ketone synthesis 1395:Stork enamine alkylation 1170:Knoevenagel condensation 1040:Ferrier carbocyclization 930:Castro–Stephens coupling 556:Hammett acidity function 546:Free-energy relationship 491:Curtin–Hammett principle 476:Conformational isomerism 3495:Knorr pyrrole synthesis 3430:Bucherer–Bergs reaction 3375:Allan–Robinson reaction 3354:Wagner-Jauregg reaction 3146:Ring-closing metathesis 3071:Larock indole synthesis 3051:Knorr pyrrole synthesis 2906:Bucherer–Bergs reaction 2771:Stieglitz rearrangement 2751:Skattebøl rearrangement 2721:Ring-closing metathesis 2581:Group transfer reaction 2546:Favorskii rearrangement 2486:Cornforth rearrangement 2416:Bamberger rearrangement 2321:Wolff–Kishner reduction 2141:Markó–Lam deoxygenation 2036:Fleming–Tamao oxidation 2031:Fischer–Tropsch process 1718:Oxymercuration reaction 1698:Knorr pyrrole synthesis 1524:Barton–Kellogg reaction 1430:Wagner-Jauregg reaction 1350:Ring-closing metathesis 1340:Reimer–Tiemann reaction 1330:Rauhut–Currier reaction 1245:Nef isocyanide reaction 1205:Malonic ester synthesis 1175:Knorr pyrrole synthesis 1110:High dilution principle 1045:Friedel–Crafts reaction 980:Cross-coupling reaction 905:Bucherer–Bergs reaction 890:Blanc chloromethylation 880:Blaise ketone synthesis 855:Baylis–Hillman reaction 850:Barton–Kellogg reaction 825:Allan–Robinson reaction 731:Woodward–Hoffmann rules 466:Charge-transfer complex 112:Ruff–Fenton degradation 106:Ruff–Fenton degradation 3599:Carbohydrate chemistry 3460:Feist–Benary synthesis 3234:Bradsher cycloaddition 3204:4+4 Photocycloaddition 3161:Simmons–Smith reaction 3106:Paternò–BĂĽchi reaction 2966:Feist–Benary synthesis 2956:Dieckmann condensation 2706:Pummerer rearrangement 2686:Oxy-Cope rearrangement 2661:Myers allene synthesis 2611:Jacobsen rearrangement 2526:Electrocyclic reaction 2501:Demjanov rearrangement 2456:Buchner ring expansion 2426:Beckmann rearrangement 2406:Aza-Cope rearrangement 2401:Arndt–Eistert reaction 2376:Alkyne zipper reaction 2296:Transfer hydrogenation 2271:Sharpless oxyamination 2246:Selenoxide elimination 2131:Lombardo methylenation 2056:Griesbaum coozonolysis 1966:Corey–Itsuno reduction 1941:Boyland–Sims oxidation 1881:Angeli–Rimini reaction 1529:Boord olefin synthesis 1473:Arndt–Eistert reaction 1465:Homologation reactions 1265:Nitro-Mannich reaction 1180:Kolbe–Schmitt reaction 990:Cross-coupling partner 910:Buchner ring expansion 830:Arndt–Eistert reaction 596:Kinetic isotope effect 343:Rearrangement reaction 48: 22:carbohydrate chemistry 3609:Degradation reactions 3604:Elimination reactions 3319:Pauson–Khand reaction 3156:Sharpless epoxidation 3111:Pechmann condensation 2991:Friedländer synthesis 2941:Davis–Beirut reaction 2796:Wallach rearrangement 2766:Stevens rearrangement 2701:Pinacol rearrangement 2681:Overman rearrangement 2596:Hofmann rearrangement 2591:Hayashi rearrangement 2556:Ferrier rearrangement 2511:Dimroth rearrangement 2496:Curtius rearrangement 2491:Criegee rearrangement 2471:Claisen rearrangement 2461:Carroll rearrangement 2396:Amadori rearrangement 2386:Allylic rearrangement 2266:Sharpless epoxidation 2001:Dess–Martin oxidation 1926:Bohn–Schmidt reaction 1786:Hofmann rearrangement 1589:Kauffmann olefination 1512:Olefination reactions 1450:Wurtz–Fittig reaction 1285:Palladium–NHC complex 1165:Kauffmann olefination 1120:Homologation reaction 970:Corey–House synthesis 950:Claisen rearrangement 746:Yukawa–Tsuno equation 706:Swain–Lupton equation 686:Spherical aromaticity 621:Möbius–HĂĽckel concept 406:Aromatic ring current 368:Substitution reaction 46: 3525:Paal–Knorr synthesis 3395:Barton–Zard reaction 3339:Staudinger synthesis 3289:Ketene cycloaddition 3259:Diels–Alder reaction 3239:Cheletropic reaction 3219:Alkyne trimerisation 3101:Paal–Knorr synthesis 3066:Kulinkovich reaction 3041:Jacobsen epoxidation 2961:Diels–Alder reaction 2756:Smiles rearrangement 2746:Sigmatropic reaction 2631:Lossen rearrangement 2481:Corey–Fuchs reaction 2446:Boekelheide reaction 2441:Bergmann degradation 2371:Achmatowicz reaction 2156:Methionine sulfoxide 1956:Clemmensen reduction 1916:Bergmann degradation 1846:Acyloin condensation 1811:Strecker degradation 1766:Bergmann degradation 1733:Ullmann condensation 1599:Peterson olefination 1574:Hydrazone iodination 1554:Elimination reaction 1455:Zincke–Suhl reaction 1375:Sonogashira coupling 1335:Reformatsky reaction 1295:Peterson olefination 1260:Nierenstein reaction 1190:Kulinkovich reaction 1005:Diels–Alder reaction 965:Corey–Fuchs reaction 945:Claisen condensation 815:Alkyne trimerisation 790:Acyloin condensation 756:ÎŁ-bishomoaromaticity 716:Thorpe–Ingold effect 328:Elimination reaction 201:Braun, GĂ©za (1940). 110:In a variation, the 47:The Wohl degradation 3545:Prilezhaev reaction 3530:Pellizzari reaction 3209:(4+3) cycloaddition 3176:Van Leusen reaction 3151:Robinson annulation 3136:Pschorr cyclization 3131:Prilezhaev reaction 2861:Bergman cyclization 2816:Wolff rearrangement 2801:Weerman degradation 2691:Pericyclic reaction 2671:Neber rearrangement 2566:Fries rearrangement 2451:Brook rearrangement 2436:Bergman cyclization 2281:Staudinger reaction 2226:Rosenmund reduction 2216:Reductive amination 2181:Oppenauer oxidation 1971:Corey–Kim oxidation 1946:Cannizzaro reaction 1821:Weerman degradation 1796:Isosaccharinic acid 1708:Mukaiyama hydration 1564:Hofmann elimination 1549:Dehydrohalogenation 1534:Chugaev elimination 1355:Robinson annulation 1300:Pfitzinger reaction 1070:Gattermann reaction 1015:Wulff–Dötz reaction 995:Dakin–West reaction 920:Carbonyl allylation 865:Bergman cyclization 651:Kennedy J. P. Orton 571:Hammond's postulate 541:Flippin–Lodge angle 511:Electromeric effect 436:Beta-silicon effect 421:Baker–Nathan effect 3294:McCormack reaction 3244:Conia-ene reaction 3076:Madelung synthesis 2866:Biginelli reaction 2656:Mumm rearrangement 2541:Favorskii reaction 2476:Cope rearrangement 2466:Chan rearrangement 2231:Rubottom oxidation 2161:Miyaura borylation 2126:Lipid peroxidation 2121:Lindgren oxidation 2101:Kornblum oxidation 2096:Kolbe electrolysis 2041:Fukuyama reduction 1951:Carbonyl reduction 1801:Marker degradation 1663:Diazonium compound 1653:Boudouard reaction 1632:Carbon-heteroatom 1559:Grieco elimination 1345:Rieche formylation 1290:Passerini reaction 1220:Meerwein arylation 1140:Hydroxymethylation 1035:Favorskii reaction 935:Chan rearrangement 870:Biginelli reaction 795:Aldol condensation 641:2-Norbornyl cation 616:Möbius aromaticity 611:Markovnikov's rule 506:Effective molarity 451:BĂĽrgi–Dunitz angle 441:Bicycloaromaticity 94:In the final step 49: 3586: 3585: 3582: 3581: 3578: 3577: 3570:Wohl–Aue reaction 3214:6+4 Cycloaddition 3031:Iodolactonization 2351:1,2-rearrangement 2316:Wohl–Aue reaction 2236:Sabatier reaction 2201:Pinnick oxidation 2166:Mozingo reduction 2111:Leuckart reaction 2066:Haloform reaction 1981:Criegee oxidation 1961:Collins oxidation 1911:Benkeser reaction 1906:Bechamp reduction 1876:Andrussow process 1861:Alcohol oxidation 1771:Edman degradation 1678:Haloform reaction 1627: 1626: 1614:Takai olefination 1579:Julia olefination 1405:Takai olefination 1280:Olefin metathesis 1155:Julia olefination 1080:Grignard reaction 1060:Fukuyama coupling 975:Coupling reaction 940:Chan–Lam coupling 810:Alkyne metathesis 805:Alkane metathesis 661:Phosphaethynolate 566:George S. Hammond 526:Electronic effect 481:Conjugated system 363:Stereospecificity 358:Stereoselectivity 323:Addition reaction 312:organic reactions 257:Collected Volumes 245:Organic Syntheses 220:Collected Volumes 208:Organic Syntheses 136:hydrogen peroxide 132:Iron(III) sulfate 128:calcium hydroxide 59:by reaction with 3621: 3565:Wenker synthesis 3555:StollĂ© synthesis 3410:Bobbitt reaction 3380:Auwers synthesis 3324:Povarov reaction 3249:Cyclopropanation 3187: 3186: 3181:Wenker synthesis 2936:Darzens reaction 2886:Bobbitt reaction 2731:Schmidt reaction 2536:Enyne metathesis 2311:Whiting reaction 2306:Wharton reaction 2251:Shapiro reaction 2241:Sarett oxidation 2206:PrĂ©vost reaction 2016:Emde degradation 1826:Wohl degradation 1806:Ruff degradation 1776:Emde degradation 1673:Grignard reagent 1609:Shapiro reaction 1594:McMurry reaction 1461: 1460: 1425:Ullmann reaction 1390:StollĂ© synthesis 1380:Stetter reaction 1370:Shapiro reaction 1360:Sakurai reaction 1255:Negishi coupling 1235:Minisci reaction 1230:Michael reaction 1215:McMurry reaction 1210:Mannich reaction 1090:Hammick reaction 1085:Grignard reagent 1025:Enyne metathesis 1010:Doebner reaction 1000:Darzens reaction 845:Barbier reaction 835:Auwers synthesis 762: 761: 736:Woodward's rules 701:Superaromaticity 691:Spiroaromaticity 591:Inductive effect 586:Hyperconjugation 561:Hammett equation 501:Edwards equation 353:Regioselectivity 304: 297: 290: 281: 280: 274: 268: 262: 260: 253: 231: 225: 223: 216: 198: 192: 190: 164: 96:sodium methoxide 69:acetic anhydride 65:sodium methoxide 18:Wohl degradation 3629: 3628: 3624: 3623: 3622: 3620: 3619: 3618: 3589: 3588: 3587: 3574: 3475:Gewald reaction 3358: 3185: 3166:Skraup reaction 3001:Graham reaction 2996:Gewald reaction 2827: 2820: 2342: 2335: 2291:Swern oxidation 2276:Stahl oxidation 2221:Riley oxidation 2176:Omega oxidation 2136:Luche reduction 2086:Jones oxidation 2051:Glycol cleavage 2046:Ganem oxidation 1991:Davis oxidation 1986:Dakin oxidation 1921:Birch reduction 1871:Amide reduction 1837: 1830: 1791:Hooker reaction 1753: 1747: 1635: 1633: 1623: 1619:Wittig reaction 1507: 1503:Wittig reaction 1478:Hooker reaction 1459: 1440:Wittig reaction 1415:Thorpe reaction 1400:Suzuki reaction 1385:Stille reaction 1320:Quelet reaction 1195:Kumada coupling 1145:Ivanov reaction 1135:Hydrovinylation 1115:Hiyama coupling 1075:Glaser coupling 885:Blaise reaction 875:Bingel reaction 860:Benary reaction 777: 775: 769: 760: 656:Passive binding 576:Homoaromaticity 426:Baldwin's rules 401:Antiaromaticity 396:Anomeric effect 372: 314: 308: 278: 277: 269: 265: 255: 232: 228: 218: 199: 195: 165: 161: 156: 144: 108: 12: 11: 5: 3627: 3617: 3616: 3614:Name reactions 3611: 3606: 3601: 3584: 3583: 3580: 3579: 3576: 3575: 3573: 3572: 3567: 3562: 3557: 3552: 3547: 3542: 3537: 3532: 3527: 3522: 3517: 3512: 3507: 3502: 3497: 3492: 3487: 3482: 3480:Hantzsch ester 3477: 3472: 3467: 3462: 3457: 3452: 3447: 3442: 3437: 3432: 3427: 3422: 3417: 3412: 3407: 3402: 3397: 3392: 3390:Banert cascade 3387: 3382: 3377: 3372: 3366: 3364: 3360: 3359: 3357: 3356: 3351: 3346: 3341: 3336: 3331: 3329:Prato reaction 3326: 3321: 3316: 3311: 3306: 3301: 3296: 3291: 3286: 3281: 3276: 3271: 3266: 3261: 3256: 3251: 3246: 3241: 3236: 3231: 3226: 3221: 3216: 3211: 3206: 3201: 3195: 3193: 3184: 3183: 3178: 3173: 3168: 3163: 3158: 3153: 3148: 3143: 3138: 3133: 3128: 3123: 3118: 3113: 3108: 3103: 3098: 3093: 3088: 3083: 3078: 3073: 3068: 3063: 3058: 3053: 3048: 3043: 3038: 3033: 3028: 3023: 3018: 3013: 3008: 3003: 2998: 2993: 2988: 2983: 2978: 2973: 2968: 2963: 2958: 2953: 2948: 2943: 2938: 2933: 2928: 2923: 2918: 2913: 2908: 2903: 2898: 2893: 2888: 2883: 2878: 2873: 2868: 2863: 2858: 2853: 2848: 2843: 2838: 2832: 2830: 2822: 2821: 2819: 2818: 2813: 2808: 2803: 2798: 2793: 2788: 2783: 2778: 2773: 2768: 2763: 2758: 2753: 2748: 2743: 2738: 2733: 2728: 2723: 2718: 2713: 2708: 2703: 2698: 2693: 2688: 2683: 2678: 2673: 2668: 2663: 2658: 2653: 2648: 2643: 2638: 2633: 2628: 2623: 2618: 2613: 2608: 2603: 2598: 2593: 2588: 2583: 2578: 2573: 2568: 2563: 2558: 2553: 2548: 2543: 2538: 2533: 2528: 2523: 2518: 2513: 2508: 2503: 2498: 2493: 2488: 2483: 2478: 2473: 2468: 2463: 2458: 2453: 2448: 2443: 2438: 2433: 2428: 2423: 2421:Banert cascade 2418: 2413: 2408: 2403: 2398: 2393: 2388: 2383: 2378: 2373: 2368: 2363: 2358: 2353: 2347: 2345: 2341:Rearrangement 2337: 2336: 2334: 2333: 2331:Zinin reaction 2328: 2323: 2318: 2313: 2308: 2303: 2301:Wacker process 2298: 2293: 2288: 2283: 2278: 2273: 2268: 2263: 2258: 2253: 2248: 2243: 2238: 2233: 2228: 2223: 2218: 2213: 2208: 2203: 2198: 2193: 2188: 2183: 2178: 2173: 2168: 2163: 2158: 2153: 2148: 2143: 2138: 2133: 2128: 2123: 2118: 2113: 2108: 2103: 2098: 2093: 2088: 2083: 2078: 2076:Hydrogenolysis 2073: 2068: 2063: 2058: 2053: 2048: 2043: 2038: 2033: 2028: 2026:Étard reaction 2023: 2018: 2013: 2008: 2003: 1998: 1993: 1988: 1983: 1978: 1973: 1968: 1963: 1958: 1953: 1948: 1943: 1938: 1933: 1931:Bosch reaction 1928: 1923: 1918: 1913: 1908: 1903: 1898: 1893: 1888: 1883: 1878: 1873: 1868: 1863: 1858: 1853: 1848: 1842: 1840: 1836:Organic redox 1832: 1831: 1829: 1828: 1823: 1818: 1813: 1808: 1803: 1798: 1793: 1788: 1783: 1778: 1773: 1768: 1763: 1757: 1755: 1749: 1748: 1746: 1745: 1740: 1735: 1730: 1725: 1720: 1715: 1710: 1705: 1700: 1695: 1690: 1685: 1680: 1675: 1670: 1668:Esterification 1665: 1660: 1655: 1650: 1645: 1639: 1637: 1629: 1628: 1625: 1624: 1622: 1621: 1616: 1611: 1606: 1601: 1596: 1591: 1586: 1581: 1576: 1571: 1566: 1561: 1556: 1551: 1546: 1541: 1536: 1531: 1526: 1521: 1515: 1513: 1509: 1508: 1506: 1505: 1500: 1495: 1490: 1485: 1480: 1475: 1469: 1467: 1458: 1457: 1452: 1447: 1445:Wurtz reaction 1442: 1437: 1432: 1427: 1422: 1417: 1412: 1407: 1402: 1397: 1392: 1387: 1382: 1377: 1372: 1367: 1362: 1357: 1352: 1347: 1342: 1337: 1332: 1327: 1322: 1317: 1315:Prins reaction 1312: 1307: 1302: 1297: 1292: 1287: 1282: 1277: 1272: 1267: 1262: 1257: 1252: 1247: 1242: 1237: 1232: 1227: 1222: 1217: 1212: 1207: 1202: 1197: 1192: 1187: 1182: 1177: 1172: 1167: 1162: 1157: 1152: 1147: 1142: 1137: 1132: 1130:Hydrocyanation 1127: 1122: 1117: 1112: 1107: 1102: 1100:Henry reaction 1097: 1092: 1087: 1082: 1077: 1072: 1067: 1062: 1057: 1052: 1047: 1042: 1037: 1032: 1027: 1022: 1017: 1012: 1007: 1002: 997: 992: 987: 982: 977: 972: 967: 962: 957: 952: 947: 942: 937: 932: 927: 922: 917: 912: 907: 902: 897: 892: 887: 882: 877: 872: 867: 862: 857: 852: 847: 842: 837: 832: 827: 822: 817: 812: 807: 802: 800:Aldol reaction 797: 792: 787: 781: 779: 774:Carbon-carbon 771: 770: 759: 758: 753: 751:Zaitsev's rule 748: 743: 738: 733: 728: 723: 718: 713: 708: 703: 698: 696:Steric effects 693: 688: 683: 678: 673: 668: 663: 658: 653: 648: 643: 638: 633: 628: 623: 618: 613: 608: 603: 598: 593: 588: 583: 578: 573: 568: 563: 558: 553: 548: 543: 538: 533: 528: 523: 518: 513: 508: 503: 498: 493: 488: 483: 478: 473: 468: 463: 458: 453: 448: 443: 438: 433: 428: 423: 418: 413: 408: 403: 398: 393: 388: 383: 377: 374: 373: 371: 370: 365: 360: 355: 350: 348:Redox reaction 345: 340: 335: 333:Polymerization 330: 325: 319: 316: 315: 307: 306: 299: 292: 284: 276: 275: 263: 240:-gluconitrile" 226: 193: 182:(1): 730–744, 158: 157: 155: 152: 151: 150: 143: 140: 107: 104: 77:sodium acetate 9: 6: 4: 3: 2: 3626: 3615: 3612: 3610: 3607: 3605: 3602: 3600: 3597: 3596: 3594: 3571: 3568: 3566: 3563: 3561: 3558: 3556: 3553: 3551: 3548: 3546: 3543: 3541: 3538: 3536: 3533: 3531: 3528: 3526: 3523: 3521: 3518: 3516: 3513: 3511: 3508: 3506: 3503: 3501: 3498: 3496: 3493: 3491: 3490:Herz reaction 3488: 3486: 3483: 3481: 3478: 3476: 3473: 3471: 3468: 3466: 3463: 3461: 3458: 3456: 3453: 3451: 3448: 3446: 3443: 3441: 3438: 3436: 3433: 3431: 3428: 3426: 3423: 3421: 3418: 3416: 3413: 3411: 3408: 3406: 3403: 3401: 3398: 3396: 3393: 3391: 3388: 3386: 3383: 3381: 3378: 3376: 3373: 3371: 3368: 3367: 3365: 3361: 3355: 3352: 3350: 3347: 3345: 3342: 3340: 3337: 3335: 3332: 3330: 3327: 3325: 3322: 3320: 3317: 3315: 3312: 3310: 3307: 3305: 3302: 3300: 3297: 3295: 3292: 3290: 3287: 3285: 3282: 3280: 3277: 3275: 3272: 3270: 3267: 3265: 3262: 3260: 3257: 3255: 3252: 3250: 3247: 3245: 3242: 3240: 3237: 3235: 3232: 3230: 3227: 3225: 3222: 3220: 3217: 3215: 3212: 3210: 3207: 3205: 3202: 3200: 3197: 3196: 3194: 3192: 3191:Cycloaddition 3188: 3182: 3179: 3177: 3174: 3172: 3169: 3167: 3164: 3162: 3159: 3157: 3154: 3152: 3149: 3147: 3144: 3142: 3139: 3137: 3134: 3132: 3129: 3127: 3124: 3122: 3119: 3117: 3114: 3112: 3109: 3107: 3104: 3102: 3099: 3097: 3094: 3092: 3089: 3087: 3084: 3082: 3079: 3077: 3074: 3072: 3069: 3067: 3064: 3062: 3059: 3057: 3054: 3052: 3049: 3047: 3044: 3042: 3039: 3037: 3036:Isay reaction 3034: 3032: 3029: 3027: 3024: 3022: 3019: 3017: 3014: 3012: 3009: 3007: 3004: 3002: 2999: 2997: 2994: 2992: 2989: 2987: 2984: 2982: 2979: 2977: 2974: 2972: 2969: 2967: 2964: 2962: 2959: 2957: 2954: 2952: 2949: 2947: 2944: 2942: 2939: 2937: 2934: 2932: 2931:Cycloaddition 2929: 2927: 2924: 2922: 2919: 2917: 2914: 2912: 2909: 2907: 2904: 2902: 2899: 2897: 2894: 2892: 2889: 2887: 2884: 2882: 2879: 2877: 2874: 2872: 2869: 2867: 2864: 2862: 2859: 2857: 2854: 2852: 2849: 2847: 2844: 2842: 2839: 2837: 2834: 2833: 2831: 2829: 2826:Ring forming 2823: 2817: 2814: 2812: 2809: 2807: 2804: 2802: 2799: 2797: 2794: 2792: 2789: 2787: 2784: 2782: 2779: 2777: 2774: 2772: 2769: 2767: 2764: 2762: 2759: 2757: 2754: 2752: 2749: 2747: 2744: 2742: 2739: 2737: 2734: 2732: 2729: 2727: 2726:Rupe reaction 2724: 2722: 2719: 2717: 2714: 2712: 2709: 2707: 2704: 2702: 2699: 2697: 2694: 2692: 2689: 2687: 2684: 2682: 2679: 2677: 2674: 2672: 2669: 2667: 2664: 2662: 2659: 2657: 2654: 2652: 2649: 2647: 2644: 2642: 2639: 2637: 2634: 2632: 2629: 2627: 2624: 2622: 2619: 2617: 2614: 2612: 2609: 2607: 2604: 2602: 2599: 2597: 2594: 2592: 2589: 2587: 2584: 2582: 2579: 2577: 2574: 2572: 2569: 2567: 2564: 2562: 2559: 2557: 2554: 2552: 2549: 2547: 2544: 2542: 2539: 2537: 2534: 2532: 2529: 2527: 2524: 2522: 2519: 2517: 2514: 2512: 2509: 2507: 2504: 2502: 2499: 2497: 2494: 2492: 2489: 2487: 2484: 2482: 2479: 2477: 2474: 2472: 2469: 2467: 2464: 2462: 2459: 2457: 2454: 2452: 2449: 2447: 2444: 2442: 2439: 2437: 2434: 2432: 2429: 2427: 2424: 2422: 2419: 2417: 2414: 2412: 2409: 2407: 2404: 2402: 2399: 2397: 2394: 2392: 2389: 2387: 2384: 2382: 2379: 2377: 2374: 2372: 2369: 2367: 2364: 2362: 2359: 2357: 2354: 2352: 2349: 2348: 2346: 2344: 2338: 2332: 2329: 2327: 2324: 2322: 2319: 2317: 2314: 2312: 2309: 2307: 2304: 2302: 2299: 2297: 2294: 2292: 2289: 2287: 2284: 2282: 2279: 2277: 2274: 2272: 2269: 2267: 2264: 2262: 2259: 2257: 2254: 2252: 2249: 2247: 2244: 2242: 2239: 2237: 2234: 2232: 2229: 2227: 2224: 2222: 2219: 2217: 2214: 2212: 2209: 2207: 2204: 2202: 2199: 2197: 2194: 2192: 2189: 2187: 2184: 2182: 2179: 2177: 2174: 2172: 2169: 2167: 2164: 2162: 2159: 2157: 2154: 2152: 2149: 2147: 2144: 2142: 2139: 2137: 2134: 2132: 2129: 2127: 2124: 2122: 2119: 2117: 2116:Ley oxidation 2114: 2112: 2109: 2107: 2104: 2102: 2099: 2097: 2094: 2092: 2089: 2087: 2084: 2082: 2081:Hydroxylation 2079: 2077: 2074: 2072: 2071:Hydrogenation 2069: 2067: 2064: 2062: 2059: 2057: 2054: 2052: 2049: 2047: 2044: 2042: 2039: 2037: 2034: 2032: 2029: 2027: 2024: 2022: 2019: 2017: 2014: 2012: 2009: 2007: 2006:DNA oxidation 2004: 2002: 1999: 1997: 1996:Deoxygenation 1994: 1992: 1989: 1987: 1984: 1982: 1979: 1977: 1974: 1972: 1969: 1967: 1964: 1962: 1959: 1957: 1954: 1952: 1949: 1947: 1944: 1942: 1939: 1937: 1934: 1932: 1929: 1927: 1924: 1922: 1919: 1917: 1914: 1912: 1909: 1907: 1904: 1902: 1899: 1897: 1894: 1892: 1889: 1887: 1886:Aromatization 1884: 1882: 1879: 1877: 1874: 1872: 1869: 1867: 1864: 1862: 1859: 1857: 1854: 1852: 1849: 1847: 1844: 1843: 1841: 1839: 1833: 1827: 1824: 1822: 1819: 1817: 1814: 1812: 1809: 1807: 1804: 1802: 1799: 1797: 1794: 1792: 1789: 1787: 1784: 1782: 1779: 1777: 1774: 1772: 1769: 1767: 1764: 1762: 1759: 1758: 1756: 1750: 1744: 1741: 1739: 1736: 1734: 1731: 1729: 1726: 1724: 1723:Reed reaction 1721: 1719: 1716: 1714: 1711: 1709: 1706: 1704: 1701: 1699: 1696: 1694: 1691: 1689: 1686: 1684: 1681: 1679: 1676: 1674: 1671: 1669: 1666: 1664: 1661: 1659: 1656: 1654: 1651: 1649: 1646: 1644: 1641: 1640: 1638: 1634:bond forming 1630: 1620: 1617: 1615: 1612: 1610: 1607: 1605: 1602: 1600: 1597: 1595: 1592: 1590: 1587: 1585: 1582: 1580: 1577: 1575: 1572: 1570: 1567: 1565: 1562: 1560: 1557: 1555: 1552: 1550: 1547: 1545: 1542: 1540: 1539:Cope reaction 1537: 1535: 1532: 1530: 1527: 1525: 1522: 1520: 1517: 1516: 1514: 1510: 1504: 1501: 1499: 1496: 1494: 1491: 1489: 1486: 1484: 1481: 1479: 1476: 1474: 1471: 1470: 1468: 1466: 1462: 1456: 1453: 1451: 1448: 1446: 1443: 1441: 1438: 1436: 1433: 1431: 1428: 1426: 1423: 1421: 1418: 1416: 1413: 1411: 1408: 1406: 1403: 1401: 1398: 1396: 1393: 1391: 1388: 1386: 1383: 1381: 1378: 1376: 1373: 1371: 1368: 1366: 1363: 1361: 1358: 1356: 1353: 1351: 1348: 1346: 1343: 1341: 1338: 1336: 1333: 1331: 1328: 1326: 1323: 1321: 1318: 1316: 1313: 1311: 1308: 1306: 1303: 1301: 1298: 1296: 1293: 1291: 1288: 1286: 1283: 1281: 1278: 1276: 1273: 1271: 1268: 1266: 1263: 1261: 1258: 1256: 1253: 1251: 1250:Nef synthesis 1248: 1246: 1243: 1241: 1238: 1236: 1233: 1231: 1228: 1226: 1225:Methylenation 1223: 1221: 1218: 1216: 1213: 1211: 1208: 1206: 1203: 1201: 1198: 1196: 1193: 1191: 1188: 1186: 1183: 1181: 1178: 1176: 1173: 1171: 1168: 1166: 1163: 1161: 1158: 1156: 1153: 1151: 1148: 1146: 1143: 1141: 1138: 1136: 1133: 1131: 1128: 1126: 1123: 1121: 1118: 1116: 1113: 1111: 1108: 1106: 1103: 1101: 1098: 1096: 1095:Heck reaction 1093: 1091: 1088: 1086: 1083: 1081: 1078: 1076: 1073: 1071: 1068: 1066: 1063: 1061: 1058: 1056: 1053: 1051: 1048: 1046: 1043: 1041: 1038: 1036: 1033: 1031: 1028: 1026: 1023: 1021: 1018: 1016: 1013: 1011: 1008: 1006: 1003: 1001: 998: 996: 993: 991: 988: 986: 983: 981: 978: 976: 973: 971: 968: 966: 963: 961: 958: 956: 953: 951: 948: 946: 943: 941: 938: 936: 933: 931: 928: 926: 923: 921: 918: 916: 913: 911: 908: 906: 903: 901: 898: 896: 893: 891: 888: 886: 883: 881: 878: 876: 873: 871: 868: 866: 863: 861: 858: 856: 853: 851: 848: 846: 843: 841: 838: 836: 833: 831: 828: 826: 823: 821: 818: 816: 813: 811: 808: 806: 803: 801: 798: 796: 793: 791: 788: 786: 783: 782: 780: 776:bond forming 772: 768: 763: 757: 754: 752: 749: 747: 744: 742: 741:Y-aromaticity 739: 737: 734: 732: 729: 727: 726:Walsh diagram 724: 722: 719: 717: 714: 712: 711:Taft equation 709: 707: 704: 702: 699: 697: 694: 692: 689: 687: 684: 682: 681:ÎŁ-aromaticity 679: 677: 674: 672: 669: 667: 664: 662: 659: 657: 654: 652: 649: 647: 644: 642: 639: 637: 634: 632: 629: 627: 624: 622: 619: 617: 614: 612: 609: 607: 606:Marcus theory 604: 602: 599: 597: 594: 592: 589: 587: 584: 582: 581:HĂĽckel's rule 579: 577: 574: 572: 569: 567: 564: 562: 559: 557: 554: 552: 549: 547: 544: 542: 539: 537: 536:Evelyn effect 534: 532: 529: 527: 524: 522: 519: 517: 516:Electron-rich 514: 512: 509: 507: 504: 502: 499: 497: 494: 492: 489: 487: 484: 482: 479: 477: 474: 472: 469: 467: 464: 462: 459: 457: 454: 452: 449: 447: 444: 442: 439: 437: 434: 432: 431:Bema Hapothle 429: 427: 424: 422: 419: 417: 414: 412: 409: 407: 404: 402: 399: 397: 394: 392: 389: 387: 384: 382: 379: 378: 375: 369: 366: 364: 361: 359: 356: 354: 351: 349: 346: 344: 341: 339: 336: 334: 331: 329: 326: 324: 321: 320: 317: 313: 305: 300: 298: 293: 291: 286: 285: 282: 272: 267: 258: 251: 247: 246: 241: 239: 236:"Pentaacetyl 230: 221: 214: 210: 209: 204: 203:"D-Arabinose" 197: 189: 185: 181: 177: 173: 169: 163: 159: 149: 146: 145: 139: 137: 133: 129: 125: 121: 120:H.J.H. Fenton 117: 113: 103: 101: 97: 92: 90: 86: 82: 78: 74: 70: 66: 62: 61:hydroxylamine 58: 54: 45: 41: 40:(1863–1939). 39: 35: 31: 27: 23: 19: 2531:Ene reaction 1891:Autoxidation 1825: 1752:Degradation 1643:Azo coupling 1420:Ugi reaction 1020:Ene reaction 820:Alkynylation 671:Polyfluorene 666:Polar effect 531:Electrophile 446:Bredt's rule 416:Baird's rule 386:Alpha effect 270: 266: 256: 249: 243: 237: 229: 219: 212: 206: 196: 179: 175: 162: 148:Nef reaction 111: 109: 93: 50: 17: 15: 1030:Ethenolysis 676:Ring strain 646:Nucleophile 471:Clar's rule 411:Aromaticity 73:acetic acid 38:Alfred Wohl 3593:Categories 3314:Ozonolysis 2841:Annulation 2191:Ozonolysis 310:Topics in 176:Chem. Ber. 154:References 87:groups to 2828:reactions 2343:reactions 1838:reactions 1754:reactions 1636:reactions 778:reactions 116:Otto Ruff 91:groups. 53:d-glucose 34:arabinose 721:Vinylogy 391:Annulene 338:Reagents 170:(1893), 168:Wohl, A. 142:See also 100:methanol 381:A value 124:bromine 89:acetate 85:alcohol 81:nitrile 30:glucose 26:aldoses 118:1898, 75:with 57:oxime 252:: 74 215:: 14 134:and 126:and 63:and 16:The 184:doi 98:in 71:in 32:to 20:in 3595:: 261:.. 254:; 250:20 248:. 242:. 224:.. 217:; 213:20 211:. 205:. 180:26 178:, 174:, 138:. 303:e 296:t 289:v 238:d 191:. 186:: 114:(

Index

carbohydrate chemistry
aldoses
glucose
arabinose
Alfred Wohl
The Wohl degradation
d-glucose
oxime
hydroxylamine
sodium methoxide
acetic anhydride
acetic acid
sodium acetate
nitrile
alcohol
acetate
sodium methoxide
methanol
Otto Ruff
H.J.H. Fenton
bromine
calcium hydroxide
Iron(III) sulfate
hydrogen peroxide
Nef reaction
Wohl, A.
"Abbau des Traubenzuckers"
doi
10.1002/cber.189302601150
"D-Arabinose"

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